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The paper presents the experimental research findings for the patterns of collisions of water droplets with pressed tableted samples used as substrates and with small particles of a pyrolyzing solid fuel. Brown coal samples were used. Droplet-substrate interactions were studied when varying the droplet diameter in the range from 1 to 4 mm and velocity from 0.5 to 4 m/s. That corresponded to the Weber number range of 7–830. The coal tablet surface temperature was varied from 20 to 700 °C. In the interactions of water droplets (0.7–1.5 mm in diameter, pre-collision velocity from 1 to 3 m/s) with coal particles (with a size of 0.2–1 mm, pre-collision velocity 0.7–2 m/s), the temperature of the latter was varied in the range of 330–480 °C. The following regimes of the interaction of droplets with solid particles during chemical reactions and phase transformations were distinguished: spreading/agglomeration and break-up/separation. Differences in the characteristics of the interaction of water droplets with coal particles at varying temperatures were identified. Droplet-particle interaction regime maps for B(We), We(Oh) and We(Ca) were constructed. The collision regime boundaries were described using fitted curves that can be utilized to develop the existing mathematical models of droplet-particle collisions in gas. It was established that the gaseous volatile production in coal pyrolysis has a modest effect on the regimes and characteristics of the droplet destruction in the temperature range under consideration (20–700 °C).

The synthesis and dissociation of methane hydrate and carbon dioxide hydrate were studied. Nonflammable gas hydrates can be used to extinguish flames in confined spaces. To increase the extinguishing efficiency, it is necessary to increase the dissociation rate (gas release rate) by using surfactant. The work investigates gas hydrates synthesized using sodium dodecyl sulfate (SDS). Experimental studies were carried out in wide ranges of surfactant concentration, the number of the stirrer revolutions and the initial water volume. To achieve the maximum rate of synthesis and dissociation, optimization of the specified parameters was performed. The influence of the key parameters on the dissociation rate was investigated experimentally and theoretically. The novelty of the work lies in solving a complex of interrelated tasks on the synthesis and dissociation of gas hydrate. It is shown that in order to achieve the maximum dissociation rate of carbon dioxide hydrate, it is necessary to optimize the following parameters: the diameter of the particles and their porosity, the porosity of the layer and the external heat flux.

The effect of coal hydrophilic particles in water-glycerol drops on the maximum diameter of spreading along a hydrophobic solid surface is experimentally studied by analyzing the velocity of internal flows by Particle Image Velocimetry (PIV). The grinding fineness of coal particles was 45–80 μm and 120–140 μm. Their concentration was 0.06 wt.% and 1 wt.%. The impact of particle-laden drops on a solid surface occurred at Weber numbers (We) from 30 to 120. It revealed the interrelated influence of We and the concentration of coal particles on changes in the maximum absolute velocity of internal flows in a drop within the kinetic and spreading phases of the drop-wall impact. It is explored the behavior of internal convective flows in the longitudinal section of a drop parallel to the plane of the solid wall. The kinetic energy of the translational motion of coal particles in a spreading drop compensates for the energy expended by the drop on sliding friction along the wall. At We = 120, the inertia-driven spreading of the particle-laden drop is mainly determined by the dynamics of the deformable Taylor rim. An increase in We contributes to more noticeable differences in the convection velocities in spreading drops. When the drop spreading diameter rises at the maximum velocity of internal flows, a growth of the maximum spreading diameter occurs. The presence of coal particles causes a general tendency to reduce drop spreading.

Gas hydrates, being promising energy sources, also have good prospects for application in gas separation and capture technologies (e.g., CO2 sequestration), as well as for seawater desalination. However, the widespread use of these technologies is hindered due to their high cost associated with high power consumption and the low growth rates of gas hydrates. Previous studies do not comprehensively disclose the combined effect of several surfactants. In addition, issues related to the kinetics of CO2 hydrate dissociation in the annealing temperature range remain poorly investigated. The presented review suggests promising ways to improve efficiency of gas capture and liquid separation technologies. Various methods of heat and mass transfer enhancement and the use of surfactants allow the growth rate to be significantly increased and the degree of water transformation into gas hydrate, which gives impetus to further advancement of these technologies. Taking the kinetics of this into account is important for improving the efficiency of gas hydrate storage and transportation technologies, as well as for enhancing models of global climate warming considering the increase in temperatures in the permafrost region.

This paper presents experimental research findings on the gas composition of pyrolysis and combustion products of typical forest fuels (leaves, needles, twigs, a mixture of these, and timber). These experiments were performed for the combustion and application of a fire extinguishing agent to a pyrolyzing material. Water, a bischofite solution, a bentonite slurry, and a foaming agent solution were utilized. Two gas analysis systems were used, as follows: an industrial one based on CO2, CO, H2, CH4, and O2 sensors and a scientific one (a gas analyzer with H2, CH4, H2S, SO2, CO, and CO2 sensors). Fires were extinguished by using two common techniques, as follows: continuous liquid supply and cycling spraying. The comparative efficiency of applying a group of fire extinguishing agents to forest fires was estimated, taking account of liquid consumption, suppression time, and environmental pollution. A method was proposed for calculating the relative efficiency factors of fire extinguishing agents when containing and suppressing forest fires, allowing for the consumed time, resources, and anthropogenic emissions.

Gas hydrates are promising components for a wide range of industries and the national economy. This paper outlines the gas hydrate application areas with the greatest potential. Gas hydrates of methane, ethane, propane, carbon dioxide and freon were investigated. Double gas hydrates were found to be coming into use. Natural and artificial hydrates are now being exploited. The main properties and component composition of hydrates, as well as their extraction methods are described. The key aspects of using hydrates in the energy industry, gas chemistry and petrochemistry, heat exchange systems and fire safety management are highlighted. These specific aspects were identified by analyzing the known experimental findings, results of mathematical modeling, bench and field tests, as well as trial runs of industrial systems. The recent advances in science and technology in this field were analyzed. The range of tasks that need to be tackled to improve the efficiency of using gas hydrates are defined.

This paper presents the experimental findings on fire containment and suppression by dropping CO2 hydrate granules and tablets on burning solid materials. We used the combustible materials typical of compartment fires—wood, linoleum, and cardboard—to determine the volume and mass of gas hydrate powder necessary for the effective fire suppression. Gaseous emissions were recorded from the combustion with and without fire suppression using hydrates. Conditions were specified in which a fire can be extinguished with minimum air pollution. We also identified the conditions for effective fire containment and suppression using hydrates as compared to water spray, snow, and ice. The necessary volume of hydrate was determined for effective fire suppression in a compartment filled with various materials. Experimental data show that the impact of temperature on the CO2 hydrate decomposition is highly nonlinear. The carbon dioxide hydrate exhibited a much better fire suppression performance than water spray in the course of total flooding of solid combustible materials. It was established that fine water spray failed to reach the lower levels of multi-tier crib fires. Finally, key patterns of total flooding with CO2 hydrate powder were identified when applied to fires.

The characteristics of the collisions of droplets with the surfaces of particles and substrates of promising oil–water slurry components (oil, water and coal) were experimentally studied. Particles of coals of different ranks with significantly varying surface wettability were used. The following regimes of droplet–particle collisions were identified: agglomeration, stretching separation and stretching separation with child droplets. The main characteristics of resulting child droplets were calculated. Droplet–particle interaction regime maps in the B = f(We) coordinates were constructed. Equations to describe the boundaries of transitions between the droplet–particle interaction regimes (B = nWek) were obtained. The calculated approximation coefficients make it possible to predict threshold shifts in transition boundaries between the collision regimes for different fuel mixture components. Differences in the characteristics of secondary atomization of droplets interacting with particles were established. Guidelines were provided on applying the research findings to the development of technologies of composite liquid fuel droplet generation in combustion chambers with the separate injection of liquid and solid components, as well as technologies of secondary atomization of fuel droplets producing fine aerosol.

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This paper presents the numerical research findings for the conditions and characteristics of methane-propane hydrate particle ignition. The curves of the ignition delay times of a hydrate particle versus its size and ambient temperature were obtained. The effect of the rates of phase transformations (evaporation and dissociation) on the hydrate particle ignition behavior was analyzed. Following the mathematical modeling of the processes under study using different heating schemes of gas hydrates, the patterns of processes developing in a particle during the induction period were identified. It was established that the ignition behavior of methane, propane, and other gases was significantly different from that of other gases produced from hydrate decomposition. The established differences form the basis for predicting the characteristics of gas hydrate ignition at different power plants.

This paper presents experimental research findings for those involved in the early phase of fire in office buildings. Class A model fires with a reaction area from 5 cm2 to 300 cm2 were chosen for investigation. To mock up a fire, the following combustible materials typical of offices were used: wood pieces, heat-insulated linoleum, paper and cardboard. The main characteristics of a model fire were recorded: temperature in the combustion zone, heat release, time of complete burnout and concentration of flue gas components. Typical trends and histograms of changes of these characteristics over time were presented; stages of ignition, flame combustion and smoldering were illustrated. The key characteristics of fire detector activation at different stages of model fire combustion were analyzed. Dead bands and operation conditions of a group of detectors (smoke, heat, optical, flame), their response time and errors were identified. It has been established that the most effective detectors are flame and smoke detectors. Specific operational aspects of detectors were established when recording the ignition of different types of model fires. The viability of combining at least two detectors to record fire behavior was established. Recommendations were made on using the obtained findings when optimizing the systems for detecting and recording the start of a compartment fire.

By adding water to fuels, several objectives are pursued, with the main ones being to stabilize combustion, minimize the anthropogenic gaseous emissions, homogenize and stabilize the fuel, as well as improve its fire and explosion safety. Water can be injected into the furnace as droplets or vapor and introduced as part of fuel samples. Water often serves as a coupling or carrier medium for the delivery of the main fuel components. In this paper, we compare the combustion behaviors of high-potential slurry fuels and gas hydrates. We also analyze the contribution of in slurries and gas hydrates to the combustion process. The values of relative combustion efficiency indicators are determined for gas hydrates and slurry fuels. The conditions are identified in which these fuels can be burned effectively in power plants. The research findings can be used to rationalize the alternative ways of using water resources, i.e., gas hydrate powder and promising composite fuel droplets. The results can also help predict the conditions for the shortest possible ignition delay, as well as effective combustion of gas hydrates as the most environmentally friendly new-generation alternative fuel.

Gas hydrates are widespread all over the world. They feature high energy density and are a clean energy source of great potential. The paper considers experimental and theoretical studies on gas hydrates in the following key areas: formation and dissociation, extraction and transportation technologies of natural methane hydrates, and ignition, and combustion. We identified a lack of research in more areas and defined prospects of further development of gas hydrates as a promising strategic resource. One of the immediate problems is that there are no research findings for the effect of sediments and their matrices on hydrate saturation, as well as on gas hydrate formation and dissociation rates. No mathematical models describe the dissociation of gas hydrates under various conditions. There is a lack of research into the renewal and improvement of existing technologies for the easier and cheaper production of gas hydrates and the extraction of natural gas from them. There are no models of gas hydrate ignition taking into account dissociation processes and the self-preservation effect.

The article discusses the modern achievements in the field of thermal recovery of industrial and municipal waste. The average accumulation rate and calorific value of typical wastes were analyzed. The focus is on the opportunities to exploit the energy potential of high-moisture waste, low-grade liquid components, and fuel slurries. We consider the relevant results in the field of combustion, pyrolysis, and gasification of such fuels. The main attention is paid to synergistic effects, the influence of additives, and external conditions on the process performance. Vortex combustion chambers, boilers with burners, and nozzles for fuel injection, grate, and fluidized bed boilers can be used for the combustion of waste-derived liquid, high-moisture, and slurry fuels. The following difficulties are possible: long ignition delay, incomplete combustion, low combustion temperature and specific calorific value, high emissions (including particulate matter, polycyclic aromatic hydrocarbons), fast slagging, and difficult spraying. A successful solution to these problems is possible due to the use of auxiliary fuel; boiler modifications; oxy-fuel combustion; and the preparation of multi-component fuels, including the use of additives. An analysis of methods of waste recovery in the composition of slurries for fuel gas production showed that there are several main areas of research: pyrolysis and gasification of coal–water slurry with additives of oil waste; study of the influence of external conditions on the characteristics of final products; and the use of specialized additives and catalysts to improve the efficiency of the pyrolysis and gasification. The prospects for improving the characteristics of thermochemical conversion of such fuels are highlighted.

The paper presents the experimental research findings for the integral characteristics of processes developing when two-phase liquid droplets collide in a heated gas medium. The experiments were conducted in a closed heat exchange chamber space filled with air. The gas medium was heated to 400–500 °C by an induction system. In the experiments, the size of initial droplets, their velocities and impact angles were varied in the ranges typical of industrial applications. The main varied parameter was the percentage of vapor (volume of bubbles) in the droplet (up to 90% of the liquid volume). The droplet collision regimes (coalescence, bounce, breakup, disruption), size and number of secondary fragments, as well as the relative volume fraction of vapor bubbles in them were recorded. Differences in the collision regimes and in the distribution of secondary fragments by size were identified. The areas of liquid surface before and after the initial droplet breakup were determined. Conditions were outlined in which vapor bubbles had a significant and, on the contrary, fairly weak effect on the interaction regimes of two-phase droplets.

A model was developed to research the critical conditions and time characteristics of the ignition of gel fuels in the course of conductive, convective, radiant and mixed heat transfer. MATLAB was used for numerical modeling. Original MATLAB code was established pursuant to the developed mathematical model. For gel fuel ignition at initial temperatures corresponding to cryogenic storage conditions with different heating schemes, a numerical analysis of interconnected processes of heat and mass transfer in the chemical reaction conditions and exothermic and endothermic phase transitions was conducted. The model was tested by comparing the theoretical results with the experimental data. Dependencies were established between the key process characteristic (i.e., the ignition delay time) and the ambient temperature when the following parameters were varied: emissivity, heat emission coefficient, activation energy and pre-exponential factor of the fuel vapor oxidation reaction. The critical values of the main parameters of the energy source were determined. For these values, gel fuel ignition conditions were consistently realized for each heating scheme. The critical heat fluxes necessary and sufficient for the ignition of typical gel fuels were determined.

The article presents the results of theoretical and experimental studies of coalescence, disruption, and fragmentation of liquid droplets in multiphase and multicomponent gas-vapor-droplet media. Highly promising approaches are considered to studying the interaction of liquid droplets in gaseous media with different compositions and parameters. A comparative analysis of promising technologies is carried out for the primary and secondary atomization of liquid droplets using schemes of their collision with each other. The influence of a range of factors and parameters on the collision processes of drops is analyzed, in particular, viscosity, density, surface, and interfacial tension of a liquid, trajectories of droplets in a gaseous medium, droplet velocities and sizes. The processes involved in the interaction of dissimilar droplets with a variable component composition and temperature are described. Fundamental differences are shown in the number and size of droplets formed due to binary collisions and collisions between droplets and particles at different Weber numbers. The conditions are analyzed for the several-fold increase in the number of droplets in the air flow due to their collisions in the disruption mode. A technique is described for generalizing and presenting the research findings on the interaction of drops in the form of theoretical collision regime maps using various approaches.

Cylinder-shaped fuel pellets that were 3 mm in diameter and 3 mm in height, with a mass of 20 mg, were produced by compressing dry coal processing waste under the pressure of 5 MPa. The first group of pellets from coal dust with a particle size less than 140 µm did not contain any additives. The pellets of the second group of fuel compositions contained an oil-impregnated porous polymer material particle with a size of 0.5 mm in the central part of the experimental sample. The particle was surrounded by coal dust from all sides. The ratio of components was 90:10% for coal dust: polymer particle. The latter value almost completely corresponds to the fraction of oil in the fuel composition, since the mass of a porous polymer material particle is negligible. The third group of compositions was a 70:30% mixture of coal dust with wood sawdust with a particle size less than 45 µm, or 45–100, 100–200 and 200–500 µm. The ignition and combustion of single fuel pellets were studied under radiant heating in an air medium while varying the temperature from 800 to 1000 °C. The processes during the fuel combustion were recorded by a high-speed video camera, and the concentrations of the main anthropogenic emissions in flue gases were measured by a gas analyzer. The main characteristics were established—ignition delay times (2–8 s) and duration of burnout (40–90 s)—at different heating temperatures. A difference was established in the combustion mechanisms of the pellets, when adding various components to the fuel mixture composition. This has a direct influence on the induction period duration and combustion time, other conditions being equal, as well as on the concentration of nitrogen and sulfur oxides in the flue gases. Adding an oil-impregnated porous polymer particle to the fuel composition intensifies ignition and combustion, since the times of ignition delay and complete burnout of fuel pellets under threshold conditions decrease by 70%, whereas adding wood sawdust reduces the content of nitrogen and sulfur oxides in the flue gases by 30% and 25%, respectively.

Anthropogenic emissions from coal combustion pose a serious threat to human wellbeing. One prospective way to solve this problem is by using slurry fuels instead of coal. The problem is especially pressing in China and Russia, so these countries need reliable experimental data on the SOx and NOx emissions reduction range more than others do. The experiments in this research are based on the components that are typical of Russia. Experimental research was conducted on the way typical forest fuels (ground pine needles, leaves and their mixtures, bark, sawdust, and charcoal) affect the gas emissions from the combustion of slurry fuels based on the wastes. It was established that using forest fuels as additives to coal-water slurries reduces SOx and NOx emissions by 5–91% as compared to coal or to slurries based on used turbine oil. It was revealed that even small concentrations of such additives (7–15%) could result in a several-fold reduction in SOx and NOx. The higher the temperature, the more prominent the role of forest biomass. The calculated complex criterion illustrates that forest fuels increase the performance indicator of fuel suspensions by 1.2–10 times.

The paper presents the results of experimental research into the heating and evaporation of droplets of water and water-based solutions, emulsions, and slurries. The main focus is on the potential opportunities of gaining new insight into the temperature fields of evaporating droplets of solutions, emulsions, and slurries, using a promising optical technique, planar-laser-induced fluorescence (PLIF). An important aspect was to define the limitations of this technique when varying droplet dimensions, the concentration and properties of additives, as well as heating conditions. Such experiments were necessary to identify opportunities to develop a large group of applications (such as thermal and flame cleaning of liquids from unspecified impurities, the production of hydrogen and syngas by heating oil-water or coal-water slurries, firefighting, etc) in order to increase the efficiency by means of high values of heating rates, phase transformations, and chemical reactions. Such values can be achieved by implementing the processes under extreme conditions, which can only be studied using non-contact techniques, in particular, PLIF. [ABSTRACT FROM AUTHOR]