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Conventional Al-air battery has many disadvantages for miniwatt applications, such as the complex water management, bulky electrolyte storage and potential leakage hazard. Moreover, the self-corrosion of Al anode continues even when the electrolyte flow is stopped, leading to great Al waste. To tackle these issues, an innovative cotton-based aluminum-air battery is developed in this study. Instead of flowing alkaline solution, cotton substrate pre-deposited with solid alkaline is used, together with a small water reservoir to continuously wet the cotton and dissolve the alkaline in-situ. In this manner, the battery can be mechanically recharged by replacing the cotton substrate and refilling the water reservoir, while the thick aluminum anode can be reused for tens of times until complete consumption. The cotton substrate shows excellent ability for the storage and transportation of alkaline electrolyte, leading to a high peak power density of 73 mW cm−2 and a high specific energy of 930 mW h g−1. Moreover, the battery discharge capacity is found to be linear to the loading of pre-deposited alkaline, so that it can be precisely controlled according to the mission profile to avoid Al waste. Finally, a two-cell battery pack with common water reservoir is developed, which can provide a voltage of 2.7 V and a power output of 223.8 mW. With further scaling-up and stacking, this cotton-based Al-air battery system with low cost and high energy density is very promising for recharging miniwatt electronics in the outdoor environment.

Atmospheric CO2 concentrations are soaring due to the continued use of fossil fuels in energy production, an anthropogenic activity that is playing a leading role in global warming. Thus, research aimed at the capture and conversion of CO2 into value-added products, such as cyclic carbonates, is booming. While CO2 is an abundant, cheap, non-toxic, and readily accessible C1 feedstock, its thermodynamic stability necessitates the development of highly efficient catalysts that are able to promote chemical reactions under mild conditions. In this work, a novel mesoporous poly(ionic liquid) with dual active sites was synthesized through a facile method that involves co-polymerization, post-synthetic metalation, and supercritical CO2 drying. Due to a high density of nucleophilic and electrophilic sites, the as-prepared poly(ionic liquid), denoted as P2D-4BrBQA-Zn, offers excellent performance in a CO2 cycloaddition reaction using epichlorohydrin as the substrate (98.9% conversion and 96.9% selectivity). Moreover the reaction is carried out under mild, solvent-free, and additive-free conditions. Notably, P2D-4BrBQA-Zn also efficiently promotes the conversion of various other epoxide substrates into cyclic carbonates. Overall, the catalyst is found to have excellent substrate compatibility, stability, and recyclability.

Electrochemical CO2 reduction (CO2RR) over molecular catalysts is a paramount approach for CO2 conversion to CO. Herein, we report a novel phthalocyanine-derived catalyst synthesized by a two-step method with a much improved electroconductivity. Furthermore, the catalyst contains both Ni–N4 sites and highly dispersed metallic Ni nanoclusters, leading to an increased CO2RR currents by two folds. Isotope labelling study and in situ spectroscopic analysis demonstrate that the existence of metallic Ni nanoclusters is the key factor for the activity enhancement and can shift the CO2RR mechanism from being electron transfer (ET)-limited (forming ∗COO−) to concerted proton-electron transfer (CPET)-limited (forming CO).

In the conversion process of syngas-to-C2 species, the OH species are inevitably produced accompanying the production of key intermediates CHx(x = 1–3), traditionally, the function of surface OH species is generally accepted as the hydrogenating reactive species. This work for the first time proposed and confirmed the assisted catalytic mechanism of surface OH species that performed as the promoter for syngas-to-C2 species on Cu-based catalysts. DFT and microkinetic modeling results reveal that the produced OH species accompanying the intermediates CHx production on the MCu (M = Co, Fe, Rh) catalysts can stably exist to form OH/MCu catalysts, on which the presence of surface OH species as the promoter not only presented better activity and selectivity toward CHx(x = 1–3) compared to MCu catalysts, but also significantly suppressed CH3OH production, providing enough CHx sources to favor the production of C2 hydrocarbons and oxygenates. Correspondingly, the electronic properties analysis revealed the essential relationship between the electronic feature of OH/MCu catalysts and catalytic performance, attributing to the unique electronic micro−environment of the catalysts under the interaction of surface OH species. This new mechanism is called as OH-assisted catalytic mechanism, which may be applied in the reaction systems related to the generation of OH species.

Synthesizing nitrogen (N)-containing molecules from biomass derivatives is a new strategy for production of this kind of chemicals. Herein, for the first time we present the synthesis of N-substituted aryl pyrroles via reductive amination/cyclization of levulinic acid (LA) with primary aromatic amines and hydrosilanes (e.g., PMHS) over CsF, and a series of N-substituted aryl pyrroles could be obtained in good to excellent yields at 120 °C. The mechanism investigation indicates that the reaction proceeds in two steps: the cyclization between amine and LA occurs first to form intermediate 5-methyl-N-alkyl-1,3-dihydro-2H-pyrrolones and their isomeride (B), and then the chemo- and region-selective reduction of intermediates take place to produce the final products. This approach for synthesis of N-substituted aryl pyrroles can be performed under mild and green conditions, which may have promising applications.

Effective and robust electrocatalysts are mainly based on innovative materials and unique structures. Herein, we designed a flakelike cobalt phosphide-based catalyst supporting on NiCo2O4 nanorods array, which in-situ grew on the nickel foam (NF) current collector, referring as N–Co2P/NiCo2O4/NF electrode. By optimizing the microstructure and electronic structure through 3D hierarchy fabrication and nitrogen doping, the catalyst features with abundant electrochemical surface area, favorable surface wettability, excellent electron transport, as well as tailored d band center. Consequently, the as-prepared N–Co2P/NiCo2O4/NF electrode exhibits an impressive HER activity with a low overpotentials of 58 mV at 10 mA cm−2, a Tafel slop of 75 mV dec−1, as well as superior durability in alkaline medium. This work may provide a new pathway to effectively improve the hydrogen evolution performance of transition metal phosphides and to develop promising electrodes for practical electrocatalysis.

Owing to the advantages of high operating voltage, environmental benignity, and low cost, potassium-based dual-ion batteries (KDIBs) have been considered as a potential candidate for large-scale energy storage. However, KDIBs generally suffer from poor cycling performance and unsatisfied capacity, and inactive components of conductive agents, binders, and current collector further lower their overall capacity. Herein, we prepare coral-like carbon nanowires (CCNWs) doped with nitrogen as a binder-free anode material for K+-ion storage, in which the unique coral-like porous nanostructure and amorphous/short-range-ordered composite feature are conducive to enhancing the structural stability, to facilitating the ion transfer and to boosting the full utilization of active sites during potassiation/de-potassiation process. As a result, the CCNW anode possesses a hybrid K+-storage mechanism of diffusive behavior and capacitive adsorption, and stably delivers a high capacity of 276 mAh g-1 at 50 mA g-1, good rate capability up to 2 A g-1, and long-term cycling stability with 93 % capacity retention after 2000 cycles at 1 A g-1. Further, assembling this CCNW anode with an environmentally benign expanded graphite (EG) cathode yields a proof-of-concept KDIB, which shows a high specific capacity of 134.4 mAh g-1 at 100 mA g-1, excellent rate capability of 106.5 mAh g-1 at 1 A g-1, and long-term cycling stability over 1000 cycles without negligible capacity loss. This study provides a feasible approach to developing high-performance anodes for potassium-based energy storage devices.

Co–N–C is a promising oxygen electrochemical catalyst due to its high stability and good durability. However, due to the limited adsorption ability improvement for oxygen-containing intermediates, it usually exhibits inadequate catalytic activity with 2-electron pathway and high selectivity of hydrogen peroxide. Herein, the adsorption of Co–N–C to these intermediates is modulated by constructing heterostructures using transition metals and their derivatives based on d-band theory. The heterostructured nanobelts with MoC core and pomegranate-like carbon shell consisting of Co nanoparticles and N dopant (MoC/Co–N–C) are engineered to successfully modulate the d band center of active Co–N–C sites, resulting in a remarkably enhanced electrocatalysis performance. The optimally performing MoC/Co–N–C exhibits outstanding bi-catalytic activity and stability for the oxygen electrochemistry, featuring a high wave-half potential of 0.865 V for the oxygen reduction reaction (ORR) and low overpotential of 370 mV for the oxygen evolution reaction (OER) at 10 mA cm−2. The zinc air batteries with the MoC/Co–N–C catalyst demonstrate a large power density of 180 mW cm−2 and a long cycling lifespan (2000 cycles). The density functional theory calculations with Hubbard correction (DFT + U) reveal the electron transferring from Co to Mo atoms that effectively modulate the d band center of the active Co sites and achieve optimum adsorption ability with “single site double adsorption” mode.

Plasma methods are given significant attention in the context of conditioning the producer gas derived from biomass gasification. The goal of this work is to present the impact of hydrogen on the other producer gas compounds during microwave plasma valorization. These compounds include main producer gas components (CO, CO2, CH4, N2) and minor impurities (tar compounds, H2S and NH3). The results prove a beneficial impact of hydrogen addition on the conversion of CH4 and toluene, increasing it from ca. 68%–95% and ca. 97%–100%, respectively. Additionally, the presence of hydrogen changes the distribution of the products, inhibiting soot and aromatics production and promoting C2 compounds. In the case of CO2, the conversion increases from ca. 18%–63% when compared to nitrogen plasma, with CO being the resulting product. The presence of hydrogen inhibits H2S conversion and does not affect CO and NH3

There is increased mobile telecommunications penetration across Nigeria. One of the realities connected to such penetration is the news-text services offered by the country’s 9Mobile mobile telecommunications company. This content analysis and covert non-participant observation research examined news entrepreneurial and citizen journalism potentials of the service. Findings show that news SMS service is encouraging, but issues such as delayed delivery and incomplete replications concurrently hamper entrepreneurial and citizen journalism benefits. The degree of diversity of 9Mobile news SMS contents is also poor. Nevertheless, there was significant use of prominent news stories – as derived from the hardcopies of the sourcing national newspapers. The research notes the need for news SMS copyright and plagiarism checks alongside other professional standards. Overall, it is pertinent to reiterate that irrespective of shortcomings, convergent news deliveries of 9Mobile SMS-MoreNews retain significant potentials for entrepreneurship and citizen journalism.

Tree fruit architecture results from combination of the training system and pruning and thinning processes across multiple growth and development years. Further, the tree fruit architecture contributes to the light interception and improves tree growth, fruit quality, and fruit yield, in addition to easing the process of orchard management and harvest. Currently tree architectural traits are measured manually by researchers or growers, which is labor-intensive and time-consuming. In this study, the remote sensing techniques were evaluated to phenotype critical architectural traits with the final goal to assist tree fruit breeders, physiologists and growers in collecting architectural traits efficiently and in a standardized manner. For this, a consumer-grade red–green–blue (RGB) camera was used to collect apple tree side-images, while an unmanned aerial vehicle (UAV) integrated RGB camera was programmed to image tree canopy at 15 m above ground level to evaluate multiple tree fruit architectures. The sensing data were compared to ground reference data associated with tree orchard blocks within three training systems (Spindle, V-trellis, Bi-axis), two rootstocks (‘WA 38 trees grafted on G41 and M9-Nic29) and two pruning methods (referred as bending and click pruning). The data were processed to extract architectural features from ground-based 2D images and UAV-based 3D digital surface model. The traits extracted from sensing data included box-counting fractal dimension (DBs), middle branch angle, number of branches, trunk basal diameter, and tree row volume (TRV). The results from ground-based sensing data indicated that there was a significant (P

In molecular communications, the direct detection of signaling molecules may be challenging due to a lack of suitable sensors and interference in the environment. Motivated by research in molecular biology, we investigate an indirect detection mechanism using chemical reactions between the signaling molecules and a molecular probe to produce an easy-to-measure product at the receiver. We consider two implementations of the proposed detection mechanism, i.e., unrestricted probe movement and probes restricted to a volume around the receiver. The reaction-diffusion equations describing the concentrations of the reactant and product molecules in the system are non-linear and coupled, and cannot be solved in closed form. Therefore, we develop an efficient iterative algorithm by discretizing the time variable and solving for the space variables of the equations in each time step. Our results show that the concentrations of the product molecules and the signalling molecules share a similar characteristic over time, i.e., a single peak and a long tail. The peak and tail values of the product molecule concentration can be controlled by choosing probes with suitable parameters. By carefully choosing the molecular probe and optimizing the decision threshold, the BER can be improved significantly and outperform that of a direct detection system., 13 pages, 11 figures, 1 table. This journal version was submitted in April 2022 to the IEEE for possible publication. A part of this article was presented at the IEEE Wireless Communications and Networking Conference 2020 and stored in the previous version on arXiv

Today there is a rapid development taking place in phenotyping of plants using non-destructive image based machine vision techniques. Machine vision based plant phenotyping ranges from single plant trait estimation to broad assessment of crop canopy for thousands of plants in the field. Plant phenotyping systems either use single imaging method or integrative approach signifying simultaneous use of some of the imaging techniques like visible red, green and blue (RGB) imaging, thermal imaging, chlorophyll fluorescence imaging (CFIM), hyperspectral imaging, 3-dimensional (3-D) imaging or high resolution volumetric imaging. This paper provides an overview of imaging techniques and their applications in the field of plant phenotyping. This paper presents a comprehensive survey on recent machine vision methods for plant trait estimation and classification. In this paper, information about publicly available datasets is provided for uniform comparison among the state-of-the-art phenotyping methods. This paper also presents future research directions related to the use of deep learning based machine vision algorithms for structural (2-D and 3-D), physiological and temporal trait estimation, and classification studies in plants.

Influenza polymerase (FluPol) plays a key role in the viral infection cycle by transcribing and replicating the viral genome. FluPol is a multifunctional, heterotrimeric enzyme with cap-binding, endonuclease, RNA-dependent RNA polymerase and polyadenylation activities. It performs its functions in the context of the viral ribonucleoprotein particle (RNP), wherein the template viral RNA is coated by multiple copies of viral nucleoprotein. Moreover, it interacts with a number of host proteins that are essential cofactors and, consequently, adaptive mutations in the polymerase are required for crossing the avian-human species barrier. In this review, we show how mechanistic understanding of how FluPol performs its multiple functions has greatly advanced over the last decade through determination of high-resolution structures by X-ray crystallography and cryo-electron microscopy. These have revealed not only the detailed architecture of FluPol but highlighted the remarkably conformational flexibility that is inherent to its functioning as a dynamic RNA synthesis machine. Structural studies are also underpinning current attempts to develop next-generation anti-influenza drugs that directly target FluPol.

This highlight is the second installment of a series of highlights on nonprecious-metal-catalyzed reactions of interest to the pharmaceutical industry. Selected transformations from March to June 2...

Defect-engineered carbon materials have been emerged as promising electrocatalysts for oxygen reduction reaction (ORR) in metal-air batteries. Developing a facile strategy for the preparation of highly active nanocarbon electrocatalysts remains challenging. Herein, a low-cost and simple route is developed to synthesize defective graphene by pyrolyzing the mixture of glucose and carbon nitride. Molecular dynamics simulations reveal that the graphene formation is ascribed to two-dimensional layered feature of carbon nitride, and high compatibility of carbon nitride/glucose systems. Structural measurements suggest that the graphene possesses rich edge and topological defects. The graphene catalyst exhibits higher power density than commercial Pt/C catalyst in a primary Zn-air battery. Combining experimental results and theoretical thermodynamic analysis, it is identified that graphitic nitrogen-modified topological defects at carbon framework edges are responsible for the decent ORR performance. The strategy presented in this work can be can be scaled up readily to fabricate defective carbon materials.

Synthesizing ring structure aviation fuels from biomass-derived platform molecules is challenging, especially for bridged ring structure aviation fuels which are typically achieved from fossil-derived chemicals. Herein, we report the synthesis of a series of ring structure biofuels in two steps by a combination of a solvent-free Michael-cyclization reaction and a hydrodeoxygenation (HDO) reaction from lignocellulose-derived 5,5-dimethyl-1,3-cyclohexanedione. These biofuels are obtained with high overall yields up to 90%, which exhibit high densities of 0.81 g cm−3-0.88 g cm−3 and high volumetric neat heat of combustion (VNHOC) values of 36.0 MJ L−1-38.6 MJ L−1. More importantly, bridged-ring structure hydrocarbons can also be achieved in two steps by a combination of a Robinson annulation reaction and an HDO reaction to afford the final products at high overall yields up to 90%. The bridged-ring structure products have comparable high densities and high VNHOC values to the best artificial fuel JP-10 (0.94 g cm−3 and 39.6 MJ L−1). The results demonstrate a promising way for the synthesis of high-density aviation fuels with different fuel properties at high yields.

3D flower-like hierarchical mesoporous Bi4O5I2/MoS2 Z-scheme layered heterojunction photocatalyst was fabricated by oil bath and hydrothermal methods. The heterojunction with narrow band gap of ∼1.95 eV extended the photoresponse to near-infrared region, which showed obvious photothermal effect due to the introduction of MoS2 with broad spectrum response. MoS2 nanosheets were anchored onto the surface of flower-like hierarchical mesoporous Bi4O5I2 nanosheets, thereby forming efficient layered heterojunctions, the solar-driven photocatalytic efficiency in degradation of highly toxic dichlorophenol and reduction of hexavalent chromium was improved to 98.5% and 99.2%, which was ∼4 and 7 times higher than that of the pristine Bi4O5I2, respectively. In addition, the photocatalytic hydrogen production rate reached 496.78 μmol h-1 g-1, which was ∼6 times higher than that of the pristine Bi4O5I2. The excellent photocatalytic performance can be ascribed to the promoted photothermal effect, as well as, the formation of compact Z-scheme layered heterojunctions. The 3D flower-like hierarchical mesoporous structure provided adequate surface active-sites, which was conducive to the mass transfer. Moreover, the high stability of the prepared photocatalyst further promoted its potential practical application. This strategy also provides new insights for fabricating layered Z-scheme heterojunctions photocatalysts with highly photothermal-photocatalytic efficiency.

The Ru-catalyzed carbonylation of alkenes with CO2 as a C1 surrogate and imidazole chlorides as the promotor is investigated by a combination of computational and experimental study. The conversion rate of CO2 to CO is positively correlated with the efficiency of both hydroesterification and hydroformylation, which is found facilitated in the presence of chloride additives with a decreasing order of BmimCl ∼ B3MimCl > BmmimCl ∼ LiCl. Taking the hydroesterification with MeOH as a representative example, BmimCl bearing C–H functionality at the C2 site of the cation assists the reduction of CO2 to CO as a hydrogen donor medium, with the anion and cation acting in a synergistic fashion. Subsequent insertion of CO2 into the formed Ru–H bond with the assistance of chloride anion produces the Ru–COOH species, which ultimately accelerates the activation of CO2.

Energy conversion technologies like fuel cells and metal-air batteries require oxygen reduction reaction (ORR) electrocatalysts with low cost and high catalytic activity. Herein, N-doped carbon spheres (N-CS) with rich micropore structure have been synthesized by a facile two-step method, which includes the polymerization of pyrrole and formaldehyde and followed by a facile pyrolysis process. During the preparation, zinc chloride (ZnCl2) was utilized as a catalyst to promote polymerization and provide a hypersaline environment. In addition, the morphology, defect content and activity area of the resultant N-CS catalysts could be regulated by controlling the content of ZnCl2. The optimum N-CS-1 catalyst demonstrated much better catalytic activity and durability towards ORR in alkaline conditions than commercial 20 wt% Pt/C catalysts, of which the half-wave potential reached 0.844 V vs. RHE. When applied in the Zn-air batteries as cathode catalysts, N-CS-1 showed a maximum power density of 175 mW cm-2 and long-term discharging stability of over 150 h at 10 mA cm-2, which outperformed 20 wt% Pt/C. The excellent performance could be due to its ultrahigh specific surface area of 1757 m2 g-1 and rich micropore channels structure. Meanwhile, this work provides an efficient method to synthesize an ultrahigh surface porous carbon material, especially for catalyst application.

Activated red mud (RM) has been proved to be a promising base material for the selective catalysis reduction (SCR) of NOx. The inherent low reducibility and acidity limited its low–temperature activity. In this work, molybdenum oxide, tungsten oxide, and cerium oxide were used to reconfigure the redox sites and acid sites of red mud based catalyst. When activated red mud was reconfigured by cerium-tungsten oxide (Ce–W@RM), the NOx conversion kept above 90% at 219–480 °C. The existence of Ce3+/Ce4+ redox electron pairs provided more surface adsorbed oxygen (Oα) and served as a redox cycle. Positive interactions between Ce, W species and Fe oxide in red mud occurred, which led to the formation of unsaturated chemical bond and promoted the activation of adsorbed NH3 species. WO3 and Ce2(WO4)3 (formed by solid–state reaction between Ce and W species) could provide more Bronsted acid sites (W–O modes of WO3, W O or W–O–W modes of Ce2(WO4)3). CeO2 species could provide more Lewis acid sites. The Langmuir–Hinshelwood (L-H) routes and Eley-Rideal (E-R) routes occurred in the low-temperature SCR reaction on the Ce–W@RM surface. NH4+ species on Bronsted acid sites, NH3 species on Lewis acid sites, bidentate nitrate and bridging nitrate species were key active intermediates species.

A novel strategy was developed to fabricate FeNx-doped carbon quantum dots (Fe-N-CQDs) to detect Cu2+ ions selectively as a fluorescence probe. The Fe-N-CQDs were synthesized by an efficient electrolysis of a carbon cloth electrode, which was coated with monoatomic iron-anchored nitrogen-doped carbon (Fe-N-C). The obtained Fe-N-CQDs emitted blue fluorescence and possessed a quantum yield (QY) of 7.5%. An extremely wide linear relationship between the Cu2+ concentration and the fluorescence intensity was obtained in the range from 100 nM to 1000 nM (R2 = 0.997), and the detection limit was calculated as 59 nM. Moreover, the Fe-N-CQDs demonstrated wide range pH compatibility between 2 and 13 due to the coordination between pyridine nitrogen and Fe3+, which dramatically reduced the affection of the protonation and deprotonation process between H+ and Fe-N-CQDs. It is notable that the Fe-N-CQDs exhibited a rapid response in Cu2+ detection, where stable quenching can be completed in 7 s. The mechanism of excellent selective detection of Cu2+ was revealed by energy level simulation that the LUMO level of Fe-N-CQDs (−4.37 eV) was close to the redox potential of Cu2+, thus facilitating the electron transport from Fe-N-CQDs to Cu2+.

Establishing highly effective charge transfer channels in carbon nitride (g-C3N4) to enhance its photocatalytic activity is still a challenging issue. Herein, the delaminated 2D Ti3C2 MXene nanosheets were employed to decorate the P-doped tubular g-C3N4 (PTCN) for engineering 1D/2D Schottky heterojunction (PTCN/TC) through electrostatic self-assembly. The optimized PTCN/TC exhibited the highest hydrogen evolution rate (565 μmol/h/g), which was 4.3 and 2.0 -fold higher than pristine bulk g-C3N4 and PTCN, respectively. Such enhancement may be primarily attributed to the phosphorus heteroatom doped and unique structure of 1D/2D g-C3N4/Ti3C2 Schottky heterojunction, enhancing the light-harvesting and charges’ separation. One-dimensional pathway of g-C3N4 tube and built-in electric field of interfacial Schottky effect can significantly facilitate the spatial separation of photogenerated charge carriers, simultaneously inhibit their recombination via Schottky barrier. In this composite, metallic Ti3C2 was served as electrons sink and photons collector. Moreover, ultrathin Ti3C2 flake with exposed terminal metal sites as a co-catalyst exhibited higher photocatalytic reactivity in H2 evolution compared to carbon materials (such as reduced graphene oxide). This work not only proposed the mechanism of tubular g-C3N4/Ti3C2 Schottky junction in photocatalysis, but also provided a feasible way to load ultrathin Ti3C2 as a co-catalyst for designing highly efficient photocatalysts.

Diphenyl carbonate (DPC) is one of the versatile carbonates, and is often used for the production of polycarbonates. In recent years, the catalytic synthesis of DPC has become an important topic but the development of a highly active metal-free catalyst is a great challenge. Herein, a series of ionic liquids-SBA-15 hybrid catalysts with different functional groups have been developed for the synthesis of DPC under solvent-free condition, which are effective and clean instead of the metal-containing catalysts. It is found that in the presence of [SBA-15-IL-OH]Br catalyst, methyl phenyl carbonate (MPC) conversion of 80.5% along with 99.6% DPC selectivity is achieved, the TOF value is thrice higher than the best value reported by using transition metal-based catalysts. Moreover, the catalyst displays remarkable stability and recyclability. This work provides a new idea to design and prepare eco-friendly catalysts in a broad range of applications for the green synthesis of carbonates.

Hydrogen energy has long been recognized as a clean alternative to conventional fossil fuels, which can be applied in a wide range of transportation and power generation applications. The rational design and engineering of high-performance and robust catalysts for hydrogen evolution reaction (HER) shows not a great significance but a challenge for efficient electrochemical water splitting. Herein, a new type of Ni-based Ni-ABDC precursor has been obtained, which leads to the formation of N-doped porous carbon nanomaterials uniformly coated with well-proportioned bimetallic AgNi alloys via a stepwise strategy. To their credit, all samples of AgNi/NC-X are structurally calcined from the pristine AgNi-ABDC-X by tuning the different concentration of AgNO3, which means all of them maintain the vermicelli-like morphology compared with Ni-ABDC. The series of AgNi/NC-X materials can be regarded as effective electrocatalysts for HER both in acidic and alkaline media, but an acid-leaching phenomenon is observed. Among them, the as-prepared AgNi/NC-2 exhibits a low overpotential of 103 mV at the current density of 10 mA cm−2 and decent durability with a high retention rate of 90.9% after 10 h in 1.0 M KOH electrolyte. The compelling HER properties of AgNi/NC-2 can be attributed to the synergistic effect between the hierarchical carbon materials, partial N-doping and abundant AgNi alloys. Meanwhile, this study provides a practicable method for the development of efficient HER electrocatalysts for energy applications, which can be conveniently prepared through the reasonable introduction of active components in the crystalline inorganic-organic precursors.

Along with the environmental pollution, the scarcity of clean water seriously threatens the sustainable development of human society. Recently, the rapid development of solar evaporators has injected new vitality into the field of water purification. However, the industry faces a considerable challenge of achieving comprehensive purification of ions, especially the efficient removal of mercury ions. In this work, we introduce an ideal mercury-removal platform based on facilely and cost-effectively synthesized polysulfide nanoparticles (PSNs). Further development of PSN-functionalized reduced graphene oxide (PSN-rGO) aerogel evaporator results in achieving a high evaporation rate of 1.55 kg m−2 h−1 with energy efficiency of 90.8% under 1 sun. With the merits of interconnected porous structure and adsorption ability, the photothermal aerogel presents overall purification of heavy metal ions from wastewater. During solar desalination, salt ions can be rejected with long-term stability. Compared with traditional water purification technologies, this highly efficient solar evaporator provides a new practical method to utilize clean energy for clean water production.

In this work, Ag/Bi5O7I nanocomposite was prepared and firstly applied in piezo/photocatalytic reduction of N2 to NH3 and methyl orange (MO) degradation. Bi5O7I was synthesized via a hydrothermal-calcination method and shows nanorods morphology. Ag nanoparticles (NPs) were photo deposited on the Bi5O7I nanorods as electron trappers to improve the spatial separation of charge carriers, which was confirmed via XPS, TEM, and electronic chemical analyses. The catalytic test indicates that Bi5O7I presents the piezoelectric-like behavior, while the loading of Ag NPs can strengthen the character. Under ultrasonic vibration, the optimal Ag/Bi5O7I presents high efficiency in MO degradation. The degradation rate is determined to be 0.033 min−1, which is 4.7 folds faster than that of Bi5O7I. The Ag/Bi5O7I also presents a high performance in piezocatalytic N2 fixation. The piezocatalytic NH3 generation rate reaches 65.4 μmol L−1 g−1 h−1 with water as a hole scavenger. The addition of methanol can hasten the piezoelectric catalytic reaction. Interestingly, when ultrasonic vibration and light irradiation simultaneously act on the Ag/Bi5O7I catalyst, higher performance in NH3 generation and MO degradation is observed. However, due to the weak adhesion of Ag NPs, some Ag NPs would fall off from the Bi5O7I surface under long-term ultrasonic vibration, which would greatly reduce the piezoelectric catalytic performance. This result indicates that a strong binding force is required when preparing the piezoelectric composite catalyst. The current work provides new insights for the development of highly efficient catalysts that can use multiple energies.

A series of CoPd/KIT-6 bimetallic catalysts with various Co:Pd molar ratios at different calcination temperatures were prepared and used for the direct synthesis of H2O2 from H2 and O2. These catalysts were characterized by nitrogen adsorption-desorption, low and wide-angle X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), scanning electron microscopy (SEM), elemental mapping and energy-dispersive X-ray (EDX) methods. It was found that the particle size, electronic interactions, morphology, and textural properties of these catalysts as well as their catalytic activity in the reaction of H2 with O2 were affected by Co addition and different calcination temperatures. Also, the results showed that while the H2O2 selectivity depends on Pd2+ species, the H2 conversion is related to Pd0 active sites. Among these catalysts, CoPd/KIT-6 calcined at 350 °C (CoPd/KIT-350 catalyst) showed the best catalytic activity with 50 % of H2O2 selectivity and 51 % conversion of H2.

Adsorptive removal of heavy metal ions from wastewater is very important, and the key is the development of efficient sorbents. In this work, oxygenated alkynyl carbon materials (OACMs) were synthesized via mechanochemical reaction of CaC2 and a carbonate (CaCO3, Na2CO3, or NaHCO3) at ambient temperature. The resultant OACMs are micro mesoporous carbon nanomaterials with high specific area (>648 m2 g−1), highly crosslinked texture, and rich alkynyl and oxygenated groups. The OACMs exhibit excellent Hg(II) adsorption due to the soft acid-soft base interaction between alkynyl and Hg(II), and OACM-3 derived from CaC2 and NaHCO3 has the saturated Hg(II) adsorbance of 483.9 mg g−1 along with good selectivity and recyclability. The adsorption is mainly chemisorption following the Langmuir mode. OACM-3 also shows high adsorbance for other heavy metal ions, e.g. 256.6 mg g−1 for Pb(II), 232.4 mg g−1 for Zn(II), and 198.7 mg g−1 for Cu(II). This work expands the mechnochemical reaction of CaC2 with carbonates and possibly other oxyanionic salts, provides a new synthesis approach for functional alkynyl carbon materials with excellent adsorption performance for heavy metal ions, as well as a feasible approach for CO2 resource utilization.

Aqueous zinc-air battery (ZAB) has attractive features as the potential energy storage system such as high safety, low cost and good environmental compatibility. However, the issue of dendrite growth on zinc metal anodes has seriously hindered the development of ZAB. Herein, the N-doped carbon cloth (NC) prepared via magnetron sputtering is explored as the substrate to induce the uniform nucleation of zinc metal and suppress dendrite growth. Results show that the introduction of heteroatoms accelerates the migration and deposition kinetics of Zn2+ by boosting the desolvation process of Zn2+, eventually reducing the nucleation overpotential. Besides, theoretical calculation results confirm the zincophilicity of N-containing functional group (such as pyridine N and pyrrole N), which can guide the nucleation and growth of zinc uniformly on the electrode surface by both promoting the redistribution of Zn2+ in the vicinity of the surface and enhancing its interaction with zinc atoms. As a result, the half-cell assembled with magnetron sputtered carbon cloth achieves a high zinc stripping/plating coulombic efficiency of 98.8% and long-term stability of over 500 cycles at 0.2 mA cm-2. And the Coulombic efficiency reached about 99.5% at the 10th cycle and maintained for more than 210 cycles at a high current density of 5.0 mA cm-2. The assembled symmetrical battery can deliver 220 plating/stripping cycles with ultra-low voltage hysteresis of only 11 mV. In addition, the assembled zinc-air full battery with NC-Zn anode delivers a high special capacity of about 429 mAh gZn-1 and a long life of over 430 cycles. The effectiveness of surface functionalization in promoting the transfer and deposition kinetics of Zn2+ presented in this work shows enlightening significance in the development of metal anodes in aqueous electrolytes.

Covalent organic frameworks (COFs) are nanoporous crystalline polymers with densely conjugated structures. This work discovers that imine-linked COFs exhibit remarkable photodegradation efficiency to azo dyes dissolved in water. Visible light generates different types of radicals from COFs, and superoxide radicals break N N bonds in dye molecules, resulting in 100% degradation of azo dyes within 1 h. In contrast, these dyes cannot be degraded by conventionally used photocatalysts, for example, TiO2. Importantly, the COF photocatalysts can be recovered from the dye solutions and re-used to degrade azo dyes for multiple times without loss of degradation efficiency. This work provides an efficient strategy to degrade synthetic dyes, and we expect that COFs with designable structures may use as new photocatalysts for other important applications.

Graphene oxide (GO) is regarded as a promising candidate to construct solar absorbers for addressing freshwater crisis, but the easy delamination of GO in water poses a critical challenge for practical solar desalination. Herein, we improve the stability of GO membranes by a self-crosslinking poly (ionic liquid) (PIL) in a mild condition, which crosslinks neighbouring GO nanosheets without blemishing the hydrophilic structure of GO. By further adding carbon nanotubes (CNTs), the sandwiched GO/CNT@PIL (GCP) membrane displays a good stability in pH = 1 or 13 solution even for 270 days. The molecular dynamics simulation results indicate that the generation of water nanofluidics in nanochannels of GO nanosheets remarkably reduces the water evaporation enthalpy in GCP membrane, compared to bulk water. Consequently, the GCP membrane exhibits a high evaporation rate (1.87 kg m−2 h−1) and displays stable evaporation rates for 14 h under 1 kW m−2 irradiation. The GCP membrane additionally works very well when using different water sources (e.g., dye-polluted water) or even strong acidic solution (pH = 1) or basic solution (pH = 13). More importantly, through bundling pluralities of GCP membrane, an efficient solar desalination device is developed to produce drinkable water from seawater. The average daily drinkable water amount in sunny day is 10.1 kg m−2, which meets with the daily drinkable water needs of five adults. The high evaporation rate, long-time durability and good scalability make the GCP membrane an outstanding candidate for practical solar seawater desalination.

A composite system consisting of aminosilicate (APS) functionalized-fullerene quantum dots (C60 QDs) and bismuth vanadate (BiVO4-APS-C60) has been developed via a facile one-step hydrothermal process. The structural analysis by XRD revealed that the integrated QDs have not affected the crystal structure of the host BiVO4, while the XPS studies showed that these QDs have been integrated via the Bi-V-O-Si-C network. The optical studies indicated that both the C60 and APS-C60 QDs have hardly influenced the optical absorption properties of the composite system. On the other hand, the dispersion of aminosilicate functionalized-QDs considerably reduced the aggregation in the layers and yielded a few nanometer thick BiVO4 layers due to their inter-layer occupancy as seen from their high-resolution TEM images. The photoluminescence, photocurrent and electrochemical impedance studies showed that the integration of APS-C60 QDs greatly improved the photoactive properties of the composite by effectively enhancing the charge recombination resistance, charge separation and transfer process between the integrated materials and surroundings. As a result, BiVO4-APS-C60 composites showed the enhanced photocatalytic efficiency towards degradation of ciprofloxacin (CIP) molecules under solar light irradiation as compared to that of bare-BiVO4 and BiVO4-C60.

Emotion recognition based on electroencephalography (EEG) is a significant task in the brain-computer interface field. Recently, many deep learning-based emotion recognition methods are demonstrated to outperform traditional methods. However, it remains challenging to extract discriminative features for EEG emotion recognition, and most methods ignore useful information in channel and time. This paper proposes an attention-based convolutional recurrent neural network (ACRNN) to extract more discriminative features from EEG signals and improve the accuracy of emotion recognition. First, the proposed ACRNN adopts a channel-wise attention mechanism to adaptively assign the weights of different channels, and a CNN is employed to extract the spatial information of encoded EEG signals. Then, to explore the temporal information of EEG signals, extended self-attention is integrated into an RNN to recode the importance based on intrinsic similarity in EEG signals. We conducted extensive experiments on the DEAP and DREAMER databases. The experimental results demonstrate that the proposed ACRNN outperforms state-of-the-art methods.

This work demonstrated the promise of using industrial-grade sugar syrups derived from corn and wood, i.e., high fructose corn syrup (HFCS), glucose corn syrup (GCS) and wood-based sugar (TMP-Bio Sugar), as cheaper and competitive feedstocks for 5-HMF production using niobium phosphate as a heterogeneous solid acid catalyst in a biphasic continuous-flow tubular reactor. 5-HMF yield as high as 53.1% with 100% sugar (glucose and fructose) conversion was obtained from catalytic dehydration of HFCS-90 (containing 90 wt% fructose) at 150 °C, with feed concentration of 200 mg/ml (glucose and fructose) and aqueous to organic phase ratio of 1:5 (v/v). Catalyst stability with time was tested over 20 h of continuous-time on stream, and the reusability of the catalyst was studied after in-situ regeneration of the used catalyst by calcination in the air for removing the deposited humins and coke on the surface of the catalyst particles. The regenerated catalyst showed good activity with almost constant selectivity, although at lower glucose conversion and reduced 5-HMF yield compared to the fresh catalyst, indicating that the in-situ regeneration process could recover a part of the acid sites on the catalyst surface. The produced humins during the reaction were characterized by Fourier transform infrared spectrometry (FT-IR), thermogravimetric analysis (TGA) and elemental analysis (CHNS). The results showed high aromaticity and the presence of a high degree of unsaturated compounds in the structure of humins.

Glyceryl monolaurate (GML), as one of widely used industrial chemicals, can be synthesized via Fischer esterification of lauric acid (LA) and glycerol (GL). In this work, we screened boric acid-based deep eutectic solvent (DES) formed from tetrapropylammonium bromide (TPAB) and boric acid to intensify the selective Fischer esterification through conductor-like screening model for realistic solvents (COSMO-RS) theory. The solid liquid equilibrium (SLE) phase behavior, hydrogen bond formation process, and thermal stability of the DES were characterized by differential scanning calorimetry (DSC), Fourier transform infrared spectrometry (FT-IR), and thermogravimetric analyzer (TGA). The results verified that equimolar TPAB and boric acid formed DES [TPAB:B(OH)3] with the lowest freezing point and very good thermal stability could efficiently intensify the Fischer esterification of GL and LA to GML. The hydrogen bond accepter TPAB of the DES made the esterification system homogeneous, which promoted the selective esterification process. In addition, the hydrogen bond donor B(OH)3 of the [TPAB:B(OH)3] combined with diol unit of GL to cyclic boric esters and led to a special selective space effect, which also improved the selectivity to GML. Thus, the esterification intensified of GL and LA by 20 wt% DES achieved GML selectivity of 85.7 % and yield of 76.4 % under the optimal reaction conditions. The esterification kinetics suggested the reaction followed pseudo-second-order model and the reaction activation energy was 33.98 kJ mol−1, similar to and/or lower than those reported works. Furthermore, DES and unreacted glycerol were readily recovered and reused through temperature controlled gravity-based separation due to the ability of homogeneity under reaction conditions and splitting phase behavior during the DES recovery. The results can expand the boric acid-based DESs for other potential intensification applications.

High surface area cerium oxide was synthesized via the reverse microemulsion method and assessed for CO2 reduction to CO via reverse water gas shift. The resulted ceria nanoparticles (ca. 4 nm) were 100% selective to CO formation, while attaining a nearly equilibrium CO2 conversion at 600 °C. As compared to ceria synthesized by wet precipitation, the reverse microemulsion-synthesized ceria exhibited enhanced surface stability and a more stable catalytic performance (declining from 63% to 50% over 100 h on stream). No significant carbon formation was detected and a relatively small decline in conversion was related to the specific surface area reduction induced by the growth of ceria nanoparticles under the reaction conditions.

Co-pyrolysis of lignin and waste plastics, for example polyethylene (PE), has been studied, but related reports are basically on condition optimizations. This study revealed a new perspective on PE-promoted lignin pyrolysis to phenolic monomers with mass transfer and radical explanation. Lignin and PE were first pyrolyzed individually to identify pyrolysis characteristics, pyrolytic products, as well as the suitable co-pyrolysis temperature. Then, co-pyrolysis of blended lignin/PE with various ratios was investigated. Yields of lignin products reached the maximum under lignin/PE ratio of 1:1, but blended approach always inhibited the production of lignin phenols. This resulted from the poor mass transfer and interactions between lignin and PE, in which PE pyrolysates could easily escape from the particle gaps. While in layered approach, PE pyrolysates had to pass through the lignin layer which contributed to the good interactions with lignin pyrolysis intermediates, thus the yields of lignin-derived products were significantly improved. Interactions between lignin and PE (or their pyrolysates) were mainly radical quenching reactions, and X-ray photoelectron spectrum (XPS) and electron paramagnetic resonance (EPR) of pyrolytic chars were conducted to verify these interactions controlled by mass transfer. The percentage of C C (sp2) and concentration of organic stable radicals in layered lignin/PE char were both the lowest compared with those in blended lignin/PE and lignin char, indicating the stabilization of lignin-derived radicals by PE pyrolysates. Moreover, the spin concentration of radicals in the char from layered char/PE was lower than that in lignin char, which further affirmed the quenching of radicals by PE in the layered co-pyrolysis mode.

In this work, a novel bamboo-like carbon nanotubes@Sn4P3@carbon (BLCNTs@Sn4P3@C) coaxial nanotubes are designed and prepared using a newly developed hydrothermal method followed by a phophidation process. The prepared Sn4P3 nanoparticles are uniformly coated and wrapped on the one-dimensional (1D) bamboo-like CNTs, which is covered by a uniform carbon layer to form a sandwich-like structure with Sn4P3 in between. The inner CNT and outer carbon can effectively maintain the structural stability and serve as the good electron conductors. Additionally, the outer carbon coating layer can effectively keep BLCNTs@Sn4P3@C nanotubes separate each other, preventing aggregation of Sn4P3 during charge/discharge when this material is used as anode for sodium ion batteries. The anode of BLCNTs@Sn4P3@C shows excellent reversible capacity and a long cycling of over 2000 cycles. The unique design of coaxial nanotubes is greatly beneficial to the electrochemical performance of Sn4P3 for sodium ion storage.

Side-chain alkylation of toluene with methanol is a green pathway to realize the one-step production of styrene under mild conditions, but the low selectivity of styrene is difficult to be improved with by-products of ethylbenzene and xylene. In this study, a new way is introduced to improve the catalytic performance by means of assisting basic compounds as co-catalysts during the toluene side-chain alkylation with methanol to styrene. As a result, high activity of side-chain alkylation appears over the basic Cs-modified zeolite catalysts prepared by ion exchange and impregnation methods. This high performance should be mainly attributed to two co-catalysis actions: (1) the promotion of basic compounds for methanol dehydrogenation to formaldehyde as the intermediate for side-chain alkylation; (2) the suppression of the styrene transfer hydrogenation on basic Cs-modified zeolites to avoid the formation of ethylbenzene. Especially for Cs2O/CsX-ex catalyst, the addition of 2 mol% 2-picoline in reaction mixture could achieve both 12.3% toluene conversion and 84.1% styrene selectivity. Whereas the higher concentration of 2-picoline (>6 mol%) caused an inhibition to the catalytic activity because the excessive basic compound poisoned the combined acid-base pathway required for the side-chain alkylation process. In addition, two possible side-chain alkylation reaction routes on Cs-modified zeolite under the different 2-picoline absorption were described.

Atomically dispersed precious metal catalysts maximize atom efficiency and exhibit unique reactivity. However, they are susceptible to sintering. Catalytic reactions occurring in reducing environments tend to result in atomically dispersed metals sintering at lower temperatures than in oxidative or inert atmospheres due to the formation of mobile metal-H or metal-CO complexes. Here, we develop a new approach to mitigate sintering of oxide supported atomically dispersed metals in a reducing atmosphere using organophosphonate self-assembled monolayers (SAMs). We demonstrate this for the case of atomically dispersed Rh on Al2O3 and TiO2 using a combination of CO probe molecule FTIR, temperature programmed desorption, and alkene hydrogenation rate measurements. Evidence suggests that SAM functionalization of the oxide provides physical diffusion barriers for the metal and weakens the interactions between the reducing gas and metal, thereby discouraging the adsorbate-promoted diffusion of metal atoms on oxide supports. Our results show that support functionalization by organic species can provide improved resistance to sintering of atomically dispersed metals with maintained catalytic reactivity.

In this work, we have prepared the hierarchically nanostructured core–shell NiCo layered double hydroxide (NiCo-LDH) nanosheets- and ZnFe2O4 nanocubes-decorated polyacrylonitrile (PAN)/pitch-based carbon nanofibers (PPCNs) webs (NiCo-LDH@PPCNs as cathode and ZnFe2O4@PPCNs as anode materials) with the bonded network structure by a facile and scalable hydrothemal method. Herein, the low-cost pitch with lower softening point (∼90 °C) as co-precursor was utilized to produce the PAN/pitch-based carbon nanofibers (PPCNs) with enhanced electrical conductivity. The obtained PPCNs with pitch content of 30% (PP30CNs) electrode material delivered higher specific capacitance (∼67 F g−1) than that (∼48 F g−1) of the PAN-based carbon nanofibers (PCNs) at 1 A g−1, due to the increased electrical conductivity and lower interfacial charge transfer resistance (RCT) of ∼0.16 Ω. Further, the NiCo-LDH-decorated PP30CNs (NiCo-LDH@PP30CNs) as cathode material showed superior specific capacitance of 1162 F g−1 at 1.0 A g−1 and ultra-high retention rate of 91.56% at 10 A g−1. The ZnFe2O4@PP30CNs as anode material also showed higher specific capacitance of 282 F g−1 at 1 A g−1 and good rate capability with capacitance retention of 56.73% at 10 A g−1. The as-fabricated asymmetric NiCo-LDH@PP30CNs//ZnFe2O4@PP30CNs hybrid supercapacitor device delivered a specific capacitance of ∼98 F g−1 at 1 A g−1 and excellent capacitance retention of ∼88% after 5000 charge–discharge cycles.

Ferric acetylacetonate/covalent organic framework (Fe(acac)3/COF) composite was synthesized by interfacial polymerization method at room temperature. The crystal structure, morphology and porosity property of the composite were characterized by X-ray diffraction, scanning electron microscope, transmission electron microscope and nitrogen adsorption. The interaction between Fe(acac)3 and COF was investigated by Fourier transform infrared spectra and X-ray photoelectron spectroscopy. The Fe(acac)3/COF composite was used as a photocatalyst for the oxidation of benzyl alcohol under mild conditions. It exhibits high activity and selectivity for the reaction, of which the mechanism was investigated by determining its photoelectric properties. The Fe(acac)3/COF catalyst developed in this work has application potential in other photocatalytic reactions.

Deep eutectic solvents (DESs) have gained much attention in the fabrication of advanced nanoelectrocatalysts due to their amazing template function. However, their stabilizing function for easily hydrolyzed inorganic nanomaterials is rarely studied. Here, a DES-mediated strategy was reported to synthesize octahedral Ni-Co precursor (NiCo-NH3 complex), which could be directly transformed into NiCo2O4 nanooctahedrons after thermal decomposition. The NiCo-NH3 precursor in octahedral shape was achieved with the DES-mediated crystallization in the choline chloride (ChCl)/glycerol. The ChCl/glycerol DES not only tailored the morphology of the as-prepared precursor by template effect but also inhibited its hydrolysis, ensuring the successful fabrication of octahedral NiCo-NH3 complex precursor with high yield. The NiCo-NH3 complex precursor was converted to well-defined NiCo2O4 nanooctahedrons, where the calcination temperature and time were explored in detail. It revealed that DES could participate in the conversion process to control the morphology of calcination product. The resultant NiCo2O4 nanooctahedrons demonstrated excellent electroactivity and remarkable durability for oxygen evolution reaction (OER). The present strategy not only offers an efficient OER electrocatalyst but also enriches the approaches of DESs in designing advanced nanocatalysts.

High-energy-density lithium-sulfur batteries has attracted substantial attention as competitive candidates for large-scale energy storage technologies. Still, the adverse “shuttle effect” and sluggish sulfur conversion reaction kinetics immensely obstruct their commercial viability. Herein, a two-dimensional metallic 1T phase WS2 (1T-WS2) nanosheets modified functional separator is developed to improve the electrochemical performance. Meanwhile, the semiconducting bulk-WS2 crystals, and 2H phase WS2 (2H-WS2) nanosheets with more basal-plane S-vacancy defects are also prepared to probe the contributions of the crystal structure (phase), S-vacancy defects, and edges to the Li–S batteries performance experimentally and theoretically. In merits of the synergistic effect of high ion and electron conductivity, enhanced binding ability to lithium polysulfides (LiPSs), and sufficient electrocatalytic active sites, the 1T-WS2 shows highly efficient electrocatalysis of LiPSs conversion and further improves Li–S battery performance. As expected, thus-fabricated cells with 1T-WS2 nanosheets present superior cycle stability that maintain capacity decline of 0.039% per cycle after 1000 cycles at 1.0 C. The strategy presented here offers a viable approach to reveal the critical factors for LiPSs catalytic conversion, which is beneficial to developing advanced Li–S batteries with enhanced properties.

Rational design and facile preparation of low-cost and efficient catalysts for the selective converting of biomass-derived monosaccharides into high value-added chemicals is highly demanded, yet challenging. Herein, we first demonstrate a N doped defect-rich carbon (NC-800-5) as metal-free catalyst for the selective oxidation of d -xylose into d -xylonic acid in alkaline aqueous solution at 100 °C for 30 min, with 57.4% yield. The doped graphitic N is found to be the active site and hydroxyl ion participating in the oxidation of d -xylose. Hydroxyl ion and d -xylose first adsorb on NC-800-5 surface, and the aldehyde group of d -xylose is catalyzed to form germinal diols ion. Then, C–H bond break to yield carboxylic group. Furthermore, NC-800-5 catalyst shows high stability in recycled test.

Meta-analysis is a statistical analysis of the data obtained from multiple studies and provides a quantitative synthesis of research results. It can be a key tool for facilitating rapid progress in aquaculture by quantifying what is known and identifying what is not yet known. However, due to the complexity of the environment and problems associated with the use of model in aquaculture, it remain few guidelines for the design, implementation or interpretation of meta-analysis in the field of aquaculture. Here, we first briefly reviewed the history of meta-analysis, then summarized the applications of meta-analysis in terms of major procedures, standards, and methods. Next, we critically reviewed the results of meta-analysis studies in the production chain of aquaculture and identified the potentials for improving yield in both quantity and quality. Overall, there is a large room for improving yield along the production chain. Large contributions can be found in breeding, feed, and farm management. For example, improving breeding can increase yield by 5.6% to 49%, depending on fish species and type of improvements. This study revealed large potentials for improving yield in the production chain of aquaculture and summarized the application of meta-analysis in aquaculture. Some recommendations of standardizing and improving meta-analysis in aquaculture were proposed.

There is a great demand for transparent films, membranes, or substrates in the fields of intelligent wearables, electronic skins, air filtration, and tissue engineering. Traditional materials such as glass and plastics cannot satisfy these requirements because of the lack of interconnected pores, undesirable porosity, and flexibility. Electrospun fibrous membranes offset these shortcomings because they contain small pores and have high porosity as well as outstanding flexibility. Thus, the development of transparent electrospun fibrous membranes is of great value. This work reports a simple and effective way to develop flexible and porous transparent fibrous membranes (TFMs) directly from electrospun fibrous membranes via mechanical pressing, without employing any other additives. In addition, the relationship between the transparency performance and the molecular structure of the polymers after pressing was summarized for the first time. After mechanical pressing, the membranes maintained fibrous morphology, micron-sized pores, and desired porosity. Polystyrene fibrous membranes, which exhibited excellent optical and mechanical properties, were used as a reference. The TFMs possessed high transparency (∼89% visible light transmittance at 550 nm), high porosity (10%–30%), and strong mechanical tensile strength (∼148 MPa), nearly 78 times that of the pristine electrospun fibrous membranes. Moreover, this study demonstrated that transparent and conductive membranes can be fabricated based on TFMs using vacuum-assisted filtration of silver nanowires followed by mechanical pressing. Compared with indium tin oxide films, conductive TFMs exhibited good electrical conductivities (9 Ω per square (Ω·sq−1), 78% transmittance at 550 nm) and notable mechanical performance (to bear abundant bending stresses).

An ongoing challenge still lies in the exploration of proficient electrocatalysts from earth-abundant non-precious metals instead of noble metal-based catalysts for clean hydrogen energy through large-Scale electrochemical water splitting. However, developing a non-precious transition metals based, stable electrocatalyst for cathodic hydrogen evolution reaction (HER) and anodic oxygen evolution reaction (OER) is important challenge for modern energy conversion technology. In this report Vanadium doped bimetallic nickel-iron nanoarray, fabricated by carbon supported architecture through carbonization process for electrochemical water splitting. Three types of catalysts were prepared in different molar ratio of Ni/Fe. The electrocatalytic performance demonstrated that the catalyst with equal mole ratio (0.06:0.06) of Ni/Fe possess high catalytic activity for both OER and HER in alkaline and acidic medium. Besides, our findings revealed that the doping of vanadium could play a strong synergetic effect with Ni/Fe, which provide a small overpotential of 90 mV and 210 mV at 10 mA cm−2 for HER and OER respectively compared to the other two catalyst counterparts. Also, the catalyst with 1:1 (Ni/Fe) molar ratio showed a high current density of 208 mA cm−2 for HER at 0.5 M H2SO4 and 579 mA cm−2 for OER at 1 M KOH solution, the both current densities are much higher than the other two catalysts (different Ni/Fe ratio). In addition, the presented catalysts showed extremely good durability, reflecting in more than 20 h of consistent Chronoamprometry study at fixed overpotential η = 250 mV without any visible voltage elevation. Similarly, the (Ni/Fe) equal ratio catalyst showed better corrosion potential 0.209 V vs Ag/AgCl and lower current density 0.594 × 10−12 A cm−2 in high alkaline medium. The V-doping, MOF/GO surface defects are significantly increased the corrosion potential of the V-NixFey-MOF/GO electrocatalyst. Besides, the water electrolyzed products were analysed by gas chromatography to get clear insights on the formed H2 and O2 products.