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This paper presents the investigation of corrosion of 15Mo3 pipe in the steam heater system of the Plomin thermal power plant. Corrosion damage led to a rupture in the system as well as delays. Therefore it was necessary to determine the type and the cause of the corrosion. Corrosion is classified according to three factors: the mechanism, the specificity of its occurrence, and the form of the corrosion attack. Power plants are explained with an emphasis on thermal power plants, along with an analysis of the sample and system in which the damage occurred. The results of the investigation of corrosion products on the pipe and the rupture itself are presented. Chemical analysis, microscopic research with light and electron microscopy, hardness tests according to Vickers, and analysis with FT-IR spectroscopy were carried out. Erosion corrosion was proven to be the cause of the failure in a specific example. [ABSTRACT FROM AUTHOR]

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This study is based on assessing fecal indicator bacteria contamination along meteorological, hydrological and physical-chemical variables after high rainy events during the summer period. The study focused on four different coastal sites in the western and eastern Adriatic coast characterized by various geomorphological and hydrological features, levels of urbanization and anthropogenic pressures, with the aim of finding appropriate and effective solutions to ensure the safety and sustainability of tourism and public health. Detailed in-situ survey revealed a wide range of fecal indicator bacterial (FIB) across the different river mouths with concentrations of E. coli ranging from 165 to 6700 CFU 100 mL -1 . It was found that nitrogen compounds track microbial load and acted as tracers for fecal contaminants. Further, a modelling tool was also used to analyze the spatial and temporal distribution of fecal pollution at these coastal sites. The integrated monitoring through high frequent survey in river waters and modeling framework allowed for the estimation of fecal indicator bacterial load at the river mouth and examination of fecal pollutant dispersion in recreational waters, considering different scenarios of fecal dispersion along the coast. This study formed the basis of a robust decision support system aimed at improving the management of recreational areas and ensuring the protection of water bodies through efficient management of bathing areas., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

Beneficial effects of a natural zeolite clinoptilolite in vivo on mammals, including humans, have been empirically observed and documented in literature. The positive biological activities have been associated to its detoxifying and antioxidative properties, and its immunostimulative and adsorption properties. Herein, we present the in vitro and in vivo study of clinoptilolite zeolite materials adsorption properties for d-glucose. In particular, we present data on the interaction of d-glucose on the tested zeolites' surface obtained by scanning electron microscope (SEM) and Energy-dispersive X-ray spectroscopy (EDS) and quantification by ultra high-performance liquid chromatography (UHPLC). We also present results on the reduction of blood glucose levels in mice pre-treated with clinoptilolite in vivo upon feeding with d-glucose. In vivo results were in line with the in vitro adsorption and/or interaction properties of tested zeolite materials for d-glucose and were quantified by UHPLC as well (11.34% for TMAZ; 10.82% for PMA and 8.76% for PMAO2). In vivo experiments in mice showed that PMA zeolite reduces blood glucose levels upon 15 min for 13% (at p < 0.05) up to 19.11% upon 120 min (without statistical significance) in clinoptilolite pre-treated mice fed by addition of d-glucose. Due to lack of explicit mechanistic knowledge on zeolite clinoptilolite interactions or adsorption with sugars in vitro and in vivo, presented study provides novel insights into these aspects for researchers in the field. The presented data merit further investigations as the material clearly shows a potential in management of hyperglycemia, such as for example in obese people, people with diabetes and people with metabolic syndrome where it could help regulate blood glucose levels., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

The development of coatings that maintain the attractive natural appearance of wood while providing ultraviolet (UV) protection is extremely important for the widespread use of wood products. In this study, the influence of different types (powder form and aqueous dispersions) of TiO 2 in an amount of 1.0 wt% by monomer weight on the properties of environmentally friendly polyacrylate (PA)/TiO 2 emulsions prepared by ex situ and in situ polymerization, as well as on the UV-protective properties of the coating films, was investigated. The results showed that the addition of TiO 2 significantly affected the particle size distribution of PA and the viscosity of PA varied according to the preparation method. Compared with the ex situ preparation method, in situ polymerization provides better dispersibility of TiO 2 nanoparticles in PA coating film, as well as a better UV protection effect and greater transparency of the coating films. Better morphology and transparency of nanocoating films were achieved by adding TiO 2 nanofillers in aqueous dispersion as compared to the addition of TiO 2 in powder form. An increase in the glass transition temperature during UV exposure associated with cross-linking in the polymer was less pronounced in the in situ-prepared coating films, confirming better UV protection, while the photocatalytic effect of TiO 2 was more pronounced in the ex situ-prepared coating films. The results indicate that the method of preparation has a significant influence on the properties of the coating films.