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The effect of non-planar substrate surface on homogeneity and quality of cold sprayed (CS) deposits was studied by scanning acoustic microscopy (SAM). Fe coatings were cold sprayed onto Al substrates containing artificially introduced grooves of square- and trapezoid-shaped geometries, with flat or cylindrical bottoms. The Al substrates were either wrought or cold sprayed, to comprehend their prospective influence on the Fe coatings build-up. SAM was then used to assess morphological properties of the materials from the cross-view and top-view directions. The microstructure below the surface of the studied samples was visualized by measuring the amplitudes of the reflection echoes and the velocity of the ultrasonic waves. The SAM analysis revealed that the regions of coating imperfections around the grooves are larger than what is suggested by standard scanning electron microscopy (SEM) observations. Furthermore, we found that the seemingly non-influenced coating regions that appear perfectly homogeneous and dense in SEM do, in fact, possess heterogeneous microstructure associated with the individual CS nozzle passes., Comment: Manuscript accepted to the Journal of Thermal Spray Technology (JTST)

The decomposition of complex networks into smaller, interconnected components is a central challenge in network theory with a wide range of potential applications. In this paper, we utilize tools from group theory and ring theory to study this problem when the network is a Cayley graph. In particular, we answer the following question: Which Cayley graphs are prime?

In this preprint I propose that the non local discrete-state-in-continuum model previously successfully used to describe the inelastic electron molecule collisions can also be used to model the electron photo-detachment from the molecular anions. The basic theory is sketched and the approach is tested on the model of electron photodetachment from diatomic molecular anion., Comment: This is preliminary preprint yet to be polished and submitted

We present a general two-dimensional model of conical intersection between metastable states that are vibronically coupled not only directly but also indirectly through a virtual electron in the autodetachment continuum. This model is used as a test ground for design and comparison of iterative solvers for resonance dynamics in low-energy electron-molecule collisions. Two Krylov-subspace methods with various preconditioning schemes are compared. To demonstrate the applicability of the proposed methods on even larger models, we also test the performance of one of the methods on a recent model of vibrational excitation of CO$_2$ by electron impact based on three vibronically-coupled discrete states in continuum (Renner-Teller doublet of shape resonances coupled to sigma virtual state) including four vibrational degrees of freedom. Two-dimensional electron energy-loss spectra resulting from the electron-molecule scattering within the models are briefly discussed., Comment: 15 pages, 12 figures, to be submited to Journal of Chemical Theory and Computation. Partially based on the bachelor and diplomma thesis of Martina Cosic (formerly Sarmanova)

Current-induced bond rupture is a fundamental process in nanoelectronic architectures such as molecular junctions and in scanning tunneling microscopy measurements of molecules at surfaces. The understanding of the underlying mechanisms is important for the design of molecular junctions that are stable at higher bias voltages and is a prerequisite for further developments in the field of current-induced chemistry. In this work, we analyse the mechanisms of current-induced bond rupture employing a recently developed method, which combines the hierarchical equations of motion approach in twin space with the matrix product state formalism, and allows accurate, fully quantum mechanical simulations of the complex bond rupture dynamics. Extending previous work [J. Chem. Phys. 154, 234702 (2021)], we consider specifically the effect of multiple electronic states and multiple vibrational modes. The results obtained for a series of models of increasing complexity show the importance of vibronic coupling between different electronic states of the charged molecule, which can enhance the dissociation rate at low bias voltages profoundly.

In scanning probe microscopy laser interferometers are usually used for measuring the position of the probe tip with a metrological traceability. As the most of the AFM setups are designed to work under standard atmospheric conditions the changes of the refractive index of air have an influence to measured values of the length with 1.0e-4 relatively. In order to achieve better accuracies the refractive index of air has to be monitored continuously and its instantaneous value has to be used for compensating the lengths measured by all of the interferometric axes. In the presented work we developed a new concept of an electronic unit which is able to monitor the refractive index of air on basis of measurement of ambient atmospheric conditions: temperature, humidity, pressure of the air and the CO2 concentration. The data processing is based on Ciddor equation for calculating the refractive index of air. The important advantage of the unit is a very low power consumption of the electronics so the unit causes only negligible temperature effects to the measured environment. The accuracy of the indirect measuring method employed by the unit was verified. We tested the accuracy in comparison with a direct method of measuring refractive index of air based on an evacuatable cell placed at the measuring arm of a laser interferometer. An experimental setup used for verification is presented together with a set of measurements describing the performance. The resulting accuracy of the electronic unit falls to the 4.1e-7 relatively., Comment: 8 pages, 4 figures; SPIE Optical Metrology 2013, 2013, Munich, Germany

The wide span and high density of lines in its rovibrational spectrum render hydrogen cyanide a useful spectroscopic media for referencing absolute frequencies of lasers in optical communication and dimensional metrology. We determined, for the first time to the best of our knowledge, the molecular transitions' center frequencies of the H13C14N isotope in the range from 1526 nm to 1566 nm with 1,3e-10 fractional uncertainty. We investigated the molecular transitions with a highly coherent and widely tunable scanning laser that was precisely referenced to a Hydrogen maser through an optical frequency comb. We demonstrated an approach to stabilize the operational conditions needed to maintain the constantly low pressure of the hydrogen cyanide to carry out the saturated spectroscopy with the third-harmonic synchronous demodulation. We demonstrated approximately a fourtyfold improvement in the line centers' resolution compared to the previous result., Comment: 9 pp, 4 figures. Originally submited to Optics Letters. Version 2 - please note: the measured center frequencies of the spectroscopic features were refined compared to Version 1

A metal oxide support and a catalytically active metal are the two main ingredients for complex catalysts used in heterogeneous catalysis. The gas environment can change the catalyst during the reaction, modifying its structural and electronic properties. Here, we use monochromated electron energy loss spectroscopy (EELS) to reveal hydrogen-pressure-dependent changes of the electronic structure at the Pd/rutile-TiO$_2$ interface in an environmental transmission electron microscope (ETEM). Hydrogen-induced changes are observed in rutile-TiO$_2$ within $2$~nm from the interface at $10$~Pa of hydrogen pressure, in the Ti $L_{3,2}$ EEL spectra. Lower pressures such as $1$~Pa show no changes in the EEL spectra. We attribute the observed changes in the EEL spectra to hydrogen-induced defects accumulating in the vicinity of the interface. Based on DFT calculations, we developed a thermodynamic multistate defect (TMD) model of the interface and the bulk of the rutile-TiO$_2$. This TMD model predicts high concentrations of positively charged defects accumulating at the interface. The presence of the Schottky barrier stabilizes these defects by significantly lowering their formation energy. Our findings provide important new insights into catalytic processes taking place at metal/metal oxide interfaces in hydrogen gas environments., Comment: 18 pages, 12 figures

We present a field report of CTU-CRAS-NORLAB team from the Subterranean Challenge (SubT) organised by the Defense Advanced Research Projects Agency (DARPA). The contest seeks to advance technologies that would improve the safety and efficiency of search-and-rescue operations in GPS-denied environments. During the contest rounds, teams of mobile robots have to find specific objects while operating in environments with limited radio communication, e.g. mining tunnels, underground stations or natural caverns. We present a heterogeneous exploration robotic system of the CTU-CRAS-NORLAB team, which achieved the third rank at the SubT Tunnel and Urban Circuit rounds and surpassed the performance of all other non-DARPA-funded teams. The field report describes the team's hardware, sensors, algorithms and strategies, and discusses the lessons learned by participating at the DARPA SubT contest., Comment: This paper have already been accepted to be published Filed Robotics special issue about DARPA SubT challange

Sprouts is a two-player pencil-and-paper game invented by John Conway and Michael Paterson in 1967. In the game, the players take turns in joining dots by curves according to simple rules, until one player cannot make a move. The game of Sprouts is very popular and simple-looking, so it may come as a surprise that there are essentially no AI Sprouts players available. This lack of computer opponents is caused by the fact that the game hides a surprisingly high combinatorial complexity and implementing it involves fascinating programming challenges. We overcome all the implementation barriers and create the first user-friendly Sprouts application with a strong artificial intelligence after more than 50 years of the existence of the game. In particular, we combine results from the theory of nimbers with new methods based on Delaunay triangulations and crossing-preserving force-directed algorithms to develop an AI Sprouts player which plays a perfect game on up to 11 spots., Comment: Appears in the Proceedings of the 29th International Symposium on Graph Drawing and Network Visualization (GD 2021)

Materials with high thermal conductivities (k) is valuable to solve the challenge of waste heat dissipation in highly integrated and miniaturized modern devices. Herein, we report the first synthesis of atomically thin isotopically pure hexagonal boron nitride (BN) and its one of the highest k among all semiconductors and electric insulators. Single atomic layer (1L) BN enriched with 11B has a k up to 1009 W/mK at room temperature. We find that the isotope engineering mainly suppresses the out-of-plane optical (ZO) phonon scatterings in BN, which subsequently reduces acoustic-optical scatterings between ZO and transverse acoustic (TA) and longitudinal acoustic (LA) phonons. On the other hand, reducing the thickness to single atomic layer diminishes the interlayer interactions and hence Umklapp scatterings of the out-of-plane acoustic (ZA) phonons, though this thickness-induced k enhancement is not as dramatic as that in naturally occurring BN. With many of its unique properties, atomically thin monoisotopic BN is promising on heat management in van der Waals (vdW) devices and future flexible electronics. The isotope engineering of atomically thin BN may also open up other appealing applications and opportunities in 2D materials yet to be explored.

We demonstrate an optical frequency analysis method using the Fourier transform of detection times of fluorescence photons emitted from a single trapped 40Ca+ ion. The response of the detected photon rate to the relative laser frequency deviations is recorded within the slope of a dark resonance formed in the lambda-type energy level scheme corresponding to two optical dipole transitions. This approach enhances the sensitivity to the small frequency deviations and does so with reciprocal dependence on the fluorescence rate. The employed lasers are phase locked to an optical frequency comb, which allows for precise calibration of optical frequency analysis by deterministic modulation of the analyzed laser beam with respect to the reference beam. The attainable high signal-to-noise ratios of up to a MHz range of modulation deviations and up to a hundred kHz modulation frequencies promise the applicability of the presented results in a broad range of optical spectroscopic applications.

A recently discovered modified low-temperature baking leads to reduced surface losses and an increase of the accelerating gradient of superconducting TESLA shape cavities. We will show that the dynamics of vacancy-hydrogen complexes at low-temperature baking lead to a suppression of lossy nanohydrides at 2\,K and thus a significant enhancement of accelerator performance. Utilizing Doppler broadening Positron Annihilation Spectroscopy, Positron Annihilation Lifetime Spectroscopy and instrumented nanoindentation, samples made from European XFEL niobium sheets were investigated. We studied the evolution of vacancies in bulk samples and in the sub-surface region and their interaction with hydrogen at different temperature levels during {\it in-situ} and {\it ex-situ} annealing.

We report on the robust experimental accumulation of nonclassicallity of motion of a single trapped ion. The nonclassicality stems from deterministic incoherent modulation of thermal phonon number distribution implemented by a laser excitation of nonlinear coupling between the ion's internal - electronic levels and external - motional states. We demonstrate that the repetitive application of this nonlinear process monotonically accumulates the observable state nonclassicality. The output states converge to a phonon number distribution with high overlap with a particular Fock state and visible quantum non-Gaussian aspects including corresponding negative Wigner function. The resulting oscillator states prove deterministic transition in the hierarchy of quantum non-Gaussianity up to four phonons. This transition is very robust against experimental imperfections and produces increasing entanglement potential.

Al-Mg-Si alloys with total solute contents ranging from 0.8 to 1.4 wt.% were solutionised, quenched and then artificially aged (AA) at 180 {\deg}C, after which positron annihilation lifetime spectroscopy was applied to obtain information about precipitation and vacancy evolution during preceding ageing. Hardness and electrical resistivity measurements were carried out to complement these measurements. AA was carried out in four different heating media, which allowed for varying the heating rate from 2.4 K/s to 170 K/s. The main result of the study is that there is a competition between vacancy losses and precipitation. Any precipitation taking place during quenching or during heating to the AA temperature helps to prevent vacancies from going to sinks and allows them to assist in solute clustering. Higher solute content, slower heating to 180 {\deg}C and natural pre-ageing before AA were found to have a comparable effect.

The laser spectroscopy is a fundamental approach for the realisation of traceable optical frequency standards. In the $1.55\,\mu$m wavelength band, widely used in telecommunications, the acetylene is the typical and the most widespread absorption media. We present our investigation of using the hydrogen cyanide (HCN) as a cost-efficient and readily available alternative, that also provides a wider frequency span (from $1527\,$nm to $1563\,$nm). We have compared the practical aspects of using new absorption media in comparison to existing experience with the acetylene with an outlook to carry out an independent measurement of the entire spectra. The results should contribute to the future inclusion of the HCN spectroscopic data into the Mise en pratique, thus allowing for the use of HCN as a reference for the realisation of traceable laser standards., Comment: CPS 2018, Lednice, CZ, September 2018; 7 pages, 7 figures

We demonstrated that an iodine stabilized Distributed Bragg Reflector (DBR) diode based laser system lasing at a wavelength in close proximity to $\lambda = 633\,$nm could be used as an alternative laser source to the He-Ne lasers in both scientific and industrial metrology. This yields additional advantages besides the optical frequency stability and coherence: inherent traceability, wider optical frequency tuning range, higher output power and high frequency modulation capability. We experimentally investigated the characteristics of the laser source in two major steps: first using a wavelength meter referenced to a frequency comb controlled with a hydrogen maser and then on a interferometric optical bench testbed where we compared the performance of the laser system with that of a traditional frequency stabilized He-Ne laser. The results indicate that DBR diode laser system provides a good laser source for applications in dimensional (nano)metrology, especially in conjunction with novel interferometric detection methods exploiting high frequency modulation or multiaxis measurement systems., Comment: Published 16 February 2017 copyright 2017 IOP Publishing Ltd