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In-operando techniques enable real-time measurement of intricate physical properties at the micro- and nano-scale under external stimuli, allowing the study of a wide range of materials and functionalities. In nanomagnetism, in-operando techniques greatly benefit from precise three-dimensional (3D) magnetic field control, enabling access to complex magnetic states forming in systems where multiple energies are set to compete with each other. However, achieving such precision is challenging and uncommon, as specific applications impose constraints on the type and geometry of magnetic field sources, limiting their capabilities. Here, we introduce an approach that leverages machine learning algorithms to achieve precise 3D magnetic field control using a hexapole electromagnet that is composed of three independent, non-collinear dipole electromagnets. In our experimental setup, magnetic field sensors are placed at a distance from the sample position due to inherent constraints, leading to indirect field measurements that differ from the magnetic field experienced by the sample. We find that the existing relationship between the remote and sample frames of reference is non-linear, thus requiring a more complex calibration method. To address this, we employ a multi-layer perceptron neural network that processes multiple inputs from a dynamic magnetic field sequence, effectively capturing the time-dependent non-linear field response. The network achieves high calibration accuracy and demonstrates exceptional generalization to unseen magnetic field sequences. This study highlights the significant potential of machine learning in achieving high-precision control and calibration, crucial for in-operando experiments where direct measurement at the point of interest is not possible.

The atmospheres of phosphorus-rich stars have been shown to contain between 10 and 100 times more P than our Sun. Given its crucial role as an essential element for life, it is especially necessary to uncover the origin of P-rich stars to gain insights into the still unknown nucleosynthetic formation pathways of P in our Galaxy. Our objective is to obtain the extensive chemical abundance inventory of four P-rich stars, covering a large range of heavy elements. This characterization will serve as a milestone for the nuclear astrophysics community to uncover the processes that form the unique chemical fingerprint of P-rich stars. We performed a detailed 1D local thermodynamic equilibrium abundance analysis on the optical UVES spectra of four P-rich stars. Our focus lay on the neutron-capture elements, in particular, on the elements between Sr and Ba, as well as on Pb, as they provide valuable constraints to nucleosynthesis calculations. We compare the obtained abundances with three different nucleosynthetic scenarios: a single i-process, a double i-process, and a combination of s- and i-processes. We have performed the most extensive abundance analysis of P-rich stars to date, including the elements between Sr and Ba, such as Ag, which are rarely measured in any type of stars. We found overabundances with respect to solar in the s-process peak elements, accompanied by an extremely high Ba abundance and slight enhancements in some elements between Rb and Sn. No global solution explaining all four stars could be found for the nucleosynthetic origin of the pattern. The model that produces the least number of discrepancies in three of the four stars is a combination of s- and i-processes, but the current lack of extensive multidimensional hydrodynamic simulations to follow the occurrence of the i-process in different types of stars makes this scenario highly uncertain., Comment: 24 pages, 9 figures, 6 tables, accepted for publication in Astronomy & Astrophysics

Carbon abundances in first-ascent giant stars are usually lower than those of their main-sequence counterparts. At moderate metallicities, stellar evolution of single stars cannot account for the existence of red-giant branch stars with enhanced carbon abundances. The phenomenon is usually interpreted as resulting from past mass transfer from an evolved binary companion now in the white dwarf evolutionary stage. Aims: We aim to confirm the links between [C/O] enhancement, s-process element enhancement and binary fraction using large-scale catalogues of stellar abundances and probable binary stars. Methods: We use a large data set from the 17 data release of the SDSS-IV/APOGEE~2 survey to identify carbon-enhanced stars in the Galactic disk. We identify a continuum of carbon enrichment throughout three different sub-populations of disk stars and explore links between the degree of carbon enrichment and binary frequency, metallicity and chemical compositions. Results: We verify a clear correlation between binary frequency and enhancement in the abundances of both carbon and cerium, lending support to the scenario whereby carbon-enhanced stars are the result of mass transfer by an evolved binary companion. In addition, we identify clustering in the carbon abundances of high-$\alpha$ disk stars, suggesting that those on the high metallicity end are likely younger, in agreement with theoretical predictions for the presence of a starburst population following the gas-rich merger of the Gaia-Enceladus/Sausage system., Comment: 20 pages

Planetary nebulae (PNe) have three main components: a central star (CS), ionised gas and dust in the nebula. Each of them contains critical chemical fingerprints of their evolution, serving as tracers of the evolution, nucleosynthesis and dust production that occurred during the preceding asymptotic giant branch (AGB) phase. We aim to build a bridge to link the PN phase to the evolution of their progenitors, trying to better understand the dust production and mass-loss mechanism during the final AGB phase. Here, we present a comprehensive study of nine Large Magellanic Cloud (LMC) spherical or elliptical PNe whose observations from the ultraviolet (UV) through the infrared (IR) are available in the literature. We characterize nebulae and CSs, finding information as the amount of gas that makes up the nebula and the dust that surrounds the CS, necessary to reconstruct the evolutionary history of mass-loss and dust production. We compare the observed energy distribution of the selected PNe to that obtained from photoionization modeling, taking into account the presence of dust. The physical and chemical parameters of the central stars are then compared with the predictions from the evolutionary tracks. We characterized the source, assigning to each CS a progenitor, early-AGB mass. We estimated the mass of the nebula and the dust-to-gas ratio. For 5 objects, we find evidence for the presence of a near-IR bump, which would be connected to the presence of hot dust., Comment: 16 pages, 8 figures. Accepted for publication on Astronomy & Astrophysics

Dusty post-red giant branch (post-RGB) stars are low- and intermediate-mass stars where the RGB evolution was prematurely terminated by a poorly understood binary interaction. These binary stars are considered to be low-luminosity analogues of post-asymptotic giant branch (post-AGB) binary stars. In this study, we investigated the chemical composition of two dusty post-RGB binary stars, SZ Mon and DF Cyg, using multi-wavelength spectroscopic data from HERMES/Mercator (optical) and the APOGEE survey (near-infrared). Owing to challenges posed by existing spectral analysis tools for the study of evolved stars with complex atmospheres, we developed E-iSpec: a dedicated spectral analysis tool for evolved stars, to consistently determine atmospheric parameters, elemental abundances, and carbon isotopic ratios. Our abundance analysis revealed that observed depletion patterns and estimated depletion efficiencies resemble those found in post-AGB binary stars. However, the onset of chemical depletion in post-RGB targets occurs at higher condensation temperatures ($T_{\rm turn-off, post-RGB}\approx1400$ K), than in most post-AGB stars ($T_{\rm turn-off, post-AGB}\approx1100$ K). Additionally, our study resulted in the first estimates of carbon isotopic ratios for post-RGB stars ($^{12}$C/$^{13}$C$_{\rm SZ Mon}=8\pm4$, $^{12}$C/$^{13}$C$_{\rm DF Cyg}=12\pm3$). We found that the observationally derived CNO abundances and the carbon isotopic ratios of our post-RGB binary targets are in good agreement with theoretical predictions from the ATON single star evolutionary models involving first dredge-up and moderately-deep extra mixing. This agreement emphasises that in post-RGB binary targets, the observed CNO abundances reflect the chemical composition expected from single star nucleosynthesis (i.e., convective and non-convective mixing processes) occurring during the RGB phase before it is terminated.

Fullerenes have been observed in several astronomical objects since the discovery of C$_{60}$ in the mid-infrared (mid-IR) spectrum of the planetary nebula (PN) Tc 1. It has been suggested that the carriers of the broad unidentified infrared (UIR) plateau features, such as the 9$-$13$\mu$m emission feature (12$\mu$m hereafter), may be related to the formation of fullerenes. In particular, their carriers have been suggested to be mixed aromatic or aliphatic hydrocarbons such as hydrogenated amorphous carbon (HAC-like hereafter) grains. For this study, we modeled the mid-IR emission of the C$_{60}$-PN Tc 1 with a photoionization code, including for the first time the laboratory optical constants ($n$ and $k$ indices) of HAC-like dust at 300 K. Interestingly, we find that the broad 12$\mu$m plateau feature in Tc 1 is well reproduced by using a distribution of canonical HAC grains, while at the same time they provide an important fraction of the IR dust continuum emission and are consistent with the other UIR features observed (e.g., the broad 6$-$9$\mu$m plateau feature). This finding suggests that HAC-like grains may be possible carriers of the 12$\mu$m plateau feature, being likely related to the fullerene formation mechanism in PNe. More laboratory experiments, to obtain the optical constants of HAC-like dust with several structures or a composition at different physical conditions, are strongly encouraged -- that is, in order to extend this pilot study to more fullerene PNe, and to unveil the details of fullerene formation and of the potential carriers of the elusive UIR plateau features., Comment: Published in Astronomy and Astrophysics Letters. 7 pages, 3 figures

This manuscript investigates the problem of locational complexity, a type of complexity that emanates from a companys territorial strategy. Using an entropy-based measure for supply chain structural complexity ( pars-complexity), we develop a theoretical framework for analysing the effects of locational complexity on the profitability of service/manufacturing networks. The proposed model is used to shed light on the reasons why network restructuring strategies may result ineffective at reducing complexity-related costs. Our contribution is three-fold. First, we develop a novel mathematical formulation of a facility location problem that integrates the pars-complexity measure in the decision process. Second, using this model, we propose a decomposition of the penalties imposed by locational complexity into (a) an intrinsic cost of structural complexity; and (b) an avoidable cost of ignoring such complexity in the decision process. Such a decomposition is a valuable tool for identifying more effective measures for tackling locational complexity, moreover, it has allowed us to provide an explanation to the so-called addiction to growth within the locational context. Finally, we propose three alternative strategies that attempt to mimic different approaches used in practice by companies that have engaged in network restructuring processes. The impact of those approaches is evaluated through extensive numerical experiments. Our experimental results suggest that network restructuring efforts that are not accompanied by a substantial reduction on the target market of the company, fail at reducing complexity-related costs and, therefore, have a limited impact on the companys profitability., Comment: This work was published in Applied Mathematical modelling (Elsevier). Cite as: Pinar-P\'erez, J.M., Ruiz-Hern\'andez, D. and Menezes, M.B.C. (2022) Market proliferation and the impact of locational complexity on network restructuring. Applied Mathematical Modelling, 104. pp. 315-338. https://doi.org/10.1016/j.apm.2021.11.031

Several planetary nebulae (PNe) have been found to contain both polycyclic aromatic hydrocarbon (PAH-like) species and fullerenes (C$_{60}$) distinguished by their mid-infrared emission. Previous laboratory and astronomical studies suggest that the formation of both species could be related to the decomposition, by photochemical processing, of hydrogenated amorphous carbon (HAC) grains. Then, HACs and, seemingly, big-fullerene related species (e.g., carbon onions) have been suggested as potential carriers of the UV bump at 2175{\AA} and the far-UV rise common to interstellar extinction curves. Our goal is to investigate the UV bump with the possible presence of a HAC extinction component in the International Ultraviolet Explorer (IUE) spectra of C-rich PNe; both with detected and non-detected fullerenes. The considered sample includes three C$_{60}$-PNe (Tc 1, IC 418, and IC 2501) and the non-C$_{60}$-PN Hen 2-5. Independently of the presence of C$_{60}$ in their circumstellar envelopes, we found that the UV bump in all sample PNe is well explained by interstellar extinction, suggesting that species different from those of the foreground insterstellar medium, e.g., large fullerene-related species like carbon onions, are not the carrier. Interestingly, we found that PNe Tc 1 and Hen 2-5 show an absorption in the FUV rise. Their IUE continuum spectra may be very well reproduced by including the extinction curve of HAC-like very small grains (VSG). The possible presence of both species, HAC-like grains and fullerenes (C$_{60}$), in Tc 1 could support the HAC photochemical processing scenario for the formation of fullerenes in the complex circumstellar envelopes of PNe., Comment: 9 pages, 8 figures. Accepted for publication in MNRAS

We present a novel approach to address dust production by low- and intermediate-mass stars. We study the asymptotic giant branch (AGB) phase, during which the formation of dust takes place, from the perspective of post-AGB and planetary nebula (PN) evolutionary stage. Using results from stellar evolution and dust formation modelling, we interpret the spectral energy distribution of carbon-dust-rich sources currently evolving through different evolutionary phases, believed to descend from progenitors of similar mass and chemical composition. Comparing the results of different stages along the AGB to PNe transition, we can provide distinct insights on the amount of dust and gas released during the very late AGB phases. While the post-AGB traces the history of dust production back to the tip of the AGB phase, investigating the PNe is important to reconstruct the mass-loss process experienced after the last thermal pulse. The dust surrounding the post-AGB was formed soon after the tip of the AGB. The PNe dust-to-gas ratio is $\sim10^{-3}$, 2.5 times smaller than what expected for the same initial mass star during the last AGB interpulse, possibly suggesting that dust might be destroyed during the PN phase. Measuring the amount of dust present in the nebula can constrains the capacity of the dust to survive the central star heating., Comment: 7 pages, 2 figures and 1 table. Accepted for publication in MNRAS

Small metal-containing molecules have been detected and recognized as one of the hybrid species efficiently formed in space; especially in the circumstellar envelopes of evolved stars. It has been predicted also that more complex hybrid species like those formed by metals and fullerenes (metallofullerenes) could be present in such circumstellar environments. Recently, quantum-chemical simulations of metallofullerenes have shown that they are potential emitters contributing to the observed mid-IR spectra in the fullerene-rich circumstellar environments of different types of evolved stars. Here we present the individual simulated mid-IR (~5-50 um) spectra of twenty-eight metallofullerene species; both neutral and charged endo- and exohedral metallofullerenes for seven different metals (Li, Na, K, Ca, Mg, Ti, and Fe) have been considered. The changes induced by the metal-C60 interaction on the intensity and position of the spectral features are highlighted using charge density difference maps and electron density partitioning. Our calculations identify the fundamental IR spectral regions where, depending on the metal binding nature, there should be a major spectral contribution from each of the metallofullerenes. The metallofullerenes IR spectra are made publicly available to the astronomical community, especially James Webb Space Telescope users, for comparisons that could eventually lead to the detection of these species in space., Comment: Accepted for publication in The Astrophysical Journal Supplement Series on 19 September 2023 (in press) (13 pages, 7 figures, and 1 table)

Optical and near-IR photometry suggests that the carbon star DY Persei exhibits fadings similar to those of R Coronae Borealis (RCB) variables. Photometric surveys of the Galaxy and Magellanic Clouds uncovered new DY Per variables with infrared photometry identifying them with cool carbon stars, perhaps, with an unusual tendency to shed mass. In an attempt to resolve DY Per's identity crisis -- a cool carbon giant or a cool RCB variable? -- we analyze a high-resolution H&K band spectrum of DY Per. The CO first-overtone bands in the K-band of DY Per show a high abundance of 18O such that 16O/18O = 4 +- 1, a ratio sharply at odds with published results for `regular' cool carbon giants with 16O/18O ~ 1000 but this exceptionally low ratio is characteristic of RCB-variables and HdC stars. This similarity suggests that DY Per indeed may be a cool RCB variable. Current opinion considers RCB-variables to result from merger of a He onto a CO white dwarf; observed abundances of these H-deficient stars including the exceptionally low 16O/18O ratios are in fair accord with predicted compositions for white dwarf merger products. A H-deficiency for DY Per is not directly observable but is suggested from the strength of a HF line and an assumption that F may be overabundant, as observed and predicted for RCB stars., Comment: Accepted for publication in ApJ (16 pages and 4 figures)

The origin of phosphorus, one of the essential elements for life on Earth, is currently unknown. Prevalent models of Galactic chemical evolution (GCE) underestimate the amount of P compared to observations. The recently discovered P-rich ([P/Fe] > 1 dex) and metal-poor giants further challenge current theories on stellar nucleosynthesis. Since the observed stars are low-mass giants, our primary goal is to find clues on their progenitor. By increasing the number of known P-rich stars, we aim to narrow down a reliable chemical abundance pattern and to place robust constraints on the responsible nucleosynthetic mechanism. In the long term, identifying the progenitor of the P-rich stars may contribute to the search for the source of P in our Galaxy. We performed a detailed chemical abundance analysis based on the H-band spectra from APOGEE-2 (DR17). Employing the BACCHUS code, we measured the abundances of 13 elements in the sample, which is mainly composed of a recent collection of Si-enhanced giants. We also analyzed the orbital motions and compared the abundance results to possible nucleosynthetic formation scenarios, and also to detailed GCE models. We enlarged the sample of confirmed P-rich stars from 16 to 78 giants, which represents the largest sample of P-rich stars to date. Significant enhancements in O, Al, Si and Ce, as well as systematic correlations among the elements, unveil the chemical fingerprint of the P-rich stars. The high Mg and C+N found in some of the P-rich stars with respect to P-normal stars is not confirmed over the full sample. Strikingly, the strong over-abundance in the $\alpha$-element Si is accompanied by normal Ca and S abundances. Our analysis of the orbital motion showed that the P-rich stars do not belong to a specific sub-population. In addition, we confirm that the majority of the sample stars are not part of binary systems., Comment: 29 pages, 18 figures, 8 tables, accepted for publication in Astronomy & Astrophysics

Planetary nebulae (PNe), the ejected envelopes of red giant stars, provide us with a history of the last, mass-losing phases of 90 percent of stars initially more massive than the Sun. Here, we analyse James Webb Space Telescope (JWST) Early Release Observation (ERO) images of the PN NGC3132. A structured, extended H2 halo surrounding an ionised central bubble is imprinted with spiral structures, likely shaped by a low-mass companion orbiting the central star at 40-60 AU. The images also reveal a mid-IR excess at the central star interpreted as a dusty disk, indicative of an interaction with another, closer companion. Including the previously known, A-type visual companion, the progenitor of the NGC3132 PN must have been at least a stellar quartet. The JWST images allow us to generate a model of the illumination, ionisation and hydrodynamics of the molecular halo, demonstrating the power of JWST to investigate complex stellar outflows. Further, new measurements of the A-type visual companion allow us to derive the value for the mass of the progenitor of a central star to date with excellent precision: 2.86+/-0.06 Mo. These results serve as path finders for future JWST observations of PNe providing unique insight into fundamental astrophysical processes including colliding winds, and binary star interactions, with implications for supernovae and gravitational wave systems., Comment: 32 pages, 5 figures for the main article. 12 pages 8 figures for the supplementary material

The formation of silicates in circumstellar envelopes of stars evolving through the AGB is still debated given the uncertainties affecting stellar evolution modelling, the description of the dust formation process, and the capability of silicate grains to accelerate stellar outflows via radiation pressure. We study the formation of dust in the winds of intermediate mass (M $\geq 4 M_{\odot}$) stars of solar metallicity while evolving through the AGB phase. We tested the different treatments of the mass-loss mechanism by this class of stars, with the aim of assessing their contribution to the general enrichment of silicates of the interstellar medium of galaxies. We consider a sub-sample of AGB stars, whose SED is characterised by deep absorption features at $10$ and $18\mu$m, which can be regarded as the class of stars providing the most relevant contribution to the silicates' production across the Universe. Results from stellar evolution and dust formation modelling were used to fit the observed SED and to reproduce, at the same time, the detected pulsation periods and the derived surface chemical composition. This analysis leads to the derivation of tight constraints on the silicates' production rates experienced by these sources during the final AGB stages. Two out of the four sources investigated are interpreted as stars currently undergoing HBB, evolving through phases close to the stage when the mass-loss rate is largest. The remaining two stars are likely evolving through the very final AGB phases, after HBB was turned off by the gradual consumption of the convective mantle. Mass-loss rates of the order of $1-2\times 10^{-4} M_{\odot}/$yr are required when looking for consistency with the observational evidence. These results indicate the need for a revision of the silicate yields by intermediate mass stars, which are found to be $\sim 3$ times higher than previously determined.

The presence of neutral C60 fullerenes in circumstellar environments has been firmly established by astronomical observations as well as laboratory experiments and quantum-chemistry calculations. However, the large variations observed in the C60 17.4um/18.9um band ratios indicate that either additional emitters should contribute to the astronomical IR spectra or there exist unknown physical processes besides thermal and UV excitation. Fullerene-based molecules such as metallofullerenes and fullerene-adducts are natural candidate species as potential additional emitters, but no specific species has been identified to date. Here we report a model based on quantum-chemistry calculations and IR spectra simulation of neutral and charged endo(exo)hedral metallofullerenes, showing that they have a significant contribution to the four strongest IR bands commonly attributed to neutral C60. These simulations may explain the large range of 17.4um/18.9um band ratios observed in very different fullerene-rich circumstellar environments like those around planetary nebulae and chemically peculiar R Coronae Borealis stars. Our proposed model also reveals that the 17.4um/18.9um band ratio in the metallofullerenes simulated IR spectra mainly depends on the metal abundances, ionization level, and endo/exo concentration in the circumstellar envelopes. We conclude that metallofullerenes are potential emitters contributing to the observed IR spectra in fullerene-rich circumstellar envelopes. Our simulated IR spectra indicate also that the James Webb Space Telescope has the potential to confirm or refute the presence of metallofullerenes (or even other fullerene-based species) in circumstellar enviroments., Comment: Accepted for publication in The Astrophysical Journal on 23 November 2022 (in press) (10 pages, 4 figures, and 1 tables)

The magneto-optical Kerr effect (MOKE) is a widely used lab-based technique for the study of thin films and nanostructures, providing magnetic characterization with good spatial and temporal resolutions. Due to the complex coupling of light with a magnetic sample, conventional MOKE magnetometers normally work by selecting a small range of incident wave-vector values, focusing the incident light beam to a small spot, and recording the reflected intensity at that angular range by means of photodetectors. This generally provides signals proportional to a mixture of magnetization components, requiring additional methodologies for full vectorial magnetic characterization. Here, we computationally investigate a Fourier-space MOKE setup, where a focused beam ellipsometer using high numerical aperture optics and a camera detector is employed to simultaneously map the intensity distribution for a wide range of incident and reflected wave-vectors. We employ circularly incident polarized light and no analyzing optics, in combination with a fitting procedure of the light intensity maps to the analytical expression of the Kerr effect under linear approximation. In this way, we are able to retrieve the three unknown components of the magnetization vector as well as the material's optical and magneto-optical constants with high accuracy and short acquisition times, with the possibility of single shot measurements. Fourier MOKE is thus proposed as a powerful method to perform generalized magneto-optical ellipsometry for a wide range of magnetic materials and devices.

The Sloan Digital Sky Survey IV (SDSS-IV) APOGEE-2 primary science goal was to observe red giant stars throughout the Galaxy to study its dynamics, morphology, and chemical evolution. The APOGEE instrument, a high-resolution 300 fiber H-band (1.55-1.71 micron) spectrograph, is also ideal to study other stellar populations in the Galaxy, among which are a number of star forming regions and young open clusters. We present the results of the determination of six stellar properties ($T_{eff}$, $\log{g}$, [Fe/H], $L/L_\odot$, $M/M_\odot$, and ages) for a sample that is composed of 3360 young stars, of sub-solar to super-solar types, in sixteen Galactic star formation and young open cluster regions. Those sources were selected by using a clustering method that removes most of the field contamination. Samples were also refined by removing targets affected by various systematic effects of the parameter determination. The final samples are presented in a comprehensive catalog that includes all six estimated parameters. This overview study also includes parameter spatial distribution maps for all regions and Hertzprung-Russell ($L/L_\odot$ vs. $T_{eff}$) diagrams. This study serves as a guide for detailed studies on individual regions, and paves the way for the future studies on the global properties of stars in the pre-main sequence phase of stellar evolution using more robust samples., Comment: 6 figures, 4 tables

Stellar spectral classification has been highly useful in the study of stars. While there is a currently accepted spectral classification system for carbon stars, the subset of Hydrogen-deficient Carbon (HdC) stars has not been well described by such a system, due predominantly to their rarity and their variability. Here we present the first system for the classification of HdCs based on their spectra, which is made wholly on their observable appearance. We use a combination of dimensionality reduction and clustering algorithms with human classification to create such a system with eight total classes corresponding to temperature, and an additional second axis corresponding to the carbon molecular band strength. We classify over half of the known sample of HdC stars using this, and roughly calibrate the temperatures of each class using their colors. Additionally, we express trends in the occurrence of certain spectral peculiarities such as the presence of Hydrogen and Lithium lines. We also present three previously unpublished spectra, report the discovery of two new Galactic dustless HdC (dLHdC) stars and additionally discuss one especially unique star that appears to border between the hottest HdCs and the coolest Extreme Helium (EHe) stars., Comment: 30 pages, 18 figures, submitted to MNRAS January 11, 2023 revision: Changes updated according to referee comments

Cylindrical magnetic nanowires are promising systems for the development of three-dimensional spintronic devices. Here, we simulate the evolution of magnetic states during fabrication of strongly-coupled cylindrical nanowires with varying degrees of overlap. By varying the separation between wires, the relative strength of exchange and magnetostatic coupling can be tuned. Hence leading to the formation of six fundamental states as a function of both inter-wire separation and wire height. In particular, two complex three-dimensional magnetic states, a 3D Landau Pattern and a Helical Domain wall, are observed to emerge for intermediate overlap. The competition of magnetic interactions and the parallel growth scheme we follow (growing both wires at the same time) favours the formation of these anti-parallel metastable states. This works shows how the engineering of strongly coupled 3D nanostructures with competing interactions can be used to create complex spin textures.

Elements with weak and blended spectral features in stellar spectra are challenging to measure and require specialized analysis methods to precisely measure their chemical abundances. In this work, we have created a catalog of approximately 120,000 giants with high signal-to-noise APOGEE DR17 spectra, for which we explore weak and blended species to measure Na, P, S, V, Cu, Ce, and Nd abundances and $^{12}$C/$^{13}$C isotopic ratios. We employ an updated version of the BACCHUS (Brussels Automatic Code for Characterizing High accUracy Spectra) code to derive these abundances using the stellar parameters measured by APOGEE's DR17 ASPCAP pipeline, quality flagging to identify suspect spectral lines, and a prescription for upper limits. Combined these allow us to provide our BACCHUS Analysis of Weak Lines in APOGEE Spectra (BAWLAS) catalog of precise chemical abundances for these weak and blended species that agrees well with literature and improves upon APOGEE abundances for these elements, some of which are unable to be measured with APOGEE's current, grid-based approach without computationally expensive expansions. This new catalog can be used alongside APOGEE and provide measurements for many scientific applications ranging from nuclear physics to Galactic chemical evolution and Milky Way population studies. To illustrate this we show some examples of uses for this catalog, such as, showing that we observe stars with enhanced s-process abundances or that we can use the our $^{12}$C/$^{13}$C ratios to explore extra mixing along the red giant branch., Comment: 49 Pages, 30 figures, 7 Tables. Accepted for publishing in The Astrophysical Journal Supplement Series. The BAWLAS chemical abundance catalog to be made publicly available as an SDSS DR17 value-added catalog: https://www.sdss.org/dr17/data_access/value-added-catalogs/

The goal of the Open Cluster Chemical Abundances and Mapping (OCCAM) survey is to constrain key Galactic dynamic and chemical evolution parameters by the construction and analysis of a large, comprehensive, uniform data set of infrared spectra for stars in hundreds of open clusters. This sixth contribution from the OCCAM survey presents analysis of SDSS/APOGEE Data Release 17 (DR17) results for a sample of stars in 150 open clusters, 94 of which we designate to be "high quality'' based on the appearance of their color-magnitude diagram. We find the APOGEE DR17-derived [Fe/H] values to be in good agreement with those from previous high resolution spectroscopic open cluster abundance studies. Using a subset of the high quality sample, the Galactic abundance gradients were measured for 16 chemical elements, including [Fe/H], for both Galactocentric radius ($R_{GC}$) and guiding center radius ($R_{Guide}$). We find an overall Galactic [Fe/H] vs $R_{GC}$ gradient of $-0.073 \pm 0.002$ dex/kpc over the range of $6 < R_{GC} < 11.5$ kpc, and a similar gradient is found for [Fe/H] versus $R_{Guide}$. Significant Galactic abundance gradients are also noted for O, Mg, S, Ca, Mn, Na, Al, K and Ce. Our large sample additionally allows us to explore the evolution of the gradients in four age bins for the remaining 15 elements., Comment: 21 pages, 14 Figures, Astronomical Journal Accepted

Galactic haloes in a $\Lambda$-CDM universe are predicted to host today a swarm of debris resulting from cannibalised dwarf galaxies. The chemo-dynamical information recorded in their stellar populations helps elucidate their nature, constraining the assembly history of the Galaxy. Using data from APOGEE and \textit{Gaia}, we examine the chemical properties of various halo substructures, considering elements that sample various nucleosynthetic pathways. The systems studied are Heracles, \textit{Gaia}-Enceladus/Sausage (GES), the Helmi stream, Sequoia, Thamnos, Aleph, LMS-1, Arjuna, I'itoi, Nyx, Icarus, and Pontus. Abundance patterns of all substructures are cross-compared in a statistically robust fashion. Our main findings include: {\it i)} the chemical properties of most substructures studied match qualitatively those of dwarf Milky Way satellites, such as the Sagittarius dSph. Exceptions are Nyx and Aleph, which are chemically similar to disc stars, implying that these substructures were likely formed \textit{in situ}; {\it ii)} Heracles differs chemically from {\it in situ} populations such as Aurora and its inner halo counterparts in a statistically significant way. The differences suggest that the star formation rate was lower in Heracles than in the early Milky Way; {\it iii)} the chemistry of Arjuna, LMS-1, and I'itoi is indistinguishable from that of GES, suggesting a possible common origin; {\it iv)} all three Sequoia samples studied are qualitatively similar. However, only two of those samples present chemistry that is consistent with GES in a statistically significant fashion; {\it v)} the abundance patterns of the Helmi stream and Thamnos are different from all other halo substructures., Comment: Accepted for publication in MNRAS. The revised version contains a detailed comparison of the chemical composition of Heracles against Aurora and its inner halo in situ counterparts as well as a revised discussion of the chemistry of various Sequoia samples in contrast with Gaia-Enceladus/Sausage

We surveyed a sample of compact Galactic planetary nebulae (PNe) with the Space Telescope Imaging Spectrograph on the Hubble Space Telescope (HST/STIS) to determine their gas-phase carbon abundances. Carbon abundances in PNe constrain the nature of their asymptotic giant branch (AGB) progenitors, as well as cosmic recycling. We measured carbon abundances, or limits thereof, of 11 compact Galactic PNe, notably increasing the sample of Galactic PNe whose carbon abundance based on HST ultraviolet spectra is available. Dust content of most targets has been studied elsewhere from Spitzer spectroscopy; given the compact nature of the nebulae, both UV and IR spectra can be directly compared to study gas- and dust-phase carbon. We found that carbon-poor (C/O<1) compact Galactic PNe have oxygen-rich dust type (ORD), while their carbon-enhanced counterparts (C/O>1) have carbon-rich dust (CRD), confirming the correlation between gas- and dust-phase carbon content which was known for Magellanic Cloud PNe. Based on models of expected final yields from AGB evolution we interpret the majority of the carbon-poor PNe in this study as the progeny of ~1.1-1.2 M$_{\odot}$ stars that experienced some extra-mixing on the red giant branch (RGB), they went through the AGB but did not go through the carbon star phase. Most PNe in this group have bipolar morphology, possibly due to the presence of a sub-solar companion. Carbon-enhanced PNe in our sample could be the progeny of stars in the ~1.5-2.5 M$_{\odot}$ range, depending on their original metallicity., Comment: The Astrophysical Journal, in press

Large scale surveys open the possibility to investigate Galactic evolution both chemically and kinematically, however, reliable stellar ages remain a major challenge. Detailed chemical information provided by high-resolution spectroscopic surveys of the stars in clusters can be used as a means to calibrate recently developed chemical tools for age-dating field stars. Using data from the Open Cluster Abundances and Mapping (OCCAM) survey, based on the SDSS/APOGEE-2 survey, we derive a new empirical relationship between open cluster stellar ages and the carbon-to-nitrogen ([C/N]) abundance ratios for evolved stars, primarily those on the red giant branch. With this calibration, [C/N] can be used a chemical clock for evolved field stars to investigate the formation and evolution of different parts of our Galaxy. We explore how mixing effects at different stellar evolutionary phases, like the red clump, affect the derived calibration. We have established the [C/N]-age calibration for APOGEE DR17 giant star abundances to be $\log[Age({\rm yr})]_{\rm DR17} = 10.14 \, (\pm 0.08) + 2.23\,(\pm 0.19) \, {\rm [C/N]}$, usable for $8.62 \leq \log(Age[{\rm yr}]) \leq 9.82$, derived from a uniform sample of 49 clusters observed as part of APOGEE DR17 applicable primarily to metal-rich, thin and thick disk giant stars. This measured [C/N]-age APOGEE DR17 calibration is also shown to be consistent with astereoseismic ages derived from Kepler photometry., Comment: 13 pages, 6 figures, accepted Astronomical Journal

Water pollution with pharmaceutical and personal care products has become a serious environmental. A reasonable strategy to mitigate the problem involves absorbent materials. In particular, the use of natural clays is an advantageous alternative considering their high adsorption capacity and compatibility with the environment. In the present work, the efficacy of a Cuban natural clay (palygorskite, Pal) as support of sulfamethoxazole (SMX), an antibiotic considered an emerging contaminant (EC), was evaluated. The amount of SMX incorporated onto clay was determined by UV spectroscopy. The resulting composite material was characterized by infrared spectroscopy (IR), X-ray diffraction (XRD), thermogravimetric analysis (TG/DTG), zeta potential (ZP), nitrogen adsorption measurements and transmission electron microscopy (TEM). The drug desorption studies in aqueous solution indicated the reversibility of the incorporation process, suggesting the potential use of the Pal nanoclay as an effective support of SMX and hence, a good prospect for water decontamination.

Stellar radial migration plays an important role in reshaping a galaxy's structure and the radial distribution of stellar population properties. In this work, we revisit reported observational evidence for radial migration and quantify its strength using the age--[Fe/H] distribution of stars across the Milky Way with APOGEE data. We find a broken age--[Fe/H] relation in the Galactic disc at $r>6$ kpc, with a more pronounced break at larger radii. To quantify the strength of radial migration, we assume stars born at each radius have a unique age and metallicity, and then decompose the metallicity distribution function (MDF) of mono-age young populations into different Gaussian components that originated from various birth radii at $r_{\rm birth}<13$ kpc. We find that, at ages of 2 and 3 Gyr, roughly half the stars were formed within 1 kpc of their present radius, and very few stars ($<5$%) were formed more than 4 kpc away from their present radius. These results suggest limited short distance radial migration and inefficient long distance migration in the Milky Way during the last 3 Gyr. In the very outer disc beyond 15~kpc, the observed age--[Fe/H] distribution is consistent with the prediction of pure radial migration from smaller radii, suggesting a migration origin of the very outer disc. We also estimate intrinsic metallicity gradients at ages of 2 and 3 Gyr of $-0.061$ dex kpc$^{-1}$ and $-0.063$ dex kpc$^{-1}$, respectively., Comment: 18 pages, 12 figures, MNRAS in press

Individual chemical abundances for fourteen elements (C, O, Na, Mg, Al, Si, K, Ca, Ti, V, Cr, Mn, Fe, and Ni) are derived for a sample of M-dwarfs using high-resolution near-infrared $H$-band spectra from the SDSS-IV/APOGEE survey. The quantitative analysis included synthetic spectra computed with 1-D LTE plane-parallel MARCS models using the APOGEE DR17 line list to determine chemical abundances. The sample consists of eleven M-dwarfs in binary systems with warmer FGK-dwarf primaries and ten measured interferometric angular diameters. To minimize atomic diffusion effects, [X/Fe] ratios are used to compare M-dwarfs in binary systems and literature results for their warmer primary stars, indicating good agreement ($<$0.08 dex) for all studied elements. The mean abundance differences in Primaries-this work M-dwarfs is -0.05$\pm$0.03 dex. It indicates that M-dwarfs in binary systems are a reliable way to calibrate empirical relationships. A comparison with abundance, effective temperature, and surface gravity results from the ASPCAP pipeline (DR16) finds a systematic offset of [M/H], $T_{\rm eff}$, log$g$ = +0.21 dex, -50 K, and 0.30 dex, respectively, although ASPCAP [X/Fe] ratios are generally consistent with this study. The metallicities of the M dwarfs cover the range of [Fe/H] = -0.9 to +0.4 and are used to investigate Galactic chemical evolution via trends of [X/Fe] as a function of [Fe/H]. The behavior of the various elemental abundances [X/Fe] versus [Fe/H] agrees well with the corresponding trends derived from warmer FGK-dwarfs, demonstrating that the APOGEE spectra can be used to Galactic chemical evolution using large samples of selected M-dwarfs., Comment: 19 pages. Accepted to ApJ

The APOGEE Open Cluster Chemical Abundances and Mapping (OCCAM) survey is used to probe the chemical evolution of the s-process element cerium in the Galactic disk. Cerium abundances were derived from measurements of Ce II lines in the APOGEE spectra using the Brussels Automatic Code for Characterizing High Accuracy Spectra (BACCHUS) in 218 stars belonging to 42 open clusters. Our results indicate that, in general, for Ages $<$ 4 Gyr, younger open clusters have higher [Ce/Fe] and [Ce/$\alpha$-element] ratios than older clusters. In addition, metallicity segregates open clusters in the [Ce/X]-Age plane (where X can be H, Fe, and the $\alpha$-elements O, Mg, Si, or Ca). These metallicity-dependant relations result in [Ce/Fe] and [Ce/$\alpha$] ratios with age that are not universal clocks. Radial gradients of [Ce/H] and [Ce/Fe] ratios in open clusters, binned by age, were derived for the first time, with d[Ce/H]dR$_{GC}$ being negative, while d[Ce/Fe]/dR$_{GC}$ is positive. [Ce/H] and [Ce/Fe] gradients are approximately constant over time, with the [Ce/Fe] gradient becoming slightly steeper, changing by $\sim$+0.009 dex-kpc$^{-1}$-Gyr$^{-1}$. Both the [Ce/H] and [Ce/Fe] gradients are shifted to lower values of [Ce/H] and [Ce/Fe] for older open clusters. The chemical pattern of Ce in open clusters across the Galactic disk is discussed within the context of s-process yields from AGB stars, $\sim$Gyr time delays in Ce enrichment of the interstellar medium, and the strong dependence of Ce nucleosynthesis on the metallicity of its AGB stellar sources., Comment: 20 pages, 10 figures, Accepted to ApJ

Recent results from chemical tagging studies using APOGEE data suggest a strong link between the chemical abundance patterns of stars found within globular clusters, and chemically peculiar populations in the Galactic halo field. In this paper we analyse the chemical compositions of stars within the cluster body and tidal streams of Palomar 5, a globular cluster that is being tidally disrupted by interaction with the Galactic gravitational potential. We report the identification of nitrogen-rich (N-rich) stars both within and beyond the tidal radius of Palomar 5, with the latter being clearly aligned with the cluster tidal streams; this acts as confirmation that N-rich stars are lost to the Galactic halo from globular clusters, and provides support to the hypothesis that field N-rich stars identified by various groups have a globular cluster origin., Comment: 8 pages, 8 figures, accepted for publication in Monthly Notices of the Royal Astronomical Society

This paper documents the seventeenth data release (DR17) from the Sloan Digital Sky Surveys; the fifth and final release from the fourth phase (SDSS-IV). DR17 contains the complete release of the Mapping Nearby Galaxies at Apache Point Observatory (MaNGA) survey, which reached its goal of surveying over 10,000 nearby galaxies. The complete release of the MaNGA Stellar Library (MaStar) accompanies this data, providing observations of almost 30,000 stars through the MaNGA instrument during bright time. DR17 also contains the complete release of the Apache Point Observatory Galactic Evolution Experiment 2 (APOGEE-2) survey which publicly releases infra-red spectra of over 650,000 stars. The main sample from the Extended Baryon Oscillation Spectroscopic Survey (eBOSS), as well as the sub-survey Time Domain Spectroscopic Survey (TDSS) data were fully released in DR16. New single-fiber optical spectroscopy released in DR17 is from the SPectroscipic IDentification of ERosita Survey (SPIDERS) sub-survey and the eBOSS-RM program. Along with the primary data sets, DR17 includes 25 new or updated Value Added Catalogs (VACs). This paper concludes the release of SDSS-IV survey data. SDSS continues into its fifth phase with observations already underway for the Milky Way Mapper (MWM), Local Volume Mapper (LVM) and Black Hole Mapper (BHM) surveys., Comment: 40 pages, 8 figures, 6 tables. In press at ApJSS (arxiv v2 corrects some minor typos and updates references)

The chemical abundances of planet-hosting stars offer a glimpse into the composition of planet-forming environments. To further understand this connection, we make the first ever measurement of the correlation between planet occurrence and chemical abundances for ten different elements (C, Mg, Al, Si, S, K, Ca, Mn, Fe, and Ni). Leveraging data from the Apache Point Observatory Galactic Evolution Experiment (APOGEE) and Gaia to derive precise stellar parameters ($\sigma_{R_\star}\approx2.3\%$, $\sigma_{M_\star}\approx4.5\%$) for a sample of 1,018 Kepler Objects of Interest, we construct a sample of well-vetted Kepler planets with precisely measured radii ($\sigma_{R_p}\approx3.4\%$). After controlling for biases in the Kepler detection pipeline and the selection function of the APOGEE survey, we characterize the relationship between planet occurrence and chemical abundance as the number density of nuclei of each element in a star's photosphere raised to a power, $\beta$. $\beta$ varies by planet type, but is consistent within our uncertainties across all ten elements. For hot planets ($P$ = 1-10 days), an enhancement in any element of 0.1 dex corresponds to an increased occurrence of $\approx$20% for Super-Earths ($R_p=1-1.9R_\oplus$) and $\approx$60% for Sub-Neptunes ($R_p=1.9-4R_\oplus$). Trends are weaker for warm ($P$ = 10-100 days) planets of all sizes and for all elements, with the potential exception of Sub-Saturns ($R_p=4-8R_\oplus$). Finally, we conclude this work with a caution to interpreting trends between planet occurrence and stellar age due to degeneracies caused by Galactic chemical evolution and make predictions for planet occurrence rates in nearby open clusters to facilitate demographics studies of young planetary systems., Comment: Accepted to AJ; 25 Figures; 67 Pages

Aims. We describe the first s-process post-processing models for asymptotic giant branch (AGB) stars of masses 3, 4 and 5 M at solar metallicity (Z=0.018) computed using the input from the stellar evolutionary code aton. Methods. The models are computed with the new code snuppat(S-process NUcleosynthesis Post-Processing code for aton), including an advective scheme for the convective overshoot that leads to the formation of the main neutron source, 13C. Each model is post-processed with 3 different values of the free overshoot parameter. Included in the code snuppat is the novel Patankar-Euler-Deflhard explicit numerical solver, that we use to solve the nuclear network system of differential equations. Results. The results are compared to those from other s-process nucleosynthesis codes (Monash,fruity, and NuGrid), as well as observations of s-process enhancement in AGB stars, planetary nebulae, and barium stars. This comparison shows that the relatively high abundance of12C in the He-rich intershell in aton results in as-process abundance pattern that favours the second over the first s-process peak for all the masses explored. Also, our choice of an advective as opposed to diffusive numerical scheme for the convective overshoot results in significants-process nucleosynthesis also for the 5 M models, which may be in contradiction with observations., Comment: 19 pages, 11 figures, 2 appendices

The SDSS-IV Apache Point Observatory Galactic Evolution Experiment (APOGEE) survey has obtained high-resolution spectra for thousands of red giant stars distributed among the massive satellite galaxies of the Milky Way (MW): the Large and Small Magellanic Clouds (LMC/SMC), the Sagittarius Dwarf (Sgr), Fornax (Fnx), and the now fully disrupted \emph{Gaia} Sausage/Enceladus (GSE) system. We present and analyze the APOGEE chemical abundance patterns of each galaxy to draw robust conclusions about their star formation histories, by quantifying the relative abundance trends of multiple elements (C, N, O, Mg, Al, Si, Ca, Fe, Ni, and Ce), as well as by fitting chemical evolution models to the [$\alpha$/Fe]-[Fe/H] abundance plane for each galaxy. Results show that the chemical signatures of the starburst in the MCs observed by Nidever et al. in the $\alpha$-element abundances extend to C+N, Al, and Ni, with the major burst in the SMC occurring some 3-4 Gyr before the burst in the LMC. We find that Sgr and Fnx also exhibit chemical abundance patterns suggestive of secondary star formation epochs, but these events were weaker and earlier ($\sim$~5-7 Gyr ago) than those observed in the MCs. There is no chemical evidence of a second starburst in GSE, but this galaxy shows the strongest initial star formation as compared to the other four galaxies. All dwarf galaxies had greater relative contributions of AGB stars to their enrichment than the MW. Comparing and contrasting these chemical patterns highlight the importance of galaxy environment on its chemical evolution., Comment: 37 pages, 21 figures, accepted for publication in ApJ

We apply a novel statistical analysis to measurements of 16 elemental abundances in 34,410 Milky Way disk stars from the final data release (DR17) of APOGEE-2. Building on recent work, we fit median abundance ratio trends [X/Mg] vs. [Mg/H] with a 2-process model, which decomposes abundance patterns into a "prompt" component tracing core collapse supernovae and a "delayed" component tracing Type Ia supernovae. For each sample star, we fit the amplitudes of these two components, then compute the residuals \Delta[X/H] from this two-parameter fit. The rms residuals range from ~0.01-0.03 dex for the most precisely measured APOGEE abundances to ~0.1 dex for Na, V, and Ce. The correlations of residuals reveal a complex underlying structure, including a correlated element group comprised of Ca, Na, Al, K, Cr, and Ce and a separate group comprised of Ni, V, Mn, and Co. Selecting stars poorly fit by the 2-process model reveals a rich variety of physical outliers and sometimes subtle measurement errors. Residual abundances allow comparison of populations controlled for differences in metallicity and [\alpha/Fe]. Relative to the main disk (R=3-13 kpc, |Z|<2 kpc), we find nearly identical abundance patterns in the outer disk (R=15-17 kpc), 0.05-0.2 dex depressions of multiple elements in LMC and Gaia Sausage/Enceladus stars, and wild deviations (0.4-1 dex) of multiple elements in \omega Cen. Residual abundance analysis opens new opportunities for discovering chemically distinctive stars and stellar populations, for empirically constraining nucleosynthetic yields, and for testing chemical evolution models that include stochasticity in the production and redistribution of elements., Comment: Submitted to AAS journals. Long paper, many figures; see end of Section 1 for a reader's guide

In this work we prove the following result: Let $K$ be a strictly convex body in the Euclidean space $\mathbb{R}^n, n\geq 3$, and let $L$ be a hypersurface, which is the image of an embedding of the sphere $\mathbb{S}^{n-1}$, such that $K$ is contained in the interior of $L$. Suppose that, for every $x\in L$, there exists $y\in L$ such that the support double-cones of $K$ with apexes at $x$ and $y$, differ by a translation. Then $K$ and $L$ are centrally symmetric and concentric.

One of the most important problems in Geometric Tomography is to establish properties of a given convex body if we know some properties over its sections or its projections. There are many interesting and deep results that provide characterizations of the sphere and the ellipsoid in terms of the properties of its sections or projections. Another kind of characterizations of the ellipsoid is when we consider properties of the support cones. However, in almost all the known characterizations, we have only a convex body and the sections, projections, or support cones, are considered for this given body. In this article we proved some results that characterizes the Euclidean ball or the ellipsoid when the sections or projections are taken for a pair of nested convex bodies, i.e., two convex bodies $K$, $L$ such that $L\subset\text{int}\, K.$ We impose some relations between the corresponding sections or projections and some apparently new characterizations of the ball or the ellipsoid appear. We also deal with properties of support cones or point source shadow boundaries when the apexes are taken in the boundary of $K$.

LIN 358 and SMC N73 are two symbiotic binaries in the halo of the Small Magellanic Cloud, each composed of a hot white dwarf accreting from a cool giant companion. In this work, we characterize these systems using a combination of SED-fitting to the extant photometric data spanning a broad wavelength range (X-ray/ultraviolet to near-infrared), detailed analysis of the APOGEE spectra for the giant stars, and orbit fitting to high quality radial velocities from the APOGEE database. Using the calculated Roche lobe radius for the giant component and the mass ratio for each system, it is found that LIN 358 is likely undergoing mass transfer via wind Roche lobe overflow while the accretion mechanism for SMC N73 remains uncertain. This work presents the first orbital characterization for both of these systems (yielding periods of >270 and >980 days, respectively, for SMC N73 and LIN 358) and the first global SED fitting for SMC N73. In addition, variability was identified in APOGEE spectra of LIN 358 spanning 17 epochs over two years that may point to a time variable accretion rate as the product of an eccentric orbit., Comment: 19 pages, 12 figures

Context. Bulge globular clusters (BGCs) are exceptional tracers of the formation and chemodynamical evolution of this oldest Galactic component. However, until now, observational difficulties have prevented us from taking full advantage of these powerful Galactic archeological tools. Aims. CAPOS, the bulge Cluster APOgee Survey, addresses this key topic by observing a large number of BGCs, most of which have only been poorly studied previously. Even their most basic parameters, such as metallicity, [{\alpha}/Fe], and radial velocity, are generally very uncertain. We aim to obtain accurate mean values for these parameters, as well as abundances for a number of other elements, and explore multiple populations. In this first paper, we describe the CAPOS project and present initial results for seven BGCs. Methods. CAPOS uses the APOGEE-2S spectrograph observing in the H band to penetrate obscuring dust toward the bulge. For this initial paper, we use abundances derived from ASPCAP, the APOGEE pipeline. Results. We derive mean [Fe/H] values of $-$0.85$\pm$0.04 (Terzan 2), $-$1.40$\pm$0.05 (Terzan 4), $-$1.20$\pm$0.10 (HP 1), $-$1.40$\pm$0.07 (Terzan 9), $-$1.07$\pm$0.09 (Djorg 2), $-$1.06$\pm$0.06 (NGC 6540), and $-$1.11$\pm$0.04 (NGC 6642) from three to ten stars per cluster. We determine mean abundances for eleven other elements plus the mean [$\alpha$/Fe] and radial velocity. CAPOS clusters significantly increase the sample of well-studied Main Bulge globular clusters (GCs) and also extend them to lower metallicity. We reinforce the finding that Main Bulge and Main Disk GCs, formed in situ, have [Si/Fe] abundances slightly higher than their accreted counterparts at the same metallicity. We investigate multiple populations and find our clusters generally follow the light-element (anti)correlation trends of previous studies of GCs of similar metallicity. We finally explore the abundances ..., Comment: 27 pages, 10 figures, 5 tables. Abridged abstract. Accepted for publication in Astronomy & Astrophysics (A&A)

We study the multiple populations of $\omega$ Cen by using the abundances of Fe, C, N, O, Mg, Al, Si, K, Ca, and Ce from the high-resolution, high signal-to-noise (S/N$>$70) spectra of 982 red giant stars observed by the SDSS-IV/APOGEE-2 survey. We find that the shape of the Al-Mg and N-C anticorrelations changes as a function of metallicity, continuous for the metal-poor groups, but bimodal (or unimodal) at high metallicities. There are four Fe populations, similar to what has been found in previously published investigations, but we find seven populations based on Fe, Al, and Mg abundances. The evolution of Al in $\omega$ Cen is compared to its evolution in the Milky Way and in five representative globular clusters. We find that the distribution of Al in metal-rich stars of $\omega$ Cen closely follows what is observed in the Galaxy. Other $\alpha-$elements and C, N, O, and Ce are also compared to the Milky Way, and significantly elevated abundances are observed over what is found in the thick disk for almost all elements. However, we also find some stars with high metallicity and low [Al/Fe], suggesting that $\omega$ Cen could be the remnant core of a dwarf galaxy, but the existence of these peculiar stars needs an independent confirmation. We also confirm the increase in the sum of CNO as a function of metallicity previously reported in the literature and find that the [C/N] ratio appears to show opposite correlations between Al-poor and Al-rich stars as a function of metallicity., Comment: Accepted for publication in MNRAS, 17 pages, 16 figures, 3 tables

Given their location on the Hertzsprung-Russell (HR) diagram, thoroughly characterized subgiant stars can place stringent constraints on a wide range of astrophysical problems. Accordingly, they are prime asteroseismic targets for the Transiting Exoplanet Survey Satellite (TESS) mission. In this work, we infer stellar properties for a sample of 347 subgiants located in the TESS Continuous Viewing Zones (CVZs), which we select based on their likelihood of showing asteroseismic oscillations. We investigate how well they can be characterized using classical constraints (photometry, astrometry), and validate our results using spectroscopic values. We derive luminosities, effective temperatures, and radii with mean 1$\sigma$ random (systematic) uncertainties of 4.5% (2%), 33 K (60 K), and 2.2% (2%), as well as more model-dependent quantities such as surface gravities, masses, and ages. We use our sample to demonstrate that subgiants are ideal targets for mass and age determination based on HR diagram location alone, discuss the advantages of stellar parameters derived from a detailed characterization over widely available catalogs, show that the generally used 3D extinction maps tend to overestimate the extinction for nearby stars (distance $\lesssim$ 500 pc), and find a correlation that supports the rotation-activity connection in post main sequence stars. The complementary roles played by classical and asteroseismic data sets will open a window to unprecedented astrophysical studies using subgiant stars., Comment: Accepted for publication in ApJ. 25 pages, 14 figures, 2 tables. Machine-readable tables are available as ancillary files