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Despite the importance of alkaline seafloor hydrothermal vents in broadening our understanding of deep-sea hydrothermal ecosystems, little is known about the mobility and concentrations of micronutrient transition metals in these environments. Here, we present new analyses of micronutrient transition metal concentrations in vent fluids from the iconic Lost City Hydrothermal Field (LCHF) and report concentrations of Fe = 2.9–18.3 µmol/kg, Zn = 1.30–5.86 µmol/kg, Cu = 0.43–5.06 µmol/kg, Ni = 86.4–556 nmol/kg, Mn = 8.3–274 nmol/kg, V = 25.9–127 nmol/kg, Mo = 24–94 nmol/kg, Co = 8.0–135 nmol/kg, W = 4.8–16 nmol/kg, and Cd = 1.7–4.5 nmol/kg. We additionally present results of a hydrothermal lherzolite alteration experiment conducted at 300 °C, 500 bar. Transition metal concentrations and major chemical parameters of experimental reaction fluids are broadly similar to LCHF vent fluids, indicating that transition metal concentrations in LCHF vent fluids, and alkaline hydrothermal fluids more generally, reflect metal solubility controlled by underlying rock-buffered hydrothermal reactions. Concentrations of Ni and Mo are especially noteworthy because of their recognized importance for biological methanogenesis (Ni) and nitrogen fixation (Mo). When compared with known biological thresholds, our findings indicate that Ni concentrations in LCHF vent fluids are sufficient to support the robust methane-metabolizing microbial communities observed in the immediate vicinity of LCHF vents and suggest that Ni availability influences the spatial distribution of LCHF methanogens. Furthermore, our laboratory hydrothermal experiments demonstrate that Mo concentrations of similar magnitude to those observed in LCHF vent fluids (and also modern seawater) can be obtained by hydrothermal alteration of ultramafic rocks with Mo-free (Na, Ca) Cl aqueous solution. Thus, we conclude that alkaline hydrothermal fluids were likely similarly enriched in Mo prior to oxidation of the Earth's atmosphere and ocean, providing localized Mo-rich geochemical environments capable of supporting Mo-dependent nitrogen fixation at currently recognized threshold concentrations. [ABSTRACT FROM AUTHOR]

Largescale volcanic eruptions and earthquakes are occurring frequently in the Philippines, and research has shown that slab metamorphism and diversity alter the impacts of subducted oceanic plates by changing water‒carbon productivity and interplate stability. Within the framework of the thermal evolution history of subducting slabs, the relationships between subduction zone seismicity characterized by both regular megathrust earthquakes and slow slip events of various magnitudes and long-term slab dehydration–decarbonation evolution in the Philippines remain poorly understood. Here, we constructed a comprehensive thermal model incorporating 3-D slab geometric data for the incoming plate and a 3-D subduction velocity field based on the MORVEL plate motion dataset for the Philippine subduction zone with high spatial and temporal resolutions. Our findings reveal that subduction seismicity and arc volcanism are prominent in belt-shaped regions with high thermal gradients (> 5 °C/km) and large-scale slab dehydration (> 0.05 wt%/km). Dehydration of serpentinite in ultramafic rocks in the subducting slab and decarbonation of carbonate minerals preferentially contribute to the generation and transport of fluids and carbonate melts, thus facilitating seismicity and carbon-rich magmatism. Our results suggest that slab geometry diversity-induced juxtaposed slab dehydration-decarbonation processes play a vital role in the generation of megathrust earthquakes below the forearc. [ABSTRACT FROM AUTHOR]

The global transition to a low-carbon energy future has ignited interest in hydrogen as a clean and versatile energy carrier. NW Saudi Arabia contains vast tracts of mantle-dominated Neoproterozoic ophiolites overlain by a sedimentary cover in the north, NE and east. Our research explores the untapped potential of Saudi Arabia's ophiolite serpentinites as a possible source of hydrogen generation through serpentinization and related processes. H 2 is commonly derived from serpentinization, which primarily involves the hydration of minerals rich in iron and magnesium (e.g., olivine), resulting in the formation of serpentine and H 2. Serpentinites are formed by reaction between fluids and mantle rocks, and hydrogen and methane are released in extreme reducing conditions. Under strongly reducing conditions, the formation of magnetite generates hydrogen during serpentinization, following reactions such as: 3Fe 2 SiO 4 + 2H 2 O = 2Fe 3 O 4 +3SiO 2 +2H 2. (1) We have conducted a comprehensive assessment of serpentinites in the Arabian Shield, employing the Geographic Information System (GIS) to locate Arabian ophiolites with the largest ultramafic segments. Ophiolites studied include Jabal Ess, Jabal Wask, Bi'r Tululah, and Jabal Tharwah. After ophiolite identification, we delineated fractures and measured fracture density to provide insight into the potential of serpentinite fractures on the amount of possible hydrogen seepage, or natural accumulation in case of an overlying seal. Our goal is to do spatial analysis that can be a guide to the most favorable environment for geologic H 2 exploration; as such, this does not however, provide an estimate of the total H 2 storage capacity. A complimentary H 2 anomaly survey however, will ground-truth the results of this study. • The Arabian Nubian Shield is comprised of numerous serpentinite-dominated ophiolites. • The possibility of natural hydrogen accumulations within these ophiolite massifs are indicated by the permeable zones of fracture density maps. • The shield is overlain by a sedimentary cover in the east which may act as an effective seal. [ABSTRACT FROM AUTHOR]

Olivine, typically occurring as a forsterite-fayalite solid solution, is a major rock-forming mineral in mafic and ultramafic igneous rocks, and it is important for understanding the genesis, evolution, and alteration of its host rocks. In this study, both GGA and GGA + U methods were employed to calculate the reduced partition function ratios of Fe, Mg, O, and Si isotopes for the forsterite-fayalite solid solution, aiming to elucidate the impacts of Fe content and Hubbard U correction on the isotope fractionation signatures of Fe, Mg, O, and Si in olivine. On the whole, the β Fe -factor, β Mg -factor, β O -factor, and β Si -factor decrease with increasing Fe content. The linear correlations between β -factors and bond lengths obtained from GGA + U are better compared to those from GGA. The Hubbard U correction can increase the β Fe -factor. When Fe/(Fe + Mg) ≤ 1/8, ≤ 1/2, and ≤ 1/2, the effect of Hubbard U correction on β Mg -factor, β O -factor, and β Si -factor can be considered negligible, respectively, suggesting that the β Mg -factor, β O -factor, and β Si -factor of Fe-bearing olivine calculated using GGA + U and those of Fe-free minerals calculated using GGA can be combined to derive 103ln α and trace geological processes. Furthermore, equilibrium fractionation of Fe, Mg, O, and Si isotopes between olivine and other minerals, including troilite, clinopyroxene, and garnet, were also calculated. Our results are helpful in interpreting the observed data regarding Fe, Mg, O, and Si isotopic compositions of olivine, leading to a comprehensive understanding of relevant geological processes. [ABSTRACT FROM AUTHOR]

Complex gold-iridium-osmium placer deposits associated with the Guli massif of ultramafic, alkaline rocks and carbonatites are located within the Maimecha-Kotui province in the northern part of the Siberian Platform. Unlike natural Os-Ir alloys, which are genetically related to ultramafic rocks, the bedrock source of gold remains controversial. We report, for the first time, morphological and compositional features of gold mineralization from calcite-dolomite carbonatite of the Guli massif. Gold minerals are represented by natural Au-Ag alloys containing gold (69.64–88.57 wt %) and silver (11.73–30.83 wt %) with low concentrations of copper (up to 0.18 wt %), which predominate over minerals of the system Au–Cu–Ag (e.g., natural alloys Au0.74Cu0.14Ag0.12 and Ag0.51Au0.47Cu0.02, tetra-auricupride (AuCu) and auricupride (Cu3Au)). Gold minerals are characterized by an early pentlandite-troilite-chalcopyrite association that form polyphase euhedral inclusions. Later galena (PbS) occurring in the form of subhedral monophase inclusions is replaced by cerussite (PbCO3). The revealed similarity of gold minerals and mineral assemblages in gold from calcite-dolomite carbonatite with those of gold minerals from placer deposits of the Guli massif indicates that derivatives of ijolite-carbonatite magmatism played a significant role in gold ore formation. [ABSTRACT FROM AUTHOR]

ABSTRACT Ultramafic rocks of the Archean greenstone belts worldwide are potential hosts for Cu‐Ni, precious metal deposits like platinum group elements (PGEs) and gold. This study highlights the geochemical evidence and genesis of Ni‐PGE mineralisation in the ultramafic rocks of Shimoga greenstone belt of the Western Dharwar Craton, India. Petrographically, the studied rocks are identified to be serpentinised dunites, while their geochemical signatures indicate komatiitic affinity. Presence of disseminated sulphides and pronounced serpentinisation in these rocks suggest a combination of Type II (disseminated sulphides) and Type IV (post‐magmatic alterations) komatiite‐related Ni–Cu‐PGE deposits. Chondritic Al2O3/TiO2 (9.65–16.38) ratios, superchondritic Gd/YbN (1.3–1.6), depleted high‐field‐strength elements (HFSEs) (Zr, Hf), enrichment of LREE over HREE and negative Nb–Ta anomalies reflect the generation of parental melts from plume‐sourced Al‐depleted komatiites with significant crustal contamination during their emplacement. The major, trace element and PGE relationships (FeO vs. MgO, Cu vs. Pd, Ni/Cu vs. Pd/Ir) infer the origin of sulphur undersaturated primary melts through moderate to higher degrees of partial melting followed by crustal assimilation that led to PGE enrichment. These observations suggest their formation from melts derived from greater depths of the upper mantle (> 400 km) at high pressure (> 10 GPa), wherein, the mantle residue retained majorite garnet. The high Ni (avg. Ni = 6511 ppm) substantiated by high Kambalda ratio ([Ni:Cr] × [Cu:Zn] = 5.6), Ni/Cr ratios (> 1) with high concentration of PGEs (avg. ∑PGE = 3078 ppb) confirm the fertile/mineralised nature of the komatiitic source and potential Ni‐PGE mineralization in the ultramafic rocks of the Shimoga greenstone belt. [ABSTRACT FROM AUTHOR]

The present work studies the rodingite that is recorded for the first time as being associated to Al-Barramiya Neoproterozoic ophiolite at Eastern Desert of Egypt, Arabian-Nubian Shield (ANS). Al-Barramiya ophiolite is one of the most important ophiolitic sequences exposed in the ANS. It is affected by different styles of alterations included carbonatization, listvenitization, chloritization and rodingitization. The Neoproterozoic ophiolitic rocks of Al-Barramiya district consists of serpentinized peridotite and metagabbros. Serpentinized peridotites are highly altered to assemblages of talc-carbonate rocks, listvenite and magnesite, while metagabbro is partly converted into rodingite. The field studies indicate that serpentinite and rodingite in Al-Barramiya area display high-strain cataclastic deformation. Rodingite consists of garnet, diopside, vesuvianite and chlorite with minor epidote, prehnite, actinolite and opaque minerals. The garnets and vesuvianite are mostly concentrated near the peripheries of the studied rodingite masses, while clinopyroxene, chlorite, epidote and prehnite gradually increase inwards due to progressive decreasing water/rock ratio as fluids originally buffered by serpentinite move towards equilibrium with gabbroic bulk chemistry. Some rodingite samples preserve a few relics of igneous textures of ophiolitic metagabbros. Garnets are distinguished into andradite, hydroandradite and grossular. Pyroxene is represented mainly by secondary clinopyroxene beside primary fresh relics of diopside; the latter has high Mg# (0.92–0.97) similar to ophiolitic clinopyroxene in the ANS. Rodingite is enriched in CaO, Fe2O3 and MgO but depleted in SiO2, Al2O3 and Na2O compared to associated metagabbro. The association of rodingite with serpentinites and metagabbros suggests that Al-Barramiya rodingite is genetically related to serpentinization of ultramafic rocks. The rodingitization occurred during ocean floor alteration contemporaneous with the serpentinization process. The superposition of cataclastic deformation on the altered rocks indicates that alteration preceded obduction and occurred on the seafloor of the suprasubduction zone where Al-Barramiya ophiolite was originally emplaced. During serpentinization the olivine in the peridotite broke down and released Mg2+ in the metasomatic fluids and clinopyroxene broke down producing Ca-rich fluids. These fluids react with the mafic protoliths and enrich them in MgO and CaO. Also, serpentinization fluids react with the plagioclase of the metagabbro, releasing Ca from the mafic source and concentrated it in the rodingitized samples. The positive Eu anomalies beside high Sr contents of the rodingite can be inherited from a plagioclase-rich protolith such as ophiolitic metagabbro. The enrichment of rodingite in Th and U indicates two distinct solutions affected the gabbroic protolith because the alteration of depleted peridotite to serpentinite cannot be an efficient source to enrich these elements. The present study indicates that the rodingitization process underwent lower greenschist facies conditions associating metamorphism that caused serpentinization and released Ca-rich metasomatic fluids. [ABSTRACT FROM AUTHOR]

Magnesite is an economically important mineral commonly found in ultramafic complexes worldwide, primarily in Archean to Proterozoic ultramafic complexes. This study focuses on the chemical and spectral characterization of magnesite found in the Neoarchean ultramafic rocks in the Attappadi region in the Southern Granulite Terrane of southern India. The research utilizes x‐ray diffraction analysis, hyperspectral, laser Raman, Fourier Transform Infrared, and Isotope Ratio Mass Spectrometry. The studied ultramafic rocks are part of a well‐exposed ophiolitic suite known as the Agali ophiolitic complex. Magnesite primarily occurs as veins, veinlets, and lenses within weathered ultramafic rocks. The hyperspectral analysis of the magnesite samples shows absorption bands in the shortwave infrared region, particularly around 2.3 and 2.5 μm, which correspond to the stretching and bending of the CO bond in the (CO3)2− ion in MgCO3. The laser Raman spectra show intensity peaks at 1095, 738, and 330 cm−1, which may be attributed to the translational and librational vibrations. The Fourier transform infrared data reveal transmittance at 1434, 880, and 747 cm−1, corresponding to MgO bond stretching and asymmetrical CO stretching. The x‐ray powder diffraction spectra exhibit diffraction peaks at 32°, 35°, 42°, 46° and 53°, characteristic of pure magnesite. The spectroscopic parameters derived from various analyses indicate that the magnesite is high quality and free from gangue minerals. Stable isotope analysis of the magnesite samples yielded δ13C values ranging from −5‰ to −9‰ and δ18O values in the range of 21‰–25‰. The estimated water temperature from which the magnesite has been precipitated is ~59 ± 3.9°C. Based on the field relations, mode of occurrence and isotopic signatures, the mineralization is considered to have been formed by the low‐temperature alteration of ultramafic rocks facilitated by CO2‐rich fluids in the near‐surface environment. This study compares the characteristics of magnesite from the study area with a few Neoproterozoic serpentinite‐hosted magnesite veins in the ophiolitic sequence of the Egyptian Eastern Desert, which is part of the Arabian Nubian shield. The research aims to contribute to understanding magnesite formation in Archaean to Proterozoic mafic–ultramafic rocks on the Earth's crust. It also provides insights into the geological processes that govern the genesis of ultramafic‐hosted magnesite globally, particularly in East Gondwana fragments. This information can enhance mineral exploration and resource evaluation in these regions, helping to identify economic prospects and assess the feasibility of magnesite resource extraction and utilization in East Gondwana fragments. [ABSTRACT FROM AUTHOR]

Chromite is formed in nature in ophiolitic layers and ultrabasic rocks through fractional crystallization. The corresponding mining technologies separate the ore from these ultrabasic rocks, which are considered to be tailings for the process but may be valorized in other applications. The need to utilize this material is due to the large quantities of its production and the special management required to avoid possible secondary pollution. In the present work, the ultrabasic rocks of chromite mining were applied to acid mine drainage (AMD) neutralization. The aim was to increase the technological maturity of the method and promote circular economy principles and sustainability in the mining sector. Ultrabasic rocks were obtained from a chromite mining facility as reference material. Furthermore, an artificial AMD solution was synthesized and applied, aiming to simulate field conditions. According to the results, the sample was successfully utilized in AMD neutralization (pH 7), achieving rapid rates in the first 30 min and maximum efficiency (liquid to solid ratio equal to 8.3) at 24 h. However, the method presented a drawback since Mg was leached, even though the concentration of other typical metals contained in an AMD solution decreased. [ABSTRACT FROM AUTHOR]

The Neoproterozoic Bou Azzer Ophiolite, located in the Pan-African orogen of the Anti-Atlas, Morocco, exposes a well-preserved mantle section of the ophiolitic sequence. Although ultramafic rocks are the most common rock types in the sequence, they have received less attention in previous studies. In this work, we investigate the petrogenesis of these ultramafic rocks in detail, including their petrology, mineralogy, and whole rock geochemistry. The mineral assemblages are mainly formed by antigorite with minor lizardite, chlorite, and accessory Cr-spinel. The only preserved primary mantle mineral is Cr-spinel, which shows unaltered cores with Cr# between 0.61 and 0.71 and alteration rims to ferrian chromite and magnetite. Whole rock analyses indicate almost total serpentinization and, locally, strong carbonation (mass loss of ignition between 11.94 and 22.20 wt%). The non-carbonated samples preserve protolith signatures, with decreased MgO/SiO2 suggesting metasomatic processes related to serpentinization. Immobile trace elements compare well with fore-arc peridotites, while melting modelling indicates intense and polyphasic melting events. We propose polyphase melting in a subduction-initiation setting, with a first stage of 14–23% anhydrous melting, forming fore-arc basalts, and a second stage of 15–25% melting with 1 wt% H2O, forming boninites. The Bou Azzer ultramafic rocks represent the fore-arc region of a supra-subduction zone, challenging previous interpretations that suggested a back-arc position. [ABSTRACT FROM AUTHOR]

The main goal of this paper is to determine the order of the paragenetic sequence and phase transitions of the Ni–Fe sulfide association hosted in listvenites. Listvenites are hydrothermally altered mafic and ultramafic rocks that are often associated with active tectonic settings, such as transform faults, suture zones, and regional extensional faults, usually in contact with volcanic or carbonate rocks. Listvenitization is displayed by a carbonation process when the original olivine, pyroxene, and serpentine group minerals are altered to Mg–Fe–Ca carbonates (magnesite, calcite, dolomite, and siderite), talc, quartz, and accessory Cr spinel, fuchsite, and Ni–Fe sulfides. The formed rocks are highly reactive; therefore, very often, younger hydrothermal processes are observed, overprinting the mineralogy and geochemistry of the original listvenitization products, including accessory Ni–Fe sulfide paragenesis. The studied samples of listvenites were collected from two locations in Kosovo (Vardar Zone): Janjevo and Melenica. The Ni–Fe sulfide textures and relationships with the surrounding listvenite-hosted minerals were obtained using reflected and transmitted light microscopy, while their chemical composition was determined using an electron microprobe. They form accessory mono-or polymetallic aggregates that usually do not exceed 100 μm in size disseminated in the studied listvenites. Generally, the paragenetic sequence of Ni–Fe sulfides is divided into three stages. The first pre-listvenite magmatic phase is represented by pentlandite and millerite. The second listvenite stage consists of Ni–Co bearing pyrite I (Ni content up to 11.57 wt.% [0.24 apfu], and Co content up to 6.54 wt.% [0.14 apfu]) and differentiated thiospinels (violarite + siegenite ± polydymite). The last, late listvenite stage is represented by younger gersdorffite−ullmannite and base metal mineralization: pyrite + marcasite + sphalerite + galena ± chalcopyrite ± sulfosalts. The findings obtained should help in the interpretation of many disseminated accessory Ni–Fe–Co mineralizations associated with mafic and ultramafic rocks worldwide. [ABSTRACT FROM AUTHOR]

The age of formation of the explosion pipes of the Chapinskii complex in the Chingasan magmatic belt in the northern part of the Yenisei Ridge is determined. U–Pb dating of zircon megacrysts from alkaline ultramafic rocks has established the values of 657.7 ± 13.4 and 647.6 ± 9.7 Ma for the Natalyinskaya pipe and Pipe no. 3, respectively. The intrusion of alkaline ultramafic explosion pipes of the Chapinskii complex corresponds to the time of manifestation of alkaline ultramafic magmatism along the southern and southwestern margin of the Siberian Craton. [ABSTRACT FROM AUTHOR]

Gold-platinum mineralization was discovered in ultramafic–mafic rocks of the Ariadne massif of the Sikhote-Alin orogenic belt. In this article, we show that ultramafic (peridotite and pyroxenite) and mafic (ilmenite and hornblende gabbro) rocks form a single series with gradual accumulation of rare and rare earth elements of more differentiated varieties. New age determinations for zircon from ilmenite gabbro are given (164 ± 0.48 Ma). We distinguished four varieties of gold differing in the Au, Ag, Cu, and Hg contents. Platinum-bearing minerals are isoferroplatinum and cuprite. The isotopic composition of sulfides from ultramafic rocks suggests a mantle source, while sulfides from ilmenite gabbros are characterized by isotopically light sulfur, indicating the possible involvement of crustal rocks in ore genesis. Carbon isotope analysis of the carbon-bearing matter of mafic–ultramafic rocks showed the presence of mantle fluids and isotopically light biogenic matter from sedimentary rocks. The data indicate the influence of mantle and crustal processes on the formation of ore-bearing mafic and ultramafic intrusions. [ABSTRACT FROM AUTHOR]

The early Martian atmosphere had 0.25 to 4 bar of CO2 but thinned rapidly around 3.5 billion years ago. The fate of that carbon remains poorly constrained. The hydrothermal alteration of ultramafic rocks, rich in Fe(II) and Mg, forms both abiotic methane, serpentine, and high-surface-area smectite clays. Given the abundance of ultramafic rocks and smectite in the Martian upper crust and the growing evidence of organic carbon in Martian sedimentary rocks, we quantify the effects of ultramafic alteration on the carbon cycle of early Mars. We calculate the capacity of Noachian-age clays to store organic carbon. Up to 1.7 bar of CO2 can plausibly be adsorbed on clay surfaces. Coupling abiotic methanogenesis with best estimates of Mars' d13C history predicts a reservoir of 0.6 to 1.3 bar of CO2 equivalent. Such a reservoir could be used as an energy source for long-term missions. Our results further illustrate the control of water-rock reactions on the atmospheric evolution of planets. [ABSTRACT FROM AUTHOR]

Abiotic synthesis of CH 4 in seafloor hydrothermal fluids is generally assumed to occur via heterogeneous reactions on mineral surfaces. Stepwise homogeneous reduction of CO 2 has, however, been suggested as an alternative (but sluggish) abiotic pathway to CH 4 , potentially via metastable species of intermediate oxidation states. In this study, we examine the effect of two temperature-dependent methylated species − methanol (CH 3 OH) and methanethiol (CH 3 SH), on homogeneous CH 4 formation rates under long-term simulated hydrothermal conditions. Aqueous solutions containing formic acid (H13COOH, generating 13CO 2 and H 2) were heated with and without H 2 S at 300–325 °C (35 MPa) in a flexible Au reaction cell over several years without added minerals. Substantial 13C-labeled CH 4 and CH 3 OH production from 13CO 2 was observed over 4.3 yr, with aqueous CH 4 formation varying with CH 3 OH abundance – a strong function of dissolved H 2 abundance and, inversely, temperature. CH 4 production was slower at 325 °C with lower CH 3 OH concentrations (in equilibrium with CO 2 and H 2), and faster at 300 °C, accompanying an equilibrium-controlled increase in CH 3 OH. Fastest CH 4 production occurred at 300 °C following injection of H 2 S and H13COOH, which led to rapid formation (<4 days) of 13C-labeled CH 3 SH that subsequently decomposed over a further 0.8 yr, partly to 13CH 4. Heating aqueous 13CH 4 to 345–387 °C (33–35 MPa) in the presence of an oxidizing hematite-magnetite-pyrite assemblage, however, yielded no detectable CH 3 SH after 112 days indicating the reverse reaction is inhibited under favorable thermodynamics. Neither direct reduction of CO 2 to CH 3 SH nor CO 2 -CH 3 SH equilibrium were evident at 300 °C, implying CH 3 SH and CH 3 OH play disparate roles in homogeneous carbon reduction to CH 4. Longer chain hydrocarbons (C 2+ alkanes) remained low throughout the experiments. CH 3 SH abundances previously reported in vent fluids at the Von Damm hydrothermal field correlate strongly with demonstrably abiotic HCOOH there, suggesting the reduction of HCOOH to CH 3 SH observed in this study may also occur in vent fluids. A comparison of mineral-free 13CH 4 production rates reported here with 13CO 2 reduction experiments involving minerals indicates that homogeneous reduction proceeds at similar rates to purported transition metal-catalyzed 13CH 4 production, and is generally faster than experiments with either added olivine or ultramafic rock. Previous claims of substantial mineral-catalyzed abiogenic CH 4 production are therefore not supported by our study. Homogeneous CO 2 reduction may be a significant source of methylated compounds and CH 4 in hydrothermal fluids characterized by decadal (or longer) residence times, such as those found in mineral-hosted inclusions or occluded fractures in igneous basement, requiring only moderate temperatures and abundant H 2 to proceed. [ABSTRACT FROM AUTHOR]

A simple method was developed for the determination of REEs, Zr, Hf, Th and U in ultramafic rocks by inductively coupled plasma‐mass spectrometry with a combination of RE and UTEVA extraction resins for their separation and pre‐concentration. Ultramafic rocks were digested with HNO3‐HF‐HClO4 and finally turned into 11 mol l−1 HCl solutions together with H3BO3 to remove insoluble fluorides. The removal of matrix elements was achieved during the loading procedure. Following this, REEs on RE resin, and Zr, Hf, Th and U on UTEVA resin were eluted with 10 ml of 0.24 mol l−1 HCl, with recoveries better than 94.4%. This method was validated using reference materials JP‐1, DTS‐2B, OKUM, UB‐N, MUH‐1 and DZΣ‐2, and the measurement results for target analytes were comparable to literature values, indicating its applicability to the determination of REEs, Zr, Hf, Th and U at ultra‐trace level in ultramafic rocks. [ABSTRACT FROM AUTHOR]

Gold, along with other highly siderophile elements, is hosted by Fe-Ni sulfide phases within peridotites and mantle melts. In this context, the lithospheric mantle emerges as a principal reservoir, providing materials crucial for the inception, augmentation, conveyance, and genesis of auriferous CO2-rich mantle fluids. EPMA and laser ablation ICP-MS data, integrated with petrographic and SEM studies, were used to assess the transfer of base and precious metals into the Earth's crust, discerning between inputs from subduction-related processes and post-formation metasomatism. The study focuses on sulfide minerals in serpentinized peridotites of the Abu Dahr ophiolite in the Eastern Desert of Egypt. Originating in a supra-subduction setting during the Neoproterozoic era, the Abu Dahr peridotites underwent serpentinization and contain discrete sulfide minerals, including pentlandite, nickeloan pyrrhotite, millerite, chalcopyrite, and violarite. The uneven distribution of calcite ± magnesite ± serpentine veins throughout the host ophiolitic rocks reflects the intricate interplay of serpentinization and carbonation, as fO2 and fCO2 conditions fluctuated. Geochemical data of the host rocks reveal a progressive geochemical evolution marked by concurrent silicification and carbonate alteration, driven by the interaction of ultramafic rocks with hydrothermal fluids, ultimately leading to the extensive silicification and formation of birbirite. The ICP-MS data show that pentlandite contains up to 6.11 ppm of Au, pyrrhotite up to 0.41 ppm, millerite 0.34 ppm, and violarite 0.12 ppm. The gold concentration in pentlandite is significantly higher than in pyrrhotite, millerite, and violarite, which exhibit lower but detectable levels of Au. Desulfurization reactions of sulfide minerals during progressive serpentinization triggered the release and redistribution of Au as well as base metals and highly siderophile elements. Published thermodynamic modeling at temperatures below 300 °C and pressures of 50 MPa closely replicates the mineral assemblage observed in the Abu Dahr ophiolites, including sulfide assemblages and variations in major elements such as Mg and Fe. This suggests that the serpentinization process, along with associated hydrothermal fluids, played a crucial role in the mobilization and redistribution of gold, particularly affecting its incorporation into secondary sulfides. The mobilization of Au and other highly siderophile elements during serpentinization occurred in an environment marked by strong oxidation, as indicated by the presence of acicular antigorite, magnetite, millerite, and goethite intergrowths. [ABSTRACT FROM AUTHOR]

The ultramafic rock located on the northern slope of Lüliang Mountain in the northwestern region of North Qaidam Orogen is altered to serpentinite. The occurrence of disseminated chromite within the serpentinite holds significant implications for understanding the petrogenesis of the protolith. This work provides strong evidence of a distinct zonal texture in the chromite found in the ultramafic rock, using petrographic microstructure and electron probe composition analysis. The core of the chromite is characterized by high contents of Cr#, with enrichment in Fe3+# (Fe3+/(Cr + Al + Fe3+)) and depletion in Al2O3 and TiO2. The Cr2O3 content ranges from 51.64% to 53.72%, while the Cr# values range from 0.80 to 0.84. The FeO content varies from 24.9% to 27.8%, while the Fe2O3 content ranges from 5.19% to 8.74%. The Al2O3 content ranges from 6.70% to 9.20%, and the TiO2 content is below the detection limit (<0.1%). Furthermore, the rocks exhibit Mg# values ranging from 0.13 to 0.25 and Fe3+# values ranging from 0.07 to 0.12. The mineral chemistry of the chromite core in the ultramafic rock suggests it to be from an ophiolite. This ophiolite originated from the fore-arc deficit asthenosphere in a supra-subduction zone. The estimated average crystallization temperature and pressure of the chromite are 1306.02 °C and 3.41 GPa, respectively. These values suggest that the chromite formed at a depth of approximately 110 km, which is comparable to that of the asthenosphere. The chromite grains are surrounded by thick rims composed of Cr-rich magnetite characterized by enrichment in Fe3+# contents and depletions in Cr2O3, Al2O3, TiO2, and Cr#. The FeO content ranges from 28.25% to 31.15%, while the Fe2O3 content ranges from 44.94% to 68.92%. The Cr2O3 content ranges from 0.18% to 23.59%, and the Al2O3 and TiO2 contents are below the detection limit (<0.1%). Moreover, the rim of the Cr-rich magnetite exhibits Cr# values ranging from 0.90 to 1.00, Mg# values ranging from 0.01 to 0.06, and Fe3+# values ranging from 0.64 to 1.00, indicating late-stage alteration processes. The LA-ICP-MS zircon U-Pb dating of the ultramafic rock yielded an age of 480.6 ± 2.4 Ma (MSWD = 0.46, n = 18), representing the crystallization age of the ultramafic rock. This evidence suggests that the host rock of chromite is an ultramafic cumulate, which is part of the ophiolite suite. It originated from the fore-arc deficit asthenosphere in a supra-subduction zone during the northward subduction of the North Qaidam Ocean in the Ordovician period. Furthermore, clear evidence of Fe-hydrothermal alteration during the post-uplift-denudation stage is observed. [ABSTRACT FROM AUTHOR]

There is a growing trend towards utilizing nickel as a raw material for non-steel products due to the increasing demand for nickel up to 2040. Data shows that global nickel production and reserves will increase until 2021. As one of the countries with the largest reserves in the world, this country contributes significantly to global nickel production. This paper will discuss Indonesia's nickel resources, reserves and production related to the distribution of locations, number of resources, number of reserves, grade, sustainability of reserves and their impact on the economy as well as efforts to maintain this sustainability. Previous articles only presented data on Indonesia's nickel reserves and production and an overview of global nickel. The data on nickel resources and reserves come from the 2021 inventory by the Geological Agency, which covers ore resources and reserves and their grades across several classifications. If there is no new data on reserve deposits or planned production rates, it is estimated that the ore reserves with nickel grades ≥ 1.7% will be depleted by 2036, while the ore reserves with Ni grades < 1.7% will be exhausted by 2056. Efforts to increase reserves include increasing exploration activities in brownfield areas, exploring remaining ultrabasic regions, and conducting detailed geological mapping of areas where ultrabasic rock is expected. Apart from raising the issue of the magnitude of nickel potential and mining value, this paper also discusses economic indicators in each nickel producing community using Gross Regional Domestic Product per capita. Based on the results of this analysis, it shows that there are differences in GDP per capita and the value of the mines owned by each region as a nickel producer. [ABSTRACT FROM AUTHOR]

Peridotites are a group within the category of ultramafic rocks. These are usually dark‐coloured rocks rich in magnesium, poor in silica and lacking feldspars. Earth's mantle, which makes up 83 percent by volume and 67 percent by weight of the planet, consists largely of peridotite, which, although relatively sparse at the surface, therefore, is Earth's most abundant rock type. Unfortunately, the mantle, which lies on average at >7 km under the oceans and >35 km under the continents, is not directly accessible for observation and our information comes largely from seismic studies, inclusions in volcanic rocks and sections of the ocean floor which have been tectonically emplaced into the crust: the ophiolite complexes and abyssal peridotites of the oceans. Such rocks also occur when mafic minerals, such as olivine, pyroxene and spinel, accumulate in magma chambers. An unusual occurrence of ultramafic rocks is the lava called komatiite, representing ultramafic liquids, which are largely restricted to Precambrian environments. [ABSTRACT FROM AUTHOR]

The morphology of the seafloor of the Madagascar Basin from Mauritius Island to the Southwest Indian Ridge (SWIR) is represented by a ridge-echeloned relief of the spreading basement. The azimuth of the relief differs by ~90° for the basin north of the SWIR and its wedge-shaped sublatitudinal rift system, separated by an abyssal escarpment. A genetic definition of this seafloor relief shape is given. This shape is formed when the ancient basement breaks up and accretion of the crust orthogonal to the azimuth, which existed before the rupture, begins. The formation of a wedge in the eastern part of the SWIR began about 41 Ma ago and is manifested by higher (±1100 m) amplitudes of relief variations than at the basement before the rupture (±250 m). The change in morphology is also associated with the change in the spreading azimuth of the lithospheric block by about 24° north of the SWIR, which opened up a new space for accretion. The morphology of the relief in the wedge and beyond shows the relationship of its parameters with slowdown in the spreading rate by almost three times when the kinematics of the plates have changed. The high-amplitude ridge-echeloned relief in the ultraslow segment of the SWIR with signs of nontransform displacement is combined with the maxima and minima of Bouguer anomalies. According to the published data, serpentized peridotites and basalts are obtained in the localization of the anomalies. These rocks indicate the presence of detachments with the exposure of ultramafic rocks and minimal magmatic output. Bouguer anomalies along the regional profile perfectly reflect deep density inhomogeneties. For intraplate volcanic edifices, they have a much greater deconsolidation in the upper mantle than near the active interplate boundary of the SWIR. According to the seismic tomography data, the absence of a deep upwelling under the newly formed SWIR segment and the presence of a "cold" gap in the "hot" lenses of the mantle indicates the action of tangential forces in the lithosphere that are not associated with general mantle convection. The formation of the new orthogonal rift system with ultraslow rates is an adaptation to variations in the kinematics parameters of the adjacent lithospheric plates. [ABSTRACT FROM AUTHOR]

The dismembered ophiolites in the Wadi Al-Barramiya area, Central Eastern Desert of Egypt, are one of a series of Neoproterozoic ophiolites present in the Arabian-Nubian Shield. Here we present new fieldwork, whole-rock geochemical data, and mineral chemistry of metapyroxenite and metagabbro associated with the Al-Barramiya ophiolite in order to constrain its nature and tectonic setting; in particular whether the ophiolite was formed in a subduction or non-subduction setting. The rocks selected were obtained from the mantle section (serpentinized peridotite), an ultramafic (pyroxenite) and the crustal section (metagabbro). The serpentinized peridotite is altered to talc carbonate and listvenite, and associated with magnesite. Pyroxenite occurs as irregular coarse-grained lenses of websterite and olivine websterite within the serpentinite and occurs adjacent to the ophiolitic metagabbro. The metagabbros form scattered allochthonous masses of various sizes that are distributed across the area. The ophiolitic rocks are metamorphosed from greenschist to lower amphibolite facies. Locally, fresh relicts of olivine and Cr-spinel can be found in the serpentinite, whereas pyroxenite has fresh relicts of olivine, clinopyroxene and Cr-spinel. Cr-spinel in the metapyroxenite is zoned, with Al2O3, Cr2O3 and MgO decreasing and FeOt increasing from cores to rims, reflecting the effects of metamorphism that selectively removed the now-depleted components. The metagabbros are characterized by enrichment in large-ion lithophile elements (LILE) over high field strength elements (HFSE) and are tholeiitic with a calc-alkaline affinity. The high Cr# (0.63–0.75) of fresh Cr-spinel relicts in the metapyroxenite, together with their low TiO2 contents (0.04–0.24 wt%), indicate that this rock is similar to highly refractory ultramafic rocks that evolved in a fore-arc setting. This is supported by the high forsterite content (Fo = 0.91–0.93) of fresh olivine and high Mg# (0.93–0.95) of fresh clinopyroxene. Clinopyroxenes in the metapyroxenite and metagabbro have the chemical characteristics of boninite, confirming the fore-arc setting. [ABSTRACT FROM AUTHOR]

Jumun Island is tectonostratigraphically situated on the marginal zone of the Gyeonggi Massif. The Massif is in contact with the southwestern margin of the Imjingang Belt and adjacent to Boreum Island, where ultramafic rock with magmatic Fe-Ti oxide deposits occurs. The northwest of Jumun Island, facing the Boreum ultramafic rock with Fe-Ti oxide ores, is composed of Precambrian Boreumdo schists containing a few magmatic intrusives, the exact ages of which are unknown. In Jumun, the ultramafic intrusion (Mg# = 75), which is confined to a narrow zone along the seaside, mainly consists of olivine (Fo = 81–82), amphibole (magnesio-horn-blende to tremolite), and phlogopite. The olivine is strongly serpentinized and encompassed by amphibole and phlogopite. The Ni-Cu sulfide mineralization found in the ultramafic rock is weak but has a typical assemblage of pyrrhotite-pentlandite-chalcopyrite with a small amount of magnetite. Notably, the Ni-Cu sulfides are closely associated with amphibole and phlogopite and are found in the fractures and interstitials of the olivine grains. The pyrrhotite (n = 2) and chalcopyrite (n = 1) are compositionally close to pure samples, whereas the pentlandite (n = 2) is characterized by enrichment with Co (up to 6.9 wt%). The sphalerite-bearing quartz vein cuts across the Precambrian gneissic rock and strikes N70 °W with an 80 °NE dip. This vein, which is traceable to a limited extent and approximately 40 cm wide, shows mineralogical zonation in the inward direction from pyrite to sphalerite-dominant. Consisting of sphalerite, pyrite, quartz, and chlorite with minor amounts of chalcopyrite, pyrrhotite, and pentlandite, it is composed of 9.56 wt% Zn with < 1.0 wt% As, Co, Cu, In, Mn, Ni, and Pb and below-detection limits (0.001 ppm) amounts of Bi, Ge, Mo, Se, Sb, Te, and W. Sphalerite, a principal ore mineral, is coarse-grained and reddish-brown and is composed of 57.3–58.8 wt% ZnS, 8.0–9.2 wt% FeS, and 32.0–32.4 wt% S with small amounts of Cu, Mn, As, and Cd. The recently discovered Ni-Cu sulfide mineralization and quartz vein with sphalerite, along with the linear array of magmatic Fe-Ti oxide deposits, provide conclusive evidence that the marginal zone of the Gyeonggi Massif may be a geologically favorable area for the formation of magmatic and magmatic-hydrothermal deposits. For exploration purposes, it is necessary to contextualize the source, tectonic setting, and magmatic evolution. [ABSTRACT FROM AUTHOR]

Subducting oceanic plates carry large amounts of carbon into the Earth's interior. The subducted carbon is mobilized by fluid and encounters ultramafic rocks in the mantle wedge, resulting in changes to the mineral assemblage and mechanical properties of the mantle. Here, we use thermodynamic modeling of interactions between carbon-bearing multi-component fluids and mantle rocks to investigate the down-dip variation in mineral assemblage in the forearc mantle along subduction megathrusts. We found that fluids rich in aqueous carbon are preferentially generated in a warm subduction zone (e.g., Nankai, SW Japan), causing a change in mineral assemblage from serpentine-rich at the mantle wedge corner to talc + carbonate-rich at greater depths. The transition caused by the infiltration of aqueous carbon may influence the depth of the boundary between the seismogenic and aseismic zones, and the down-dip limit of episodic tremor and slip. Infiltration of carbon-rich fluids promotes the formation of carbonate minerals and weak minerals in the forearc mantle and influences the down-dip limit of seismic zones, according to thermodynamic calculations between fluid and mantle rocks. [ABSTRACT FROM AUTHOR]

Serpentinization is an important geochemical process producing natural hydrogen (H 2), and mafic and ultramafic serpentinized rocks, typically occurring in ophiolites and peridotite massifs, are major targets for H 2 exploration. Understanding the volumes of H 2 stored in these rocks is a key step towards establishing the potential of sepentinized systems to host H 2 sources and reservoirs. Nonetheless, published data on the concentration of H 2 directly extracted from serpentinized rocks are extremely scarce. This work provides a first dataset of H 2 extracted by planetary ball mill from 58 rock samples from different ophiolites in Greece, peridotites of the Tekirova ophiolite in Turkey, and chromitites and surrounding talc schist from an Archean-Paleoproterozoic greenstone belt in Brazil. The highest H 2 concentrations, from 0.1 mL/kg (considered as a threshold above which artificial H 2 by milling is negligible) to 16.2 mL/kg, were found in serpentinized harzburgites or dunites, and in chromitites hosted within serpentinized peridotites. The H 2 content of other mafic rocks that are not in contact or influenced by a serpentinized system, mostly basalts, is below 0.1 mL/kg. Serpentinized peridotites represent the logical source rocks of H 2 (i.e., hydrogen in peridotites is generally autochtonous) and chromitites, lacking significant olivine and serpentinized minerals, may host H 2 derived by the surrounding serpentinized rocks (hydrogen in chromitites is mostly allochtonous). The H 2 dataset of this work can be used as a reference for further studies on the capacity of ophiolitic rocks to produce and host natural hydrogen. • First dataset on H 2 concentration in mL/kg in different ophiolitic rocks. • Serpentinized harzburgites/dunites and chromitites host the highest H 2 concentrations. • Hypothesis of autochtonous hydrogen in peridotites, allochtonous hydrogen in chromitites. [ABSTRACT FROM AUTHOR]

The results of detailed mineralogical and geochemical studies of precious metals from ultrabasic rocks of the Ariadnoe massif (Sikhote-Alin orogenic belt) are presented. The presence of several varieties of gold with different ratios of Ag, Cu, and Hg has been revealed. Isoferroplatinum predominates among platinum minerals. The isotopic composition of ultrabasite sulfides corresponds to the mantle source, while basites are characterized by isotope–light sulfur, indicating the possibility of participation in the oreogenesis of crustal rocks. Isotope-carbon analysis of igneous rocks indicates that they contain derivatives of deep fluids and isotope-light biogenic matter of sedimentary rocks. The presented data show that mantle and crustal processes were involved in the formation of ore-bearing intrusions of ultrabasic–basic rocks. The association of ilmenite, gold, and platinum in ultrabasites and basites, a derivative of these processes, can serve as a search criterion for the detection of industrially promising sources of strategic metals. [ABSTRACT FROM AUTHOR]

Isotopic signatures of heavy noble gases in the Earth's mantle contain a major component recycled by subduction. The experimental and field studies reported in the literature show increasing evidence that serpentine minerals can hold large quantities of noble gases, potentially serving as their primary vectors to depth. However, at present, their retention mechanism in these minerals is not fully understood. Additionally, noble gas solubilities from field and experimental studies show large differences in terms of elemental concentrations. Here, we performed crystal chemical modeling to evaluate the incorporation mechanism of noble gases and their solubilities in serpentine minerals along subduction zone geotherms. To this end, we determined the thermal equation of state of xenon using in situ X-ray diffraction and absorption up to 60 GPa and 728 K. In this range, the xenon equation of state is well-adjusted using the Mie-Grüneisen-Debye formalism with relevant fitting parameters. We show that the experimentally observed solubility trend, which follows the order Ne < He < Ar < Kr < Xe, can be explained by the incorporation of noble gases at two distinct crystallographic sites. The light noble gases He and Ne are most likely retained at the van der Waals hydrogen-oxygen bond position between the layers, while the heavy and larger noble gases enter the voids between the six-membered SiO 4 rings. It should be noted that octahedral sites can potentially host xenon, but cannot accommodate argon and krypton. Indeed, this would require unrealistic flexibility of the crystal lattice. Our models extended to mantle wedge conditions predict decreasing solubilities, particularly for light noble gases, in agreement with observations from natural samples. Compared to the noble gas concentrations determined experimentally in serpentine, natural concentrations are much higher and very variable. Our solubility model confirms that equilibrium processes cannot explain these observations. We therefore suggest that the high and variable noble gas concentrations found in natural samples must be due to hybrid hydration processes in ultramafic rocks that involve different degrees of water activities. [ABSTRACT FROM AUTHOR]

The Parecis Basin, one of Brazil's most extensive intracratonic basins, holds significant potential for hydrocarbon exploration. Despite its vast size, Parecis has yet to be extensively explored, with only five wildcat wells drilled. So far, no commercial discoveries have been announced. Regional studies have suggested Paleozoic sedimentation, while recent analyses have revealed a Neoproterozoic infill. Its tectonic model is still a matter of debate, and to date, no detailed structural map for the whole basin has been published. The present work proposes a new detailed structural map of the Parecis Basin based on a four-step interpretation workflow integrating seismic and gravimetric data. The first step includes converting the public 2D seismic lines to the depth domain. The second step is estimating the residual Bouguer anomaly, where the computed residual anomalies should relate to the basin's tectonic features. The third step comprises the 2D forward modeling of the gravimetric anomalies using the 2D seismic interpretation as a constraint. The final step compiled all the interpreted features into our new structural map. This map reveals the top of the basement, forming a complex framework of horsts and grabens. Normal faults define the main structural style in the basin. Further, we could recognize thick, high-density bodies embedded in the crystalline basement. These bodies consist of Orosian–Calimian (1.8–1.6 Ga) mafic and ultramafic rocks, which may be a potential source for hydrogen exploration in the basin. Subsequent geophysical and geochemical surveys will assess the hydrogen potential in the area. [ABSTRACT FROM AUTHOR]

An enrichment in nickel (Ni) or platinum group elements (PGE) is seldom observed in ores of the iron oxide–copper–gold (IOCG) type. This phenomenon is, however, known from a few deposits and prospects in the Carajás Mineral Province, Brazil. The Ni-PGE enrichment is explained, in part, by the spatial association of the IOCG-type ores with altered mafic-ultramafic lithologies, as well as by reworking and remobilization of pre-existing Ni and PGE during multiple mineralization and tectonothermal events across the Archean-Proterozoic. One such example of this mineralization is the Jatobá deposit in the southern copper belt of the Carajás Domain. This is the first detailed study of the Ni and PGE mineralization at Jatobá, with implications for understanding ore genesis. Petrographic and compositional study of sulfides shows that pyrite is the main Ni carrier, followed by pyrrhotite and exsolved pentlandite. Measurable concentrations of palladium (Pd) and platinum (Pt), albeit never more than a few ppm, are noted in pyrite. More importantly, however, the trace mineral signature of the Jatobá deposit features several platinum group minerals (PGM), including merenskyite, naldrettite, sudburyite, kotulskite, sperrylite, and borovskite. These PGM occur as sub-10 µm-sized grains that are largely restricted to fractures and grain boundaries in pyrite. All Pd minerals reported contain mobile elements such as Te, Bi, and Sb and are associated with rare earth- and U-minerals. This conspicuous mineralogy, differences in sulfide chemistry between the magnetite-hosted ore and stringer mineralization without magnetite, and microstructural control point to a genetic model for the sulfide mineralization at Jatobá and its relative enrichment in Ni and PGE. Observations support two alternative scenarios for ore genesis. In the first, an initial precipitation of disseminated or semi-massive Ni-PGE-bearing sulfides took place within the mafic rock pile, possibly in a VHMS-like setting. Later partial dissolution and remobilization of this pre-existing mineralization by mineralizing fluids of IOCG-type, possibly during the retrograde stage of a syn-deformational metamorphic event, led to their re-concentration within magnetite along structural conduits. The superposition of IOCG-style mineralization onto a pre-existing assemblage resulted in the observed replacement and overprinting in which PGE combined with components of the IOCG fluids like Sb, Bi, and Te. An alternative model involves leaching, by the IOCG-type fluids, of Ni and PGE from komatiites within the sequence or from ultramafic rocks in the basement. The discovery of PGM in Jatobá emphasizes the potential for additional discoveries of Ni-PGE-enriched ores elsewhere in the Carajás Domain and in analogous settings elsewhere. [ABSTRACT FROM AUTHOR]

The De'erni Cu–Zn-Co deposit is a typical altered ultramafic-hosted volcanogenic massive sulfide deposit comprising four lenticular main orebodies (0.57 Mt Cu, 1.27% Cu average ore grade; 0.03 Mt Co, 0.09% Co average ore grade; 0.16 Mt Zn, 1.04% Zn average ore grade) hosted in serpentinite and a 200-m-thick basalt was found below the No. I orebody. Serpentinite spinel Al2O3, TiO2, Cr#, and Mg# indicate a mantle-source. Serpentinite magmatic-hydrothermal genesis is indicated by the following: (i) high Rb/Y and Th/Zr ratios, low Nb/Zr ratios, and low δ65Cu values; (ii) altered magnetite rims on spinel being characterized by high Cr, Ni, and Ti, and low Ga contents; (iii) pyrite appears along the boundary of spinel grains and has a higher Co and Ni content than pyrite in ores. Therefore, the ultramafic host rocks are formed by strong fluid alteration of primary mantle rocks. The compositional zoning of Co, Cu, and Zn in euhedral coarse-grained pyrite from massive sulfide ore suggests that metal enrichment was associated with three fluid phases, with a clear temporal interval between the fluid activity that introduced Co/Cu enrichment and Zn enrichment (Zn-rich veins in magnetite cross-cut early spinel). Serpentinite exhibits a higher Zn content and decoupling of Ni and Co contents compared to Dur'ngoi ophiolite serpentinite distal from the orebody, implying primary ultramafic rocks may have provided Co to the ores. The apparently high Cu content of the Dur'ngoi ophiolite basalt in comparison with ophiolite basalts worldwide indicates basalt may have supplied the Cu. [ABSTRACT FROM AUTHOR]

The flora of New Caledonia is renowned as one of the world's most significant biodiversity hotpots. The contrasting soil conditions that characterize this small archipelago profoundly influence species local diversity and distribution. Because the difference between soil chemistry is likely to cause variation in leaf elemental composition, we wanted to test how different soil properties affect plant community and leaf elemental concentration. We focused on two adjacent forests, of similar physiognomy, growing on serpentinite (ultramafic rock), and on volcano‐sedimentary rock. Both soils strongly differed in their pH, cation exchange capacity, and element concentration (Al, Mn, and Ni). The two adjacent forests have a diverse endemic flora and share a relatively high proportion of species (35%–42%). The tree composition differs more than the total vascular flora. Leaf element concentrations of 30 tree species that grow on both soil types, as well as the corresponding soil–plant‐available nutrients, were analyzed. Leaf element concentrations indicated N, P, K, and Ca deficiency. Despite higher plant‐available Mn concentration in ultramafic soil than volcano‐sedimentary soil, leaf Mn concentrations were significantly higher for plants growing on volcano‐sedimentary soil. Leaf Ni concentrations were higher on ultramafic soil and Al concentration was higher on volcano‐sedimentary soil. Major differences in leaf elemental concentration were for micronutrients (metals) while macronutrients varied in much lower proportion between the two soil types, suggesting a tight regulation of macronutrients compared to micronutrients. [ABSTRACT FROM AUTHOR]

The Tepsi ultrabasic body is located in the northeastern Fennoscandian Shield close to the junction of the Serpentinite Belt–Tulppio Belt (SB–TB) with suites of the Lapland–Belomorian Belt (LBB) of Paleoproterozoic age. The body is a deformed laccolith that has tectonic contacts with Archean rocks. Its primary textures and magmatic parageneses are widely preserved. Fine-grained olivine varies continuously from Fo90.5 to Fo65.4. The whole-rock variations in MgO, Fe2O3, SiO2, and other geochemical data are also indicative of a significant extent of differentiation. Compositional variations were examined in the grains of calcic and Mg-Fe amphiboles, clinochlore, micas, plagioclase, members of the chromite–magnetite series, ilmenite, apatite, pentlandite, and a number of other minor mineral species. Low-sulfide disseminated Ni-Cu-Co mineralization occurred sporadically, with the presence of species enriched in As or Bi, submicrometric grains rich in Pt and Ir, or diffuse zones in pentlandite enriched in (Pd + Bi). We recognize two series: the pentlandite series (up to 2.5–3 wt.% Co) and the cobaltpentlandite series (~1 to ~8 apfu Co). The latter accompanied serpentinization. The two series display differences in their substitutions: Ni ↔ Fe and Co → (Ni + Fe), respectively. Relative enrichments in H2O, Cl, and F, observed in grains of apatite (plus high contents of Cl in hibbingite or parahibbingite), point to the abundance of volatiles accumulated during differentiation. We provide the first documentation of scheelite grains in ultrabasic rocks, found in evolved olivine-rich rocks (Fo77–72). We also describe unusual occurrences of hypermagnesian clinopyroxene associated with tremolite and serpentine. Abundant clusters of crystallites of diopside display a microspinifex texture. They likely predated serpentinization and formed owning to rapid crystallization in a differentiated portion of a supercooled oxidized melt or, less likely, fluid, after bulk crystallization of the olivine. We infer that the laccolithic Tepsi body crystallized rapidly, in a shallow setting, and could thus not form megacycles in a layered series or produce a well-organized structure. Our findings point to the existence of elevated PGE-Au-Ag potential in numerous ultrabasic–basic complexes of the SB–TB–LBB megastructure. [ABSTRACT FROM AUTHOR]

The 10th International Conference on Serpentine Ecology was held in Nancy, France on 12–16 June, 2023. As a major international scientific forum in the field of serpentine (ultramafic) ecology, this conference brings together botanists, zoologists, microbiologists, physiologists, geneticists, geologists, soil scientists, and other applied specialists studying the ecology of ultramafic rocks and soil. A notable aspect of these meetings is the multidisciplinary nature of research on ultramafic biota, including diversity, ecology, evolution, physiology, and applied research in phytotechnologies and conservation. The main goals of the conference were to create a platform for the exchange of ideas and experiences and to promote scientific dialogue among scientists from numerous fields who share expertise in the study of ultramafic habitats worldwide. In this Special Issue we present the major topics and provide some highlights of the contributions to the 10th International Conference on Serpentine Ecology. [ABSTRACT FROM AUTHOR]

Although checklists are essential tools for managing and conserving ultramafic ecosystems, no updated checklist currently exists for ultramafic ecosystems on the southern Iberian Peninsula. Thus, the objectives of our study were (1) to create an updated checklist of serpentinophytes on southern Iberian Peninsula, (2) to determine whether the distribution of serpentinophytes is associated with certain specific types of ultramafic rocks, and (3) to calculate the abundance and richness of serpentinophytes per outcrop to guide conservation efforts. Following a methodology involving field work and searches of bibliographies and herbaria we produced an updated checklist containing 28 serpentinophytes (i.e., 23 obligates, one preferential taxon, one sub‐serpentinophyte, and three regional serpentinophytes). The serpentinophytes showed different petrological affinity, where harzburgite–lherzolite and harzburgite–pyroxenite–dunite exhibited higher occupancy, possibly due to their mineralogical and chemical composition (e.g., containing heavy metals) and/or the larger surface area of those outcrops. We also observed that the occupancy of 21 species was higher in different petrographic entities, the reasons for which could be elucidated by future soil analyses. The highest richness of serpentinophytes was found in the main outcrop of Bermeja, followed by smaller outcrops of Alpujata, Aguas, and Guadalhorce Valley. Although the richness of Aguas resembled that of Alpujata, a notable difference emerged in some of its areas owing to bioclimatic and biogeographic isolation. Given the exclusive presence of serpentinophyte flora on the southern Iberian Peninsula, all southern Iberian outcrops should receive some form of conservation as protected natural spaces. [ABSTRACT FROM AUTHOR]

Ailanthus altissima is one of the major invasive trees at a global scale. Despite numerous reports about its invasiveness in different habitats, so far it was not observed on harsh ultramafic soils and to colonize the vegetation of these outcrops. In this paper we show that the species can also spread in these habitats in the Mediterranean region and is able to cope with the severe anomalies of ultramafic soils. We sampled A. altissima in four ultramafic outcrops of central Italy and in control sites to unravel the behavior of this species toward the typically high soil concentrations of trace metals, such as Ni, Cr and Co, as well the imbalance of the Ca:Mg quotient. A similar sampling was performed for the native Fraxinus ornus that occurs naturally on a broad range of soils, including those from ultramafic rocks. Trace metal concentrations in leaves of both species were below toxicity thresholds, but A. altissima showed lower translocation and bioaccumulation factors (TF and BF, respectively) for Ni. Compared with F. ornus, the invasive species displayed higher leaf concentrations of Mg, thus suggesting a higher tolerance of potentially toxic levels of this element. Moreover, the higher TF and BF values for Ca in both control and serpentine populations suggested that A. altissima was more able to extract and accumulate this macronutrient in leaves in respect to F. ornus. Given the inherent deficiency of this element in ultramafic soils, efficient use of Ca could be a key trait contributing to the invasiveness of A. altissima on these soils. [ABSTRACT FROM AUTHOR]

Shergottites are mafic to ultramafic igneous rocks that represent the majority of known Martian meteorites. They are subdivided into gabbroic, poikilitic, basaltic, and olivine–phyric categories based on differences in mineralogy and textures. Their geologic contexts are unknown, so analyses of crystal sizes and preferred orientations have commonly been used to infer where shergottites solidified. Such environments range from subsurface cumulates to shallow intrusives to extrusive lava flows, which all have contrasting implications for interactions with crustal material, cooling histories, and potential in situ exposure at the surface. In this study, we present a novel three‐dimensional (3‐D) approach to better understand the solidification environments of these samples and improve our knowledge of shergottites' geologic contexts. Shape preferred orientations of most phases and crystal size distributions of late‐forming minerals were measured in 3‐D using X‐ray computed tomography (CT) on eight shergottites representing the gabbroic, poikilitic, basaltic, and olivine–phyric categories. Our analyses show that highly anisotropic, rod‐like pyroxene crystals are strongly foliated in the gabbroic samples but have a weaker foliation and a mild lineation in the basaltic sample, indicating a directional flow component in the latter. Star volume distribution analyses revealed that most phases (maskelynite, pyroxene, olivine, and oxides/sulfides) preserve a foliated texture with variable strengths, and that the phases within individual samples are strongly to moderately aligned with respect to one another. In combination with relative cooling rates during the final stages of crystallization determined from interstitial oxide/sulfide crystal size distribution analyses, these results indicate that the olivine–phyric samples were emplaced as shallow intrusives (e.g., dikes/sills) and that the gabbroic, poikilitic, and basaltic samples were emplaced in deeper subsurface environments. [ABSTRACT FROM AUTHOR]

The Shasatpich area hosts an ophiolitic complex located in the south of Kerman, southeast Iran. This ophiolitic complex is composed of lherzolite, harzburgite, and dunite. Olivine is one of the important minerals found in these rocks, which is observed along with pyroxene (orthopyroxene and clinopyroxene) and spinel. The combined range of olivines is forsterite to chrysolite, range of 84 to 92%. NiO with an average amount of about 0.38 wt% and MnO with an average of 0.14 wt% in olivines show the range has related to abyssal peridotites. In addition to serpentinization as a general alteration in the ultramafic rocks, petrographic studies show that evidence of metamorphism in the olivines of some harzburgites along with recrystallized antigorite crystals, which indicate a phase of thermal metamorphism in this harzburgite. These results have been confirmed in mineral chemistry studies too. Metamorphic olivines have an abnormality compared to magmatic olivines with a decrease in CaO. In chemical mineralogical studies, the amounts of forsterite and olivines show a regular increase from lherzolite to harzburgite and dunite. Raman spectroscopy studies on the studied olivines show the relationship between the peak shift of 854 waves/cm and forsterite values ​​of olivine minerals in the study area. [ABSTRACT FROM AUTHOR]

Meso-Neoarchean fuchsite quartzites are present in different stratigraphic positions of Dharwar Craton including the oldest (~ 3.3 Ga) Sargur Group of western Dharwar Craton. The present study deals with the petrographic and geochemical characteristics of the fuchsite quartzites from the Ghattihosahalli belt to evaluate their genesis, depositional setting and the enigma involved in the ancient sedimentation history. Their major mineral assemblages include quartz, fuchsite, and feldspars along with accessory kyanite and rutile. The geochemical compositions are characterized by high SiO2, Al2O3, low MgO, CaO, strongly enriched Cr (1326–6899 ppm), Ba (1165–3653 ppm), Sr (46–210 ppm), V (107–868 ppm) and Zn (11–158 ppm) contents compared to the upper continental crust (UCC). The UCC normalized rare earth element (REE) patterns are characterized by depleted light REE [(La/Sm)UCC = 0.33–0.95] compared to heavy REE [(Gd/Yb)UCC = 0.42– 1.65)] with conspicuous positive Eu-anomalies (Eu/Eu* = 1.35–18.27) characteristic of hydrothermal solutions evidenced through the interlayered barites. The overall major and trace element systematics reflect a combined mafic-felsic provenance and suggest their deposition at a passive continental margin environment. The comprehensive field, petrographic, and geochemical studies indicate that these quartzites are infiltrated by Cr-rich fluids released during high-grade metamorphism of associated ultramafic rocks. The Sargur and the subsequent Dharwar orogeny amalgamated diverse lithounits from different tectonic settings, possibly leading to the release of Cr-rich fluids and the formation of fuchsite quartzite during or after the orogeny. These findings suggest a pre-existing stable crust prior to the Sargur Group and the link between orogenic events and various mineral deposits in the Dharwar Craton. [ABSTRACT FROM AUTHOR]

New data favor the view previously substantiated by geological, geochemical and isotopic data that the orebodies of the Belogorskoe deposit are the Triassic erosion products of the laterite weathering crust after gabbroids, which were metamorphosed and partially regenerated in the Late Cretaceous–Paleogene. The source for the formation of the Belogorskoe deposit was shown to be the products of exogenic destruction of rocks, the isotopic and geochemical characteristics of which are close to those of Cambrian gabbroids of the Vladimiro-Aleksandrovsky massif (southern part of the Okrainsko-Sergeevsky terrane). It has been found that the Belogorskoe deposit consists of rocks and ores, the primary (magmatic) REE distribution in which was variably modified as a result of interaction between sediments (protoliths) and seawater (presumably during the Late Jurassic–Early Cretaceous accretion), as well as between their metamorphosed analogues and hydrothermal solutions (in the Late Cretaceous–Paleogene). The influence of gabbroids (as a source of material) on the chemical and mineral composition of the Belogorskoe deposit agrees with the data reported in a paper on the enrichment of orebodies in such elements as Fe and Mn characteristic of ultramafic rocks and the presence of Au–Ag–Pd–Pt, Ni–Co, and Bi mineralization in them. The orebodies of the Belogorskoe deposit contain accessory minerals and mineral varieties that are rare in nature and poorly studied. They include an unusually Th-rich variety of zircon, baddeleyite, gudmundite, a large group of bismuth compounds, including Bi2Te, (Ag,Pb)BiS2, as well as coloradoite, lafossaite, sanbornite, perovskite, and the compound InPO4. There is also a large group of rare and unusual noble metal compounds: copper gold, platinum gold, jonassonite, disordered solid solutions of Cu, Ag and Au (Au-based), Pt–Pd, Pt–Ag intermetallides, and other rare minerals and mineral varieties. [ABSTRACT FROM AUTHOR]

Ultramafic rocks are promising candidates for carbon sequestration by enhanced carbon dioxide (CO2) mineralization strategies due to their highly CO2-reactive mineral composition and their abundant availability. This study reports the mineralogy and microtextures of a representative ultramafic rock from the Ma-Hin Creek in northern Thailand and provides evidence of CO2 mineralization occurring through the interaction between CO2 and the rock in the presence of water under ambient conditions. After sample collection, rock description was determined by optical petrographic analysis. The rock petrography revealed a cumulated wehrlite comprising over 50% olivine and minor amounts of clinopyroxene, plagioclase, and chromian spinel. Approximately 25% of the wehrlite had altered to serpentine and chlorite. A series of CO2 batch experiments were conducted on six different rock sizes at a temperature of 40 °C and pressure of 1 atm over five consecutive days. The post-experimental products were dried, weighed, and geochemically analyzed to detect changes in mineral species. Experimental results showed that product weight and the presence of calcite increased with reducing grain size. Additionally, the modal mineralogy of the wehrlite theoretically suggests potential CO2 uptake of up to 53%, which is higher than the average uptake values of mafic rocks. These findings support the rock investigation approach used and the preliminary assessment of carbon mineralization potential, contributing to enhanced rock weathering techniques for CO2 removal that could be adopted by mining and rock supplier industries. [ABSTRACT FROM AUTHOR]

Ophiolite-derived clastic rocks of the Rassokha terrane in the Chersky Range of the Verkhoyansk−Kolyma folded area were studied to obtain representative characteristics of the eroded source metamorphosed ultramafic and mafic rocks, to gain an insight into the possible geodynamic setting in which the protoliths of these rocks were formed, and to identify the possible source of the eroded material. The composition of lithoclasts and detrital minerals of the serpentinite and listwanite sandstones suggests that their source was composed of serpentinite, chloritite, listwanite, and dolomite rocks and that this source was proximal. Prior to the source erosion, the ultramafic and mafic rocks were metamorphosed and recrystallized, listwanite was formed, and the ultramafic rocks were tectonically disintegrated and combined with units of carbonate rocks (dolomite). Ultramafic rocks from lithoclasts experienced allochemical metamorphic retrogression during at least the latest stage of their serpentinization in a nonoceanic setting, where also the listwanite was formed. The Late Neoproterozoic ophiolites of the collisional belt of the Chersky Range were the most probable source for the protoliths of the clastic material. The protoliths of the ophiolite rock were probably formed in a backarc setting. Considered together with the published ages, our data indicate that relics of suprasubduction oceanic lithosphere of the Neoproterozoic basin occurred in the Chersky Range. [ABSTRACT FROM AUTHOR]

During an expedition in 2016, a rich fauna of freshwater gastropods of the family Tateidae Thiele, 1925 was discovered on the ultramafic terrains of the Southeast of New Caledonia (NC). Hitherto, only three of the 62 known NC family members were reported from this type of bedrock. With less than 1.5 mm in length, many of the new species are particularly small. In order to establish a methodological setup for the description and phylogenetic analyses of these new species, we here describe Viriiella touaouroua gen. et sp. nov. and assess its relationships based on three gene fragments. Viriiella is morphologically well defined and resembles Fluviopupa Pilsbry, 1911 not present in NC. In the phylogenetic analyses, though, Viriiella appeared as a member of the Hemistomia-clade, the NC tateids occurring on non-ultramafic terrain. However, Viriiella had the longest branch and, sister group to different genera in maximum likelihood and Bayesian analyses, its position was unstable, probably an artifact due to long-branch attraction. Considering that Viriiella does not share the defining character states of Hemistomia s. lat., it may well be possible that inclusion of more related genera will show that the new taxa share a most recent common ancestor with the Hemistomia-clade, but as sister group.

Today, carbon dioxide removal from the atmosphere is the most ambitious challenge to mitigate climate changes. Basalt rocks are abundant on the Earth's surface (? 10%) and very abundant in the ocean floors and subaerial environments. Glassy matrix and minerals constituting these rocks contain metals (Ca2+, Mg2+, Fe2+) that can react with carbonic acid to form metal carbonates (CaCO3, MgO3 and FeCO3). Here, we present a data compilation of the chemical composition of waters circulating in basalt aquifers worldwide and the results of simple basalt-water-CO2 experiments. Induced or naturally occurring weathering of basalts rocks release elements in waters and elemental concentration is closely dependent on water CO2 concentration (and hence on water pH). We also performed two series of experiments where basaltic rock powder interacts with CO2-charged waters for one month at room temperature. Laboratory experiments evidenced that in the first stages of water-rock interaction, the high content of CO2 dissolved in water accelerates the basalt weathering process, releasing in the water not only elements that can form carbonate minerals but also other elements, which depending on their concentration can be essential or toxic for life. Relative mobility of elements such as Fe and Al, together with rare earth elements, increases at low pH conditions, while it decreases notably at neutral pH conditions. The comparison between experimental findings and natural evidence allowed to better understand the geochemical processes in basaltic aquifers hosted in active and inactive volcanic systems and to discuss these findings in light of the potential environmental impact of CO2 storage in mafic and ultramafic rocks. [ABSTRACT FROM AUTHOR]

Composition and age of unserpentinized harzburgites found as boudins and relict bodies in the Voikar–Synya massif in the olivine–antigorite fields have been studied. Rock and mineral structure and composition, as well as REE distribution and Sm–Nd absolute dating (≈2330 Ma) make it possible to consider these unserpentinized harzburgites as mantle fragments and the earliest ultramafic rocks of the Voikar–Synya massif. Silicates of these harzburgites are characterized by higher chromium which turns into chrome spinellide in different subsequent processes. Based on the data obtained, the resources of chromium mobilized during the transformation of primary ultramafic rocks have been evaluated. [ABSTRACT FROM AUTHOR]

This study presents the first comprehensive investigation of perovskite from its type locality (Mineral Mines of Southern Urals, Russia), where this mineral was first described by Gustav Rose in 1839. The new data includes results from precise chemical analyses (electron-probe microanalyzer, LA-ICP-MS) and U-Pb ages (SHRIMP-II) of perovskite. Perovskite occurs in silicate-carbonate veins that transect the marginal parts of the Middle Riphaean Kusinsko-Kopanskaya layered intrusion, previously thought to be skarns. The perovskite crystals range from micrometer-scale grains to up to 11 cm in size. Chemical investigations revealed a low content of trace elements (rare earth elements, Y, Nd, U, Th) compared to perovskites from alkaline ultramafic rocks, silica-undersaturated basic rocks, carbonatites, and kimberlites. The determined age of the perovskite, 535 ± 43 Ma, significantly differs from the 1379 ± 8 Ma age of the Kusinsko-Kopanskaya intrusion, challenging the skarn-origin hypothesis for perovskite. Instead, the findings suggest a carbonatite origin for the perovskite mineralization. This timing indicates a previously unknown stage of endogenic activity on the Western Slope of the Southern Urals. [ABSTRACT FROM AUTHOR]

Several gold deposits in the eastern region of Cuba are genetically related to the island arc- and the ophiolitic complex formation. These have been studied and exploited since the time of the Spanish colonization in the mid-sixteenth century. These deposits belong to the Aguas Claras-Guajabales mineral field in the Holguín Province (Cuba) and lie in an elongated zone approximately 15 km in length. The object of this work is to make a methodical, detailed, and chronological review of the geological and mining work carried out in this region, as well as highlight the degree of the previously achieved studies. To realize this, an extensive bibliographic review of all available data, including published reports and articles, as well as unpublished material, was carried out. Moreover, ore mineralogy and petrography were reviewed by thin section analyses from samples from these deposits by petrographic and scanning electron microscopy. The results obtained from this study highlight that the gold mineralization in that area is closely linked to metasomatic processes produced by the circulation of hydrothermal fluids that affected the different volcanic and ultramafic rocks. This study shows that the highest gold contents observed are controlled by the contacts between the different host lithologies with high rheological contrasts. The presence of different alteration styles such as serpentinization, listvenitization, rodingitization, and propylitization have played a primary role in the deposition of gold during mineralization processes. This work could be a very useful exploration guide for future research in this region, as it provides a useful and practical compilation of the characteristics of the mineralization and alteration styles, as well as a precise indication of the spatial position, thicknesses, and contents of the gold-rich horizons. [ABSTRACT FROM AUTHOR]

Nickel isotopes have been employed to trace various processes such as the weathering of mafic and ultramafic rocks, mineral adsorption and co-precipitation, and the metabolism of methanogenic archaea. Nickel isotopes have displayed significant potential for application, regardless of whether the processes occur at high or low temperatures. However, the currently employed nickel isotope separation methods have certain limitations in terms of separation effectiveness, blank contribution, separation efficiency, and cost-effectiveness of the resin used. Therefore, in this study, we have devised a user-friendly three-step chromatographic procedure that relies on the Chelex-100 resin and other resins for the efficient isolation and purification of nickel from a wide array of geological samples. The three resins utilized in this procedure are Chelex-100, AGMP-1M, and AGMP-50. It is worth noting that Chelex-100 has exhibited exceptional performance in eliminating alkali metals, alkaline earth metals, and iron. Following chromatographic separation, the recovery of nickel surpassed 96%, with a procedural blank below 1.2 ng. To evaluate the procedure's effectiveness, we conducted nickel isotope measurements on nine geological reference materials (BCR-2, GSR-3, GSP-2, NOD-A-1, GSMC-1, SGR-1, SDO-1, GSD-5a, and GSD-23) using MC-ICP-MS. The obtained values were consistent with previously published data, confirming the reliability of our results. The findings of our study establish the applicability of the developed separation procedure for nickel isotope analysis in various geological samples. [ABSTRACT FROM AUTHOR]

Detrital chromite is currently accumulating in the wave-influenced gravel-dominated shoreface of eastern Port au Port Bay of western Newfoundland adjacent to the mouth of Fox Island River. Chromium (Cr) concentrations of up to 7485 ppm occur in modern cross-bedded shallow marine gravel and pebbly sand facies sourced from rapidly eroding coastal cliffs cut in a lateglacial and early postglacial fan delta and raised beach facies. These sediments fill a broad coastal embayment and were deposited by a glacially influenced Fox Island River during a phase of low relative sea level following final deglaciation of the Newfoundland Ice Cap between approximately 13 700 years B.P. (ybp) and 9500 ybp. Since then, coastal outcrops of these raised sediments have undergone rapid erosion in response to ongoing postglacial sea level rise outpacing the rate of crustal recovery. Geochemical analysis of 1149 sediment samples across the entire Fox Island River watershed identifies relatively low Cr concentrations (maximum 1860 ppm) in glacial and fluvial sediments, including those areas adjacent to chromite-bearing rocks of the Bay of Islands Ophiolite Complex. Conversely, uplifted lateglacial shallow marine gravels and associated raised beach/nearshore deposits along the coast show elevated Cr concentrations up to 5400 ppm, highlighting the importance of marine concentration of glacially derived sediment during deglaciation. At the present day, chromite-bearing lateglacial sediment is being reworked and transported southwards by shore-parallel littoral currents resulting in reconcentration of Cr within a nearshore placer about 8 km long and 2 km wide, though the deposit may be more extensive offshore where it is likely covered by transgressive marine muds. The glacial and postglacial history of the Port au Port Bay area was widely replicated in other areas of ultrabasic rock along the western coast of Newfoundland and the results of this investigation may aid the search for other nearshore glacially influenced marine placers. [ABSTRACT FROM AUTHOR]

This study investigates natural hydrogen (H2) occurrences in the Paris Basin, using Optical Character Recognition (OCR) technology to analyze an extensive, yet underexploited, database that contains historic drilling records. The potential of natural hydrogen has been largely unexplored in conventional oil and gas wells. Utilizing the in‐house CVAGeoDB database based on public well data, which includes well logs, mudlogs, and End Drilling Reports (EDRs) in PDF image format, we applied the Tesseract‐OCR Engine to convert these documents into searchable formats for efficient data analysis. Our analysis revealed several H2‐bearing wells across French sedimentary basins. The hydrogen occurrences in the Aquitaine Basin may be explained by the geological context and in particular the presence of a mantle body at shallow depth. On the contrary, the detection of H2 in the Paris Basin cannot be explained in a straightforward manner as the presence of ultramafic or U‐rich rocks is poorly documented so far. In the Paris Basin, H2 has been detected in four main formations: the Lusitanian, the Dogger, and Triassic aquifers as well as in the basement. The highest hydrogen concentration (52 vol%) was measured in the Dogger aquifer. These wells are primarily located along the Bray Fault, indicating at least a structural influence on H2 distribution. Finaly, the presence of serpentinzed dunite from the Lizard complex associated with the bedrock may have played the role as a source for H2. This research demonstrates the effectiveness of OCR in reassessing historical drilling data for natural hydrogen exploration, highlighting the need for comprehensive exploration methodologies in this emerging field. Plain Language Summary: This study explores the presence of natural hydrogen (H2) in the Paris Basin, employing Optical Character Recognition (OCR) technology to sift through an extensive database of old drilling records that have not been fully utilized in the past. As the world increasingly seeks carbon‐neutral energy sources, natural hydrogen produced through interactions between water and rocks emerges as a promising alternative to fossil fuels. Our research focuses on the CVAGeoDB database, which contains detailed information on drilling activities but in a non‐searchable PDF image format. OCR is a tool that turns images containing text, such as scanned documents, into text files that one can easily search and analyze. Our findings indicate the presence of H2 in several wells across French sedimentary basins. The Paris Basin, exhibits unexpected H2 occurrences not directly linked to anticipated geological factors classically used in H2 exploration. In the Paris Basin, the highest hydrogen concentration (52 vol%) was discovered in the Dogger aquifer. These wells are predominantly situated along the Bray Fault, suggesting a structural control on the distribution of hydrogen. This research underscores the utility of OCR in re‐evaluating historical drilling data for natural hydrogen exploration. Key Points: Natural hydrogen exploration in former oil and gas provinceUse of the Optical Character Recognition algorithm to optimize processing of a large drilling report databaseIndices for a potential H2 system (source, migration, trap) in the Paris Basin [ABSTRACT FROM AUTHOR]