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Hydrofluorocarbons are a class of fluorinated molecules used extensively in residential and industrial refrigeration systems. This study examines the potential of using adsorption processes with the silicalite-1 zeolite to separate a mixture of difluoromethane (CH2F2, HFC-32) and pentafluoroethane (CF3CF2H, HFC-125) at various concentrations. Pure adsorption data were measured using a XEMIS gravimetric microbalance, whereas binary data were determined using the Integral Mass Balance method. Grand canonical Monte Carlo molecular simulations were performed with the Cassandra package. We found that the results from molecular simulations are in satisfactory agreement with experimental loading measurements. Moreover, we show that ideal adsorbed solution theory could not quantitatively match the experimental or computational measurements of binary adsorption or selectivity. Molecular simulations show that refrigerant molecules do not have a uniform distribution in the zeolite framework. [ABSTRACT FROM AUTHOR]

We outline a surface scattering kernel for rarefied gas flows through ideally ordered nanomaterials, such as high aspect ratio carbon nanotubes. The derived model allows for a comparison of the tangential momentum accommodation coefficient, and, hence, the total effective friction, for different species of gases as a function of the particle diameter. This surface kernel is incorporated with a Fokker–Planck model as an approximation to transport of a rarefied gas through ideally ordered carbon nanotubes. The results of this analysis predict that H 2 experiences higher friction in such systems in comparison with larger molecules such as C H 4 . The results are proposed as a potential explanation of the reduced gas transport of hydrogen gas in nanoporous systems. [ABSTRACT FROM AUTHOR]

Liquid–liquid phase separation in diverse manufacturing and biological contexts often occurs in the presence of aggregated particles or complex-shaped structures that do not actively participate in the phase separation process, but these "background" structures can serve to direct the macroscale phase separation morphology by their local symmetry-breaking presence. We perform Cahn–Hilliard phase-field simulations in two dimensions to investigate the morphological evolution, wetting, and domain growth phenomena during the phase separation of a binary mixture in contact with model fractal aggregates. Our simulations reveal that phase separation initially accelerates around the fractal due to the driving force of wetting, leading to the formation of the target composition patterns about the fractals, as previously observed for circular particles. After the formation of a wetting layer on the fractal, however, we observe a dramatic slowing-down in the kinetics of phase separation, and the characteristic domain size eventually "pins" to a finite value or approaches an asymptotic scaling regime as an ordinary phase if the phase separation loses memory of the aggregates when the scale of phase separation becomes much larger than the aggregate. Furthermore, we perform simulations to examine the effects of compositional interference between fractals with a view to elucidating interesting novel morphological features in the phase-separating mixture. Our findings should be helpful in understanding the qualitative aspects of the phase separation processes in mixtures containing particle aggregates relevant for coating, catalyst, adhesive, and electronic applications as well as in diverse biological contexts, where phase separation occurs in the presence of irregular heterogeneities. [ABSTRACT FROM AUTHOR]

We present the phase separation dynamics of a binary (AB), simple fluid (SF), and amphiphilic polymer (AP) mixture using dissipative particle dynamics simulation at d = 3. We study the effect of different AP topologies, including block copolymers, ring block copolymers (RCP), and miktoarm star polymers, on the evolution morphologies, dynamic scaling functions, and length scale of the AB mixture. Our results demonstrate that the presence of APs leads to significantly different evolution morphologies in SF. However, the deviation from dynamical scaling is prominent, mainly for RCP. Typically, the characteristic length scale for SF follows the power law R(t) ∼ tϕ, where ϕ is the growth exponent. In the presence of high AP, we observe diffusive growth (ϕ → 1/3) at early times, followed by saturation in length scale (ϕ → 0) at late times. The extent of saturation varies with constraints imposed on the APs, such as topology, composition ratio, chain length, and stiffness. At lower composition ratios, the system exhibits inertial hydrodynamic growth (ϕ → 2/3) at asymptotic times without clearly exhibiting the viscous hydrodynamic regime (ϕ → 1) at earlier times in our simulations. Our results firmly establish the existence of hydrodynamic growth regimes in low surfactant-influenced phase separation kinetics of binary fluids and settle the related ambiguity in d = 3 systems. [ABSTRACT FROM AUTHOR]

Temperature gradients induce mass separation in mixtures in a process called thermal diffusion and are quantified by the Soret coefficient ST. Thermal diffusion in fluid mixtures has been interpreted recently in terms of the so-called (pseudo-)isotopic Soret effect but only considering the mass and moment of inertia differences of the molecules. We demonstrate that the first moment of the molecular mass distribution, the mass dipole, contributes significantly to the isotopic Soret effect. To probe this physical effect, we investigate fluid mixtures consisting of rigid linear molecules that differ only by the first moment of their mass distributions. We demonstrate that such mixtures have non-zero Soret coefficients in contrast with ST = 0 predicted by current formulations. For the isotopic mixtures investigated in this work, the dependence of ST on the mass dipole arises mainly through the thermal diffusion coefficient DT. In turn, DT is correlated with the dependence of the molecular librational modes on the mass dipole. We examine the interplay of the mass dipole and the moment of inertia in defining the isotopic Soret effect and propose empirical equations that include the mass dipole contribution. [ABSTRACT FROM AUTHOR]

The Robeson bound is a theoretical limit that applies to kinetics-driven membrane separations of gas mixtures. However, this bound does not apply to sorption-driven membrane processes such as CO2/N2 separation, which lacks a theoretical explanation. As a result, we are uncertain about the factors that control the limiting behavior of sorption-driven separations. To address this issue, we employed a simple lattice model and dynamic mean field theory to examine the transport properties of disordered model structures, isolating sorption effects from purely kinetic effects. Our findings indicate that transport effects play a crucial role in sorption-driven processes, and perm-selectivity is consistently lower than sorption selectivity, which is an unattainable limit. We used basic geometric fragments of the structure to explain how transport effects emerge and manifest themselves in sorption-driven processes. [ABSTRACT FROM AUTHOR]

This paper describes the use of PolyJet 3D printing to fabricate microchip electrophoresis devices with integrated microwire electrodes for amperometric detection. The fabrication process involves 3D printing of two separate pieces, a channel layer and an electrode layer. The channel layer is created by 3D printing on a pre-fabricated mold with a T-intersection. For the electrode layer, a stencil design is printed directly on the printing tray and covered with a piece of transparent glass. Microwire electrodes are adhered over the glass piece (guided by underlaying stencil) and a CAD design of the electrode layer is then printed on top of the microwire electrode. After delamination from the glass after printing, the microwire is embedded in the printed piece, with the stencil design ensuring that alignment and positioning of the electrode is reproducible for each print. After a thermal bonding step between the channel layer and electrode layer, a complete electrophoresis device with integrated microelectrodes for amperometric detection results. It is shown that this approach enables different microwire electrodes (gold or platinum) and sizes (100 or 50 µm) to be integrated in an end-channel configuration with no gap between the electrode and the separation channel. These devices were used to separate a mixture of catecholamines and the effect of separation voltage on the potential voltage applied on the working electrode was also investigated. In addition, the effect of electrode size on the number of theoretical plates and limit of detection was studied. Finally, a device that contains different channel heights and a detection electrode was 3D-printed to integrate continuous flow sampling with microchip electrophoresis and amperometric detection. [ABSTRACT FROM AUTHOR]

Copyright of Petroleum Refinery Engineering is the property of Petroleum Refinery Engineering Editorial Office and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Membrane separation technology is one of the most widely studied methods for wastewater treatment. This paper is based on the non-solvent-induced phase separation (NIPS) method, which is combined with phase-field simulation to develop a fluid model for the volume fraction of tetrameric polyvinylidene fluoride (PVDF).In this paper, DMSO, DMAc and DMF are used as solvents, and pure water is used as a gel bath to simulate the relevant parameters of PVDF membrane; and PVP and LiCl are used as additives, and DMF and DMAc are used as solvents for the two-by-two combinations, and by calculating the relevant parameters of the PVDF quaternary membrane system, comparing and verifying the simulation results through experiments. results show that: the different solvents on the PVDF membrane in the order of DMSO > DMAc > DMF; additive LiCl system, the polymer diffusion rate in the polymer solution layer are faster than the PVP system. However, the top layer of the polymer solution layer in the PVP system is relatively flat, while the top layer of the polymer solution layer in the additive LiCl system is more undulating or even broken, indicating that LiCl has a greater influence on the membrane than PVP. [ABSTRACT FROM AUTHOR]

In Part I, a companion paper of the two-part article, a subsonic turbine stage and a transonic one conditioned at the same Reynolds number, flow coefficient, loading coefficient and reaction, but two different exit Mach numbers are designed to provide a direct contrast between a high-subsonic and a transonic flow conditioning for rotor blade squealer tips. In this paper as Part II, further analyses are carried out to address the main issues of interest arising from Part I: first, to identify the driving flow physical mechanisms for the contrasting aerodynamic efficiency sensitivities of the two stages; second to seek a more suitable heat transfer objective function for the tip aerothermal design optimization, given the seemingly strong conflicts among those conventionally adopted heat transfer objective functions. Two counter-rotating tip vortical structures, the pressure side vortex (PSV) and the casing-driven cavity vortex (CCV), are shown to impact the aero-performance differently between the two stages. For the subsonic stage, the leakage flow is strongly affected by a stronger residual PSV at the squealer cavity exit. For the transonic stage however, the tip choking in limiting the over tip leakage (OTL) mass flow and favorable pressure gradient in a transonic flow over a separation bubble led to a much stronger and more persistent CCV and thus lower aero-effectiveness of squealer tip for the transonic stage. The two vortices also show major heat transfer signatures on the cavity surfaces by impingement. For the PSV, the impingement impact is mainly on the cavity floor. For the CCV, on the other hand, its impact is mainly on the inner side-wall of the suction side rim. The latter is found to be mainly responsible for the overall linear variations of the heat load with the squealer height. Again, the relative strength between PSV and CCV serves as an effective differentiator in the heat transfer performance. The stronger and more persistent CCV in the transonic stage results in a strong signature on a large portion of the suction side cavity inner sidewall, thus a much higher increment in heat transfer with the squealer height than that for the subsonic stage. In seeking to establish a more consistent heat transfer objective function for combined aerothermal design and optimization, a coolability weighted nonuniformity parameter is proposed to integrate the local heat transfer and the coolability. The proposed objective function is shown to lead to consistent Pareto fronts for the combined aerothermal performance sensitivities, particularly for the present cases with strong heat transfer nonuniformity which are particularly challenging to those conventional treatments as shown in Part I. The coolability-augmented objective function should thus serve as an enabler to help practical applications of blade tip aerothermal design optimizations. [ABSTRACT FROM AUTHOR]

Family law services assisting clients with post-separation parenting arrangements can play a key role in encouraging collaborative communication between separating parents. Increasingly, this communication takes place by digital means. Services and practitioners need to understand which communication technologies (CTs) are used by their clientele, how they are experienced in both positive and negative ways, and why some technologies might be favoured over others as a result. This paper reports on an exploratory mixed methods study of the use and misuse of 'everyday' CTs (text/instant messaging, email and social media) among parents accessing post-separation services in Victoria, Australia. A survey of 118 clients was followed by interviews with 12 participants. Post-separation clients readily differentiated between common CTs in terms of the extent to which they were helpful or unhelpful for co-parenting. Most participants had recent experience of some form of CT misuse by their ex-partners. An improved understanding of client experiences will help post-separation services incorporate explicit discussion of CT use in the negotiation of parenting arrangements. [ABSTRACT FROM AUTHOR]

The exploitation of high-performance membranes selective for propylene is important for developing energy-efficient propylene/propane (C3H6/C3H8) separation technologies. Although metal–organic frameworks with a molecular sieving property have been considered promising filler materials in mixed-matrix membranes (MMMs), their use in practical applications has been challenging due to a lack of interface compatibility. Herein, we adopted a surface coordination strategy that involved rationally utilizing carboxyl-functionalized PIM-1 (cPIM) and ZIF-8 to prepare a mixed-matrix membrane for efficient propylene/propane separation. The interfacial coordination between the polymer and the MOF improves their compatibility and eliminates the need for additional modification of the MOF, thereby maximizing the inherent screening performance of the MOF filler. Additionally, the utilization of porous PIM-1 guaranteed the high permeability of the MMMs. The obtained MMMs exhibited excellent separation performance. The 30 wt% ZIF-8/cPIM-1 membrane performed the best, exhibiting a high C3H6 permeability of 1023 Barrer with a moderate C3H6/C3H8 selectivity of 13.97 under 2 bars of pressure. This work presents a method that can feasibly be used for the preparation of defect-free MOF-based MMMs for specific gas separations. [ABSTRACT FROM AUTHOR]

Compared with wet coal preparation and traditional dry coal preparation, detection of coal and gangue with small particle size is a difficult problem for dual-energy X-ray separation technology. And small target segmentation is the premise of its detection, which is poor due to the fewer number of pixels and texture information in coal and gangue dual-energy X-ray images. So, the Otsu with crotch structure based on Adaptive Particle Swarm Optimization (APSO) for small target segmentation method is proposed, called after APSO-C_Otsu. Firstly, the Otsu with crotch structure is used to increase the contrast between small target and background. Meanwhile, the APSO algorithm was used to optimize the Otsu algorithm with crotch structure in order to improve its convergence speed and reduce its calculation amount. Finally, after binarization, the location of the targets are labeled based on the bwlabel algorithm. The results revealed that the APSO-C_Otsu algorithm could effectively segment the coal and gangue with a particle size of 5–30 mm, and was also applicable to the coal and gangue with the particle size larger than 30 mm, which was of great significance for accurate detection of coal and gangue and the improvement of coal utilization. [ABSTRACT FROM AUTHOR]

An internal thermally coupled air separation column (ITCASC) process is an effective energy‐saving technology in the air separation process. However, a large economic investment is a crucial factor for the widespread use of this technology in practical applications. In this article, an alternative configuration design, namely, top‐integrated (T‐ITCASC), bottom‐integrated (B‐ITCASC), and top‐bottom‐integrated ITCASC (T‐B‐ITCASC) with a focus on energy savings and economic feasibility are studied. A rigorous optimization based on a nonlinear interior‐point algorithm was developed by integrating the dynamic model into the optimization formulation. In the context of ITCASC process design and optimization, numerical simulations demonstrated that T‐ITCASC, B‐ITCASC, and T‐B‐ITCASC configurations improved energy‐saving potential and reduced capital investment, compared to the F‐ITCASC and conventional air separation column (CASC) configurations. Among these optimized configurations, the T‐B‐ITCASC configuration is preferred. [ABSTRACT FROM AUTHOR]

Copyright of Industrial Minerals & Processing / Huagong Kuangwu yu Jiagong is the property of Industrial Minerals & Processing Editorial Office and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Biochar remediation technology is increasingly being valued due to its economic and environmental advantages in treating heavy metal contaminated soil. In order to comprehensively grasp the research progress in this field, we analyzed the current research status, hotspots, and development directions of biochar passivation remediation of heavy metal contaminated soil based on the core collection database of Web of Science from 2008 to 2022, using bibliometrics and CiteSpace visualization technology. The analysis results indicate that since 2014, research on biochar remediation technology has become a hot topic in the treatment of heavy metal contaminated soil, and the number of literature in this field has grown rapidly. The application scope, mechanism of action, application effect, preparation method, and optimization technology of biochar are the main focus of this field. The selection of iron-modified biochar in the rice-soil system, biochar-based nanocomposites, and the combined application of phytoremediation and biochar are current research hotspots. The interaction mechanism between biochar and soil system, microbial remediation technology based on biochar, potential long-term effects of biochar use, and separation technology between biochar and soil are future research directions in the field of biochar remediation of heavy metal contaminated soil. [ABSTRACT FROM AUTHOR]

Biobutanol is a green solvent commonly used as gasoline additive. In this study, it is proposed the separation of azeotropic mixtures of butanol and n‐butyl ether (DBE) using ionic liquids (ILs). Suitable anions [AC]− and [H2PO4]− were screened by COSMO‐RS, and the effect of carbon chain length on the separation effect was investigated using quantum chemical calculations. It was found that the anion was primarily responsible for the separation effect, which grew as the carbon chain grew. Molecular dynamics simulations were used to verify the separation performance of the selected ILs. The separation effect of ILs was further verified using vapor–liquid phase equilibrium (VLE) experiments. The extractive distillation process with [PrMIM][AC] as the extractant was investigated to demonstrate the feasibility of ILs for the separation of butanol and DBE. This study analyzes the whole process from microscopic mechanism of action, which provides new ideas for the separation of alcohol‐ether systems. [ABSTRACT FROM AUTHOR]

Metal-based membranes have emerged as a promising solution, providing selective permeability and impressive durability. However, a comprehensive understanding of their environmental performance across their entire life cycle remains elusive. This research offers a comprehensive life cycle assessment (LCA) of electroless plated palladium alloy-based membranes for hydrogen separation. It evaluates the environmental impacts across various stages, from the synthesis of supports to the application of intermediate and selective layers. Key findings include the identification of alumina supports and graphite intermediate layers as having minimal environmental impacts, and the Pd–Cu membrane as the most sustainable choice among palladium alloy membranes. This research advances our understanding of the eco-friendly performance of palladium based H 2 separation membranes, guiding the development of more sustainable hydrogen separation technologies. [Display omitted] • Environmental comparison of support, intermediate, and selective layers in metal-based H 2 separation membranes. • Use of the Electroless Plating method. • Alumina supports have the least environmental impact. • Graphite layers offer the lowest comprehensive environmental effects across various categories for the intermediate layers. • Pd–Cu membrane is the most sustainable choice in Pd alloy membranes due to its minimal environmental impact. [ABSTRACT FROM AUTHOR]

The development of polymers with high separation characteristics for the efficient removal of carbon dioxide from bio‐/natural gases is the key to reducing the environmental impact of CO2. In this work, preparation and gas‐separation properties of novel vinyl‐addition polynorbornenes containing oxirane‐moieties at spiro centers, which combine high CO2‐permeability with remarkable selectivities for separation of CO2 from its mixtures with nitrogen and methane are published. Gas permeability data of the epoxidized polymer based on 5‐ethylidene‐2‐norbornene exceed the Robeson upper bound of 2019 for the CO2/N2 system (CO2 permeability is 1000 Barrer, α(CO2/N2) = 67)). Separation experiments with mixtures of gases confirm the high separation performance of this polymer. In particular, the data for CO2/CH4 separation are above or close to the upper bound of 2018 for mixed gases. A similar effect of introducing oxirane moieties into spiro centers is also shown for another vinyl‐addition polymer derived from 5‐isopropylidene‐2‐norbornene and is not observed for a related polymer bearing oxirane moieties at the ends of side chains. A simple synthesis of the epoxidized polymer from available 5‐ethylidene‐2‐norbornene, combined with high CO2‐permeability and selectivities, may open a window for industrial applications of this polymer in important membrane processes, in particular, for natural/biogas upgrading. [ABSTRACT FROM AUTHOR]

AbstractFree-fall tribo-electrostatic separators have long been used for sorting granular plastic wastes. The aim of this paper is to propose a modified configuration of the electrode system of such a separator and validate its effectiveness for processing a mixture of polyethylene (PE) and polypropylene (PP) flakes originating from the processing of packaging waste at GRANUPLAST Company, Jassans-Riottier, France. The mixture to be treated is not homogeneous and consisted of roughly 2/3 PE and 1/3 PP. The granular mixture samples were charged by triboelectric effect in a fluidized bed device, and then introduced into a laboratory-scale free-fall electrostatic separator. Preliminary tests were conducted to ascertain the mass of the mixture to be introduced in the fluidized bed and the duration of the charging process. Better results were obtained with the modified electrode configuration of the free-fall electrostatic separator. Thus, from 100 g of mixed flakes, 98.2% of PE and 96.6% of PP were recovered with purities of 99.1% and 98%, respectively. In addition, numerical modeling of the PP and PE particles trajectory was performed to simulate the behavior of charged particles in the standard and modified electrode configurations. Work is in progress for the industrial implementation of this tribo- electrostatic separation technology. [ABSTRACT FROM AUTHOR]

This publication explores current and prospective methods for hydrogen production and purification, with a strong emphasis on membrane-based technologies for purification and separation. This focus is justified by the ongoing shift towards renewable energy sources (RESs) in electricity generation, necessitating strategic changes to increase hydrogen utilization, particularly in the automotive, heavy road, and rail sectors, by 2025–2030. The adoption of hydrogen from RESs in the construction, energy, and industrial sectors (e.g., for process heat or fertilizer production) is also under consideration, driving the need for innovative production, separation, and purification methods. Historically, industrial-scale hydrogen has been predominantly derived from fossil fuels, but renewable sources such as electrolysis, biological, and thermal processes now offer alternatives with varying production efficiencies (0.06–80%) and gas compositions. Therefore, selecting appropriate separation and purification methods is critical based on specific usage requirements and the gas composition. Industrial-scale hydrogen purification commonly employs pressure swing adsorption (PSA) technologies, capable of achieving up to 99.99% purity. Cryogenic distillation is suitable for applications needing up to 95% purity. Membrane technologies, including polymer, metallic, and electrolytic membranes, have traditionally been limited to moderate volumes of pure gas production but are crucial for hydrogen purification and separation. This publication critically evaluates the potential of membrane technology for hydrogen separation, particularly in response to the anticipated rise in demand for RES-derived hydrogen, including from renewable feedstocks. [ABSTRACT FROM AUTHOR]

Regarding to the problem that excessive stem sliver in cigarettes could damage their physical properties and affect the smoking sensation, the separation technology and equipment for stem silver removing in the cigarette manufacturing process were reviewed in this study. It was summarized that the separation of stem sliver was concentrated in two key stages including cut tobacco making and cigarette packaging. The main technologies for stem sliver separation including air separation, vibrating screen, and composite processes. Among them, air separation was the main process. The separation efficiency could be improved through equipment improvement and parameter optimization. However, the balance between tobacco loss and purity still faced challenges. The vibrating screen was easily affected by the shortcomings of screen blocking and cleaning, but the composite process combining it with air separation were gradually receiving attention. The composite process of stem sliver separation combined optical identification selection and air separation had showed more accurate and intelligent separation solutions for the cigarette industry, but it was not been widely applied in actual production lines. In the future, the research and development of air separation technology can be strengthened, and it can be deeply and systematically integrated with vibration screen, light identification separation and other technologies. These will achieve the balanced development of cigarette product quality and material consumption. [ABSTRACT FROM AUTHOR]

Membrane distillation is a novel membrane-based separation technology with the potential to produce pure water from high-salinity brine. It couples transport behaviors along the membrane and across the membrane. The brine in the feed is gradually concentrated due to the permeate flux across the membrane, which is a significant factor in initiating the scaling behavior on the membrane surface along the feed flow direction. It is of great interest to investigate and estimate the development of scaling on the membrane surface. This work specifically focuses on a long-distance membrane distillation process with a sodium chloride solution as the feed. A modeling approach has been developed to estimate the sodium chloride scaling development on the membrane surface along the flow direction. A set of experiments was conducted to validate the results. Based on mathematical simplification and analytical fitting, a simplified model was summarized to predict the initiating position of sodium chloride scaling on the membrane, which is meaningful for scaling control in industrial-scale applications of membrane distillation. [ABSTRACT FROM AUTHOR]

Design of experiment is an efficient and cost-effective tool to optimize the chromatographic separation of a multicomponent mixture. The central composite design was conducted to develop and optimize a green high performance liquid chromatography (HPLC) method for simultaneous quantitation of a quaternary mixture of paracetamol, chlorpheniramine maleate, caffeine and ascorbic acid in their pharmaceutical dosage form as well as the determination of their dissolution profile. A five-level three-factor model was performed to investigate the effect of mobile phase composition, pH and flow rate on enhanced resolution and short run time. Analysis was performed using a Kinitex EVO C18 column and a mobile phase composed of methanol: 0.02 M phosphate buffer pH 3.3 (34:66, v/v) at 1.0 mL/min using photodiode array detection. Optimum chromatographic separation was achieved in <6 min with a desirability of 0.999. Linearity was achieved over a range of 1.00–300.00, 1.00–50.00, 2.00–50.00 and 2.00–100.00 μg/mL for paracetamol, chlorpheniramine maleate, caffeine and ascorbic acid, respectively, with a limit of detection (<0.1 μg/mL). The greenness profile was evaluated using the analytical eco-scale and Analytical GREEnness Metric Approach with values of 81 and 0.77, respectively. [ABSTRACT FROM AUTHOR]

Cyclones are pivotal in mechanical process engineering and crucial in the complex field of separation technology. Their robustness and compact spatial requirements render them universally applicable and versatile across various industrial domains. Depending on the utilized fluid and field of application, both gas-based cyclones and hydrocyclones (HCs) are well established. Regarding HC design, enduring elongated flat cones have seen minimal alterations in shape and structure since their introduction over more than a hundred years ago. Experimental investigations regarding unconventional cone designs within scientific studies remain the exception. Therefore, this study focuses on alternative geometric configurations of the separation chambers and highlights their impact on separation and energy efficiency. To achieve this objective, different geometric shapes are investigated and retrofitted into HCs. The geometric foundation is derived from upcycled glass bottles. The repurposed bottles with a volume of 750 mL are used in conjunction with an inlet part, following the established Rietema design. Experimental tests are conducted with dilute phase separation, using 0.1–200 µm test particles in water. Comparisons between a bottle-based HC and a conventional Rietema design were conducted, establishing a benchmark against the standard. The findings revealed a noticeable correlation between separation efficiency and cone geometry. Conical designs demonstrated enhanced separation, particularly at lower volume flows. At the highest volume flow of 75 L min−1, the best performing bottle cyclones showed separation efficiencies of 78.5%, 78.4% and 77.9% and therefore are in a competitive range with 78.0% efficiency, achieved using the commercial Rietema design. Minimal disparities in cut sizes were observed in terms of separation grade efficiency among the models tested. Variations in separation efficiency and fractional efficiency curves indicated nuanced differences in classification efficiency. [ABSTRACT FROM AUTHOR]

Worldwide, it is estimated that there are 1.8 to 2.7 million cases of envenoming caused by snakebites. Snake venom is a complex mixture of protein toxins, lipids, small molecules, and salts, with the proteins typically responsible for causing pathology in snakebite victims. For their chemical characterization and identification, analytical methods are required. Reversed-phase liquid chromatography coupled with electrospray ionization mass spectrometry (RP-LC-ESI-MS) is a widely used technique due to its ease of use, sensitivity, and ability to be directly coupled after LC separation. This method allows for the efficient separation of complex mixtures and sensitive detection of analytes. On the other hand, matrix-assisted laser desorption/ionization mass spectrometry (MALDI-MS) is also sometimes used, and though it typically requires additional sample preparation steps, it offers desirable suitability for the analysis of larger biomolecules. In this study, seven medically important viperid snake venoms were separated into their respective venom toxins and measured by ESI-MS. In parallel, using nanofractionation analytics, post-column high-resolution fractionation was used to collect the eluting toxins for further processing for MALDI-MS analysis. Our comparative results showed that the deconvoluted snake venom toxin masses were observed with good sensitivity from both ESI-MS and MALDI-MS approaches and presented overlap in the toxin masses recovered (between 25% and 57%, depending on the venom analyzed). The mass range of the toxins detected in high abundance was between 4 and 28 kDa. In total, 39 masses were found in both the ESI-MS and/or MALDI-MS analyses, with most being between 5 and 9 kDa (46%), 13 and 15 kDa (38%), and 24 and 28 kDa (13%) in size. Next to the post-column MS analyses, additional coagulation bioassaying was performed to demonstrate the parallel post-column assessment of venom activity in the workflow. Most nanofractionated venoms exhibited anticoagulant activity, with three venoms additionally exhibiting toxins with clear procoagulant activity (Bothrops asper, Crotalus atrox, and Daboia russelii) observed post-column. The results of this study highlight the complementarity of ESI-MS and MALDI-MS approaches for characterizing snake venom toxins and provide a complementary overview of defined toxin masses found in a diversity of viper snake venoms. [ABSTRACT FROM AUTHOR]

This paper studies the distributed output feedback consensus control for a class of uncertain nonlinear multi-agent systems (MASs). The dynamics of subsystems are heterogeneous and contain unknown control gains. A novel distributed fuzzy consensus control protocol is constructed by employing variable separation technology and adaptive backstepping technique. The main advantage of the protocol is that it is distributed only depending on the relative output information. Moreover, it does not require the observer information exchange, which can avoid network attacks. A numerical example is given to illustrate the effectiveness of the proposed scheme. [ABSTRACT FROM AUTHOR]

The rampant hepatitis B virus (HBV) seriously endangers human health, and hepatitis B surface antigen (HBsAg) is its early diagnostic marker. Therefore, it is crucial to construct a fast and highly sensitive HBsAg detection method. Based on high-efficiency magnetic separation technology and fluorescent composite material labelling technology, an accurate, fast and sensitive fluorescent immunosensing system for HBsAg detection was developed. Immunomagnetic beads constructed from carboxyl-functionalized Fe3O4 nanoparticles (Fe3O4-COOH) with excellent magnetic response performance were used as efficient capture carriers for HBsAg. Immunofluorescence composite microspheres constructed based on ultra-stable polystyrene-coated CsPbBr3 perovskite nanocrystals (CPB@PSAA) with high hydrophilic properties, were excellent fluorescent markers for HBsAg. Using this sensitive sandwich fluorescence sensing system a good linear relationship within the range of 0.2–15 ng/mL was established between HBsAg concentration and fluorescence intensity with a limit of detection (LOD) of 0.05 ng/mL. The system obtained satisfactory results when tested on real human serum samples. The magnetic-assisted fluorescence immune-sandwich sensor system has broad application prospects in biomedicine such as rapid and early diagnosis and effective prevention of infectious diseases. [ABSTRACT FROM AUTHOR]

The separation of plastic mixtures from waste electrical and electronic equipment is an increasingly active domain of research. Several electrostatic separation processes and devices have been developed to recover plastic waste. All these processes are based on the use of the triboelectric effect to charge the plastic granules to separate them in an intense electric field. The objective of this study is to investigate the effect of ambient humidity on the efficiency of the triboelectric charging and electrostatic separation process, especially in an industrial environment where granular plastic waste may contain residual moisture due to previous processing by flotation or inappropriate storage. The experiments were carried out using a rotating-multi-cylinder tribocharger and a roll-type electrostatic separator. The samples were composed in equal proportions of either: (1) acrylonitrile butadiene styrene (ABS) and polystyrene (PS) or (2) polypropylene (PP) and polyethylene (PE), the average particle diameter of which was between 2 and 6 mm. The efficiency of the tribo-electrostatic separation was evaluated by measuring the purity and recovery of the products. The results confirm that separating (ABS + PS) and (PP + PE) mixtures is feasible. The best separation results were obtained when the materials were stored and processed at an ambient relative humidity of around 50%. [ABSTRACT FROM AUTHOR]

Diesel-Ethanol (DE) blends have gained attention as an alternative fuel due to their potential to reduce emissions and improve the performance of diesel engines. However, a significant challenge when dealing with DE blends is that of phase separation. Achieving optimal miscibility between ethanol and diesel often requires the addition of additives. This research article thoroughly examines the miscibility, blend stability, and phase separation of DE mixtures with various additives. To prepare blends for the miscibility analysis, DE blends with 10%, 15%, and 20% ethanol were mixed with selected additives (n-pentanol, n-butanol, ethyl acetate, and diethyl ether) at a 2% concentration in each blend. Prior to the miscibility analysis, all blends were mixed using a magnetic stirrer and a probe ultrasonicator. The results indicated that DE10 with 2% n-propanol, DE10 with 2% n-butanol, DE15 with 2% n-butanol, and DE10 with 2% diethyl ether exhibited good miscibility without phase separation or sedimentation after four weeks. However, it was noted that all the other blends with higher ethanol content were eventually phase-separated after four weeks. [ABSTRACT FROM AUTHOR]

The Functionalized Cahn Hilliard (FCH) equation was used to model micro-phase separation in mixtures of amphiphilic molecules in solvent. In this paper, we proposed a Tri-Harmonic Modified (THM) numerical approach for efficiently solving the FCH equation with symmetric double well potential by extending the ideas of the Bi-harmonic Modified (BHM) method. THM formulation allowed for the nonlinear terms in the FCH equation to be computed explicitly, leading to fast evaluations at every time step. We investigated the convergence properties of the new approach by using benchmark problems for phase-field models, and we directly compared the performance of the THM method with the recently developed scalar auxiliary variable (SAV) schemes for the FCH equation. The THM modified scheme was able to produce smaller errors than those obtained from the SAV formulation. In addition to this direct comparison with the SAV schemes, we tested the adaptability of our scheme by using an extrapolation technique which allows for errors to be reduced for longer simulation runs. We also investigated the adaptability of the THM method to other 6th order partial differential equations (PDEs) by considering a more complex form of the FCH equation with nonsymmetric double well potential. Finally, we also couple the THM scheme with a higher order timestepping method, (implicit-explicit) IMEX schemes, to demonstrate the robustness and adaptability of the new scheme. Numerical experiments are presented to investigate the performance of the new approach. [ABSTRACT FROM AUTHOR]

Carlin-type gold ore flotation is one of the difficulties in beneficiation and also one of the research hotspots. A certain gold deposit is of Carlin-type with complex ore properties and is disseminated in subsieve particles with high content of carbonate minerals, clay minerals and carbonaceous minerals. The gold-bearing minerals have poor floatability, making the recovery of gold extremely difficult. Starting from the key technical challenges that seriously affect flotation indicators, such as high content of gangue slime that is difficult to suppress, subsieve disseminated gold, and large differences in floatability of gold-bearing minerals, this study adopts deep dispersion depression-activation synergism-flotation at a different velocity and utilizes the synergistic effect of the collector to effectively reduce the circulating load of middling ore and realize efficient separation and recovery of gold minerals. A gold concentrate with a gold grade of 24.61 g • t-1 and a gold recovery rate of 80.42% could be obtained by the flotation closed-circuit test. After adopting this technology, there is no need to remove the slime beforehand, which solves both the problems of low gold grade and recovery in the past, reduces the operation process, and provides technical support for solving the recovery of sluggish gold resources. [ABSTRACT FROM AUTHOR]

The paper presents a case study that applies a model predictive control (MPC) approach in a Micro850 programmable logic controller (PLC) to a laboratory pressure swing adsorption (PSA) process used for separating gas mixtures of CO2 and CH4. PLC is an industrial hardware characterized by its robustness to hazardous environments and limited computational capacities, which poses computational challenges for MPC implementation. This paper's main contribution is the application of the modified Takagi–Sugeno–Kang-based MPC (MTSK-MPC) algorithm to this PSA unit, which provides features to investigate and implement feasible MPC designs in PLCs. The investigation consists of a sensitivity analysis of how some design parameters influence the PLC memory and the MPC implementation and a comparative evaluation of the computational processing from different MPC algorithms and simulations. The comparison comprises software-in-the-loop simulations with three algorithms in the PC: an implicit MPC, an explicit MPC, and the MTSK-MPC. Additionally, it includes a hardware-in-the-loop simulation with the implemented MTSK-MPC in Micro850. The results show that the MPC algorithms achieve close performance, tracking setpoint changes and rejecting output disturbances, with the MTSK-MPC presenting the lower processing time among the MPCs in the PC. The study concludes that the implementation of MTSK-MPC in the Micro850 is feasible. [ABSTRACT FROM AUTHOR]

The goal of the present study is to evaluate the effect of plasticizer in PIMs properties and performance for zinc separation. Membranes were prepared by casting a solution containing poly (vinyl chloride) (PVC) as base polymer, di (2‐ethylhexyl) phosphoric acid (D2EHPA) as carrier, and 2‐nitrophenyl octyl ether (NPOE) or tris (2‐butoxyethyl) phosphate (TBEP) as plasticizers. The newly developed PIMs transported practically all ZnII ions from a feed phase at pH 5 to a 1 M H2SO4 stripping phase. The results showed that the transport flux and its efficiency depend on the chemical nature of the plasticizer. It can be perceived that NPOE (with dielectric constant of 23.1) produced the highest transport flux of zinc (J0=1.62±0.05 10−5 mol m−2 s−1). The single ion transport of zinc was significantly higher than the binary and ternary mixtures. In ternary solution, the transport efficiency for metal ions was in the order of ZnII>CuII>NiII. The transport efficiency of the PVC/NPOE/D2EHPA membrane remained constant until the seventh use. The findings of this work will allow the invention of advanced separation technology ensuring the sustainability of metal resources. [ABSTRACT FROM AUTHOR]

Development of high-performance CO2 separation membrane materials is the most vital challenge in membrane separation technology for carbon emission reduction and carbon neutrality. Mixed matrix membranes (MMMs) were prepared using polyether-block-polyamide (Pebax-1074) as the membrane matrix and multi-walled carbon nanotubes (MWCNTs) as the filler. The morphology, microstructure, surface functional groups, and thermal properties of the MMMs were characterized by scanning electron microscope, X-ray diffraction, infrared spectroscopy, and thermogravimetric analysis, respectively. The effects of MWCNTs content, permeation temperature, and permeation pressure on the microstructure and gas separation properties of the prepared MMMs were investigated. The results show that the microstructure and the gas separation performance of the membrane can be significantly regulated through varying the content of MWCNTs. The optimal separation performance is attained to 291.4 Barrer of CO2 permeability and 160.2 of CO2/N2 selectivity for the MMMs containing 12% MWCNTs under the condition of 30 °C and 0.2 MPa. The exceptional separation performance is far beyond the commercially attractive Robeson upper-bound. [ABSTRACT FROM AUTHOR]

Enantiopure pharmaceuticals are especially important in medicinal applications. Phenylglycine, as a critical pharmaceutical intermediate, is often utilized in single enantiomeric form for drug synthesis. Chiral membrane separation offers advantages such as simple operation, low energy consumption, and scalability, holding great potential for chiral drug separations. In this work, cellulose triacetate (CTA) membranes are prepared via phase inversion and used for permeation experiments driven by a concentration gradient to investigate selective permeation of D,L‐phenylglycine solutions. Scanning electron microscopy reveals surface and cross‐sectional morphologies of the fabricated membranes. After single‐factor optimization, the CTA membrane exhibits an enantiomeric excess of 68.94% for D,L‐phenylglycine separation. The membrane maintains its selective permeation capability after repeated use. This indicates the CTA membrane has favorable chiral selective permeation for D,L‐phenylglycine solutions with stable performance. The chiral carbon on the six‐membered ring of the CTA backbone, as well as the single‐handed helical structure of the backbone, are thought to be responsible for the chiral selectivity of the membrane. This is the first report of using CTA membranes for chiral amino acid separation, providing experimental references and theoretical basis for membrane separation of racemic mixtures. It could facilitate scalable applications of chiral membranes. [ABSTRACT FROM AUTHOR]

In the processing of construction waste, the sorting of the delivered mixtures is one of the decisive process steps in order to produce recyclates that can be reused. In the fine‐grain range, there is a lack of suitable processes for this. A procedure that has not been investigated so far is to separate concrete‐mortar‐brick mixtures on the basis of the magnetic susceptibility. Based on measurements of the susceptibility, sorting experiments were carried out using a rare earth roll magnetic separator. The positive results of the experiments described here call for further investigation of the performance of the sorting method. [ABSTRACT FROM AUTHOR]

This study reports the separation of pure hydrogen (H 2) employing pressure swing adsorption (PSA). The Li-X and Li-hierarchical X (Li–H-X) zeolite were prepared by an ion exchange process. The sorbents were evaluated through several experiments including, breakthrough, empty bed contact time (EBCT), single-bed, and two-bed PSA with different steps. The effect of pressure, purity, and recovery relationship was developed. The high-pressure PSA study was performed at 4, 6, and 10 bar with varying feed flow rates to assess their efficacy in pure H 2 separation using binary gas stream (H 2 /CO 2 , 75/25 vol.%). The breakthrough adsorption capacity of Li–H-X exhibited 3.4 mmol g−1 and 0.212 mmol g−1 of CO 2 and H 2 , respectively. Li–H-X shows ∼8% higher CO 2 sorption capacity than the Li-X sorbent at 1 bar and 300 K due to the large meso-microporous structure of the sorbent. The two-bed PSA purity and recovery were found higher than single-bed PSA. Using two-bed PSA, the Li–H-X achieved a 99.5% of purity, 92.9% of recovery, and 10.4 mL min−1 g−1 of productivity, which was ∼16% higher recovery and productivity than single-bed PSA at a flow rate of 1200 mL min−1 at 6 bar. With increasing the pressure and flow rate, the recovery of Li–H-X was enhanced up to 93.7% with 99.1%–99.9% H 2 purity. The long-term PSA was run using Li–H-X sorbent for 7.5 h with 230 cycles with H 2 purity between 98.5 and 99.5% at 6 bar. Interestingly, the adsorbent shows the scalability of PSA for efficient H 2 separation for a binary mixture of H 2 /CO 2. [Display omitted] • Li–H-X was evaluated using single and two-bed PSA using different conditions. • H 2 purity & recovery of Li–H-X sorbent was higher than Na-X and Li-X adsorbent. • H 2 recovery was higher in two bed PSA compare to sing bed PSA. • PSA cycles were run for a long duration with a marginal decrease in H 2 purity. • Li–H-X was potential sorbent for pure H 2 separtion from binary gas mixture. [ABSTRACT FROM AUTHOR]

The treatment of produced water is a major challenge faced by oil and gas industries worldwide. As a result of the increase in industrial activities, the generation of produced water has increased significantly. The most commonly used method for produced water oil–water separation is de-oiling hydrocyclone technology due to its simple construction, compact design, easy maintenance, and high efficiency. A wide breadth of scientific research studies has been carried out on performance evaluation, design optimisation, geometric parametrisation, external interventions, etc., to enhance the performance of hydrocyclones. These studies mostly rely on either experimental data obtained from the field, in laboratories under a controlled environment, or the application of numerical techniques for oil-in-water separation. Considering the extensive research studies published on hydrocyclone technology, this study aims to provide a comprehensive review of recent technological advancements in hydrocyclone technology in order to identify key areas where scientific research efforts should be concentrated. This will help make well-informed decisions for strategic investments in this wide area of research. Furthermore, it will widen the scope of applicability of hydrocyclones in the industrial sector. [ABSTRACT FROM AUTHOR]

• Different fabrication methods and their advantages and disadvantages of COF membranes are reviewed. • The application potential COF membrane in different liquid separations is introduced. • The mechanisms of COF membrane during liquid separation processes are summarized. • The challenges and prospects of the application of COF membrane are presented. Covalent organic frameworks (COFs) are a new kind of crystalline porous materials composed of organic molecules connected by covalent bonds, processes the characteristics of low density, large specific surface area, adjustable pore size and structure, and easy to functionalize, which have been widely used in the field of membrane separation technology. Recently, there are more and more researches focusing on the preparation methods, separation application, and mechanism of COF membranes, which need to be further summarized and compared. In this review, we primarily summarized several conventional preparation methods, such as two-phase interfacial polymerization, in-situ growth on substrate, unidirectional diffusion method, layer-by-layer assembly method, mixed matrix membranes, and so on. The advantages and disadvantages of each method are briefly summarized. The application potential of COF membrane in liquid separation are introduced from four aspects: dyeing wastewater treatment, heavy metal removal, seawater desalination and oil-water separation. Then, the mechanisms including pore structure, hydrophilic/hydrophobic, electrostatic repulsion/attraction and Donnan effect are introduced. For the efficient removal of different kind of pollutions, researchers can select different ligands to construct membranes with specific pore size, hydrophily, salt or organic rejection ability and functional group. The ideas for the design and preparation of COF membranes are introduced. Finally, the future direction and challenges of the next generation of COF membranes in the field of separation are prospected. [Display omitted] [ABSTRACT FROM AUTHOR]

Metal‐organic frameworks (MOFs) that exhibit dynamic phase‐transition behavior under external stimuli could have great potential in adsorptive separations. Here we report on a zinc‐based microporous MOF (JNU‐80) and its reversible transformation between two crystalline phases: large pore (JNU‐80‐LP) and narrow pore (JNU‐80‐NP). Specifically, JNU‐80‐LP can undergo a dehydration‐induced cluster consolidation under heat treatment, resulting in JNU‐80‐NP with a reduced channel that allows exclusion of di‐branched hexane isomers while high adsorption of linear and mono‐branched hexane isomers. We further demonstrate the fabrication of MOF‐polymer composite (JNU‐80‐NP‐block) and its application in the purification of di‐branched isomers from liquid‐phase hexane mixtures (98 % di‐branched) at room temperature, affording the di‐branched hexane isomers with 99.5 % purity and close to 90 % recovery rate over ten cycles. This work illustrates an interesting dehydration‐induced cluster consolidation in MOF structure and the ensuing channel shrinkage for sieving di‐branched hexane isomers, which may have important implications for the development of MOFs with dynamic behavior and their potential applications in non‐thermal driven separation technologies. [ABSTRACT FROM AUTHOR]

A technique has been proposed for measuring the contact angle of plastics, which makes it possible to determine the degree of wettability of their surface, on the basis of which assumptions can be made about the applicability of surfactants as wetting agents in the process of flotation separation of a mixture of plastics. The effect of aqueous solutions of surfactants on the contact angle and efficiency of flotation separation of a mixture of polybutelene terephthalate and acrylonitrile butadiene styrene was studied. The wettability of the surface of these plastics with aqueous solutions of sodium laureth-3 sulfosuccinate, sodium lauryl sarcosinate, polysorbate 80, and C8-C14 alkyl polyglucoside with a concentration of 2∙10–3–0.01 g/dm3 was determined. It has been found that the wettability of the surface of plastics with aqueous solutions of surfactants and the efficiency of floation separation of a mixture of plastics depend on the type of surfactants and their concentration in the aqueous solution. [ABSTRACT FROM AUTHOR]

The subject of this study was to compare the enantioseparation of fourteen racemic esters that are liquid crystals. This study aimed to determine the difference in the enantioseparation of mixtures with protonated and fluorinated aliphatic chains and those with different orders of occurrence of benzene rings (benzoates and biphenylates). This research was carried out on two chiral polysaccharide columns: amylose tris(3-chloro-5-methylphenylcarbamate) (ReproSil Chiral MIG) and cellulose tris(3,5-dichlorophenylcarbamate) (ReproSil Chiral MIC). The columns were evaluated in HPLC separation. The analyses were performed in the normal- and reversed-phase systems. The mobile phase consisted of different solvent systems (acetonitrile/water and n-hexane/2-propanol) in different volume ratios to select optimal separation conditions. The main parameter evaluated in separating racemic mixtures was the resolution—Rs. All measurements were performed at 25 °C. The elution order was also determined. The highest value of resolution (over 11) and selectivity (over 3) was obtained for the ReproSil Chiral MIG column and the volume ratio of ACN:H2O (95:5 v/v). [ABSTRACT FROM AUTHOR]

The importance of rare earth elements as a basis for the development of new technologies or the improvement of existing ones makes their recovery from raw and waste materials necessary. In this recovery, hydrometallurgy and its derivative solvometallurgy play key roles due to their operational characteristics, which are emphasized with the use of ionic liquids. This manuscript reviews the most recent advances (2023 and 2024) in the use of ionic liquids in unit operations (leaching and separation technologies) aimed at the recovery of these valuable and strategic metals. Moreover, a comprehensive review is presented of the use of these chemicals in the development of advanced materials containing some of these rare earth elements. [ABSTRACT FROM AUTHOR]

Experts have always been interested in mechanizing and improving agricultural operations due to the diverse and growing human needs. One of the processes in agricultural products is post-harvest operations. Transferring straw with a mechanized method uses a straw collector. During this process, there is a possibility of mixing gravel and other particles on the ground with the straw. These particles ultimately reduce the quality of the harvested straw. This study constructed and evaluated a laboratory cyclone to handle these challenges. The results of this study were conducted using a factorial experiment in a completely randomized design, with four gravel-to-straw ratios (3.5%, 5%, 10%, and 15%). The experiments were performed at three levels of cyclone inlet opening (1, 0.6, and 0.3), two heights of the vortex finder (0 and 15 cm), and two suction impellers (2574 and 2860 rpm). By performing three repetitions for each of the experiments, a total of 144 data were obtained. The cyclone performance was determined by calculating two separation efficiency factors: the percentage of the separated gravels and the percentage of straw separated from the mixture. The analysis of variance (ANOVA) and comparison of the means was performed using the Duncan post-test at a 5% probability level using SPSS software version 26. The obtained results showed that the cyclone inlet opening level was the most effective factor in the separation efficiency of gravel and straw. The highest separation efficiency occurred at a suction impeller frequency of 2860 rpm and a vortex finder position of zero. Also, the cyclone performance was maximum for gravel and straw ratios of 3.5% and 5%, respectively. [ABSTRACT FROM AUTHOR]

Copyright of China Brewing is the property of China Brewing Editorial Office and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Using a finite mixture regression approach, we identify two groups of individuals, family- and career-oriented. Depending on whether the employment status is treated as a binomial or trinomial (with part-time work) variable, 55–70% of women and 4–10% of men belong to the family-oriented group. Children variables are the main source of differences between the two identified groups and between the family-oriented group and the average woman. Treating all women as one group leads to averaged-out estimates of children effects and underestimates the importance of part-time work for family-oriented women. Our results are important for studying women's labour supply and for designing policies aimed at encouraging women's labour market involvement. [ABSTRACT FROM AUTHOR]

The mutual separation of Am and Cm is conducted using an alkyl-diamide amine (ADAAM(EH)) extractant. ADAAM(EH) exhibits an extremely high separation factor (SF) with respect to Am and Cm separation (SF = 5.9) in an HNO3-n-dodecane system. The batch-wise multistage extractions are performed using a system containing 0.2 M ADAAM(EH) and 1.5 M HNO3, with their distribution ratios (D) of the system for Am and Cm equal to 2.55 and 0.434, respectively. In this multistage extraction, 3 stages of feed, 9 stages involving scrubbing, and 11 stages involving the use of an organic solvent give 96.5% and 1.06% yields of Am and Cm, respectively. After the mutual separation, the aqueous and the organic phases including actinides increase four times in volume compared to the feed solution. Additional extraction steps are to reduce the volume of the solutions including actinides. We use tetraethyl diglycolamide (TEDGA)/water for Am concentration, tetraoctyl diglycolamide/n-dodecane for the intermediate extraction, and TEDGA/water for stripping in the Cm concentration step. Taking the additional steps, Am and Cm can be recovered in just two or three stages in the aqueous phases. [ABSTRACT FROM AUTHOR]

Due to the similarity and diversity among kinases, small molecule kinase inhibitors (SMKIs) often display multi-target effects or selectivity, which have a strong correlation with the efficacy and safety of these inhibitors. However, due to the limited number of well-known popular databases and their restricted data mining capabilities, along with the significant scarcity of databases focusing on the pharmacological similarity and diversity of SMIKIs, researchers find it challenging to quickly access relevant information. The KLIFS database is representative of specialized application databases in the field, focusing on kinase structure and co-crystallised kinase-ligand interactions, whereas the KLSD database in this paper emphasizes the analysis of SMKIs among all reported kinase targets. To solve the current problem of the lack of professional application databases in kinase research and to provide centralized, standardized, reliable and efficient data resources for kinase researchers, this paper proposes a research program based on the ChEMBL database. It focuses on kinase ligands activities comparisons. This scheme extracts kinase data and standardizes and normalizes them, then performs kinase target difference analysis to achieve kinase activity threshold judgement. It then constructs a specialized and personalized kinase database platform, adopts the front-end and back-end separation technology of SpringBoot architecture, constructs an extensible WEB application, handles the storage, retrieval and analysis of the data, ultimately realizing data visualization and interaction. This study aims to develop a kinase database platform to collect, organize, and provide standardized data related to kinases. By offering essential resources and tools, it supports kinase research and drug development, thereby advancing scientific research and innovation in kinaserelated fields. [ABSTRACT FROM AUTHOR]

Copyright of Baghdad Science Journal is the property of Republic of Iraq Ministry of Higher Education & Scientific Research (MOHESR) and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)