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1. Herbicidally Active Derivatives of Aminomethylenebis-Phosphonic Acid-Mode of Action and Structure - Activity Relationship

Author

Joanna Korf, Roman Gancarz, Giuseppe Forlani, Piotr Wieczorek, Hubert Wojtasek, Jadwiga Sołoducho, Bogdan Boduszek, Barbara Lejczak, Christophe Torreilles, Joanna Hafner, and Paweł Kafarski

Subjects
chemistry.chemical_classification, amino acid biosynthesis, biology, Stereochemistry, Organic Chemistry, (N-pyridylamino)methylenebisphosphonates, DAHP synthase, Biochemistry, Inorganic Chemistry, chemistry.chemical_compound, inhibitors, Enzyme, chemistry, Biosynthesis, biology.protein, Aromatic amino acids, Structure–activity relationship, Shikimate pathway, Mode of action
Abstract

(N-pyridylamino)methylenebisphosphonates exhibit strong herbicidal activity which may be reversed by supplementation of the growth media with aromatic amino acids. They appeare to be the inhibitors of aromatic amino acids biosynthesis acting as inhibitors of DAHP synthase the first enzyme of shikimate pathway. Over 40 analogues of these acids were synthesized in order to determine the structure-activity relationship.

Published
1996
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