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Dielectric elastomer generator (DEG), which consists of a dielectric elastomer (DE) film sandwiched between two flexible electrodes (FEs), has the advantages of lightweight, high energy density, and high energy conversion efficiency, providing a simple and feasible solution for harvesting energy from human motion or nature. As crucial constituents of DEG, FEs are expected to possess excellent conductivity and compliance. Nevertheless, there is currently no quantitative characterization method for FE compliance. In addition, the impact mechanism of FE compliance on the energy harvesting performance and fatigue life of the DEG remains unclear. In this study, the dynamic mechanical property (DMP) was used to assess the compliance of FEs, and the quantitative characterization method of FE compliance was proposed. A series of silicone rubber electrodes (SREs) with different DMPs and compliance were designed and prepared, and the impact mechanism of FE compliance on the energy harvesting stability and fatigue life of the DEG was investigated. The results indicate that the key to achieving excellent FE compliance lies in reducing the difference in the magnitude of the complex modulus and phase angle between the FEs and DE, which can significantly reduce interfacial friction and extend the fatigue life of DEG. Benefiting from the enhanced FE compliance, the fatigue life and full-life energy density of the DEG device increase by 20.3 times and 26.4 times, respectively, compared with those of the commonly used carbon-based electrodes.

Dielectric elastomer transducers (DETs), with a dielectric elastomer (DE) film sandwiched between two compliant electrodes, are highly sought after in the fields of soft robotics, energy harvesting, and human-machine interaction. To achieve a high-performance DET, it is essential to develop electrodes with high conductivity, strain-insensitive resistance, and adaptability. Herein, we design an electrode (Supra-LMNs) based on multiple dynamic bond cross-linked supramolecular networks (Ns) and liquid metal (LM), which realizes high conductivity (up to 16,000 S cm -1 ), negligible resistance changes at high strain (1.3-fold increase at 1000% strain), instantaneous self-healability at ambient temperature, and rapid recycling. The conductive pathway can be activated through simple friction by transmitting stress through the silver nanowires (AgNWs) and cross-linking sites of LM particles. This method is especially attractive for printing circuits on flexible substrates, especially DE films. Utilized as dielectric elastomer generator (DEG) electrodes, it reduces the charge loss by 3 orders of magnitude and achieves high generating energy density and energy conversion efficiency on a low-resistance load. Additionally, serving as sensor (DES) and actuator (DEA) electrodes, it enables a highly sensitive sensing capability and complex interaction.

Dielectric elastomer generators (DEGs) with high generated energy density and high conversion efficiency are of great interest. Among several dielectric elastomers (DEs), silicone elastomer filled with ceramic fillers have been extensively studied for their high elasticity, insulation, and permittivity. However, the stretched breakdown strength (E bs ) of such composites decreases significantly under large strain, thus sharply reduces its energy harvesting performances. In this study, a polar rubber-based dielectric (GNBR) is synthetized and creatively used as "soft filler" for silicone elastomer. Benefiting from the deformability under stretching and its inherent strong interface bonding with silicone elastomer, this soft filler effectively avoids the formation of weak interface under large strain and reduces the local field strength of interface area. As expected, the composite filled with soft filler (GNBR/PMVS) shows enhanced E bs of 2.8 times that of composite with traditional hard filler (TiO 2 /PMVS) under equibiaxial strain of 200%. As a result, GNBR/PMVS composite exhibits maximum energy density of 130.5 mJ g -1 with up-to-date highest power conversion efficiency of reported DEG (44.5%). The findings will provide new insights in the rational design of DE composites characterized by high stretched breakdown strength for advanced energy harvesting system., (© 2023 Wiley-VCH GmbH.)

Highly immiscible blend materials with distinctive and excellent properties play a key role in meeting the application needs, especially in extreme environments, and reactive nanoparticles are used to increase the interface adhesion and optimize the morphology of highly immiscible blending. However, these reactive nanoparticles tend to aggregate and even agglomerate during reactive blending, which significantly deteriorates their compatibilization efficiency. Herein, reactive Janus particles with the epoxy group and various siloxane molecular long chain grafting ratios (E-JP-PDMS) were synthesized using SiO 2 @PDVB Janus particles (JP) and used as compatibilizers for polyamide and methyl vinyl silicone elastomer (PA/MVQ) blends, which were highly immiscible. The effects of the structure of E-JP-PDMS Janus nanoparticles on their location at the interfaces between the PA and MVQ as well as their compatibilization efficiency for the PA/MVQ blends were investigated. The location and dispersion of E-JP-PDMS at the interfaces were improved by increasing the PDMS content in E-JP-PDMS. The average diameter of the MVQ domains of the PA/MVQ (70/30, w/w) was 79.5 μm and was reduced to 5.3 μm in the presence of 3.0 wt % of the E-JP-PDMS with 65 wt % PDMS. As a comparison, it was 45.1 μm in the presence of 3.0 wt % of a commercial compatibilizer (ethylene-butylacylate-maleic anhydride copolymer, denoted as EBAMAH), which provides a guideline for the design and preparation of efficient compatibilizers for highly immiscible polymer blends.

A dielectric composite with high dielectric constant, low dielectric loss and low percolation threshold was prepared by using the combined strategy of encapsulating of graphene oxide nanosheets (GONS) on carboxylated nitrile rubber (XNBR) latex particles and the in situ thermal reduction in GONS at a moderate temperature. The encapsulation of GONS on XNBR latex particles was mainly realized via the hydrogen bonding interactions between GONS and XNBR during latex mixing. A segregated graphene network was obtained at a low content of thermally reduced graphene (TRG), resulting in a low percolation threshold (0.25 vol.%). The dielectric constant at 100 Hz obviously increased from 23 for pure XNBR to 2211 and 5542 for the composite with 0.5 vol.% and 0.75 vol.% of TRG, respectively. The dielectric loss of the composites retained at a low value (less than 1.5). Meanwhile, the elastic modulus only slightly increased with the presence of 0.1-0.5 vol.% of TRG, keeping the good flexibility of the dielectric composites. This study provides a simple, low-cost and effective method to prepare high performance dielectric composites, facilitating the wide application of dielectric materials., (Copyright © 2014 Elsevier Inc. All rights reserved.)