Search

Zero-shot learning (ZSL) aims to predict unseen classes without using samples of these classes in model training. The ZSL has been widely used in many knowledge-based models and applications to predict various parameters, including categories, subjects, and anomalies, in different domains. Nonetheless, most existing ZSL methods require the pre-defined semantics or attributes of particular data environments. Therefore, these methods are difficult to be applied to general data environments, such as ImageNet and other real-world datasets and applications. Recent research has tried to use open knowledge to enhance the ZSL methods to adapt it to an open data environment. However, the performance of these methods is relatively low, namely the accuracy is normally below 10%, which is due to the inadequate semantics that can be used from open knowledge. Moreover, the latest methods suffer from a significant "semantic gap" problem between the generated features of unseen classes and the real features of seen classes. To this end, this paper proposes a multi-view graph representation with a similarity diffusion model, applying the ZSL tasks to general data environments. This model applies a multi-view graph to enhance the semantics fully and proposes an innovative diffusion method to augment the graph representation. In addition, a feature diffusion method is proposed to augment the multi-view graph representation and bridge the semantic gap to realize zero-shot predicting. The results of numerous experiments in general data environments and on benchmark datasets show that the proposed method can achieve new state-of-the-art results in the field of general zero-shot learning. Furthermore, seven ablation studies analyze the effects of the settings and different modules of the proposed method on its performance in detail and prove the effectiveness of each module., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 The Author(s). Published by Elsevier Ltd.. All rights reserved.)

Partial nitritation-anammox (PN/A) process is known as an energy-efficient technology for wastewater nitrogen removal, which possesses a great potential to bring wastewater treatment plants close to energy neutrality with reduced carbon footprint. To achieve this goal, various PN/A processes implemented in a single reactor configuration (one-stage system) or two separately dedicated reactors configurations (two-stage system) were explored over the past decades. Nevertheless, large-scale implementation of these PN/A processes for low-strength municipal wastewater treatment has a long way to go owing to the low efficiency and effectiveness in nitrogen removal. In this work, we provided a comprehensive analysis of one-stage and two-stage PN/A processes with a focus on evaluating their engineering application potential towards mainstream implementation. The difficulty for nitrite-oxidizing bacteria (NOB) out-selection was revealed as the critical operational challenge to achieve the desired effluent quality. Additionally, the operational strategies of low oxygen commonly adopted in one-stage systems for NOB suppression and facilitating anammox bacteria growth results in a low nitrogen removal rate (NRR). Introducing denitrification into anammox system was found to be necessary to improve the nitrogen removal efficiency (NRE) by reducing the produced nitrate with in-situ utilizing the organics from wastewater itself. However, this may lead to part of organics oxidized with additional oxygen consumed in one-stage system, further compromising the NRR. By applying a relatively high dissolved oxygen in PN reactor with residual ammonium control, and followed by a granules-based anammox reactor feeding with a small portion of raw municipal wastewater, it appeared that two-stage system could achieve a good effluent quality as well as a high NRR. In contrast to the widely studied one-stage system, this work provided a unique perspective that more effort should be devoted to developing a two-stage PN/A process to evaluate its application potential of high efficiency and economic benefits towards mainstream implementation., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

Sulfide and methane production are a major concern in sewer management. Many solutions with the use of chemicals have been proposed yet incurring huge costs. Here, this study reports an alternative solution to reduce sulfide and methane production in sewer sediments. This is achieved through integration of urine source separation, rapid storage, and intermittent in situ re-dosing into a sewer. Based on a reasonable capacity of urine collection, an intermittent dosing strategy (i.e. 40 min per day) was designed and then experimentally tested using two laboratory sewer sediment reactors. The long-term operation showed that the proposed urine dosing in the experimental reactor effectively reduced sulfidogenic and methanogenic activities by 54% and 83%, compared to those in the control reactor. In-sediment chemical and microbial analyses revealed that the short-term exposure to urine wastewater was effective in suppressing sulfate-reducing bacteria and methanogenic archaea, particularly within a surface active zone of sediments (0-0.5 cm) likely attributed to the biocidal effect of urine free ammonia. Economic and environmental assessments indicated that the proposed urine approach can save 91% in total costs, 80% in energy consumption and 96% in greenhouse gas emissions compared to the conventional use of chemicals (including ferric salt, nitrate, sodium hydroxide, and magnesium hydroxide). These results collectively demonstrated a practical solution without chemical input to improve sewer management., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

The waste activated sludge (WAS) of wastewater treatment system is often rich in phosphorus (P), which is a basic element of human life and could use up in the near future. This study proposed an integrated approach to efficiently recover P as vivianite from WAS and simultaneously enhance the sludge dewaterability. The raw WAS was first acidified using FeCl 3 , which was then fed to anaerobic fermenter for Fe 3+ reduction. After fermentation, a technology named acid-elutriation was introduced to convert Fe and P from solid phase to liquid phase and concomitantly enhance the liquor-solid separation. Finally, vivianite was obtained via sludge eluate neutralization. The enhanced sludge dewaterability not only increases the recovery efficiency of Fe and P but also decreases the cost of sludge disposal., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 The Author(s). Published by Elsevier Ltd.. All rights reserved.)

The acidic (i.e., pH ∼5) activated sludge process is attracting attention because it enables stable nitrite accumulation and enhances sludge reduction and stabilization, compared to the conventional process at neutral pH. Here, this study examined the production and potential pathways of nitric oxide (NO) and nitrous oxide (N 2 O) during acidic sludge digestion. With continuous operation of a laboratory-scale aerobic digester at high dissolved oxygen concentration (DO>4 mg O 2 L -1 ) and low pH (4.7±0.6), a significant amount of total nitrogen (TN) loss (i.e., 18.6±1.5% of TN in feed sludge) was detected. Notably, ∼40% of the removed TN was emitted as NO, with ∼8% as N 2 O. A series of batch assays were then designed to explain the observed TN loss under aerobic conditions. All assays were conducted with a low concentration of volatile solids (VS), i.e., VS<4.5 g L -1 . This VS concentration is commensurate with the values commonly found in the aeration tanks of full-scale wastewater treatment systems, and thus no significant nitrogen loss should be expected when DO is controlled above 4 mg O 2 L -1 . However, nitrite disappeared at a significant rate (with the chemical decomposition of nitrite excluded), leading to NO production in the batch assays at pH 5. The nitrite reduction could be associated with endogenous microbial activities, e.g., nitrite detoxification. The significant NO production illustrates the importance of aerobic nitrite reduction during acidic aerobic sludge digestion, suggesting this process cannot be neglected in developing acidic activated sludge technology., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

Mainstream nitrogen removal via anammox is widely recognized as a promising wastewater treatment process. However, its application is challenging at large scale due to unstable suppression of nitrite-oxidizing bacteria (NOB). In this study, a pilot-scale mainstream anammox process was implemented in an Integrated Fixed-film Activated Sludge (IFAS) configuration. Stable operation with robust NOB suppression was maintained for over one year. This was achieved through integration of three key control strategies: i) low dissolved oxygen (DO = 0.4 ± 0.2 mg O 2 /L), ii) regular free nitrous acid (FNA)-based sludge treatment, and iii) residual ammonium concentration control (NH 4 + with a setpoint of ∼8 mg N/L). Activity tests and FISH demonstrated that NOB barely survived in sludge flocs and were inhibited in biofilms. Despite receiving organic-deficient wastewater from a pilot-scale High-Rate Activated Sludge (HRAS) system as the feed, the system maintained a stable effluent total nitrogen concentration mostly below 10 mg N/L, which was attributed to the successful retention of anammox bacteria. This study successfully demonstrated large-scale long-term mainstream anammox application and generated new practical knowledge for NOB control and anammox retention., Competing Interests: The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (© 2023 The Author(s).)

With the growing concern of global warming, many water utilities are pioneering in mitigating greenhouse gas (GHG) emissions, with some water utilities aiming to achieve net-zero emissions operation in the next decade. However, for wastewater treatment plants (WWTPs), the carbon footprint of different treatment technologies and its contribution among various units within each treatment configuration is still unclear. This study evaluates the impacts of process design on the carbon footprint of WWTPs through the analysis of scope 1 (direct emission), scope 2 (indirect emission), and scope 3 (value chain emission) emissions. The comprehensive configuration design in this work considered three nutrient removal processes including typical aerobic and anaerobic wastewater treatment technologies. Emissions from the sludge management processes are also calculated, including aerobic and anaerobic sludge stabilization processes, short-term and long-term sludge storage, and three sludge disposal options. In total, 45 processes were analysed and the results were compared. The results showed the carbon footprints are highly dependent on the treatment configurations of WWTPs. Analysis suggested scope 2 & 3 emissions can be reduced by selecting suitable processes. In general, anaerobic wastewater and sludge stabilization technologies are more suitable than aerobic technologies to reduce scope 2 & 3 emissions, leading to a lower overall carbon footprint. In comparison, configuration design offers limited opportunities to reduce scope 1 emissions, which may be the future challenge for WWTP to achieve carbon neutrality., (Copyright © 2022. Published by Elsevier Inc.)

As a promising energy- and carbon efficient process for nitrogen removal from wastewater, mainstream nitrite shunt has been extensively researched. However, beyond the laboratory it is challenging to maintain stable performance by suppressing nitrite-oxidising bacteria (NOB). In this study, a pilot-scale reactor system receiving real sewage was operated in two stages for >850 days to evaluate two novel NOB suppression strategies for achieving nitrite shunt: i) sidestream sludge treatment based on alternating free nitrous acid (FNA) and free ammonia (FA) and ii) sidestream FNA/FA sludge treatment integrated with in-situ NOB suppression via step-feed. The results showed that, with sidestream sludge treatment alone, NOB developed resistance relatively quickly to the treatment, leading to unstable nitrite shunt. In contrast, robust nitrite shunt was achieved and stably maintained for more than a year when sidestream sludge treatment was integrated with a step-feed strategy. Kinetic analyses suggested that sludge treatment and step-feed worked in synergy, leading to stable NOB suppression. The integrated strategy demonstrated in this study removes a key barrier to the implementation of stable mainstream nitrite shunt., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022. Published by Elsevier Ltd.)

Buffer capacity is a critical parameter in sludge management of domestic wastewater treatment plants that determines acid/base usage. It is here shown that gravity settling or centrifugation significantly increased the buffer capacity in the supernatant of the sludge. The sludge thickening considerably elevated the total alkalinity of the sludge from 16.0 to 31.5 mgCaCO 3 taking pH 5.0 for example with the sludge concentration times increasing from 2 to 20 times, while insignificantly affected the total acidity (initial 335.3 vs 240.2 mgCaCO 3 at concentration times of 10 considering pH increased to 11.0). These findings indicate that the inherent buffer in sludge can be released during sludge thickening and the primary component of this buffer is alkalinity. The released buffer may be correlated to a negative surface charge inside sludge flocs, as it consumed base in titration. The increased buffer capacity in supernatant could be due to the buffer released from bound water to free water, and in particular, from the release of interstitial water, an important part of the bound water. Further mechanism analysis suggested that the increased buffer capacity in thickened sludge could relate to extracellular polymeric substances, for which more studies are needed. Overall, this study for the first time reports that sludge thickening can change the buffer capacity of sludge, affecting the efficiency and acid/base usage of sludge treatment., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

Free Nitrous Acid (FNA) pre-treatment is a promising technology demonstrated effective in improving waste activated sludge degradability and anaerobic digestion (AD) performance. Pre-treatment conditions including FNA concentration and treatment duration determine operational and capital cost of full-scale implementation, which have not been studied in long-term experiments. The knowledge of FNA pre-treatment conditions improving the AD performance is urgently required to determine suitable conditions for the technology implementation. In this work, five different FNA concentrations (2.2, 4.4, 7.2, 12 mgN/L and nitrite only without pH adjustment) and three treatment durations (8, 24 and 48 h) were studied in four lab-scale semi-continuous AD reactors for over 300 days. FNA pre-treatment was shown under all tested conditions effective in enhancing AD performances, while its effectiveness and resulted benefits varied substantially amongst different pre-treatment conditions. The long-term experiment demonstrated that the methane production, sludge reduction and digested sludge viscosity of AD are positively correlated with the FNA concentration and durations, until an optimal condition is reached, which was identified in this work to be FNA concentration of 7.2 mgN/L and treatment duration of 24 h. Microbial community changes supported the apparent observation of enhanced sludge degradation at elevating FNA concentrations applied during pre-treatment. The short-term sludge solubilization results were inconsistent with the long-term AD performance, which was potentially caused by inhibitions from stringent FNA pre-treatment conditions applied (FNA = 12 mgN/L with 24-hour treatment & FNA = 7.2 mgN/L with 48-hour treatment). Overall, results suggested FNA pre-treatment at the optimized condition is highly beneficial to WWTPs and competitive with other pre-treatment technologies, e.g., thermal hydrolysis pre-treatment. This work comprehensively evaluated the key design parameters of FNA pre-treatment process, reached a major milestone in the development and applications of FNA technologies., (Copyright © 2021. Published by Elsevier Ltd.)

Biological nitrogen (N) removal via the short-cut pathway (NH 4 + -N→NO 2 - -N→N 2 ) is economically attractive in wastewater treatment plants (WWTPs). However, biological phosphorus (P) removal processes remain a bottleneck in these systems due to the strong inhibitory effect of nitrite or its protonated form (HNO 2 , free nitrous acid - FNA) on polyphosphate accumulating organisms (PAOs). In this study, a novel combined nitrogen and phosphorus removal strategy was verified and achieved in a biological short-cut nitrogen removal system via side-stream sludge treatment with FNA, and the mechanisms impacting this process were investigated. The side-stream FNA treatment process applied here led to a significant reduction in the real sludge retention time (SRT) in the mainstream (approximately 2.7 days) based on the biocidal effect of FNA to the majority of the organisms. This work also found that around 40% of the P uptake activity was still maintained at a much higher FNA level of 38 μg N/L with potential PAOs, which highly broadened the current knowledge of PAOs community. An economic analysis revealed advantages of the proposed as compared to conventional biological nitrogen and phosphorus removal (13% savings in total cost), biological short-cut nitrogen removal (via FNA treatment) with chemical phosphorus precipitation (21% savings) and conventional biological nitrogen removal with chemical precipitation (27% savings). Overall, this study presents a novel and viable retrofit strategy in integrating biological short-cut nitrogen removal with EBPR for next generation WWTPs., (Copyright © 2021. Published by Elsevier Ltd.)

Iron salts (i.e. FeCl 3 ) are the most used chemicals in the urban wastewater system. Iron is commonly dosed into sewage or the mainstream system, which provides multiple benefits such as enhanced phosphorus removal and improved sludge settleability/dewaterability. This study reported and demonstrated a new approach that dosed FeCl 3 into returned sludge in order to bring two more benefits to wastewater management: short-cut nitrogen removal via the nitrite pathway and less biomass production. This approach is achieved based on our findings that with similar amount of FeCl 3 , centralized iron dosing into a sidestream sludge unit generated iron concentration two orders of magnitude higher than the common mainstream dosing (e.g. 10-40 mg Fe/L-wastewater), leading to sludge acidification (pH = 2.1) with Fe (III) hydrolysis. Together with accumulated nitrite in the supernatant of the sludge, ppm-level of free nitrous acid was generated and thus enabled sludge disintegration, cell lysis, and selective elimination of nitrite-oxidizing bacteria (NOB). Long-term effects on nitrifying bacteria and overall reactor performance were evaluated using two laboratory reactor experiments for over one year. The experimental reactor showed stable nitrite accumulation with an average NO 2 - /(NO 2 -  + NO 3 - ) ratio above 80% and ∼30% observed biomass yield reduction compared to those in control reactors. In addition, the centralized sludge dosing strategy still provided benefits such as improved settleability and dewaterability of sludge and enhanced phosphorus removal., (Copyright © 2021. Published by Elsevier Ltd.)

Anaerobic digestion (AD) is an essential process in wastewater treatment plants as it can reduce the amount of waste activated sludge (WAS) for disposal, and also enables the recovery of bioenergy (i.e. methane). Here, a new pretreatment method to enhance anaerobic digestion was achieved by treating thickened WAS (TWAS) with ferric (as FeCl 3 ) and nitrite simultaneously for 24-hour at room temperature. Biochemical methane potential tests showed markedly improved degradability in the pretreated TWAS, with a relative increase in hydrolysis rate by 30%. A comparative experiment with the operation of two continuous-flow anaerobic digesters further demonstrated the improvement in biogas quantity and quality, digestate disposal, and phosphorus recovery in the experimental digester. The dosed FeCl 3 (i.e. ~6 mM) decreased the pH of TWAS to ~5, which led to the formation of free nitrous acid (FNA, HNO 2 ) at parts per million levels (i.e. ~6 mg N/L), after dosing nitrite at 250 mg NO 2 - -N/L. This FNA treatment caused a 26% increase in methane yield and volatile solids destruction, 55% reduction in the viscosity of sludge in digester, and 24% less polymer required in further digestate dewatering. In addition, the dosed Fe(III) was reduced to Fe(II) which precipitated sulfide and phosphorus, leading to decreased hydrogen sulfide concentration in biogas, and increased percentage of vivianite in the total crystalline iron species in digested sludge. Our study experimentally demonstrated that combined dosing of FeCl 3 and nitrite is a useful pretreatment strategy for improving anaerobic digestion of WAS., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021. Published by Elsevier Ltd.)