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α-MnO 2 has been recognized as a potential material for supercapacitor applications because of its abundance, cost-effectiveness, environmental-benign nature and high theoretical specific capacitance ( C sp ) of 1370 F g -1 . In this study, we succeeded for the first time to achieve the theoretical C sp with 3D multi-walled carbon nanotubes (MWCNTs) horizontally dispersed on 2D graphene oxide (GO) nanosheet framework-supported MnO 2 ternary nanocomposites synthesized by a simple precipitation method. The in situ formation of α-MnO 2 and GO, and the growth of 3D MWCNT/GO framework took place simultaneously in a strong acidic suspension containing functionalized-MWCNTs, graphite, NaNO 3 and KMnO 4 . Characterizations of the composites synthesized by varying % wt MWCNTs were performed with state-of-the-art techniques. These composites were characterized to be semi-crystalline and mesoporous in nature, and the scrupulous analyses of field emission scanning electron microscopic images showed MnO 2 nano-flower distributed over 3D MWCNTs dispersed-on-GO-nanosheet frameworks. These composites deposited on a graphite electrode exhibited an ideal supercapacitive behavior in an Na 2 SO 4 solution measured via cyclic voltammetry and chronopotentiometry. Optimum contents of MnO 2 and MWCNTs in the composites showed a maximum C sp of 1380 F g -1 with satisfactory energy and power densities compared in the Ragone plot. An ascending trend of C sp against the charge-discharge cycle number studied for 700 cycles was noticed. Well-dispersion of α-MnO 2 nanoparticles throughout 3D MWCNTs covalently-anchored to the GO nanosheet framework is discussed to aid in achieving the frontier C sp of MnO 2 ., Competing Interests: There are no conflicts to declare., (This journal is © The Royal Society of Chemistry.)