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The high-temperature superconducting Maglev-evacuated tube transport (HTS Maglev-ETT) system has significant potential for practical applications. In order to employ HTS bulks in an ETT system, it is necessary to study the magnetic levitation and guidance performance of bulk superconductors under low ambient pressure conditions that are representative of those inside the tube. As a result, we have investigated the Maglev performance of Y–Ba–Cu–O (YBCO) and Gd–Ba–Cu–O (GdBCO) single grain, bulk superconductors under different ambient pressures of 100 kPa, 60 kPa and 20 kPa using a bespoke pressure-controlling platform, in which the superconductors were positioned above a Halbach permanent magnet guideway. The levitation forces under conditions of field-cooling (FC) and zero-field-cooling (ZFC) have been measured and analyzed. The guidance force for the FC case and the levitation force relaxation for the ZFC case were also measured. It was found from the experimental results that the Maglev performance of both types of bulk superconductor improves significantly by reducing the ambient pressure in their immediate working environment. The levitation forces of YBCO and GdBCO bulk superconductors were observed to increase by 11.6% and 4.4% in the case of FC, and by 20.3% and 13.7% in the case of ZFC, respectively, as the ambient pressure changed from 100 kPa to 20 kPa. An improvement of the guidance force and an inhibition of the levitation force relaxation were also observed for these materials. The supercooled liquid nitrogen cryogen in the low-pressure environment further reduces the temperature, which, in turn, increases the critical current density Jc of the bulk superconductors and improves their levitation performance. These results provide further evidence of the significant advantages of combining HTS Maglev with evacuated tube technologies as a key enabling feature of the HTS Maglev-ETT system. The data further indicate that YBCO bulk superconductors tend to be more sensitive to ambient pressure and temperature variation than GdBCO bulk superconductors. This difference essentially reflects the dependence of Maglev performance of HTS bulk superconductors on Jc when operating in a low-pressure environment. [ABSTRACT FROM AUTHOR]

Bulk, single grain (RE)Ba2Cu3O7−δ [(RE)BCO, where RE is a rare earth element or yttrium] high temperature superconductors exhibit significant potential for use in a variety of engineering applications due to their ability to trap large magnetic fields, which can be up to ten times greater than those generated by conventional, iron-based magnets. Limitations on the maximum size to which single grains can be grown, however, are a major obstacle to the further development of these materials. Indeed, multiple samples are often required to achieve the required superconducting properties in particular applications. The geometry of bulk (RE)BCO single grain samples plays an important role in determining the superconducting properties of a given technical arrangement. In order to gain a better understanding of the full application potential of bulk single grain superconductors, three relatively long, cylindrical YBCO single grains of different diameters were fabricated and their trapped field and total trapped flux measured at 77 K as a function of sample height. The effects of size and aspect ratio of YBCO single grains on these key applied properties have been investigated experimentally and the results compared qualitatively with the predictions of an established theoretical model. Conclusions based on the trapped field measurements on a variety of single grain samples are presented in this study and the possibilities of using assemblies of smaller samples for engineering devices, in particular, are discussed. [ABSTRACT FROM AUTHOR]

The two-step top seeded infiltration and growth (TSIG) melt process has emerged as a successful and reliable technique for the fabrication of single grain (RE)Ba2Cu3O7−δ (where RE is a rare-earth element or yttrium) bulk high temperature superconductors with engineered microstructures that exhibit improved superconducting properties. In this study, the performance of these materials in large applied magnetic fields has been investigated by field cooling single grain samples in a magnetic field of 18 T. YBa2Cu3O7−δ samples processed without added Ag by the TSIG technique, in the two-sample stack configuration, trapped a magnetic field of 14.3 T at 28 K after field cooling from 100 K and subsequent removal of the applied field. This result is particularly significant in that, previously, only single grain (RE)Ba2Cu3O7−δ bulk superconductors containing Ag have been reported to be able to tolerate the large stresses on the samples inherent in the magnetisation process at large fields. The samples prepared in the present study were pre-stressed using a reinforcing stainless-steel ring, although, otherwise, they did not contain any additives, dopants or resin impregnation. The ability of samples processed by TSIG to withstand large tensile forces without Ag addition is attributed to the reduced incidence of intrinsic cracks/pores in the single grain microstructure. [ABSTRACT FROM AUTHOR]

Magnetisation is one of the main barriers to practical use of bulk superconductors as high field magnets. Recently several authors have reported a flux jump effect that allows penetration of magnetic flux into a bulk superconductor during pulsed field magnetisation (PFM) at lower fields than that would be predicted on the basis of the Bean model. We have systematically investigated macroscopic flux jumps in single grain GdBa2Cu3O7−δ–Ag (GdBCO–Ag) bulk superconductors with diameters of up to 30 mm when subjected to pulsed magnetic fields. Flux jumps were observed at temperatures between 30 and 77 K and in applied magnetic fields of up to 7 T. The applied pulsed field required to trigger the instability or flux jump field, Bj, was determined experimentally and found to increase with decreasing temperature. An extended instability criterion based on a 2D axisymmetric model was used to predict Bj at various temperatures and the results are in good agreement with experiments. A significant temperature rise has been measured experimentally during the magnetisation process which indicates that local heat generation due to the sharp rise of the applied field in the PFM process is the primary cause of the flux jumps. The experimental results suggest further that the critical current density reduces to almost zero in the warm part of the sample during the short period of non-equilibrium. A peak trapped field of 4.1 T at the surface and 5.3 T between a stack of two GdBCO–Ag bulk superconductors was achieved at 30 K by means of an optimised two-step pulse sequence with the assistance of the flux jumps, which is extremely promising for potential applications of these technologically important materials. [ABSTRACT FROM AUTHOR]

Progress in superconducting bulk materials has been somewhat overshadowed by the considerable effort required to produce practical long-length conductors. There has, however, been steady progress in both the materials science of bulk superconducting materials and the technologies required to use them effectively in engineering applications. In particular, magnetised bulk superconductors are capable of acting as quasi-permanent magnets with the potential of providing magnetic fields of several tesla or greater from a small volume of material, they can act as magnetic shields and they can provide self-stabilised levitation. This roadmap, based on a workshop which involved the participation of a wide range of academic and industrial participants (see doi: 10.17863/CAM.586 for details of the workshop methodology), aims to explore some of the key potential domains of application of bulk superconductors. Detailed technological roadmaps are presented for four key applications that were identified as providing both good market opportunity and feasibility. These are: portable systems for bulk superconductivity; portable, high-field magnet systems for medical devices; ultra-light superconducting rotating machines for next-generation transport & power applications; and magnetic shielding applications for electric machines, equipment and other high-field devices. [ABSTRACT FROM AUTHOR]

Large, single grain (RE)Ba2Cu3O7 (where RE is a rare-earth element or yttrium) high temperature superconductors are technologically important materials due to their ability to trap large magnetic fields and to provide stable magnetic levitation for a number of potential high field applications. The fabrication of samples in the large singe grain form is a challenge, however, due to the characteristic slow growth rate of these materials and the need to produce samples that are electrically well-connected in order to generate trapped magnetic fields that are significantly greater than those produced by conventional permanent magnets (PM). In this work, we investigate whether large, single grain samples are optimum for the generation of high levitation forces for engineering applications. Three large bar-shaped Y–Ba–Cu–O samples of dimensions 60 × 20 × 12 mm3 were prepared for this investigation, including one single-seeded, one multi-seeded and one consisting of three square samples packed together closely in an array. The processing of these samples is described and their trapped field and levitation performance at 77 K measured using different PM arrays. We find that the multi-seeded samples and those assembled from smaller, individual bulk superconductors are able to achieve a higher levitation force than an equivalent single seed sample arrangement, at least in some geometries. This result is significant in that it suggests clearly that it is not always necessary to fabricate bulk (RE)BCO superconductors in the form of very large single grains for levitation applications, although the specific configuration of the system does need to be considered on an application-by-application basis. [ABSTRACT FROM AUTHOR]

Bulk, single grains of RE–Ba–Cu–O [(RE)BCO] high temperature superconductors have significant potential for a wide range of applications, including trapped field magnets, energy storage flywheels, superconducting mixers and magnetic separators. One of the main challenges in the production of these materials by the so-called top seeded melt growth technique is the reliable seeding of large, single grains, which are required for high field applications. A chemically aggressive liquid phase comprising of BaCuO2 and CuO is generated during the single grain growth process, which comes into direct contact with the seed crystal either instantaneously or via infiltration through a buffer pellet, if employed in the process. This can cause either partial or complete melting of the seed, leading subsequently to growth failure. Here, the underlying mechanisms of seed crystal melting and the role of seed porosity in the single grain growth process are investigated. We identify seed porosity as a key limitation in the reliable and successful fabrication of large grain (RE)BCO bulk superconductors for the first time, and propose the use of Mg-doped NdBCO generic seeds fabricated via the infiltration growth technique to reduce the effects of seed porosity on the melt growth process. Finally, we demonstrate that the use of such seeds leads to better resistance to melting during the single grain growth process, and therefore to a more reliable fabrication technique. [ABSTRACT FROM AUTHOR]

We report that the dynamic levitation force of bulk high temperature superconductors (HTS) in motion attenuates when exposed to an inhomogeneous magnetic field. This phenomenon has significant potential implications for the long-term stability and running performance of HTS in maglev applications. In order to suppress the attenuation of the levitation force associated with fluctuations in magnetic field, we compare the dynamic levitation performance of single grain Y–Ba–Cu–O (YBCO) and Gd–Ba–Cu–O (GdBCO) bulk superconductors with relatively high critical current densities. A bespoke HTS maglev dynamic measurement system (SCML-03) incorporating a rotating circular permanent magnet guideway was employed to simulate the movement of HTS in a varying magnetic field at different frequencies (i.e. speed of rotation). The attenuation of the levitation force during dynamic operation, which is key parameter for effective maglev operation, has been evaluated experimentally. It is found that GdBCO bulk superconductors that exhibit superior levitation force properties are more able to resist the attenuation of levitation force compared with YBCO bulk materials under the same operating conditions. This investigation indicates clearly that GdBCO bulk superconductors can play an important role in suppressing attenuation of the levitation force, therefore improving the long-term levitation performance under dynamic operating conditions. This result is potentially significant in the design and application of HTS in maglev systems. [ABSTRACT FROM AUTHOR]

The use of RE-Ba–Cu–O [(RE)BCO] bulk superconductors, where RE = Y, Gd, Sm, in practical applications is, at least in part, limited by their mechanical properties and brittle nature, in particular. Alloying these materials with silver, however, produces a significant improvement in strength without any detrimental impact on their superconducting properties. Unfortunately, the top seeded melt growth technique, used routinely to process bulk (RE)BCO superconductors in the form of large, single grains required for practical applications, is complex and has a large number of inter-related variables, so the addition of silver increases the complexity of the growth process even further. This can make successful growth of this system extremely challenging. Here we report measurements of the growth rate of YBCO-Ag fabricated using a new growth technique consisting of continuous cooling and isothermal hold process. The resulting data form the basis of a model that has been used to derive suitable heating profiles for the successful single grain growth of YBCO-Ag bulk superconductors of up to 26 mm in diameter. The microstructure and distribution of silver within these samples have been studied in detail. The maximum trapped field at the top surface of the bulk YBCO-Ag samples has been found to be comparable to that of standard YBCO processed without Ag. The YBCO-Ag samples also exhibit a much more uniform trapped field profile compared to that of YBCO. [ABSTRACT FROM AUTHOR]

Most established top seeded melt growth (TSMG) processes of bulk, single grain Y–Ba–Cu–O (YBCO) superconductors are performed using a mixture of pre-reacted precursor powders. Here we report the successful growth of large, single grain YBCO samples by TSMG with good superconducting properties from a simple precursor composition consisting of a sintered mixture of the raw oxides. The elimination of the requirement to synthesize precursor powders in a separate process prior to melt processing has the potential to reduce significantly the cost of bulk superconductors, which is essential for their commercial exploitation. The growth morphology, microstructure, trapped magnetic field and critical current density, Jc, at different positions within the sample and maximum levitation force of the YBCO single grains fabricated by this process are reported. Measurements of the superconducting properties show that the trapped filed can reach 0.45 T and that a zero field Jc of 2.5 × 104 A cm−2 can be achieved in these samples. These values are comparable to those observed in samples fabricated using pre-reacted, high purity commercial oxide precursor powders. The experimental results are discussed and the possibility of further improving the melt process using raw oxides is outlined. [ABSTRACT FROM AUTHOR]

A major limitation to the widespread application of Y–Ba–Cu–O (YBCO) bulk superconductors is the relative complexity and low yield of the top seeded melt growth (TSMG) process, by which these materials are commonly fabricated. It has been demonstrated in previous work on the recycling of samples in which the primary growth had failed, that the provision of an additional liquid-rich phase to replenish liquid lost during the failed growth process leads to the reliable growth of relatively high quality recycled samples. In this paper we describe the adaptation of the liquid phase enrichment technique to the primary TSMG fabrication process. We further describe the observed differences between the microstructure and superconducting properties of samples grown with additional liquid-rich phase and control samples grown using a conventional TSMG process. We observe that the introduction of the additional liquid-rich phase leads to the formation of a higher concentration of Y species at the growth front, which leads, in turn, to a more uniform composition at the growth front. Importantly, the increased uniformity at the growth front leads directly to an increased homogeneity in the distribution of the Y-211 inclusions in the superconducting Y-123 phase matrix and to a more uniform Y-123 phase itself. Overall, the provision of an additional liquid-rich phase improves significantly both the reliability of grain growth through the sample thickness and the magnitude and homogeneity of the superconducting properties of these samples compared to those fabricated by a conventional TSMG process. [ABSTRACT FROM AUTHOR]

SmBa2Cu3O7−δ (Sm-123) is a light-rare-earth barium-cuprate (LRE-BCO) high-temperature superconductor (HTS) with significant potential for high field industrial applications. We report the fabrication of large, single grain bulk [Sm–Ba–Cu–O (SmBCO)] superconductors containing 1 wt% CeO2 and 0.1 wt% Pt using a top-seeded melt growth process. The performance of the SmBCO bulk superconductors containing the different dopants was evaluated based on an analysis of their superconducting properties, including critical transition temperature, Tc and critical current density, Jc , and on sample microstructure. We find that both CeO2 and Pt dopants refine the size of Sm2BaCuO5 (Sm-211) particles trapped in the Sm-123 superconducting phase matrix, which act as effective flux pinning centres, although the addition of CeO2 results in broadly improved superconducting performance of the fully processed bulk single grain. However, 1 wt% CeO2 is significantly cheaper than 0.1 wt% Pt, which has clear economic benefits for use in medium to large scale production processes for these technologically important materials. Finally, the use of CeO2 results generally in the formation of finer Sm-211 particles and to the generation of fewer macro-cracks and Sm-211 free regions in the sample microstructure. [ABSTRACT FROM AUTHOR]

A fundamental requirement of the fabrication of high performing, (RE)–Ba–Cu–O bulk superconductors is achieving a single grain microstructure that exhibits good flux pinning properties. The top seeded melt growth (TSMG) process is a well-established technique for the fabrication of single grain (RE)BCO bulk samples and is now applied routinely by a number of research groups around the world. The introduction of a buffer layer to the TSMG process has been demonstrated recently to improve significantly the general reliability of the process. However, a number of growth-related defects, such as porosity and the formation of micro-cracks, remain inherent to the TSMG process, and are proving difficult to eliminate by varying the melt process parameters. The seeded infiltration and growth (SIG) process has been shown to yield single grain samples that exhibit significantly improved microstructures compared to the TSMG technique. Unfortunately, however, SIG leads to other processing challenges, such as the reliability of fabrication, optimisation of RE2BaCuO5 (RE-211) inclusions (size and content) in the sample microstructure, practical oxygenation of as processed samples and, hence, optimisation of the superconducting properties of the bulk single grain. In the present paper, we report the development of a near-net shaping technique based on a novel two-step, buffer-aided top seeded infiltration and growth (BA-TSIG) process, which has been demonstrated to improve greatly the reliability of the single grain growth process and has been used to fabricate successfully bulk, single grain (RE)BCO superconductors with improved microstructures and superconducting properties. A trapped field of ∼0.84 T and a zero field current density of 60 kA cm−2 have been measured at 77 K in a bulk, YBCO single grain sample of diameter 25 mm processed by this two-step BA-TSIG technique. To the best of our knowledge, this value of trapped field is the highest value ever reported for a sample fabricated by an infiltration and growth process. In this study we report the successful fabrication of 14 YBCO samples, with diameters of up to 32 mm, by this novel technique with a success rate of greater than 92%. [ABSTRACT FROM AUTHOR]

Bulk (RE)–Ba–Cu–O ((RE)BCO, where RE stands for rare-earth), single grain superconductors can trap magnetic fields of several tesla at low temperatures and therefore can function potentially as high field magnets. Although top seeded melt growth (TSMG) is an established process for fabricating relatively high quality single grains of (RE)BCO for high field applications, this technique suffers from inherent problems such as sample shrinkage, a large intrinsic porosity and the presence of (RE)2BaCuO5 (RE-211)-free regions in the single grain microstructure. Seeded infiltration and growth (SIG), therefore, has emerged as a practical alternative to TSMG that overcomes many of these problems. Until now, however, the superconducting properties of bulk materials processed by SIG have been inferior to those fabricated using the TSMG technique. In this study, we identify that the inferior properties of SIG processed bulk superconductors are related to the presence of a relatively large Y-211 content (∼41.8%) in the single grain microstructure. Controlling the RE-211 content in SIG bulk samples is particularly challenging because it is difficult to regulate the entry of the liquid phase into the solid RE-211 preform during the infiltration process. In an attempt to solve this issue, we have investigated the effect of careful control of both the infiltration temperature and the quantity of liquid phase powder present in the sample preforms prior to processing. We conclude that careful control of the infiltration temperature is the most promising of these two process variables. Using this knowledge, we have fabricated successfully a YBCO bulk single grain using the SIG process of diameter 25 mm that exhibits a trapped field of 0.69 T at 77 K, which is the largest value reported to date for a sample fabricated by the SIG technique. [ABSTRACT FROM AUTHOR]

Reliable seeding of the superconducting (RE)Ba2Cu3O7−δ (RE-123) phase is a critical step in the melt growth of large, single grain, (RE)BaCuO ((RE)BCO) bulk superconductors. Recent improvements to the top seeded melt growth (TSMG) processing technique, which is an established method of fabricating bulk (RE)BCO superconductors, based on the use of a buffer layer between the seed and green body preform, has significantly improved the reliability of the single grain growth process. This technique has been used successfully for the primary TSMG and infiltration melt growth of all compositions within the ((RE)BCO–Ag) family of materials (where RE = Sm, Gd and Y), and in recycling processes. However, the mechanism behind the improved reliability of the melt process is not understood fully and its effect on the superconducting properties of the fully processed single grains is not clear. In this paper, we investigate the effect of the use of a buffer pellet between the seed and green body on the microstructure, critical current, critical temperature and trapped field of the bulk superconductor. We conclude that the introduction of the buffer pellet evolves the melt growth process towards that observed in the technologically challenging hot seeding technique, but has the potential to yield high quality single grain samples but by a commercially viable melt process. [ABSTRACT FROM AUTHOR]

Bulk high temperature superconductor magnets (HTSMs) have a higher flux-generating capability compared to conventional permanent magnets (PMs). These materials potentially can be used in high temperature superconducting (HTS) linear synchronous motors (LSMs) as superconducting secondary magnets, what will result in a reduced volume and weight as well as in higher force density and efficiency of these devices when compared to conventional PMs. The focus of this paper is on the effect of size of the secondary HTSM on the static performance (thrust force and normal force) of a LSM. In order to obtain high-field HTSM as the secondary, single grain bulk GdBCO-Ag superconductors of diameter 20 mm, 30 mm and 40 mm, which have higher Jc and trapped fields than YBCO superconductors, were used in this device for the first time following application by the same optimized magnetization condition. It was found that both thrust and normal forces increase and saturate with the increasing size of the HTSM secondary at the small size range, and then potentially distort when the physical size of the HTSM secondary approaches the pole pitch of the linear three-phase primary windings of the LSM. Furthermore, more experiments of a larger-sized multi-seeded HTSM secondary, confirmed that the relationship between the HTSM secondary size and the pole pitch of the primary is an important factor for achieving higher thrust and normal forces. It is suggested that the multi-pole HTSM secondary will be more beneficial to future HTS LSM designs since the single-pole HTSM secondary size should be equal to or smaller than the stator pole pitch in the paper. [ABSTRACT FROM AUTHOR]

The two-step top seeded infiltration and growth (TSIG) melt process has emerged as a successful and reliable technique for the fabrication of single grain (RE)Ba2Cu3O7−δ (where RE is a rare-earth element or yttrium) bulk high temperature superconductors with engineered microstructures that exhibit improved superconducting properties. In this study, the performance of these materials in large applied magnetic fields has been investigated by field cooling single grain samples in a magnetic field of 18 T. YBa2Cu3O7−δ samples processed without added Ag by the TSIG technique, in the two-sample stack configuration, trapped a magnetic field of 14.3 T at 28 K after field cooling from 100 K and subsequent removal of the applied field. This result is particularly significant in that, previously, only single grain (RE)Ba2Cu3O7−δ bulk superconductors containing Ag have been reported to be able to tolerate the large stresses on the samples inherent in the magnetisation process at large fields. The samples prepared in the present study were pre-stressed using a reinforcing stainless-steel ring, although, otherwise, they did not contain any additives, dopants or resin impregnation. The ability of samples processed by TSIG to withstand large tensile forces without Ag addition is attributed to the reduced incidence of intrinsic cracks/pores in the single grain microstructure. [ABSTRACT FROM AUTHOR]

Magnetisation is one of the main barriers to practical use of bulk superconductors as high field magnets. Recently several authors have reported a flux jump effect that allows penetration of magnetic flux into a bulk superconductor during pulsed field magnetisation (PFM) at lower fields than that would be predicted on the basis of the Bean model. We have systematically investigated macroscopic flux jumps in single grain GdBa2Cu3O7−δ–Ag (GdBCO–Ag) bulk superconductors with diameters of up to 30 mm when subjected to pulsed magnetic fields. Flux jumps were observed at temperatures between 30 and 77 K and in applied magnetic fields of up to 7 T. The applied pulsed field required to trigger the instability or flux jump field, Bj, was determined experimentally and found to increase with decreasing temperature. An extended instability criterion based on a 2D axisymmetric model was used to predict Bj at various temperatures and the results are in good agreement with experiments. A significant temperature rise has been measured experimentally during the magnetisation process which indicates that local heat generation due to the sharp rise of the applied field in the PFM process is the primary cause of the flux jumps. The experimental results suggest further that the critical current density reduces to almost zero in the warm part of the sample during the short period of non-equilibrium. A peak trapped field of 4.1 T at the surface and 5.3 T between a stack of two GdBCO–Ag bulk superconductors was achieved at 30 K by means of an optimised two-step pulse sequence with the assistance of the flux jumps, which is extremely promising for potential applications of these technologically important materials. [ABSTRACT FROM AUTHOR]

Progress in superconducting bulk materials has been somewhat overshadowed by the considerable effort required to produce practical long-length conductors. There has, however, been steady progress in both the materials science of bulk superconducting materials and the technologies required to use them effectively in engineering applications. In particular, magnetised bulk superconductors are capable of acting as quasi-permanent magnets with the potential of providing magnetic fields of several tesla or greater from a small volume of material, they can act as magnetic shields and they can provide self-stabilised levitation. This roadmap, based on a workshop which involved the participation of a wide range of academic and industrial participants (see doi: 10.17863/CAM.586 for details of the workshop methodology), aims to explore some of the key potential domains of application of bulk superconductors. Detailed technological roadmaps are presented for four key applications that were identified as providing both good market opportunity and feasibility. These are: portable systems for bulk superconductivity; portable, high-field magnet systems for medical devices; ultra-light superconducting rotating machines for next-generation transport & power applications; and magnetic shielding applications for electric machines, equipment and other high-field devices. [ABSTRACT FROM AUTHOR]

Large, single grain (RE)Ba2Cu3O7 (where RE is a rare-earth element or yttrium) high temperature superconductors are technologically important materials due to their ability to trap large magnetic fields and to provide stable magnetic levitation for a number of potential high field applications. The fabrication of samples in the large singe grain form is a challenge, however, due to the characteristic slow growth rate of these materials and the need to produce samples that are electrically well-connected in order to generate trapped magnetic fields that are significantly greater than those produced by conventional permanent magnets (PM). In this work, we investigate whether large, single grain samples are optimum for the generation of high levitation forces for engineering applications. Three large bar-shaped Y–Ba–Cu–O samples of dimensions 60 × 20 × 12 mm3 were prepared for this investigation, including one single-seeded, one multi-seeded and one consisting of three square samples packed together closely in an array. The processing of these samples is described and their trapped field and levitation performance at 77 K measured using different PM arrays. We find that the multi-seeded samples and those assembled from smaller, individual bulk superconductors are able to achieve a higher levitation force than an equivalent single seed sample arrangement, at least in some geometries. This result is significant in that it suggests clearly that it is not always necessary to fabricate bulk (RE)BCO superconductors in the form of very large single grains for levitation applications, although the specific configuration of the system does need to be considered on an application-by-application basis. [ABSTRACT FROM AUTHOR]

Bulk, single grains of RE–Ba–Cu–O [(RE)BCO] high temperature superconductors have significant potential for a wide range of applications, including trapped field magnets, energy storage flywheels, superconducting mixers and magnetic separators. One of the main challenges in the production of these materials by the so-called top seeded melt growth technique is the reliable seeding of large, single grains, which are required for high field applications. A chemically aggressive liquid phase comprising of BaCuO2 and CuO is generated during the single grain growth process, which comes into direct contact with the seed crystal either instantaneously or via infiltration through a buffer pellet, if employed in the process. This can cause either partial or complete melting of the seed, leading subsequently to growth failure. Here, the underlying mechanisms of seed crystal melting and the role of seed porosity in the single grain growth process are investigated. We identify seed porosity as a key limitation in the reliable and successful fabrication of large grain (RE)BCO bulk superconductors for the first time, and propose the use of Mg-doped NdBCO generic seeds fabricated via the infiltration growth technique to reduce the effects of seed porosity on the melt growth process. Finally, we demonstrate that the use of such seeds leads to better resistance to melting during the single grain growth process, and therefore to a more reliable fabrication technique. [ABSTRACT FROM AUTHOR]

We report that the dynamic levitation force of bulk high temperature superconductors (HTS) in motion attenuates when exposed to an inhomogeneous magnetic field. This phenomenon has significant potential implications for the long-term stability and running performance of HTS in maglev applications. In order to suppress the attenuation of the levitation force associated with fluctuations in magnetic field, we compare the dynamic levitation performance of single grain Y–Ba–Cu–O (YBCO) and Gd–Ba–Cu–O (GdBCO) bulk superconductors with relatively high critical current densities. A bespoke HTS maglev dynamic measurement system (SCML-03) incorporating a rotating circular permanent magnet guideway was employed to simulate the movement of HTS in a varying magnetic field at different frequencies (i.e. speed of rotation). The attenuation of the levitation force during dynamic operation, which is key parameter for effective maglev operation, has been evaluated experimentally. It is found that GdBCO bulk superconductors that exhibit superior levitation force properties are more able to resist the attenuation of levitation force compared with YBCO bulk materials under the same operating conditions. This investigation indicates clearly that GdBCO bulk superconductors can play an important role in suppressing attenuation of the levitation force, therefore improving the long-term levitation performance under dynamic operating conditions. This result is potentially significant in the design and application of HTS in maglev systems. [ABSTRACT FROM AUTHOR]

The use of RE-Ba–Cu–O [(RE)BCO] bulk superconductors, where RE = Y, Gd, Sm, in practical applications is, at least in part, limited by their mechanical properties and brittle nature, in particular. Alloying these materials with silver, however, produces a significant improvement in strength without any detrimental impact on their superconducting properties. Unfortunately, the top seeded melt growth technique, used routinely to process bulk (RE)BCO superconductors in the form of large, single grains required for practical applications, is complex and has a large number of inter-related variables, so the addition of silver increases the complexity of the growth process even further. This can make successful growth of this system extremely challenging. Here we report measurements of the growth rate of YBCO-Ag fabricated using a new growth technique consisting of continuous cooling and isothermal hold process. The resulting data form the basis of a model that has been used to derive suitable heating profiles for the successful single grain growth of YBCO-Ag bulk superconductors of up to 26 mm in diameter. The microstructure and distribution of silver within these samples have been studied in detail. The maximum trapped field at the top surface of the bulk YBCO-Ag samples has been found to be comparable to that of standard YBCO processed without Ag. The YBCO-Ag samples also exhibit a much more uniform trapped field profile compared to that of YBCO. [ABSTRACT FROM AUTHOR]

Most established top seeded melt growth (TSMG) processes of bulk, single grain Y–Ba–Cu–O (YBCO) superconductors are performed using a mixture of pre-reacted precursor powders. Here we report the successful growth of large, single grain YBCO samples by TSMG with good superconducting properties from a simple precursor composition consisting of a sintered mixture of the raw oxides. The elimination of the requirement to synthesize precursor powders in a separate process prior to melt processing has the potential to reduce significantly the cost of bulk superconductors, which is essential for their commercial exploitation. The growth morphology, microstructure, trapped magnetic field and critical current density, Jc, at different positions within the sample and maximum levitation force of the YBCO single grains fabricated by this process are reported. Measurements of the superconducting properties show that the trapped filed can reach 0.45 T and that a zero field Jc of 2.5 × 104 A cm−2 can be achieved in these samples. These values are comparable to those observed in samples fabricated using pre-reacted, high purity commercial oxide precursor powders. The experimental results are discussed and the possibility of further improving the melt process using raw oxides is outlined. [ABSTRACT FROM AUTHOR]

A major limitation to the widespread application of Y–Ba–Cu–O (YBCO) bulk superconductors is the relative complexity and low yield of the top seeded melt growth (TSMG) process, by which these materials are commonly fabricated. It has been demonstrated in previous work on the recycling of samples in which the primary growth had failed, that the provision of an additional liquid-rich phase to replenish liquid lost during the failed growth process leads to the reliable growth of relatively high quality recycled samples. In this paper we describe the adaptation of the liquid phase enrichment technique to the primary TSMG fabrication process. We further describe the observed differences between the microstructure and superconducting properties of samples grown with additional liquid-rich phase and control samples grown using a conventional TSMG process. We observe that the introduction of the additional liquid-rich phase leads to the formation of a higher concentration of Y species at the growth front, which leads, in turn, to a more uniform composition at the growth front. Importantly, the increased uniformity at the growth front leads directly to an increased homogeneity in the distribution of the Y-211 inclusions in the superconducting Y-123 phase matrix and to a more uniform Y-123 phase itself. Overall, the provision of an additional liquid-rich phase improves significantly both the reliability of grain growth through the sample thickness and the magnitude and homogeneity of the superconducting properties of these samples compared to those fabricated by a conventional TSMG process. [ABSTRACT FROM AUTHOR]

SmBa2Cu3O7−δ (Sm-123) is a light-rare-earth barium-cuprate (LRE-BCO) high-temperature superconductor (HTS) with significant potential for high field industrial applications. We report the fabrication of large, single grain bulk [Sm–Ba–Cu–O (SmBCO)] superconductors containing 1 wt% CeO2 and 0.1 wt% Pt using a top-seeded melt growth process. The performance of the SmBCO bulk superconductors containing the different dopants was evaluated based on an analysis of their superconducting properties, including critical transition temperature, Tc and critical current density, Jc , and on sample microstructure. We find that both CeO2 and Pt dopants refine the size of Sm2BaCuO5 (Sm-211) particles trapped in the Sm-123 superconducting phase matrix, which act as effective flux pinning centres, although the addition of CeO2 results in broadly improved superconducting performance of the fully processed bulk single grain. However, 1 wt% CeO2 is significantly cheaper than 0.1 wt% Pt, which has clear economic benefits for use in medium to large scale production processes for these technologically important materials. Finally, the use of CeO2 results generally in the formation of finer Sm-211 particles and to the generation of fewer macro-cracks and Sm-211 free regions in the sample microstructure. [ABSTRACT FROM AUTHOR]

A fundamental requirement of the fabrication of high performing, (RE)–Ba–Cu–O bulk superconductors is achieving a single grain microstructure that exhibits good flux pinning properties. The top seeded melt growth (TSMG) process is a well-established technique for the fabrication of single grain (RE)BCO bulk samples and is now applied routinely by a number of research groups around the world. The introduction of a buffer layer to the TSMG process has been demonstrated recently to improve significantly the general reliability of the process. However, a number of growth-related defects, such as porosity and the formation of micro-cracks, remain inherent to the TSMG process, and are proving difficult to eliminate by varying the melt process parameters. The seeded infiltration and growth (SIG) process has been shown to yield single grain samples that exhibit significantly improved microstructures compared to the TSMG technique. Unfortunately, however, SIG leads to other processing challenges, such as the reliability of fabrication, optimisation of RE2BaCuO5 (RE-211) inclusions (size and content) in the sample microstructure, practical oxygenation of as processed samples and, hence, optimisation of the superconducting properties of the bulk single grain. In the present paper, we report the development of a near-net shaping technique based on a novel two-step, buffer-aided top seeded infiltration and growth (BA-TSIG) process, which has been demonstrated to improve greatly the reliability of the single grain growth process and has been used to fabricate successfully bulk, single grain (RE)BCO superconductors with improved microstructures and superconducting properties. A trapped field of ∼0.84 T and a zero field current density of 60 kA cm−2 have been measured at 77 K in a bulk, YBCO single grain sample of diameter 25 mm processed by this two-step BA-TSIG technique. To the best of our knowledge, this value of trapped field is the highest value ever reported for a sample fabricated by an infiltration and growth process. In this study we report the successful fabrication of 14 YBCO samples, with diameters of up to 32 mm, by this novel technique with a success rate of greater than 92%. [ABSTRACT FROM AUTHOR]

Bulk (RE)–Ba–Cu–O ((RE)BCO, where RE stands for rare-earth), single grain superconductors can trap magnetic fields of several tesla at low temperatures and therefore can function potentially as high field magnets. Although top seeded melt growth (TSMG) is an established process for fabricating relatively high quality single grains of (RE)BCO for high field applications, this technique suffers from inherent problems such as sample shrinkage, a large intrinsic porosity and the presence of (RE)2BaCuO5 (RE-211)-free regions in the single grain microstructure. Seeded infiltration and growth (SIG), therefore, has emerged as a practical alternative to TSMG that overcomes many of these problems. Until now, however, the superconducting properties of bulk materials processed by SIG have been inferior to those fabricated using the TSMG technique. In this study, we identify that the inferior properties of SIG processed bulk superconductors are related to the presence of a relatively large Y-211 content (∼41.8%) in the single grain microstructure. Controlling the RE-211 content in SIG bulk samples is particularly challenging because it is difficult to regulate the entry of the liquid phase into the solid RE-211 preform during the infiltration process. In an attempt to solve this issue, we have investigated the effect of careful control of both the infiltration temperature and the quantity of liquid phase powder present in the sample preforms prior to processing. We conclude that careful control of the infiltration temperature is the most promising of these two process variables. Using this knowledge, we have fabricated successfully a YBCO bulk single grain using the SIG process of diameter 25 mm that exhibits a trapped field of 0.69 T at 77 K, which is the largest value reported to date for a sample fabricated by the SIG technique. [ABSTRACT FROM AUTHOR]

Reliable seeding of the superconducting (RE)Ba2Cu3O7−δ (RE-123) phase is a critical step in the melt growth of large, single grain, (RE)BaCuO ((RE)BCO) bulk superconductors. Recent improvements to the top seeded melt growth (TSMG) processing technique, which is an established method of fabricating bulk (RE)BCO superconductors, based on the use of a buffer layer between the seed and green body preform, has significantly improved the reliability of the single grain growth process. This technique has been used successfully for the primary TSMG and infiltration melt growth of all compositions within the ((RE)BCO–Ag) family of materials (where RE = Sm, Gd and Y), and in recycling processes. However, the mechanism behind the improved reliability of the melt process is not understood fully and its effect on the superconducting properties of the fully processed single grains is not clear. In this paper, we investigate the effect of the use of a buffer pellet between the seed and green body on the microstructure, critical current, critical temperature and trapped field of the bulk superconductor. We conclude that the introduction of the buffer pellet evolves the melt growth process towards that observed in the technologically challenging hot seeding technique, but has the potential to yield high quality single grain samples but by a commercially viable melt process. [ABSTRACT FROM AUTHOR]

Bulk high temperature superconductor magnets (HTSMs) have a higher flux-generating capability compared to conventional permanent magnets (PMs). These materials potentially can be used in high temperature superconducting (HTS) linear synchronous motors (LSMs) as superconducting secondary magnets, what will result in a reduced volume and weight as well as in higher force density and efficiency of these devices when compared to conventional PMs. The focus of this paper is on the effect of size of the secondary HTSM on the static performance (thrust force and normal force) of a LSM. In order to obtain high-field HTSM as the secondary, single grain bulk GdBCO-Ag superconductors of diameter 20 mm, 30 mm and 40 mm, which have higher Jc and trapped fields than YBCO superconductors, were used in this device for the first time following application by the same optimized magnetization condition. It was found that both thrust and normal forces increase and saturate with the increasing size of the HTSM secondary at the small size range, and then potentially distort when the physical size of the HTSM secondary approaches the pole pitch of the linear three-phase primary windings of the LSM. Furthermore, more experiments of a larger-sized multi-seeded HTSM secondary, confirmed that the relationship between the HTSM secondary size and the pole pitch of the primary is an important factor for achieving higher thrust and normal forces. It is suggested that the multi-pole HTSM secondary will be more beneficial to future HTS LSM designs since the single-pole HTSM secondary size should be equal to or smaller than the stator pole pitch in the paper. [ABSTRACT FROM AUTHOR]