251. Control of Hg0 Re-Emission from Simulated Wet Flue Gas Desulfurization Liquors by Sodium Dithiocarbamate
- Author
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Yu Ze Jiang, Chuan Min Chen, Li Xing Jiang, and Song Tao Liu
- Subjects
chemistry.chemical_classification ,Flue gas ,chemistry ,Sodium ,Inorganic chemistry ,General Engineering ,chemistry.chemical_element ,Limiting oxygen concentration ,Dithiocarbamate ,Oxygen ,Flue-gas desulfurization ,Mercury (element) - Abstract
Secondary atmospheric pollutions may result from wet flue gas desulfurization (WFGD) systems caused by the reduction of Hg2+to Hg0and lead to a damping of the co-benefit mercury removal efficiency by WFGD systems. The effects of the operating conditions, which included the pH, temperature, and oxygen concentrations, on Hg0re-emission inhibition efficiency by DTCR from WFGD liquors was carried out. The established data reflected an outstanding performance on the Hg0re-emission inhibition from the simulated WFGD liquors by adding DTCR. Our data suggested that a concentration of 0.0005% (v/v) was enough for Hg0re-emission inhibition in the simulated WFGD liquors. The results also indicated that the Hg0re-emission inhibition efficiency by adding DTCR decreased as the operational temperatures increased and the Hg0re-emission inhibition efficiency increased as pH values and the oxygen concentration in the flue gas increased. The present findings could be valuable for industrial application of DTCR as a precipitant for stabilizing dissolved Hg2+to prevent re-emission of Hg0in WFGD solutions.
- Published
- 2012
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