251. INTRAGRAIN SENSITIZATION OF FE-28CR-5NI STAINLESS STEEL ASSOCIATED WITH 475°C EMBRITTLEMENT
- Author
-
Yuichi Ishikawa, Toshihiko Yoshimura, and Toshinori Ozaki
- Subjects
Materials science ,Precipitation (chemistry) ,Spinodal decomposition ,Metallurgy ,Analytical chemistry ,chemistry.chemical_element ,Corrosion ,law.invention ,Nickel ,chemistry ,law ,Ageing ,Phase (matter) ,Electron paramagnetic resonance ,Embrittlement - Abstract
Iron-28%chromium-5%nickel stainless steel was aged at 450°C for up to 5000h. Microstructural change upon ageing was examined by atom probe-field ion microscopy (FIM). Change in corrosion resistance of the steel upon ageing was evaluated by electrochemical potentiokinetic reactivation (EPR) method. Upon ageing the steel undergoes phase separation via spinodal decomposition. This results in a closely knitted precipitation of Cr-rich alpha prime phase of 2nm in size in the matrix of Crdepleted alpha phase of several nm in size upon ageing for 5000h. In the Cr-depleted alpha phase, the Cr concentration is below 12at%. Simultaneously the steel becomes hardened and shows the sensitization in the grain. Upon ageing for 100h, two distinct reactivation peaks appear at -200 and -410mV (vs Ag/AgCl). These peaks grow as the ageing proceeds. The peak at -200mV is attributed to the Cr-depleted α phase where Cr concentration is below 12at%.
- Published
- 1992