251. Far infrared absorption in metal-insulator composites
- Author
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G. L. Carr, N. E. Russell, and David B. Tanner
- Subjects
Range (particle radiation) ,Materials science ,Far infrared ,Attenuation coefficient ,Inorganic chemistry ,Analytical chemistry ,Evaporation ,Particle size ,Molar absorptivity ,Absorption (electromagnetic radiation) ,Grain size - Abstract
The absorption coefficient of composite systems, formed by by compacting together small metal particles and finely ground KCl powder, has been measured at far infrared frequencies (4−400 cm−1). The measurements were made on particles of aluminum, prepared by inert gas evaporation, having mean diameters in the range 200 A to 1000 A and on particles of palladium, with mean diameter 2 μm. Measurements were made for metal filling factors, f, between 0.001 and 0.10. The absorption coefficient is nearly linear in concentration for small concentrations but rises more rapidly than linearly at larger values of f, indicating the onset of a metal‐insulator transition. The dependence of the absorption coefficient on particle size is very weak. A theory which includes eddy current (magnetic dipole) absorption gives a fair description of the data for the largest particles but falls several orders of magnitude below the data for the smallest ones.
- Published
- 1978
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