201. Studies on dielectric features of Li2O-Ga2O3-SiO2: Cr2O3/MoO3/WO3 glass systems.
- Author
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Krishna, S. Vijaya, Pavić, L., Bafti, A., Pisk, J., Bhadrarao, D., Rao, Y. Dana, Sekhar, A. Venkata, Kumar, V. Ravi, and Veeraiah, N.
- Subjects
GLASS ,DIELECTRIC properties ,PERMITTIVITY ,DIELECTRICS ,LIGHT absorption ,ALUMINUM-lithium alloys - Abstract
This investigation consists of results of the studies on dielectric properties and a.c. conductivity of Li
2 O-Ga2 O3 -SiO2 (LGS) glass with 2.0 mol% of Cr2 O3 , MoO3 , WO3 across 0.01 Hz to 1 MHz and 20 °C to 240 °C. Structural analysis using optical absorption and IR spectra indicated dopant ions predominantly in Cr3+ , Mo6+ /Mo5+ , W6+ states, and occupied Td and Oh positions. Dielectric constant and conductivity were found to be the maximal for LGSMo glass, with the lowest impedance, while LGSCr glass exhibited the opposite trend. From the analysis of dipolar relaxation effects probable dipoles were identified in each glass. Studies on conductivity revealed that contribution of ionic components is very low and a substantial polaronic contribution in LGSMo glass, whereas, LGSCr glass showed a larger ionic component, specifically Li+ ion diffusion and hence more useful material for solid-state batteries with respect to the other two glasses. [ABSTRACT FROM AUTHOR]- Published
- 2024
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