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We design a new kind of phase zone plates (PZPs) to improve the diffraction efficiency of soft x ray zone plates (ZPs). The design replaces blank parts of PZPs with metals of negative phase shift at the working energy, which is called as the positive and negative PZPs (PNPZPs). According to the calculation, PNPZPs have a higher maximum efficiency than conventional ZPs with the same zone width. With the help of a negative phase coefficient, it is much easier to achieve a π phase shift in one period, resulting in a smaller zone height. This design can help fabricate finer PZPs to achieve a better image resolution.

Measurements with a CubeSat gas pixel detector reveal a change in the Crab pulsar polarization after a glitch in the spin period, suggesting that starquakes alter the magnetosphere.

The soft X-ray excess - the excess of X-rays below 2 keV with respect to the extrapolation of the hard X-ray spectral continuum model - is a very common feature among type 1 active galactic nuclei (AGN); yet the nature of the soft X-ray excess is still poorly understood and hotly debated. To shed some light on this issue, we have measured in a model-independent way the soft excess strength in a flux-limited sample of broad-line and narrow-line Seyfert 1 galaxies (BLS1s and NLS1s) that are matched in X-ray luminosity but different in terms of the black hole mass and the accretion rate values, with NLS1s being characterized by smaller MBH and larger accretion rate values. Our analysis, in agreement with previous studies carried out with different AGN samples, indicates that: 1) a soft excess is ubiquitously detected in both BLS1s and NLS1s; 2) the strength of the soft excess is significantly larger in the NLS1 sample, compared to the BLS1 sample; 3) combining the two samples, the strength of the soft excess appears to positively correlate with the photon index as well as with the accretion rate, whereas there is no correlation with the black hole mass. Importantly, our work also reveals the lack of an anticorrelation between the soft excess strength and the luminosity of the primary X-ray component, predicted by the absorption and reflection scenarios. Our findings suggest that the soft excess is consistent with being produced by a warm Comptonization component. Larger, more complete samples of NLS1s and BLS1s are needed to confirm these conclusions., 16 pages, 9 figures, 6 tables, accepted for publication in MNRAS

High brilliance synchrotrons and FELs require high performing detector systems to realise their full potential. High dynamic range, low noise and high frame rate are all of great importance. In this paper we present first optical characterization results of the P2M CMOS sensor, designed for soft X-ray detection at such facilities. Previous work is summarised and an overview of the sensor is presented. Test results for the sensor’s column-parallel ADC and readout chain are presented, and first test results for the pixel acquired using the Photon Transfer Curve (PTC) method are shown. Finally, an outline of future work is provided.

We present here a combined analysis of four high spectral resolution observations of the Diffuse X-ray Background (DXRB), made using the University of Wisconsin-Madison/Goddard Space Flight Center X-ray Quantum Calorimeter (XQC) sounding rocket payload. The observed spectra support the existence of a $\sim0.1~$keV Local Hot Bubble and a $\sim0.2~$keV Hot Halo, with discrepancies between repeated observations compatible with expected contributions of time-variable emission from Solar Wind Charge Exchange (SWCX). An additional component of $\sim0.9~$keV emission observed only at low galactic latitudes can be consistently explained by unresolved dM stars., 21 pages, 6 figures, accepted for publication in ApJ

This paper presents the designs and simulations of twin Wolter mirrors for focusing and imaging experiments with soft Xray free electron lasers. Wave-optical simulations at a photon energy of 100 eV indicate that the designed focusing Wolter mirror focuses soft X-ray beams to a 300 nm × 200 nm spot with an acceptable rotational error of 1.7 mrad × 1.4 mrad and that the objective Wolter mirror, which receives the beam that passes through the focusing Wolter mirror and a sample, forms bright-field images with a spatial resolution of 140 nm × 140 nm. The focusing Wolter mirror enables long-term experiments with high stability, and the objective Wolter mirror is applicable to imaging-before-destruction.

New instruments and methods for nanoimaging with the use of a compact laser plasma soft X-ray source are presented. The source is based on a double-stream gas puff target irradiated with nanosecond laser pulses from a Nd:YAG laser. Three imaging instruments, operating in the soft X-ray ‘water window’ range, namely two soft X-ray transmission microscopes and a soft X-ray contact microscope, have been developed. The transmission microscopes are based on grazing incidence Wolter type or diffractive Fresnel type optics. Application of these instruments for nanoimaging of hydrated and dry biological samples is presented. A new method for X-ray nanoimaging based on optical coherence tomography (OCT) technique using broad-band soft X-ray emission from the laser plasma source is also demonstrated.

Cellular complexity is represented best in high-spatial resolution, three-dimensional (3D) reconstructions. Soft X-ray tomography (SXT) generates detailed volumetric reconstructions of cells preserved in a near-to-native, frozen-hydrated state. SXT is broadly applicable and can image specimens ranging from bacteria to large mammalian cells. As a reference, we summarize light and electron microscopic methods. We then present an overview of SXT and discuss its role in cellular imaging. We detail the methods used to image biological specimens and present recent highlights that illustrate the capabilities of the technique. We conclude by discussing correlative imaging, specifically the combination of SXT and fluorescence microscopy performed on the same specimen. This correlated approach combines the structural morphology of a cell with its physiological characteristics to build a deeply informative composite view.

We report the detection in Chandra ACIS archival data of an elongated soft (, ApJ in press

Reliable results when fitting X-ray data require proper consideration of the statistics involved. We probe the impact of Gaussian versus Poisson statistics at low count levels using both the standard χ2 method and maximum likelihood based on Poisson (C) statistics. The difference is studied and quantified through simulated spectra with known properties. We then test the results through analysis of Mn Kα calibration data taken with the flight spare microcalorimeter for the Hitomi soft X-ray spectrometer. Through comparison with simulations, our results show that the χ2 method tends to give overly optimistic estimates of the detector energy resolution, in particular when there are few counts. Given an energy resolution of ∼5 eV and a line with about 100 photons, the line width becomes ∼10% lower in the χ2 method than in Poisson statistics. This is a consequence of the uncertainties being dominated by counting statistics, and therefore highlights the need to choose the appropriate fit statistic.

We have carried out angle-integrated photoemission spectroscopy (AIPES) and angle-resolved photoemission spectroscopy (ARPES) experiments using soft x rays on single crystals of ${\mathrm{EuCu}}_{2}{\mathrm{Ge}}_{2}$ and ${\mathrm{EuCu}}_{2}{\mathrm{Si}}_{2}$ grown by the Bridgman method to investigate their electronic structures. The AIPES results showed that the Eu ions in ${\mathrm{EuCu}}_{2}{\mathrm{Ge}}_{2}$ and ${\mathrm{EuCu}}_{2}{\mathrm{Si}}_{2}$ are in a divalent state and a nearly trivalent state, respectively, in accordance with the previously reported magnetic properties. The three-dimensional band structures and shapes of the Fermi surfaces of ${\mathrm{EuCu}}_{2}{\mathrm{Ge}}_{2}$ and ${\mathrm{EuCu}}_{2}{\mathrm{Si}}_{2}$ were studied by ARPES measurements. We found that the band structures near the Fermi level and Fermi surfaces of ${\mathrm{EuCu}}_{2}{\mathrm{Ge}}_{2}$ and ${\mathrm{EuCu}}_{2}{\mathrm{Si}}_{2}$ are very different from each other and are well reproduced by the band structure calculations based on density-functional theory for ${\mathrm{SrCu}}_{2}{\mathrm{Ge}}_{2}$ and ${\mathrm{YCu}}_{2}{\mathrm{Si}}_{2}$. This suggests that a charge transfer from the localized $4f$ states into the valence bands is responsible for the difference in the electronic states between ${\mathrm{EuCu}}_{2}{\mathrm{Ge}}_{2}$ and ${\mathrm{EuCu}}_{2}{\mathrm{Si}}_{2}$.

Information about the real-time response of carriers to optical fields is paramount to advance information processing or to understand the bottlenecks of light-matter interaction and energy harvesting. Transition-metal dichalcogenide (TMDC) compounds are an emerging class of materials with attractive structural and electronic properties that can be thinned to the 2D limit and TiS 2 is a paradigmatic example for a semi-metallic TMDC, since its electron mobility ranges between that of a metal and a semiconductor.

To advance the frontiers of ultrafast X-ray science, Shanghai soft X-ray free-electron laser (SXFEL) user facility was proposed to develop which is now under construction as planned. The SXFEL facility provides ultraintense femtosecond X-ray pulses from 0.1 keV to 1 keV in a repetition rate of 50 Hz. The first phase of the SXFEL includes two beamlines and 5 experimental end-stations. The SXFEL user facility provides some advanced X-ray measurement tools in the research fields of biomaterial, condensed matters, atomic and molecular physics, and novel functional materials by means such as coherent diffraction imaging, time-resolved resonant X-ray scattering, and single-pulse time-resolved x-ray emission spectroscopy etc. In this presentation, I will report the latest status of the beamlines at Shanghai SXFEL.

International audience; This work presents an innovative usage of the GEMpix detector for soft X-rays (SXR) measurements aimed to make an estimate of the electron temperature of a Laser Produced Plasma (LPP). The GEMpix is a proportional gas detector based on three Gas Electron Multipliers (GEMs) with a Front-End Electronics (FEE) based on four Timepix chips. This FEE provides the Time over Threshold (ToT) acquisition mode pixel by pixel and then a digital measure of the released charge in the gas mixture. In addition, the charge can be amplified through the GEM foils with 4 orders of magnitude spanning gain offering, in this way, a big dynamic range and adjustable sensitivity. Chip design provides a threshold for each channel. All the thresholds are set in order to cut electronic noise and detect X-rays. In this configuration, a cut on the low amplitude signals is set, but the gain has been tuned in order to observe the main signal due to the soft X-rays reaching the detector. This detector works in an energy range between 2 to 15 keV . It offers good imaging properties, high efficiency and absolute calibration. It offers a good immunity to Electromagnetic Pulse (EMP), as checked at VEGA-2 laser facility (hundreds of TW in about 30 fs). In these experiments, where the formation of warm dense matter produced by blast waves has been studied, a measure of the plasma temperature was required. This measurement was realized applying some filters on the active area of the detector, in correspondence of three chips. With this configuration a study of the GEMpix response due to the photons coming from the coronal plasma produced by the laser on the target has been done for each single shot. GEMpix revealed innovative and attractive features, compared to the state of the art where passive films or detectors based on indirect conversion are used, for SXR imaging and spectral analysis to infer the electron temperature.

The cross sections of ultra-soft x-ray bremsstrahlung in at electron scattering by Ar, Kr and Xe are theoretically calculated. The results are consistent with the absolute values of the differential cross sections measured by Gnatchenko et al [Phys. Rev. A 80, 022707 (2009)] for scattering electrons with an energy of 600 eV on these atoms., 5 pages, 1 figure

High harmonic generation (HHG) of an intense laser pulse is a highly nonlinear optical phenomenon that provides the only proven source of tabletop attosecond pulses, and it is the key technology in attosecond science. Recent developments in high-intensity infrared lasers have extended HHG beyond its traditional domain of the XUV spectral range (10–150 eV) into the soft X-ray regime (150 eV to 3 keV), allowing the compactness, stability and sub-femtosecond duration of HHG to be combined with the atomic site specificity and electronic/structural sensitivity of X-ray spectroscopy. HHG in the soft X-ray spectral region has significant differences from HHG in the XUV, which necessitate new approaches to generating and characterizing attosecond pulses. Here, we examine the challenges and opportunities of soft X-ray HHG, and we use simulations to examine the optimal generating conditions for the development of high-flux, attosecond-duration pulses in the soft X-ray spectral range. This article is part of the theme issue ‘Measurement of ultrafast electronic and structural dynamics with X-rays’.

The data for X‐ray images studied in this paper can be downloaded from Zenodo (https://doi.org/10.5281/zenodo.1415285).

This chapter provides a timely overview of the application of resonant and polarized soft X-ray scattering in polymer electronics to date. It reviews the basic principles and morphological parameters that dictate the morphology and applications of soft X-ray scattering in the field of polymer semiconductors. The chapter presents a non-exhaustive survey of soft X-ray scattering studies on the basis of representative semiconducting polymeric systems, such as neat polymers, polymer:fullerene blends, polymer:nonfullerene small molecule blends, polymer:polymer blends, and ternary blend systems. It argues that the new quantitative relations established will vastly reduce the parameter space of the trial-and-error synthesis and optimization approach by clearly delineating why a particular set of materials and processing condition might fail, or which aspect may need to be improved. The chapter highlights the state-of-the-art achievements, remaining challenges, and future research developments of soft X-ray scattering.

An experimental and theoretical study of the photoinduced homolysis of the carbon-chlorine bond in an ice matrix of chlorobenzene is presented. A condensed chlorobenzene film has been grown in situ and near edge X-ray fine structure (NEXAFS) spectra were collected after exposing the condensed film to a monochromatic photon beam centered at the 2822 eV resonant excitation of chlorine and at 2850 eV. The photoabsorption to the Cl 1s → σ* and Cl 1s → π* states has been measured and the hypothesis of free radical coupling reactions was investigated via time-dependent density functional theory (TD-DFT) and complete active space self-consistent field (CASSCF) calculations. Also, potential energy pathways to the C-Cl cleavage have been obtained at the CASSCF level to the Cl 1s → σ*, 1s → π*, and 1s → ∞ states. A strong dissociative character was only found for the Cl 1s → σ* resonance.

Commissioning and first operation of an angle-resolved photoelectron spectrometer for non-invasive shot-to-shot diagnostics at the European XFEL soft X-ray beamline are described. The objective with the instrument is to provide the users and operators with reliable pulse-resolved information regarding photon energy and polarization that opens up a variety of applications for novel experiments but also hardware optimization.

In this paper, we will present the measurements of diffraction efficiency of commercially available replica reflection gratings which are applied to the realization of monochromators for soft X-rays in the classical and off-plane geometry. The efficiency curves for different blaze wavelengths has been measured at the Circular Polarization beamline of the ELETTRA Synchrotron (Italy) and simulated with GSolver, which is a full vector implementation of a class of algorithms known as Rigorous Coupled Wave Analysis (RCWA). Aim of the measurements is the comparison between the two diffraction geometries when used for the realization of instruments with ultrafast response. The advantages and drawbacks of both configurations when applied to the spectral selection of ultrafast pulses below 10 nm are discussed.

Metals form an essential part of the Universe at all scales. Without metals we would not exist, and the Cosmos would look completely different. Metals are primarily born through nuclear processes in stars. They leave their cradles through winds or explosions, and then start their journey through space. This can lead them in and out of astronomical objects on all scales, ranging from comets, planets, stars, entire galaxies, groups and clusters of galaxies to the largest structures of the Universe. Their wanderings are fundamental in determining how these objects, and the entire universe, evolve. In addition, their bare presence can be used to trace what these structures look like. The scope of this paper is to highlight the most important open astrophysical problems that will be central in the next decades and for which a deep understanding of the Universe-wandering metals, their physical and kinematical states and their chemical composition represents the only viable solution. The majority of these studies can only be efficiently performed through High Resolution Spectroscopy in the soft X-ray band., White-Paper submitted in response to the "Voyage-2050" ESA call: cover page + 20 page text (including 16 figures) + 5 page references + list of team-members. Additional supporting authors are listed in the acknowledgment section at page 20 of the paper

In this paper, we are presenting the Percival detector, a monolithic CMOS Imager for detection of soft x-rays in Synchrotron Rings and Free Electron Lasers. The imager consists in a 2D array of many (2M) small (27um pitch) pixels, without dead or blind zones in the imaging area. The imager achieves low noise and high dynamic range by means of an adaptive-gain in-pixel circuitry, that has been validated on prototypes. The imager features on-chip Analogue-to-Digital conversion to 12+1 bits, and has a readout speed which is compatible with most of Free Electron Laser Facilities. For direct detection of low-energy x-rays, the imager is back-illuminated and post-processed to achieve 100% fill factor.

I review the basics of the disc instability model (DIM) for dwarf novae and soft-X-ray transients and its most recent developments, as well as the current limitations of the model, focusing on the dwarf nova case. Although the DIM uses the Shakura-Sunyaev prescription for angular momentum transport, which we know now to be at best inaccurate, it is surprisingly efficient in reproducing the outbursts of dwarf novae and soft X-ray transients, provided that some ingredients, such as irradiation of the accretion disc and of the donor star, mass transfer variations, truncation of the inner disc, etc., are added to the basic model. As recently realized, taking into account the existence of winds and outflows and of the torque they exert on the accretion disc may significantly impact the model. I also discuss the origin of the superoutbursts that are probably due to a combination of variations of the mass transfer rate and of a tidal instability. I finally mention a number of unsolved problems and caveats, among which the most embarrassing one is the modelling of the low state. Despite significant progresses in the past few years both on our understanding of angular momentum transport, the DIM is still needed for understanding transient systems., Comment: 20 pages, 9 figures, 1 table. Accepted for publication in Advances in Space Research

We develop an experimental strategy for generating high-flux soft x-ray high-order harmonics (HH) driven by loosely focused high-energy infrared femtosecond pulses. Strong soft x-ray HHs are generated in a long Ne medium.

We report the direct wavefront characterization of an intense ultrafast high-harmonic-seeded soft X-ray laser (λ=32.8 nm) depending on the arrival time of the seed pulses by high-resolution ptychographic imaging and subsequently perform single-shot nanoscale imaging.

We report a strong soft X-ray excess in the BL--Lacartae $\gamma$-ray blazar OJ~287 during the long exposure in May 2015, amongst two of the latest \xmm~{} observations performed in May 2015 and 2018. In case of May 2015 observation, a logparabola model fits the EPIC-pn data well while a logparabola plus powerlaw describes the overall simultaneous optical to X-ray spectra, suggesting the excess as the synchrotron tail. This interpretation, however, is inconsistent with the observed spectral break between near-infrared and optical spectra, attributed to standard disk around a supermassive black hole (SMBH). Based on this, we considered two commonly invoked accretion disk based models in AGNs to explain the soft excess: the cool Comptonization component in the accretion disk and the blurred reflection from the partially ionized accretion disk. We found that both cool Comptonization and blurred reflection models provide equally good fit to the data and favor a super-heavy SMBH of mass $\sim 10^{10}~M_\odot$. Further investigation of about a month long simultaneous X-ray and UV pointing observations revealed a delayed UV emission with respect to the 1.5-10 keV band, favoring X-ray reprocessing phenomenon as the dominant mechanism. The results suggest that the soft excess is probably caused by strong light bending close to the SMBH. The detected soft excess in 2015 data and its disappearance in 2018 data is also consistent with the presence of accretion disk emission, inferred from the NIR-optical spectral} break between May 2013 to March 2016., Comment: 12 pages, 5 figures, 2 tables; accepted for publication in the ApJ journal

Since the demonstration of room temperature plating and stripping of calcium with high capacities and low polarization using Ca(BH4)2 as the electrolyte, there is considerable interest in the study of electrochemical processes in calcium batteries in addition to the conventional magnesium batteries. The greater polarizability of Ca2+ over Mg2+represents greater configurational flexibility, facilitating ionic cluster formation and rapid delivery of Ca2+ ions to the electrode interface. With such motivation in calcium batteries, a critical question to address is the probing of the solvation and charge transfer mechanism at the electrode/electrolyte interface. In this work, the solvation and charge transfer mechanisms of two calcium electrolytes, Ca(BH4)2 and calcium hexafluoroisopropoxyborate (Ca(BHFIP)2), with different types of anions, are compared under operando conditions. It has been reported that when BH4 - is substituted by the more weakly coordinated BHFIP-, the electrolyte ionic conductivity will increase by an order of magnitude, which demonstrates the strong coordination of BH4 - to Ca2+ in THF. To probe the Ca2+ coordination chemistry difference at this electrolyte/electrode interface as a function of the type of anions, total electron yield (TEY) mode soft X-ray absorption spectra (XAS) sensitive to the interfacial speciation have been employed under operando electrochemical conditions. It was observed that the Ca(BHFIP)2 in THF shows a small shoulder on the right side of the L2-edge and a pre-edge peak on the left side of the L2-edge peak. A less prominent pre-edge peak is also observed on the left side of the L3-edge peak. These signatures become more prominent when the potential is swept negatively and are not reversible when the potential is swept positively in a cyclic voltammetry cycle. On the other hand, the Ca(BH4)2 in THF is more reversible, and no shoulder peak on the right side of the L2-edge peak was observed. The TEY spectra indicate their differences in the Ca2+coordination chemistry at the electrode/electrolyte interface as a result of the interacted anions and it will guide future development of electrolytes for calcium batteries. The detailed solvation structure of the calcium is to be resolved with the DFT calculations. Such operando soft XAS studies of the interfacial dynamics reveal the transient processes in the solvation at the electrolyte/electrode interface and will pave the way for the development of calcium electrolytes in batteries.

A ns Nd:YAG pulsed laser has been employed to produce plasma from the interaction with a dense target, generating continuum and UV and soft x-ray emission depending on the laser parameters and target properties. The laser hits solid and gaseous targets producing plasma in high vacuum, which was investigated by employing a silicon carbide detector. The two different interaction mechanisms were studied, as well as their dependence on the atomic number. The photon emission from laser-generated plasma produced by solid targets, such as boron nitride (BN) and other elements (Al, Cu, Sn and Ta) and compounds such as polyethylene, has been compared with that coming from plasma produced by irradiating different gas-puff targets based on N2 and other gases (Ar, Xe, Kr, SF6). The experimental results demonstrated that the yields are comparable and, in both cases, increase proportionally to the target atomic number. The obtained results, focusing the attention on the advantages and drawbacks of the employed targets, are presented and discussed.

Observations by the spacecraft Extreme Ultraviolet Explorer (EUVE), Far Ultraviolet Spectroscopic Explorer (FUSE), Chandra, and XMM-Newton of Capella (α Aurigae) have encountered problems with the relative intensities of the Fe xviii and Fe xix line emission in the soft-X-ray (XUV) and extreme-ultraviolet spectral ranges versus various model predictions based on theoretical atomic data. The reason may either lie in astrophysical phenomena, e.g., at emission or because of absorption by the interstellar medium, in the theoretical atomic data, in one or more spectrometer calibrations, or in the spectral modeling. By measurements using an electron beam ion trap we provide laboratory data obtained under conditions that are reasonably close to stellar emission regions. The laboratory data on Fe xviii and Fe xix show line ratios that are rather similar to the observations of Capella. The measurements, therefore, rule out astrophysical phenomena and calibration errors and point to issues with the modeling of the observed Capella emission.

The discovery of two-dimensional (2D) materials with single or a few-atom-thick layers has presented unprecedented opportunities to study, control and harness the properties of van der Waals (vdW) materials at their 2D limit. It also offers a platform that allows the arbitrary creation of heterostructures in a materials-by-design approach with properties tailored by the constituting components. Combining organic molecules with 2D materials to form hybrid heterointerfaces has recently emerged as a facile and versatile approach to engineer the electronic, optical, magnetic and chemical properties of 2D materials for new or optimized device applications. Underpinning the development of organic–2D materials heterostructures is the ability to interrogate the interfacial electronic structures and properties at multiple dimensions. This review provides a timely update on the application of synchrotron-based soft X-ray spectroscopies (SR-SXS) in the characterization of organic–2D materials interfaces. By harnessing the unparalleled high energy resolution, tunable energy, high brilliance and tunable polarization inherent to synchrotron radiation, electronic structures, charge transfer dynamics, molecular orientations and spin configurations at the hybrid interfaces can be examined, which helps us to formularize a coherent understanding of the organic–2D materials interfaces that will guide the design of new hybrid vdW structures and devices. We also offer our perspective on the future application of SR-SXS in the exploration of organic–2D materials heterostructures.

A forward modeling technique is developed for determining the characteristic features of observed MHD modes from the line-of-sight data of the soft x-ray (SXR) tomography diagnostics in the Wendelstein 7-X (W7-X) stellarator. In particular, forward modeling is used to evaluate the poloidal mode numbers m, radial location, poloidal rotation direction and ballooning character of the MHD modes. The poloidal mode structures have been modeled by the radially localized Gaussian-shaped emission regions rotating along the magnetic surfaces. In the present study the cases of rigid-shape emission regions and flexible emission regions are modeled. Various mode phase velocity dependences on the magnetic surface position are simulated. The modeled phase dynamics of line-integrated oscillations and the distribution of oscillation amplitudes are compared with the experimental signals of the SXR cameras which observe the plasma at various viewing angles in the poloidal cross-section. Application of this technique enables describing of the 1–50 kHz modes. In particular, in the discharge W7X-PID 20180918.045 three identified branches with the poloidal mode numbers m= 8, m= 10 and m= 11 localized at ρ ≈ 0.3 are rotating in the clockwise poloidal direction. The present paper reports the first application of the forward modeling technique to the data from the SXR diagnostics in W7-X. The high m-modes are identified by forward modeling in W7-X.

The molecular orientation and partial density of states were evaluated using NewSUBARU by soft X-ray absorption spectroscopy (XAS) and soft X-ray emission spectroscopy measurements. The degree of molecular alignment was degraded by increasing mesh temperature in hot mesh deposition (HMD), in other words, was changed from pentacene (Pn) to 6,13-dihydropentacene (DHP). At a mesh temperature of 1450 °C, the different XAS was obtained due to the mixing effect of Pn and DHP, and presence of Pn oligomer. The HMD carbon film transformed into the graphite-like film and the graphene on the quartz substrate and the Ni/quartz substrate after soft X-ray irradiation, respectively. The HMD carbon film after soft X-ray irradiation showed the peaks due to terminal carbon such as CH n and COOH in comparison with the reported large graphene sheet. It indicates that the flake size of the graphene on the Ni/quartz substrate was small and had many edges.

Soft x-ray tomograms are inferred from experimental data obtained during the recent operational phases of the superconducting, optimized stellarator Wendelstein 7-X. It is shown that the reconstructed soft x-ray emission profiles of the plasma are consistent with the numerically calculated magneto-hydrodynamic equilibrium of Wendelstein 7-X. In order to obtain reliable tomograms, the full chain of electrical and geometrical influences on the x-ray observation has to be taken into account. This has been achieved by formulation and application of an extended forward model. The forward model has been verified using phantom data derived from surrogate tomograms.