201. Study of dopant salt concentration in a silver molybdoarsenate glassy system
- Author
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G. Govindaraj, A. Karthikeyan, M. Venkateswarlu, and N. Satyanarayana
- Subjects
chemistry.chemical_classification ,Quenching ,Materials science ,Dopant ,Mechanical Engineering ,Diffusion ,Inorganic chemistry ,Salt (chemistry) ,Conductivity ,Liquid nitrogen ,Condensed Matter Physics ,Ion ,chemistry ,Mechanics of Materials ,Electrical resistivity and conductivity ,General Materials Science - Abstract
Quaternary superionic conducting AgIAg2O(MoO3 + As2O5) glasses with different dopant salt (AgI) contents were prepared by fast quenching of the melt into liquid nitrogen, and characterized by X-ray diffraction. Electrical conductivity studies on pressed pellets are reported. At room temperature (303 K), the highest conductivity, σ = 1.65 × 10 −2 S cm −1 was obtained for the glass with 60 mol.% of AgI. The Ag+ ion concentration and the packing density for glasses were calculated. The conductivity variation with dopant salt is discussed based on the diffusion path model.
- Published
- 1992
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