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International audience; Hyperion, Saturn's eighth largest icy satellite, is a body of irregular shape in a state of chaotic rotation. The surface is segregated into two distinct units. A spatially dominant high-albedo unit having the strong signature of H2O ice contrasts with a unit that is about a factor of four lower in albedo and is found mostly in the bottoms of cup-like craters. Here we report observations of Hyperion's surface in the ultraviolet and near-infrared spectral regions with two optical remote sensing instruments on the Cassini spacecraft at closest approach during a fly-by on 25-26 September 2005. The close fly-by afforded us the opportunity to obtain separate reflectance spectra of the high- and low-albedo surface components. The low-albedo material has spectral similarities and compositional signatures that link it with the surface of Phoebe and a hemisphere-wide superficial coating on Iapetus.

We review the current state of knowledge of (1) the origin and evolution of Venus and (2) the photochemical and thermochemical processes occurring in the middle and lower atmosphere there. For each, we review the promise of on-going and planned orbital observations by ESA's Venus Express and Japan's Venus Climate Orbiter missions. We review the need for future in-situ measurements for understanding Venus origin and evolution and present-day chemistry, and the implications for understanding the origin and history of the Earth and other bodies in the inner solar system, as well as for understanding terrestrial planets in other solar systems. We prioritize the goals remaining in the post Venus Express era, based on the Decadal Survey (National Research Council, 2003). Using past experience with Pioneer Venus, VEGAs, Veneras, and, most recently, Venus Express as guides, we suggest appropriate techniques and measurements to address these fundamental science issues.

PH3 exponential sum k coefficients were computed between 2750 and 3550/cm (2.82-3.64 (microns), in view of future application to radiative transfer analyses of Jupiter and Saturn in a phosphine absorption band near 3 microns. The temperature and pressure of this data set cover the ranges from 80 to 350 K and from 10 (exp -3)to 10(exp 1) bars, respectively. Transmission uncertainty incurred by the use of the k coefficients is smaller than a few percent as long as the radiation is confined above an altitude of a few bars in the giant planets. In spectral regions of weak absorption at high pressures close to 10 bars, contributions from far wings of strong absorption lines must be carefully taken into account. Our data set helps map the three-dimensional distribution of PH3 on the giant planets, revealing their global atmospheric dynamics extending down to the deep interior. The complete k coefficient data set of this work is available at the Web site of the NASA Planetary Data System Atmospheres Node.

With its comprehensive suite of near-infrared instruments, Venus Express will perform the first detailed global exploration of the depths of the thick Venusian atmosphere. Through the near-daily acquisition of Visible and Infrared maps and spectra, three infraredsensing instruments—the Planetary Fourier Spectrometer (PFS), the Venus Monitoring Camera (VMC), and the Visible and Infrared Thermal Imaging Spectrometer (VIRTIS)—will comprehensively investigate the Thermal structure, meteorology, dynamics, chemistry, and stability of the deep Venus atmosphere. For the surface, these instruments will provide clues to the emissivity of surface materials and provide direct evidence of active volcanism. In so doing, ESA’s Venus Express Mission directly addresses numerous high-priority Venus science objectives advanced by America’s National Research Council (2003) decadal survey of planetary science. r 2006 Elsevier Ltd. All rights reserved.

Observations of Saturn's satellite Enceladus using Cassini's Visual and Infrared Mapping Spectrometer instrument were obtained during three flybys of Enceladus in 2005. Enceladus' surface is composed mostly of nearly pure water ice except near its south pole, where there are light organics, CO 2 , and amorphous and crystalline water ice, particularly in the region dubbed the “tiger stripes.” An upper limit of 5 precipitable nanometers is derived for CO in the atmospheric column above Enceladus, and 2% for NH 3 in global surface deposits. Upper limits of 140 kelvin (for a filled pixel) are derived for the temperatures in the tiger stripes.

International audience; The Visual and Infrared Mapping Spectrometer (VIMS) instrument on the Cassini Saturn Orbiter returned spectral imaging data as the spacecraft undertook six close encounters with Titan beginning 7 July, 2004. Three of these flybys each produced overlapping coverage of two distinct regions of Titan's surface. Twenty-four points were selected on approximately opposite hemispheres to serve as photometric controls. Six points were selected in each of four reflectance classes. On one hemisphere each control point was observed at three distinct phase angles. From the derived phase coefficients, preliminary normal reflectances were derived for each reflectance class. The normal reflectance of Titan's surface units at 2.0178 mum ranged from 0.079 to 0.185 for the most absorbing to the most reflective units assuming no contribution from absorbing haze. When a modest haze contribution of tau=0.1 is considered these numbers increase to 0.089-0.215. We find that the lowest three reflectance classes have comparable normal reflectance on either hemisphere. However, for the highest brightness class the normal reflectance is higher on the hemisphere encompassing longitude 14-65° compared to the same high brightness class for the hemisphere encompassing 122-156° longitude. We conclude that an albedo dichotomy observed in continental sized units on Titan is due not only to one unit having more areal coverage of reflective material than the other but the material on the brighter unit is intrinsically more reflective than the most reflective material on the other unit. This suggests that surface renewal processes are more widespread on Titan's more reflective units than on its less reflective units. We note that one of our photometric control points has increased in reflectance by 12% relative to the surrounding terrain from July of 2004 to April and May of 2005. Possible causes of this effect include atmospheric processes such as ground fog or orographic clouds; the suggestion of active volcanism cannot be ruled out. Several interesting circular features which resembled impact craters were identified on Titan's surface at the time of the initial Titan flyby in July of 2004. We traced photometric profiles through two of these candidate craters and attempted to fit these profiles to the photometric properties expected from model depressions. We find that the best-fit attempt to model these features as craters requires that they be unrealistically deep, approximately 70 km deep. We conclude that despite their appearance, these circular features are not craters, however, the possibility that they are palimpsests cannot be ruled out. We used two methods to test for the presence of vast expanses of liquids on Titan's surface that had been suggested to resemble oceans. Specular reflection of sunlight would be indicative of widespread liquids on the surface; we found no evidence of this. A large liquid body should also show uniformity in photometric profile; we found the profiles to be highly variable. The lack of specular reflection and the high photometric variability in the profiles across candidate oceans is inconsistent with the presence of vast expanses of flat-lying liquids on Titan's surface. While liquid accumulation may be present as small, sub-pixel-sized bodies, or in areas of the surface which still remain to be observed by VIMS, the presence of large ocean-sized accumulations of liquids can be ruled out. The Cassini orbital tour offers the opportunity for VIMS to image the same parts of Titan's surface repeatedly at many different illumination and observation geometries. This creates the possibility of understanding the properties of Titan's atmosphere and haze by iteratively adapting models to create a best fit to the surface reflectance properties.

Cassini observations of the surface of Titan offer unprecedented views of its surface through atmospheric windows in the 1–5 μm region. Images obtained in windows for which the haze opacity is low can be used to derive quantitative photometric parameters such as albedo and albedo distribution, and physical properties such as roughness and particle characteristics. Images from the early Titan flybys, particularly T0, Ta, and T5 have been analyzed to create albedo maps in the 2.01 and 2.73 μm windows. We find the average normal reflectance at these two wavelengths to be 0.15±0.02 and 0.035±0.003, respectively. Titan's surface is bifurcated into two albedo regimes, particularly at 2.01 μm. Analysis of these two regimes to understand the physical character of the surface was accomplished with a macroscopic roughness model. We find that the two types of surface have substantially different roughness, with the low-albedo surface exhibiting mean slope angles of not, vert, similar18°, and the high-albedo terrain having a much more substantial roughness with a mean slope angle of not, vert, similar34°. A single-scattering phase function approximated by a one-term Henyey–Greenstein equation was also fit to each unit. Titan's surface is back-scattering (gnot, vert, similar0.3–0.4), and does not exhibit substantially different backscattering behavior between the two terrains. Our results suggest that two distinct geophysical domains exist on Titan: a bright region cut by deep drainage channels and a relatively smooth surface. The two terrains are covered by a film or a coating of particles perhaps precipitated from the satellite's haze layer and transported by eolian processes. Our results are preliminary: more accurate values for the surface albedo and physical parameters will be derived as more data is gathered by the Cassini spacecraft and as a more complete radiative transfer model is developed from both Cassini orbiter and Huygens Lander measurements.

[1] A large (>3 × 104 km2), lobate, 5-μm-bright region seen by Cassini on Titan's leading equatorial region is best explained as a flow field. We discuss observations from the Visual and Infrared Mapping Spectrometer and Imaging Science Subsystem of the feature and present a map of the field. We establish relative ages of flow features and discuss possible formation mechanisms and the implications of this finding for the evolution of Titan's surface.

International audience; Spectra from Cassini's Visual and Infrared Mapping Spectrometer reveal that the horizontal structure, height, and optical depth of Titan's clouds are highly dynamic. Vigorous cloud centers are seen to rise from the middle to the upper troposphere within 30 minutes and dissipate within the next hour. Their development indicates that Titan's clouds evolve convectively; dissipate through rain; and, over the next several hours, waft downwind to achieve their great longitude extents. These and other characteristics suggest that temperate clouds originate from circulation-induced convergence, in addition to a forcing at the surface associated with Saturn's tides, geology, and/or surface composition.

International audience; The wide spectral coverage and extensive spatial, temporal, and phase-angle mapping capabilities of the Visual Infrared Mapping Spectrometer (VIMS) onboard the Cassini-Huygens Orbiter are producing fundamental new insights into the nature of the atmospheres of Saturn and Titan. For both bodies, VIMS maps over time and solar phase angles provide information for a multitude of atmospheric constituents and aerosol layers, providing new insights into atmospheric structure and dynamical and chemical processes. For Saturn, salient early results include evidence for phosphine depletion in relatively dark and less cloudy belts at temperate and mid-latitudes compared to the relatively bright and cloudier Equatorial Region, consistent with traditional theories of belts being regions of relative downwelling. Additional Saturn results include (1) the mapping of enhanced trace gas absorptions at the south pole, and (2) the first high phase-angle, high-spatial-resolution imagery of CH4 fluorescence. An additional fundamental new result is the first nighttime near-infrared mapping of Saturn, clearly showing discrete meteorological features relatively deep in the atmosphere beneath the planet's sunlit haze and cloud layers, thus revealing a new dynamical regime at depth where vertical dynamics is relatively more important than zonal dynamics in determining cloud morphology. Zonal wind measurements at deeper levels than previously available are achieved by tracking these features over multiple days, thereby providing measurements of zonal wind shears within Saturn's troposphere when compared to cloudtop movements measured in reflected sunlight. For Titan, initial results include (1) the first detection and mapping of thermal emission spectra of CO, CO2, and CH3D on Titan's nightside limb, (2) the mapping of CH4 fluorescence over the dayside bright limb, extending to ˜ ˜750 km altitude, (3) wind measurements of ˜ ˜0.5 ms-1, favoring prograde, from the movement of a persistent (multiple months) south polar cloud near 88° S latitude, and (4) the imaging of two transient mid-southern-latitude cloud features.

International audience; Observations from the Cassini Visual and Infrared Mapping Spectrometer show an anomalously bright spot on Titan located at 80°W and 20°S. This area is bright in reflected light at all observed wavelengths, but is most noticeable at 5 microns. The spot is associated with a surface albedo feature identified in images taken by the Cassini Imaging Science Subsystem. We discuss various hypotheses about the source of the spot, reaching the conclusion that the spot is probably due to variation in surface composition, perhaps associated with recent geophysical phenomena.

The origin of Phoebe, which is the outermost large satellite of Saturn, is of particular interest because its inclined, retrograde orbit suggests that it was gravitationally captured by Saturn, having accreted outside the region of the solar nebula in which Saturn formed. By contrast, Saturn's regular satellites (with prograde, low-inclination, circular orbits) probably accreted within the sub-nebula in which Saturn itself formed. Here we report imaging spectroscopy of Phoebe resulting from the Cassini-Huygens spacecraft encounter on 11 June 2004. We mapped ferrous-iron-bearing minerals, bound water, trapped CO2, probable phyllosilicates, organics, nitriles and cyanide compounds. Detection of these compounds on Phoebe makes it one of the most compositionally diverse objects yet observed in our Solar System. It is likely that Phoebe's surface contains primitive materials from the outer Solar System, indicating a surface of cometary origin.

The Visual and Infrared Mapping Spectrometer (VIMS) observed the Galilean satellites during the Cassini spacecraft's 2000/2001 flyby of Jupiter, providing compositional and thermal information about their surfaces. The Cassini spacecraft approached the jovian system no closer than about 126 Jupiter radii, about 9 million kilometers, at a phase angle of

International audience; During Cassini - Jupiter flyby occurred in December 2000, Visual-Infrared mapping spectrometer (VIMS) instrument took several image cubes of Jupiter at different phase angles and distances. We have analysed the spectral images acquired by the VIMS visual channel by means of a principal component analysis technique (PCA). The original data set consists of 96 spectral images in the 0.35-1.05 mum wavelength range. The product of the analysis are new PC bands, which contain all the spectral variance of the original data. These new components have been used to produce a map of Jupiter made of seven coherent spectral classes. The map confirms previously published work done on the Great Red Spot by using NIMS data. Some other new findings, presently under investigation, are presented.

International audience; The Cassini visual and infrared mapping spectrometer (VIMS) investigation is a multidisciplinary study of the Saturnian system. Visual and near-infrared imaging spectroscopy and high-speed spectrophotometry are the observational techniques. The scope of the investigation includes the rings, the surfaces of the icy satellites and Titan, and the atmospheres of Saturn and Titan. In this paper, we will elucidate the major scientific and measurement goals of the investigation, the major characteristics of the Cassini VIMS instrument, the instrument calibration, and operation, and the results of the recent Cassini flybys of Venus and the Earth Moon system.

The Cassini Visual and Infrared Mapping Spectrometer (VIMS) is an imaging spectrometer covering the wavelength range 0.3–5.2 μm in 352 spectral channels, with a nominal instantaneous field of view of 0.5 mrad. The Cassini flyby of Jupiter represented a unique opportunity to accomplish two important goals: scientific observations of the jovian system and functional tests of the VIMS instrument under conditions similar to those expected to obtain during Cassini's 4-year tour of the saturnian system. Results acquired over a complete range of visual to near-infrared wavelengths from 0.3 to 5.2 μm are presented. First detections include methane fluorescence on Jupiter, a surprisingly high opposition surge on Europa, the first visual-near-IR spectra of Himalia and Jupiter's optically-thin ring system, and the first near-infrared observations of the rings over an extensive range of phase angles (0–120°). Similarities in the center-to-limb profiles of H + 3 and CH 4 emissions indicate that the H + 3 ionospheric density is solar-controlled outside of the auroral regions. The existence of jovian NH 3 absorption at 0.93 μm is confirmed. Himalia has a slightly reddish spectrum, an apparent absorption near 3 μm, and a geometric albedo of 0.06±0.01 at 2.2 μm (assuming an 85-km radius). If the 3-μm feature in Himalia's spectrum is eventually confirmed, it would be suggestive of the presence of water in some form, either free, bound, or incorporated in layer-lattice silicates. Finally, a mean ring-particle radius of 10 μm is found to be consistent with Mie-scattering models fit to VIMS near-infrared observations acquired over 0–120° phase angle.

A comprehensive analysis of volatiles in the Chicxulub impact strongly supports the hypothesis that impact-generated sulfate aerosols caused over a decade of global cooling, acid rain, and disruption of ocean circulation, which contributed to the mass extinction at the Cretaceous/Tertiary (K/T) boundary. The crater size, meteoritic content of the K/T boundary clay, and impact models indicate that the Chicxulub crater was formed by a short period comet or an asteroid impact that released 0.7-3.4 x 10(31) ergs of energy. Impact models and experiments combined with estimates of volatiles in the projectile and target rocks predict that over 200 gigatons (Gt) each of SO2 and water vapor, and over 500 Gt of CO2, were globally distributed in the stratosphere by the impact. Additional volatiles may have been produced on a global or regional scale that formed sulfate aerosols rapidly in cooler parts of the vapor plume, causing an early, intense pulse of sulfuric acid rain. Estimates of the conversion rate of stratospheric SO2 and water vapor to sulfate aerosol, based on volcanic production of sulfate aerosols, coupled with calculations of diffusion, coagulation, and sedimentation, demonstrate that the 200 Gt stratospheric SO2 and water vapor reservoir would produce sulfate aerosols for 12 years. These sulfate aerosols caused a second pulse of acid rain that was global. Radiative transfer modeling of the aerosol clouds demonstrates (1) that if the initial rapid pulse of sulfate aerosols was global, photosynthesis may have been shut down for 6 months and (2) that for the second prolonged aerosol cloud, solar transmission dropped 80% by the end of first year and remained 50% below normal for 9 years. As a result, global average surface temperatures probably dropped between 5 degrees and 31 degrees K, suggesting that global near-freezing conditions may have been reached. Impact-generated CO2 caused less than 1 degree K greenhouse warming and therefore was insignificant compare to the sulfate cooling. The magnitude of sulfate cooling depends largely upon the rate of ocean mixing as surface waters cool, sink, and are replaced by upwelling of deep ocean water. This upwelling apparently drastically altered ocean stratification and circulation, which may explain the global collapse of the delta 13C gradient between surface and deep ocean waters at the K/T boundary.

International audience; Two giant ovals in Jupiter's southern atmosphere, vortices of counterclockwise-rotating winds, merged in a 3-week period, starting in March 2000. One of the ovals called FA was more than 60 years old; the other called BE was the product of two 60-year-old ovals (BC and DE) that merged in 1998 (A. Sanchez-Lavega et al. 1999, Icarus142, 116-124). The merger took place when the ovals were southeast of the Great Red Spot and after the disappearance of a smaller, clockwise-rotating oval midway between them. The interaction began when the high-altitude oval clouds showed counterclockwise rotation about each other, followed by coalescence and shrinking. The interaction in deeper clouds did not include mutual rotation, but there was evidence of complex cloud structure during the merger.

Cassini/VIMS T85 observations of a solar specular reflection off of Kivu Lacus (87.?4N 241.?1E) provide an empirical transmission spectrum of Titan's atmosphere. Because this observation was acquired from short range (33,000?km), its intensity makes it visible within the 2.0, 2.7, and 2.8 ?m atmospheric windows in addition to the 5 ?m window where all previous specular reflections have been seen. The resulting measurement of the total one-way normal atmospheric optical depth (corresponding to haze scattering plus haze and gas absorption) provides strong empirical constraints on radiative transfer models. Using those models, we find that the total haze column abundance in our observation is 20% higher than the Huygens equatorial value. Ours is the first measurement in the 2-5 ?m wavelength range that probes all the way to the surface in Titan's arctic, where the vast majority of surface liquids are located. The specular technique complements other probes of atmospheric properties such as solar occultations and the direct measurements from Huygens. In breaking the degeneracy between surface and atmospheric absorptions, our measured optical depths will help to drive future calculations of deconvolved surface albedo spectra.

We report the first detection and profile characterization of thermal emission from the surface of Venus at 0.85 and 0.90 μm, observed in the first planetary spectrum acquired by the Visual-Infrared Mapping Spectrometer onboard the Cassini spacecraft en route to the Saturn system. The strength and shape of these two newly observed nightside emissions agree with theoretical predictions based on the strength of the strong emission observed at 1.01 μm. These emissions, together with previously-reported surface emission features at 1.01, 1.10, and 1.18 μm, potentially provide a new technique for remotely mapping the mineralogical composition of the venusian surface.

Galileo infrared observations of Jupiter have been performed with two instruments, the Near Infrared Mapping Spectrometer (NIMS) and the Photo-Polarimeter Radiometer (PPR). A first data set was obtained at the time of the collision of comet Shoemaker—Levy 9 with Jupiter in July 1994. Information was retrieved about the energy budget of the event, the penetration level of the explosion, the temperature and diameter of the fireball and its evolution with time, the temperature of the atmosphere heated by the infalling debris, and the amount of water formed after the explosion. The second set of data was recorded in 1996 after the Galileo probe entry. Evidence was found for a very low water abundance in the hot spots; this result is in full agreement with the conclusions derived from the Galileo probe Infrared observations of the Great Red Spot allow us to derive its 3-D structure, which appears compatible with the model of an anticyclonic vortex.

Earth-based observations of Jupiter indicate that the Galileo probe probably entered Jupiter's atmosphere just inside a region that has less cloud cover and drier conditions than more than 99 percent of the rest of the planet. The visual appearance of the clouds at the site was generally dark at longer wavelengths. The tropospheric and stratospheric temperature fields have a strong longitudinal wave structure that is expected to manifest itself in the vertical temperature profile.

Observations obtained over two years by the Cassini Imaging Science Subsystem suggest that rain showers fall on the surface. Using measurements obtained by the Visual Infrared Mapping Spectrometer, we identify the main component of the rain to be ethane, with methane as an additional component. We observe five or six probable rainfall events, at least one of which follows a brief equatorial cloud appearance, suggesting that frequent rainstorms occur on Titan. The rainfall evaporates, sublimates, or infiltrates on timescales of months, and in some cases it is associated with fluvial features but not with their creation or alteration. Thus, Titan exhibits frequent gentle rainfall instead of, or in addition to, more catastrophic events that cut rivers and lay down large fluvial deposits. Freezing rain may also be present, and the standing liquid may exist as puddles interspersed with patches of frost. The extensive dune deposits found in the equatorial regions of Titan imply multi-season arid conditions there, which are consistent with small, but possibly frequent, amounts of rain, in analogy to terrestrial deserts.

An analysis of thermal profiles and dynamics over a wide range of latitudes for the venusian atmosphere between 70 and 90 km is presented based on high spatial resolution infrared spectra of the night side obtained by the near infrared mapping spectrometer (NIMS) experiment during the Galileo-Venus encounter in February 1990. Using the 4.3-μm CO2 absorption band, the temperature profile is retrieved in the 75- to 91-km altitude region over a latitudinal range of -59° to + 64°. Compared to earlier observations from the Pioneer Venus mission, the temperature at 91 km is about 10 K higher and between 74 and 83 km about 3.6 K colder. An equator to pole warming at constant pressure levels is found and implications for the zonal wind profiles are drawn under the assumption that the atmosphere is in cyclostrophic balance in the region of 70 to 90 km. The results are in correspondence with direct wind measurements from ground-based observations at 95 km and 105 km altitude. © 1995 Academic Press. All rights reserved.

The aftermath of the impacts of periodic comet Shoemaker-Levy 9 on Jupiter was studied with the Wide Field Planetary Camera 2 on the Hubble Space Telescope. The impact debris particles may owe their dark brown color to organic material rich in sulfur and nitrogen. The total volume of aerosol 1 day after the last impact is equal to the volume of a sphere of radius 0.5 kilometer. In the optically thick core regions, the particle mean radius is between 0.15 and 0.3 micrometer, and the aerosol is spread over many scale heights, from approximately 1 millibar to 200 millibars of pressure or more. Particle coagulation can account for the evolution of particle radius and total optical depth during the month following the impacts.

We present infrared spectra and images of the jovian aurorae taken at wavelengths sensitive to the H-3(+) molecular ion during the period around the impact of Comet Shoemaker Levy-9. The spectra were obtained using CGS4 on the United Kingdom Infrared Telescope and the images using NSF cam on NASA's Infrared Telescope Facility. Comparison with spectra obtained in May, 1993, shows that while the relative intensities of the northern and southern auroral zones prior to and during impact week (July 16 - 22, 1994) were broadly comparable with those of 1993, a few days after the last collision the northern aurora was considerably enhanced and its southern counterpart somewhat depressed. The north/south auroral ratio was returning to more normal values a week later. The effect of material drifting from the impact sites to the southern auroral zone is discussed in relation to these results.

The spatial organization and time dependence of Jupiter's temperatures near 250-millibar pressure were measured through a jovian year by imaging thermal emission at 18 micrometers. The temperature field is influenced by seasonal radiative forcing, and its banded organization is closely correlated with the visible cloud field. Evidence was found for a quasi-periodic oscillation of temperatures in the Equatorial Zone, a correlation between tropospheric and stratospheric waves in the North Equatorial Belt, and slowly moving thermal features in the North and South Equatorial Belts. There appears to be no common relation between temporal changes of temperature and changes in the visual albedo of the various axisymmetric bands.

Analysis of high-spatial-resolution (approximately 0.8 arcsec) methane band and continuum imagery of Neptune's relatively homogeneous Equatorial Region yields significant constraints on (1) the stratospheric gaseous methane mixing ratio (fCH4,s), (2) the column abundances and optical properties of stratospheric and tropospheric hydrocarbon hazes, and (3) the wavelength-dependent single-scattering albedo of the 3-bar opaque cloud. From the center-to-limb behavior of the 7270-angstroms and 8900-angstrom sCH4 bands, the stratospheric methane mixing ratio is limited to fCH4,s1.7 x 10(-3), with a nominal value of fCH4,s = 3.5 x 10(-4), one to two orders of magnitude less than pre-Voyager estimates, but in agreement with a number of recent ultraviolet and thermal infrared measurements, and largely in agreement with the tropopause mixing ratio implied by Voyager temperature measurements. Upper limits to the stratospheric haze mass column abundance and 6190-angstroms and 8900-angstroms haze opacities are 0.61 microgram cm-2 and 0.075 and 0.042, respectively, with nominal values of 0.20 microgram cm-2 and 0.025 and 0.014 for the 0.2-micrometer radius particles preferred by the recent Voyager PPS analysis of Pryor et al. (1992, Icarus 99, 302-316). The tropospheric CH4 haze opacities are comparable to that found in the stratosphere, upper limits of 0.104 and 0.065 at 6190 angstroms and 8900 angstroms, respectively, with nominal values of 0.085 and 0.058. This indicates a column abundance less than 11.0 micrograms cm-2, corresponding to the methane gas content within a well-mixed 3% methane tropospheric layer only 0.1 cm thick near the 1.5-bar CH4 condensation level. Constraints on the single-scattering albedos of these hazes include (1) for the stratospheric component, 6190-angstroms and 8900-angstroms imaginary indices of refraction less than 0.047 and 0.099, respectively, with 0.000 (conservative scattering) being the nominal value at both wavelengths, and (2) CH4 haze single-scattering albedos greater than 0.85 and 0.50 at these two wavelengths, with conservative scattering again begin the preferred value. However, conservative scattering is ruled out for the opaque cloud near 3 bars marking the bottom of the visible atmosphere. Specifically, we find cloud single-scattering albedos of 0.915 +/- 0.006 at 6340 angstroms, 0.775 +/- 0.012 at 7490 angstroms, and 0.803 +/- 0.010 at 8260 angstrom. Global models utilizing a complete global spectrum confirm the red-absorbing character of the 3-bar cloud. The global-mean model has approximately 7.7 times greater stratospheric aerosol content then the Equatorial Region. An analysis of stratospheric haze precipitation rates indicates a steady-state haze production rate of 0.185-1.5 x 10(-14) g cm-2 sec-1, in agreement with recent theoretical photochemical estimates. Finally, reanalysis of the Voyager PPS 7500-angstroms phase angle data utilizing the fCH4,s value derived here confirms the Pryor et al. result of a tropospheric CH4 haze opacity of a few tenths in the 22-30 degrees S latitude region, several times that of the Equatorial Region or of the globe. The factor-of-10 reduction in fCH4,s below that assumed by Pryor et al. implies decreased gas absorption and consequently a decrease in the forward-scattering component of tropospheric aerosols.

The Chicxulub impact crater in Mexico is the site of the impact purported to have caused mass extinctions at the Cretaceous/Tertiary (K/T) boundary. 2-D hydrocode modeling of the impact, coupled with studies of the impact site geology, indicate that between 0.4 and 7.0 x 10(17) g of sulfur were vaporized by the impact into anhydrite target rocks. A small portion of the sulfur was released as SO3 or SO4, which converted rapidly into H2SO4 aerosol and fell as acid rain. A radiative transfer model, coupled with a model of coagulation indicates that the aerosol prolonged the initial blackout period caused by impact dust only if the aerosol contained impurities. A larger portion of sulfur was released as SO2, which converted to aerosol slowly, due to the rate-limiting oxidation of SO2. Our radiative transfer calculations, combined with rates of acid production, coagulation, and diffusion indicate that solar transmission was reduced to 10-20% of normal for a period of 8-13 yr. This reduction produced a climate forcing (cooling) of -300 Wm-2, which far exceeded the +8 Wm-2 greenhouse warming, caused by the CO2 released through the vaporization of carbonates, and therefore produced a decade of freezing and near-freezing temperatures. Several decades of moderate warming followed the decade of severe cooling due to the long residence time of CO2. The prolonged impact winter may have been a major cause of the K/T extinctions.

During the Earth-1 Galileo flyby (December 1990), the Near-Infrared Mapping Spectrometer (NIMS) experiment investigated the illuminated side of the Earth in the spectral range 0.7-5.2 micrometers. Mosaics of the entire terrestrial globe were recorded with a spatial resolution ranging from 100 to 500 km. From these spectra, information is retrieved upon the large-scale temperature structure in the stratosphere and in the mesosphere (0-70 km altitude range) from the inversion of the CO2 bands at 4.3 and 4.8 micrometers. These data also permit monitoring of the cloud temperatures, and derivation of the abundances of several minor atmospheric constituents (H2O, CO, N2O, CH4 and O3). These observations constitute a continuation of the study of the atmospheres of the three planets (i.e. Venus, the Earth and Jupiter) targeted by the Galileo spacecraft during its mission. Observing these atmospheres with the NIMS instrument in the near-infrared will provide a unique data set, useful for comparative planetary studies.

Models possessing an upper haze layer of finite optical depth and a lower cloud layer of infinite optical depth at discrete altitudes are used to bound the wavelength-averaged phase integrals and bolometric albedos of Uranus and Neptune. The models differ in the assumed value of the particles' single scattering phase function and the wavelength dependence of the haze optical depth. A range of phase functions, from the isotropic to those characterizing Titan, Jupiter, and Saturn atmosphere particles, are discussed. The results obtained imply that the meteorological regimes in the observable atmospheres of Uranus and Neptune may differ considerably; internal heat flux could play a much more important role for Neptune than for Uranus.

Radiometric measurement of Uranus and Neptune near 21 and 32 μm have been made with filters with widths of 8 and 5 μm, respectively. The observations at 21 μm, made on 1985 June 19 at the NASA Infrared telescope facility at Mauna Kea, Hawaii, were calibrated against α Boo and corresponded to brightness temperatures of 54.1 ± 0.3 K for Uranus and 58.1 ± 0.3 K for Neptune. The observations at 32 μm were made on three nights: 1983 May 1 and 1984 May 30 and 31, also at the NASA IRTF. Calibrated against the Jovian satellites Callisto (J4) and Ganymede (J3), these measurements corresponded to brightness temperatures of 51.8 ± 1.5 K for Uranus and 55.6 ± 1.2 K for Neptune. The observations are consistent with higher-resolution studies and confirm the general decrease of brightness temperatures going from about 20 to 30 μm.

New center-to-limb (CTL) equatorial region profiles of Neptune have been extracted from spatially well-resolved images. The 8900-A CTL profile entails the presence of material above the 5-mbar level whose optical depth is less than 0.5. CH4-band data admit of thin scattering hazes in the 0.4-1.5 bar pressure level, although optical depths must be lower than 0.05; so thin a haze falls short of the reflected flux at 6340 A, thereby implying the presence of another scattering layer deeper than 1.5 bars. A good fit to the observed reflectivity is obtained by a bright cloud layer with an optical depth of 3.0.

Recent high quality spectral observations have allowed the derivation of constraints on the atmospheric structure of Uranus. The present analysis, which is based on the detailed modeling of a broadband geometric albedo spectrum and high resolution observations of the H2 4-0 quadrupole and 6818.9-A CH4 features, yields (1) a family of models which parameterize an upper tropospheric haze layer, (2) a lower, optically infinite cloud at a given pressure level, (3) the cloud-level methane molar fraction, and (4) the mean ortho/para ratio in the visible atmosphere. The single scattering albedo of atmospheric aerosols exhibits a steep darkening between 5890 and 6040 A.

Ambitious objectives for the NASA/ESA Cassini orbiter/Titan probe mission to the saturnian system include the determination of composition and distribution of material within rings, on satellite surfaces, and within the atmospheres of Saturn and Titan. Dynamic processes which lead to spatial and temporal variations are also to be investigated. Known materials include hydrogen, methane, ammonia, phosphine, germane, and carbon monoxide for Saturn; nitrogen, methane, and higher hydrocarbons for Titan; and water and possibly ammonia ice for the other satellites and rings. Within atmospheres, ammonia (for Saturn) and methane (for Titan) are suspected condensates. Such an assortment of materials in a diverse set of planetary objects calls for versatile yet low power, low mass instrumentation. Polarimetric imagers enable investigations of ices in atmospheres, rings, and satellite surfaces. Acoustooptic tunable filters (AOTFs) specifically enable rapid, high signal-to-noise simultaneous acquisition of orthogonally polarized images in arbitrary spectral bands. Spectral mappers enable the assessment of trace gases within planetary atmospheres. Specifically, digital array scanned interferometers (DASIs) address desired high and low resolution, wide spectral band observations at high throughput, efficiency, and spectral fidelity. AOTFs and DASIs are compact, no moving parts, electronically spectrally adaptive instruments well suited for analyses of material within the saturnian system.

The National Aeronautics and Space Administration (NASA) Infrared Telescope Facility was used to investigate the collision of comet Shoemaker-Levy 9 with Jupiter from 12 July to 7 August 1994. Strong thermal infrared emission lasting several minutes was observed after the impacts of fragments C, G, and R. All impacts warmed the stratosphere and some the troposphere up to several degrees. The abundance of stratospheric ammonia increased by more than 50 times. Impact-related particles extended up to a level where the atmospheric pressure measured several millibars. The north polar near-infrared aurora brightened by nearly a factor of 5 a week after the impacts.

In its first two years of operation since arrival at Jupiter in December 1995, the Near Infrared Mapping spectrometer (NIMS) on the Galileo orbiter spacecraft obtained extensive coverage of the planet, including detailed coverage of the north equatorial belt (NEB) 'hot spot' region and the Great Red Spot. We will present the current state of data analysis including recent results on the abundances and variability of several minor constituents (H2O, CH4, NH3, GeH4, CH3D and PH3) and the cloud structure and morphology. (C) 1999 COSPAR. Published by Elsevier Science Ltd.

This paper presents the analysis of hot spot observations in the Jovian North Equatorial Belt obtained with the near-infrared mapping spectrometer (NIMS) instrument on the Galileo spacecraft. The data were acquired during the closest approach sequences between June 1996 and April 1997. We focus on the spectral window between 4.5 and 5.2 [Jim determining the cloud opacity above 2 bar, the water vapor relative humidity, and the ammonia abundance between 4 and 8 bar. We find a linear relationship between the cloud opacity and the continuum level of the spectrum. For a given radiance level of an individual spectrum, significant variations in the water vapor relative humidity are seen. However, no clear evidence for a relationship between the cloud opacity and the water relative humidity is seen. A cloud structure similar to that measured by the Galileo entry probe, with no significant cloud opacity below 2 bar, is adequate. The air in the hot spots is found to be overall dry, consistent with the probe measurements. None of the considered spectra show water vapor relative humidities exceeding 10%. Significant spatial variations of the water vapor relative humidity are found, and the distribution over the observed hot spot regions is complex. Because of a low sensitivity of the NIMS spectra to ammonia, uncertainties in the derived ammonia abundance are much higher than for water. There is, however, a possible trend in all the observed hot spots toward more ammonia inside than outside the hot spots at the sounded pressure levels. Copyright 1998 by the American Geophysical Union.

A reassessment of ground-based observations confirms to better than a 98% confidence level that the Galileo probe entered a 5-μm hot spot, a region of unusual clarity and dryness, some 900±300 km north of its southern boundary. Cloud conditions at that point were similar to those in the center of this region, some 600 km further north. At the time of the probe entry, the region was evolving to a slightly larger size and even thinner cloud conditions, as evidenced by its rapidly brightening appearance at 4.78 μm. The low reflectivity of the region in red light is highly anticorrelated with 4.78-μm thermal emission, but this correlation breaks down in the blue. In general, the reflectivity of most hot spots is remarkably uniform, although the 4.78-μm thermal emission is highly variable. A cloud structure most consistent with both the observed reflected sunlight and thermal emission properties consists of two layers: (1) a cloud layer above the 450-mbar level extending up to the 150-mbar level that probably consists of submicron sized particles and (2) a tropospheric cloud that is probably below the 1-bar level, possibly ammonia hydrosulfide, with low optical thickness in the infrared. A population of particles larger than ∼3 μm, clearly present at the NH3 ice cloud level outside hot spots, is absent inside them. The NH3 gas abundance near 300–400 mbar pressure does not appear to be unusually depleted in hot spots. Zonal structures in the tropospheric temperature field near the probe entry site were not correlated with the location of 5-μm hot spots but moved at speeds closer to the internal rotation rate of the planet. The properties of the tropospheric thermal waves at the probe entry latitude show little correlation to the properties of the 5-μm hot spot waves. Temperatures at the probe entry site derived from remote sensing are warmer than the Atmospheric Structure Instrument (ASI) experiment results near the tropopause, probably because the low-temperature ASI features are confined to regions smaller than the ∼6000-km resolution characteristic of the remote sensing.

Observations of Jupiter's spectrum near the R5(0) HD line at 6063.88 A are reported. A feature with an equivalent width of 0.065 + or - 0.021 mA is coincident with the expected line. This feature is compared with HD profiles computed for inhomogeneous scattering models for Jupiter to yield a range for the Jovian D/H ratio of 1.0-2.9 x 10 to the -5th. This D/H ratio is in the lower range of previously reported D/H values for Jupiter and corresponds to an essentially solar D/H ratio for Jupiter. The detection of HD features in the presence of probable blends with spectral features of minor atmospheric hydrocarbon molecules is discussed. Such blends may make unambiguous identification of HD features difficult.

Spectral profiles of the H2 S4(0) and S4(1) lines are presented for Neptune on three consecutive nights; no variation is detected in the equivalent widths of the H2 4-0 features to within an observational uncertainty of about 20 percent. Comparisons with previous H2 quadrupole observations indicate that no secular trends have been detected over about 15 yr. The equivalent-width error limits are interpreted in terms of the maximum variability of Neptunian tropospheric aerosols. Specifically, the error bars for the globally averaged equivalent widths of the two H2 quadrupole absorption features constrain the bottom of the visible atmosphere, as defined by a bright optically infinite isotropically scattering cloud, to be 2.9 + or - 0.6 bars, while the methane haze opacity is constrained to be 0.30 + or - 0.25.