Search

The treatment of methylene blue (MB) dye wastewater through the adsorption process has been a subject of extensive research. However, a comprehensive understanding of the thermodynamic aspects of dye solution adsorption is lacking. Previous studies have primarily focused on enhancing the adsorption capacity of methylene blue dye. This study aimed to develop an environmentally friendly and cost-effective method for treating methylene blue dye wastewater and to gain insights into the thermodynamics and kinetics of the adsorption process for optimization. An adsorbent with selective methylene blue dye adsorption capabilities was synthesized using rice straw as the precursor. Experimental studies were conducted to investigate the adsorption isotherms and models under various process conditions, aiming to bridge gaps in previous research and enhance the understanding of adsorption mechanisms. Several adsorption isotherm models, including Langmuir, Temkin, Freundlich, and Langmuir–Freundlich, were applied to theoretically describe the adsorption mechanism. Equilibrium thermodynamic results demonstrated that the calculated equilibrium adsorption capacity (qe) aligned well with the experimentally obtained data. These findings of the study provide valuable insights into the thermodynamics and kinetics of methylene blue dye adsorption, with potential applications beyond this specific dye type. The utilization of rice straw as an adsorbent material presents a novel and cost-effective approach for MB dye removal from wastewater. [ABSTRACT FROM AUTHOR]

One of the direct and unavoidable consequences of global warming-induced rising temperatures is the more recurrent and severe heatwaves. In recent years, even countries like Malaysia seldom had some mild to severe heatwaves. As the Earth's average temperature continues to rise, heatwaves in Malaysia will undoubtedly worsen in the future. It is crucial to characterize and monitor heat events across time to effectively prepare for and implement preventative actions to lessen heatwave's social and economic effects. This study proposes heatwave-related indices that take into account both daily maximum (Tmax) and daily lowest (Tmin) temperatures to evaluate shifts in heatwave features in Peninsular Malaysia (PM). Daily ERA5 temperature dataset with a geographical resolution of 0.25° for the period 1950–2022 was used to analyze the changes in the frequency and severity of heat waves across PM, while the LandScan gridded population data from 2000 to 2020 was used to calculate the affected population to the heatwaves. This study also utilized Sen's slope for trend analysis of heatwave characteristics, which separates multi-decadal oscillatory fluctuations from secular trends. The findings demonstrated that the geographical pattern of heatwaves in PM could be reconstructed if daily Tmax is more than the 95th percentile for 3 or more days. The data indicated that the southwest was more prone to severe heatwaves. The PM experienced more heatwaves after 2000 than before. Overall, the heatwave-affected area in PM has increased by 8.98 km2/decade and its duration by 1.54 days/decade. The highest population affected was located in the central south region of PM. These findings provide valuable insights into the heatwaves pattern and impact. [ABSTRACT FROM AUTHOR]

The current study involves a synthesis of a composite of nickel oxide nanoparticles (NiONPs) with a chromium dopant to yield (Cr/NiONPs). Synthesis of nickel oxide was performed by the co-precipitation method. The synthesis of the composite was conducted by the impregnation method. FTIR, EDX, SEM, and XRD were used to characterize the synthesized materials. The synthesised materials' point zero charges (PZC) were performed using the potentiometric titration method. The obtained results show that the PZC for neat nickel oxide was around 5, and it was around 8 for Cr/NiONPs. The adsorption action of the prepared materials was examined by applying them to remove Reactive Red 2 (RR2) and Crystal Violate (CV) dyes from solutions. The outcomes demonstrated that Cr/NiONPs were stronger in the removal of dyes than NiONPs. Cr/NiONPs achieved 99.9% removal of dyes after 1 h. Adsorption isotherms involving Freundlich and Langmuir adsorption isotherms were also conducted, and the outcomes indicated that the most accurate representation of the adsorption data was offered by Langmuir adsorption isotherms. Additionally, it was discovered that the adsorption characteristics of the NiONPs and Cr/NiONPs correspond well with the pseudo-second-order kinetic model. Each of the NiONPs and Cr/NiONPs was reused five times, and the results display that the effectiveness of the removal of RR2 dye slightly declined with the increase in reuse cycles; it lost only 5% of its original efficiency after the 5 cycles. Generally, Cr/NiONPs showed better reusability than NiONPs under the same conditions. [ABSTRACT FROM AUTHOR]

A straightforward and efficient spectrum technique was created using Ortho-chloranil as the electron acceptor (-acceptor) in a charge transfer (CT) complex formation reaction to determine the concentration of famotidine (FMD) in solutions. Compared to the double-distilled blank solution, the reaction result detected a definite violet colour at a maximum absorption wavelength of 546 nm, For concentrations range 2—28 µg/ml, the technique demonstrated excellent compliance with Beer-Law and Lambert's, as evidenced by its molar absorptivity of 2159.648 L mol−1 cm–1. Lower detection limits of 0.3024 µg/ml and 1.471 µg/ml, respectively, were discovered. The complexes of famotidine and Ortho-chloranil were found to have a 2:1 stoichiometry. Additionally, the suggested approach effectively estimated famotidine concentrations in pharmaceutical formulations, particularly in tablet form. [ABSTRACT FROM AUTHOR]

An accurate assessment of nitrate leaching is important for efficient fertiliser utilisation and groundwater pollution reduction. However, past studies could not efficiently model nitrate leaching due to utilisation of conventional algorithms. To address the issue, the current research employed advanced machine learning algorithms, viz., Support Vector Machine, Artificial Neural Network, Random Forest, M5 Tree (M5P), Reduced Error Pruning Tree (REPTree) and Response Surface Methodology (RSM) to predict and optimize nitrate leaching. In this study, Urea Super Granules (USG) with three different coatings were used for the experiment in the soil columns, containing 1 kg soil with fertiliser placed in between. Statistical parameters, namely correlation coefficient, Mean Absolute Error, Willmott index, Root Mean Square Error and Nash–Sutcliffe efficiency were used to evaluate the performance of the ML techniques. In addition, a comparison was made in the test set among the machine learning models in which, RSM outperformed the rest of the models irrespective of coating type. Neem oil/ Acacia oil(ml): clay/sulfer (g): age (days) for minimum nitrate leaching was found to be 2.61: 1.67: 2.4 for coating of USG with bentonite clay and neem oil without heating, 2.18: 2: 1 for bentonite clay and neem oil with heating and 1.69: 1.64: 2.18 for coating USG with sulfer and acacia oil. The research would provide guidelines to researchers and policymakers to select the appropriate tool for precise prediction of nitrate leaching, which would optimise the yield and the benefit–cost ratio. [ABSTRACT FROM AUTHOR]

The commonly used precipitation-based drought indices typically rely on probability distribution functions that can be suitable when the data exhibit minimal discrepancies. However, in arid and semi-arid regions, the precipitation data often display significant discrepancies due to highly irregular rainfall patterns. Consequently, imposing any probability distributions on the data for drought analysis in such regions may not be effective. To address this issue, this study employs a novel drought index called the Discrepancy Precipitation Index (DPI), specifically designed for arid regions. Unlike traditional methods, the DPI does not impose a probability distribution on the precipitation data; instead, it relies on the discrepancy between the data and the mean value. Drought severity classifications (i.e., Drought-I, Drought-II, and Drought-III) are proposed based on the DPI values. The DPI is used to characterize and assess the meteorological drought years based on annual and monsoonal precipitation over nineteen districts in Western Rajasthan, India, during 1901–2019. Additionally, a novel statistic called Discrepancy Measure (DM) is employed to assess the degree of discrepancy in the precipitation climatology of the districts for annual and monsoon precipitation time series. Based on annual precipitation, Jaisalmer district exhibited the highest number of historical drought years (35), whereas three districts, i.e., Jhunjhunu, Dausa, and Bhilwara exhibited the lowest number of drought years (11). Similarly, based on monsoon precipitation, Jaisalmer and Bhilwara encountered the highest (34) and the lowest (11) number of drought years, respectively. The return period of Drought-II is lower for monsoon precipitation-based DPI as compared to that of the annual precipitation-based DPI for all the districts. The DM and DPI-based total number of droughts are found to be strongly correlated for both annual and monsoon precipitation. The DM value is highest for Jaisalmer and lowest for Bhilwara district. The findings reveal DPI as an efficient tool for assessing drought years, particularly in arid climatic conditions. Moreover, as the DM value increases for a precipitation series, the DPI becomes more effective in capturing drought events. [ABSTRACT FROM AUTHOR]

Exploration of groundwater is an integral part of viable resource growth for society, economy, and irrigation. However, uncontrolled utilization is mainly reported in urban and industries due to the increasing demand for water in semi-arid and arid regions of the world. In the background, groundwater demarcation for potential areas is vital in meeting necessary demand. The current study applied an integrated method comprising the analytical hierarchy process (AHP), multiple influence factors (MIF), combined with a linear regression curve and observatory well data for groundwater prospects mapping. Thematic maps such as flow direction, flow accumulation, elevation map, land use land cover, slope, soil texture, hill shade, geomorphology, normalized vegetation index, and groundwater depth map were generated utilizing remote sensing techniques. The relative weight of each parameter was estimated and then assigned to major and minor parameters. Potential zones for groundwater were classified into five classes, namely very good, good, moderate, poor, and very poor, based on AHP and MIF methods. A spatially explicit sensitivity and uncertainty analysis method to a GIS-based multi-criteria groundwater potential zone model is presented in this research. The study addressed a flaw in the way groundwater potential mapping results are typically presented in GIS-based multi-criteria decision analysis studies, where discrete class outputs are used without any assessment of their certainty with respect to variations in criteria weighting, which is one of the main contributors to output uncertainty. The study region is categorized based on inferred results as very poor, poor, marginal, and very good in potential ground quality 3.04 km2 is considered extremely poor, 3.33 km2 is considered poor, 64.42 km2 is considered very good, and 85.84 km2 is considered marginal zones, which shows reliable and potential implementation. The outcomes of AHP and MIF were validated by linear regression curve and actual water table in a study area. The study results help to formulate the potential demarcation of groundwater zones for future sustainable planning and development of groundwater sources. This study may be helpful to provide a cost-effective solution to water resources crises. The current study finding may be helpful for decision-makers and administrative professionals for sustainable management of groundwater resources for present and future demands. [ABSTRACT FROM AUTHOR]

In the context of degradation of soil health, environmental pollution, and yield stagnation in the rice–wheat system in the Indo-Gangetic Plains of South Asia, an experiment was established in split plot design to assess the long-term effect of crop residue management on productivity and phosphorus requirement of wheat in rice–wheat system. The experiment comprised of six crop residue management practices as the main treatment factor with three levels (0, 30 and 60 kg P2O5 ha–1) of phosphorus fertilizer as sub-treatments. Significant improvement in soil aggregation, bulk density, and infiltration rate was observed under residue management (retention/incorporation) treatments compared to residue removal or residue burning. Soil organic carbon (SOC), available nutrient content (N, P, and K), microbial count, and enzyme activities were also significantly higher in conservation tillage and residue-treated plots than without residue/burning treatments. The residue derived from both crops when was either retained/incorporated improved the soil organic carbon (0.80%) and resulted in a significant increase in SOC (73.9%) in the topsoil layer as compared to the conventional practice. The mean effect studies revealed that crop residue management practices and phosphorus levels significantly influenced wheat yield attributes and productivity. The higher grain yield of wheat was recorded in two treatments, i.e. the basal application of 60 kg P2O5 ha–1 without residue incorporation and the other with half the P-fertilizer (30 kg P2O5 ha–1) with rice residue only. The grain yield of wheat where the rice and wheat residue were either retained/incorporated without phosphorus application was at par with 30 and 60 kg P2O5ha–1. Phosphorus levels also significantly affected wheat productivity and available P content in the soil. Therefore, results suggested that crop residue retention following the conservation tillage approach improved the yield of wheat cultivated in the rice–wheat cropping system. [ABSTRACT FROM AUTHOR]

In the plains of western North India, traditional rice and wheat cropping systems (RWCS) consume a significant amount of energy and carbon. In order to assess the long-term energy budgets, ecological footprint, and greenhouse gas (GHG) pollutants from RWCS with residual management techniques, field research was conducted which consisted of fourteen treatments that combined various tillage techniques, fertilization methods, and whether or not straw return was present in randomized block design. By altering the formation of aggregates and the distribution of carbon within them, tillage techniques can affect the dynamics of organic carbon in soil and soil microbial activity. The stability of large macro-aggregates (> 2 mm), small macro-aggregates (2.0–2.25 mm), and micro-aggregates in the topsoil were improved by 35.18%, 33.52%, and 25.10%, respectively, over conventional tillage (0–20 cm) using tillage strategies for conservation methods (no-till in conjunction with straw return and organic fertilizers). The subsoil (20–40 cm) displayed the same pattern. In contrast to conventional tilling with no straw returns, macro-aggregates of all sizes and micro-aggregates increased by 24.52%, 28.48%, and 18.12%, respectively, when conservation tillage with organic and chemical fertilizers was used. The straw return (aggregate-associated C) also resulted in a significant increase in aggregate-associated carbon. When zero tillage was paired with straw return, chemical, and organic fertilizers, the topsoil's overall aggregate-associated C across all aggregate proportions increased. Conversely, conventional tillage, in contrast to conservation tillage, included straw return as well as chemical and organic fertilizers and had high aggregate-associated C in the subsurface. This study finds that tillage techniques could change the dynamics of microbial biomass in soils and organic soil carbon by altering the aggregate and distribution of C therein. [ABSTRACT FROM AUTHOR]

Recently, the spread of white spot disease in shrimps has a major impact on the aquaculture activity worldwide affecting the economy of the countries, especially South-East Asian countries like Vietnam. This deadly disease in shrimps is caused by the White Spot Syndrome Virus (WSSV). Researchers are trying to understand the spread and control of this disease by doing field and laboratory studies considering effect of environmental conditions on shrimps affected by WSSV. Generally, they have not considered spatial factors in their study. Therefore, in the present study, we have used spatial (distances to roads and factories) as well as physio-chemical factors of water: Chemical Oxygen Demand (COD), Dissolved Oxygen (DO), Salinity, NO3, P3O4 and pH, for developing WSSV susceptibility maps of the area using Decision Tree (DT)-based Machine Learning (ML) models namely Random Tree (RT), Extra Tree (ET), and J48. Model's performance was evaluated using standard statistical measures including Area Under the Curve (AUC). The results indicated that ET model has the highest accuracy (AUC: 0.713) in predicting disease susceptibility in comparison to other two models (RT: 0.701 and J48: 0.641). The WSSV susceptibility maps developed by the ML technique, using DT (ET) method, will help decision makers in better planning and control of spatial spread of WSSV disease in shrimps. [ABSTRACT FROM AUTHOR]

Rainfall is crucial for the development and management of water resources. Six hybrid soft computing models, including multilayer perceptron (MLP)–Henry gas solubility optimization (HGSO), MLP–bat algorithm (MLP–BA), MLP–particle swarm optimization (MLP–PSO), radial basis neural network function (RBFNN)–HGSO, RBFNN–PSO, and RBFGNN–BA, were used in this study to forecast monthly rainfall at two stations in Malaysia (Sara and Banding). Different statistical measures (mean absolute error (MAE) and Nash–Sutcliffe efficiency (NSE) and percentage of BIAS (PBIAS)) and a Taylor diagram were used to assess the models' performance. The results indicated that the MLP–HGSO performed better than the other models in forecasting rainfall at both stations. In addition, transition matrices were computed for each station and year based on the conditional probability of rainfall or absence of rainfall on a given month. The values of MAE for testing processes for the MLP–HGSO, MLP–PSO, MLP–BA, RBFNN–HGSO, RBFNN–BA, and RBFNN–PSO at the first station were 0.712, 0.755, 0.765, 0.717, 0.865, and 0.891, while the corresponding NSE and PBIAS values were 0.90–0.23, 0.83–0.29, 0.85–0.25, 0.87–0.27, 0.81–0.31, and 0.80–0.35, respectively. For the second station, the values of MAE were found 0.711, 0.743, 0.742, 0.719, 0.863 and 0.890 for the MLP–HGSO, MLP–PSO, MLP–BA, RBFNN–HGSO, RBFNN–BA, and RBFNN–PSO during testing processes and the corresponding NSE–PBIAS values were 0.92–0.22, 0.85–0.28, 0.89–0.26, 0.91–0.25, 0.83–0.31, 0.82–0.32, respectively. Based on the outputs of the MLP–HGSO, the highest rainfall was recorded in 2012 with a probability of 0.72, while the lowest rainfall was recorded in 2006 with a probability of 0.52 at the Sara Station. In addition, the results indicated that the MLP–HGSO performed better than the other models within the Banding Station. According to the findings, the hybrid MLP–HGSO was selected as an effective rainfall prediction model. [ABSTRACT FROM AUTHOR]

Floods are both complex and destructive, and in most parts of the world cause injury, death, loss of agricultural land, and social disruption. Flood susceptibility (FS) maps are used by land‐use managers and land owners to identify areas that are at risk from flooding and to plan accordingly. This study uses machine learning ensembles to produce objective and reliable FS maps for the Haraz watershed in northern Iran. Specifically, we test the ability of the support vector regression (SVR), together with linear kernel (LK), base classifier (BC), and hyper‐parameter optimization (HPO), to identify flood‐prone areas in this watershed. We prepared a map of 201 past floods to predict future floods. Of the 201 flood events, 151 (75%) were used for modeling and 50 (25%) were used for validation. Based on the relevant literature and our field survey of the study area, 10 effective factors were selected and prepared for flood zoning. The results show that three of the 10 factors are most important for predicting flood‐sensitive areas, specifically and in order of importance, slope, distance to the river and river. Additionally, the SVR‐HPO model, with area under the curve values of 0.986 and 0.951 for the training and testing phases, outperformed the other two tested models. [ABSTRACT FROM AUTHOR]

Recent technological advances have made it possible to produce particles with nanometer dimensions that are uniformly and steadily suspended in traditional solar liquids and have enhanced the impact of thermo-physical parameters. In this research, a three-dimensional flat plate solar collector was built using a thin flat plate and a single working fluid pipe. The physical model was solved computationally under conditions of conjugated laminar forced convection in the range 500 ≤ Re ≤ 1900 and a heat flux of 1000W/m². Distilled water (DW) and different types of hybrid nanofluids (namely, 0.1%-Al2O3@Cu/DW, 0.1%-MWCNTs@Fe3O4/DW, 0.3%-MWCNTs@Fe3O4/DW, 0.5%-Ag@MgO/DW, 1%-Ag@MgO/DW, 1%-S1 and 1%-S2, where MWCNTs are multi-wall carbon nanotubes, S1 means 2CuO--1Cu and S2 means 1CuO--2Cu nanocomposites) were evaluated via a set of parameters. The numerical results revealed that, by increasing the working fluid velocity (the Reynolds number), the average heat transfer coefficient, pressure loss, heat gain and solar collector efficiency were increased. Meanwhile, outlet fluid temperature and flat plate surface temperature were decreased. At Re = 1900, 1%-S2 and 1%-S1 presented higher thermal performance enhancement by 44.28% and 36.72% relative to DW. Moreover, low thermal performance enhancement of 7.59% and 7.44% were reported by 0.1%-Al2O3@Cu/DW and 0.3%-MWCNTs@Fe3O4/DW, respectively. [ABSTRACT FROM AUTHOR]

The flat-plate solar collector (FPSC) three-dimensional (3D) model was used to numerically evaluate the energy and economic estimates. A laminar flow with 500 ≤ Re ≤ 1900, an inlet temperature of 293 K, and a solar flux of 1000W/m² were assumed the operating conditions. Two mono nanofluids, CuO-DW and Cu-DW, were tested with different shapes (Spherical, Cylindrical, Platelets, and Blades) and different volume fractions. Additionally, hybrid nanocomposites from CuO@Cu/DW with different shapes (Spherical, Cylindrical, Platelets and Blades), different mixing ratios (60%+40%, 50%+50% and 40%+60%) and different volume fractions (1 volume%, 2 volume%, 3 volume% and 4 volume%) were compared with mono nanofluids. At 1 volume% and Re = 1900, CuO-Platelets demonstrated the highest pressure drop (33.312 Pa). CuO-Platelets achieved the higher thermal enhancement with (8.761%) at 1 vol.% and Re = 1900. CuO-Platelets reduced the size of the solar collector by 25.60%. Meanwhile, CuO@Cu-Spherical (40:60) needed a larger collector size with 16.69% at 4 vol.% and Re = 1900. CuO-Platelets with 967.61, CuO -- Cylindrical with 976.76, Cu Platelets with 983.84, and Cu-Cylindrical with 992.92 presented the lowest total cost. Meanwhile, the total cost of CuO -- Cu -- Platelets with 60:40, 50:50, and 40:60 was 994.82, 996.18, and 997.70, respectively. [ABSTRACT FROM AUTHOR]

Increasing global energy consumption has become an urgent problem as natural energy sources such as oil, gas, and uranium are rapidly running out. Research into renewable energy sources such as solar energy is being pursued to counter this. Solar energy is one of the most promising renewable energy sources, as it has the potential to meet the world's energy needs indefinitely. This study aims to develop and evaluate artificial intelligence (AI) models for predicting hourly global irradiation. The hyperparameters were optimized using the Broyden-Fletcher-Goldfarb-Shanno (BFGS) quasi-Newton training algorithm and STATISTICA software. Data from two stations in Algeria with different climatic zones were used to develop the model. Various error measurements were used to determine the accuracy of the prediction models, including the correlation coefficient, the mean absolute error, and the root mean square error (RMSE). The optimal support vector machine (SVM) model showed exceptional efficiency during the training phase, with a high correlation coefficient (R = 0.99) and a low mean absolute error (MAE = 26.5741 Wh/m²), as well as an RMSE of 38.7045 Wh/m² across all phases. Overall, this study highlights the importance of accurate prediction models in the renewable energy, which can contribute to better energy management and planning. [ABSTRACT FROM AUTHOR]

This study addresses the issue of eliminating Congo red dye from aqueous solutions through green pyrolysis of hybrid iron oxides/graphene-coated iron slag. A novel adsorbent was developed, utilizing cost-effective date fruit-derived graphite and iron slag byproducts. The resulting macroporous structures resemble two-dimensional graphene sheets on an iron slag substrate. Optimal production conditions were determined as pH 12 and 1 g/50 mL slag dosage for 3 h, achieving a remarkable dye removal efficiency of over 95%. Furthermore, a maximum removal percentage of 97% was attained at pH 3 within 60 min, using 0.2 g of adsorbent per 50 mL of solution with an initial dye concentration of 50 mg/L. Sorption data fit well with both the Freundlich and pseudo-second-order models. Increasing the number of composite sorbents in the column resulted in enhanced sorption capacity and prolonged breakthrough time, effectively represented by the belter model. Based on these findings, we recommend the application of this innovative adsorbent for efficient removal of Congo red dye from wastewater. [ABSTRACT FROM AUTHOR]