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Ocean-island basalts (OIBs) provide a unique insight into the extent of lithological heterogeneity (peridotite vs pyroxenite) in the Earth’s convecting mantle. However, crustal processing of these mantle melts significantly influences minor-element concentrations in olivine phenocrysts, challenging the suitability of this widely-used approach to identify lithological variations in their mantle source. Using a numerical model of magma recharge, mixing and diffusional re-equilibration we show that this type of crustal processing -- which is widely observed in OIBs -- results in elevated Ni and lower Ca contents of Fo-rich olivine causing erroneously high estimates of the proportion of pyroxenite-derived melt. We applied our model of magma recharge and mixing to several OIBs including the Galápagos, Canaries and La Réunion. In particular, we critically examine olivine compositional variations in basalts from the eastern Galápagos, which display Sr- and Pb-isotope ratios similar to N-MORBs. Whilst previous interpretations (based on olivine chemistry) argue for a significant contribution from pyroxenite-derived melt, our results indicate that the postulated presence of pyroxenite in the eastern Galápagos mantle is an artefact of processing of magmas and their olivine cargo as they transition through the crust, consistent with major element and isotopic evidence for a dominantly peridotitic source in this region. This new model for magma recharge and mixing may have important implications for our understanding of lithological heterogeneity beneath OIBs globally, and highlights the importance of considering crustal processes when attempting to interpret olivine compositions with regard to mantle heterogeneity.

The poorly constrained nature of the physical transfer of sulfides along magmatic conduits\ud has implications for the genesis and localization of mineral deposits as well as for understanding the\ud large-scale mobility of volatiles and metals across different geochemical reservoirs. Our natural\ud laboratory to address this topic is a sulfide-bearing ultramafic pipe emplaced in the deep crust of the\ud Ivrea-Verbano Zone, northwest Italy. The pipe comprises a volatile-rich peridotite, that contains\ud disseminated, blebby and semi-massive sulfides enriched in nickel, copper and platinum-group\ud elements. The integration of electron backscatter diffraction orientation data and 3D X-ray computed\ud tomography analyses from this study indicate that 1) most of olivine crystallized upon emplacement\ud of the magma; and 2) the shape and texture of the intra-granular sulfide blebs principally hosted\ud within the central portions of the pipe reflect early sulfide saturation and 3) that marginal areas\ud 1recorded higher strain compare to the cores of the pipes. The differences in the size distribution of\ud the sulfide grains between the central and marginal areas of the pipe are due to magma emplacement\ud dynamics. The larger sulfide aggregates forming the bulk of the Ni-Cu-PGE sulfide mineralization\ud along the margins of the pipe are interpreted to form by coalescence of a large number of smaller\ud sulfide droplets. The observed sulfide size distribution between the central and marginal areas of the\ud Valmaggia pipe is principally due to the dynamics of the magma upon emplacement, and locally\ud record the role of water- and carbon dioxide-bearing volatiles in the physical entrainment of dense\ud sulfide liquids. These processes provide a viable mechanism to transport sulfides enriched in\ud chalcophile and siderophile metals from the upper mantle into the lower continental crust, where\ud they may be available for later remobilization into ore systems that may form subsequently in the\ud middle and upper crust.

The Holocene Series/Epoch is the most recent series/epoch in the geological timescale, spanning the interval from 11,700 yr to the present day. Together with the subadjacent Pleistocene, it comprises the Quaternary System/Period. The Holocene record contains diverse geomorphological, biological, climatological and archaeological evidence, within sequences that are often continuous and extremely well-preserved at decadal, annual and even seasonal resolution. As a consequence, the Holocene is perhaps the most intensively-studied series/epoch within the entire Geological Time Scale. Yet until recently little attention had been paid to a formal subdivision of the Holocene. Here we describe an initiative by the Subcommission on Quaternary Stratigraphy (SQS) of the International Commission on Stratigraphy (ICS) to develop a formal stratigraphical subdivision of the Holocene, with three new stages/ages, two underpinned by Global Boundary Stratotype Sections and Points (GSSPs in an ice core, and a third in a speleothem. These stages/ages are defined together with their equivalent subseries/subepochs. The new stages/ages are the Greenlandian with its GSSP in the Greenland NGRIP2 ice core and dated at 11,700 yr b2k (before 2000 CE); the Northgrippian with its GSSP in the Greenland NGRIP1 ice core and dated to 8236 yr b2k; and the Meghalayan, with its GSSP in a speleothem from Mawmluh Cave, northeastern India, with a date of 4250 yr b2k. This subdivision was formally ratified by the Executive Committee of the International Union of Geological Sciences (IUGS) on 14th June 2018.

© 2018 Collegium Boreas. Published by John Wiley & Sons Ltd During a pre-site survey and construction of a new metro route and station in Copenhagen, fossiliferous organic-rich sediments were encountered. This paper reports on multidisciplinary investigations of these organic sediments, which occurred beneath a sediment succession with a lower till, glacifluvial sand and gravel, an upper till and glacifluvial sand. The organic sediments were underlain by glacifluvial sand and gravel. The organic-rich sediments, which were up to 0.5 m thick, accumulated in a low-energy environment, possibly an oxbow lake. They were rich in plant fossils, which included warmth-demanding trees and other species, such as Najas minor, indicating slightly higher summer temperatures than at present. Freshwater shells were also frequent. Bithynia opercula allowed the sediments to be put into an aminostratigraphical framework. The amino acid racemization (AAR) ratios indicate that the organic sediments formed during Marine Isotope Stage 7 (MIS 7), which is consistent with optically stimulated luminescence dating that gave ages of 206 and 248 ka from the underlying minerogenic deposit. The assemblages from Trianglen are similar to interglacial deposits from the former Free Port (1.4 km away) in Copenhagen, except that Corbicula and Pisidium clessini were not found at Trianglen. The presence of these bivalves at the Free Port and the ostracod Scottia tumida at Trianglen indicates a pre-Eemian age. AAR data from archived Bithynia opercula from the Free Port were almost identical to those from Trianglen, indicating that the two sites are contemporary. We suggest the Trianglen interglacial be used as a local name for the MIS 7 interglacial deposits in Copenhagen. MIS 7 deposits have rarely been documented from the region, but MIS 7 deposits may have been mistaken for other ages. The use of AAR ratios in Bithynia opercula has a great potential for correlation of interglacial non-marine deposits in mainland northern Europe.

Microbially mediated early diagenetic pyrite formation in the immediate vicinity of organic material has been the favoured mechanism by which to explain widespread preservation of soft-bodied organisms in late Ediacaran sedimentary successions, but an alternative rapid silicification model has been proposed for macrofossil preservation in sandstones of the Ediacara Member in South Australia. We here provide petrological evidence from Nilpena National Heritage Site and Ediacara Conservation Park to demonstrate the presence of grain20 coating iron oxides, framboidal hematite, and clay minerals along Ediacara Member sandstone bedding planes, including fossil-bearing bed soles. SEM and petrographic data reveal that framboids and grain coatings, which we interpret as oxidized pyrite, formed before the precipitation of silica cements. In conjunction with geochemical and taphonomic considerations, our data suggest that anactualistically high concentrations of silica need not be invoked to explain Ediacara Member fossil preservation: we conclude that the pyritic ‘death mask’ model remains compelling.

Estimates of the volume of the earliest crust based on zircon ages and radiogenic isotopes remain equivocal. Stable isotope\ud systems, such as molybdenum, have the potential to provide further constraints but remain underused due to the lack of complementarity between mantle and crustal reservoirs. Here we present molybdenum isotope data for Archaean komatiites and\ud Phanerozoic komatiites and picrites and demonstrate that their mantle sources all possess subchondritic signatures complementary to the superchondritic continental crust. These results confirm that the present-day degree of mantle depletion was\ud achieved by 3.5 billion years ago and that Earth has been in a steady state with respect to molybdenum recycling. Mass balance\ud modelling shows that this early mantle depletion requires the extraction of a far greater volume of mafic-dominated protocrust\ud than previously thought, more than twice the volume of the continental crust today, implying rapid crustal growth and destruction in the first billion years of Earth’s history

The penultimate deglaciation (PDG, ∼138–128 thousand years before present, hereafter ka) is the transition from the penultimate glacial maximum (PGM) to the Last Interglacial (LIG, ∼129–116 ka). The LIG stands out as one of the warmest interglacials of the last 800 000 years (hereafter kyr), with high-latitude temperature warmer than today and global sea level likely higher by at least 6 m. Considering the transient nature of the Earth system, the LIG climate and ice-sheet evolution were certainly influenced by the changes occurring during the penultimate deglaciation. It is thus important to investigate, with coupled atmosphere–ocean general circulation models (AOGCMs), the climate and environmental response to the large changes in boundary conditions (i.e. orbital configuration, atmospheric greenhouse gas concentrations, ice-sheet geometry and associated meltwater fluxes) occurring during the penultimate deglaciation. A deglaciation working group has recently been set up as part of the Paleoclimate Modelling Intercomparison Project (PMIP) phase 4, with a protocol to perform transient simulations of the last deglaciation (19–11 ka; although the protocol covers 26–0 ka). Similar to the last deglaciation, the disintegration of continental ice sheets during the penultimate deglaciation led to significant changes in the oceanic circulation during Heinrich Stadial 11 (∼136–129 ka). However, the two deglaciations bear significant differences in magnitude and temporal evolution of climate and environmental changes. Here, as part of the Past Global Changes (PAGES)-PMIP working group on Quaternary interglacials (QUIGS), we propose a protocol to perform transient simulations of the penultimate deglaciation under the auspices of PMIP4. This design includes time-varying changes in orbital forcing, greenhouse gas concentrations, continental ice sheets as well as freshwater input from the disintegration of continental ice sheets. This experiment is designed for AOGCMs to assess the coupled response of the climate system to all forcings. Additional sensitivity experiments are proposed to evaluate the response to each forcing. Finally, a selection of paleo-records representing different parts of the climate system is presented, providing an appropriate benchmark for upcoming model–data comparisons across the penultimate deglaciation.

Uslular and Gençalioğlu‐Kuşcu (2018) have written a lengthy, and highly critical, comment about McNab et al. (2018, https://doi.org/10.1002/2017GC007251) which states that our data compilation for Neogene (and Quaternary) volcanic rocks from Anatolia is selective, inconsistent, and not fit for purpose. We state for the record that our compilation is not based on analyses from the published GEOROC database. Uslular and Gençalioğlu‐Kuşcu (2018) also state that our subdivision of this database into three broad longitudinal categories is unrealistic since it does not consider the full range of different tectonic units. They conclude that our interpretation of the link between Neogene‐Quaternary volcanism and uplift of Anatolia is erroneous. We refute this rather strongly worded comment by carefully addressing the five substantive issues raised.

International audience; The oxidation state of volcanic gas emissions influences the composition of the exosphere and planetary habitability. It is widely considered to be associated with the oxidation state of the melt from which volatiles exsolve. Here, we present a global synthesis of volcanic gas measurements. We define the mean oxidation state of volcanic gas emissions on Earth today and show that, globally, gas oxidation state, relative to rock buffers, is a strong function of emission temperature, increasing by several orders of magnitude as temperature decreases. The trend is independent of melt composition and geodynamic setting. This observation may explain why the mean oxidation state of volcanic gas emissions on Earth has apparently increased since the Archean, without a corresponding shift in melt oxidation state. We argue that progressive cooling of the mantle and the cessation of komatiite generation should have been accompanied by a substantial increase of the oxidation state of volcanic gases around the onset of the Great Oxidation Event. This may have accelerated or facilitated the transition to an oxygen-rich atmosphere. Overall, our data, along with previous work, show that there are no single nor simple relationships between mantle-, magma- and volcanic gas-redox states.

Ice–ocean interactions at the bases of Antarctic ice shelves are rarely observed, yet have a profound influence on ice sheet evolution and stability. Ice sheet models are highly sensitive to assumed ice shelf basal melt rates; however, there are few direct observations of basal melting or the oceanographic processes that drive it, and consequently our understanding of these interactions remains limited. Here we use in situ observations from the Ross Ice Shelf to examine the oceanographic processes that drive basal ablation of the world’s largest ice shelf. We show that basal melt rates beneath a thin and structurally important part of the shelf are an order of magnitude higher than the shelf-wide average. This melting is strongly influenced by a seasonal inflow of solar-heated surface water from the adjacent Ross Sea Polynya that downwells into the ice shelf cavity, nearly tripling basal melt rates during summer. Melting driven by this frequently overlooked process is expected to increase with predicted surface warming. We infer that solar heat absorbed in ice-front polynyas can make an important contribution to the present-day mass balance of ice shelves, and potentially impact their future stability. High melt rates in a key location beneath the Ross Ice Shelf result from a seasonal inflow of water heated in the Ross Sea Polynya, according to in situ observations.

Marine radiocarbon dates, corrected for ocean-atmosphere reservoir age offsets (R-ages) are widely used to constrain marine chronologies. R-ages also represent the surface boundary condition that links the ocean interior radiocarbon distribution (i.e. ‘radiocarbon ventilation ages’) to the ocean’s large-scale overturning circulation. Understanding how R-ages have varied over time is therefore essential both for accurate dating and for investigations into past ocean circulation/carbon cycle interactions. A number or recent studies have shed light on surface reservoir age changes over the last deglaciation; however a clear picture of global/regional spatiotemporal patterns of variability has yet to emerge. Here we combine new and existing reservoir age estimates to show coherent but distinct regional reservoir age trends in the sub-polar North Atlantic and Southern Ocean. It can be further shown that similar, but lower amplitude changes occurred at mid-latitudes in each hemisphere. An apparent link between regional patterns of reservoir age variability and the ‘thermal bipolar seesaw’ suggests a causal link with changes in ocean circulation, mixed layer depth, and/or sea ice dynamics. A further link to atmospheric CO2 is also apparent, and underlines a potentially dominant role for changes in the ocean’s ‘disequilibrium carbon’ pool, rather than changes in ocean transport. The existence of significant R-age variability over the last deglaciation poses a problem for marine radiocarbon age calibrations. However, its apparent regional consistency also raises the prospect of developing region-specific marine calibration curves for radiocarbon-dating purposes.

The amount of dioxygen (O2) in the atmosphere may have varied from as little as 10 % to as high as 35 % during the Phanerozoic eon (541 Ma–Present). These changes in the amount of O2 are large enough to have lead to changes in atmospheric mass, which may alter the radiative budget of the atmosphere, leading to this mechanism being invoked to explain discrepancies between climate model simulations and proxy reconstructions of past climates. Here we present the first fully 3D numerical model simulations to investigate the climate impacts of changes in O2 during different climate states using the HadGEM3-AO and HadCM3-BL models. We show that simulations with an increase in O2 content result in increased global mean surface air temperature under conditions of a pre-industrial Holocene climate state, in agreement with idealised 1D and 2D modelling studies. We demonstrate the mechanism behind the warming is complex and involves trade-off between a number of factors. Increasing atmospheric O2 leads to a reduction in incident shortwave radiation at Earth's surface due to Rayleigh scattering, a cooling effect. However, there is a competing warming effect due to an increase in the pressure broadening of greenhouse gas absorption lines and dynamical feedbacks, which alter the meridional heat transport of the ocean, warming polar regions and cooling tropical regions. Case studies from past climates are investigated using HadCM3-BL which show that in the warmest climate states, increasing oxygen may lead to a temperature decrease, as the equilibrium climate sensitivity is lower. For the Maastrichtian (72.1–66.0 Ma), increasing oxygen content leads to a better agreement with proxy reconstructions of surface temperature at that time irrespective of the carbon dioxide content. For the Asselian (298.9–295.0 Ma), increasing oxygen content leads to a warmer global mean surface temperature and reduced carbon storage on land, suggesting that high oxygen content may have been a contributing factor in preventing a Snowball Earth during this period of the early Permian. These climate model simulations reconcile the surface temperature response to oxygen content changes across the hierarchy of model complexity and highlight the broad range of Earth system feedbacks that need to be accounted for when considering the climate response to changes in atmospheric oxygen content.

An accurate description of the carbonate system in porewaters is valuable in studies involving the degradation of sedimentary organic matter, recrystallization of calcium carbonate minerals, calculations of mineral saturation state and cycling of ions affected by pH. Here we analyze water chemistry of porewater extracted using centrifugation and Rhizon samplers from hemipelagic sediments in the Gulf of Aqaba, Red Sea, and a shallow salt marsh from Norfolk, England. In both study areas, the data is internally consistent for each porewater separation technique, but the measured isotopic composition of the dissolved inorganic carbon (δ13C(DIC)) differs between the two techniques. We performed laboratory experiments that show that both Rhizons and centrifugation are prone to degassing of CO2 enriched with 12C. We suggest that during sampling with Rhizons, air fills the voids left by extracted porewater; combined with the membrane’s design to exclude air, some of the aqueous CO2 diffuses into these air bubbles instead of the sampler. Rhizons produce reliable calcium, strontium, manganese and barium concentration data when soaked in deionized water and then flushed with the sample immediately prior to sampling. However, porewater extractions with Rhizons are less reliable for analyses of pH and δ13C(DIC). Centrifugation produces reliable carbonate chemistry and major element data when tubes are fully filled without headspace and sealed tightly. Working in CO2 low/free atmosphere (e.g., N2 glovebox) enhances the chance of losing CO2 from the sample in both sampling techniques due to increased negative gradient of CO2 between the core and its surrounding.

Copyright © 2016, SEPM (Society for Sedimentary Geology). The mechanisms by which soft-bodied organisms were preserved in late Ediacaran deep-marine environments are revealed by petrographic and geochemical investigation of fossil-bearing surfaces from the Conception and St. John's groups (Newfoundland, Canada). Framboidal pyrite veneers are documented on fossilbearing horizons at multiple localities. The pyrite is interpreted to have formed via microbial processes in the hours to weeks following burial of benthic communities. This finding extends the 'death mask' model for Ediacaran soft-tissue preservation to deep-marine settings. Remineralization of pyrite to iron oxides and oxyhydroxides is recognized to result from recent oxidation by meteoric fluids in the shallow subsurface. Consideration of other global Ediacaran macrofossil occurrences reveals that pyrite is observed in association with Ediacaran macrofossils preserved in all four previously described styles of moldic preservation (Flinders-, Conception-, Fermeuse- and Nama-type). This suggests that replication of external morphology by framboidal pyrite was a widespread mechanism by which softbodied organisms and associated organic surfaces were preserved, in multiple facies and depositional environments, 580-541 million years ago. The extensive global burial of pyrite in medium- to coarse-grained clastics and carbonates is a previously unrecognized yet potentially significant geological sink of iron and sulfur, and may have contributed to rising atmospheric and marine oxygen concentrations across the late Ediacaran interval.

The suite of sedimentary landforms produced on continental shelves by fast-flowing ice streams is typified by features that are elongate and streamlined in the direction of past ice flow (e.g. Stokes & Clark 2001; Ottesen et al. 2005 a ; Livingstone et al. 2012). By contrast, the slower-flowing parts of an ice sheet, located between ice streams and fed by drainage basins that are often an order of magnitude or more smaller than the interior basins feeding the ice stream, have a very different set of characteristic submarine landforms; these are orientated predominantly transverse to the direction of past ice flow (Ottesen & Dowdeswell 2009; Klages et al. 2013, 2016). In addition, on many high-latitude shelf-banks glacial landforms produced beneath and at the margins of ice sheets are often reworked by the ploughing action of iceberg keels, sometimes to the point where these primary depositional landforms are almost obliterated (e.g. Dowdeswell et al. 1993, 2014). Submarine landforms from the western margin of the former Eurasian Ice Sheet, which extended across the shallow banks and deeper intervening troughs on the continental shelves of Norway and Svalbard at the Last Glacial Maximum (LGM) (Svendsen et al. 2004; Ottesen et al. 2005 a ), are used to illustrate this inter-ice stream palaeo-glacial setting (Fig. 1). In these locations, ice flux is limited by relatively small drainage-basin size and ice flow is likely to be slow relative to the 103–104 m a−1 velocities of adjacent ice streams (Dowdeswell & Siegert 1999). Fig. 1. ( a ) Location of study areas offshore of Norway and Svalbard (red boxes; map from IBCAO v. 3.0). Bathymetric data showing the pattern of shallow banks and intervening cross-shelf troughs offshore of ( b ) NW Norway and ( c ) NW Spitsbergen. WI, Wijdefjorden; KR, Krossfjorden. ### Description The …

A series of plate impact experiments were conducted to investigate the shock response of a simulant for adobe, a traditional form of building material widely used around the world. Air dried bricks were sourced from the London brick company, dry machined and impacted at a range of velocities in a single stage gas gun. The shock Hugoniot was determined (Us =2.26up+0.37) as well as release information. The material was found to behave in a manner which was similar to that of loose sand and considerably less stiff than a weak porous sandstone. The effect of any cementing of the grains was examined by shocking powdered samples contained within a cell arrangement.

Melting is pervasive along the ice surrounding Antarctica. On the surface of the grounded ice sheet and floating ice shelves, extensive networks of lakes, streams and rivers both store and transport water. As melting increases with a warming climate, the surface hydrology of Antarctica in some regions could resemble Greenland’s present-day ablation and percolation zones. Drawing on observations of widespread Antarctica surface water and decades of study in Greenland, we consider three modes by which meltwater could impact Antarctic mass balance: increased runoff, meltwater injection to the bed, and meltwater-induced ice-shelf fracture, all of which may contribute to future ice sheet mass loss from Antarctica.

As well as gases that regulate climate over geological time, volcanoes emit prodigious quantities of metals into the atmosphere, where they have key roles as catalysts, pollutants and nutrients. Here we compare measurements of arc basaltic volcano metal emissions with those from hotspot settings. As well as emitting higher fluxes of metals (similar to those building ore deposits), these arc emissions possess a distinct compositional fingerprint, particularly rich in tungsten, arsenic, thallium, antimony and lead when compared with those from hotspots. We propose that volcanic metal emissions are controlled by magmatic water content and redox: hydrous arc magmas that do not undergo sulfide saturation yield metal-rich, saline aqueous fluid; shallow degassing and resorption of late-stage sulfides feeds volcanic gases in Hawai’i and Iceland. Although global arc magma chemistries vary considerably, our findings suggest that volcanic emissions in arcs have a distinct fingerprint when compared with other settings. A shift in global volcanic metal emissions may have occurred in Earth’s past as more oxidized, water-rich magmas became prevalent, influencing the surface environment. Arc volcanism emits higher metal fluxes to Earth’s atmosphere than hotspot volcanism. The systems’ unique gas compositions are controlled by magmatic water content and redox state, as shown by a compilation of volcanic gas and aerosol metal data.

Half-space cooling and plate models of varying complexity have been proposed to account for changes in basement depth and heat flow as a function of lithospheric age in the oceanic realm. Here, we revisit this well-known problem by exploiting a revised and augmented database of 2028 measurements of depth to oceanic basement, corrected for sedimentary loading and variable crustal thickness, and 3597 corrected heat flow measurements. Joint inverse modeling of both databases shows that the half-space cooling model yields a mid-oceanic axial temperature that is >100°C hotter than permitted by petrologic constraints. It also fails to produce the observed flattening at old ages. Then, we investigate a suite of increasingly complex plate models and conclude that the optimal model requires incorporation of experimentally determined temperature- and pressure-dependent conductivity, expansivity and specific heat capacity, as well as a low conductivity crustal layer. This revised model has a mantle potential temperature of 1300 ± 50°C, which honors independent geochemical constraints and has an initial ridge depth of 2.6 ± 0.3 km with a plate thickness of 135 ± 30 km. It predicts that the maximum depth of intraplate earthquakes is bounded by the 700°C isothermal contour, consistent with laboratory creep experiments on olivine aggregates. Estimates of the lithosphere-asthenosphere boundary derived from studies of azimuthal anisotropy coincide with the 1175 ± 50°C isotherm. The model can be used to isolate residual depth and gravity anomalies generated by flexural and sub-plate convective processes.

The Ditrău Igneous Complex (north-east Romania) is a tilted Mesozoic alkaline intrusion (~19 km diameter), with enrichments in rare earth elements (REE), niobium, and molybdenum. It has the potential to contribute to a secure and sustainable European REE mining industry, ensuring supply security for these critical metals. The complex comprises a sequence of ultramafic rocks, alkali gabbros, diorites, syenites, nepheline syenites and alkali granites. These units have been significantly modified by sub-solidus interaction with late-stage magmatic fluids and are cut by secondary mafic dykes. The complex was subsequently cut by REE-mineralised carbonate-rich veins. Geochemical and petrological data, including apatite mineral chemistry, from the alkaline igneous rocks, dykes and veins within the Ditrău Complex, have been used to assess the interplay of magmatic processes with late-stage magmatic and hydrothermal fluids, and the effects of these processes on element remobilisation and concentration of critical metals. Only limited critical metal enrichment was achieved by magmatic processes; the REE were preferentially incorporated into titanite and apatite in ultramafic cumulates during primary crystallisation, and were not enriched in evolved magmas. A hydrothermal system developed within the Ditrău Complex magma chamber during the later stages of magmatic crystallisation, causing localised alteration of nepheline syenites by a sodium-rich fluid. Mafic dykes subsequently acted as conduits for late stage, buoyant potassic fluids, which leached REE and HFSE from the surrounding syenitic rocks. These fluids percolated up and accumulated in the roof zone, causing the breakdown of nepheline to K-rich pseudomorphs and the precipitation of hydrothermal minerals such as zircon and pyrochlore within veins. REE mineralisation within the Ditrău Complex is hosted in the latest hydrothermal phase, mineralised carbonate-rich veins, which cross-cut the complex. Monazite is the main REE-bearing phase, it crystallised from a late REE- and carbonate-rich fluid with pH controlled REE deposition.

This essay introduces the legal dimensions of the Anthropocene, i.e. the currently advocated new geological epoch in which humans are the defining force. It explores in this context two basic propositions. First, law as a technology of social organisation has been neglected in the otherwise highly technology-focused accounts by natural and social scientists of the drivers of the Anthropocene. Secondly, in those rare instances where law has been discussed, there is a tendency to assume that the role of law is to tackle the negative externalities of transactions (e.g. their environmental or social implications) rather than the core of the underlying transactions, i.e. the organisation of production and consumption processes. Such focus on externalities fails to unveil the role of law in prompting, sustaining and potentially managing the processes that have led to the Anthropocene. The essay provides an extensive survey of the relevant literature from a range of disciplines. After a brief introduction to the Anthropocene narrative and the possible role of law in it, it focuses on three main questions identified in humanities, social and natural sciences, and then discusses their legal dimensions: the disconnection between natural and human history, the profound inequalities within the human variable driving the Anthropocene, and the technological transition required to reach a sustainable societal organisation. The essay concludes with a concise research agenda linking specific legal questions to the broader questions raised by the advent of the Anthropocene.

International audience; Over the past 3.5 million years, there have been several intervals when climate conditions were warmer than during the pre-industrial Holocene. Although past intervals of warming were forced differently than future anthropogenic change, such periods can provide insights into potential future climate impacts and ecosystem feedbacks, especially over centennial-to-millennial timescales that are often not covered by climate model simulations. Our observation-based synthesis of the understanding of past intervals with temperatures within the range of projected future warming suggests that there is a low risk of runaway greenhouse gas feedbacks for global warming of no more than 2 °C. However, substantial regional environmental impacts can occur. A global average warming of 1–2 °C with strong polar amplification has, in the past, been accompanied by significant shifts in climate zones and the spatial distribution of land and ocean ecosystems. Sustained warming at this level has also led to substantial reductions of the Greenland and Antarctic ice sheets, with sea-level increases of at least several metres on millennial timescales. Comparison of palaeo observations with climate model results suggests that, due to the lack of certain feedback processes, model-based climate projections may underestimate long-term warming in response to future radiative forcing by as much as a factor of two, and thus may also underestimate centennial-to-millennial-scale sea-level rise.

True substrates are defined as sedimentary bedding planes that demonstrably existed at the sediment-water or sediment-air interface at the time of deposition, as evidenced by features such as ripple marks or trace fossils. Here we describe true substrates from the Silurian Tumblagooda Sandstone of Western Australia, which have been identified by the presence of the surficial trace fossil Psammichnites. The examples are unexpected because they have developed along erosional internal bounding surfaces within a succession of cross-bedded sandstones. However, their seemingly counterintuitive preservation can be explained with reference to recent advances in our understanding of the time-incomplete sedimentary-stratigraphic record (SSR). The preservation of true substrates seems to be an inevitable and ordinary result of deposition in environments where sedimentary stasis and spatial variability play important roles. We show that the true substrates developed during high-frequency allogenic disturbance of migrating bedforms, forcing a redistribution of the loci of sedimentation within an estuarine setting, and subsequently permitting an interval of sedimentary stasis during which the erosional bounding surfaces could be colonized. These observations provide physical evidence that supports recent contentions of how sedimentary stasis and the interplay of allogenic and autogenic processes impart a traditionally underestimated complexity to the chronostratigraphic record of geological outcrop.

Freshwater ecosystems are a major source of methane (CH4), contributing 0.65 Pg (in CO2 equivalents) yr-1 towards global carbon emissions and offsetting ~25% of the terrestrial carbon sink. Most CH4 emissions come from littoral sediments, where large quantities of plant material are decomposed. Climate change is predicted to shift plant community composition, and thus change the quality of inputs into detrital food webs, with the potential to affect CH4 production. Here we find that variation in phenol availability from decomposing organic matter underlies large differences in CH4 production in lake sediments. Production is at least 400-times higher from sediments composed of macrophyte litter compared to terrestrial sources because of inhibition of methanogenesis by phenol leachates. Our results now suggest that earth system models and carbon budgets should consider the effects of plant communities on sediment chemistry and ultimately CH4 emissions at a global scale.

The time of origin of Earth’s dynamo is unknown. Detrital zircon crystals containing ferromagnetic inclusions from the Jack Hills of Western Australia have the potential to contain the oldest records of the geodynamo. It has recently been argued that magnetization in these zircons indicates that an active dynamo existed as far back as 4.2 Ga. However, the ages of ferromagnetic inclusions in the zircons are unknown. Here we present the first detailed characterization of the mineralogy and spatial distribution of ferromagnetic minerals in Jack Hills detrital zircons. We demonstrate that ferromagnetic minerals in most Jack Hills zircons are commonly located in cracks and on the zircons’ exteriors. Hematite is observed to dominate the magnetization of many zircons, while other zircons also contain significant quantities of magnetite and goethite. This indicates that the magnetization of most zircons is likely to be dominantly carried by secondary minerals that could be hundreds of millions to billions of years younger than the zircons’ crystallization ages. We conclude that the existence of the geodynamo prior to 3.5 Ga has yet to be established

The identification of sediment sources to the ocean is a prerequisite to using marine sediment cores to extract information on past climate and ocean circulation. Sr and Nd isotopes are classical tools with which to trace source provenance. Despite considerable interest in the Arctic Ocean, the circum-Arctic source regions are poorly characterised in terms of their Sr and Nd isotopic compositions. In this study we present Sr and Nd isotope data from the Paleogene Central Basin sediments of Svalbard, including the first published data of stream suspended sediments from Svalbard. The stream suspended sediments exhibit considerable isotopic variation (εNd = −20.6 to −13.4; 87Sr ∕ 86Sr = 0.73421 to 0.74704) which can be related to the depositional history of the sedimentary formations from which they are derived. In combination with analysis of the clay mineralogy of catchment rocks and sediments, we suggest that the Central Basin sedimentary rocks were derived from two sources. One source is Proterozoic sediments derived from Greenlandic basement rocks which are rich in illite and have high 87Sr ∕ 86Sr and low εNd values. The second source is Carboniferous to Jurassic sediments derived from Siberian basalts which are rich in smectite and have low 87Sr ∕ 86Sr and high εNd values. Due to a change in depositional conditions throughout the Paleogene (from deep sea to continental) the relative proportions of these two sources vary in the Central Basin formations. The modern stream suspended sediment isotopic composition is then controlled by modern processes, in particular glaciation, which determines the present-day exposure of the formations and therefore the relative contribution of each formation to the stream suspended sediment load. This study demonstrates that the Nd isotopic composition of stream suspended sediments exhibits seasonal variation, which likely mirrors longer-term hydrological changes, with implications for source provenance studies based on fixed end-members through time.

The Mg and Sr content of ostracod valves have been used to reconstruct past temperature and salinity, and their stable isotopes have been used to reveal aspects of marine, lake and estuary hydrology. However, significant uncertainties surround ostracod calcification processes, the incorporation mechanisms of trace elements, and the sensitivity of proxy tracers to complex confounding factors. The valves of most ostracods are composed of micron-scale crystalline grains embedded in an organic matrix. The fine-scale geochemistry of these structures, and the nature of the influence of biological mineralisation processes on valve chemistry, remain poorly constrained. We have performed sub-micron resolution X-ray microscopy of a marine Krithe ostracod valve, and determined the chemical coordination of Mg, and the distribution of Mg, Na and S throughout the crystal-organic valve structure. These trace elements display systematic sub-micron-scale compositional variations within the mineral grains and inter-granular matrix of the valve ultrastructure. These patterns imply that Krithe biomineralisation processes significantly modulate trace element incorporation at the sub-micron scale. Thus Krithe chemical composition is likely to be decoupled to some extent from the water in which they calcified. Most importantly, Mg K-edge Near-Edge X-Ray Absorption Fine Structure (NEXAFS) spectra, and the coincidence of high-Mg regions with S-rich organic layers reveal that Mg is not primarily hosted in the calcite structure in the valve. Our results highlight the need to understand the processes that drive this fine-scale chemical heterogeneity and their influence on connections between the external environment and valve geochemistry, if ostracods are to be used as sources of paleoenvironmental proxies.

International audience; Gas bubbles form as magmas ascend in the crust and exsolve volatiles. These bubbles evolve chemically and physically as magma decompression and crystallization proceed. It is generally assumed that the gas remains in thermal equilibrium with the melt but the relationship between gas and melt redox state is debated. Here, using absorption spectroscopy, we report the composition of gases emitted from the lava lake of Kīlauea Volcano, Hawaii, and calculate equilibrium conditions for the gas emissions. Our observations span a transition between more and less vigorous-degassing regimes. They reveal a temperature range of up to 250 °C, and progressive oxidation of the gas, relative to solid rock buffers, with decreasing gas temperature. We suggest that these phenomena are the result of changing gas bubble size. We find that even for more viscous magmas, fast-rising bubbles can cool adiabatically, and lose the redox signature of their associated melts. This process can result in rapid changes in the abundances of redox-sensitive gas species. Gas composition is monitored at many volcanoes in support of hazard assessment but time averaging of observations can mask such variability arising from the dynamics of degassing. In addition, the observed redox decoupling between gas and melt calls for caution in using lava chemistry to infer the composition of associated volcanic gases.

We thank Noffke (2017) for her comment and for providing an opportunity to clarify our classification of “sedimentary surface textures”. We accord great credit to Dr. Noffke and other dedicated researchers whose detailed work has brought microbially induced sedimentary structures (MISS) to the widespread attention of geoscientists. However, we stand by our assertion that attributing structures observed in practical field and laboratory studies to processes of formation is much more problematic than Noffke (2017) indicates. Indeed, points in the Comment confirm the need for a classification system that categorises the degree of certainty attributed to a given interpretation. We stress that our paper was not designed as a critique of previous studies of MISS but rather was designed to encourage a reasonable assessment of uncertainty in assigning sedimentary surface textures to physical processes or to MISS.

Is groundwater abundant in Antarctica and does it modulate ice flow? Answering this question matters because ice streams flow by gliding over a wet substrate of till. Water fed to icestream beds thus influences ice-sheet dynamics and, potentially, sea-level rise. It is recognized that both till and the sedimentary basins from which it originates are porous and could host a reservoir of mobile groundwater that interacts with the subglacial interfacial system. According to recent numerical modelling, up to half of all water available for basal lubrication, and time lags between hydrological forcing and ice-sheet response as long as millennia, may have been overlooked in models of ice flow. Here, we review evidence in support of Antarctic groundwater and propose how it can be measured to ascertain the extent to which it modulates ice flow. We present new seismoelectric soundings of subglacial till, and magnetotelluric and transient electromagnetic forward models of subglacial groundwater reservoirs. We demonstrate that multifaceted and integrated geophysical datasets can detect, delineate and quantify the groundwater contents of subglacial sedimentary basins and, potentially, monitor groundwater exchange rates between subglacial till layers. The paper thus describes a new area of glaciological investigation and how it should progress in future.

The last deglaciation represents the most recent example of natural global warming associated with large-scale climate changes. In addition to the long-term global temperature increase, the last deglaciation onset is punctuated by a sequence of abrupt changes in the Northern Hemisphere. Such interplay between orbital- and millennial-scale variability is widely documented in paleoclimatic records but the underlying mechanisms are not fully understood. Limitations arise from the difficulty in constraining the sequence of events between external forcing, high- and low- latitude climate, and environmental changes. Greenland ice cores provide sub-decadal-scale records across the last deglaciation and contain fingerprints of climate variations occurring in different regions of the Northern Hemisphere. Here, we combine new ice d-excess and 17O-excess records, tracing changes in the midlatitudes, with ice δ18O records of polar climate. Within Heinrich Stadial 1, we demonstrate a decoupling between climatic conditions in Greenland and those of the lower latitudes. While Greenland temperature remains mostly stable from 17.5 to 14.7 ka, significant change in the midlatitudes of the northern Atlantic takes place at ∼16.2 ka, associated with warmer and wetter conditions of Greenland moisture sources. We show that this climate modification is coincident with abrupt changes in atmospheric CO2 and CH4 concentrations recorded in an Antarctic ice core. Our coherent ice core chronological framework and comparison with other paleoclimate records suggests a mechanism involving two-step freshwater fluxes in the North Atlantic associated with a southward shift of the Intertropical Convergence Zone.

The sedimentary fill of the Parnaíba basin in NE Brazil is punctuated by two episodes of basaltic magmatism in Jurassic and Cretaceous times, known as the Mosquito and Sardinha formations, respectively. A quantitative understanding of the depth and degree of melting that generated these basalts should provide useful constraints on the history of vertical motions in this cratonic basin. We carried out forward and inverse modelling of major, trace and rare earth element concentrations for primitive melts from both igneous provinces. We calculated the melt fraction as a function of depth to determine the melt volumes and mantle potential temperatures. Our results suggest that both episodes of magmatism resulted from shallow decompression melting within the asthenospheric mantle. The Mosquito basalts record an excess temperature of 55–75°C and are probably related to the widespread Central Atlantic Magmatic Province associated with the initial break-up of Gondwanaland. By contrast, the Sardinha basalts record localized lithospheric thinning to less than half its original thickness with excess temperatures of 15–25°C. This younger activity is probably part of the Paraná–Etendeka large igneous province, which is linked to rifting between South America and Africa. We suspect that these magmatic episodes are associated with phases of regional epeirogenic uplift affecting the Parnaíba basin.

Serious haze can cause contaminant diseases that trigger productive labour time by raising mortality and morbidity rates in cardiovascular and respiratory diseases. Health studies rarely consider macroeconomic impacts of industrial interlinkages while disaster studies seldom involve air pollution and its health consequences. This study adopts a supply-driven input–output model to estimate the economic loss resulted from disease-induced working-time reduction across 30 Chinese provinces in 2012 using the most updated Chinese multiregional input–output table. Results show a total economic loss of CNY 398.23 billion ( ∼ 1 % of China's GDP in 2012), with the majority coming from Eastern China and the Mid-South. The total number of affected labourers amounts to 82.19 million. Cross-regional economic impact analysis indicates that the Mid-South, North China, and Eastern China entail the majority of the regional indirect loss. Indeed, most indirect loss in North China, the Northwest and the Southwest can be attributed to manufacturing and energy in other regions, while loss in Eastern China, the Mid-South and the Northeast largely originate from coal and mining in other regions. At the subindustrial level, most inner-regional loss in North China and the Northwest originate from coal and mining, in Eastern China and Southwest from equipment and energy, and in the Mid-South from metal and non-metal. These findings highlight the potential role of geographical distance in regional interlinkages and regional heterogeneity in inner- and outer-regional loss due to distinctive regional economic structures and dependences between the north and south.

Tephrochronology is a widely applied method recognized for its exceptional precision in geologic dating and stratigraphic correlation. Tephra from the ~7.6 kyr B.P. Mount Mazama caldera-forming (”climactic”) eruption have been widely identified and applied as stratigraphic isochrons sediments of northwestern North America, as well as in the Greenland ice core records. Recent findings of a microscopic tephra accumulation, or cryptotephra, from Mazama in Newfoundland indicated that this horizon should also be found in Lake Superior sediments. We present findings that confirm the presence of Mazama ash in two sediment cores from the Lake Superior basin, which indicates its likely presence in the rest of the Laurentian Great Lakes and in deposits throughout much of eastern North America and beyond. The ubiquity of this stratigraphic horizon should be applicable to a higher resolution evaluation of climatological, ecological, and archaeological events during the early- to mid-Holocene thermal maximum throughout much of North America.

The calcite tests of foraminifera lie in marine sediments for thousands to millions of years, before being analysed to generate trace element and isotope palaeoproxy records. These sediments constitute a distinct physio-chemical environment from the conditions in which the tests formed. Storage in sediments can modify the trace element and isotopic content of foraminiferal calcite through diagenetic alteration, which has the potential to confound their palaeoceanographic interpretation. A previous study of G. tumida from the Ontong Java Plateau, western equatorial Pacific, found that preferential dissolution of higher-Mg chamber calcite, and the preservation of a low-Mg crust on the tests significantly reduced whole-test Mg/Ca and Sr/Ca [Brown and Elderfield, 1996]. Here, we revisit these specimens with a combination of synchrotron X-ray computed tomography (sXCT) and electron probe micro-analyses (EPMA) to re-evaluate the nature of their diagenetic alteration. The dissolution of higher-Mg calcite with depth was directly observed in the sXCT data, confirming the inference of the previous study. The sXCT data further reveal a thickening of the chemically and structurally distinct calcite crust with depth. We propose that these crusts have a diagenetic origin, driven by the simultaneous dissolution of high-Mg chamber calcite and precipitation of low-Mg crust from the resulting modified pore-water solution. While the breadth of the study is limited by the nature of the techniques, the observation of both dissolution and re-precipitation of foraminiferal calcite serves to demonstrate the action of two simultaneous diagenetic alteration processes, with significant impacts on the resulting palaeoproxy signals.

The oldest evidence of eukaryotes in the fossil record comes from a recurrent assemblage of morphologically differentiated late Paleoproterozoic to early Mesoproterozoic microfossils. Although widely distributed, the principal constituents of this Tappania-Dictyosphaera-Valeria assemblage have not hitherto been recognized on Laurentia. We have recovered all three taxa from a shallow-water shale succession in the early Mesoproterozoic Greyson Formation (Belt Supergroup, Montana, USA). An exceptionally preserved population of Tappania substantially expands the morphological range of this developmentally complex organism, suggesting phylogenetic placement within, or immediately adjacent to, crown-group eukaryotes. Correspondence with Tappania-bearing biotas from China, India, Australia, and Siberia demonstrates an open-ocean connection to the intracratonic Belt Basin and, along with broadly co-occurring macrofossils Grypania and Horodyskia, supports the recognition of a globally expressed biozone. The Greyson Formation, along with contiguous strata in Glacier National Park, is unique in preserving all currently confirmed taxa of early eukaryotic and macroscopic fossils.

Primitive basalt melt inclusions from Borgarhraun, northern Iceland, display large correlated variations in CO2 and nonvolatile incompatible trace elements (ITEs) such as Nb, Th, Rb, and Ba. The average CO2/ITE ratios of the Borgarhraun melt inclusion population are precisely determined (e.g., CO2/Nb = 391 ± 16; 2σM [two standard errors of the mean], n = 161). These data, along with published data on five other populations of undegassed mid-oceanic ridge basalt (MORB) glasses and melt inclusions, demonstrate that upper mantle CO2/Ba and CO2/Rb are nearly homogeneous, while CO2/Nb and CO2/Th are broadly correlated with long-term indices of mantle heterogeneity reflected in Nd isotopes (143Nd/144Nd) in five of the six regions of the upper mantle examined thus far. Our results suggest that heterogeneous carbon contents of the upper mantle are long-lived features, and that average carbon abundances of the mantle sources of Atlantic MORB are higher by a factor of two than those of Pacific MORB. This observation is correlated with a similar distinction in water contents and trace elements characteristic of subduction fluids (Ba, Rb). We suggest that the upper mantle beneath the younger Atlantic Ocean basin contains components of hydrated and carbonated subduction-modified mantle from prior episodes of Iapetus subduction that were entrained and mixed into the upper mantle during opening of the Atlantic Ocean basin., Maclennan is supported by Natural Environment Research Council grant NE/M000427/1. This research was supported by the Carnegie Institution of Washington and is a contribution to the Deep Carbon Observatory.

This is the author accepted manuscript. The final version is available from Wiley via http://onlinelibrary.wiley.com/doi/10.1002/2017TC004657/abstract, The Zailisky Alatau is a >250-km-long mountain range in Southern Kazakhstan. Its northern rangefront around the major city of Almaty has more than 4 km topographic relief, yet in contrast to other large mountain fronts in the Tien Shan, little is known about its Late Quaternary tectonic activity despite several destructive earthquakes in the historical record. We analyse the tectonic geomorphology of the rangefront fault using field observations, differential GPS measurements of fault scarps, historical and recent satellite imagery, metre-scale topography derived from stereo satellite images, and decimetre-scale elevation models from UAV surveys. Fault scarps ranging in height from ~2 m to >20 m in alluvial fans indicate surface rupturing earthquakes occurred along the rangefront fault since the Last Glacial Maximum (LGM). Minimum estimated magnitudes for those earthquakes are M6.8- 7. Radiocarbon dating results from charcoal layers in uplifted river terraces indicate a Holocene slip rate of ~1.2-2.2 mm/a. We find additional evidence for active tectonic deformation all along the Almaty rangefront, basinward in the Kazakh platform, and in the interior of the Zailisky mountain range. Our data indicate the seismic hazard faced by Almaty comes from a variety of sources, and we emphasize the problems related to urban growth into the loess-covered foothills and secondary earthquake effects. With our structural and geochronologic framework we present a schematic evolution of the Almaty rangefront that may be applicable to similar settings of tectonic shortening in the mountain ranges of Central Asia.

Surface runoff at the margin of the Greenland Ice Sheet drains to the ice-sheet bed leading to enhanced summer ice flow. Ice velocities show a pattern of early summer acceleration followed by mid-summer deceleration, due to evolution of the subglacial hydrology system in response to meltwater forcing. Modelling the integrated hydrological – ice dynamics system to reproduce measured velocities at the ice margin remains a key challenge for validating the present understanding of the system, and constraining the impact of increasing surface runoff rates on dynamic ice mass loss from the GrIS. Here we show that a multi-component model incorporating supraglacial, subglacial, and ice dynamic components applied to a land-terminating catchment in western Greenland produces modeled velocities which are in good agreement with those observed in GPS records for three melt seasons of varying melt intensities. This provides support for the hypothesis that the subglacial system develops analogously to alpine glaciers, and supports recent model formulations capturing the transition between distributed and channelized states. The model shows development of efficient conduit drainage up-glacier from the ice sheet margin which develops more extensively, and further inland, as melt intensity increases. This suggests current trends of decadal timescale slow-down in the ablation zone will continue in the near future, although the strong summer velocity scaling in our results could begin to offset potential future fall and winter velocity decreases for very high melt rates which are predicted for the end of the 21st century.

Corbetti caldera is the southernmost large volcanic system in Ethiopia, and has been categorized at the highest level of uncertainty in terms of hazard and risk. Until now, the number and frequency of past explosive eruptions at Corbetti has been unknown, due to limited studies of frequently incomplete and patchy outcrop sequences. Here we use volcanic ash layers preserved in sediments from three Main Ethiopian Rift lakes to provide the first detailed record of volcanism for the Corbetti caldera. We show that lake sediments yield more comprehensive, stratigraphically-resolved dossiers of long-term volcanism than often available in outcrop. Our eruptive history for Corbetti spans the last 10 k.y. and reveals eruptions at an average return period of ~900 years. The threat posed by Corbetti has, until now, been underestimated. Future explosive eruptions, similar to those of the past 10 k.y. would blanket nearby Awassa and Shashamene, currently home to ~260,000 people, with pumice fall deposits and would have significant societal impacts. A lake sediment tephrostratigraphic approach shows significant potential for application throughout the East African Rift system, and will be essential to better understanding volcanic hazards in this rapidly developing region.

Seafloor morphology beyond nine tidewater glaciers terminating in open-marine settings in eastern Svalbard has been investigated using multibeam swath-bathymetry. Historical information on tidewater glacier fluctuations over the past century or so shows that the seafloor offshore has been exposed only recently. Most glaciers have been observed to surge or have looped surface moraines indicating past surges. During these ice advances and subsequent retreat, a well-preserved submarine landform assemblage has been produced. (a) Subglacial landforms include: overridden moraine ridges, mega-scale glacial lineations (MSGLs), other streamlined lineations, elongate drumlins and medial moraines, small ridges forming a complex boxwork or rhombohedral pattern, and meltwater-related eskers and channels. (b) Ice-marginal landforms include: large terminal moraines with debris flow lobes on their outer flanks and indentations on their inner sides, small transverse retreat moraines, and crater-like kettle holes. (c) Glacimarine features include: iceberg ploughmarks and an otherwise relatively smooth sedimentary seafloor produced by fine-grained debris rain-out. A schematic plan-view landform assemblage model for tidewater glaciers advancing into open-marine settings is developed. Arcuate terminal moraines marking the ice-advance limit provide a distinctive component. Submarine basin(s) exposed inside these moraine ridges when ice retreats contain suites of individual landforms, produced subglacially and ice-marginally, with a consistent order of timing of deposition and stratigraphic superposition. The new schematic model is compared with earlier models based on submarine landforms associated with surges in the more topographically constrained setting of Spitsbergen fjords. Differences include: (i) the overall arcuate shape of the open-marine assemblage; (ii) the indented ice-proximal sides of terminal moraine ridges; (iii) the fan-shaped pattern of streamlined lineations; (iv) crater-like kettle holes at the inner lateral margins of many submarine basins; (v) prominent systems of eskers and channels. Modern glaciological analogues from ongoing surges of ice caps in eastern Svalbard and Severnaya Zemlya provide contemporary observations of ice advance into open-marine settings, including heavily crevassed ice lobes with finger-like termini.

One of the key requirements for a Global Stratotype Section and Point (GSSP) is the absence of tectonic disturbance. The GSSP for the Triassic–Jurassic system boundary was recently defined at Kuhjoch, Northern Calcareous Alps, Austria. New field observations in the area of the Triassic–Jurassic boundary GSSP site demonstrate that the overturned, tight, and almost upright Karwendel syncline was formed at semibrittle deformation conditions, confirmed by axial planar foliation. Tight to isoclinal folds at various scales were related to a tectonic transport to the north. Brittle faulting occurred before and after folding as confirmed by tilt tests (the rotation of structural data by the average bedding). Foliation is ubiquitous in the incompetent units, including the Kendlbach Formation at the GSSP. A reverse fault (inferred to be formed as a normal fault before folding) crosscuts the GSSP sections, results in the partial tectonic omission of the Schattwald Beds, and thus makes it impossible to measure a complete and continuous stratigraphic section across the whole Kendlbach Formation. Based on these observations, the Kuhjoch sections do not fulfil the specific requirement for a GSSP regarding the absence of tectonic disturbances near boundary level.

Investigations of the impacts of past volcanic eruptions on climate, environment, and society require accurate chronologies. However, eruptions that are not recorded in historical documents can seldom be dated exactly. Here we use annually resolved radiocarbon ($^{14}$C) measurements to isolate the 775 CE cosmogenic $^{14}$C peak in a subfossil birch tree that was buried by a glacial outburst flood in southern Iceland. We employ this absolute time marker to date a subglacial eruption of Katla volcano at late 822 CE to early 823 CE. We argue for correlation between the 822–823 CE eruption and a conspicuous sulfur anomaly evident in Greenland ice cores, which follows in the wake of an even larger volcanic signal (ca. 818–820 CE) as yet not attributed to a known eruption. An abrupt summer cooling in 824 CE, evident in tree-ring reconstructions for Fennoscandia and the Northern Hemisphere, suggests a climatic response to the Katla eruption. Written historical sources from Europe and China corroborate our proposed tree ring–radiocarbon–ice core linkage but also point to combined effects of eruptions occurring during this period. Our study describes the oldest precisely dated, high-latitude eruption and reveals the impact of an extended phase of volcanic forcing in the early 9$^{th}$ century. It also provides insight into the existence of prehistoric woodland cover and the nature of volcanism several decades before Iceland's permanent settlement began.

Mistaken Point Ecological Reserve (MPER) World Heritage Site, on the southeastern coast of Newfoundland, Canada, is one of the foremost global Ediacaran fossil localities. MPER contains some of the oldest known assemblages of the soft-bodied Ediacaran macrobiota, and its fossils have contributed significantly to Ediacaran paleobiological research since their initial discovery in 1967. Preservation of multiple in situ benthic paleocommunities, some comprising thousands of specimens, has enabled research into Ediacaran paleoecology, ontogeny, taphonomy, taxonomy and morphology, offering insights into the possible phylogenetic positions of Ediacaran taxa within the tree of life. Meanwhile, a thick and continuous geological record enables the fossils to be placed within a well-resolved temporal and paleoenvironmental context spanning an interval of at least 10 million years. This article reviews the history of paleontological research at MPER, and highlights key discoveries that have shaped global thinking on the Ediacaran macrobiota.RÉSUMÉLe site du Patrimoine mondial de la Réserve écologique de Mistaken Point (MPER), sur la côte sud-est de Terre-Neuve, au Canada, est l'une des principales localités fossilifères édiacariennes de la planète. Le MPER renferme quelques-uns des plus anciens assemblages connus de macrobiote édicarien à parties molles, et ses fossiles ont contribué de manière significative à la recherche paléobiologique édiacarienne depuis leur découverte en 1967. La préservation de multiples paléocommunautés benthiques in situ, dont certaines comptant des milliers de spécimens, a permis de faire des recherches en paléoécologie, ontogenèse, taphonomie, taxonomie et morphologie de biotes édiacariens, ce qui a permis d’avoir un aperçu de différentes positions phylogénétiques possibles des taxons édiacariens dans l'arborescence biologique. Aussi, grâce à une colonne géologique épaisse et continue, on a pu placer ces fossiles dans un contexte temporel et paléoenvironnemental bien circonscrit qui s’étend sur un intervalle d'au moins 10 millions d'années. Cet article passe en revue l'histoire de la recherche paléontologique au MPER et souligne les découvertes majeures qui ont façonné la réflexion sur le macrobiote édiacarien.

An examination of the past descriptions of the Pleistocene Observatory Gravels and the sediments of the Travellers’ Rest Pit of north-west Cambridge has illustrated their relation to the local landscape in terms of sediments and age. The Travellers’ Rest Pit sediments, which include gravels and ‘loams’, represent aggradation and alluviation/colluviation in a former drainage way which resulted from diversion to the west of the Cam valley drainage by glaciation in the Fenland in the Late Wolstonian Stage. The drainage way may have carried both Cam valley catchment waters and proglacial waters. The Travellers’ Rest Pit gravels and ‘loams’ now lie on a ridge of Gault and Chalk Marl. The Observatory Gravels occur on the western slope of this ridge, at a lower level than the sediments of the Travellers’ Rest Pit, and are associated with the incision of the Washpit Brook valley, on Gault Formation bedrock to the west of the Observatory slope, at a later date. The periglacial ground-ice structures and palaeontology of the Travellers’ Rest Pit sediments are described, The Palaeolithic archaeology contained within the sequence, bears comparison with Palaeolithic finds elsewhere in Late Wolstonian proglacial gravels of the Fenland margins.

We investigated dental homologies, development, and growth in living and fossil hyracoids, and tested if hyracoids and other mammals show correlations between eruption patterns, gestation time, and age at maturity. Unlike living species, fossil hyracoids simultaneously possess replaced P1 and canine teeth. Fossil species also have shorter crowns, an upper and lower I3 locus, an upper I2, and a hypoconulid on m3. Prenatal specimens of the living $\textit{Procavia capensis}$ and $\textit{Heterohyrax brucei}$ show up to three tooth buds posterior to upper dI1 and anterior to the seven upper cheek teeth that consistently erupt; these include an anterior premolar but not a canine. Most lower cheek teeth finish eruption during growth in hyracoids, not after growth as in most other afrotherians. All hyracoids show the m1 at (lower) or near (upper) the beginning of eruption of permanent teeth; M3/m3 is the last permanent tooth to erupt. The living P. capensis erupts most lower antemolar loci before m2. In contrast, fossil hyraxes erupt lower antemolars after m2. While the early eruption of antemolars correlates with increased gestation time and age at maturity in primates and $\textit{Tupaia}$ (i.e., "Schultz's Rule"), and while modern hyraxes resemble some anthropoid primates in exhibiting long gestation and eruption of antemolars at or before molars, eruption patterns do not significantly co-vary with either life history parameter among afrotherians sampled so far. However, we do observe a shift in eruption timing and crown height in $\textit{Procavia}$ relative to fossil hyracoids, mirroring observations recently made for other ungulate-grade mammals.

© 2017. American Geophysical Union. All Rights Reserved. A multidisciplinary approach is used to analyze the Cenozoic uplift history of South America. Residual depth anomalies of oceanic crust abutting this continent help to determine the pattern of present-day dynamic topography. Admittance analysis and crustal thickness measurements indicate that the elastic thickness of the Borborema and Altiplano regions is ≤10 km with evidence for sub-plate support at longer wavelengths. A drainage inventory of 1827 river profiles is assembled and used to investigate landscape development. Linear inverse modeling enables river profiles to be fitted as a function of the spatial and temporal history of regional uplift. Erosional parameters are calibrated using observations from the Borborema Plateau and tested against continent-wide stratigraphic and thermochronologic constraints. Our results predict that two phases of regional uplift of the Altiplano plateau occurred in Neogene times. Regional uplift of the southern Patagonian Andes also appears to have occurred in Early Miocene times. The consistency between observed and predicted histories for the Borborema, Altiplano, and Patagonian plateaux implies that drainage networks record coherent signals that are amenable to simple modeling strategies. Finally, the predicted pattern of incision across the Amazon catchment constrains solid sedimentary flux at the Foz do Amazonas. Observed and calculated flux estimates match, suggesting that erosion and deposition were triggered by regional Andean uplift during Miocene times.

The first-order importance of tectonic and environmental controls for terrigenous sediment supply has rarely been questioned, but the role of vegetation in the modification of ancient alluvial signatures has been observed since the mid-20th century (Vogt 1941). Studies of sparsely vegetated rivers (Schumm 1968) and alluvial stratigraphic variation (Cotter 1978; Davies & Gibling 2010) led to observations of (1) plant modulation of alluvial signatures and (2) Palaeozoic facies shifts (PFS): unidirectional changes to facies diversity and frequency, in stratigraphic alliance with the plant fossil record. One PFS is the Siluro-Devonian appearance of mud-rich, architecturally complex alluvium, traditionally ascribed to meandering rivers, and sedimentologically distinct from pre-vegetation strata (Davies & Gibling 2010; Long 2011). Using selected secondary data, Santos et al. (2017) dispute the correlation of these observations using three key points, as follows. (1) The mid-Palaeozoic was typified by orogenic assembly of low-gradient equatorial continents and elevated sea-level, which led to tropical weathering (abundant fine sediment) and extensive alluvial plains. This drove the PFS by promoting river meandering independently of vegetation. (2) Meandering does not require vegetation; this is shown by examples in Precambrian deposits, on other planets, and in ‘non-vegetated’ deserts. Meandering rivers were more abundant than the pre-vegetation rock record suggests, owing to selective bypass and deflation of fine material. (3) Early Siluro-Devonian (meaning Ludlow–Early Devonian) land plants were too small, their biomass and cover too limited, and their wetland habitat too narrow to have stabilized meandering channels, influencing landscape little more than earlier microbial communities. We contest the conclusions and method of the paper, and deal with each point in turn.