151. Synthesis and characterization of spider-web-like electrospun mats of meta-aramid.
- Author
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Oh, Hyun Ju, Pant, Hem Raj, Kang, Young Sic, Jeon, Kyung Soo, Pant, Bishweshwar, Kim, Cheol Sang, and Kim, Hak Yong
- Subjects
SPIDER webs ,ELECTROSPINNING ,SCANNING electron microscopy ,POROUS materials - Abstract
The effect of salt formation during condensation polymerization on the morphology of electrospun meta-aramid fibers was investigated. The presence of a by-product salt (CaCl
2 ) improved the electrospinability of the meta-aramid solution and induced the formation of a spider-web-like structure in the mat. The effect of the concentration of the solution and the applied voltage on the formation of the spider-web-like fibrous structure was investigated. Field emission scanning electron microscopy images indicated that thin fibers were uniformly distributed with thick fibers throughout the mats in the form of a spider-web-like structure. Thermogravimetric analysis showed that the thermal stability of the electrospun mat was affected by CaCl2 . The observed enhancement in the thermal and mechanical properties of the mats, which was attributed to the formation of the spider-web-like structure, may increase the number of potential applications of meta-aramids, such as water/air filtration, protective clothing and electrical insulation. Copyright © 2012 Society of Chemical Industry [ABSTRACT FROM AUTHOR]- Published
- 2012
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