151. Enhanced performance for dye-sensitized solar cells based on spherical TiO2 nanorod-aggregate light-scattering layer
- Author
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Song Bi, Zhou Xiao, Genliang Hou, Zhaohui Liu, Haipeng Jia, and Xunjia Su
- Subjects
Photocurrent ,Materials science ,Renewable Energy, Sustainability and the Environment ,business.industry ,Energy conversion efficiency ,Energy Engineering and Power Technology ,Light scattering ,Nanocrystalline material ,Overlayer ,Dye-sensitized solar cell ,Optoelectronics ,Nanorod ,Electrical and Electronic Engineering ,Physical and Theoretical Chemistry ,business ,Layer (electronics) - Abstract
A new bilayer-structured photoelectrode film with spherical TiO2 nanorod aggregates as a light-scattering overlayer and nanocrystalline TiO2 as an underlayer is fabricated and studied with the aim of improving energy conversion efficiency in dye-sensitized solar cells (DSSCs). An overall energy conversion efficiency of 6.10% and a short-circuit photocurrent density of 18.47 mA cm−2 are achieved by introducing a spherical TiO2 nanorod-aggregate light-scattering layer. These are respectively 37.1% and 42.6% higher than those of a DSSC using a conventional 200 nm-diameter solid TiO2 particle light-scattering layer. These improvements are attributed to the spherical TiO2 nanorod-aggregate overlayer, which has a large surface area for sufficient dye adsorption, sub-micrometer size for efficient light scattering, and lower surface state traps, allowing a longer exciton lifetime.
- Published
- 2012