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The synthesis and the X-ray structure of the Zn(II) zwitterionic complex:1-ethylpiperaziniumtrichlorozincate (II) are described. In the atomic arrangement, the ZnCl 3 N entities, grouped in pairs, are deployed along the b -axis to form layers. The organic entities are inserted between these layers through N H⋯Cl and C H⋯Cl hydrogen bonds to form infinite three-dimensional network. The 3D Hirshfeld surfaces were investigated for intermolecular interactions. The optimized geometry, Mulliken charge distribution, molecular electrostatic potential (MEP) maps and thermodynamic properties have been calculated using the Lee-Yang-Parr correlation functional B3LYP with the LanL2DZ basis set. The HOMO and LUMO energy gap and chemical reactivity parameters were made. The 13 C and 15 N CP-MAS NMR spectra are in agreement with the X-ray crystal structure. The vibrational absorption bands were identified by infrared spectroscopy. DFT calculations allowed the attribution of the NMR peaks and of the IR bands. [ABSTRACT FROM AUTHOR]

Complementarity has frequently, but mistakenly, been conflated with wave-particle duality, and this conflation has led to pervasive misunderstandings of Bohr's views and several misguided claims of an experimental “disproof” of complementarity. In this paper, I explain what Bohr meant by complementarity, and how this is related to, but distinct from, wave-particle duality. I list a variety of possible meanings of wave-particle duality, and canvass the ways in which they are (or are not) supported by quantum physics and Bohr's interpretation. I also examine the extent to which wave-particle duality should be viewed as an example of the sort of dualities one finds in, e.g., string theory. I argue that the most fruitful way of reading of Bohr's account complementarity is by comparing it to current accounts of effective theories with limited domains of applicability. [ABSTRACT FROM AUTHOR]

This paper investigates the significance of T-duality in string theory: the indistinguishability with respect to all observables, of models attributing radically different radii to space—larger than the observable universe, or far smaller than the Planck length, say. Two interpretational branch points are identified and discussed. First, whether duals are physically equivalent or not: by considering a duality of the familiar simple harmonic oscillator, I argue that they are. Unlike the oscillator, there are no measurements ‘outside’ string theory that could distinguish the duals. Second, whether duals agree or disagree on the radius of ‘target space’, the space in which strings evolve according to string theory. I argue for the latter position, because the alternative leaves it unknown what the radius is. Since duals are physically equivalent yet disagree on the radius of target space, it follows that the radius is indeterminate between them. Using an analysis of Brandenberger and Vafa (1989) , I explain why—even so—space is observed to have a determinate, large radius. The conclusion is that observed, ‘phenomenal’ space is not target space, since a space cannot have both a determinate and indeterminate radius: instead phenomenal space must be a higher-level phenomenon, not fundamental. [ABSTRACT FROM AUTHOR]

A theoretical and phenomenological consideration is given to higher order, strong field effects in electron/laser interactions. A consistent strong field theory is the Furry interaction picture of intense field quantum field theory. In this theory, fermions are embedded in the strong laser field and the Volkov wavefunction solutions that result, are exact with respect to the strong field. When these Volkov fermions interact with individual photons from other sources, the transition probability is enhanced in a series of resonances when the kinematics allow the virtual fermion to go on-shell. An experiment is proposed in which, for the first time, resonances could be used to generate high energy photons from relativistic electrons at rates orders of magnitude in excess of usual mechanisms. [ABSTRACT FROM AUTHOR]

The Zn(II) complex with the monodentate ligand 4-fluoroaniline, ZnCl 2 (C 6 H 4 FNH 2 ) 2 , has been prepared and characterized by single crystal X-ray diffraction, solid state nuclear magnetic resonance, infrared spectroscopy and differential scanning calorimetry. The Zn(II) ion is tetracoordinated by two nitrogen atoms of two monodentate 4-fluoroaniline ligands and two chlorine atoms. In the molecular arrangement, the ZnCl 2 (C 6 H 4 FNH 2 ) 2 entities are interconnected via N H⋯Cl hydrogen bonds to form layers parallel to the ( a , b ) plane. The nature and proportion of contacts in the crystal packing were investigated through the Hirshfeld surfaces. The crystal is mainly maintained by electrostatic attractions Cl − … H N and by extensive hydrophobic contacts as revealed by the Hirshfeld 2D fingerprint plots and statistical analysis. The 13 C and 19 F CP-MAS NMR spectra are in agreement with the X-ray structure and confirm the phase purity of the crystalline sample. The vibrational absorption bands were identified by infrared spectroscopy. A calorimetric study shows that the title compound is stable until 262.5 °C. [ABSTRACT FROM AUTHOR]

We conjecture that all connected graphs of order n have von Neumann entropy at least as great as the star K 1 , n − 1 and prove this for almost all graphs of order n . We show that connected graphs of order n have Rényi 2-entropy at least as great as K 1 , n − 1 and for α > 1 , K n maximizes Rényi α -entropy over graphs of order n . We show that adding an edge to a graph can lower its von Neumann entropy. [ABSTRACT FROM AUTHOR]

Despite certain quantum concepts, such as superposition states, entanglement, 'spooky action at a distance' and tunnelling through insulating walls, being somewhat counterintuitive, they are no doubt extremely useful constructs in theoretical and experimental physics. More uncertain, however, is whether or not these concepts are fundamental to biology and living processes. Of course, at the fundamental level all things are quantum, because all things are built from the quantized states and rules that govern atoms. But when does the quantum mechanical toolkit become the best tool for the job? This review looks at four areas of 'quantum effects in biology'. These are biosystems that are very diverse in detail but possess some commonality. They are all (i) effects in biology: rates of a signal (or information) that can be calculated from a form of the 'golden rule' and (ii) they are all protein-pigment (or ligand) complex systems. It is shown, beginning with the rate equation, that all these systems may contain some degree of quantum effect, and where experimental evidence is available, it is explored to determine how the quantum analysis aids in understanding of the process. [ABSTRACT FROM AUTHOR]

The quantum Otto cycle serves as a bridge between the macroscopic world of heat engines and the quantum regime of thermal devices composed from a single element. We compile recent studies of the quantum Otto cycle with a harmonic oscillator as a working medium. This model has the advantage that it is analytically trackable. In addition, an experimental realization has been achieved, employing a single ion in a harmonic trap. The review is embedded in the field of quantum thermodynamics and quantum open systems. The basic principles of the theory are explained by a specific example illuminating the basic definitions of work and heat. The relation between quantum observables and the state of the system is emphasized. The dynamical description of the cycle is based on a completely positive map formulated as a propagator for each stroke of the engine. Explicit solutions for these propagators are described on a vector space of quantum thermodynamical observables. These solutions which employ different assumptions and techniques are compared. The tradeoff between power and efficiency is the focal point of finite-time-thermodynamics. The dynamical model enables the study of finite time cycles limiting time on the adiabatic and the thermalization times. Explicit finite time solutions are found which are frictionless (meaning that no coherence is generated), and are also known as shortcuts to adiabaticity. The transition from frictionless to sudden adiabats is characterized by a non-hermitian degeneracy in the propagator. In addition, the influence of noise on the control is illustrated. These results are used to close the cycles either as engines or as refrigerators. The properties of the limit cycle are described. Methods to optimize the power by controlling the thermalization time are also introduced. At high temperatures, the Novikov-Curzon-Ahlborn efficiency at maximum power is obtained. The sudden limit of the engine which allows finite power at zero cycle time is shown. The refrigerator cycle is described within the frictionless limit, with emphasis on the cooling rate when the cold bath temperature approaches zero. [ABSTRACT FROM AUTHOR]

Complex network research has attracted lots of attention in both academic community and various application fields. Complex network clustering, as one of the key issues in complex network, explores the internal organization of the nodes in a complex network. The discrete particle swarm optimization strategy has been successfully proposed for network clustering, while the existing method works with weak robust. In this paper, we model the task of complex network clustering as a multi-objective optimization problem and solve the problem with the quantum mechanism based particle swarm optimization algorithm, which is a parallel algorithm. To our knowledge, this is the first attempt to apply the quantum mechanism based discrete particle swarm optimization algorithm into network clustering. In addition, the non-dominant sorting selection operation is employed for individual replacement. Consequently, a quantum-behaved discrete multi-objective particle swarm optimization algorithm is proposed for complex network clustering. The experimental results demonstrate that the proposed algorithm performs effectively and achieves competitive performance with the state-of-the-art approaches on the extension of Girvan and Newman benchmarks and real-world networks, especially on large-scale networks. [ABSTRACT FROM AUTHOR]

Bringing quantum science and technology to the space frontier offers exciting prospects for both fundamental physics and applications such as long-range secure communication and space-borne quantum probes for inertial sensing with enhanced accuracy and sensitivity. But despite important terrestrial pathfinding precursors on common microgravity platforms and promising proposals to exploit the significant advantages of space quantum missions, large-scale quantum test beds in space are yet to be realised due to the high costs and lead times of traditional ‘Big Space’ satellite development. But the ‘small space’ revolution, spearheaded by the rise of nanosatellites such as CubeSats, is an opportunity to greatly accelerate the progress of quantum space missions by providing easy and affordable access to space and encouraging agile development. We review space quantum science and technology, CubeSats and their rapidly developing capabilities and how they can be used to advance quantum satellite systems. [ABSTRACT FROM AUTHOR]

α-Formylketene dithioacetal is an active precursor for the synthesis of a variety of organic compounds including pyrimidines and its functionalized materials. The present study deals with the structural versatility of a solid representative compound from the family of α-formylketene dithioacetal to the formation of functionalized pyrimidines derivatives through experimental as well as theoretical methods. 2-(3,4-dimethoxybenzoyl)-3,3-bis(methylsulfanyl)prop-2-enal, the representative compound was synthesized with a reported protocol and characterized through spectral methods. The complete three dimensional solid state structural studies were carried out utilizing single crystal X-ray crystallographic technique along with theoretical methods like classical and accelerated molecular dynamics simulation. Various quantum chemical parameters were also discussed to reveals the complete molecular geometry and reactivity of designated compound. [ABSTRACT FROM AUTHOR]

The main result of this note is the proof of degenerate quantum integrability of quantum spin Calogero-Moser systems and the description of the spectrum of quantum Hamiltonians in terms of the decomposition of tensor products of irreducible representations of corresponding Lie algebra. [ABSTRACT FROM AUTHOR]

Together with bit commitment, Oblivious Transfer is a very useful cryptographic primitive with important applications, most notably in secure multiparty computations. It has been long known that secure Quantum Oblivious Transfer can be achieved from a secure implementation of Quantum Bit Commitment. Unfortunately, it is also well known that unconditionally secure Quantum Bit Commitment is impossible, so building a secure Oblivious Transfer protocol on top of Quantum Bit Commitment is ruled out. In this paper, we propose a relatively simple quantum protocol for Oblivious Transfer which does not require qubit storage, does not rely on bit commitment as a primitive and is easily implementable with current technology, if the two actors are honest. The protocol is proven to be secure against any individual measurements and entanglement-based attacks. Any cheating attempt trying to speculate collective measurements would be considerably difficult to put in practice, even in the near future. Furthermore, the number of qubits used in our scheme (embodied as photons in a physical realization of the protocol) acts as a security parameter, making it increasingly hard to cheat. [ABSTRACT FROM AUTHOR]

The black hole information paradox is among the most outstanding puzzles in physics. I argue here there is yet another black hole quandary which, in light of the recent direct detection of gravitational waves by Advanced LIGO, reveals a new window to probe the nature of spacetime in the forthcoming era of 'precision gravity.' [ABSTRACT FROM AUTHOR]

Planck's constant, h, as an action constant is one of the most widely studied concepts in theoretical physics. It appears in many equations from Planck's energy equation to the famous Schrodinger equation. Historically, the energy equation, E = hv, and units for h, [J × s], were chosen by convention. However, this essay describes a method of analysis that sees h as an energy constant and not an action constant. Using the logic of the calibration and the equations for calculating Planck natural units, an attempt is made to find the smallest measuring sticks or "pixels" for the domains of time, space, mass, charge, and temperature. Using this method, it is found that Planck units for the domains of mass, charge, and temperature do not correspond to the smallest measure-units. To correct this, Planck's energy equation is modeled as the equation of an experiment, E = htv, and the extra unit of [s], which is normally assigned to h, is assigned to a previously hidden measure-time variable, t. Here, h has the units of [J] and interprets as quantum of energy, Qenergy. Quantum of mass, Qmass, is calculated using h/c² which herein has units of mass. Using this logic, a complete set of quantum measure-units, calibrated to the time scale of the cycle is derived and tested. A self-similar set of measure-units, calibrated to the time scale of the second, is also derived. This approach leads to a modified unit analysis (MUA) that differs somewhat from that found in the NIST standard. MUA offers a slightly more complex but much more exact unit analysis where everything is accounted for and nothing is hidden. Using MUA as a foundation, an alternate cosmology is proposed that puts the first cycle of time or Planck epoch at a temperature of 10-12 K, in stark contrast to the big bang model which puts the Planck epoch at. a temperature of 10+32 K. The implications of this result, if correct, are of great significance. [ABSTRACT FROM AUTHOR]

The synthesis, crystal structure and spectroscopic characterization of the novel 1-(2-hydroxyethyl)piperaziniumtrichlorozincate(II) zwitterionic complex are reported. In the atomic arrangement, the ZnCl 3 N entities, grouped in pairs, are deployed in rows along the a -axis to form layers parallel to the ( a , c ) plane. The organic molecules are inserted between these layers through N-H…Cl, C-H…Cl, O-H…Cl and N-H…O hydrogen bonds to form infinite three-dimensional networks. Intermolecular interactions were investigated by Hirshfeld surfaces. The 13 C and 15 N CP-MAS NMR spectra are in agreement with the X-ray structure. The vibrational absorption bands were identified by infrared spectroscopy. DFT calculations allowed the attribution of the NMR peaks and of the IR bands. [ABSTRACT FROM AUTHOR]

In this paper, we consider a newly introduced class of convex functions that is η-convex functions. We give some new quantum analogues for Hermite-Hadamard, Iynger and Ostrowski type inequalities via η-convex functions. Some special cases are also discussed. [ABSTRACT FROM AUTHOR]

A sufficiently complex set of molecules, if subject to perturbation, will self-organize and show emergent behaviour. If such a system can take on information it will become subject to natural selection. This could explain how self-replicating molecules evolved into life and how intelligence arose. A pivotal step in this evolutionary process was of course the emergence of the eukaryote and the advent of the mitochondrion, which both enhanced energy production per cell and increased the ability to process, store and utilize information. Recent research suggest that from its inception life embraced quantum effects such as 'tunnelling' and 'coherence' while competition and stressful conditions provided a constant driver for natural selection. We believe that the biphasic adaptive response to stress described by hormesis - a process that captures information to enable adaptability, is central to this whole process. Critically, hormesis could improve mitochondrial quantum efficiency, improving the ATP/ROS ratio, whereas inflammation, which is tightly associated with the aging process, might do the opposite. This all suggests that to achieve optimal health and healthy aging, one has to sufficiently stress the system to ensure peak mitochondrial function, which itself could reflect selection of optimum efficiency at the quantum level. [ABSTRACT FROM AUTHOR]

A novel organic–inorganic hybrid material, C 6 H 15 N 2 CdCl 3 .H 2 O, was synthesized, and its structure was determined at room temperature in the monoclinic space group P2 1 / n with the following parameters: a = 10.3829 (17), b = 7.7459 (12), c = 14.905 (2) Å, β = 98.801 (15), and Z = 4. Its crystal structure is characterized by one-dimensional polymeric chains of edge-sharing CdCl 5 N distorted octahedra. These chains are linked to the water molecules via O H … Cl hydrogen bonds to form layers parallel to the ( b , a + c ) plane. The crystal structure was stabilized by an extensive network of N H … Cl, O H … Cl and N H … O hydrogen bonds. The differential scanning calorimetry (DSC) reveals that the title compound is stable until 101.6 °C. The optimized geometry parameters, normal mode frequencies, and corresponding vibrational assignments of the present compound were theoretically examined by DFT/B3LYP method with the Lanl2dz basis set. The FT-IR spectrum of the polycrystalline sample was examined and compared to the calculated spectrum. The calculated results showed that the optimized geometry could well reproduce the crystal structure and that the theoretical vibrational frequency values were in good agreement with their experimental counterparts. [ABSTRACT FROM AUTHOR]

Reversible logic is getting more and more attention in quantum computing, optical computing, nanotechnology and low-power complementary metal oxide semiconductor designs since reversible circuits do not loose information during computation and have only small energy dissipation. In this paper, a novel carry-selected reversible adder is proposed primarily optimised for low latency. A 4-bit reversible full adder with two kinds of outputs, minimum delay and optimal quantum cost is presented as the building block for-bit reversible adder. Three new reversible gates NPG (new Peres gate), TEPG (triple extension of Peres gate) and RMUX21 (reversible 2-to-1 multiplexer) are proposed and utilised to design efficient adder units. The secondary carry propagation chain is carefully designed to reduce the time consumption. The novelty of the proposed design is the consideration of low latency. The comparative study shows that the proposed adder achieves the improvement from 61.46% to 95.29% in delay over the existing designs. [ABSTRACT FROM AUTHOR]

Using semiclassical methods, it is possible to construct very accurate approximations in the short-wavelength limit of quantum dynamics that rely exclusively on classical dynamical input. For systems whose classical realization is strongly chaotic, there is an exceedingly short logarithmic Ehrenfest time scale, beyond which the quantum and classical dynamics of a system necessarily diverge, and yet the semiclassical construction remains valid far beyond that time. This fact leads to a paradox if one ponders the reversibility and predictability properties of quantum and classical mechanics. They behave very differently relative to each other, with classical dynamics being essentially irreversible/unpredictable, whereas quantum dynamics is reversible/stable. This begs the question: 'How can an accurate approximation to a reversible/stable dynamics be constructed from an irreversible/unpredictable one?' The resolution of this incongruity depends on a couple of key ingredients: a well-known, inherent, one-way structural stability of chaotic systems; and an overlap integral not being amenable to the saddle point method. [ABSTRACT FROM AUTHOR]

Echoes are ubiquitous phenomena in several branches of physics, ranging from acoustics, optics, condensed matter and cold atoms to geophysics. They are at the base of a number of very useful experimental techniques, such as nuclear magnetic resonance, photon echo and time-reversal mirrors. Particularly interesting physical effects are obtained when the echo studies are performed on complex systems, either classically chaotic, disordered or many-body. Consequently, the term Loschmidt echo has been coined to designate and quantify the revival occurring when an imperfect time-reversal procedure is applied to a complex quantum system, or equivalently to characterize the stability of quantum evolution in the presence of perturbations. Here, we present the articles which discuss the work that has shaped the field in the past few years. [ABSTRACT FROM AUTHOR]

Power and performance tradeoff optimization is one of the most significant issues on heterogeneous multiprocessor or multicomputer systems (HMCSs) with dynamically variable voltage. In this paper, the problem is defined as energy-constrained performance optimization and performance-constrained energy optimization. Task scheduling for precedence-constrained parallel applications represented by a directed acyclic graph (DAG) in HMCSs is an NP-HARD problem. Over the last three decades, several task scheduling techniques have been developed for energy-aware scheduling. However, it is impossible for a single task scheduling technique to outperform all other techniques for all types of applications and situations. Motivated by these observations, hyper-heuristic framework is introduced. Moreover, a quantum-inspired high-level learning strategy is proposed to improve the performance of this framework. Meanwhile, a fast solution evaluation technique is designed to reduce the computational burden for each iteration step. Experimental results show that the fast solution evaluation technique can improve average algorithm search speed by 38 percent and that the proposed algorithm generally exhibits outstanding convergence performance. [ABSTRACT FROM PUBLISHER]

The original Two Cultures debate has been told and retold as a struggle for the moral high ground; the entitlement to define ‘culture’ and especially the route to understanding humanity. Later skirmishes and attempts to define a ‘Third culture’ snatched elements of these and the battleground shifted, with the strangely playground-sounding claims that science had ‘won’. However I will argue that more interesting features of the debate were the underlying assumptions about epistemology; how can we, and should we, proceed in understanding our world and experience, and how sixty years of intellectual and cultural developments in many fields illuminate profoundly new and apparently incompatible discourses. This wide-ranging argument will necessarily be superficial but my purpose is to draw attention to what I regard as central concerns of twenty-first century lay and expert epistemologies and why they matter. [ABSTRACT FROM PUBLISHER]

Recently normalized Laplacian matrices of graphs are studied as density matrices in quantum mechanics. Separability and entanglement of density matrices are important properties as they determine the nonclassical behavior in quantum systems. In this note we look at the graphs whose normalized Laplacian matrices are separable or entangled. In particular, we show that the number of such graphs is related to the number of 0–1 matrices that are line sum symmetric and to the number of graphs with at least one vertex of degree 1. [ABSTRACT FROM AUTHOR]

We obtain a general connection between a large quantum advantage in communication complexity and Bell nonlocality. We show that given any protocol offering a sufficiently large quantum advantage in communication complexity, there exists a way of obtaining measurement statistics that violate some Bell inequality. Our main tool is port-based teleportation. If the gap between quantum and classical communication complexity can grow arbitrarily large, the ratio of the quantum value to the classical value of the Bell quantity becomes unbounded with the increase in the number of inputs and outputs. [ABSTRACT FROM AUTHOR]

The principle of increasing entropy is derived from statistical physics of open systems assuming that quanta of actions, as undividable basic build blocks, embody everything. According to this tenet, all systems evolve from one state to another either by acquiring quanta from their surroundings or by discarding quanta to the surroundings in order to attain energetic balance in least time. These natural processes result in ubiquitous scale-free patterns: skewed distributions that accumulate in a sigmoid manner and hence span log–log scales mostly as straight lines. Moreover, the equation for least-time motions reveals that evolution is by nature a non-deterministic process. Although the obtained insight in thermodynamics from the notion of quanta in motion yields nothing new, it accentuates that contemporary comprehension is impaired when modeling evolution as a computable process by imposing conservation of energy and thereby ignoring that quantum of actions are the carriers of energy from the system to its surroundings. [ABSTRACT FROM AUTHOR]

I show explicitly how concerns about wave function collapse and ontology can be decoupled from the bulk of technical analysis necessary to recover localized, approximately Newtonian trajectories from quantum theory. In doing so, I demonstrate that the account of classical behavior provided by decoherence theory can be straightforwardly tailored to give accounts of classical behavior on multiple interpretations of quantum theory, including the Everett, de Broglie–Bohm and GRW interpretations. I further show that this interpretation-neutral, decoherence-based account conforms to a general view of inter-theoretic reduction in physics that I have elaborated elsewhere, which differs from the oversimplified picture that treats reduction as a matter of simply taking limits. This interpretation-neutral account rests on a general three-pronged strategy for reduction between quantum and classical theories that combines decoherence, an appropriate form of Ehrenfest׳s Theorem, and a decoherence-compatible mechanism for collapse. It also incorporates a novel argument as to why branch-relative trajectories should be approximately Newtonian, which is based on a little-discussed extension of Ehrenfest׳s Theorem to open systems, rather than on the more commonly cited but less germane closed-systems version. In the Conclusion, I briefly suggest how the strategy for quantum-classical reduction described here might be extended to reduction between other classical and quantum theories, including classical and quantum field theory and classical and quantum gravity. [ABSTRACT FROM AUTHOR]

Bi2S3 quantum dots modified mesoscopic Tio2 films were prepared by in-situ solution chemical reaction deposition, using ethylene glycol monomethylether (EGME) and ethanol as solvent of Cationic precursor solution and anionic precursor solution respectively. UV-vis-NIR absorption spectra reveal that the Bi2S3 QDs extends the range of the photo response of the Tio2 films to visible region. A maximum conversion efficiency of 0.205% was obtained after five deposition cycles under illuminationat 1000 W/m². These results indicate that the Bi2S3 has potential application in the field of QDSSC. [ABSTRACT FROM AUTHOR]

In this paper we explore the boundary shared by biology and formal systems. [ABSTRACT FROM AUTHOR]

An application of the quantum N-portrait to the Universe is discussed, wherein the spacetime geometry is understood as a Bose-Einstein condensate of N soft gravitons. If near or at the critical point of a quantum phase transition, indications are found that the vacuum energy is partly suppressed by 1/ N, as being due to quanta not in the condensate state. Time evolution decreases this suppression, which might have implications for cosmic expansion. [ABSTRACT FROM AUTHOR]

As a direct consequence of the no-cloning theorem, the deterministic amplification as in classical communication is impossible for unknown quantum states. This calls for more advanced techniques in a future global quantum network, e.g., for cloud quantum computing. A unique solution is the teleportation of an entangled state, i.e., entanglement swapping, representing the central resource to relay entanglement between distant nodes. Together with entanglement purification and a quantum memory it constitutes a so-called quantum repeater. Since the aforementioned building blocks have been individually demonstrated in laboratory setups only, the applicability of the required technology in real-world scenarios remained to be proven. Here we present a free-space entanglement-swapping experiment between the Canary Islands of La Palma and Tenerife, verifying the presence of quantum entanglement between two previously independent photons separated by 143 km. We obtained an expectation value for the entanglement-witness operator, more than 6 SDs beyond the classical limit. By consecutive generation of the two required photon pairs and space-like separation of the relevant measurement events, we also showed the feasibility of the swapping protocol in a long-distance scenario, where the independence of the nodes is highly demanded. Because our results already allow for efficient implementation of entanglement purification, we anticipate our research to lay the ground for a fully fledged quantum repeater over a realistic high-loss and even turbulent quantum channel. [ABSTRACT FROM AUTHOR]

Establishing the reaction mechanisms involved in the biosynthesis of natural products plays an important role in phytochemistry and pharmacology. Mechanistic studies of the biogenesis of natural products have been mainly explored by means of theoretical calculations, and taking into account experimental structures of reagents and products. Using a hybrid meta density functional theory method (mPW1B95), we studied the mechanisms associated with the biogenesis of five neoclerodanes isolated from Salvia mycrophylla. The reaction mechanisms presented here explain the formation of the five neo-clerodanes and coincides with the formulated biogenetic hypothesis. [ABSTRACT FROM AUTHOR]

The historical part of this paper analyzes in detail how ideas and expectations regarding the role of time in quantum theory arose and evolved in the early years of quantum mechanics (from 1925 to 1927). The general theme is that expectations which seemed reasonable from the point of view of matrix mechanics and Dirac׳s q-number formalism became implausible in light of Dirac–Jordan transformation theory, and were dashed by von Neumann׳s Hilbert space formalism which came to replace it. Nonetheless, I will identify two concerns that remain relevant today, and which blunt the force of Hilgevoord׳s (2005) claim that the demand that time feature as an observable arose as the result of a simple conceptual error. First, I advocate the need for event time observables, which provide a temporal probability distribution for the occurrence of a particular event. Second, I claim that Dirac׳s use of the extended phase space to define time and (minus the) energy as conjugates is not subject to ‘Pauli׳s Theorem,’ the result that rules out time observables in von Neumann׳s formalism. I also claim that the need to define these event time observables leads to a novel motivation for considering Dirac׳s extended state space. [ABSTRACT FROM AUTHOR]

In this article I reply to Fleming׳s response to my ‘Time and quantum theory: a history and a prospectus.’ I take issue with two of his claims: (i) that quantum theory concerns the (potential) properties of eternally persisting objects; (ii) that there is an underdetermination problem for Positive Operator Valued Measures (POVMs). I advocate an event-first view which regards the probabilities supplied by quantum theory as probabilities for the occurrence of physical events rather than the possession of properties by persisting objects. [ABSTRACT FROM AUTHOR]

In this paper, we obtain some new quantum analogues of Hermite–Hadamard and Iyengar type inequalities for some classes of preinvex functions. Some special cases are also discussed. [ABSTRACT FROM AUTHOR]

We apply boundary integral equations for the first time to the two-dimensional scattering of time-harmonic waves from a smooth obstacle embedded in a continuously-graded unbounded medium. In the case we solve, the square of the wavenumber (refractive index) varies linearly in one coordinate, i.e. ( Δ + E + x 2 ) u ( x 1 , x 2 ) = 0 where E is a constant; this models quantum particles of fixed energy in a uniform gravitational field, and has broader applications to stratified media in acoustics, optics and seismology. We evaluate the fundamental solution efficiently with exponential accuracy via numerical saddle-point integration, using the truncated trapezoid rule with typically 10 2 nodes, with an effort that is independent of the frequency parameter E . By combining with a high-order Nyström quadrature, we are able to solve the scattering from obstacles 50 wavelengths across to 11 digits of accuracy in under a minute on a desktop or laptop. [ABSTRACT FROM AUTHOR]

A free particle is constrained to move on a knot obtained by winding around a putative torus. The classical equations of motion for this system are solved in a closed form. The exact energy eigenspectrum, in the thin torus limit, is obtained by mapping the time-independent Schrödinger equation to the Mathieu equation. In the general case, the eigenvalue problem is described by the Hill equation. Finite-thickness corrections are incorporated perturbatively by truncating the Hill equation. Comparisons and contrasts between this problem and the well-studied problem of a particle on a circle (planar rigid rotor) are performed throughout. [ABSTRACT FROM AUTHOR]

We explain features of two dimensional structures in a precise way, in terms of the non-commutative space which defines these structures. The novel feature here is a fundamental explanation for the FQHE. [ABSTRACT FROM AUTHOR]

An environmental friendly, NIS mediated oxidative cyclocondensation of 2-aminopyridine and aryl methyl ketone/cinnamaldehydes has been realized for the synthesis of 2-arylimidazo [1,2-a]pyridines and their 3-formylated products respectively. This one pot protocol involves simple reaction conditions, tolerates wide range of substrates and the products were formed in good to excellent yields. [Display omitted] [ABSTRACT FROM AUTHOR]

This paper analyses the thesis of the second antinomy. First, I intend to demonstrate that the thesis and its proof can only be referred to simple material parts of extended bodies in space and not to immaterial simple substances. Then, I intend to demonstrate that in the thesis and its proof both a pure categorial and an empirical synthesis are involved, which correspond to the category of quality. I claim that the proof of the thesis does not proceed by mere concepts, but introduces some reference to intuition. This reference will be explained through the empirical synthesis of reality and will confirm that the thesis deals with simple material parts. [ABSTRACT FROM AUTHOR]

We give the first proof of security for an identity-based encryption (IBE) scheme in the quantum random oracle model. This is the first proof of security for any scheme in this model that does not rely on the assumed existence of so-called quantum-secure pseudorandom functions (PRFs). Our techniques are quite general and we use them to obtain security proofs for two random oracle hierarchical IBE schemes and a random oracle signature scheme, all of which have previously resisted quantum security proofs, even assuming quantum-secure PRFs. We also explain how to remove quantum-secure PRFs from prior quantum random oracle model proofs. We accomplish these results by developing new tools for arguing that quantum algorithms cannot distinguish between two oracle distributions. Using a particular class of oracle distributions that we call semi-constant distributions, we argue that the aforementioned cryptosystems are secure against quantum adversaries. [ABSTRACT FROM AUTHOR]

We report on an experimental and theoretical investigation of quantum imaging where the images are stored in both space and time. Ghost images of remote objects are produced with either one or two beams of chaotic laser light generated by a rotating ground glass and two sensors measuring the reference field and bucket field at different space-time points. We further observe that the ghost images translate depending on the time delay between the sensor measurements. The ghost imaging experiments are performed both with and without turbulence. A discussion of the physics of the space-time imaging is presented in terms of quantum nonlocal two-photon analysis to support the experimental results. The theoretical model includes certain phase factors of the rotating ground glass. These experiments demonstrated a means to investigate the time and space aspects of ghost imaging and showed that ghost imaging contains more information per measured photon than was previously recognized where multiple ghost images are stored within the same ghost imaging data sets. This suggests new pathways to explore quantum information stored not only in multi-photon coincidence information but also in time delayed multi-photon interference. The research is applicable to making enhanced space-time quantum images and videos of moving objects where the images are stored in both space and time. [ABSTRACT FROM AUTHOR]

We present a review of the recently developed landscape and flux theory for non-equilibrium dynamical systems. We point out that the global natures of the associated dynamics for non-equilibrium system are determined by two key factors: the underlying landscape and, importantly, a curl probability flux. The landscape (U) reflects the probability of states (P) () and provides a global characterization and a stability measure of the system. The curl flux term measures how much detailed balance is broken and is one of the two main driving forces for the non-equilibrium dynamics in addition to the landscape gradient. Equilibrium dynamics resembles electron motion in an electric field, while non-equilibrium dynamics resembles electron motion in both electric and magnetic fields. The landscape and flux theory has many interesting consequences including (1) the fact that irreversible kinetic paths do not necessarily pass through the landscape saddles; (2) non-equilibrium transition state theory at the new saddle on the optimal paths for small but finite fluctuations; (3) a generalized fluctuation–dissipation relationship for non-equilibrium dynamical systems where the response function is not just equal to the fluctuations at the steady state alone as in the equilibrium case but there is an additional contribution from the curl flux in maintaining the steady state; (4) non-equilibrium thermodynamics where the free energy change is not just equal to the entropy production alone, as in the equilibrium case, but also there is an additional house-keeping contribution from the non-zero curl flux in maintaining the steady state; (5) gauge theory and a geometrical connection where the flux is found to be the origin of the gauge field curvature and the topological phase in analogy to the Berry phase in quantum mechanics; (6) coupled landscapes where non-adiabaticity of multiple landscapes in non-equilibrium dynamics can be analyzed using the landscape and flux theory and an eddy current emerges from the non-zero curl flux; (7) stochastic spatial dynamics where landscape and flux theory can be generalized for non-equilibrium field theory. We provide concrete examples of biological systems to demonstrate the new insights from the landscape and flux theory. These include models of (1) the cell cycle where the landscape attracts the system down to an oscillation attractor while the flux drives the coherent motion on the oscillation ring, the different phases of the cell cycle are identified as local basins on the cycle path and biological checkpoints are identified as local barriers or transition states between the local basins on the cell-cycle path; (2) stem cell differentiation where the Waddington landscape for development as well as the differentiation and reprogramming paths can be quantified; (3) cancer biology where cancer can be described as a disease of having multiple cellular states and the cancer state as well as the normal state can be quantified as basins of attractions on the underlying landscape while the transitions between normal and cancer states can be quantified as the transitions between the two attractors; (4) evolution where more general evolution dynamics beyond Wright and Fisher can be quantified using the specific example of allele frequency-dependent selection; (5) ecology where the landscape and flux as well as the global stability of predator–prey, cooperation and competition are quantified; (6) neural networks where general asymmetrical connections are considered for learning and memory, gene self-regulators where non-adiabatic dynamics of gene expression can be described with the landscape and flux in expanded dimensions and analytically treated; (7) chaotic strange attractor where the flux is crucial for the chaotic dynamics; (8) development in space where spatial landscape can be used to describe the process and pattern formation. We also give the philosophical implications of the theory and the o [ABSTRACT FROM AUTHOR]

We consider the 'membrane in the middle' optomechanical model consisting of a laser pumped cavity which is divided in two by a flexible membrane that is partially transmissive to light and subject to radiation pressure. Steady state solutions at the mean-field level reveal that there is a critical strength of the light-membrane coupling above which there is a symmetry breaking bifurcation where the membrane spontaneously acquires a displacement either to the left or the right. This bifurcation bears many of the signatures of a second order phase transition and we compare and contrast it with that found in the Dicke model. In particular, by studying limiting cases and deriving dynamical critical exponents using the fidelity susceptibility method, we argue that the two models share very similar critical behaviour. For example, the obtained critical exponents indicate that they fall within the same universality class. Away from the critical regime we identify, however, some discrepancies between the two models. Our results are discussed in terms of experimentally relevant parameters and we evaluate the prospects for realizing Dicke-type physics in these systems. [ABSTRACT FROM AUTHOR]

We present a dense coding network based on continuous-variable graph state along with its corresponding protocol. A scheme to distill bipartite entanglement between two arbitrary modes in a graph state is provided in order to realize the dense coding network. We also analyze the capacity of network dense coding and provide a method to calculate its maximum mutual information. As an application, we analyze the performance of dense coding in a square lattice graph state network. The result showed that the mutual information of the dense coding is not largely affected by the complexity of the network. We conclude that the performance of dense coding network is very optimistic. [ABSTRACT FROM AUTHOR]

Hydrogen bond donor strength ( [ABSTRACT FROM AUTHOR]

Recently quantum computation and cryptography principles are exploited in the design of security systems for wireless sensor networks (WSNs), which are consequently named as quantum WSN. Quantum cryptography is presumably secure against any eavesdropper and thus labeled as providing unconditional security. This paper tries to analyze the aspect of the applicative use of quantum principles in WSN. The outcome of the analysis elaborates a summary about the inadequacy of applicative use of quantum cryptography in WSN and presents an overview of all possible applicative challenges and problems while designing quantum-based security systems for WSN. Since WSNs are highly complex frameworks, with many restrictions and constraints, every security system has to be fully compatible and worthwhile. The aim of the paper was to contribute a verdict about this topic, backed up by equitable facts. [ABSTRACT FROM AUTHOR]

In the first part, a review is made of the development of the many-body perturbation theory for the last half century. The development of methods for quantum electrodynamics (QED) calculations, which have occurred essentially in parallel, is also briefly reviewed. In the second part, an effort of unifying the two is discussed. The covariant-evolution-operator method, developed primarily for QED calculations by the Gothenburg group, can be combined with atomic/molecular many-body perturbation theory (MBPT) and for the first time making it possible to combine full QED with electron correlation of arbitrary order. The basic idea is to extend the standard procedure of MBPT to a time- or energy-dependent formalism, which makes it possible to include QED perturbations in a rigorous fashion. The procedure has been implemented and as a first test applied to helium like ions. The method can also be applied to dynamical processes. © 2014 Wiley Periodicals, Inc. [ABSTRACT FROM AUTHOR]

Large-scale quantum computers will require the ability to apply long sequences of entangling gates to many qubits. In a photonic architecture, where single-qubit gates can be performed easily and precisely, the application of consecutive two-qubit entangling gates has been a significant obstacle. Here, we demonstrate a two-qubit photonic quantum processor that implements two consecutive CNOT gates on the same pair of polarisation-encoded qubits. To demonstrate the flexibility of our system, we implement various instances of the quantum algorithm for solving of systems of linear equations. [ABSTRACT FROM AUTHOR]