Search

We review the integration techniques for incorporating various materials into silicon-based devices. We discuss on-chip light sources with gain materials, linear electro-optic modulators using electro-optic materials, low-power piezoelectric tuning devices with piezoelectric materials, highly absorbing materials for on-chip photodetectors, and ultra-low-loss optical waveguides. Methodologies for integrating these materials with silicon are reviewed, alongside the technical challenges and evolving trends in silicon hybrid and heterogeneously integrated devices. In addition, potential research directions are proposed. With the advancement of integration processes for thin-film materials, significant breakthroughs are anticipated, leading to the realization of optoelectronic monolithic integration featuring on-chip lasers. [ABSTRACT FROM AUTHOR]

Mechanochemical reactions, achieved through milling, grinding, or other mechanical actions, have emerged as a solvent‐free alternative to traditional solution‐based chemistry. Mechanochemistry not only provides the opportunity to eliminate bulk solvent use, reducing waste generation, but also unveils a new reaction strategy which enables the realization of reactions previously inaccessible in solution. While the majority of organic reactions facilitated by mechanical force traditionally follow two‐electron transfer pathways similar to their solution‐based counterparts, the field of mechanochemically induced single‐electron transfer (SET) reactions has witnessed rapid development. This review outlines examples of mechanochemical reactions facilitated by the SET process, focusing on the reagents that initiate SET, thereby positioning mechanochemistry as a burgeoning field within the realm of single‐electron chemistry. [ABSTRACT FROM AUTHOR]

AbstractAiming at the problems of high environmental vibration frequency, low output power and short life of the energy harvesters, a noncontact magnetically coupled piezo-electromagnetic rotary energy harvester is proposed in this paper. It consists of a base, a top cover, a rotating body, a cantilever beam, a permanent magnet, a coil, a hollow tube and a clamp. The novel hybrid harvester can produce both piezoelectric and electromagnetic energy at the same time, and in addition, it can efficiently generate electricity at low ambient vibration. Moreover, the piezoelectric material is protected from direct collision by noncontact magnetic coupling excitation. In order to conduct a comprehensive study on the performance of the piezoelectric-electromagnetic rotary energy harvester, we set up a rotating test platform to carry out systematic test verification, and to determine the distance between the permanent magnet and the rotating body and the number of permanent magnets on the rotating body. The test results show that when four permanent magnets are uniformly pasted on the rotating body and the rotating speed is 775 r/min, the piezoelectric and electromagnetic output power are 3.4 mW and 2.69 mW, respectively, and the total hybrid output power is 6.09 mW. [ABSTRACT FROM AUTHOR]

2D piezoelectric catalysts with strong piezoresponse and high piezoelectric potential have valuable applications in catalytic degradation of organic pollutants and antibiotics, but the development of novel nanomaterials with powerful piezopotential still remains a serious challenge. Bismuth oxysulfide (Bi2O2S) nanosheets possessing large piezoelectric potentials were prepared using a low-heating solid-state chemical reaction and used for the first time for piezoelectric catalysis in this work. Moreover, Bi2O2S nanosheets can degrade pollutants universally, and the degradation efficiencies of methyl blue and rhodamine B are as high as 97.7% and 92.9% within 60 min under ultrasonication, respectively, which is superior to most piezoelectric materials reported in the literature. [ABSTRACT FROM AUTHOR]

Electrical devices are integral to daily life, but limited battery life remains a significant issue. A proposed solution is to convert dissipated energy from human motion into electricity using piezoelectric materials. This study investigates lead–zirconate–titanate (PZT) piezoelectric materials in bimorph configuration, conducts performance tests to understand their characteristics and determine the optimal load resistance, and develops an energy-harvesting prototype. Performance tests adjusted input parameters and varied load resistance and input magnitude to optimize power gained from the PZT bimorph. A suitable human movement for the application of the bimorph is a mouse-clicking motion by fingers. A prototype was created by integrating the bimorph into a computer mouse to capture energy from clicks. The results showed that the deformation rate of the PZTs, input magnitude, and resistance load were key factors in optimization. The bimorph configuration produced 0.34 mW of power and 5.5 V at an optimum load of 5072 Ω, requiring less effort to generate electricity. For the computer mouse energy harvester case, it yielded a total average power of approximately 38.4 μW per click with a click frequency of 4 Hz. This power could be used to support IoT devices such as human sensors (e.g., CO2, temperature, and pulse sensors) and smart home sensors, enabling comprehensive health and environmental monitoring. In conclusion, input specifications, magnitude, and load resistance are essential for optimizing piezoelectric energy harvesters. [ABSTRACT FROM AUTHOR]

The increasing need for wearable and portable electronics and the necessity to provide a continuous power supply to these electronics have shifted the focus of scientists toward harvesting energy from ambient sources. Harvesting energy from ambient sources, including solar, wind, and mechanical energies, is a solution to meet rising energy demands. Furthermore, adopting lightweight power source technologies is becoming more decisive in choosing renewable energy technologies to power novel electronic devices. In this regard, piezoelectric nanogenerators (PENGs) based on polymer composites that can convert discrete and low-frequency irregular mechanical energy from their surrounding environment into electricity have attracted keen attention and made considerable progress. This review highlights the latest advancements in this technology. First, the working mechanism of piezoelectricity and the different piezoelectric materials will be detailed. In particular, the focus will be on polymer composites filled with lead-free BaTiO3 piezoceramics to provide environmentally friendly technology. The next section will discuss the strategies adopted to enhance the performance of BaTiO3-based polymer composites. Finally, the potential applications of the developed PENGs will be presented, and the novel trends in the direction of the improvement of PENGs will be detailed. [ABSTRACT FROM AUTHOR]

Assessing the vibration signature produced by a rotating component of the wind turbine enables the identification of operational conditions and the detection of potential faults at an early stage. The main purpose is to enhance the sustainability of wind turbines while increasing the lifespan and uptime of their operational systems. This vibration analysis is based on the processing of the signal provided by sensors, which often incorporates piezoelectric transducers. This paper evaluates the consequences of employing piezoelectric sensors used for vibration measurement on electrical machines integrated into wind turbines by conducting a life cycle assessment (LCA). The widespread use of piezoelectric materials is due to their high sensitivity to vibrations, although their selection is also influenced by regulatory restrictions. This research focuses on the environmental impact of piezoelectric accelerometers used commonly in condition monitoring systems. The collected literature data on the manufacturing processes are inputted into the LCA model which is powered by the Ecoinvent 3 database. The impact assessment is carried out using the European ILCD 2011 Midpoint+ method by calculating the unique scores of the selected impact categories. The results are presented and discussed in terms of environmental indicators, as well as ecological recommendations on the design. [ABSTRACT FROM AUTHOR]

This study uses an analytical method to examine the scattering of a Love wave from an interfacial crack in a thin lossy media (viscoelastic material) that serves as a waveguide layer attached to an unbounded loss-less media (piezoelectric material). The viscoelastic material is modeled using the Kelvin–Voigt equation. Phase velocity and attenuation have been calculated by equating the real and imaginary parts of the dispersion relation to zero, respectively, due to the complex wave number of viscoelastic material. Using the integral transform approach and the dislocation density function, the scattering field close to the crack tip is determined, resulting in a Cauchy singular integral equation of the first type. It has been transformed into a system of linear algebraic equations using Gauss-Chebyshev numerical integration. It has been investigated how frequency, waveguide layer thickness, and viscoelastic material loss factor affect phase velocity and Love wave attenuation. The mode-III dynamic stress intensity factor at the left and right crack-tip is investigated for various thicknesses of the waveguide layer and loss factor of viscoelastic material. The outcomes were verified using numerical data from the COMSOL Multiphysics 5.6 FEA software. The findings are fundamental and could be used in the design of particular sensors. [ABSTRACT FROM AUTHOR]

A bimaterial piezoelectric space with collinear electrically limited permeable cracks along the material's interface is considered under plane strain conditions. The distances between the cracks, their location and number can be arbitrary. The problem of linear relationship is formulated and solved exactly. The electric flux over the crack regions is found. The closed-form expressions for stresses and electric displacement outside cracks and also for displacement jumps over cracks regions are found. The energy release rates at the crack tips are also derived in an analytical form. Numerical analysis is performed for different loading, cracks permittivity, their number, lengths, and locations. [ABSTRACT FROM AUTHOR]

Recently, the application of two–dimensional (2D) piezoelectric materials has been seriously hindered because most of them possess only in–plane piezoelectricity but lack out–of–plane piezoelectricity. In this work, using first–principles calculation, by atomic substitution of penta–graphene (PG) with tiny out–of–plane piezoelectricity, we design and predict stable 2D X–PG (X = Si or Ge) semiconductors with excellent in–plane and out–of–plane piezoelectricity and extremely high in–plane hole mobility. Among them, Ge–PG exhibits better performance in all aspects with an in–plane strain piezoelectric coefficient d11 = 8.43 pm/V, an out–of–plane strain piezoelectric coefficient d33 = −3.63 pm/V, and in–plane hole mobility μh = 57.33 × 103 cm2 V−1 s−1. By doping Si and Ge atoms, the negative Poisson's ratio of PG approaches zero and reaches a positive value, which is due to the gradual weakening of the structure's mechanical strength. The bandgaps of Si–PG (0.78 eV) and Ge–PG (0.89 eV) are much smaller than that of PG (2.20 eV), by 2.82 and 2.47 times, respectively. This indicates that the substitution of X atoms can regulate the bandgap of PG. Importantly, the physical mechanism of the out–of–plane piezoelectricity of these monolayers is revealed. The super–dipole–moment effect proposed in the previous work is proved to exist in PG and X–PG, i.e., it is proved that their out–of–plane piezoelectric stress coefficient e33 increases with the super–dipole–moment. The e33–induced polarization direction is also consistent with the super–dipole–moment direction. X–PG is predicted to have prominent potential for nanodevices applied as electromechanical coupling systems: wearable, ultra–thin devices; high–speed electronic transmission devices; and so on. [ABSTRACT FROM AUTHOR]

Nerve injury can lead to defects in related motor functions. It is critical to achieve long‐term and convenient real‐time evaluation of motor function recovery status during nerve injury repair. In this study, an implantable PLLA/BTO piezoelectric sensor (PBPS) with good biodegradability and biocompatibility for real time evaluation of the motor function recovery after nerve injury is developed. PLLA fibers doped with BTO are employed as piezoelectric material in PBPS, which can convert the biomechanical signals generated by motion into electrical signals. PBPS can be implant simultaneously with commonly used tissue scaffolds for treatment in the rats with sciatic nerve injury. The linearity of the pressure and the output voltage of PBPS is ≈0.9445. For the evaluation effectiveness, as the treatment process progresses, the signals generated by PBPS exhibited good consistency with EMG signals, indicating effectively evaluation of the motor function. Moreover, the integration of PBPS and wireless module can break the limitations of time and space for sensing and realize wireless evaluation of motor function in rat. The implantable sensor based on PBPS may bring new ideas for the development of implantable bioelectronics. [ABSTRACT FROM AUTHOR]

The ferroelectric domain plays an important role in determining the piezoelectric performance of ferroelectric ceramics. Herein, LiNbO 3 (LN) is used as an additive to tune the ferroelectric domain of 0.49Pb(Ni 1/3 Nb 2/3)O 3 -0.2Pb(In 1/2 Nb 1/2)O 3 -0.31PbTiO 3 (PNN-PIN-PT) ceramics. PNN-PIN-PT-0LN ceramic exhibits the ordered tetragonal phase (90 °) domain wall and rhombohedral phase (71 ° and 109 °) domain wall. Incorporating LN into the system leads to the transformation of the majority of structured macro-domains into random micro-domains with smaller sizes, which disrupt their long-range ordered ferroelectric domains, resulting in significant piezoelectric enhancement. Compared to PNN-PIN-PT-0LN ceramics, PNN-PIN-PT-1.8LN ceramics exhibit giant piezoelectric responses with d 33 = 1112 pC/N, d 31 =521 pC/N, d 33 * =1220 pm/V (@ E = 5 kV/cm), ε r = 12092. These findings shed light on a specific aspect of domain engineering in piezoelectric materials, thus contributing to a more comprehensive understanding of the underlying factors that give rise to the phenomenon of giant piezoelectricity. [ABSTRACT FROM AUTHOR]

Flexible electronic components such as wearable sensors, energy harvesting devices, and human health monitoring systems based on piezoelectric materials have garnered significant attention within the scientific community. In this study, PZT nanofibers were modified with dopamine hydrochloride prior to their integration into PVDF fibers, serving as piezoelectric reinforcements to enhance the mechanical and piezoelectric characteristics of composite fiber films. Subsequently, a facile hot-pressing method was employed to fabricate multilayered films characterized by a densely packed surface fiber arrangement and a loosely organized internal fiber orientation, which markedly improved the self-supporting ability and fiber density of the electrospun fiber films. A detailed investigation into the micro-morphology, crystallinity, and enhanced piezoelectric properties of the films was conducted. Notably, the composite fiber film containing 6 wt% PZT NFs exhibited a peak piezoelectric coefficient (d 33) of 29 pC/N, resulting in an output voltage of 13.8 V. This represents a 2.23-fold enhancement in d 33 value and a 4.6-fold increase in output voltage when compared to the pristine PVDF fiber film, which had a d 33 of 13 pC/N and an output voltage of 3 V. The power density achieved by the sensor is 0.73 μW/cm2. This performance is underpinned by a high piezoelectric coefficient, outstanding output characteristics, and robust stability, which collectively enhance the sensor's efficacy in various applications. This research presents an effective approach for augmenting the piezoelectric performance of PVDF-based composite films and paves the way for the advancement of piezoelectric energy harvesting applications. [ABSTRACT FROM AUTHOR]

Piezoelectric materials enabling direct conversion between electrical and mechanical energies are ubiquitously implemented in high-power apparatuses, where both superior piezoelectricity and high-power performance are demanded. However, it remains a challenge to simultaneously achieve the two goals, which are hindered by their antagonistic relationship. Herein, hot-pressing is employed to address this dilemma, as exemplified in lead-free (K,Na)NbO 3 (KNN) piezoceramics. In contrast to the samples prepared using normal sintering (NS–KNN), hot-pressed KNN (HP–KNN) polycrystals show higher density, lager piezoelectricity (d 33 ∼129 pC/N), and more active domain wall movement. In particular, the normalized strain d 33 * of HP-KNN piezoceramics exhibits high thermal stability (variation of d 33 *<10 %) in a broad temperature range from ambient temperature up to 150 °C. Moreover, the HP-KNN samples show superior high-power characteristics with a maximum vibration speed of 1.1 m/s, which is almost 78 % larger than that of NS-KNN. This study not only demonstrates that the HP-KNN lead-free piezoceramics hold great potential for high-power implements, but also opens a new avenue for integrating antagonistic properties for the enhancement of the collective performance in functional materials. [ABSTRACT FROM AUTHOR]

Accurate mechanical analysis is essential for reliable utilization of piezoelectric composite materials (PCMs). Isogeometric analysis (IGA) of PCMs (termed PCMIGA) based on the asymptotic homogenization method (AHM) is presented in this study and employed to investigate the static mechanical characteristics of PCMs. PCMIGA provides accurate curve representation and shorter preprocessing time, and thus demonstrates both precision and efficiency. First, AHM is utilized to calculate the effective parameters of PCMs at different volume fractions. Next, these effective parameters are combined with the basic equations and boundary conditions of PCMs to derive equations of PCMIGA based on AHM. Finally, the results from several numerical examples are compared with the reference solution to validate the convergence and precision. PCMIGA is proven to be a reliable and accurate method for analyzing the mechanical properties of PCMs. [ABSTRACT FROM AUTHOR]

Incorporating mechanoluminescent (ML) materials into piezoelectric polymer nanofibers enables the development of advanced pressure sensors and human–machine interactive devices by providing mechanical flexibility and enhancing processibility. This study demonstrates that introducing water during the electrospinning process significantly improves the piezoelectric properties of polyvinylidene fluoride (PVDF)‐based polymers, attributed to the enhanced formation of piezoelectrically active β‐phases. A biphasic relationship between piezoelectricity and water concentration is revealed, with an optimal water concentration of 4 wt.% for both polyvinylidene fluoride‐hexafluoropropylene (PVDF‐HFP) and polyvinylidene fluoride‐trifluoroethylene (PVDF‐TrFE). Furthermore, the inclusion of water in the electrospinning solution facilitates the integration of ZnS: Mn2+ mechanoluminescent microparticles into the polymer fibers, resulting in fibrous composite membranes with significantly enhanced mechano‐optical responses. After thermal annealing, the fibrous membrane by electrospinning PVDF‐TrFE and ZnS: Mn2+ microparticles with 8 wt.% water addition demonstrates the best ML performance with high light emission intensity and reduced pressure threshold down to 18 kPa. This exceptional performance can be attributed to the local electric field generated by the encapsulation of microparticles within the PVDF‐TrFE fibers, which facilitates electroluminescence and subsequently boosts the overall light emission. [ABSTRACT FROM AUTHOR]

AbstractTo solve the multi-physical coupling characteristics of piezoelectric structures, the thermal-mechanical-electrical coupling isogeometric analysis method (TMEC-IGA) is proposed to explore the structures of piezoelectric materials. Based on the basic equations and boundary conditions of piezoelectric materials, NURBS basis function is introduced to construct displacement and electrical potential functions, and the control equation of TMEC-IGA is derived. Numerical examples show that TMEC-IGA is effective in solving the thermal-mechanical-electro coupling problem of piezoelectric structures, and has broad application prospects in the design, development and performance analysis of piezoelectric devices. [ABSTRACT FROM AUTHOR]

Piezoelectric materials with tunable photoluminescence have gained widespread attention for their application in optical communications and optoelectronic sensing devices. This has provided new opportunities to explore the possibility of developing flexible piezoelectric devices with both piezoelectricity and photoluminescence for multifunctional applications. In this study, we prepared a crystalline Pr‐doped perovskite BaTiO3 (BPTO) film on a flexible mica substrate using the radio‐frequency (RF) sputtering technique. The photoluminescence intensity remarkably increased by about 210% when external mechanical stress was applied to the film. This remarkable increase in photoluminescence is attributed to lattice distortion and a decrease in crystal symmetry. The BPTO film also exhibited reversible and high‐endurance behavior even after 103 fatigue bending cycles. Moreover, the BPTO film was utilized as a piezoelectric nanogenerator device, which demonstrated a maximum output voltage of about 2.68 V when external stress was applied through palm tapping. The nanogenerator device yielded an instantaneous output power of 1.80 μW with an external load resistance of 0.8 MΩ. These versatile and robust properties of the BPTO film demonstrate its potential for future development of lead‐free self‐powered optoelectronic sensing applications, such as artificial intelligence and biomedical devices. [ABSTRACT FROM AUTHOR]

Piezoelectric actuator (PEA) is widely applied in the field of micro/nano high precision positioning. However PEA has the phenomenon of hysteresis non-linearity between input voltage and output displacement, owing to the natural property of piezoelectric materials. The PEA hysteresis can be compensated by the hysteresis models and control methods, which make the input voltage and output displacement more linearity. The research work on tracking control of PEA trajectories by using various feedforward-feedback controller has been being a hot topic. This paper presents a feedforward-feedback controller based on the modified Prandtl–Ishlinskii (PI) (MPI) model and submodel and the incremental proportional-integral–differential(IPID) controller for tracking control the trajectories of PEA. The polynomial model is adopted as submodel, and parameters of MPI model and submodel are calculated by matlab optimization tool box. The proposed hybrid controller is compiled by C language in VC + + environment. A series of comparative experiments are validated on a platform of commercial PEA. Comparing with the classical PI model, Bouc-Wen model, and other MPI models based IPID controller, the proposed hybrid controller has better control performance. According to the experimental results of the sinusoidal and triangular trajectories of different peaks and the mix sinusoidal and triangular trajectories, the proposed hybrid control method is feasible and effective in improving the tracking control accuracy of PEA trajectories. [ABSTRACT FROM AUTHOR]

In the current electromechanical model of cantilevered piezoelectric energy harvesters, the assumption of uniform electric field strength within the piezoelectric layer is commonly made. This uniform electric field assumption seems reasonable since the piezoelectric layer looks like a parallel-plate capacitor. However, for a piezoelectric bender, the strain distribution along the thickness direction is not uniform, which means the internal electric field generated by the spontaneous polarization cannot be uniform. In the present study, a non-uniform electric field in the piezoelectric layer is resolved using electrostatic equilibrium equations. Based on these, the traditional distributed parameter electromechanical model is corrected and simplified to a practical single mode one. Compared with a traditional model adopting a uniform electric field, the bending stiffness term involved in the electromechanical governing equations is explicitly corrected. Through comparisons of predicted power output with two-dimensional finite element analysis, the results show that the present model can better predict the power output performance compared with the traditional model. It is found that the relative corrections to traditional model have nothing to do with the absolute dimensions of the harvesters, but only relate to three dimensionless parameters, i.e., the ratio of the elastic layer's to the piezoelectric layer's thickness; the ratio of the elastic modulus of the elastic layer to the piezoelectric layer; and the piezoelectric materials' electromechanical coupling coefficient squared, k 31 2 . It is also found that the upper-limit relative corrections are only related to k 31 2 , i.e., the higher k 31 2 is, the larger the upper-limit relative corrections will be. For a PZT-5 unimorph harvester, the relative corrections of bending stiffness and corresponding resonant frequency are up to 17.8% and 8.5%, respectively. An inverse problem to identify the material parameters based on experimentally obtained power output performance is also investigated. The results show that the accuracy of material parameters identification is improved when considering a non-uniform electric field. [ABSTRACT FROM AUTHOR]

In space optical applications, the piezoelectric-actuated fast steering mirror (FSM) is one of the pivotal components for high-precision beam capturing and trajectory tracking. The FSM is restrained in small-angle scanning applications due to the short actuation stroke of the incorporated piezoelectric materials. This study introduces a dual-axis sub-radian stroke FSM with a high ratio of output range to resolution and self-sensing capability, based on cascading structures for displacement amplification and flexible parts for feedback. Theoretical analyses and finite element analysis (FEA) are applied to elucidate the driving and deformation mechanisms of the proposed FSM structure. To ensure the performance of the proposed FSM, the double-loop control strategies are implemented independently for rotation around the two orthogonal axes. Experimental results reveal that both axes can rotate 148.67 mrad under the closed-loop control, with the ratio of output range to resolution larger than 3.90 × 104, superior to existing FSMs. We further demonstrate with designed experiments of tracking complex trajectories that the relative tracking accuracy error remains lower than 0.02%. [ABSTRACT FROM AUTHOR]

This review provides a comprehensive understanding of magnetoelectric (ME) nanocomposite, cobalt ferrite–barium titanate (CFO–BTO) as a potential candidate for targeting specific cells. The synthesized core–shell material uses strain-mediated coupling between magnetostrictive and piezoelectric material. CFO–BTO has the competitive advantage of a high ME coefficient and is biocompatible. The shape and size play a pivotal role in passive drug delivery due to the enhanced permeability and retention effect at tumor sites. Surfactants can also enhance drug absorption and influence the interaction with nanoparticle composite. A comparison between external magnetic field–frequency parameters to navigate the ME nanoparticle and trigger release of the drug at site is also reviewed. Coating the nanoparticles with a layer of surfactant can reduce the threshold external magnetic field for navigation and triggering of drug particle release, making the prospect viable for clinical studies. [ABSTRACT FROM AUTHOR]

The scattering of flexural waves in piezoelectric thin plates with defects effects the electro-mechanical coupling property. Theoretical analysis for flexural waves is lack of a suitable decoupling function. Here, we have developed a method based on applied electric field to make a solution of the dynamic moment concentration factor (DMCF) for flexural waves scattering problems. The DMCFs of the piezoelectric materials have been found that it is significantly larger than those of the ordinary elastic materials because of electro-mechanical coupling. In the region of low frequency, DMCFs have a dependence on applied electric field and independent on the incident angle. Those opposite phenomena are observed as the frequency increasing. Those results provide theoretical guidance for dynamic analysis and strength design of piezoelectric material structures. [ABSTRACT FROM AUTHOR]

This study examines the use of piezoelectric materials/patches for passive, active, and hybrid repairs of a double-edged cracked plate. The study considers the stiffness effect of the piezoelectric patch for passive repair, the actuation effect of piezoelectric materials for active repair, and their combination as hybrid repair. The analytical model for cracked structures is developed using linear elastic fracture mechanics, which calculates the stress intensity factor (SIF) for various repair techniques under constant tensile load. The passive effect of the piezoelectric patch is determined using Rose's equations, while the stress produced by the piezoelectric material is computed using the weight function method. The fatigue life cycle for various repair configurations is determined under cyclic tensile loading using the Paris law with a stress ratio (R) of 0.1 and different voltage ratios (VR). The model is verified with experimental results and analytical fatigue life with FE solutions using ABAQUS software. It is to be noted that an analytical model is developed for the first time to account for both passive and active repairs, i.e., hybrid repair, and to verify the efficacy of the model using published experimental and FE solutions using ABAQUS. A parametric study is conducted to choose the best-sized piezoelectric actuator/patch, voltage, and voltage ratio. The results show a significant reduction in Mode-I SIF for all repair cases, with hybrid repair achieving the greatest reduction and extending fatigue life by 174.88, 116.23, and 37.92% as compared to without repair, active, and passive repairs, respectively, under 500 V with zero VR application. [ABSTRACT FROM AUTHOR]

The goal of this research article is to investigate the effects of using two-dimensional functionally graded materials on the performance of piezoelectric sensors/actuators when subjected to simultaneous complex loading conditions. The considered disc-shaped sensors/actuators have nonuniform thicknesses and undergo asymmetric hygro-thermo-electro-mechanical loading. A power-law model is used to grade the materials radially, whereas the cosine function, which includes two independent parameters, describes the pattern along the circumferential direction. Comparing the results obtained by using the finite element method with those of one-dimensional graded structures leads to promising outcomes. For example, the radial displacement exhibits vital changes that varied between - 13 and 31 % . This is beneficial for such structures in terms of enhancing their sensing/actuating abilities. Also, the tangential stress can be reduced substantially by about 39.5 % through the proper selection of the corresponding material parameters. In addition, this reduction of the tangential stress has a positive effect on the von Mises stress that can be decreased by nearly 33 % . Accordingly, the structure would have improved durability and sustain higher loads. These findings would revolutionize the manufacturing of smart structures and enhance their behaviors under severe conditions. [ABSTRACT FROM AUTHOR]

[Display omitted] Conventional piezoelectric nanogenerators (PNGs) face challenges in terms of degradation and reusability, which have negative environmental implications. On the other hand, biocompatible and degradable piezoelectric materials often exhibit lower piezoelectric response. In this study, potassium sodium niobate (KNN) powder and the biodegradable polymer poly(ε-caprolactone) (PCL) were used to fabricate piezoelectric composite films through solution casting. By constructing staggered electrodes, the total polarized charges quantity is increased, achieving a larger current output. The three-unit PNG (3-PNG) based on the composite film with 15 wt% KNN powder, reaches a maximum output current of 0.85 μA, which exhibits higher charging efficiency compared to 1-PNG. Moreover, the prepared 3-PNG can effectively harvest mechanical energy from human activities and maintain a stable output after 10,000 cycles of bending and releasing. The film exhibits complete degradation when exposed to acidic, neutral, and alkaline solutions. This research provides a promising option for environmentally friendly piezoelectric materials selected and output performance enhanced through optimized structural designs, making them more suitable for practical applications. [ABSTRACT FROM AUTHOR]

Granite is a common engineering material that exhibits complex mechanical properties under external loads. This study conducted experimental research and analysis in conjunction with the active monitoring technology of piezoelectric ceramics. A quantitative analysis method for the mechanical properties of rock materials based on piezoelectric health monitoring was established, and for the first time, the piezoelectric monitoring results of rock were mapped and compared with the uniaxial compression performance indicators of rock. In this study, two sets of cyclic impact experiments were conducted on granite samples using a drop hammer. The piezoelectric signals of the granite samples were detected using piezoelectric ceramic active sensing technology. A piezoelectric ceramic damage monitoring method was proposed, and the damage factor of the granite samples was calculated using the wavelet packet energy method. Subsequently, uniaxial compression experiments were performed on the damaged granite samples to obtain mechanical performance data. Finally, a mathematical relationship model was established between the piezoelectric signal and the uniaxial compressive strength of the rocks. It was found that the damage factor of the piezoelectric monitoring signal of the damaged rock were linearly related to the uniaxial compressive strength of the damaged rock. [ABSTRACT FROM AUTHOR]

In this paper, a novel flexible piezoelectric thick-film generator is proposed to address the challenges caused by flexible deformation and high piezoelectricity. This improves the output charge of the generator, which breaks the limitation imposed by the rigid and brittle nature of traditional piezoelectric bulks on elastic strain and piezoelectric performance. Additionally, the low piezoelectric coefficient of piezoelectric polymer-based piezoelectric generators is also resolved. Given the high thickness precision of electrohydrodynamic jet printing technology, the facile production of 10-μm thick film components is achieved through a process of printing and layer-by-layer accumulation on a flexible substrate, which ensures the flexible deformation and piezoelectric characteristics of the functional film. To ensure that AC is converted into stable DC output, a bipolar charge collection circuit is developed. The printed thick film produces an excellent performance in surface uniformity and smoothness. Notably, the piezoelectric constant d 33 is measured to be approximately 80 pC/N, which is five times higher than the d 33 value of flexible PVDF films. Additionally, the strength of adhesion between the printed thick film and the flexible substrate is remarkably high, reaching up to 20 N, which is an order of magnitude higher than the magnetron sputtering method. In a single cycle, the forward charge output reaches an impressively high level of 260 nC, which is approximately thirteen times the charge transfer capability of PVDF flexible generator. Furthermore, a bipolar charge collection circuit is applied to convert AC into DC effectively. This increases the output voltage from 2 V to 4 V. The illumination of commercial electronic screens and 39 LED lights demonstrates the applicability of micron-scale jet-printed thick films in micro-energy harvesting. [ABSTRACT FROM AUTHOR]

This paper is devoted to a new gauge of small dynamic bending deformations of structures. Unlike previously existing strain gauges that measure elongation or compression at a certain point on the surface of a deformable body, the proposed gauge measures the change in curvature at a point on the surface of a deformable body and does not respond to elongation–compression strains. The gauge is a layered bar made of piezoelectric and elastic materials. It functions using the direct piezoelectric effect. In order to competently study the deformed state of a structure at points on a surface, it is necessary to determine all components of the strain tensor. The gauges currently used measure only elongational or compressive strains, which does not provide a complete picture of the strain state. It is very important to complement these deformations with bending strains measured by the new gauge. [ABSTRACT FROM AUTHOR]

In recent years, the demand for sustainable and degradable materials and electronic devices has increased significantly. Among a range of biodegradable polymers, poly(lactic acid) (PLA) is a good alternative to conventional petrol-based polymers because of its attractive mechanical properties and its easy processability. Recently, PLA has also been described as a promising dielectric material with piezoelectric and electret properties. We expect that PLA—after further optimization—will play an important role as a material for environmentally friendly sensors in the future, where first applications such as air filters and pressure sensors have already been proposed. However, degradation under normal ambient conditions is very slow, and an accelerated and controllable degradation process is highly desirable for any type of PLA-based sensors. Enzymatic hydrolysis with embedded enzymes has been proposed as an approach to accelerate and control degradation. In this work, we investigate the properties of PLA in terms of dielectric and mechanical properties with a focus on its ability to store charges after the enzyme proteinase K (Trit. album) has been incorporated. Results reveal that proteinase K has a positive effect on the charge stability of solvent-cast PLA electrets after complete evaporation of the solvent. Furthermore, we observed a concentration-dependent acceleration of mass loss in a Tris-HCl buffer. A fast degradation within only one day occurred at a concentration of 6 wt% proteinase K. [ABSTRACT FROM AUTHOR]

This paper presents a comprehensive exploration of the role of smart materials, specifically triboelectric and piezoelectric materials, in the context of human-integrated healthcare systems. The study begins by elucidating the fundamentals of smart materials in healthcare, providing a detailed definition and characteristics of these materials and underscoring their paramount importance in advancing healthcare technologies. The research approach employed in this study involves a combination of literature review, experimental investigation, and computational modeling to analyze the potential of smart materials in healthcare applications. The subsequent sections delve into the individual contributions of triboelectric and piezoelectric materials in healthcare systems, outlining their unique attributes and potential applications. Eventually, real-world implementation challenges, such as scaling p production, ensuring stability, and establishing ethical deployment protocols, are meticulously examined. [ABSTRACT FROM AUTHOR]

The piezoelectric effect refers to a physical phenomenon where piezoelectric materials generate an electric field when subjected to mechanical stress or undergo mechanical deformation when subjected to an external electric field. This principle underlies the operation of piezoelectric sensors. Piezoelectric sensors have garnered significant attention due to their excellent self-powering capability, rapid response speed, and high sensitivity. With the rapid development of sensor techniques achieving high precision, increased mechanical flexibility, and miniaturization, a range of flexible electronic products have emerged. As the core constituents of piezoelectric sensors, flexible piezoelectric composite materials are commonly used due to their unique advantages, including high conformability, sensitivity, and compatibility. They have found applications in diverse domains such as underwater detection, electronic skin sensing, wearable sensors, targeted therapy, and ultrasound diagnostics for deep tissue. The advent of flexible piezoelectric composite materials has revolutionized the design concepts and application scenarios of traditional piezoelectric materials, playing a crucial role in the development of next-generation flexible electronic products. This paper reviews the research progress on flexible piezoelectric composite materials, covering their types and typical fabrication techniques, as well as their applications across various fields. Finally, a summary and outlook on the existing issues and future development of these composite materials are provided. [ABSTRACT FROM AUTHOR]

Typical wind tunnel testing involves a series of configuration changes (to the angles of control surfaces) to simulate the lift and resistance characteristics of control surfaces in different flight conditions. It is very time-consuming and labor-intensive to manually change the angles of control surfaces, especially in the large continuous reflux wind tunnel. Thus, there is a demand for a morphing system design within the wind tunnel model that can deflect the control surfaces remotely and automatically. The basic design flow and characteristics of different actuator techniques for the morphing systems were summarized in this paper, including electromechanical actuator, pneumatic actuator, shape memory material actuator and piezoelectric actuator. In the case study, the accuracy of the control surface angle and aerodynamic performance of the ultrasonic-driven automatic control surface system reached the level of traditional fixed control surface systems, while its efficiency was much higher than that of the traditional fixed control surface systems. [ABSTRACT FROM AUTHOR]

Tissue engineering is based on combining cells with suitable scaffolds and growth factors. Recently, bone tissue engineering has been especially investigated deeply due to a large number of bone-related diseases. One approach to improve scaffolds is based on using piezoelectric materials as a way to influence the growing bone tissue by mechanical stress. Another method to stimulate tissue growth is by applying an external magnetic field to composites of magnetostrictive and piezoelectric materials, as well as the possibility to prepare oriented surfaces by orienting embedded magnetic fibers or nanoparticles. In addition, magnetic scaffolds without other special properties have also been reported to show improved properties for bone tissue and other tissue engineering. Here, we provide an overview of recent research on magnetic scaffolds for tissue engineering, differentiating between bone and other tissue engineering. We show the advantages of magnetic scaffolds, especially related to cell guidance and differentiation, and report recent progress in the production and application of such magnetic substrates for different areas of tissue engineering. [ABSTRACT FROM AUTHOR]

Flexible materials with both in-plane and out-of-plane piezoelectric coefficients are needed in the development of advanced nanoelectromechanical systems. However, the challenge is to find flexible materials with the coexistence of in-plane and -out-of-plane piezoelectric responses, which hinders the progress of high-performance piezoelectric sensor development. In this paper, we propose the flexible XMAY2 (X = I; M = Ti, Zr; A = Al, Ga; Y = S, Se) monolayers, which belong to the group III-VI XMAY2 family, which showcase notable in-plane and out-of-plane piezoelectric coefficients. The in-plane (d11) and out-of-plane (d31) piezoelectric coefficients of the XMAY2 monolayers vary from 5.20 to 7.04 pm/V and from −0.23 to 0.48 pm/V, respectively. The large in-plane and out-plane piezoelectric responses coexist (d11 = 7.04 pm/V; d31 = 0.48 pm/V) in the IZrGaS2 monolayer, which is larger than other materials in the XMAY2 family, such as SMoSiN2 (d11 = 2.51; d31 = 0.28 pm/V). In addition, the mechanical and transport properties of XMAY2 demonstrate its impressive flexibility characteristics as well as its efficient electrical conductivity. Due to inversion symmetry breaking in both atomic structure and charge distribution of XMAY2 monolayers, the group III-VI XMAY2 family exhibits a potentially rich scope of applications in the field of piezoelectricity. [ABSTRACT FROM AUTHOR]

Piezoelectric materials have become a key component in sensors and actuators in many industrial fields, such as energy harvesting devices, self-powered structures, biomedical devices, nondestructive testing, owing to the novel properties including high piezoelectric coefficient and electromechanical coupling factors. Piezoelectric thin films integrated on silicon substrates are widely investigated for their high performance and low manufacturing costs to meet the requirement of sensor networks in internet of things (IoT). The aim of this work is to clarify the application and design structure of various piezoelectric thin films types, synthesis methods, and device processes. Based on latest literature, the process of fabricating thin film sensors is outlined, followed by a concise overview of techniques used in microelectromechanical systems (MEMS) processing that can integrate more complex functions to obtain relevant information in surrounding environment. Additionally, by addressing piezoelectric thin films sensors as a cutting-edge technology with the ability to produce self-powered electronic devices, this work delivers incisive conclusions on all aspects of piezoelectric sensor related features. A greater understanding of piezoelectricity is necessary regarding the future development and industry challenges. [ABSTRACT FROM AUTHOR]

Copyright of Piezoelectrics & Acoustooptics is the property of Piezoelectric & Acoustooptic and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

Re-poling of unexpected partially depoled piezoelectric materials conventionally needs to be first fully depoled through annealing above their Curie temperature to revive piezoelectric performances. Here, we investigated de-poling and re-poling of Pb(In1/2Nb1/2)O3-Pb(Mg1/3Nb2/3)O3-PbTiO3 single crystals under electric fields at room temperature. We found that alternating current electric fields with amplitudes near the coercive field at low frequencies (<10 Hz) can be employed to successfully depolarize poled crystals at room temperature. We also demonstrated a reversible polarization switching process with a relaxor-PbTiO3 single crystal ultrasound transducer without device performance degradations. This experimental observation is supported by phase-field simulation, showing that alternating current electric fields can readily induce de-poling at room temperature, while direct current electric fields induce a transient depoled state only within an uncontrollable short period of time. The findings suggest new strategies for unprecedented in-device tailoring of the polarization states of ferroelectric materials. The authors find that alternating current electric fields with amplitudes near the coercive field at low frequencies (<10 Hz) can be employed to depolarize poled relaxor-PbTiO3 single crystals at room temperature, without conventional heat treatment. [ABSTRACT FROM AUTHOR]

Skeletal muscle loss is a common clinical disease, whose long treatment period and expensive treatment costs bring a heavy burden to patients. Currently, the use of piezoelectric materials to generate in situ and efficient electrical stimulation has been proven to significantly promote wound healing and other defects. However, skeletal muscle requires repaired materials with high elastic deformation to accompany its reciprocating movement during the healing process. Therefore, developing biocompatible materials that combine high piezoelectricity and stretchability is a great challenge. In the present work, a piezoelectric elastomer PPBE is prepared by copolymerization of bio‐based diacid and diol. PPBE has matching elastic modulus with the skeletal muscle to accompanied proceed stretching and recovery movements. Piezoelectrical charge from PPBE scaffold under ultrasound and mechanical stimuli could promote myogenic differentiation via Ca2+ signaling pathway and modulate cell functions, resulting in improved muscle morphology and functional performance of skeletal muscle. Thus, development of the degradable PPBE scaffold would provide new therapy strategy for volumetric muscle loss (VML) and present great potential in repairing of other tissues. [ABSTRACT FROM AUTHOR]

We discovered large electric-field-induced strain in pyro-vanadate-phosphate Cu2−xZnxV1.8P0.2O7. Distinct from conventionally used piezoelectric materials including lead-zirconate-titanate, this material expands almost isotropically at room temperature when an electric field is applied. This volume change, exceeding 1000 ppm under the field of E = 3900 V/cm, is of the largest class induced by an electric field. The strain is phenomenologically interpreted as electrostriction because it is symmetric about E = 0 and because it obeys a higher term than E-linear such as E squared. The present x-ray diffraction experiments suggest that the applied electric field distorts the crystal lattice, although there is no structural phase transition. This material performs a volume-change-driven actuator function that is distinct from the strain-driven counterpart of piezoelectric materials. The discovery of actuator functionality in a material system with a non-perovskite structure, unlike the actuator materials developed to date, is a major breakthrough for future actuator engineering. [ABSTRACT FROM AUTHOR]

Most piezoelectric materials exhibit a positive longitudinal piezoelectric effect (PLPE), while a negative longitudinal piezoelectric effect (NLPE) is rarely reported or paid much attention. Here, utilizing first-principles calculations, we unveil the origin of negative longitudinal piezoelectricity in ferroelectric hafnia by introducing the concept of weighted projected bond strength around cation in the c direction (WPBc), which is proposed to quantitatively characterize the asymmetric bonding stiffness along the strain direction. When the WPBc is anti-parallel to the direction of bulk spontaneous polarization, the polarization decreases with respect to tensile strain and leads to a negative piezoelectricity. Furthermore, to confirm the influence of WPBc on the piezoelectric effect and understand how the value of WPBc influences the piezoelectric coefficient e33, we acquire both the piezoelectric coefficient of doped hafnia and the corresponding bonding environment around each cation. The finding reveals that the more negative piezoelectric coefficient can be achieved through a concurrent achievement of the more negative average WPBc and the lower standard deviation (STD) of WPBc. In addition, the Sn-doped hafnia with the lowest average WPBc and smaller STD-WPBc is identified to have the highest piezoelectric coefficient (−2.04 C/m2) compared to other dopants, showing great potential in next-generation electromechanical devices. [ABSTRACT FROM AUTHOR]

The lead-free piezoelectric ceramics used in piezoelectric actuators have attracted extensive attention owing to their substantial electric-field-induced strain. In this study, The (1- x)Bi 0.5 (Na 0.41 K 0.09)TiO 3 - x Sr(Hf 0.5 Sb 0.4)O 3 (BNKT- x SHS) piezoelectric ceramics were synthesized using the conventional solid-state reaction method. The impact of SHS substitution on the microstructure and electrical properties was systematically explored. Among them, the BNKT-0.015SHS sample, featuring ergodic relaxor states, demonstrates a high piezoelectric strain coefficient (d 33 *) of 785 p.m./V under a low electric field of 50 kV/cm(Strain = 0.392 %). It exhibits a repeatable strain value of 0.47 % under an 80 kV/cm electric field(d 33 * = 590 p.m./V). Moreover, the strain values remain around 0.4 % between room temperature and 100 °C, with variations within 90 %. The heightened repeatable strain response is considered to be linked to the electric field-induced reversible phase transition occurring within the ergodic relaxor state. The higher strain temperature stability is ascribed to the coexistence of quadrilateral polar nanoregions and rhombic polydomain nanoregions. This study provides an effective example for achieving significant strain responses, presenting a feasible candidate material for applications in piezoelectric actuators. [ABSTRACT FROM AUTHOR]

This paper is dedicated to the research of phenomena noticed during tests of biodegradable carrageenan-based force and pressure sensors. Peculiar voltage characteristics were noticed during the impact tests. Therefore, the sensors' responses to impact were researched more thoroughly, defining time-dependent sensor output signals from calibrated energy impact. The research was performed using experimental methods when a free-falling steel ball impacted the sensor material to create relatively definable impact energy. The sensor's output signal, which is analogue voltage, was registered using an oscilloscope and transmitted to the PC for further analysis. The obtained results showed a very interesting outcome, where the sensor, which was intended to be piezoresistive, demonstrated a combination of behaviour typical for galvanic cells and piezoelectric material. It provides a stable DC output that is sensitive to the applied statical pressure, and in case of a sudden impact, like a hit, it demonstrates piezoelectric behaviour with some particular effects, which are described in the paper as proton transfer in the sensor-sensitive material. Such phenomena and sensor design are a matter of further development and research. [ABSTRACT FROM AUTHOR]

Piezoelectric energy harvesting technology is drawing substantial attention as an eco‐friendly method to promote energy transformation, which is at the forefront of current scientific research. However, the difficulties involved in obtaining a stable output voltage (Vout) and a controllable output current density (Iout) represent bottlenecks in the development of piezoelectric energy harvesters (PEHs) for practical applications. Here, a novel strategy that couples elastic polarization configuration with activity rattling space in lead‐free potassium sodium niobate‐based piezoceramics is proposed to break through this barrier. The cantilever beam‐type PEHs assembled using the rationally designed piezoceramic system show a stable Vout (≈22 V) and a controllable Iout over the range from 6.09 to 20.16 µA cm−2, which is sufficient to drive multiple types of wireless sensors that have the same rated voltage but different rated current requirements. These fantastic power generation performances are associated with a stable piezoelectric voltage coefficient (g33), an increasing piezoelectric charge coefficient (d33), and a weakened electrostrictive coefficient (Q33) that stem from polarization configuration optimization in combination with introduction of the activity rattling space design. This work provides a good approach to modulation of the overall performance of piezoelectric materials to meet the demands of advanced PEH applications. [ABSTRACT FROM AUTHOR]

Bismuth titanate-ferrite (Bi 5 Ti 3 FeO 15 , BTF) has received extensive attention for electromagnetic and ferromagnetic coupling applications due to the coexistence of ferroelectric and antiferromagnetic orders. Recent reports indicate that the ferroelectric BTF is a good high-temperature piezoelectric material due to its high Curie temperature T c (∼761 ℃). However, the piezoelectric properties of BTF have not been sufficiently studied yet; in addition, the low electrical resistance and poor piezoelectric properties of BTF at elevated temperatures limit its high-temperature piezoelectric applications. Herein, we report the significantly piezoelectric performance of BTF through rare-earth gadolinium-substitutions. The crystal structure, microstructural morphology, and piezoelectric properties of gadolinium-substituted BTF with nominal compositions of Bi 5- x Gd x Ti 3 FeO 15 (abbreviated as BTF-100 x Gd) were investigated in detail. Benefiting from the enhanced tetragonal lattice distortion revealed by the X-ray diffraction (XRD) refinements and the decreased domain size that detected by the piezo-response force microscopy (PFM), the BTF-6Gd exhibits a significantly enhanced piezoelectric constant d 33 of 24.2 pC/N, which is three times larger than that of BTF (7.1 pC/N), simultaneously accompanied with a high T c of 808 ℃. Furthermore, the BTF-6Gd exhibits a high-temperature dc electrical resistivity ρ of 1.3 × 105 Ω cm at 500 ℃, and excellent thermal stabilities of piezoelectric and electromechanical properties up to 400 ℃. These results suggest that BTF-100 x Gd ceramic materials are outstanding candidates for high-temperature piezoelectric applications. [ABSTRACT FROM AUTHOR]

The demand for self‐powered sensing technology and energy harvesting system necessitates high‐performance and flexible piezoelectric materials. This paper presents a novel approach utilizing coaxial electrospinning to fabricate all‐organic PVDF/PMMA piezoelectric fiber films with a shell–core structure. The resulting fiber films, cut into 2 × 2 cm2 square pieces and hot‐pressed every three pieces, demonstrate enhanced piezoelectric properties while retaining high flexibility. The interaction between the CO bonds in the PMMA polymer and the CH2 in PVDF promotes the arrangement of F atoms in PVDF, enhancing the content of the piezoelectric active phase. Additionally, the coaxial electrospinning process fosters vertically oriented hydrogen bonds between PVDF and PMMA, augmenting cross‐linking and improving mechanical properties. Notably, when the PVDF to PMMA layer volume ratio is 5:1, the piezoelectric coefficient (|d33|) of the composite fiber film exhibits a significant 60% increase from 10 pC N−1 in neat PVDF to 16 pC N−1. This research holds substantial promise for applications in self‐powered sensing and energy harvesting piezoelectric materials. [ABSTRACT FROM AUTHOR]

Piezoelectric actuators have been extensively utilized as micro-displacement devices because of their advantages of large output displacement, high sensitivity, and immunity to electromagnetic interference. Here, we propose a straightforward approach to design <110>-oriented defect dipoles by introducing A-site vacancies and oxygen vacancies in (K0.48Na0.52)0.99NbO2.995 ceramics. As a result, we achieve ultrahigh electrostrains of 0.7% at 20 kV cm-1 (with an effective piezoelectric strain coefficient d33* = 3500 pm V-1), outperforming the performance of existing piezoelectric ceramics at the same driving field. The exceptional electrostrain is primarily attributed to the large stretching of defect dipoles when subjected to an applied electric field, a phenomenon that has been experimentally confirmed. Moreover, the strong interaction between these defect dipoles and <110> spontaneous polarizations plays a critical role in minimizing hysteresis and ensuring excellent fatigue resistance. Our findings present a practical and effective strategy for developing high-performance piezoelectric materials tailored for advanced actuator applications. [ABSTRACT FROM AUTHOR]

The development of green and efficient deuteration methods is of great significance for various fields such as organic synthesis, analytical chemistry, and medicinal chemistry. Herein, we have developed a dehalogenative deuteration strategy using piezoelectric materials as catalysts in a solid‐phase system under ball‐milling conditions. This non‐spontaneous reaction is induced by mechanical force. D2O can serve as both a deuterium source and an electron donor in the transformation, eliminating the need for additional stoichiometric exogenous reductants. A series of (hetero)aryl iodides can be transformed into deuterated products with high deuterium incorporation. This method not only effectively overcomes existing synthetic challenges but can also be used for deuterium labelling of drug molecules and derivatives. Bioactivity experiments with deuterated drug molecule suggest that the D‐ipriflavone enhances the inhibitory effects on osteoclast differentiation of BMDMs in vitro. [ABSTRACT FROM AUTHOR]

Piezocatalysis is considered as an evolving technology based on the piezoelectric properties of catalysts, has shown great potential in the field of environmental remediation, water splitting, and biotechnology. In this work, the catalytic performance of (Ba0.95Ca0.05) (Ti1-xSnx)O3 (BCT1-xSx, 0.04 ≤ x ≤ 0.12) piezoelectric ceramics was studied systematically. The relationship between piezoelectric performance and piezo-photocatalytic performance was investigated. As the Sn content increased, the crystalline structure gradually changed from the orthorhombic (O) phase (x = 0.04) to O-pseudocubic (PC) two-phase coexistence (x = 0.08 and x = 0.10), and finally to the PC phase (x = 0.12). The piezoelectric constant d33 exhibited an initial increases followed by a decreases with rising Sn content, reaching peak of 509pC/N at x = 0.10. The enhanced d33 was due to multiphase coexistence and a Curie temperature near room temperature. The piezocatalytic efficacy of BCT1-xSx was linked to d33, with the maximum degradation rate achieved at x = 0.10. However, the optimal piezo-photocatalytic performance was obtained at x = 0.08 instead of x = 0.10 with the highest degradation rate of 69%. The photo-piezocatalytic performance was discovered to be intricately linked not only to the band gap of piezocatalysts but also influenced by their piezoelectric properties. These results will provide guidance for designing new lead-free piezoelectric materials with excellent catalytic properties. [ABSTRACT FROM AUTHOR]