994 results on '"Physical separation"'
Search Results
152. Development and demonstration of a cleaner process to produce diosgenin from Dioscorea zingiberensis based on physical separation.
- Author
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Pan, Cenxuan, Zhao, Yi, Liu, Guihua, Dou, Guangyu, Ru, Zhenguang, and Zhu, Kesong
- Subjects
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CLEANING , *DIOSGENIN , *YAMS , *SEPARATION (Technology) , *POLLUTANTS , *WASTEWATER treatment , *CHEMICAL oxygen demand - Abstract
Abstract: A new, cleaner process to produce diosgenin (CAS number 512-04-9) from Dioscorea zingiberensis with much less pollutant generation has been developed based on physical separation. A demonstration factory with an annual production capacity of 200 t of diosgenin has been built in Shanyang County, Shaanxi Province, China. The new process employs several new techniques including separation and refinement of starch, reuse of acid and mechanical washing of acid hydrolyzate. Through the application of a series of cleaner techniques, the water consumption was reduced by 66.2%, the wastewater generation was reduced by 63.3%, the acid consumption was reduced by 81.1%, the residual acid in the wastewater was reduced by 93.4% and the chemical oxygen demand production was reduced by 43.7%. The overall economic benefit increased RMB 38,087 Yuan (USD 6046) per t of diosgenin. Based on the new process, the wastewater can be treated to meet the national discharge standard using a common wastewater treatment technology. [Copyright &y& Elsevier]
- Published
- 2014
- Full Text
- View/download PDF
153. A report on the housing vervet monkeys adjacent to domestic cats as a means of environmental enrichment
- Author
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Andre Ganswindt, John K. Chipangura, and Vinny Naidoo
- Subjects
Male ,animal diseases ,Zoology ,Pilot Projects ,Alarm signal ,stress ,domestic cats ,biology.animal ,Chlorocebus aethiops ,parasitic diseases ,medicine ,Animals ,Primate ,Habituation ,vervet monkeys ,Original Research ,faecal glucocorticoid metabolites ,Environmental enrichment ,lcsh:Veterinary medicine ,CATS ,General Veterinary ,biology ,Aggression ,General Medicine ,Stress alleviation ,Housing, Animal ,Physical separation ,Cats ,lcsh:SF600-1100 ,Female ,medicine.symptom - Abstract
In current research guidelines, much focus is placed on ethical management of animals and the application of principles of reduction, refinement and replacement. Of these refinements through environmental enrichment is an important aspect when housing primate to prevent behavioural problems. In this study, we investigated the co-housing of domestic cats and vervet monkeys as a novel method of enrichment based on the cohabitation and stress alleviation effect of horses housed with goats and from seeing cats cohabitating with vervet monkeys in an animal sanctuary. The study used a habituation method whereby the cats were stepwise introduced to the monkeys by sight and smell but with physical separation. Assessment included changes in behaviour, weight and faecal glucocorticoid metabolite (fGCM) concentrations over time. On the first day of housing, the vervets whilst inquisitive kept their distance. The vervets housed in cages that were closest to the cats were the most active and during the first minute of introduction made more alarm calls, which stopped a few days later. The fGCMs were non-significantly different. The results of this study provide evidence that vervet monkeys and domestic cats could potentially be housed together without overt aggression. We thus suggest further observations to ascertain if the co-housing could have long-term benefits for vervet monkeys, from the companionship that would be offered by the cats.
- Published
- 2020
154. Evaluation of a recycling process for printed circuit board by physical separation and heat treatment.
- Author
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Fujita, Toyohisa, Ono, Hiroyuki, Dodbiba, Gjergj, and Yamaguchi, Kunihiko
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PRINTED circuits , *WASTE recycling , *SEPARATION (Technology) , *HEAT treatment , *CERAMIC capacitors - Abstract
Highlights: [•] The parts mounted on printed circuit board (PCB) were liberated by underwater explosion and mechanical crushing. [•] The crushed PCB without surface-mounted parts was carbonized under inert atmosphere at 873K to recover copper. [•] The multi-layered ceramic capacitors including nickel was carbonized at 873K to recover nickel by the magnetic separation. [•] The tantalum powders were recovered from the molded resins by heat treatment at 723 and 823K in air atmosphere and screening. [•] Energy and treatment cost of new process increased, however, the environmental burden decreased comparing conventional one. [Copyright &y& Elsevier]
- Published
- 2014
- Full Text
- View/download PDF
155. Implementation of a model for Falcon separation units using continuous size-density distributions.
- Author
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Kroll-Rabotin, Jean-Sébastien and Sanders, R. Sean
- Subjects
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FALCONS , *SEPARATION (Technology) , *GRAVITY , *CONTINUOUS functions , *COAL , *PARTICLE size distribution - Abstract
Highlights: [•] Modeling of the Falcon enhanced gravity separator. [•] Representation of washabilities with continuous functions. [•] Application to coal fines and dredged sediments particle size–density distributions. [•] Step towards validation of the model for industrial scale Falcon devices. [Copyright &y& Elsevier]
- Published
- 2014
- Full Text
- View/download PDF
156. Increasing desilication product particle size to enable its physical separation from Bayer residue
- Author
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Dilini Nadika Seneviratne
- Subjects
Residue (complex analysis) ,Chemical engineering ,Chemistry ,Product (mathematics) ,Physical separation ,Particle size - Published
- 2020
157. CREATIVE CONNECTIONS: MAINTAINING STUDIO CULTURE IN AN AGE OF PHYSICAL SEPARATION
- Author
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Alvin Huang, Tatiana Estrina, and Vincent Hui
- Subjects
Engineering ,business.industry ,Physical separation ,business ,Studio ,Visual arts - Published
- 2020
158. Accesibilidad espacial en áreas de proximidad peatonal a equipamientos educativos públicos en Sincelejo, año 2019
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Guzmán Benitorevollo, Shaira and Gómez Ramos, Arnulfo Manuel
- Subjects
Educación Pública ,Physical separation ,Justicia espacial ,Separación física ,Public education ,Spatial justice ,SIG ,GIS - Abstract
Education is one of the most essential universal rights, therefore it is necessary to guarantee its accessibility to the entire population and especially to the most disadvantaged areas. This study analyzes the physical proximity of the population to the public education system, seen from the perspective of pedestrian displacement, for which quantitative variables (conditions of displacement, recruitment of students) and qualitative variables (social characteristics of the population) were contrasted. In the first part, it was possible to clarify that the state educational offer in Sincelejo exhibits a spatial pattern of random distribution in all levels of education, while in the second part it was possible to show that the distance (spatial separation) and the time used to travel towards educational facilities, it is given according to the spatial arrangement of each establishment and the road articulation of Sincelejo. The analysis showed that the level of general physical access to public educational institutions is favorable, with an average time of 11.8 minutes, hence communes two, four, eight, and one present the best conditions as they are below the average, in On the other hand, in the areas where cohesion and road infrastructure present deficiencies, the members of the student community can see the increase in travel times to 12.6 15 and 24.6 minutes in communes 9, 6 and 7 respectively. Keywords: public education, spatial justice, physical separation, GIS. Resumen .......................................................................................................................................... 4 Summary ......................................................................................................................................... 5 1. Introducción ............................................................................................................................... 6 2. Área de estudio ....................................................................................................................... 9 3. Materiales y métodos ........................................................................................................... 11 3.1. Procesamiento de la información ............................................................................ 13 4. Análisis de resultados .......................................................................................................... 15 4.1. Análisis de distribución y accesibilidad espacial al equipamiento educativo más cercano en el área urbana de Sincelejo durante el año 2019. ................................................................... 15 4.2. Accesibilidad promedio a equipamientos educativos de nivel preescolar y básica primaria. ....................................................................................................................................................................... 18 4.3. Accesibilidad promedio a equipamientos educativos de nivel básica secundaria y media académica. ................................................................................................................................. 21 4.4. Accesibilidad promedio a equipamientos educativos de ciclo completo. ...................... 23 4.5. Proximidad promedio a equipamientos de educación en Sincelejo. .............................. 26 5. Discusión ............................................................................................................................... 28 6. Conclusión ............................................................................................................................. 31 7. Referencias bibliográficas ..................................................................................................... 33 Monografía La educación supone uno de los derechos universales más esenciales, por ello es necesario que se garantice su accesibilidad a toda la población y en especial a las zonas más desfavorecidas. En este estudio se analiza la proximidad física de la población al sistema de educación pública, visto desde la perspectiva del desplazamiento peatonal, para lo cual fueron contrastadas variables cuantitativas (condiciones de desplazamiento, captación de estudiantes) y cualitativas (características sociales de la población). En la primera parte se logró esclarecer que la oferta educativa estatal en Sincelejo exhibe un patrón espacial de distribución aleatorio en todos los niveles de educación, mientras que en la segunda parte se logró evidenciar que la distancia (separación espacial) y el tiempo empleado para desplazarse hacia los equipamientos educativos, se da en función de la disposición espacial de cada establecimiento y la articulación vial de Sincelejo. El análisis demostró que el nivel de acceso físico general a instituciones educativas públicas es favorable, con un tiempo promedio de 11,8 minutos, de ahí que las comunas dos, cuatro ocho y uno presenten las mejores condiciones al estar por debajo del promedio, en cambio, en las zonas donde la cohesión e infraestructura vial presentan deficiencias los miembros de la comunidad estudiantil pueden ver el aumento en los tiempos de desplazamiento a 12,6 15 y 24,6 minutos en las comunas 9, 6 y 7 respectivamente. Pregrado Geógrafo(a)
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- 2020
159. Glass entanglement
- Author
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Tobias Klein
- Subjects
Physics ,Work (thermodynamics) ,Classical mechanics ,Group (mathematics) ,Quantum state ,Physical separation ,Particle ,Biological cell ,Quantum entanglement - Abstract
In quantum physics, quantum entanglement is a phenomenon that occurs when a group of particles is generated in such a way that the quantum state of each individual particle cannot be described independently from the other. The work Glass Entanglement constructs a similar state in which neither its digital nor analog parts could be read individually and where each part could not be described independently from the other. This work consists of the physical separation of the parts of cellular glass volumes from one another and the 3D-printed form interacting with these single objects to form an ecosystem between the glass volumes. The elements are held together by digitally modeled, tendril-like structures, analogous to the biological cell growth when forming multicellular higher-order organisms.
- Published
- 2020
160. No More 'Social Distancing' But Practice Physical Separation
- Author
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David Wong, Debasree Das Gupta, and Springer New York LLC
- Subjects
Canada ,medicine.medical_specialty ,2019-20 coronavirus outbreak ,distancing ,Coronavirus disease 2019 (COVID-19) ,Distancing ,Severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) ,physical separation ,Physical Distancing ,social distance ,Pandemic ,medicine ,Humans ,Sociology ,Pandemics ,Public health ,Social distance ,pandemic ,Public Health, Environmental and Occupational Health ,COVID-19 ,Special Section on COVID-19: Letter to the Editor ,General Medicine ,Kinesiology ,Social Isolation ,Physical separation ,Public Health ,Social psychology - Abstract
Though not a new term, “social distancing” exploded onto the global stage as an expression to publicize the only means currently available to control the transmission of COVID-19. This term is increasingly being adopted and translated into the vernacular to inform and guide public behavior in most, if not all, countries around the world. However, any effective global response requires direct and unambiguous communication and sharing of ideas across communities with different cultural backgrounds as well as between researchers and responders across the disciplinary spectrum. Unfortunately, social distancing is a misnomer. The current use of social distancing – separating ourselves physically to avoid infection – is not consistent with what the term actually means. Consequently, as a diktat, social distancing is not self-explanatory, conceptually ambiguous, practically misleading, and intellectually misplaced. To highlight these problems, we present arguments from multiple perspectives, calling governments, public health officials, and the media to abandon the use of social distancing, replacing it with more intuitively accurate and meaningful terms. Such a move would ensure clear consistent messaging that is critical to retain public trust especially during global public health crises.
- Published
- 2020
161. Recovery of single source DNA profiles from mixtures by direct single cell subsampling and simplified micromanipulation
- Author
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Jack Ballantyne, Erin K. Hanson, and Kaitlin Huffman
- Subjects
010401 analytical chemistry ,Sampling (statistics) ,DNA ,01 natural sciences ,DNA extraction ,DNA Fingerprinting ,Polymerase Chain Reaction ,0104 chemical sciences ,Pathology and Forensic Medicine ,03 medical and health sciences ,Forensic dna ,Micromanipulation ,0302 clinical medicine ,STR analysis ,DNA profiling ,Single-cell analysis ,Physical separation ,Humans ,030216 legal & forensic medicine ,Deconvolution ,Biological system ,Mathematics ,Microsatellite Repeats - Abstract
Deconvolution of forensic DNA mixtures into their individual component DNA (geno)types is of great investigative value, though often complex and difficult. Two-person mixtures comprising a major and minor contributor are often easily interpreted although, when the DNA ratio of the two individuals is approximately equal (~1:1), deconvolution and interpretation becomes much more difficult. To address this issue, a physical separation of individual-, two- or three- cell subsamples prior to autosomal STR analysis was performed using a simplified micromanipulation technique paired with a decreased reaction volume and increased cycle number PCR. Using this method, single and multiple buccal epithelial cells were collected from a 1:1 two-person mixture (i.e. from individual 'A' and 'B') and directly amplified, omitting standard DNA extraction and purification steps. Single cell subsamples resulted in partial single-source profiles for both contributors while, in accordance with expectations of a quasi-binomial sampling schema, two- and three-cell subsamples resulted in single source informative partial profiles of individual A and individual B as well as complete consensus profiles, and equally mixed 1:1 (2-cell subsamples) and 2:1 (3-cell subsamples) admixed profiles of individual A and B.This proof-of-concept approach shows promise in permitting the DNA deconvolution of mixed samples where the individual contributors are present in similar amounts that would otherwise be difficult to interpret, resulting in an increase in evidentiary value. The subsampling approach can be readily investigated for DNA casework applications without additional investment in costly, new equipment, requiring only a stereo microscope and a tungsten needle.
- Published
- 2020
162. Serendipitous Discovery of a Physical Binary Quasar at z=1.76
- Author
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S. Brennan, E. Altamura, Kasper E. Heintz, Tapio Pursimo, Johan P. U. Fynbo, S. Geier, Palle Møller, S. N. dos Reis, A. Leśniewska, and V. Pintér
- Subjects
010504 meteorology & atmospheric sciences ,Astrophysics::High Energy Astrophysical Phenomena ,FOS: Physical sciences ,Binary number ,DUST ,Redshifted ,Astrophysics ,Astrophysics::Cosmology and Extragalactic Astrophysics ,01 natural sciences ,0103 physical sciences ,Emission spectrum ,Double quasars ,Quasars ,010303 astronomy & astrophysics ,Astrophysics::Galaxy Astrophysics ,0105 earth and related environmental sciences ,Physics ,Astrophysics of Galaxies ,Angular distance ,DIGITAL-SKY-SURVEY ,Astrophysics::Instrumentation and Methods for Astrophysics ,Astronomy and Astrophysics ,Quasar ,Astrophysics - Astrophysics of Galaxies ,GRAVITATIONALLY LENSED QUASAR ,Redshift ,Cosmology ,EFFICIENT PHOTOMETRIC SELECTION ,EXCESS ,Space and Planetary Science ,Astrophysics of Galaxies (astro-ph.GA) ,Physical separation ,SEPARATION - Abstract
Binary quasars are extremely rare objects, used to investigate clustering on very small scales at different redshifts. The cases where the two quasar components are gravitationally bound, known as physical binary quasars, can also exhibit enhanced astrophysical activity and therefore are of particular scientific interest. Here we present the serendipitous discovery of a physical pair of quasars with an angular separation of $\Delta\theta = (8.76 \pm 0.11)$ arcsec. The redshifts of the two quasars are consistent within the errors and measured as $z = (1.76\pm 0.01)$. Under the motivated assumption that the pair does not arise from a single gravitationally lensed quasar, the resulting projected physical separation was estimated as $(76 \pm 1)$ kpc. For both targets we detected Si VI, C VI, C III], and Mg II emission lines. However, the two quasars show significantly different optical colours, one being among the most reddened quasars at $z > 1.5$ and the other with colours consistent with typical quasar colours at the same redshift. Therefore it is ruled out that the sources are a lensed system. This is our second serendipitous discovery of a pair of two quasars with different colours, having a separation $\lesssim 10$ arcsec, which extends the very limited catalogue of known quasar pairs. We ultimately argue that the number of binary quasars may have been significantly underestimated in previous photometric surveys, due to the bias arising from paired quasars with very different colours.
- Published
- 2020
163. Two alternative process routes for recovering pure indium from waste liquid crystal display panels
- Author
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Antero Laitinen, Sami Virolainen, Tommi Huhtanen, Tuomo Sainio, Lappeenrannan-Lahden teknillinen yliopisto LUT, Lappeenranta-Lahti University of Technology LUT, and fi=School of Engineering Science|en=School of Engineering Science
- Subjects
Materials science ,Indium tin oxide (ITO) ,020209 energy ,Strategy and Management ,chemistry.chemical_element ,02 engineering and technology ,Alternative process ,Indium ,Industrial and Manufacturing Engineering ,law.invention ,chemistry.chemical_compound ,Physical separation ,Bench-scale ,law ,0202 electrical engineering, electronic engineering, information engineering ,Hydrometallurgy ,SDG 7 - Affordable and Clean Energy ,0505 law ,General Environmental Science ,Liquid-crystal display ,Renewable Energy, Sustainability and the Environment ,05 social sciences ,Metallurgy ,Sulfuric acid ,Indium tin oxide ,Extraction Purification ,chemistry ,050501 criminology ,LCD panels ,Leaching (metallurgy) - Abstract
Recovering indium from liquid crystal display (LCD) screen waste is important from a sustainability point of view for several reasons: the environmentally hazardous metals are not landfilled, the recovery process involves lower CO2 emissions than primary production, and supply from secondary sources matches the continuously increasing demand of indium. In this study, two alternative process routes for recycling the critical metal, indium, from LCD panel waste were studied and compared using laboratory and bench-scale experiments. The first process was a conventional hydrometallurgical process that involves manual dismantling, hammer mill crushing of the glass, cross-current sulfuric acid leaching of the metals, and liquid-liquid extraction separation of indium. Using this process, over 99% pure indium solution can be produced with a recovery yield of over 70%. The second process is novel because it includes (manual) scraping of the indium tin oxide (ITO) layer from the glass panels, followed by sulfuric acid leaching of the metals. The yield of indium was over 80%, and the purity of the resulting solution was over 99%. The solutions obtained from either of the suggested processes were sufficiently pure for cementing indium in high purity. The novel process appears much more straightforward and economically more feasible because the polarizing filter need not be removed and the liquid-liquid extraction purification step is excluded. Moreover, less amount of leaching acid is required. Post-print / Final draft
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- 2020
164. Reunifying and separating: An analysis of residential arrangements of migrant couples in Ouagadougou, Burkina Faso
- Author
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Souleymane Sanogo, Marie-Laurence Flahaux, Madeleine Wayack‐Pambè, Yacouba Compaoré, Abdramane Bassiahi Soura, Laboratoire Population-Environnement-Développement (LPED), Institut de Recherche pour le Développement (IRD)-Aix Marseille Université (AMU), Université Joseph Ki-Zerbo [Ouagadougou] (UJZK), Centre de recherche en démographie (DEMO), Université Catholique de Louvain = Catholic University of Louvain (UCL), and Université Catholique de Louvain (UCL)
- Subjects
mixed methods ,residential arrangements ,Geography, Planning and Development ,0211 other engineering and technologies ,0507 social and economic geography ,Context (language use) ,02 engineering and technology ,[SHS.DEMO]Humanities and Social Sciences/Demography ,migration ,Living apart together ,Urbanization ,Sociology ,Ouagadougou ,10. No inequality ,Demography ,urbanisation ,Qualitative interviews ,Gender relations ,05 social sciences ,021107 urban & regional planning ,living apart together ,Physical separation ,Demographic economics ,Demographic surveillance system ,050703 geography ,Family reunification ,family reunification - Abstract
International audience; This paper offers new evidence on the residential arrangements of couples in the context of migration and urbanisation in Africa, focusing on the case of Ouagadougou, Burkina Faso's capital city. We use a mixed-methods approach, combining data from a survey on the family histories of migrants merged with data from the Ouagadougou Health and Demographic Surveillance System and qualitative interviews. The objective is to analyse how the migrants themselves perceive "living apart together", the extent of this phenomenon, its timing, and the factors influencing it. The longitudinal nature of our data specifically allows for the study of the drivers of couple reunification in Ouagadougou and of the physical separation of partners, whereby one goes to live away from Ouagadougou. Our results reveal that 25% of migrants in a union had a partner living outside Ouagadougou in 2015, and that the residential arrangements of such couples were associated with gender relations, family cycle, and integration into the city.
- Published
- 2020
165. ‘Transported to your presence’: Leigh Hunt’s Letters to the Shelleys
- Author
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Daniel Westwood
- Subjects
Literature ,Style (visual arts) ,Friendship ,State (polity) ,business.industry ,media_common.quotation_subject ,Physical separation ,Ideology ,Art ,business ,Ambivalence ,media_common ,Shadow (psychology) - Abstract
‘Whenever I write to you, I seem to be transported to your presence’: the remarks that open Leigh Hunt’s 23 August 1819 letter to the Shelleys exhibit, in miniature, the characteristics that define Hunt’s epistolary style. If Hunt is a writer who delights in the bonds that might be established or maintained through the letter, his letters remain conscious of the physical experiences and encounters that cannot be replicated easily within the scope of the epistolary form. In the above quotation, the conditional ‘seem’ casts a qualifying shadow over Hunt’s celebration of an imagined proximity, even as the letter prizes this state of seeming as a means of converting absence into a virtual form of presence, however temporary this illusion may be. Such ambivalence is typical of Hunt’s letters to the Shelleys, which exemplify Hunt’s use of the letter as a means of negotiating divisions between himself and his correspondents, as well as Hunt’s understanding of the letter as a vehicle of mobility, a space in which a writer must adopt varying postures and positions depending on the needs of his correspondent and the communicative situation. Having first met in 1811, Hunt and Shelley forged a friendship in 1816 that remained close until Shelley’s death in 1822, including the years from 1818 onwards when Shelley, with Mary, was resident in Italy. Their separation shaped a correspondence that involved Marianne Hunt and Mary Shelley as active participants (though Marianne wrote less frequently than Shelley, Mary, or Hunt), with letters often centring on the enduring quality of the two couples’ friendship and the possibility of the Hunts joining the Shelleys in Italy, a reunion belatedly achieved just weeks prior to Shelley’s death. Focusing on letters exchanged by Hunt and the Shelleys in 1819, including those written while Shelley was composing works such as The Mask of Anarchy late that year, this essay will explore the varying ways Hunt’s letters attempt to conjure into being a sense of proximity, connection, or consensus that might reconcile, or at least mitigate, divisions ranging from physical separation to ideological discord.
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- 2020
166. The screening efficiency of linear vibrating screen - An experimental investigation
- Author
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S. Bharath Kumar, Harsha Vardhan, Marutiram Kaza, H. Harish, Rameshwar Sah, and M. Govinda Raj
- Subjects
Blinding ,business.industry ,Computer science ,Physical separation ,Process engineering ,business ,Production rate - Abstract
Screening is a process of continuous physical separation of two or more powdered material depending on the particle size and particle shape. The present investigation involves the study of screening efficiency obtained in the widely used plant scale linear vibrating screen. The present investigation also involves the recommendations for improving screening efficiency. The result shows that the linear vibrating screen has the maximum screening efficiency of 65.92% for first 10 minutes of screening and reduced up to 59.34% for 60 minutes of screening. The reduction in screening efficiency with respect to screening time is due to the screen blinding. The screening of powdered materials faces the problem of screen mesh blinding which reduces the screening efficiency. The present authors recommend utilizing the screen configuration of circular vibrating screen which can provide higher screening efficiency with reduced screen blinding. The utilization of circular vibrating screen will reduce the screen blinding and prevents the labor requirement for removing screen blinding thereby increasing the efficiency and the production rate of screening.
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- 2020
167. Nuclear Waste and Biocatalysis: A Sustainable Liaison?
- Author
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Kristina Djanashvili, Wuyuan Zhang, Frank Hollmann, Huanhuan Liu, Miguel Alcalde, Antonia G. Denkova, Peter-Leon Hagedoorn, and Morten M. C. H. van Schie
- Subjects
biocatalysis ,010405 organic chemistry ,Chemistry ,peroxygenases ,Radical ,Radioactive waste ,General Chemistry ,010402 general chemistry ,sustainability ,01 natural sciences ,Catalysis ,0104 chemical sciences ,oxyfunctionalization ,radiation ,chemistry.chemical_compound ,Biocatalysis ,Physical separation ,Radiolysis ,Water splitting ,Biochemical engineering ,Hydrogen peroxide ,Research Article - Abstract
It is well-known that energy-rich radiation induces water splitting, eventually yielding hydrogen peroxide. Synthetic applications, however, are scarce and to the best of our knowledge, the combination of radioactivity with enzyme-catalysis has not been considered yet. Peroxygenases utilize H2O2 as an oxidant to promote highly selective oxyfunctionalization reactions but are also irreversibly inactivated in the presence of too high H2O2 concentrations. Therefore, there is a need for efficient in situ H2O2 generation methods. Here, we show that radiolytic water splitting can be used to promote specific biocatalytic oxyfunctionalization reactions. Parameters influencing the efficiency of the reaction and current limitations are shown. Particularly, oxidative inactivation of the biocatalyst by hydroxyl radicals influences the robustness of the overall reaction. Radical scavengers can alleviate this issue, but eventually, physical separation of the enzymes from the ionizing radiation will be necessary to achieve robust reaction schemes. We demonstrate that nuclear waste can also be used to drive selective, peroxygenase-catalyzed oxyfunctionalization reactions, challenging our view on nuclear waste in terms of sustainability.
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- 2020
168. Engineered adsorbents for the removal of contaminants of emerging concern from water
- Author
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Bethzaely Fernández-Reyes, Krisiam Ortiz-Martínez, José A. Lasalde-Ramírez, and Arturo J. Hernández-Maldonado
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Adsorption ,Materials science ,Chemical engineering ,chemistry ,Physical separation ,Surface modification ,chemistry.chemical_element ,Contamination ,Mesoporous silica ,Carbon - Abstract
The successful use of physical separation via adsorption for the removal of contaminants of emerging concern (CECs) from water ultimately will depend on the ability of designing the adsorbent from the bottom up to tailor its textural properties and surface functional groups to simultaneously target both the physical and chemical identities of the contaminants. In this chapter, we present and discuss various efforts made in this area for particular families of adsorbent materials, namely carbon-based zeolites, metal–organic frameworks, mesoporous silica, clays, and composites. Functionalization of these materials in attempts to enhance surface area, pore volume, and surface charging, as well as imparting combined hydrophobicity and specific surface interactions (other than electrostatic), and how these affect both CEC adsorption capacity and selectivity are thoroughly discussed.
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- 2020
169. The Gaia Ultra-Cool Dwarf Sample - III: Seven new multiple systems containing at least one Gaia DR2 ultracool dwarf
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D. J. Pinfield, Kelle L. Cruz, L. M. Sarro, Federico Marocco, Adam J. Burgasser, J. M. Rees, R. L. Smart, Jose A. Caballero, Dan Caselden, R. Van Linge, Eric E. Mamajek, Sarro, L. M. [0000-0002-5622-5191], Smart, R. [0000-0002-4424-4766], Burgasser, A. J. [0000-0002-6523-9536], National Aeronautics and Space Administration (NASA), NNX15AI75G, Ministerio de Economía y Competitividad (MINECO), Unidad de Excelencia Científica María de Maeztu Centro de Astrobiología del Instituto Nacional de Técnica Aeroespacial y CSIC, MDM-2017-0737, National Aeronautics and Space Administration (NASA), and Agencia Estatal de Investigación (AEI)
- Subjects
Physics ,Brown dwarfs ,010308 nuclear & particles physics ,Brown dwarf ,Binary number ,Astronomy and Astrophysics ,Astrophysics ,Star (graph theory) ,visual [Binaries] ,01 natural sciences ,LT UMa ,Space and Planetary Science ,V478 Lyr ,CD-28 8692 ,low-mass [Stars] ,Physical separation ,0103 physical sciences ,010303 astronomy & astrophysics ,Data release ,individual: HD 164507 [Stars] - Abstract
We present 10 new ultracool dwarfs in seven wide binary systems discovered using Gaia second data release data, identified as part of our Gaia Ultra-Cool Dwarf Sample project. The seven systems presented here include an L1 companion to the G5 IV star HD 164507, an L1: Companion to the V478 Lyr AB system, an L2 companion to the metal-poor K5 V star CD-28 8692, an M9 V companion to the young variable K0 V star LT UMa, and three low-mass binaries consisting of late Ms and early Ls. The HD 164507, CD-28 8692, V478 Lyr, and LT UMa systems are particularly important benchmarks, because the primaries are well characterized and offer excellent constraints on the atmospheric parameters and ages of the companions. We find that the M8 V star 2MASS J23253550+4608163 is ∼2.5 mag overluminous compared to M dwarfs of similar spectral type, but at the same time it does not exhibit obvious peculiarities in its near-infrared spectrum. Its overluminosity cannot be explained by unresolved binarity alone. Finally, we present an L1+L2 system with a projected physical separation of 959 au, making this the widest L + L binary currently known., With funding from the Spanish government through the "María de Maeztu Unit of Excellence" accreditation (MDM-2017-0737)
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- 2020
170. Advances in lipidomics for cancer biomarker discovery
- Author
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Laura M. Lilley, Harshini Mukundan, and Loreen R. Stromberg
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business.industry ,Cancer ,Computational biology ,medicine.disease ,Key factors ,Physical separation ,Lipidomics ,medicine ,Disease biomarker ,lipids (amino acids, peptides, and proteins) ,Biomarker discovery ,Lipid biomarkers ,Disease manifestation ,business - Abstract
The cumulative work of several decades of cancer research has unveiled a wealth of genotypic and phenotypic profiles on many types of cancer and associated biomarkers. While therapies and diagnostics targeting specific protein-based biomarkers have demonstrated enormous success, there are many biomarkers left to discover and evaluate for efficacy. Lipids play a significant role in the manifestation of cancer. However, research into lipid biomarkers of cancer is still in its infancy, as methods for isolating and characterizing lipids still predominantly rely on physical separation techniques and spectroscopic evaluation. Disease biomarkers often have hydrophobic and hydrophilic moieties required for biological function. Yet, most detection methods target the hydrophilic proteomic or glycosylated components, and ignore the relevance of lipids in disease manifestation. Recent advances in lipid-based detection technologies coupled with continued development of antibodies against small, lipidic molecules may serve as key factors for unlocking the future of lipid-based cancer diagnostics.
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- 2020
171. Mathematical Quantification of Transmission in Experiments : FMDV Transmission in Pigs Can Be Blocked by Vaccination and Separation
- Author
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P.L. Eblé, Mart C.M. de Jong, Thomas J. Hagenaars, Herman J W van Roermund, and Aldo Dekker
- Subjects
pig ,disease control ,separation ,040301 veterinary sciences ,Epidemiology ,Bioinformatica & Diermodellen ,Kwantitatieve Veterinaire Epidemiologie ,Virus ,law.invention ,reproduction ratio ,0403 veterinary science ,03 medical and health sciences ,law ,vaccine ,Bio-informatics & Animal models ,foot-and-mouth ,Methods ,Epidemiology, Bio-informatics & Animal models ,030304 developmental biology ,Epidemiologie ,0303 health sciences ,lcsh:Veterinary medicine ,General Veterinary ,Significant difference ,transmission ,Quantitative Veterinary Epidemiology ,04 agricultural and veterinary sciences ,Disease control ,Virology ,Virology & Molecular Biology ,Virologie & Moleculaire Biologie ,Vaccination ,Transmission (mechanics) ,Physical Barrier ,Physical separation ,Epidemiologie, Bioinformatica & Diermodellen ,WIAS ,lcsh:SF600-1100 ,Veterinary Science ,epidemiology - Abstract
Quantitative understanding of transmission with and without control measures is important for the control of infectious diseases because it helps to determine which of these measures (or combinations thereof) will be effective to reduce transmission. In this paper, the statistical methods used to estimate transmission parameters are explained. To show how these methods can be used we reviewed literature for papers describing foot-and-mouth disease virus (FMDV) transmission in pigs and we used the data to estimate transmission parameters. The analysis showed that FMDV transmits very well when pigs have direct contact. Transmission, however, is reduced when a physical barrier separates infected and susceptible non-vaccinated pigs. Vaccination of pigs can prevent infection when virus is administered by a single intradermal virus injection in the bulb of the heel, but it cannot prevent infection when pigs are directly exposed to either non-vaccinated or vaccinated FMDV infected pigs. Physical separation combined with vaccination is observed to block transmission. Vaccination and separation can make a significant difference in the estimated number of new infections per day. Experimental transmission studies show that the combined effect of vaccination and physical separation can significantly reduce transmission (R < 1), which is a very relevant result for the control of between-farm transmission.
- Published
- 2020
172. A critical review on chemical analysis of heavy metal complexes in water/wastewater and the mechanism of treatment methods
- Author
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Qingrui Zhang, Zhe Xu, Xuchun Li, and Xianfeng Huang
- Subjects
General Chemical Engineering ,Treatment method ,Heavy metals ,General Chemistry ,Industrial and Manufacturing Engineering ,Characterization methods ,Wastewater ,Mechanism (philosophy) ,Physical separation ,Genetic algorithm ,Environmental Chemistry ,Environmental science ,Biochemical engineering ,Metal speciation - Abstract
Efficient mitigation of toxic and recalcitrant heavy metal complexes (HMCs) from water and wastewater is critical to guarantee the environmental health and safety, but still faces many challenges. Although a number of techniques have been developed to deal with HMCs laden water/wastewater, there is still a lack of comprehensive and insightful understanding of the relevant mechanisms. One of the main reasons is the complicated heavy metal speciation in water/wastewater, which masks the speciation distribution and coordination circumstance of heavy metals. In this review, prevalent methods for HMC elimination (e.g., physical separation and chemical decomplexation) are briefly presented and evaluated. Especially, the characterization methods of HMCs, which afford to provide valuable information on the speciation distribution of heavy metals, are underlined and discussed. Furthermore, typical cases are provided to elucidate the essential role of species transformation in the decomplexation of HMCs and the implications for enhanced mitigation of HMCs are also discussed. Finally, the current challenges and perspectives for future study in this field are proposed.
- Published
- 2022
173. Detailed Microparticle Analyses Providing Process Relevant Chemical and Microtextural Insights into the Black Mass
- Author
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Mickaël Dadé, Thomas Wallmach, and Odile Laugier
- Subjects
Li-ion battery ,black mass ,geometallurgy ,automated mineralogy ,purification ,digital simulations ,physical separation ,liberation ,recycling ,Geology ,Geotechnical Engineering and Engineering Geology - Abstract
Eramet uses a combination of physical and hydrometallurgical treatment to recycle lithium-ion batteries. Before hydrometallurgical processing, mechanical treatment is applied to recover the Black Mass which contains nickel, cobalt, manganese and lithium as valuable elements as well as graphite, solvent, plastics, aluminium and copper. To evaluate the suitability for hydrometallurgical recycling, it is essential to analyse the Black Mass chemically but also with respect to size, shape and composition of particles in the Black Mass. The Black Mass of various battery recyclers was investigated by using a combination of SEM/QEMSCAN® analyses. This specific QEMSCAN® database contains 260 subgroups, which comprise major and minor chemical variations of phases. The database was created using millions of point analyses. Major observations are: (1) particles can be micro-texturally characterised and classified with respect to chemical element contents; (2) important textural and chemical particle variations exist in the Black Mass from several origins leading to different levels of quality; (3) elements deleterious to hydrometallurgical processing (i.g. Si, Ca, Ti, Al, Cu and others) are present in well liberated particles; (4) components can be quantified and cathodes active material compositions (LCO, different NMC, NCA, LFP, etc.) that are specific for each battery type can be identified; (5) simulation of further physical mineral processing can optimise Black Mass purity in valuable elements.
- Published
- 2022
174. Recent advances in the beneficiation of ultrafine coal particles
- Author
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Changning Wu, Weng Li, Xuetao Bai, Ali Kiani, Guichao Wang, and Ke Liu
- Subjects
Grinding process ,Clean coal ,Economies of agglomeration ,business.industry ,020209 energy ,General Chemical Engineering ,technology, industry, and agriculture ,Energy Engineering and Power Technology ,Beneficiation ,02 engineering and technology ,respiratory system ,Coal particle ,complex mixtures ,respiratory tract diseases ,Fuel Technology ,020401 chemical engineering ,Physical separation ,otorhinolaryngologic diseases ,0202 electrical engineering, electronic engineering, information engineering ,Particle ,Environmental science ,Coal ,0204 chemical engineering ,Process engineering ,business - Abstract
Only when problems in ultrafine coal particle beneficiation process are well understood and clarified, efficient methods can be devised to recover ultrafine coal particles in an economically viable way. When minerals are fully liberated from organic substances in the grinding process, coal beneficiation methods are needed to efficiently separate organic materials from mineral ones. This is necessary for clean coal technologies as the pollutants associated with coal utilization are the key factor in limiting the sustainability of coal utilization. To assess the current state of knowledge available in this area, a comprehensive literature review on the ultrafine coal particle beneficiation techniques is carried out with main focus on recent progresses. In this paper, previous studies on the ultrafine coal beneficiation have been critically analyzed with respect to the effects of particle sizes and surface properties. The techniques are classified into two categories, physical separation (including gravity, magnetic and electrostatic separation method) and physico-chemical separation (including oil agglomeration and bubble flotation method). The aim of this paper is to review developments and limitations of current ultrafine coal particle beneficiation techniques and also to identify the future development in recovering ultrafine coal particles.
- Published
- 2018
175. Use of Space in the Physical Separation of the Bourgeoisie and the Working Class in 'The Exterminating Angel' (1962) and 'The Swamp' (2001)
- Author
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Matthew Berg
- Subjects
geography ,geography.geographical_feature_category ,lcsh:NX1-820 ,media_common.quotation_subject ,Spanish language ,lcsh:Arts in general ,Space (commercial competition) ,Swamp ,gender studies ,Working class ,Aesthetics ,Latin American film ,Physical separation ,Bourgeoisie ,Sociology ,class ,Spanish film ,media_common - Abstract
The struggle between the bourgeoisie and the working class is reflected in the filmography of many countries, including that of Spain and Argentina, specifically through the films El Ángel Exterminador (The Exterminating Angel) (1962), directed by Luis Buñuel, and La Ciénaga (The Swamp) (2001), directed by Lucrecia Martel. Each director utilizes interior and exterior space to demonstrate the difference between the working and bourgeoise classes within their films. As stated by Charles Shiro Tashiro in his observations of The Go-Between, the set design and narrative of cinema are intertwined in such a way that the setting of a film is essential to the successful delivery of the message and context of said film. This comparative study will focus on how Buñuel’s and Martel’s aforementioned films follow a similar pattern in 3 aspects of this use of space: the use of large estates with the mansion in The Exterminating Angel and the La Madrágona house in The Swamp to create a physical barrier that is representative of the metaphorical barrier between socioeconomic classes, the use of interior space to create a sense of entrapment within the confines of the bourgeoisie, and the sense of barrenness created by the grandeur of the bourgeois space.
- Published
- 2018
176. Enacting Expertise: Ritual and Risk in Cybersecurity
- Author
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James Shires
- Subjects
Middle East ,conference ,cybersecurity ,expertise ,performance ,skills gap ,Public Administration ,Sociology and Political Science ,0211 other engineering and technologies ,02 engineering and technology ,Participant observation ,Internationale Beziehungen ,Computer security ,computer.software_genre ,Ideal (ethics) ,Politics ,lcsh:Political science (General) ,Political science ,050602 political science & public administration ,lcsh:JA1-92 ,Risk management ,International relations ,021110 strategic, defence & security studies ,business.industry ,05 social sciences ,International Relations, International Politics, Foreign Affairs, Development Policy ,0506 political science ,Physical separation ,Business intelligence ,Social differences ,internationale Beziehungen, Entwicklungspolitik ,business ,computer ,ddc:327 - Abstract
This article applies the concept of ritual to cybersecurity expertise, beginning with the cybersecurity “skills gap”: the perceived lack of suitably qualified professionals necessary to tackle contemporary cybersecurity challenges. It proposes that cybersecurity expertise is best understood as a skilled performance which satisfies decision-makers’ demands for risk management. This alternative understanding of cybersecurity expertise enables investigation of the types of performance involved in key events which congregate experts together: cybersecurity conferences. The article makes two key claims, which are empirically based on participant observation of cybersecurity conferences in the Middle East. First, that cybersecurity conferences are ritualized activities which create an expert community across international boundaries despite significant political and social differences. Second, that the ritualized physical separation between disinterested knowledge-sharing and commercial advertisement at these conferences enacts an ideal of “pure” cybersecurity expertise rarely encountered elsewhere, without which the claims to knowledge made by cybersecurity experts would be greatly undermined. The approach taken in this article is thus a new direction for cybersecurity research, with significant implications for other areas of international politics.
- Published
- 2018
177. Gas-liquid membrane contactors: Modeling study of non-uniform membrane wetting
- Author
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Seyyed Abbas Mousavi, Ashkan Zolfaghari, Fatemeh Bakhtiari, and Ramin Bozorgmehri Bozarjomehri
- Subjects
Pore size ,geography ,Materials science ,geography.geographical_feature_category ,Filtration and Separation ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Inlet ,01 natural sciences ,Biochemistry ,0104 chemical sciences ,Separation process ,Membrane ,Chemical engineering ,Physical separation ,General Materials Science ,Wetting ,Physical and Theoretical Chemistry ,Current (fluid) ,0210 nano-technology ,Contactor - Abstract
Current available models for simulation of the separation process in gas-liquid membrane contactor (MC) systems consider a uniform partial membrane wetting along the membrane length ( L mem ) . However, transmembrane pressure changes along the L mem . Additionally, the available models usually consider a simplified uniform pore size to represent the micro-porous MC. Additionally, not all pores in a MC have the same size. In this study, a pore-scale network model is developed to simulate the physical separation of H2S using MCs by taking to account for (i) transmembrane pressure variation and (ii) pore size distribution of MC. The model results are compared with the experimental results of H2S separation. Modeling results indicate that membrane wetting is non-uniformly distributed along L mem . The membrane wetting ratio is maximum at the inlet of the liquid phase, and it decreases toward the liquid outlet. Also, increasing the inlet gas pressure reduces the membrane wetting ratio, and leads to higher H2S separation. Moreover, the model results indicate that shifting of the pore size distribution of MC towards smaller pore size declines the membrane wetting ratio and increases the H2S separation efficiency.
- Published
- 2018
178. Pendekatan Antrhopometry Tinggi Penglihatan Mata Sebagai Dasar Ukuran Redesain Median Jalan (Studi Kasus Jalan Diponegoro Simpang Gili Tugel)
- Author
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Ali Mushoffan and Tri Susila Hidayati
- Subjects
Transport engineering ,Computer science ,Physical separation - Abstract
The road median is a physical separation of the traffic lane that serves to eliminate traffic conflictsfrom the opposite direction, which in turn will improve the safety of traffic. road infrastructure factorsthat do not meet safety standards. An example is due to the manufacture of a median road at eachintersection that does not meet such standards as too wide and too high such as in the tegal city ofDiponegoro, this indicates reduced main function of the median road, Antrhopometry is anapproximation of the size of the human body. In this study discusses how to make the mediandesign does not eliminate the main function of traffic separator traffic by using antrhopometry. Thedata used are high-dimensional data of sight and median dimension size, looking forstandardeviation as the lowest value of high vision value to find the right value as a redesignracetrack.
- Published
- 2018
179. Family life before and during incarceration
- Author
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Justin Landwehr, Tasseli McKay, Danielle Steffey, Rose Kelley Feinberg, Christine Lindquist, and Anupa Bir
- Subjects
Divergence (linguistics) ,05 social sciences ,Rehabilitation ,Face (sociological concept) ,Family life ,Physical separation ,050501 criminology ,Child Well-Being ,0501 psychology and cognitive sciences ,Demographic economics ,Convergence (relationship) ,Imprisonment ,Psychology ,Law ,050104 developmental & child psychology ,0505 law - Abstract
It is widely recognized that a father’s incarceration strains a family, but too little is known about preincarceration family life, how families divided by incarceration navigate the imprisonment, and what they expect for postrelease family life. We analyze data from 1,482 incarcerated men and their partners to examine the assets and challenges that families brought with them into the incarceration experience; their considerable efforts to maintain family life during an incarceration in the face of physical separation and other obstacles; and the areas of convergence and divergence in their expectations for family life after the male partner’s release.
- Published
- 2018
180. Advanced Gravity Concentration of Fine Particles: A Review
- Author
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Biswajit Sarkar and Avimanyu Das
- Subjects
Gravity (chemistry) ,business.industry ,Process (engineering) ,Computer science ,Mechanical Engineering ,Density separation ,02 engineering and technology ,General Chemistry ,Geotechnical Engineering and Engineering Geology ,Field (computer science) ,020501 mining & metallurgy ,0205 materials engineering ,Physical separation ,Economic Geology ,Process engineering ,business ,Mineral processing ,Gravity separation - Abstract
The article makes an effort in consolidating the developments in the field of advanced gravity separation techniques for processing fine particles over the last few decades. The application potentials of various unit operations and the influence of process variables and feed characteristics on the process performance are identified. Fundamentals of advanced gravity separators are discussed from theoretical and applied perspectives. Comparative analyses of various related unit operations are incorporated including the advantages and short falls of different advanced gravity separation techniques. A general guideline is presented that will help designing new mineral processing flow sheets with better efficiency indices.
- Published
- 2018
181. Technology-Mediated Relationship Maintenance in Romantic Long-Distance Relationships: An Autoethnographical Research through Design
- Author
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Wei-Chi Chien and Marc Hassenzahl
- Subjects
Human-Computer Interaction ,Physical separation ,05 social sciences ,050109 social psychology ,0501 psychology and cognitive sciences ,Relationship maintenance ,Psychology ,Social psychology ,Romance ,050107 human factors ,Applied Psychology - Abstract
Many routine relationship maintenance activities, such as supporting each other in the household, rely on responsive interaction. Unfortunately, the physical separation typical for long-distance re...
- Published
- 2017
182. Enhancing the reactivity of aluminosilicate materials toward geopolymer synthesis
- Author
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Stephen O. Ekolu and L.N. Tchadjié
- Subjects
Materials science ,Mechanical Engineering ,0211 other engineering and technologies ,02 engineering and technology ,Treatment parameters ,021001 nanoscience & nanotechnology ,law.invention ,Geopolymer ,Portland cement ,Chemical engineering ,Mechanics of Materials ,Aluminosilicate ,law ,Physical separation ,021105 building & construction ,General Materials Science ,Reactivity (chemistry) ,Activation method ,0210 nano-technology ,Alkaline activation - Abstract
Geopolymers are alternative materials to portland cement, obtained by alkaline activation of aluminosilicates. They exhibit excellent properties and a wide range of potential applications in the field of civil engineering. Several natural aluminosilicates and industrial by-products can be used for geopolymer synthesis, but a lot of starting materials have the disadvantage of poor reactivity and low strength development. This paper presents a comprehensive review of the main methods used to alter the reactivity of aluminosilicate materials for geopolymer synthesis, as reported recently in the literature. The methods consist of mechanical, thermal, physical separation and chemical activation, of which mechanical activation is the most commonly employed technique. The reactivity of the activated aluminosilicate materials is mainly related to the activation method and the treatment parameters. Chemical activation by alkaline fusion is a promising method allowing preparation of one-part geopolymer materials, an alternative class of geopolymeric binders. However, the resulting alkaline-fused geopolymer products are vulnerable to attack by excessive alkalis.
- Published
- 2017
183. Optimal Thermal Treatment for Effective Copper Recovery in Waste Printed Circuit Boards by Physical Separation: Influence of Temperature and Gas
- Author
-
Yosep Han, Chul-Hyun Park, Minuk Jung, Seongmin Kim, Seungsoo Park, Boram Kim, Dae-Weon Kim, Ho-Seok Jeon, and Seongsoo Han
- Subjects
Materials science ,heat treatment ,physical separation ,Glass fiber ,Thermal decomposition ,chemistry.chemical_element ,Geology ,Fraction (chemistry) ,Epoxy ,Thermal treatment ,liberation ,Mineralogy ,Geotechnical Engineering and Engineering Geology ,Copper ,Degree (temperature) ,Printed circuit board ,chemistry ,Cu recovery ,visual_art ,visual_art.visual_art_medium ,printed circuit boards ,Composite material ,strength ,QE351-399.2 - Abstract
Printed circuit boards (PCBs) are difficult to recycle because of the layered structure of non-metal (i.e., epoxy resin, glass fiber) and copper. In this work, we conducted a systematic investigation to effectively recover copper from PCB. A thermal treatment was employed for improving the crushing performance of PCB and conducted by varying the temperature and the gas. Then, the mechanical strength, degree of liberation (DL), and copper separation efficiency of the heat-treated and untreated PCBs were investigated. After heat treatment under a 300 °C air atmosphere, the mechanical strength of PCB decreased from 386.36 to 24.26 MPa, and copper liberation improved from 9.3% to 100% in the size range of a coarser size fraction (>, 1400 μm). Accordingly, when electrostatic separations were performed under these conditions, a high-Cu-grade concentrate and high recovery could be obtained. The results show that the change in the physical properties of the PCBs leads to an improvement in the DL following thermal decomposition at 300 °C in air. Our study elucidates the physical properties of PCBs and the DL under various heat treatment conditions. Furthermore, it shows that the heat treatment condition of 300 °C in air is ideal for recovering copper from the PCB.
- Published
- 2021
184. Effects of abiotic components induced by biochar on microbial communities.
- Author
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Sun, Daquan, Meng, Jun, and Chen, Wenfu
- Subjects
- *
BIOCHAR , *SOIL microbiology , *SOIL ecology , *GEL electrophoresis , *SOIL sampling , *COMMUNITY organization , *BIOMASS - Abstract
Soil microorganisms play an important role on ecosystems and are influenced by a variety of abiotic and biotic variables. The influence of biochar on the microbial community has been reported, but its mechanism modifying soil microbial distribution is less understood. In this paper, biochar was physically separated from soil, and the abiotic characteristics generally recognised influencing soil microbial communities were examined. The microbial community structure was assessed via denaturing gradient gel electrophoresis (DGGE). The influence of abiotic components including available N, Olsen P and extractable K, pH and C/N induced by biochar on soil microbial communities was compared by canonical correspondence analysis (CCA). Results indicated that biochar fostered more fungi and stimulated bacteria growth in the adjacent soil. Biochar particles at three sampling times exhibited the similar microbial community composition, although it was also impacted by temporal factors. Phylogenetic distributions of the operational taxonomic units (OTUs) could be divided into the following eight groups: Bacillaceae, Gemmatinomadetes, Sphingomanas, Acidobacteria, Proteobacteria, Chloroflexaceae, Actibacteria (similarity > 95%) and unknown (similarity < 85%). CCA revealed the great contribution of C/N, Olsen P and extractable K to fungi growth, and C/N and Olsen P to actinomycete abundance. The presence of biochar not only induced increase of available nutrients but also increased microbial biomass and diversity, which indicated beneficial effects on soil microorganisms and soil fertility. [ABSTRACT FROM PUBLISHER]
- Published
- 2013
- Full Text
- View/download PDF
185. Physical analysis and modeling of the Falcon concentrator for beneficiation of ultrafine particles.
- Author
-
Kroll-Rabotin, Jean-Sébastien, Bourgeois, Florent, and Climent, Éric
- Subjects
- *
FALCONS , *ORE-dressing , *PARTICLE physics , *EMPIRICAL research , *DATA analysis , *SUSPENSIONS (Chemistry) - Abstract
Abstract: A predictive model of the Falcon enhanced gravity separator has been derived from a physical analysis of its separation principle, and validated against experimental data. After summarizing the previous works that led to this model and the hypotheses on which they rely, the model is extended to cover a wide range of operating conditions and particle properties. The most significant development presented here is the extension of the analytical law to concentrated suspensions, which makes it applicable to actual plant operating conditions. Two examples of industrial use cases are described and studied by interrogation of the model: dredged sediment waste reduction and coal recovery from fine tailings. Comparisons with empirical studies available in the literature show a good agreement between model predictions and industrial data. The model is then used to identify separation efficiency limitations as well as possible solutions to overcome them. These two examples serve to show how this predictive model can be used to obtain valuable information to improve physical separation processes using a Falcon concentrator, or to evaluate Falcon separator's abilities for new applications. [Copyright &y& Elsevier]
- Published
- 2013
- Full Text
- View/download PDF
186. Recycling of municipal solid waste incinerator fly ash by using hydrocyclone separation
- Author
-
Ko, Ming-Sheng, Chen, Ying-Liang, and Wei, Pei-Shou
- Subjects
- *
MUNICIPAL solid waste incinerator residues , *WASTE recycling , *WASTE management , *MACHINE separators , *SEPARATION (Technology) , *CALCIUM compounds , *HEAVY metals - Abstract
Abstract: The municipal solid waste incinerators (MSWIs) in Taiwan generate about 300,000 tons of fly ash annually, which is mainly composed of calcium and silicon compounds, and has the potential for recycling. However, some heavy metals are present in the MSWI fly ash, and before recycling, they need to be removed or reduced to make the fly ash non-hazardous. Accordingly, the purpose of this study was to use a hydrocyclone for the separation of the components of the MSWI fly ash in order to obtain the recyclable portion. The results show that chloride salts can be removed from the fly ash during the hydrocyclone separation process. The presence of a dense medium (quartz sand in this study) is not only helpful for the removal of the salts, but also for the separation of the fly ash particles. After the dense-medium hydrocyclone separation process, heavy metals including Pb and Zn were concentrated in the fine particles so that the rest of the fly ash contained less heavy metal and became both non-hazardous and recyclable. [Copyright &y& Elsevier]
- Published
- 2013
- Full Text
- View/download PDF
187. Advanced Separation Techniques for Industrial Effluents.
- Author
-
Kothari, D.C., Renge, V.C., Padma, B., Rao, S., Raidas, Rahul, and Pitt, M.J.
- Subjects
- *
INDUSTRIAL waste purification , *EXTRACTION techniques , *FERMENTATION , *BIOCHEMISTRY , *ELECTRIC contactors - Abstract
Continuous stirrer tank mixer–settlers are still widely used in the treatment of industrial effulents and in the bio-chemical process industry for operations that require high capacity and for stages such as fermentation. The obvious disadvantages of mixing and settling are the capital cost, space requirement and the inventory of material held up in the equipment. An economic design for a contactor would produce the most efficient contact combined with rapid and complete separation of the two phases in the smallest possible volume and time. There are a number of alternatives to the mixer–settler, of which the gullwing separator appears particularly promising owing to its simplicity, compact nature and energy efficiency. The gullwing contactor separator is a novel design of equipment that works by turbulent jet contact, combined with instantaneous hydro-cyclone separation for extraction of solute from one solvent to another where the two solvents are immiscible and have a density difference. The fundamental reason why the mass transfer coefficient is increased in the gullwing contactor separator is the high relative velocity between the two phases, which reduces interfacial film resistance. A modified design of a batch as well as a two-stages continuous contactor has been successfully developed and optimized for a test system. To carry out separation in a jet contactor separator, continuous contact of tetrachloroethylene (TCE)+5% Ethyl Acetate (EA) and water is achieved with the help of a recirculation pump. This recirculation pump produces a high velocity of light phase (water), which moves through 20 turbulent jets. When the high velocity streams come into contact with a stagnant pool of droplets forming the dispersed phase (TCE), mass transfer occurs. The heavy phase (TCE+5% EA) is broken into discrete droplets and EA is entrained in the light phase (water), resulting in forced diffusion and extraction. Simultaneously, the separation of heavy and light phase takes place as the TCE coalesces under the wings, rotates circumferentially and returns to the bottom of the contactor. The centrifugal force expected to be developed in the gullwing was calculated. It was observed that, using a 65 mm gullwing with 10 mm extra, 20×4 mm jets per stage, 40 mm heavy phase pool depth and injecting light phase at 2 m/s, a centrifugal force three times greater than gravity was obtained. Total escape axial and radial velocities of the light phase in the gullwing were also evaluated. It was also observed that the total escape, that is, the combination of radial and axial escape, affects the overall separation of two phases in the two-stage counter-current gullwing contactor separator. The stage arrangement is compact. The design is also potentially capital cost-effective as extraction and separation are carried out in the same vessel. Since any number of stages can be accommodated in the same vessel, the extractor/separator can be tailored to a great variety of extraction processes. (It may be considered to be similar to a horizontal extraction column with phases in counter flow.) Extraction and separation are achieved without moving parts in the main contacting vessel. The moving parts that are associated with the centrifugal pumps would be useful for the separation of industrial effluents. [ABSTRACT FROM AUTHOR]
- Published
- 2012
- Full Text
- View/download PDF
188. Feasibility of gravity and magnetic separation for Yxsjöberg historical tungsten ore tailings
- Author
-
Mulenshi, Jane, Khavari, Pourya, Chelgani, Saeed Chehreh, Rosenkranz, Jan, Mulenshi, Jane, Khavari, Pourya, Chelgani, Saeed Chehreh, and Rosenkranz, Jan
- Abstract
Repositories of historical tailings (HT) pose environmental risks but could also become new resources for valuable metals. This is because relatively high minerals and metals content characterize them due to less efficient extraction methods and/or relatively low metal prices at the time. In this investigation, geometallurgical studies were conducted by collecting drill core samples (DCS) from the Smaltjärnen tailings repository in Yxsjöberg, Sweden. The collected DCS were from the main layers of the longest drill core, and were characterized physically (color, texture, moisture content and particle size distribution) and chemically (elemental composition and distribution, and mineralogical composition). The characterization of DCS indicated that the tailings mass distribution was high in the coarser particle size fraction of +149 μm. Tungsten (W) and Copper (Cu) were the metals of interest with highest concentrations being 0.22 %WO3 and 0.11 %Cu. Feasible physical separation methods selected were Knelson concentrator, LIMS and HIMS, based on the knowledge from literature, tailings characteristics, and assessment of processes from which the Yxsjöberg HT were produced. Using the Knelson concentrator, the recovery of scheelite, which is the main W mineral, was enhanced, with 75 wt.% tungsten recovered in the 34 wt.% of concentrate produced. In magnetic separation, sulphur (S) was mostly recovered in the ferromagnetic and paramagnetic fractions with only 1.0 wt.% in the non-magnetic fraction, meaning pyrrhotite, the main Fe-sulphide mineral in the HT responsible for AMD, was separated to the desired magnetic fractions of the LIMS and HIMS. These results are fundamental in the development of methods for separation of valuable minerals from these HT in order to produce an inert and environmentally safe residue., REMinE (Improve Resource Efficiency and Minimize Environmental Footprint)
- Published
- 2019
189. Disassembly and physical separation of electric/electronic components layered in printed circuit boards (PCB)
- Author
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Lee, Jaeryeong, Kim, Youngjin, and Lee, Jae-chun
- Subjects
- *
ELECTRIC circuits , *ELECTRONIC equipment , *PRINTED circuits , *PRECIOUS metals , *WASTE recycling , *MAGNETIC separation , *MOLECULAR sieves - Abstract
Abstract: Although printed circuit boards (PCBs) contain various elements, only the major elements (i.e., those with content levels in wt% or over grade) of and precious metals (e.g., Ag, Au, and platinum groups) contained within PCBs can be recycled. To recover other elements from PCBs, the PCBs should be properly disassembled as the first step of the recycling process. The recovery of these other elements would be beneficial for efforts to conserve scarce resources, reuse electric/electronic components (EECs), and eliminate environmental problems. This paper examines the disassembly of EECs from wasted PCBs (WPCBs) and the physical separation of these EECs using a self-designed disassembling apparatus and a 3-step separation process of sieving, magnetic separation, and dense medium separation. The disassembling efficiencies were evaluated by using the ratio of grinding area (E area) and the weight ratio of the detached EECs (E weight). In the disassembly treatment, these efficiencies were improved with an increase of grinder speed and grinder height. 97.7% (E area) and 98% (E weight) could be accomplished ultimately by 3 repetitive treatments at a grinder speed of 5500rpm and a grinder height of 1.5mm. Through a series of physical separations, most groups of the EECs (except for the diode, transistor, and IC chip groups) could be sorted at a relatively high separation efficiency of about 75% or more. To evaluate the separation efficiency with regard to the elemental composition, the distribution ratio (R dis) and the concentration ratio (R conc) were used. 15 elements could be separated with the highest R dis and R conc in the same separated division. This result implies that the recyclability of the elements is highly feasible, even though the initial content in EECs is lower than several tens of mg/kg. [Copyright &y& Elsevier]
- Published
- 2012
- Full Text
- View/download PDF
190. Cleaning of marine sediment samples for large diatom stable isotope analysis.
- Author
-
Xiong, Zhifang, Li, Tiegang, and Crosta, Xavier
- Subjects
- *
DIATOMS , *MARINE sediments , *OCEAN bottom , *SEDIMENTS , *OCEANOGRAPHY - Abstract
Diatom stable isotope analysis offers considerable potential in palaeoceanography, particularly where carbonate material is scarce or absent. However, extracting pure diatom frustules free of external labile organic matter from marine sediments is an essential requirement for their applications as paleoenvironmental proxies. Here, based largely on previous work, we developed a method including physical separation and chemical oxidation steps to concentrate and clean pure large diatoms from laminated diatom mat and diatomaceous clay sediment samples for their stable isotope analysis. Using the physical separation techniques consisting of the removal of carbonate and excess organic matter, sieving, differential settling, and heavy liquid floatation, pure diatoms can be successfully isolated from the sediment samples with opal concentration more than 10%. Subsequent time oxidation experiment shows that labile organic matter coating pure diatom valves can be effectively removed with 30% HO at 65 °C for 2 h. Measurements of δC after every step of physical separation demonstrate that contaminants and lost diatoms can influence the original diatom stable isotope signal, highlighting the importance of a visual check for dominant diatom size in the initial sample and purity in the final sample. Although the protocol described here was only applied to diatom mats or diatom oozes containing large diatoms ( Ethmodiscus rex), we believe that this method can be adapted to common diatoms of general marine sediment samples. [ABSTRACT FROM AUTHOR]
- Published
- 2012
- Full Text
- View/download PDF
191. Liberation characteristic and physical separation of printed circuit board (PCB)
- Author
-
Guo, Chao, Wang, Hui, Liang, Wei, Fu, Jiangang, and Yi, Xin
- Subjects
- *
PRINTED circuits , *METAL recycling , *WASTE treatment , *INDUCTIVELY coupled plasma atomic emission spectrometry , *PNEUMATICS , *ELECTROSTATIC separation , *MAGNETIC separation - Abstract
Abstract: Recycling of printed circuit board (PCB) is an important subject and to which increasing attention is paid, both in treatment of waste as well as recovery of valuable material terms. Precede physical and mechanical method, a good liberation is the premise to further separation. In this study, two-step crushing process is employed, and standard sieve is applied to screen crushed material to different size fractions, moreover, the liberation situation and particles shape in different size are observed. Then metal of the PCB is separated by physical methods, including pneumatic separation, electrostatic separation and magnetic separation, and major metal contents are characterized by inductively coupled plasma emission spectrometry (ICP-AES). Results show that the metal and nonmetal particles of PCB are dissociated completely under the crush size 0.6mm; metal is mainly enriched in the four size fractions between 0.15 and 1.25mm; relatively, pneumatic separation is suitable for 0.6–0.9mm size fraction, while the electrostatic separation is suitable for three size fractions that are 0.15–0.3mm, 0.3–0.6mm and 0.9–1.25mm. The whole process that involves crushing, electrostatic and magnetic separation has formed a closed cycle that can return material and provide salable product. [Copyright &y& Elsevier]
- Published
- 2011
- Full Text
- View/download PDF
192. Ability of whey protein isolate and/or fish gelatin to inhibit physical separation and lipid oxidation in fish oil-in-water beverage emulsion
- Author
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Taherian, Ali R., Britten, Michel, Sabik, Hassan, and Fustier, Patrick
- Subjects
- *
PROTEINS , *GELATIN , *WHEY , *FISH oils , *EMULSIONS , *RHEOLOGY , *LIPIDS , *OXIDATION - Abstract
Abstract: The effect of pH on the capability of whey protein isolate (WPI) and fish gelatin (FG), alone and in conjugation, to form and stabilize fish oil-in-water emulsions was examined. Using layer-by-layer interfacial deposition technique for WPI–FG conjugate, a total of 1% protein was used to prepare 10% fish oil emulsions. The droplets size distributions and electrical charge, surface protein concentration, flow and dynamic rheological properties and physiochemical stability of emulsions were characterize at two different pH of 3.4 and 6.8 which were selected based on the ranges of citrus and milk beverages pHs, respectively. Emulsions prepared with WPI–FG conjugate had superior physiochemical stability compare to the emulsions prepared with individual proteins. Higher rate of coalescence was associated with reduction in net charge and consequent decrease of the repulsion between coated oil droplets due to the proximity of pH to the isoelectric point of proteins. The noteworthy shear thinning viscosity, as an indication of flocculation onset, was associated with whey protein stabilized fish oil emulsion prepared at pH of 3.4 and gelatin stabilized fish oil emulsion made at pH of 6.8. At pH 3.4, it appeared that lower surface charge and higher surface area of WPI stabilized emulsions promoted lipid oxidation and production of hexanal. [Copyright &y& Elsevier]
- Published
- 2011
- Full Text
- View/download PDF
193. Versatile label free biochip for the detection of circulating tumor cells from peripheral blood in cancer patients
- Author
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Tan, Swee Jin, Lakshmi, Rumkumar Lalitha, Chen, Pengfei, Lim, Wan-Teck, Yobas, Levent, and Lim, Chwee Teck
- Subjects
- *
BIOCHIPS , *CANCER cells , *CELLULAR mechanics , *MICROFLUIDICS , *BLOOD cells , *IMMUNOFLUORESCENCE - Abstract
Abstract: The isolation of circulating tumor cells (CTCs) using microfluidics is attractive as the flow conditions can be accurately manipulated to achieve an efficient separation. CTCs are rare events within the peripheral blood of metastatic cancer patients which makes them hard to detect. The presence of CTCs is likely to indicate the severity of the disease and increasing evidences show its use for prognostic and treatment monitoring purposes. We demonstrated an effective separation using a microfluidic device to utilize the unique differences in size and deformability of cancer cells to blood cells. Using physical structures placed in the path of blood specimens in a microchannel, CTCs which are generally larger and stiffer are retained while most blood constituents are removed. The placements of the structures are optimized by computational analysis to enhance the isolation efficiency. With blood specimens from metastatic lung cancer patients, we confirmed the successful detection of CTCs. The operations for processing blood are straightforward and permit multiplexing of the microdevices to concurrently work with different samples. The microfluidic device is optically transparent which makes it simple to be integrated to existing laboratory microscopes and immunofluorescence staining can be done in situ to distinguish cancer cells from hematopoietic cells. This also minimizes the use of expensive staining reagents, given the small size of the microdevice. Identification of CTCs will aid in the detection of malignancy and disease stage as well as understanding the phenotypic and genotypic expressions of cancer cells. [ABSTRACT FROM AUTHOR]
- Published
- 2010
- Full Text
- View/download PDF
194. Effects of soil erosion and deposition on soil organic carbon dynamics at a sloping field in Black Soil region, Northeast China.
- Author
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Shulan CHENG, Huajun FANG, Tianhong ZHU, Jiaojiao ZHENG, Xueming YANG, Xiaoping ZHANG, and Guirui YU
- Subjects
SOIL erosion ,HUMUS ,CARBON ,SOIL corrosion - Abstract
Soil erosion transports light density and fine particle soil material from hills down to low-lying land areas, which can lead to carbon loss and subsequent sequestration. In the present paper, the profile distribution of soil organic carbon (SOC) and soil
13 C natural abundance (δ13 C) were analyzed across five geomorphic positions, distributed along a typical rolling farmland in the Black Soil region of Northeast China. The contents of particulate organic carbon (POC) and mineral-associated organic carbon (MOC) at each geomorphic position were measured with physical fraction method. The results showed that soil erosion decreased 5.3–22.4% of SOC and increased 4.0–6.1% of δ13 C of surface soils at the eroding sites. At the typical depositional sites, SOC content and δ13 C value in the buried surface layer were 1.5 times and 1.1 times as much as those of the current plough layer, respectively. Soil erosion did not change the POC content, but MOC content decreased by 9.3–35.2%. At the eroding sites, the coefficient of determination between soil δ13 C and MOC ( R2 = 0.52) was higher than that between soil δ13 C and POC ( R2 = 0.37). Our study indicated that soil erosion decreased SOC content and increased δ13 CSOC in surface layer mainly through transferring fine sized and13 C-depleted SOC fraction. Deep burial and re-aggregation of eroded materials at depositional sites were in favor of stabilization and sequestration of SOC. [ABSTRACT FROM AUTHOR]- Published
- 2010
- Full Text
- View/download PDF
195. A Contribution of the Analysis of the Road Macrotexture and Microtexture Roles vis-à-vis Skid Resistance
- Author
-
Malal Kane
- Subjects
Algebraic relations ,Resistance (ecology) ,Skid (automobile) ,Mechanics of Materials ,Mechanical Engineering ,Physical separation ,Road texture ,General Materials Science ,Dynamical friction ,Geotechnical engineering ,Operating speed ,Texture (geology) ,Mathematics - Abstract
Skid resistance of roads enables drivers to shorten their stopping distances and to follow their desired trajectories on curves, too. The road texture remains the principal parameter governing skid resistance, especially in wet conditions. That texture is composed of a multitude of wavelengths with the microtexture and macrotexture considered to be the most important vis-a-vis to skid resistance. The present work contributes to the numerous analyses of the role of these two texture scales, as many authors have done before. It is based on the physical separation of these two scales of textures using an empirical mode decomposition and systematic identification of their roles on skid resistance using a dynamic friction model. The results found in this present work consolidate well the findings of previous works. Indeed, they show that the higher the microtexture is, the better the skid resistance will be at low speeds. Furthermore, the higher macrotexture is, the better the skid resistance is at high speed. These results have led to the proposal of algebraic relations linking skid resistance to microtexture and macrotexture at all speeds, constituting then a clear step forward compared to previous works.
- Published
- 2021
196. Indices De Minéralisations En Or Dans La Province Panafricaine Du Sud Maradi (Sud Niger)
- Author
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Souley Baraou Idi, Abdoulwahid Sani, Yacouba Ahmed, and Moussa Konaté
- Subjects
Socle ,Craton ,geography ,West african ,geography.geographical_feature_category ,Basement (geology) ,Physical separation ,Geochemistry ,Alluvium ,Gold mineralization ,Geology - Abstract
Le socle du Sud Maradi (Sud Niger) correspond à l’extrémité Nord du bouclier Bénino-Nigérian, appartenant à la zone mobile panafricaine à l’Est du Craton Ouest-Africain. Cette étude apporte une modeste contribution dans la caractérisation géochimique des minéralisations aurifères de cette province métallogénique panafricaine. A cet effet, l’approche méthodologique mise en oeuvre associe le dosage géochimique de l’or par absorption atomique (Au Fire Assay/AA) pour les roches saines, et la séparation des pépites d’or par l’utilisation de la table à secousse pour les altérites du socle et les sédiments (placers et paléoplacers). Les analyses géochimiques ont mis en évidence l’existence de deux types de minéralisations: primaires et secondaires. Les minéralisations primaires de l’or sont à l’état disséminé (faibles teneurs de 0.005 à 0.017 g/t) mais des teneurs relativement plus élevées (0.006 à 0.017 g/t) ont été enregistrées au voisinage des zones de cisaillement du socle. Tandis que la minéralisation secondaire, mise en évidence dans les altérites du socle, dans les alluvions (placers) et dans les grès du Crétacé (paléoplacers) présentent des teneurs en or plus élevées (5 à 30 g/t), dépassant largement les teneurs des minéralisations primaires observées dans les roches saines du socle. Ce grand écart de teneurs s’explique par un fort lessivage du socle, qui aurait permis une reconcentration de l’or dans les sédiments. The South Maradi (South Niger) basement corresponds to the northeastern part of the Benin-Nigerian Shield, belonging to the Pan-African mobile zone, which is located to the east of the West African Craton. This study brings a modest contribution to the geochemical characterization of gold mineralization in this Pan-African metallogenic province. For this purpose, the methodological approach implemented combines the geochemical determination of gold contents by atomic absorption (Au Fire Assay/AA) for basement rocks and physical separation of gold specks by using the vibrating table process for basement alterites and sediments (placers and paleoplacers). The obtained results showed two types of gold mineralization: primary and secondary. Primary gold mineralization is in a disseminated state (low contents of 0.005 to 0.017 g / t) but relatively the higher values (0.006 to 0.017 g / t) were recorded near the basement shear zones. While the secondary gold mineralization, highlighted in basement alterites, alluvium (placers) and Cretaceous sandstones (paleoplacers) present higher gold contents (5 to 30 g / t) than primary gold contents observed in basement rocks. This large difference in values can be explained by a strong alteration of the basement, which would have allowed a reconcentration of the gold in the sediments.
- Published
- 2021
197. Microdevice for the isolation and enumeration of cancer cells from blood.
- Author
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Tan, Swee, Yobas, Levent, Lee, Gabriel, Ong, Choon, and Lim, Chwee
- Abstract
Cancer metastasis is the main attribute to cancer-related deaths. Furthermore, clinical reports have shown a strong correlation between the disease development and number of circulating tumor cells (CTCs) in the peripheral blood of cancer patients. Here, we present a label-free microdevice capable of isolating cancer cells from whole blood via their distinctively different physical properties such as deformability and size. The isolation efficiency is at least 80% for tests performed on breast and colon cancer cells. Viable isolated cells are also obtained which may give further insights to the understanding of the metastatic process. Contrasting with conventional biochemical techniques, the uniqueness of this microdevice lies in the mechanistic and efficient means of isolating viable cancer cells in blood. The microdevice has the potential to be used for routine monitoring of cancer development and cancer therapy in a clinical setting. [ABSTRACT FROM AUTHOR]
- Published
- 2009
- Full Text
- View/download PDF
198. Detailed Microparticle Analyses Providing Process Relevant Chemical and Microtextural Insights into the Black Mass.
- Author
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Dadé, Mickaël, Wallmach, Thomas, and Laugier, Odile
- Subjects
- *
CHEMICAL processes , *CHEMICAL elements , *LITHIUM-ion batteries , *MINERAL processing , *DIGITAL computer simulation , *MANGANESE - Abstract
Eramet uses a combination of physical and hydrometallurgical treatment to recycle lithium-ion batteries. Before hydrometallurgical processing, mechanical treatment is applied to recover the Black Mass which contains nickel, cobalt, manganese and lithium as valuable elements as well as graphite, solvent, plastics, aluminium and copper. To evaluate the suitability for hydrometallurgical recycling, it is essential to analyse the Black Mass chemically but also with respect to size, shape and composition of particles in the Black Mass. The Black Mass of various battery recyclers was investigated by using a combination of SEM/QEMSCAN® analyses. This specific QEMSCAN® database contains 260 subgroups, which comprise major and minor chemical variations of phases. The database was created using millions of point analyses. Major observations are: (1) particles can be micro-texturally characterised and classified with respect to chemical element contents; (2) important textural and chemical particle variations exist in the Black Mass from several origins leading to different levels of quality; (3) elements deleterious to hydrometallurgical processing (i.g. Si, Ca, Ti, Al, Cu and others) are present in well liberated particles; (4) components can be quantified and cathodes active material compositions (LCO, different NMC, NCA, LFP, etc.) that are specific for each battery type can be identified; (5) simulation of further physical mineral processing can optimise Black Mass purity in valuable elements. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
199. Soil washing for the remediation of dioxin-contaminated soil: A review.
- Author
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Tran, Huu Tuan, Lin, Chitsan, Hoang, Hong Giang, Bui, Xuan Thanh, Le, Van Giang, and Vu, Chi Thanh
- Subjects
- *
SOIL washing , *SOIL remediation , *SOIL pollution , *VOLATILE organic compounds , *FLOTATION - Abstract
Dioxin-contaminated soil has attracted worldwide attention due to its potential negative impacts on human health and the ecosystem. Thus, technological development aiming at high treatment efficiency and low cost for dioxin-contaminated soil is largely needed. In this review, approximately 200 documents were involved to summarize up-to-date scientific achievements of soil washing technology for the remediation of dioxin-contaminated soil. The mechanisms, advantages, and limitations of physical separation techniques (e.g. mechanical stirring, mechanical shaking, ultrasonication, and froth flotation) and washing solutions (e.g. organic solvents, edible oils, and surfactants) used for chemical extraction were comprehensively reviewed. Froth flotation is very promising for field-scale soil washing, whereas organic solvents show high removal efficiencies (up to 99%) of dioxins from contaminated soil. Further, the combination of physical separation and chemical extraction can help enhance dioxin removal efficiency (from 1.5 to 2 times), reducing energy consumption and cost (about 2 times). Among available remediation technologies for dioxin-contaminated soil, soil washing is truly promising since it has shown high removal efficiency (66–99% different remediation scales) with reasonable cost (46 – 250 USD per metric ton). However, the washed solution and volatile organic compounds generated during the process remain a concern and should be addressed in future research. [Display omitted] • Dioxin concentrations of contaminated soil are often higher than regulatory limits. • Soil washing is a promising remediation technology for dioxin-contaminated soil. • Combining physical separation and chemical extraction enhances removal efficiency. • The treatment of washed solutions requires future research. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
200. Physical Separation of Contaminated Soil Using a Washing Ejector Based on Hydrodynamic Cavitation.
- Author
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Cho, Kanghee, Kim, Hyunsoo, Purev, Oyunbileg, Choi, Nagchoul, and Lee, Jaewon
- Abstract
A washing ejector is a pre-treatment technology used to remediate contaminated soil by separating fine particles. The washing ejector developed in this study is a device that utilizes fast liquid jets to disperse soil aggregates by cavitation flow. The cavitation phenomenon is affected by the Bernoulli principle, and the liquid pressure decreases with the increase in kinetic energy. The cavitating flow of the fluid through the Ventrui nozzle can remove surface functional groups and discrete particles. The main methodology involves the removal of small particles bound to coarse particles and the dispersion of soil aggregates. Particle collisions occur on the surface soil, such as the metal phase that is weakly bound to silicate minerals. It was observed that the dispersed soil affected the binding of toxic heavy metals and the mineralogical characteristics of the soil. The quantity of oxides, organic matter, and clay minerals affected the properties of the soil. An almost 40–60% removal efficiency of total metals (As, Zn, and Pb) was obtained from the contaminated soils. After treatment by a washing ejector, the volume of fine particles was reduced by 28–47%. When the contaminants are associated with particulates, separation using a washing ejector can be more effective. Therefore, physical separation improves the removal efficiency of heavy metals from soil aggregates. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
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