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Understanding the electrical transport in carbon nanotube (CNT) materials is one key to reach very high electrical conductivities. All CNT material resistivity (ρ (T)) as function of the temperature are fully apprehended by their reduced activation W (T) = d ln (ρ) d ln (T) curves. Up to now, no model accurately fits W(T) curves, thus preventing from precisely describing the CNT material electrical transport. We present a new electrical transport model that perfectly fits all W(T) curves found in the literature and in our own data. CNT material resistivities are modeled by ρ(T)= ρ0(T−α + M(1 + βTγT2)). Our model has few enough parameters (α, M, β, γ) to relate them to the CNT physics. Below 70 K, we experimentally show that CNT material resistivity follows the Luttinger Liquid theory justifying the T−α term in our model. Above 70 K, the polynomial part becomes dominant and depends on the two different CNT fabrication techniques which lead to two very different yarn structures. For yarns made from floating catalyst chemical vapor deposition CNTs, the polynomial is explained by the percolation of metallic CNT walls. Whereas, the polynomial of yarns spun from CNT arrays is explained by the electrical transport in CNT bundles which are the basic building blocks of this type of yarns. [ABSTRACT FROM AUTHOR]

The synthesized ternary composite Co3O4/polyaniline/graphene delivered high capacitance of ~ 476 F g−1 at a current density of 2 A g−1, within the voltage window from − 0.8 to 0.8 V in three-electrode configuration. The symmetric device, fabricated using the composite material returned specific capacitance of ~ 37 F g−1 at a current density of 0.5 A g−1. Further, the effect of redox additive KI in electrolyte 1 M Na2SO4 was investigated in symmetric device configuration. The optimum results were obtained when 75 mmol KI was added with 1 M Na2SO4 electrolyte and capacitance increased more than two times, compared to the case while no redox additive was added in electrolyte and the maximum capacitance was found to be ~ 94 F g−1, at a current density 1 A g−1. [ABSTRACT FROM AUTHOR]

The nanostructure materials are a prefer option to the high-growth technological changes. The remarkable nanotubes and other carbon nanostructure properties have been theoretically and experimentally tested. These nanostructures can be used as reinforcement materials in composites; the research main challenge is the dispersion of these carbon materials in different matrices caused by cluster formations produced by the intermolecular forces. The aim of this research was the synthesis and characterization of a composite material from carbon nanotubes and styrene oligomers with hydroxyl end groups; and the analysis of their dispersion and mechanical and electrical properties. Pristine and functionalized carbon nanotubes and polystyrene with hydroxyl end groups were synthesized; furthermore, magnetic field was applied to the composites to promote dispersion of carbon nanotubes. The materials were characterized by scanning electron microscopy, FTIR and Raman spectroscopy. The Raman spectroscopy has demonstrated interaction between carbon nanostructures and polymers; this changes their mechanical and electrical properties. The composites formed with functionalized carbon nanotubes (1.6 wt%) have the highest hardness value (91.16 HV), five times over the pristine polymer. As carbon nanostructure concentration increases, the composite acquires conductivity and the electron transport is promoted. The values obtained in the composites qualify them as electromagnetic interference shields, those demand materials with higher electrical conductivity than conventional polystyrene. [ABSTRACT FROM AUTHOR]

Purpose: To critically report outcomes from a contemporary series of patients undergoing single-stage Asopa dorsal inlay urethroplasty for penile stricture. Methods: First, we retrospectively evaluated patients who underwent Asopa urethroplasty for penile stricture between 2009 and 2016 at our department. Clinical and surgical characteristics were compared across treatment groups (proximal penile, mid-penile, distal penile). Recurrence-free survival was plotted using Kaplan–Meier curves. Treatment satisfaction was assessed using a validated outcome measurement tool. Second, a literature review was performed through Medline to summarize the available evidence on Asopa urethroplasty and put our own results into context. Results: Of 125 patients, 38 (30%), 74 (59%), and 13 (10%) had distal penile, mid-penile, and proximal penile stricture, respectively. Patients with distal strictures were younger and graft length was shorter compared to other groups (P ≤ 0.009). The majority of strictures were iatrogenic (38%), followed by hypospadias related (24%), congenital (17%), traumatic (10%), inflammatory (9%), and post-infectious strictures (2.4%). At a median follow-up of 36 months, overall success rate was 70%. In sensitivity analyses, success rates were only marginally improved to 71% after exclusion of hypospadias- and lichen sclerosus-associated strictures. Patients with mid-penile strictures were significantly more satisfied compared to other groups. Overall, 272 patients from 9 studies in the literature review underwent Asopa urethroplasty and success rates ranged from 73 to 100%. Conclusions: Success rates of Asopa urethroplasty in penile strictures are lower than previously reported. This is most likely due to both complex stricture etiology and surgical history and last resort single-stage surgery in many cases. Pre-operative counseling must consider high recurrence risk and staged urethroplasty should be discussed in selective cases to optimize patient satisfaction. [ABSTRACT FROM AUTHOR]

Electronic sensors based on biomaterials can lead to novel green technologies that are low cost, renewable, and eco-friendly. Here we demonstrate bioelectronic ammonia sensors made from protein nanowires harvested from the microorganism Geobacter sulfurreducens. The nanowire sensor responds to a broad range of ammonia concentrations (10 to 106 ppb), which covers the range relevant for industrial, environmental, and biomedical applications. The sensor also demonstrates high selectivity to ammonia compared to moisture and other common gases found in human breath. These results provide a proof-of-concept demonstration for developing protein nanowire based gas sensors for applications in industry, agriculture, environmental monitoring, and healthcare. [ABSTRACT FROM AUTHOR]

Silver nanowires (Ag NWs) is a potential material to be used as the transparent conductive electrode (TCE) material, in the flexible electronic applications. The polyol method is the commonly used technique to synthesis the silver nanowires. The growth of the silver nanowires is facilitated by the oxidative etching of the silver seed particles. The present work investigates the influence of the manganese(II) ions to promote the growth of silver nanowires. The manganese(II) ions, due to its multiple oxidation states, play an essential role in removing the dissolved atomic oxygen, which prevent the growth of longer nanowires. Its effect on the length and diameter of the silver nanowires is studied in detail with different concentration levels. Characterization tools, such as X-ray diffractometry, electron microscopy (FESEM and TEM) and UV–VIS spectroscopy are used to characterise the synthesised silver nanowires. The addition of manganese(II) ions alters the aspect ratio of the silver nanowires that in turn, affects the optoelectrical properties of the TCE films. By using the synthesised silver nanowires, transparent heaters are successfully fabricated and their performances under different conditions are evaluated. [ABSTRACT FROM AUTHOR]

Objective: To evaluate the long‐term outcomes of dorsal onlay urethroplasty using lingual mucosal graft for repairing urethral strictures associated with genital lichen sclerosis. Methods: This study included 36 patients who had lichen sclerosis long anterior urethral strictures that were managed with dorsal onlay urethroplasty using lingual mucosal graft, and were followed up ≥5 years. Preoperatively, we measured the maximum urinary flow rate and the International Prostate Symptom Score, then every 3 months in the first year, and annually thereafter. During follow up, patients with obstructive symptoms were subjected to urethrography and/ or urethroscopy. A successful urethroplasty was defined as normal voiding and no need for further intervention. Results: Of the 36 patients, two were lost during the follow up, thus 34 patients were involved in the assessment. After lingual mucosal graft urethroplasty, there were significant improvements in maximum urinary flow rate and International Prostate Symptom Score (P < 0.0001). This improvement was sustained during the 5‐year follow‐up period. The median follow‐up period was 66.5 months (interquartile range 64–70 months). The overall success rate in this study was 88.2%. Postoperative complications that required intervention were reported within the first year in four (11.8%) patients. Oral site complications were mild in the early postoperative period with no long‐term complications. Conclusions: Dorsal onlay urethroplasty using lingual mucosal graft is a reliable and durable procedure for repairing lichen sclerosis urethral stricture. It provides a long‐term success rate with few failures occurring within the first year. Lingual mucosal graft harvesting is associated with minor, immediate oral complications, and no long‐term morbidity. [ABSTRACT FROM AUTHOR]

Studies the photodissociation detection of microwave transitions in highly excited vibrational states. Dipole moment measurement in the vibrational state provided by the Stark effect; Dissociation threshold of the ground electronic state.

Penile urethral strictures have been managed by a staged surgical approach. In selected cases, spongiofibrosis can be excised, a neo-urethral plate created using buccal mucosa graft (BMG) and tubularized during the same procedure, performing a "two-in-one" stage approach. We aim to identify stricture factors which indicate suitability for this two-in-one stage approach. We assess surgical outcome and compare with staged reconstruction. We conducted an observational descriptive study. The data were prospectively collected from two-in-one stage and staged penile urethroplasties using BMG in a single center between 2007 and 2017. The minimum follow-up was 6 months. Outcomes were assessed clinically, radiologically, and by flow-rate analysis. Failure was defined as recurrent stricture or any subsequent surgical or endoscopic intervention. Descriptive analysis of stricture characteristics and statistical comparison was made between groups. Of 425 penile urethroplasties, 139 met the inclusion criteria: 59 two-in-one stage and 80 staged. The mean stricture length was 2.8 cm (single stage) and 4.5 cm (staged). Etiology was lichen sclerosus (LS) 52.5% (single stage) and 73.8% hypospadias related (staged). 40.7% of patients had previous failed urethroplasties in the single-stage group and 81.2% in the staged. The most common stricture locations were navicular fossa (39.0%) and distal penile urethra (59.3%) in the single-stage group and mid or proximal penile urethra (58.7%) in the staged group. Success rates were 89.8% (single stage) and 81.3% (staged). A trend toward a single-stage approach for select penile urethral strictures was noted. We conclude that a single-stage substitution penile urethroplasty using BMG as a "two-in-one" approach is associated with excellent functional outcomes. The most suitable strictures for this approach are distal, primary, and LS-related strictures. [ABSTRACT FROM AUTHOR]

For its powerful antimicrobial properties, nanosilver is the most widely used nanoparticle in commercial odor-neutralizing and anti-infective textiles. However, the recent prevalent use of nanosilver has prompted concerns for the potential adverse human and environmental effects caused from the leaching of nanosilver during usage and laundering, necessitating innovative strategies in characterizing nanosilver on textile substrates. This study investigated the viability of surface-enhanced Raman spectroscopy (SERS) as an analytical method for the characterization and quantification of nanosilver (silver nanoparticles, 12.4 ± 5.1 nm) in cotton. Two indicators, iron (III) tris (dimethyldithiocarbamate) (ferbam) and rhodamine 6G (R6G) were used to compare how efficiently they bind onto nanosilver incorporated into cotton (nanosilver-cotton) and exhibit signature SERS responses. Comparing the SERS spectra of the two indicators, R6G was found to be more appropriate for nanosilver-cotton. The solvent system for R6G was important in enhancing the SERS intensity in the cotton medium – the intensity obtained from water was nearly threefold greater than those from methanol and the 50:50 mixture of water and methanol. A linear correlation (R2 = 0.9761) between the intensity at 1503 cm−1 of R6G and the concentration of nanosilver in cotton was developed and was validated by analyzing the washing stability of nanosilver-cotton fabrics through simulated laundering cycles. The technique was also successfully applied to spatially resolve the distribution and aggregation of nanosilver on textile fabrics by mapping a coffee-ring deposition produced by the surface application of nanosilver to textile samples of raw cotton, scoured raw cotton, and 50:50 and 80:20 blends of polyester-cotton. These results validate SERS as a rapid and facile tool for monitoring the dispersion and concentration of nanosilver on textiles after application and laundering. [ABSTRACT FROM AUTHOR]

The first variational calculations of the rotational-vibrational levels of PF 3 are performed and intensities for dipole transitions between them computed. This is accomplished using new state of the art potential energy and dipole moment surfaces. This allows the infrared spectrum of PF 3 to be simulated, providing a complete overview of the ro-vibrational spectrum up to J=100 in the wavenumber range 0–3100 cm−1. The behaviour of PF 3 at high rotational excitations is also investigated. The formation of quasi-degenerate 6-fold rotational energy clusters at high rotational excitation are investigated up to J=270 and are found to occur around J=200. The clustering effect is analysed in terms of semi-classical rotational energy surfaces. [ABSTRACT FROM AUTHOR]

Lichen sclerosus (LS) is a severe, chronic, dermatosis characterised by inflammatory, sclerotic, pruritic lesions that causes significant morbidity in patients of all genders and ages. In boys, the lesions typically affect the foreskin and glans (termed balanitis xerotica obliterans (BXO)), leading to phimosis and potentially meatal stenosis. The incidence of the disease is not well reported but the average age of affected boys is 8 years (range 1-16). Diagnosis can often be made clinically, although histological study remains important to rule out important differential diagnoses. Complications include genital scarring, urinary and sexual dysfunction as well as the development of carcinomas in adult life. Circumcision has been regarded as definitive management of BXO in boys, but this may be supplemented with medical therapies such as topical steroids, immune modulators, intralesional triamcinolone and ozonated olive oil. Supportive measures including emollients, avoidance of irritants, surveillance of complications and recurrence as well as education and counselling remain important.Conclusion: BXO remains an important cause of phimosis in boys. The frequency of this condition appears unclear but seems likely to be less than 1% of males. Treatment generally involves circumcision, with some evidence that topical steroids or immunomodulators may decrease the incidence of recurrent meatal stenosis.What is Known:• Surgical circumcision is considered the definitive management of BXO• Many aspects of BXO are still in contention or require further study including the epidemiology and aetiology.What is New:• There is increasing awareness of non-surgical modalities that may be used in adjunct to surgery including topical corticosteroids, immune modulators, intralesional triamcinolone and ozonated olive oil• Awareness of meatal stenosis-related BXO has led to the development of surgical techniques such as preputioplasty as well as buccal mucosal inlay grafts. [ABSTRACT FROM AUTHOR]

Background Urethral stricture is widely prevalent disease and its management is a challenging surgery. Nosoleideal surgical procedure appropriate inevery situation. The Grafting by Buccal Mucosa (BMGurethroplasty) represents the most appropriate and widely used procedure torepairstricture of urethra. We disclosedtheextended followup thecasesof stricture of urethrathat managed by (BMG urethroplasty) aiming to determine the success rate, recurrence and complications rate. Patients and Method A study was orchestrated to prospectively followup a 39 patients with bulbar and proximal penile urethral stricture disease repaired by BMG urethroplasty. Retrograde urethrography done to confirm the diagnosis, measure the length and locate urethral strictures. Patient demographics, stricture aetiology and anatomy all were recorded. Follow up data in term of success and failure rate, and complication. Results thirty-nine patients (the mean age was 35.4 years) with urethral strictures disease diagnosed by urethrography of more than 3 cm in length (the mean ofstricture length was 5.34cm). 23, 7, and 9 patients had bulbar, penile and long combined (bulbar and penile) strictures respectively. Early peri- and post-operative complications occurred in 35% it was almost minor complications included scrotal swelling, minor hematoma, urinary infections, and urgency. 4 patients only developed re-stricture 2 of them had a failure. The most frequent major complications were a urethrocutaneousfistula. Conclusion Buccal mucosal graft urethroplasty appear to be a rightful and durable treatmentchoice for cases with urethral strictures, moreover it has a fewer major complications. [ABSTRACT FROM AUTHOR]

Understanding of the elastic deformation behaviours of recently synthesised carbon nanorings (CNRs) is crucial in guiding their future applications, because the strain engineering provides an efficient means to modify their physical and chemical properties. In this paper, by using molecular dynamics simulations and nonlocal continuum mechanics models, we study the elastic deformations of CNRs with three different molecular structures, i.e., cycloparaphenylenes (CPPs), [4]cyclochrysenylenes and cyclacenes. Our results show that, compared to other two types of CNRs, CPPs have the smallest mechanical stiffness, which is attributed to the influence of numerous weak connecting carbon–carbon bonds existing between their component benzene rings. In addition to the molecular structure, the elastic deformation behaviours of CNRs are also found to strongly depend on the size. Specifically, the compressive stiffness of CNRs is found to increase as their size (radius) decreases. Meanwhile, the size reduction of CNRs can trigger the anisotropy of their compressive stiffness and can also aggravate the influence of small-scale effects on their elastic deformation behaviours, which can significantly reduce the compressive stiffness. [ABSTRACT FROM AUTHOR]

Purpose: Organ-sparing surgery (OSS) is recommended in selected patients with testicular tumors and penile cancer (PC). The functional and psychological impacts of organ excision for these genital tumors are profound. In this review, we summarize the indications, techniques and outcomes of OSS for these two tumors. Methods: PubMed® was searched for relevant articles up to December 2018. For Testicular sparing surgery (TSS) search, keywords used were; testicular tumors alone and in combination with "testicular sparing surgery", "partial orchiectomy" and outcomes. For penile conserving surgery (PCS), keywords used were: penile cancer alone and in combination with "penile conserving surgery", "partial penectomy" and outcomes. Because of the low quality of available evidence, a narrative rather that systematic review has been performed. Results: Indications of TSS are tumors ≤ 2 cm in solitary testis or bilateral tumors and no rete testis invasion. Prerequisites include normal testosterone and luteinizing hormone levels and patient compliance with follow-up. Indications for PCS are distal penile lesions with clinical stage ≤ T1. Adequate penile stump (3 cm) is required after surgery to maintain forward urine stream. Frozen section helps to reduce the risk of recurrence. Local recurrence after PCS is not associated with reduced survival and can be managed with another PCS in selected patients. The reported oncological and functional outcomes following TSS and PCS are adequate. Conclusions: In properly selected patient OSS in testicular and penile tumors has a comparable oncological outcome to total organ excision with added advantages of preserving organ function and psychological well-being. [ABSTRACT FROM AUTHOR]

A novel cross 1,3-dipolar cycloaddition between azomethine imines with in situ generated nitrile oxides has been developed. This is the first example of employing a reaction partner containing two heteroatoms in the [3+3] cycloaddition involving azomethine imines. This strategy not only provides structurally diverse N,O-heterocycles but also greatly enriches the chemistry of azomethine imines and nitrile oxides. [ABSTRACT FROM AUTHOR]

Lichen sclerosus (LS) is an autoimmune chronic inflammatory disease usually involving the anogenital skin of both sexes; more rarely LS exclusively involves extragenital areas. As a chronic inflammatory disease, in most cases, LS evolves and progresses causing scleroatrophy of the skin or scars which may cause stenosis in the affected areas. A few LS patients are at risk of developing squamous cell carcinoma in their lifetime, but appropriate long-term treatment diminishes the possibility of a malignant evolution. Oxidative stress (OS) has been proven to play a role not only in the pathogenesis of LS, but also in the development and progression of the disease. OS, by causing DNA damage and lipid peroxidation, contributes directly to the possible malignant transformation of LS. Moreover, the increase in oxidative DNA damage is associated with mutations in tumor suppressor genes. Considering the role that OS plays in LS, therapeutic use of antioxidants appears to be rational and possible, in association with other treatments. Antioxidants would counteract the oxidative DNA damage, which is the most important factor for the progression of LS and its malignant transformation. [ABSTRACT FROM AUTHOR]

Carbon nanotube (CNT) film can be used as thin film electrodes and wearable electronic devices due to their excellent mechanical and electrical properties. The femtosecond laser has the characteristics of an ultra-short pulse duration and an ultra-high peak power, and it is one of the most suitable methods for film material processing. The ablation and patterning of CNT film are performed by a femtosecond laser with different parameters. An ablation threshold of 25 mJ/cm2 was obtained by investigating the effects of laser pulse energy and pulse number on ablation holes. Raman spectroscopy and scanning electron microscope (SEM) were used to characterize the performance of the pattern groove. The results show that the oligomer in the CNT film was removed by the laser ablation, resulting in an increase in Raman G band intensity. As the laser increased, the ablation of the CNTs was caused by the energy of photons interacting with laser-induced thermal elasticity when the pulse energy was increased enough to destroy the carbon–carbon bonds between different carbon atoms. Impurities and amorphous carbon were found at and near the cut edge while laser cutting at high energy, and considerable distortion and tensile was produced on the edge of the CNTs' groove. Furthermore, appropriate cutting parameters were obtained without introducing defects and damage to the substrate, which provides a practical method applied to large-area patterning machining of CNT film. [ABSTRACT FROM AUTHOR]

Hybrid transparent conductive thin films (TCFs) with a bilayer structure composed of aluminum-doped zinc oxide (AZO) and Cu micro-mesh (CuM) are prepared on polyethylene terephthalate (PET) substrates. The AZO layers are deposited by RF magnetron sputtering at room temperature. The CuM is fabricated by UV-lithography and DC magnetron sputtering. The optical properties and conductivity can be modified by the thickness of CuM, and the conduction mechanism involving metal Cu–AZO carrier injection is proposed. The flexible CuM/AZO composite thin films exhibit outstanding optoelectronic performance, with the best figure of merit ≈ 1247 (at average optical transmittance of 85.8%, sheet resistance of 1.9 Ω/sq. and resistivity of 1.89 × 10−4 Ω·cm), as well as excellent mechanical flexibility. The resulting hybrid TCFs with CuM/AZO composite structure show potential applications in flexible electronics, organic light emitting diodes and photovoltaic devices. [ABSTRACT FROM AUTHOR]

Purpose: To present results of an algorithmic approach to perineal urethrostomy (PU) based on a midline perineal incision among men with complex urethral strictures. Methods: A single surgeon retrospective review of consecutive patients who underwent PU between 2008 and 2017 was performed. Patient demographics and outcomes were collected via medical record review. After a midline perineal incision, the PU was matured either by (a) mobilization of the urethral plate (loop) alone in cases with distal strictures or low body mass index (BMI), or (b) with creation of a lateral perineal skin flap (7-flap) for those with longer urethra-to-skin distances. Success was defined as functional voiding without the need for further procedures. Patients were contacted by phone and administered validated questionnaires. Results: Of 62 PU patients, 20 (32.3%) underwent the loop technique, and 42 (67.7%) had the 7-flap procedure, 7 of which were reoperative for prior failed PU. Median age was 61.9 years (range 23–85) and the median stricture length was 8.0 cm (range 2.5–18 cm). Mean BMI was greater among 7-flap compared to loop patients (34.9 vs. 30.0 kg/m2, p = 0.01). Success rates were 92.9% (39/42) in the 7-flap group and 100% (20/20) in the loop PU cohort during a median follow-up of 30.7 months. Among 62 PU patients, 19 (30.6%) responded to the survey—median PGI-I score was 1.0 (range 1–2) indicating that symptoms were "very much improved". Conclusions: The algorithmic midline approach to PU offers a standardized, versatile solution with excellent surgical outcomes and high patient satisfaction, even in obese or refractory stricture patients. [ABSTRACT FROM AUTHOR]

Introduction. Glans resurfacing has been suggested as a treatment option for the surgical management of superficial penile cancer (Tis, Ta, T1aG1, T1aG2). In this article we describe in detail the glans resurfacing technique with skin graft for penile cancer in a video presentation and we review the current knowledge of the literature. Material and Methods. The procedure is described in a stepwise fashion. Initially the patient is circumcised. The glans is marked in quadrants and completely stripped by dissecting and removing the epithelium and subepithelium layer of the glans. Deep spongiosal biopsies are taken to exclude invasion. Each quadrant is sent separately for biopsy. The surface of the graft size needed is estimated. A partial thickness skin graft is harvested from the thigh with a dermatome. The skin graft is then fenestrated. The graft is rolled over the glans and quilted with multiple sutures. A silicone 16F Foley catheter and a suprapubic catheter are placed. The penis is dressed with multiple gauzes and compressed with an elastic band. Results. The patient is discharged the next day. The dressing and Foley catheter are removed in 7 days. The patient continues to use the suprapubic catheter for 7 more days. The patient refrains from any sexual activity for 6 weeks and is closely followed. Conclusions. Glans resurfacing is an emerging new appealing surgical technique that is already a recommendation in the EAU guidelines for the treatment of premalignant and superficial penile lesions. The overall satisfaction rate and recovery of the sexual function are acceptable, and it can be considered an ideal procedure to treat superficial penile cancer. [ABSTRACT FROM AUTHOR]

Background: Long anterior urethral stricture due to variable etiological factors constitutes a challenge for reconstruction. We evaluated our centers experience with cases of long anterior urethral stricture due to different etiologies that were managed by 2-stage substitution urethroplasty using buccal mucosal graft procedure.Methods: During the period between November 2009 and November 2016. All cases with long anterior urethral stricture that were planned for substitution urethroplasty in our department were enrolled in this study. The first stage was excision of most fibrotic areas of the urethral plate, the remaining of the urethra is laid open and augmented with buccal mucosal graft for second stage closure after 6-9 months.Results: The study included 123 patients who underwent first stage, 105 patients of them underwent second stage urethroplasty. Eighteen cases were missed after first stage. The mean (range) age was 38.4 (17-60 years). The mean (range) stricture length was 8.3 (4-13 cm). The cause of stricture was idiopathic in 47, inflammatory in 15, lichen sclerosus in 26 and post failed hypospadias repair in 35 patients. First stage was complicated by graft contracture in 11 (8.9%) patients that needed re-grafting, 5(4.1%) patient had bleeding from the buccal mucosa site that needed haemostatic sutures, oral numbness was reported in 7 (5.7%) patients. Second stage was complicated by wound dehiscence in 2(1.9%) patients, restricture in 11 (10.5%), fistula in 6 (5.7%) patients, meatal stenosis in 3 (2.9%). The overall success rate was 79.1% (83 cases out of 105) with a mean (range) follow-up of 34.7 (10-58 months).Conclusions: Staged urethroplasty using buccal mucosal graft procedure is an effective surgical option for patients with long anterior urethral strictures especially for patients with lichen sclerosus and those with failed previous surgical repair. [ABSTRACT FROM AUTHOR]

In the development of wearable energy devices, polypyrrole (PPy) is considered as a promising electrode material owing to its high capacitance and good mechanical flexibility. Herein, we report a PPy-based hybrid structure consisting of vertical PPy nanotube arrays and carbon nano-onions (CNOs) grown on textile for wearable supercapacitors. In this hybrid nanostructure, the vertical PPy nanotubes provide straight and superhighways for electron and ion transport, boosting the energy storage; while the CNOs mainly act as a conductivity retainer for the underlayered PPy film during stretching. A facile template-degrading method is developed for the large-area growth of the PPy-based hybrid nanostructures on the textile through one-step polymerization process. The fabricated stretchable supercapacitor exhibits superior energy storage capacitance with the specific capacitance of 64 F·g−1. Also, it presents the high capacitance retention of 99% at a strain of 50% after 500 stretching cycles. Furthermore, we demonstrate that the textile-based stretchable supercapacitor device can provide a stable energy storage performance in different wearable situations for practical applications. The use of the PPy-based hybrid nanostructures as the supercapacitor electrode offers a novel structure design and a promising opportunity for wearable power supply in real applications. [ABSTRACT FROM AUTHOR]

A number of techniques have been described for managing anterior urethral strictures in men. In this review, we aimed to summarize contemporary considerations regarding the holistic management of such strictures. The efficacy of reported outcomes is compared to provide evidence-based treatment recommendations. For anterior urethral strictures, durable long-term success rates of >90% may be achieved if the procedure is performed in capable hands at a high-volume referral center, even in recurrent strictures after previous open reconstruction. A one-stage urethroplasty is preferable to avoid a protracted treatment course with multiple interventions after dilation and direct vision internal urethrotomy. Staged urethroplasties are useful in complex anterior strictures providing durable success rates. In addition, perineal urethrostomy represents a valid last resort option with sufficient objective and subjective results. A follow-up evaluation should incorporate objective assessments such as radiographic and functional diagnostics as well as subjective, validated, and disease-specific patient-reported outcome measurement tools to allow for a better comparability and to improve individual risk prediction. [ABSTRACT FROM AUTHOR]

Examines the largest angle generalization of the rotating bond order potential (LAGROBO) functional representation of potential energy. Connection of atom-diatom arrangements from the reactive processes; Extension of the LAGROBO system for electronically excited atom; Use of LAGROBO potential for lithium, fluorine and hydrogen reaction.

The potential energy surface of the O([SUP1]D)+HCl reaction has been calculated at an ab initio level. The calculated values have been fitted using a bond-order polynomial. On this potential energy surface quasiclassical trajectory calculations have been performed. These calculations reproduce most of the available experimental information better than the other existing potential energy surfaces. [ABSTRACT FROM AUTHOR]

The aim of this study is to describe the outcomes for a modified glans-resurfacing technique for benign and malignant penile conditions in which the uninvolved glans corona is preserved in order to maintain glans erogenous sensation. A total of 13 patients underwent coronal-sparing glans resurfacing (CSGR), with follow-up every 3 months for ≥2 years. Positive surgical margin and local recurrence (LR) rates were evaluated. Surgical complications and cosmetic outcomes were also recorded. Patients were asked to complete the International Index of Erectile Function-5 (IIEF-5) questionnaire starting 12 months after the surgery. The median (interquartile range [IQR]) age and follow-up periods were 63 (53-68) years and 29 (14-38) months, respectively. Eight patients were diagnosed with primary penile squamous cell carcinoma (SCC), three had refractory lichen sclerosus, and two had penile intraepithelial neoplasia (PeIN). No surgical complications were recorded. All patients had a complete graft take and reported satisfactory cosmetic results with preserved erogenous sensation. Two cancer patients developed LR which was managed with further penile preserving surgery. The median (IQR) postoperative IIEF-5 value was 20 (17-23). This modified coronal-sparing technique was suitable for glans lesions that spare the coronal ridge and coronal sulcus. Preservation of the coronal ridge helps maintain sexual function and provides excellent cosmetic outcomes., (© 2021. The Author(s), under exclusive licence to Springer Nature Limited.)

Recent advances in the field of nanotechnology applications in nuclear medicine offer the promise of better diagnostic and therapeutic options. In recent years, increasing efforts have been focused on developing nanoconstructs that can be used as core platforms for attaching medical radionuclides with different strategies for the purposes of molecular imaging and targeted drug delivery. This review article presents an introduction to some commonly used nanomaterials with zero‐dimensional, one‐dimensional, two‐dimensional, and three‐dimensional structures, describes the various methods applied to radiolabeling of nanomaterials, and provides illustrative examples of application of the nanoscale radionuclides or radiolabeled nanocarriers in nuclear nanomedicine. Especially, the passive and active nanotargeting delivery of radionuclides with illustrating examples for tumor imaging and therapy was reviewed and summarized. The accurate and early diagnosis of cancer can lead to increased survival rates for different types of this disease. Although, the conventional single‐modality diagnostic methods such as positron emission tomography/single photon emission computed tomography or MRI used for such purposes are powerful means; most of these are limited by sensitivity or resolution. By integrating complementary signal reporters into a single nanoparticulate contrast agent, multimodal molecular imaging can be performed as scalable images with high sensitivity, resolution, and specificity. The advent of radiolabeled nanocarriers or radioisotope‐loaded nanomaterials with magnetic, plasmonic, or fluorescent properties has stimulated growing interest in the developing multimodality imaging probes. These new developments in nuclear nanomedicine are expected to introduce a paradigm shift in multimodal molecular imaging and thereby opening up an era of new diagnostic medical imaging agents. © 2018 Wiley Periodicals, Inc. J Biomed Mater Res Part A: 107A: 251–285, 2019. [ABSTRACT FROM AUTHOR]

A general approach was developed to fabricate graphene/semiconducting single-wall carbon nanotube (graphene/s-SWCNT) film Schottky junctions on a large scale. The graphene/s-SWCNT film photodiodes array based on the vertically stacked Schottky junction were fabricated. The all-carbon cross-shaped structure consisted of multielement graphene/s-SWCNT Schottky photodiodes and presented a rich collection of electronics and photonics. The as-fabricated carbon-based photodiode presented an ultra-broadband photodetection characteristic with a high responsivity of 1.75 A/W at near-infrared wavelengths and a fast response rise time of 15 μs. The as-fabricated device clearly showed gate-tunable and wavelength-dependent photoelectric characteristic. Moreover, the corresponding photocurrent excitation spectrum was also demonstrated. In particular, the Si compatible and high throughput fabrication process for the devices made it conducive for large-area multielement optoelectronics devices. [ABSTRACT FROM AUTHOR]

Ag-Pt bimetallic nanoparticles decorated on MWCNTs/PANI nanocomposites have been synthesized by in-situ chemical oxidative polymerization and chemical co-reduction method. The Fourier transform infrared (FT-IR) spectroscopy, X-ray diffraction (XRD), ultraviolet-visible (UV-vis) absorption spectroscopy, scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were used to characterize the morphology and structure of the nanocomposites. It can be observed that the PANI was uniformly grown along the MWCNTs to form MWCNsT/PANI fiber-like nanocomposites with diameter about 60 nm, and the Ag-Pt binary nanoparticles were decorated onto MWCNTs/PANI with particle sizes around 6.8 nm. Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) were used to characterize the electrochemical performance of the prepared electrode. The results demonstrated that the obtained MWCNTs/PANI/Ag-Pt electrode displayed a good electrochemical activity and fast electron transport, which has potential applications in biosensors and supercapacitors. [ABSTRACT FROM AUTHOR]

Here, we put forward an optimum proposal to prepare high-performance polypyrrole (PPy) electrodes for supercapacitor applications. A detailed study regarding the effects of different preparation conditions including electropolymerized mode, parameter, and current collector on the electrochemical capacitive performances of PPy electrodes is carried out. Fourier transform infrared spectroscopy and X-ray diffraction tests indicate the above preparation conditions have no effect on the component and crystal structure of PPy prepared. Electrochemical measurements manifest a significant effect of current collector on supercapacitive properties of PPy electrodes. Graphite foil as the current collector with low resistance shows remarkably superior capacitive performances compared with FTO-conducting glass and ITO conductive plastic. SEM characterizations show galvanostatically polymerized PPy particles have obviously smaller aggregation degree than potentiostatically polymerized PPy particles, which results in better electrochemical properties for former. Among different preparation conditions, the PPy deposited on graphite foil under galvanostatic mode with 2 mA cm−2 shows the best electrochemical capacitive properties. The optimized PPy/graphite electrodes show a high specific capacitance of 173.0 mF cm−2 at 0.2 mA cm−2, superior rate capability, and outstanding cycling stability (retaining 90.5% of initial capacitance for 5000 cycles). [ABSTRACT FROM AUTHOR]

Diameters and crystallinity of multi-walled carbon nanotubes (MWCNTs) dependent on reduction temperature of the Fe--Co/MgO catalyst were investigated. MWCNTs were synthesized by catalytic chemical vapor depositing and the Fe--Co/MgO catalyst was fabricated by using a sol-gel method. According to Raman analysis, transmission electron microscopy and thermogravimetric analysis, the diameter distribution of MWCNTs was broadened with increasing reduction temperature of the Fe--Co/MgO catalyst and crystallinity was improved. The above results are attributed to an increased size and enhanced crystallinity of metal catalyst particles by increasing reduction temperature. [ABSTRACT FROM AUTHOR]

Abstract: The specific energy parameters of nanostructured electrode materials of electrochemical capacitors obtained by the method of multistage calendering are studied in this work. The dependence of electrical conductivity; the specific capacity of an electrical double layer of electrodes; and the internal resistance of electrochemical capacitors on the nature, quantity, and spatial localization (in the volume of the active layer and/or at the active layer-current collector interface) of conductive dopants (carbon black and grown in vacuum carbon fibers) are examined. [ABSTRACT FROM AUTHOR]

We established diagnostic criteria and severity classification of lichen sclerosus et atrophicus, because there is no established diagnostic criteria or widely accepted severity classification of the disease. Also, there is no clinical guideline for lichen sclerosus et atrophicus in Japan, so we proposed its clinical guideline. The clinical guidelines were formulated by clinical questions and recommendations on the basis of evidence-based medicine according to the New Minds Clinical Practice Guideline Creation Manual (version 1.0). We aimed to make the guidelines easy to use and reliable including the newest evidence, and to present guidance for various clinical problems in treatment of lichen sclerosus et atrophicus. [ABSTRACT FROM AUTHOR]

Carbon nanotube thin film transistors (CNT-TFTs) are a potential TFT technology for future high-performance macroelectronics. Practical application of CNT-TFTs requires the production of large-area, highly uniform, density-controllable, repeatable, and high-throughput CNT thin films. In this study, CNT films were fabricated on 4-inch Si wafers and 2.5th generation (G2.5) backplane glasses (370 mm × 470 mm) by dip coating using a chloroform-dispersed high-purity semiconducting CNT solution. The CNT density was controlled by the solution concentration and coating times, but was almost independent of the substrate lifting speed (1-450 mm·min−1), which enables high-throughput CNT thin film production. We developed an image processing software to efficiently characterize the density and uniformity of the large-area CNT films. Using the software, we confirmed that the CNT films are highly uniform with coefficients of variance (CV) < 10% on 4-inch Si wafers and ∼ 13.8% on G2.5 backplane glasses. High-performance CNT-TFTs with a mobility of 45-55 cm2·V−1·s−1 were obtained using the fabricated CNT films with a high-performance uniformity (CV ≈ 11%-13%) on a 4-inch wafer. To our knowledge, this is the first fabrication and detailed characterization of such large-area, high-purity, semiconducting CNT films for TFT applications, which is a significant step toward manufacturing CNT-TFTs. [ABSTRACT FROM AUTHOR]

Metal-free supercapacitors were designed and fabricated using a 3D printing process. An attempt was made to use carbon conductive paint to create both current collector and electrode. Two 3D printing techniques were combined and used to manufacture the electric double layer capacitors (EDLCs). The electrode material made from carbon conductive paint and distilled water showed a good electrical performance. The manufacturing process for the EDLCs has been explained in detail and the process showed a good reproducibility. Different thicknesses of electrode were tested and characterized. The results showed that both the mass of the electrode material and the capacitance of the supercapacitor increased as the thickness of the active layer increased. The thickness of the electrode increased 4 times from 0.5 mm to 2.0 mm, the mass of the electrode material increased nearly 3 times from 0.514 g to 1.498 g, which resulted in the increase of capacitance from 0.133 F to 0.295 F. [ABSTRACT FROM AUTHOR]

[3+2] cycloadditions of ynones derived from glycine and (S)-alanine and some other dipolarophiles with azomethine imines, nitrile oxides, diazoacetate, and azidoacetate were studied. The dipolarophiles were obtained from α-amino acids, either by the reduction of the carboxy function with ethynylmagnesium bromide or by propiolation of the amino function. Cu-catalyzed cycloadditions of ynones to azomethine imines were regioselective and gave the expected cycloadducts as inseparable mixtures of diastereomers. In some instances, further oxidative hydrolytic ring-opening took place to afford 3,3-dimethyl-3-(1H-pyrazol-1-yl)propanoic acids. Acid-catalyzed cycloadditions of 3-butenone were also regioselective and provided mixtures of diastereomeric cycloadducts, which were separated by chromatography. In the reactions of title ynones with alkyl diazoacetates, in situ-formed benzonitrile oxides, and tert-butyl azidoacetate, all cycloadducts were obtained as single regioisomers. The structures of all novel compounds were established by nuclear magnetic resonance and X-ray diffraction. [ABSTRACT FROM AUTHOR]

Carbon nanotube (CNT) fiber-based emitters have shown great potential to deliver stable, high current beams for various potential applications. Because of joule heating, CNT field emitters are heated to high temperatures during field emission. It is important to improve the thermal management of emitters to increase their reliability and prevent premature failure. This paper compares the field emission characteristics and the temperature distribution of a new configuration of a looped CNT fiber emitter with a traditional single vertical CNT fiber emitter. It is found that the maximum temperature of the looped fiber emitter (~300 °C) is significantly reduced compared to that of the vertical fiber (~600 °C) at the same emission current of 3 mA. The experimentally measured temperature distribution is compared with a recent theory on joule heating of a one-dimensional conductor. This study provides new insights into the design of high performance field emitters. [ABSTRACT FROM AUTHOR]

The relationship between particle dynamics in a suspension drop during drying and final coffee ring patterns was investigated using suspension systems with spherical and non-spherical ellipsoidal particles. Employing multi-speckle diffusing wave spectroscopy (MSDWS), fast particle Brownian motions in suspension drops containing spherical and ellipsoidal particles were quantitatively compared during the drying process in real time. From the autocorrelation function data and characteristic times for β-relaxation, we confirmed that ellipsoidal particles move more slowly than spherical particles in a suspension drop due to their structural factor. The resulting coffee ring patterns by spherical and ellipsoidal particles are clearly distinguishable from one another and are dependent upon particulate concentration, initial drop volume, and particle shape. Notably, ellipsoidal particles in a suspension drop form coffee rings less readily than spherical particles. [ABSTRACT FROM AUTHOR]