1,990 results on '"Hillers, A."'
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152. Computational investigation of photoswitch conjugates for molecular solar energy storage
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Elholm, Jacob L., primary, Liasi, Zacharias, additional, Mikkelsen, Marie K., additional, Hillers-Bendtsen, Andreas Erbs, additional, and Mikkelsen, Kurt V, additional
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- 2023
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153. Exploring the impact of select anchor groups for norbornadiene/quadricyclane single-molecule switches
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Ghasemi, Shima, primary, Ornago, Luca, additional, Liasi, Zacharias, additional, Johansen, Magnus Bukhave, additional, von Buchwald, Theo Juncker, additional, Hillers-Bendtsen, Andreas Erbs, additional, van der Poel, Sebastiaan, additional, Hölzel, Helen, additional, Wang, Zhihang, additional, Amombo Noa, Francoise M., additional, Öhrström, Lars, additional, Mikkelsen, Kurt V., additional, van der Zant, Herre S. J., additional, Lara-Avila, Samuel, additional, and Moth-Poulsen, Kasper, additional more...
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- 2023
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154. Excited state dynamics and conjugation effects of the photoisomerization reactions of dihydroazulene
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Andreas Erbs Hillers-Bendtsen, Frederik Ørsted Kjeldal, Nicolai Ree, Eduard Matito, and Kurt V. Mikkelsen
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General Physics and Astronomy ,Physical and Theoretical Chemistry - Abstract
Herein, we present an investigation of the excited state dynamics of the dihydroazulene photoswitch and its photoinduced reaction to vinylheptafulvene. The focus is on how the introduction of a benzannulated ring in different sites of the structure can modify the excited state topology and thus the kinetics of the ring opening reaction of DHA by alteration of the excited state conjugation of the system. The dynamics of the systems is obtained utilizing more...
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- 2022
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155. Cormac, Solomon, and One Shearing for Another
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John Carey and Barbara Hillers
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Linguistics and Language ,Archeology ,History ,Literature and Literary Theory ,Visual Arts and Performing Arts ,Language and Linguistics - Published
- 2022
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156. Optimization of the thermochemical properties of the norbornadiene/quadricyclane photochromic couple for solar energy storage using nanoparticles
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Andreas Erbs Hillers-Bendtsen, Frederik Ørsted Kjeldal, Nicolai Machholdt Høyer, and Kurt V. Mikkelsen
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General Physics and Astronomy ,Physical and Theoretical Chemistry - Abstract
In this paper, we present an investigation concerning the prospects of using nanoparticles to improve solar energy storage properties of three different norbornadiene/quadricyclane derivatives. Computationally, we study how different nanoparticles influence the properties of the systems that relate to the storage of solar energy, namely, the storage energy and the back reaction barrier. Our approach employs hybrid quantum mechanical/molecular mechanical calculations in which the molecular systems are described using density functional theory while the nanoparticles are described using molecular mechanics. The interactions between the two subsystems are determined using polarization dynamics. The results show that the influence of the nanoparticles on the thermochemical properties largely depends on the type of nanoparticle used, the relative orientation with respect to the nanoparticle, and the distance between the the nanoparticle and the molecular system. Additionally, we find indications that copper and/or titanium dioxide nanoparticles can lower the energy barrier of the back reaction for all of the studied systems without significantly lowering the storage capability of the systems. Consequently, the study shows that nanoparticles can potentially be employed in the optimization of molecular photoswitches towards solar energy storage. more...
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- 2022
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157. Amnirana parva Griesbaum & Jongsma & Penner & Kouamé & Doumbia & Gonwouo & Hillers & Glos & Blackburn & Rödel 2023, sp. nov
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Griesbaum, Frederic, Jongsma, Gregory F. M., Penner, Johannes, Kouamé, N'Goran Germain, Doumbia, Joseph, Gonwouo, Nono L., Hillers, Annika, Glos, Julian, Blackburn, David C., and Rödel, Mark-Oliver
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Amphibia ,Ranidae ,Amnirana ,Animalia ,Biodiversity ,Anura ,Chordata ,Taxonomy ,Amnirana parva - Abstract
Amnirana parva sp. nov. Lesser White-Lipped Frog Figs. 5–7 Holotype. ZMB 88458 (field #: RG27, GenBank #: 16S: OQ400914), adult male, Liberia, Krahn-Bassa Proposed Protected Area, 5°39′02.1′′N, 8°39′05.0′′W, 28 March 2018, leg. M.-O. Rödel & J. Glos. Paratypes. Twelve males, ten females: ZMB 71273 (field #: MOR ANK 15, GenBank #: 16S: MG552248), adult female, Ghana, Ankasa National Park, 5°16′38.5212′′N, 2°38′41.8812″W, 5 August 2005, leg. A.C. Agyei & A. Hillers; ZMB 71274 (field #: MOR OWS 28, GenBank #: 16S: MG552262), adult female, Ghana, Owabi Wildlife Sanctuary, 6°44′50.5212″N, 1°42′11.6388″W, July 2005, leg. A.C. Agyei & A. Hillers; ZMB 71276 (field #: MOR LE 11, GenBank #: 16S: MG552287), adult female, Ghana, Leklebi-Agbesia, 6°56′ 1.3812″N, 0°29′1.5612″W, 19 July 2005, leg. A.C. Agyei & A. Hillers; ZMB 79187 (field #: GO14), adult male, Liberia, Gola National Forest, 7°27′10.6812″N, 10°41′31.3188″W, 28 November 2005, leg. A. Hillers; ZMB 79197 (field #: G84), adult female, Ghana, Volta Region, 22 August 2001, leg. M.-O. R ̂del; ZMB 79210 (field #: GOL 060, GenBank #: 16S: MG552310), adult male, Sierra Leone, Gola North Forest Reserve, 7°35′10.14″N, 11°1′30.9612″W, 15 September 2005, leg. A. Barrie & A. Hillers; ZMB 79253 (field #: GRE 010, GenBank #: 16S: MG552307), adult female, Liberia, Grebo National Forest, 5°24′6.48″N, 7°44′0.6612″W, 7 December 2005, leg. A. Hillers; ZMB 87105–06 (field #: P.LI 12 004–P.LI 12 005, GenBank #: 16S: MG552296 & MG552305), adult female and male, Liberia, Gba Community Managed Forest, 7°28′52.6584″N, 8°34′28.5564″W, 28 January 2012, leg. J. Penner; ZMB 87107 (field #: P.LI 12 077, GenBank #: 16S: MG552312), adult male, Liberia, Gba Community Managed Forest, 7°30′34.5636″N, 8° 41′50.7408″W, 3 February 2012, leg. J. Penner; ZMB 87108 (field #: P.LI 12 321, GenBank #: 16S: MG552315), adult male, Liberia, Sapo National Park, 5°29′42.8352″N, 8°21′55.1988″W, 5 September 2012, leg. J. Penner & N.L. Gonwouo; ZMB 87109 (field #: P.LI 12 466, GenBank #: 16S: MG552323), adult male, Liberia, Mount Ghi South, 5°38′34.9944″N, 8°12′30.1428″W, 29 September 2012, leg. J. Penner & N.L. Gonwouo; ZMB 87110–11 & 87116 (field #: P.LI 12 503–P.LI 12 505, GenBank #: 16S: MG552319 & MG552320), adult male, female and male, Liberia, Mount Ghi South, 5°39′11.124″N, 8°12′21.708″W, 3 October 2012, leg. J. Penner & N.L. Gonwouo; ZMB 87112 (field #: P.LI 12 300, GenBank #: 16S: MG552322), adult male, Liberia, Sapo National Park, 5°31′20.8272″N, 8°20′46.2084″W, 14 September 2012, leg. J. Penner & N.L. Gonwouo; ZMB 87113 (field #: P.LI 12 377, GenBank #: 16S: MG552317), adult male, Liberia, Sapo National Park, 5°30′18.5652″N, 8°20′14.9208″W, 18 September 2012, leg. J. Penner & N.L. Gonwouo; ZMB 87114 (field #: P.LI 12 432, GenBank #: 16S: MG552316), adult female, Liberia, Mount Swa, 6°26′18.0636″N, 9°3′25.9416″W, 24 September 2012, leg. J. Penner & N.L. Gonwouo; ZMB 87115 (field #: P.LI 12 279, GenBank #: 16S: MG552314), adult female, Liberia, Sapo National Park, 5°31′34.8564″N, 8°20′53.1636″W, 12 September 2012, leg. J. Penner & N.L. Gonwouo; ZMB 88438 (field #: RG07), adult female, Liberia, Krahn-Bassa Proposed Protected Area, 06°02′34.8″N, 08°20′10.3″W, 25 March 2018, leg. M.-O. R ̂del & J. Glos; ZMB 88512 (field #: RG80), adult male, Liberia, Foya Proposed Protected Area, 08°00′21.3″N, 10°25′20.2″W, 5April 2018, leg. M.-O. Rödel & J. Glos; ZMB 88549 (field #: RG118, GenBank #: 16S: OQ400915), adult male, Liberia, Foya Proposed Protected Area, 08°03′18.6″N, 10°23′04.0″W, 8 April 2018, leg. M.-O. R ̂del & J. Glos. Additional material. Ten males, ten females; ZMB 90052 (field #: N035), adult female, Guinea, Keoulenta, 7°41′20.6”N, 8°21′19.0”W, 21 September 2009, leg. J. Doumbia, L. Sandberger, K. Camara & F. Gbêmou; ZMB 90053 (field #: N064), adult female, Guinea, Foromota, 7°42′58.3”N, 8°21′41.6”W, 3 November 2009, leg. J. Doumbia, L. Sandberger, K. Camara & F. Gbêmou; ZMB 90054 (field #: S4- Dian 91), adult male, Guinea, Diandian Missidé, 10°59′10.356”N, 13°47′44.556”W, 3 October 2016, leg. J. Doumbia & K. Camara; ZMB 90055 (field #: Ban _0362), adult female, Guinea, Banco, 8°31′6.312”N, 8°56′15.864”W, 17 May 2019, leg. J. Doumbia & K. Camara; ZMB 90056 (field #: G009), adult female, Liberia, Gangra, 7°33′47.556”N, 8°38′15.144”W, 14 January 2009, leg. J. Doumbia, K. Camara & A. T. Johnson; ZMB 90057 (field #: Wata 2_0201), adult female, Guinea, Wataférédou, 8°39′15.192”N, 8°51′11.196”W, 8 May 2019, leg. J. Doumbia & K. Camara; ZMB 90059 (field #: G003), subadult female, Liberia, Gangra, 7°32′40.992”N, 8°37′35.58”W, 12 January 2009, leg. J. Doumbia, K. Camara & A. T. Johnson; ZMB 90060 (field #: G009), adult male, Liberia, Gangra, 7°33′47.556”N, 8°38′15.144”W, 14 January 2009, leg. J. Doumbia, K. Camara & A. T. Johnson; ZMB 90062 (field #: Obay _0548), adult male, Liberia, Obayanmai, 8°8′59.82”N, 9°52′49.764”W, 7 April 2019, leg. J. Doumbia, K. Camara, F. Gbêmou & F. B. Beyan; ZMB 90063 (field #: Obay _0611), adult male, Liberia, Obayanmai, 8°8′56.04”N, 9°52′26.436”W, 9 April 2019, leg. J. Doumbia, K. Camara, F. Gbêmou & F.B. Beyan; ZMB 90159 (field #: PG.L.15/040), adult female, near Bouaflé, Ivory Coast, 7°0′15.1488”N, 5°34′37.0344”W, 7 May 2015, leg. J. Penner & N.L. Gonwouo; ZMB 90161 (field #: PG.L.13 033), subadult female, Liberia, Dugbe, 5°5′15”N, 8°36′29.88”W, 26 August 2013, leg. J. Penner & N.L. Gonwouo; ZMB 90162 (field #: PG.L.13 109), adult male, Liberia, Dugbe, 5°8′40.92”N, 8°29′57.12”W, 3 September 2013, leg. J. Penner & N.L. Gonwouo; ZMB 90163 (field #: LI10 014), adult male, Liberia, Tokadeh, 7°26′40.704”N, 8°39′27.972”W, 11 November 2010, leg. J. Penner; ZMB 90164 (field #: PG.L.13 054), adult female, Liberia, Dugbe, 5°4′20.28”N, 8°33′23.76”W, 28 August 2013, leg. J. Penner & N.L. Gonwouo; ZMB 90165 (field #: LI10 121), adult male, Liberia Tokadeh, 7°27′52.164”N, 8°39′53.928”W, 27 November 2010, leg. J. Penner; ZMB 90166 (field #: LI10 114), adult male, Liberia, Eastern Nimba Nature Reserve, 7°29′3.264”N, 8°34′36.264”W, 26 November 2010, leg. J. Penner; ZMB 90167 (field #: LI10 136), adult male, Liberia, Geipa, 7°28′59.196”N, 8°32′13.344”W, 3 December 2010, leg. J. Penner; ZMB 90168 (field #: PG.L.13 188, adult male, Liberia, Dugbe, 5°5′45”N, 8°29′32.64”W, 13 September 2013, leg. J. Penner & N.L. Gonwouo; ZMB 90169 (field #: LI10 120, adult female, Liberia, Eastern Nimba Nature Reserve, 7°29′3.264”N, 8°34′36.264”W, 28 November 2010, leg. J. Penner. Diagnosis. Amnirana parva sp. nov. differs from other West African Amnirana genetically, morphologically, and acoustically. The uncorrected pairwise-divergence in 16S ribosomal RNA between the new species and its closest congener, A. fonensis, is 5.8%. The new species can be distinguished from A. fonensis by several morphological traits in male specimens. SVL of male A. parva sp. nov. (41.9–50.4 mm) is smaller than in A. fonensis (48.7–65.3 mm). Area of humeral gland is smaller in A. parva sp. nov. (3.7–14.8 mm 2) than in A. fonensis (13.5–26.4 mm 2) as well. Males of A. occidentalis and A. galamensis reach larger SVL (67 and up to 80 mm, respectively; females of these species reach 96 and 86 mm, respectively), have differing color pattern and completely smooth dorsal skin (R̂del & Bangoura 2004; Channing & R̂del 2019). Most males of A. parva sp. nov. have dark spots on the dorsum. Breeding males of A. fonensis differ by a yellow dorsal coloration. The ranges of two Central African Amnirana species that are morphologically similar to A. parva sp. nov., A. albolabris (comprising various lineages, see Jongsma 2018) and A. asperrima (Perret, 1977), do not overlap with the new species. Nominotypical A. albolabris from Central Africa show a larger body size in males (Perret 1977 reports 44–57 mm SVL for A. albolabris from Cameroon). Amnirana asperrima can also be distinguished by both its larger adult body size (SVL of males: 46.7–60.1 mm) and the texture of its dorsal skin, which is densely covered with tiny spines. Other Central African Amnirana species show distinct morphological traits and cannot be confused with Amnirana parva sp. nov.: A. amnicola (Perret, 1977) adults are larger (SVL of males and females: 53–72 mm) and have a more pointed snout; and A. lepus (Andersson, 1903) adults are much larger (SVL: 70–100 mm), have finely granular skin, fully webbed toes, and much longer hind limbs. Last, the new species also differs from populations previously referred to A. longipes (Perret, 1960) that are much larger (SVL 77–87 mm) and have a more robust body and longer hind limbs. Although we follow Jongsma (2018) in recognizing A. longipes as a junior synonym of A. albolabris, we include it here in anticipation that this may be recognized as a valid taxon if one or several lineages of Central African A. albolabris are recognized as distinct species. Description of the holotype. Figs. 5–6; measurements in mm. Adult male with long and slender body, slightly dorsoventrally flattened; snout–vent length 42.9; snout acuminate with rounded tip in dorsal view, narrowly rounded in lateral view; head length 15.8, approximately 27% of SVL; head width 13.6; eye–snout distance 6.7; nostrils directed laterally; nostril closer to the snout (1.7) than to eye (4.7); eye diameter 6.1, slightly larger than tympanum diameter (5.2); interorbital distance 4.3; approximately one third of eye projecting above dorsal margin of head in lateral view; canthus rostralis distinct and sharply protruding; loreal region concave; anterocranial part of upper arm with large protruding gland (3.6 long, 2.0 wide, surface: 7.2 mm 2); long and slender fingers, tips broader than subarticular tubercles, forming discs, reaching 130–200% of finger width, inner metacarapal tubercle large and elongated, outer metacarpal tubercle smaller and more rounded; manual webbing absent; finger formula IIVariation. Measurements (in mm) of all individuals are summarized in Table 5. Overall, the male paratypes were similar to the holotype in external appearance and coloration. Male SVL ranged from 41.9–50.4 (mean ± sd: 45.9 ± 2.9, N= 13). The humeral gland area spanned between 3.7–14.8 mm 2 (9.4 ± 2.7 mm 2, N= 13). Female SVL ranged from 53.6–75.6 (63.9 ± 7.8, N= 10) thus markedly exceeding male SVL (Fig. 7). Seven of 13 showed slightly more extended (1-1), and a single male paratype showed slightly less extended webbing (2-2) of the fourth toe. In female paratypes seven of 10 individuals exhibited a webbing formula with slightly more extended webbing on toe IV(1-1). The dorsal skin was covered with small tubercles in all individuals, but females had fewer, smaller, and less spiny tubercles. In some individuals, the skin appeared almost smooth at first sight, but tiny granules were always present upon detailed inspection. The dorsolateral ridge was interrupted in the majority of specimens: females (six of 10) and males (nine of 13). Females showed a brighter brown dorsum and few to no dark spots (see Figs. 6b, 7b, 8e, g, 11c). On the dorsum of males, the ground color varied from chocolate-brown to dark brown and all males had at least some dark spots. The ventral coloration varied greatly among males. Among the paratypes, some had a plain white throat (e.g., ZMB 88549, 87112), similar to the holotype, whereas others exhibited dusty brown speckling covering almost the entire throat (e.g., ZMB 87113). The belly of all males were white to cream, and some individuals had irregular brown spots (e.g., ZMB 87110) that were densest near the legs, throat, or flanks, but were absent at the center of the venter. Females showed some color variation on the venter. In ZMB 87114, the belly and throat were white, whereas ZMB 79253 and ZMB 79197 had a cream-colored belly and a dusty brown speckled throat. Concerning life coloration (Figs. 8, 11), the dorsum exhibited various shades of brown, sometimes with darker spots (especially in males, most females without darker spots). The flanks in males were greenish yellow (Fig. 8f, h) to chocolate brown dorsally (Fig. 8b), usually turning lighter ventrally (but see Fig. 8a). The flanks in females were olive green, turning paler ventrally (Figs. 8c, e, g, 11c), and becoming almost cream-colored towards the belly (then often with some greenish or brownish mottling). The tympanum was brown in both sexes. Males had a narrow green line surrounding the eyes. In both sexes the iris was golden, sometimes with a reddish tinge, with the lower half of the iris being darker. The limbs and dorsum were a similar shade of brown in both sexes. The limbs sometimes were somewhat lighter, but with darker patterning. The number of conspicuous dark transverse bars on the hind limbs varied among individuals (e.g. compare Figs. 8b & 8h). The venter was beige or cream. Both sexes had a light cream or white upper lip, and rarely the anterior part of the lip was brownish (Fig. 8h). Juveniles showed a more contrasting pattern compared to adults. It consisted of a greenish brown dorsum with black spots and an almost black loreal region and flank. The ventral part of the flank and the belly were white with black dots. The juveniles had more conspicuous dark cross bands on the hind limbs and blackish dots on the forelegs; a bright white upper lip, and a bright red iris (uppermost part golden) (Fig. 11f). Acoustics. The advertisement call of Amnirana parva sp. nov. consists of a whiny-voiced croaking sound with ascending frequency modulation from 932 to 1092 Hz (mean ± sd: 1030 ± 86, N= 3). The sound consists of up to five harmonics of which the second-lowest is the dominant one in the first half, the lowest one in the second half (Fig. 4a). The call duration ranges from 0.26– 0.78 s (0.52 ± 0.26, N= 3). Dominant frequency at the beginning of the call ranges from 948–1034 Hz (1004 ± 49, N= 3). All call characteristics are summarized in Table 4. A call description by Schiøtz (1964c) from central Sierra Leone seems to refer to our new species. In that paper, Schiøtz describes three different sections of the call (such a clear distinction of sections was not detected by us). Call duration and complexity, however, seem to increase with the motivation of the frogs (MOR pers. obs.). Schiøtz (1964c) also mentions that these calls were different from those he recorded in Cameroon for A. albolabris, though he did not provide further details. Distribution. Confirmed A. parva sp. nov. records so far are known from western Sierra Leone to southerncentral Ghana, all within the belt of the (former) rainforest zone, bordering the southern humid Guinean savanna (Fig. 9). So far, no confirmed genetic records exist for Ivory Coast. However, morphologically we could assign frogs from the Taï National Park, the Azagny National Park, the Banco National Park, the Haute Dodo, Cavally and Tanoé forest reserves, as well as the Ivorian parts of Mount Nimba to the new species. Other formerly published records of A. albolabris (see literature cited below) from this country from habitats that include primary lowland evergreen and humid but semi-deciduous forest cannot be unambiguously assigned to either A parva sp. nov. or A. fonensis (see below). Life history. It is difficult in many cases to assign previous field observations and literature records to A. parva sp. nov. or A. fonensis. We summarize observations based on confirmed records (morphology and genetics of vouchers, and/or acoustics) as well as records, which originate from primary humid-evergreen rainforest. The latter decision was based on the results of the environmental niche modelling (see below). All observed and collected individuals of A. parva sp. nov. were encountered in closed primary or slightly degraded lowland rainforest, on the banks of or near to small to medium-sized streams (Fig. 10). In Banco National Park, southeastern Ivory Coast, the species was recorded in the forest, forest patches dominated by bamboos, and in man-made ponds of a fish-farm in a forest clearing (Fig. 11a, b). Although we often heard small choruses, Published as part of Griesbaum, Frederic, Jongsma, Gregory F. M., Penner, Johannes, Kouamé, N'Goran Germain, Doumbia, Joseph, Gonwouo, Nono L., Hillers, Annika, Glos, Julian, Blackburn, David C. & Rödel, Mark-Oliver, 2023, The smallest of its kind: Description of a new cryptic Amnirana species (Amphibia, Anura, Ranidae) from West African rainforests, pp. 301-339 in Zootaxa 5254 (3) on pages 309-319, DOI: 10.11646/zootaxa.5254.3.1, http://zenodo.org/record/7727536, {"references":["R ˆ del, M. - O., Bangoura, M. A. & B ˆ hme, W. (2004) The amphibians of south-eastern Republic of Guinea (Amphibia: Gymnophiona, Anura). Herpetozoa, 17, 99 - 118.","Jongsma, G. F., Barej, M. F., Barratt, C. D., Burger, M., Conradie, W., Ernst, R., Greenbaum, E., Hirschfeld, M., Leache, A. D., Penner, J., Portik, D. M., Zassi-Boulou, A. - G., R ˆ del, M. - O. & Blackburn, D. C. (2018) Diversity and biogeography of frogs in the genus Amnirana (Anura: Ranidae) across sub-Saharan Africa. Molecular Phylogenetics and Evolution, 120, 274 - 285. https: // doi. org / 10.1016 / j. ympev. 2017.12.006","Perret, J. - L. (1977) Les Hylarana (Amphibiens, Ranides) du Cameroun. Revue suisse de Zoologie, 84, 841 - 868. https: // doi. org / 10.5962 / bhl. part. 91429","Schiotz, A. (1964 c) The voices of some West African amphibians. Videnskabelige Meddelelser fra dansk Naturhistorik Forening, 127, 35 - 83.","Lamotte, M., Lauwarier, G. & Perret, J. - L. (1957) Contribution a l'etude des batraciens de l'Ouest Africain V. - Le developpement larvaires de Rana (Hylarana) albolabris. Bulletin de l'Institut fondamental d'Afrique Noire, Ser. A, 19, 1312 - 1327.","Guibe, J. & Lamotte, M. (1958) La reserve naturelle integrale du Mont Nimba. XII. Batraciens (sauf Arthroleptis, Phrynobatrachus et Hyperolius). Memoires de l'Institut Francais d'Afrique Noire, 53, 241 - 273.","Channing, A., R ˆ del, M. - O. & Channing J. (2012) Tadpoles of Africa. The biology and identification of all known tadpoles in sub-Saharan Africa. Edition Chimaira, Frankfurt am Main, Germany, 402 pp.","McIntyre, P. (1999) Hylarana albolabris, predation. Herpetological Review, 30, 223."]} more...
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- 2023
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158. Amnirana fonensis
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Griesbaum, Frederic, Jongsma, Gregory F. M., Penner, Johannes, Kouamé, N'Goran Germain, Doumbia, Joseph, Gonwouo, Nono L., Hillers, Annika, Glos, Julian, Blackburn, David C., and Rödel, Mark-Oliver
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Amphibia ,Ranidae ,Amnirana fonensis ,Amnirana ,Animalia ,Biodiversity ,Anura ,Chordata ,Taxonomy - Abstract
Redescription of A. fonensis (Rödel & Bangoura, 2004) Figs. 12–14 Holotype. SMNS 11788, adult male, Guinea, Simandou Range, northwest flank of Pic de Fon, 8°36′N, 8°51′W; 6 November 2002, leg. M.A. Bangoura. Paratypes. SMNS 11790, adult male, Guinea, Simandou Range, village situated to the northwest of Pic de Fon, 3 November 2002, leg. M.A. Bangoura; ZFMK 64481–64482, adult males, Guinea, Park National du Haut Niger, November 1996 – February 1997, leg. G. Nikolaus. Referenced specimens. Six males, one female; ZMB 79185 (field #: TI 60, GenBank #: 16S: MG552336), adult female, Sierra Leone, Tingi Hills, 8°52′2.1″N, 10°47′32.1612″W, 4 June 2007, leg. J. Johnny & A. Hillers; ZMB 79203 & 84733 (field #: SI 032–033, GenBank #: 16S: MG552334 & MG552340), two adult males, Guinea, Korombadou, 9°16′49.62″N, 9°6′ 52.0812″W, 5 October 2008, leg. J. Doumbia & A. Hillers; ZMB 79208 (field #: TI 020, GenBank #: 16S: MG552335), adult male, Sierra Leone, Tingi Hills, 8°53′25.44″N, 10°47′24.7812″W, 1 June 2007, leg. J. Johnny & A. Hillers; ZMB 90058 (field #: N044, 09-609), adult male, Guinea, N’Zérékore, 7°35′33.3″N, 8°28′5.4″W, 24 October 2009, leg. J. Doumbia, L. Sandberger, K. Camara & F. Gbêmou; ZMB 90158 (field #: LI10 088), adult male, Liberia, Tokadeh, 7°26′40.704″N, 8°39′27.972″W; 22 November 2010, leg. J. Penner & N.L. Gonwouo; ZMB 90160 (field #: PG.L. 15/041), adult male, Ivory Coast, 7°0′15.1488″N, 5°34′37.0344″W, 7 May 2015, leg. J. Penner & N.L. Gonwouo. For diagnostic differences to A. parva sp. nov., please see the diagnosis of the new species above. Description (based on the type series and seven additional specimens; measurements in mm, see Table 5). Medium-sized, slender frog, SVL of males range from 48.7 to 65.3 (mean ± sd: 57.2 ± 5.2, N= 10); a female measured 68.0; head slightly longer than broad, approximately one third of SVL; snout acuminate with rounded tip in dorsal view, narrowly rounded in lateral view; tympanum diameter around 85% of eye diameter, in two type specimens (SMNS 11788 & 11790) tympanum slightly larger than eye; inter-orbital distance slightly smaller than eye diameter; nostril closer to snout than to eye; canthus rostralis distinct and rounded; loreal region concave; dorsolateral ridge broad and protruding, only two male individuals show slight discontinuities in the posterior third of the ridge; males with large humeral glands on anterocraniad part of upper arms; area of humeral gland spans between 13.5–26.4 mm 2 (20.5 ± 4.86, N= 10); fingers long and thin, without webbing; tips rounded, forming small discs; finger formula: II– d), dark spots on dorsum and bands on hind limbs visible but paler; limbs and yellowish brown; flanks yellow, lighter towards cream belly; lip and throat bright yellow; dorsolateral ridge yellow to reddish brown; tympanum of breeding males with yellow center bordered by pale brown ring; tympanum of females dark or reddish brown (Fig. 13e, f). Acoustics. The advertisement call of male A. fonensis consists of a whiny-voiced croaking sound with an ascending frequency modulation of 548–723 Hz (mean ± sd: 633 ± 87, N= 3). The sound comprises up to five harmonics of which the lowest is the dominant one (see Fig. 4b) and lasts 0.55– 0.92 s (0.7 ± 0.19, N = 3). All call characteristics are summarized in Table 4. Distribution. Amnirana fonensis was described from the Pic de Fon, Simandou Range, and from the Haut Niger National Park, both located in Guinea. Our new records add further localities, including the first records from eastern Sierra Leone, the Nimba Mountains in northern Liberia, and central Ivory Coast. However, we cannot at this point clarify which previous West African records of Amnirana albolabris refer to either A. fonensis or A. parva sp. nov. (but see below). Life history. The observed and collected individuals were found near forest streams. These forests were less humid than in confirmed A. parva sp. nov. records and comprise semi-deciduous and degraded forest fragments (Fig. 14d) surrounded by savanna. Amnirana fonensis males differ from breeding A. parva sp. nov. males, by a bright yellow breeding coloration. Similar yellow breeding color has been reported from many, unrelated frogs across the tropics. In West Africa such color change has been observed in Phrynobatrachus alleni Parker, 1936 (R̂del 2003; Kanga 2021), Sclerophrys maculata (Hallowell, 1854) (Hillers & R̂del 2007) and S. togoensis (Ahl, 1924) (R̂del & Bangoura 2004). Amnirana fonensis breeds in water bodies of different sizes but seems to prefer stagnant or slow-flowing water. In a savanna-like habitat (Foma), males called from inundated patches, well concealed between grasses and reeds. In degraded gallery forests at Wataférédou, males called while floating on the water surface (Fig. 14a), well concealed between roots of trees and shrubs, or between low vegetation at the water edge. One to two males initiated calling and many other males then joined the chorus. Amnirana fonensis called at night as well as during the day. For instance, between 20:35 GMT and 23:00 GMT, we encountered many calling males (N> 100); the peak of calling activity was between 20:40 GMT and 21:30 GMT. Likewise between 14:45 and 16:00 GMT, we observed numerous calling males (N> 70); the peak of calling activity was at 14:57 GMT. In Foma, females attached eggs to grasses emerging from flowing water. After a few hours these eggs became submerged. In Wataférédou, the eggs were deposited between roots of trees and shrubs in the forest streams. The dark brown and yellow eggs were deposited in large clumps (Fig. 14b, c). We counted 809, 1074, and 2017 eggs in three clutches. The egg diameter ranged from 0.9‒2.4 mm (mean ± sd: 2.1 ± 0.42 mm mm; N= 100). We observed aquatic heteropterans (family Nepidae) preying on the eggs. It is likely that the tadpoles described by Lamotte (1957) from the Simandou range, can actually be assigned to A. fonensis. At Wataférédou, where A. fonensis was breeding, the forest stream was regularly polluted by people washing laundry. The edges of this gallery forest were degraded by subsistence farming, and cattle, and cleared for charcoal production and fuelwood., Published as part of Griesbaum, Frederic, Jongsma, Gregory F. M., Penner, Johannes, Kouamé, N'Goran Germain, Doumbia, Joseph, Gonwouo, Nono L., Hillers, Annika, Glos, Julian, Blackburn, David C. & Rödel, Mark-Oliver, 2023, The smallest of its kind: Description of a new cryptic Amnirana species (Amphibia, Anura, Ranidae) from West African rainforests, pp. 301-339 in Zootaxa 5254 (3) on pages 319-322, DOI: 10.11646/zootaxa.5254.3.1, http://zenodo.org/record/7727536, {"references":["Rodel, M. - O. & Bangoura, M. A. (2004) A conservation assessment of amphibians in the Foret Classee du Pic de Fon, Simandou Range, southeastern Republic of Guinea, with the description of a new Amnirana species (Amphibia Anura Ranidae). Tropical Zoology, 17, 201 - 232. https: // doi. org / 10.1080 / 03946975.2004.10531206","R ˆ del, M. - O. (2003) The amphibians of Mont Sangbe National Park, Ivory Coast. Salamandra, 39, 91 - 110.","Kanga, K. P., Kouame, N. G., Zogbasse, P., Gongomin, B. A. - I., Agoh, K. L., Kouame, A. M., Konan, J. C. B. Y. N., Adepo-Gourene, A. B., Gourene, G. & R ˆ del, M. - O. (2021) Amphibian diversity of a West African biodiversity hotspot: an assessment and commented checklist of the batrachofauna of the Ivorian part of the Nimba Mountains. Amphibian and Reptile Conservation, 15 (1) [General Section]: 71 - 107 (e 275).","R ˆ del, M. - O., Bangoura, M. A. & B ˆ hme, W. (2004) The amphibians of south-eastern Republic of Guinea (Amphibia: Gymnophiona, Anura). Herpetozoa, 17, 99 - 118.","Lamotte, M., Lauwarier, G. & Perret, J. - L. (1957) Contribution a l'etude des batraciens de l'Ouest Africain V. - Le developpement larvaires de Rana (Hylarana) albolabris. Bulletin de l'Institut fondamental d'Afrique Noire, Ser. A, 19, 1312 - 1327."]} more...
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- 2023
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159. The smallest of its kind: Description of a new cryptic Amnirana species (Amphibia, Anura, Ranidae) from West African rainforests
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FREDERIC GRIESBAUM, GREGORY F.M. JONGSMA, JOHANNES PENNER, N’GORAN GERMAIN KOUAMÉ, JOSEPH DOUMBIA, NONO L. GONWOUO, ANNIKA HILLERS, JULIAN GLOS, DAVID C. BLACKBURN, and MARK-OLIVER RÖDEL
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Amphibia ,Ranidae ,Animalia ,Animal Science and Zoology ,Biodiversity ,Anura ,Chordata ,Ecology, Evolution, Behavior and Systematics ,Taxonomy - Abstract
The distribution of the White-Lipped Frog Amnirana albolabris was long assumed to extend from eastern-central to western African rainforests. However, recent molecular phylogenetic analyses revealed that this taxon likely represents several undescribed species. Because the name-bearing types were collected in Gabon, the distantly related West African populations clearly represent an undescribed species that partly occurs in sympatry with Amnirana fonensis. Based on an integrative taxonomic approach, including molecular, morphological, and acoustic data, we describe the ‘albolabris’ populations from the Upper Guinean Forest Zone as a new species, and redescribe the morphologically similar A. fonensis on the bases of a larger series of genotyped individuals, including the first known females. We also provide new biological information for A. fonensis, including their advertisement call, habitat, and reproductive data. The new species is sister to A. fonensis and the two species differ by 5.8% in the mitochondrial 16S ribosomal RNA gene. Morphologically, males of the new species are smaller and have relatively smaller humeral glands. Females of the new species seem to have shorter legs than A. fonensis. In comparison to A. fonensis, the advertisement call of the new species has a higher dominant frequency and more pronounced frequency modulation. The two species differ in their distribution and habitat preferences, as revealed by environmental niche modelling. Whereas the new species is restricted to the Upper Guinean forests and thus is a true lowland-rainforest inhabitant, A. fonensis lives predominantly in Guinean montane forests in the forest-savanna mosaic zone. more...
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- 2023
160. Local beamforming and back-projection of induced earthquakes in Helsinki, southern Finland
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Bo Li, Alice-Agnes Gabriel, and Gregor Hillers
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SeisSol ,point source simulation - Abstract
Seismic array processing is routinely used to infer detailed earthquake properties of intermediate and large events, however, the source properties of microseismicity often remain elusive. In this study, we use high signal-to-noise ratio seismograms of 204 earthquakes induced by the 6 km deep 2018 Espoo/Helsinki geothermal stimulation to evaluate the capabilities of beamforming and back-projection array methods. We show that mini array beamforming is sensitive to medium heterogeneity and requires calibration to mitigate systematic slowness biases.A combined and wave back-projection approach significantly improves depth resolution, reducing offsets to catalogue locations from km to m. Supported by numerical experiments, we demonstrate that back-projection swimming patterns can constrain focal mechanisms. Our results imply that back-projection of data collected over a wide azimuthal range can be used to monitor and characterize local-scale microseismicity, whereas beamforming calibration requires independently obtained reference observations. more...
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- 2023
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161. De novogenome assemblies reveal structural variations between laboratory and natural isolates ofC. elegans
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Zachary D. Bush, Alice F. S. Naftaly, Devin Dinwiddie, Cora Albers, Kenneth J. Hillers, and Diana E. Libuda
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High quality reference genomes are vital to study the impact of sequence variation on genome structure and function. Recent advancements in long-read sequencing have greatly improved the quality ofde novogenome assemblies and enhanced the detection of sequence variants at the scale of hundreds or thousands of bases. The nematodeCaenorhabditis elegansis a powerful model system for both genetic and evolutionary studies. Comparisons between two diverged wild isolates, the Bristol and Hawaiian strains, have been widely utilized in the analysis of small genetic structural variations inC. elegans. The reference genomes most widely used for these isolates were assembled using short read sequencing, which makes the detection of large structural variations challenging. To comprehensively detect both large and small structural variations as well as sequence divergence in the Hawaiian and BristolC. elegansisolates, we generatedde novogenome assemblies for each strain using both long- and short-read sequencing. With these assemblies, we annotate over 3.1Mb of sequence divergence between the Bristol and Hawaiian isolates: 337,584 SNPs, 94,503 small insertion-deletions (50bp). By comparing ourde novogenome assembly of the Bristol isolate to the VC2010 Bristol assembly, we also reveal that lab lineages display 1,162 SNPs, 1,528 indels, as well as 897 structural variations-over 2Mb of total variation. Our work highlights both the importance of using long-read sequencing inde novogenome assembly to identify the total genetic variation between strains and the underappreciated impact of long-term laboratory cultivation on genome structure. more...
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- 2023
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162. Seismic surface wave focal spot imaging: numerical resolution experiments
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Bruno Giammarinaro, Christina Tsarsitalidou, Gregor Hillers, Julien de Rosny, Léonard Seydoux, Stefan Catheline, Michel Campillo, Philippe Roux, Institut Langevin - Ondes et Images (UMR7587) (IL), Ecole Superieure de Physique et de Chimie Industrielles de la Ville de Paris (ESPCI Paris), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Institut de Physique du Globe de Paris (IPGP (UMR_7154)), Institut national des sciences de l'Univers (INSU - CNRS)-Université de La Réunion (UR)-Institut de Physique du Globe de Paris (IPG Paris)-Centre National de la Recherche Scientifique (CNRS)-Université Paris Cité (UPCité), Institut National de la Santé et de la Recherche Médicale (INSERM), Institut des Sciences de la Terre (ISTerre), Institut national des sciences de l'Univers (INSU - CNRS)-Institut de recherche pour le développement [IRD] : UR219-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Université Gustave Eiffel-Université Grenoble Alpes (UGA), ANR-19-P3IA-0003,MIAI,MIAI @ Grenoble Alpes(2019), Institute of Seismology, Department of Geosciences and Geography, and Helsinki Institute of Urban and Regional Studies (Urbaria) more...
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1171 Geosciences ,FAULT ZONE ,Wave propagation ,Seismic noise ,RETRIEVAL ,Refocusing ,Seismic interferometry ,Surface waves ,114 Physical sciences ,GREENS-FUNCTION ,NOISE CORRELATION ,WESTERN ,Body waves ,Geophysics ,Geochemistry and Petrology ,Numerical modelling ,[SDU]Sciences of the Universe [physics] ,TOMOGRAPHY ,CROSS-CORRELATION ,Focal spot ,ARRAY ,Surface waves and free oscillations ,PASSIVE ELASTOGRAPHY ,CRUSTAL STRUCTURE - Abstract
SUMMARY Numerical experiments of seismic wave propagation in a laterally homogeneous layered medium explore subsurface imaging at subwavelength distances for dense seismic arrays. We choose a time-reversal approach to simulate fundamental mode Rayleigh surface wavefields that are equivalent to the cross-correlation results of three-component ambient seismic field records. We demonstrate that the synthesized 2-D spatial autocorrelation fields in the time domain support local or so-called focal spot imaging. Systematic tests involving clean isotropic surface wavefields but also interfering body wave components and anisotropic incidence assess the accuracy of the phase velocity and dispersion estimates obtained from focal spot properties. The results suggest that data collected within half a wavelength around the origin is usually sufficient to constrain the used Bessel functions models. Generally, the cleaner the surface wavefield the smaller the fitting distances that can be used to accurately estimate the local Rayleigh wave speed. Using models based on isotropic surface wave propagation we find that phase velocity estimates from vertical–radial component data are less biased by P-wave energy compared to estimates obtained from vertical–vertical component data, that even strong anisotropic surface wave incidence yields phase velocity estimates with an accuracy of 1 per cent or better, and that dispersion can be studied in the presence of noise. Estimates using a model to resolve potential medium anisotropy are significantly biased by anisotropic surface wave incidence. The overall accurate results obtained from near-field measurements using isotropic medium assumptions imply that dense array seismic Rayleigh wave focal spot imaging can increase the depth sensitivity compared to ambient noise surface wave tomography. The analogy to elastography focal spot medical imaging implies that a high station density and clean surface wavefields support subwavelength resolution of lateral medium variations. more...
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- 2023
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163. Array-derived rocking and vertical ground motion scaling relations from seismicity induced by the 2018 Espoo/Helsinki geothermal stimulation
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Sadeghi-Bagherabadi, A. and Hillers, G.
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The observation of ground motions excited by induced earthquakes near urban areas is of significant engineering importance. During the 2018 geothermal stimulation in the Otaniemi district of Helsinki, Finland, five seismic arrays consisting of 3 to 25 three-component geophones were deployed with interstation distances of 50 meters to record ground motions of 6-km deep induced events. This dataset provides an opportunity to study the ground motion patterns in the low-attenuation environment of the Fennoscandian Shield. The translational seismograms are used to calculate rotational motion for ~400 events with local magnitudes ranging from -0.5 to 1.8 using the seismogeodetic method. We evaluate the relationship between array-derived ground rocking rate (GRR) and vertical ground acceleration (VGA) associated with direct body waves. The robustness of the GRR estimates in the 2-15 Hz frequency range are assessed by comparing the VGA waveforms to the GRRs from the full arrays and to the GRRs from subarrays with different wavelength-to-aperture ratios. By rotating the two perpendicular components of the GRRs, we obtained the radial-transverse coordinate system that minimizes the GRR values on the radial component. We, find different P- and S-wave propagation directions that deviate from the theoretical back-azimuth of the earthquakes, and variations in the apparent body wave velocities beneath the arrays that we attribute to local propagation effects. While the deployment of broadband rotational sensors for wavefield gradiometry analyses is anticipated to become a common practice in the near future, this study provides a low-tech and band-limited experimental verification of the theoretical scaling models., The 28th IUGG General Assembly (IUGG2023) (Berlin 2023) more...
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- 2023
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164. A Night of Storytelling and Years in the 'Z-Closet': The Re-discovery and Restoration of "Oidhche Sheanchais", Robert Flaherty's 'Lost' Irish Folklore Film
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Sumner, Natasha, Hillers, Barbara, and McKenna, Catherine
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- 2015
165. Life in the spray zone – overlooked diversity in West African torrent-frogs (Anura, Odontobatrachidae, Odontobatrachus)
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Michael Barej, Andreas Schmitz, Johannes Penner, Joseph Doumbia, Laura Sandberger-Loua, Mareike Hirschfeld, Christian Brede, Mike Emmrich, N’Goran Germain Kouamé, Annika Hillers, Nono Legrand Gonwouo, Joachim Nopper, Patrick Joel Adeba, Mohamed Alhassane Bangoura, Ceri Gage, Gail Anderson, and Mark-Oliver Rödel more...
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Biology (General) ,QH301-705.5 - Abstract
West African torrent-frogs of the genus Odontobatrachus currently belong to a single species: Odontobatrachus natator (Boulenger, 1905). Recently, molecular results and biogeographic separation led to the recognition of five Operational Taxonomic Units (OTUs) thus identifying a species-complex. Based on these insights, morphological analyses on more than 150 adult specimens, covering the entire distribution of the family and all OTUs, were carried out. Despite strong morphological congruence, combinations of morphological characters made the differentiation of OTUs successful and allowed the recognition of five distinct species: Odontobatrachus natator, and four species new to science: Odontobatrachus arndti sp. n., O. fouta sp. n., O. smithi sp. n. and O. ziama sp. n. All species occur in parapatry: Odontobatrachus natator is known from western Guinea to eastern Liberia, O. ziama sp. n. from eastern Guinea, O. smithi sp. n. and O. fouta sp. n. from western Guinea, O. arndti sp. n. from the border triangle Guinea-Liberia-Côte d’Ivoire. In addition, for the first time the advertisement call of a West African torrent-frog (O. arndti sp. n.) is described. more...
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- 2015
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166. YDE-Fix: design, simulation and testing of a 1:3 scaled model of a remotelY towed operateD vehiclE for coastal area research of marine traffic emissions
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Michaela Gerriets, Thomas H. Badewien, Rasmus Hohmann, Nick Russmeier, Laurin Rosemeier, Jann Strybny, Julius Zielke, Gregor Schellenberger, and Kai Hillers
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- 2022
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167. YDE-Fix: design, simulation and testing of a 1:3 scaled model of a remotelY towed operateD vehiclE for coastal area research of marine traffic emissions
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Gerriets, Michaela, primary, Badewien, Thomas H., additional, Hohmann, Rasmus, additional, Russmeier, Nick, additional, Rosemeier, Laurin, additional, Strybny, Jann, additional, Zielke, Julius, additional, Schellenberger, Gregor, additional, and Hillers, Kai, additional more...
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- 2022
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168. On the temporal stability of the coda of ambient noise correlations
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Colombi, Andrea, Chaput, Julien, Brenguier, Florent, Hillers, Gregor, Roux, Philippe, and Campillo, Michel
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- 2014
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169. Preparing for CO2 storage in the Arctic – Assessing background seismic activity and noise characteristics at the CO2 Lab site, Svalbard
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Kühn, D., Oye, V., Albaric, J., Harris, D., Hillers, G., Braathen, A., and Olaussen, S.
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- 2014
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170. Co-limitation towards lower latitudes shapes global forest diversity gradients
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Jingjing Liang, Javier G. P. Gamarra, Nicolas Picard, Mo Zhou, Bryan Pijanowski, Douglass F. Jacobs, Peter B. Reich, Thomas W. Crowther, Gert-Jan Nabuurs, Sergio de-Miguel, Jingyun Fang, Christopher W. Woodall, Jens-Christian Svenning, Tommaso Jucker, Jean-Francois Bastin, Susan K. Wiser, Ferry Slik, Bruno Hérault, Giorgio Alberti, Gunnar Keppel, Geerten M. Hengeveld, Pierre L. Ibisch, Carlos A. Silva, Hans ter Steege, Pablo L. Peri, David A. Coomes, Eric B. Searle, Klaus von Gadow, Bogdan Jaroszewicz, Akane O. Abbasi, Meinrad Abegg, Yves C. Adou Yao, Jesús Aguirre-Gutiérrez, Angelica M. Almeyda Zambrano, Jan Altman, Esteban Alvarez-Dávila, Juan Gabriel Álvarez-González, Luciana F. Alves, Bienvenu H. K. Amani, Christian A. Amani, Christian Ammer, Bhely Angoboy Ilondea, Clara Antón-Fernández, Valerio Avitabile, Gerardo A. Aymard, Akomian F. Azihou, Johan A. Baard, Timothy R. Baker, Radomir Balazy, Meredith L. Bastian, Rodrigue Batumike, Marijn Bauters, Hans Beeckman, Nithanel Mikael Hendrik Benu, Robert Bitariho, Pascal Boeckx, Jan Bogaert, Frans Bongers, Olivier Bouriaud, Pedro H. S. Brancalion, Susanne Brandl, Francis Q. Brearley, Jaime Briseno-Reyes, Eben N. Broadbent, Helge Bruelheide, Erwin Bulte, Ann Christine Catlin, Roberto Cazzolla Gatti, Ricardo G. César, Han Y. H. Chen, Chelsea Chisholm, Emil Cienciala, Gabriel D. Colletta, José Javier Corral-Rivas, Anibal Cuchietti, Aida Cuni-Sanchez, Javid A. Dar, Selvadurai Dayanandan, Thales de Haulleville, Mathieu Decuyper, Sylvain Delabye, Géraldine Derroire, Ben DeVries, John Diisi, Tran Van Do, Jiri Dolezal, Aurélie Dourdain, Graham P. Durrheim, Nestor Laurier Engone Obiang, Corneille E. N. Ewango, Teresa J. Eyre, Tom M. Fayle, Lethicia Flavine N. Feunang, Leena Finér, Markus Fischer, Jonas Fridman, Lorenzo Frizzera, André L. de Gasper, Damiano Gianelle, Henry B. Glick, Maria Socorro Gonzalez-Elizondo, Lev Gorenstein, Richard Habonayo, Olivier J. Hardy, David J. Harris, Andrew Hector, Andreas Hemp, Martin Herold, Annika Hillers, Wannes Hubau, Thomas Ibanez, Nobuo Imai, Gerard Imani, Andrzej M. Jagodzinski, Stepan Janecek, Vivian Kvist Johannsen, Carlos A. Joly, Blaise Jumbam, Banoho L. P. R. Kabelong, Goytom Abraha Kahsay, Viktor Karminov, Kuswata Kartawinata, Justin N. Kassi, Elizabeth Kearsley, Deborah K. Kennard, Sebastian Kepfer-Rojas, Mohammed Latif Khan, John N. Kigomo, Hyun Seok Kim, Carine Klauberg, Yannick Klomberg, Henn Korjus, Subashree Kothandaraman, Florian Kraxner, Amit Kumar, Relawan Kuswandi, Mait Lang, Michael J. Lawes, Rodrigo V. Leite, Geoffrey Lentner, Simon L. Lewis, Moses B. Libalah, Janvier Lisingo, Pablito Marcelo López-Serrano, Huicui Lu, Natalia V. Lukina, Anne Mette Lykke, Vincent Maicher, Brian S. Maitner, Eric Marcon, Andrew R. Marshall, Emanuel H. Martin, Olga Martynenko, Faustin M. Mbayu, Musingo T. E. Mbuvi, Jorge A. Meave, Cory Merow, Stanislaw Miscicki, Vanessa S. Moreno, Albert Morera, Sharif A. Mukul, Jörg C. Müller, Agustinus Murdjoko, Maria Guadalupe Nava-Miranda, Litonga Elias Ndive, Victor J. Neldner, Radovan V. Nevenic, Louis N. Nforbelie, Michael L. Ngoh, Anny E. N’Guessan, Michael R. Ngugi, Alain S. K. Ngute, Emile Narcisse N. Njila, Melanie C. Nyako, Thomas O. Ochuodho, Jacek Oleksyn, Alain Paquette, Elena I. Parfenova, Minjee Park, Marc Parren, Narayanaswamy Parthasarathy, Sebastian Pfautsch, Oliver L. Phillips, Maria T. F. Piedade, Daniel Piotto, Martina Pollastrini, Lourens Poorter, John R. Poulsen, Axel Dalberg Poulsen, Hans Pretzsch, Mirco Rodeghiero, Samir G. Rolim, Francesco Rovero, Ervan Rutishauser, Khosro Sagheb-Talebi, Purabi Saikia, Moses Nsanyi Sainge, Christian Salas-Eljatib, Antonello Salis, Peter Schall, Dmitry Schepaschenko, Michael Scherer-Lorenzen, Bernhard Schmid, Jochen Schöngart, Vladimír Šebeň, Giacomo Sellan, Federico Selvi, Josep M. Serra-Diaz, Douglas Sheil, Anatoly Z. Shvidenko, Plinio Sist, Alexandre F. Souza, Krzysztof J. Stereńczak, Martin J. P. Sullivan, Somaiah Sundarapandian, Miroslav Svoboda, Mike D. Swaine, Natalia Targhetta, Nadja Tchebakova, Liam A. Trethowan, Robert Tropek, John Tshibamba Mukendi, Peter Mbanda Umunay, Vladimir A. Usoltsev, Gaia Vaglio Laurin, Riccardo Valentini, Fernando Valladares, Fons van der Plas, Daniel José Vega-Nieva, Hans Verbeeck, Helder Viana, Alexander C. Vibrans, Simone A. Vieira, Jason Vleminckx, Catherine E. Waite, Hua-Feng Wang, Eric Katembo Wasingya, Chemuku Wekesa, Bertil Westerlund, Florian Wittmann, Verginia Wortel, Tomasz Zawiła-Niedźwiecki, Chunyu Zhang, Xiuhai Zhao, Jun Zhu, Xiao Zhu, Zhi-Xin Zhu, Irie C. Zo-Bi, Cang Hui, Liang, Jingjing, Gamarra, Javier GP, Picard, Nicolas, Zhou, Mo, Keppel, Gunnar, Hui, Cang, Liang J., Gamarra J.G.P., Picard N., Zhou M., Pijanowski B., Jacobs D.F., Reich P.B., Crowther T.W., Nabuurs G.-J., de-Miguel S., Fang J., Woodall C.W., Svenning J.-C., Jucker T., Bastin J.-F., Wiser S.K., Slik F., Herault B., Alberti G., Keppel G., Hengeveld G.M., Ibisch P.L., Silva C.A., ter Steege H., Peri P.L., Coomes D.A., Searle E.B., von Gadow K., Jaroszewicz B., Abbasi A.O., Abegg M., Yao Y.C.A., Aguirre-Gutierrez J., Zambrano A.M.A., Altman J., Alvarez-Davila E., Alvarez-Gonzalez J.G., Alves L.F., Amani B.H.K., Amani C.A., Ammer C., Ilondea B.A., Anton-Fernandez C., Avitabile V., Aymard G.A., Azihou A.F., Baard J.A., Baker T.R., Balazy R., Bastian M.L., Batumike R., Bauters M., Beeckman H., Benu N.M.H., Bitariho R., Boeckx P., Bogaert J., Bongers F., Bouriaud O., Brancalion P.H.S., Brandl S., Brearley F.Q., Briseno-Reyes J., Broadbent E.N., Bruelheide H., Bulte E., Catlin A.C., Cazzolla Gatti R., Cesar R.G., Chen H.Y.H., Chisholm C., Cienciala E., Colletta G.D., Corral-Rivas J.J., Cuchietti A., Cuni-Sanchez A., Dar J.A., Dayanandan S., de Haulleville T., Decuyper M., Delabye S., Derroire G., DeVries B., Diisi J., Do T.V., Dolezal J., Dourdain A., Durrheim G.P., Obiang N.L.E., Ewango C.E.N., Eyre T.J., Fayle T.M., Feunang L.F.N., Finer L., Fischer M., Fridman J., Frizzera L., de Gasper A.L., Gianelle D., Glick H.B., Gonzalez-Elizondo M.S., Gorenstein L., Habonayo R., Hardy O.J., Harris D.J., Hector A., Hemp A., Herold M., Hillers A., Hubau W., Ibanez T., Imai N., Imani G., Jagodzinski A.M., Janecek S., Johannsen V.K., Joly C.A., Jumbam B., Kabelong B.L.P.R., Kahsay G.A., Karminov V., Kartawinata K., Kassi J.N., Kearsley E., Kennard D.K., Kepfer-Rojas S., Khan M.L., Kigomo J.N., Kim H.S., Klauberg C., Klomberg Y., Korjus H., Kothandaraman S., Kraxner F., Kumar A., Kuswandi R., Lang M., Lawes M.J., Leite R.V., Lentner G., Lewis S.L., Libalah M.B., Lisingo J., Lopez-Serrano P.M., Lu H., Lukina N.V., Lykke A.M., Maicher V., Maitner B.S., Marcon E., Marshall A.R., Martin E.H., Martynenko O., Mbayu F.M., Mbuvi M.T.E., Meave J.A., Merow C., Miscicki S., Moreno V.S., Morera A., Mukul S.A., Muller J.C., Murdjoko A., Nava-Miranda M.G., Ndive L.E., Neldner V.J., Nevenic R.V., Nforbelie L.N., Ngoh M.L., N'Guessan A.E., Ngugi M.R., Ngute A.S.K., Njila E.N.N., Nyako M.C., Ochuodho T.O., Oleksyn J., Paquette A., Parfenova E.I., Park M., Parren M., Parthasarathy N., Pfautsch S., Phillips O.L., Piedade M.T.F., Piotto D., Pollastrini M., Poorter L., Poulsen J.R., Poulsen A.D., Pretzsch H., Rodeghiero M., Rolim S.G., Rovero F., Rutishauser E., Sagheb-Talebi K., Saikia P., Sainge M.N., Salas-Eljatib C., Salis A., Schall P., Schepaschenko D., Scherer-Lorenzen M., Schmid B., Schongart J., Seben V., Sellan G., Selvi F., Serra-Diaz J.M., Sheil D., Shvidenko A.Z., Sist P., Souza A.F., Sterenczak K.J., Sullivan M.J.P., Sundarapandian S., Svoboda M., Swaine M.D., Targhetta N., Tchebakova N., Trethowan L.A., Tropek R., Mukendi J.T., Umunay P.M., Usoltsev V.A., Vaglio Laurin G., Valentini R., Valladares F., van der Plas F., Vega-Nieva D.J., Verbeeck H., Viana H., Vibrans A.C., Vieira S.A., Vleminckx J., Waite C.E., Wang H.-F., Wasingya E.K., Wekesa C., Westerlund B., Wittmann F., Wortel V., Zawila-Niedzwiecki T., Zhang C., Zhao X., Zhu J., Zhu X., Zhu Z.-X., Zo-Bi I.C., Hui C., Purdue University [West Lafayette], Food and Agriculture Organization of the United Nations [Rome, Italie] (FAO), Groupement d'Interêt Public Ecosystèmes Forestiers GIP ECOFOR (GIP ECOFOR ), Forêts et Sociétés (UPR Forêts et Sociétés), Centre de Coopération Internationale en Recherche Agronomique pour le Développement (Cirad), Département Environnements et Sociétés (Cirad-ES), Ecologie des forêts de Guyane (UMR ECOFOG), Centre de Coopération Internationale en Recherche Agronomique pour le Développement (Cirad)-AgroParisTech-Université de Guyane (UG)-Centre National de la Recherche Scientifique (CNRS)-Université des Antilles (UA)-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE), Territoires, Environnement, Télédétection et Information Spatiale (UMR TETIS), Centre de Coopération Internationale en Recherche Agronomique pour le Développement (Cirad)-AgroParisTech-Centre National de la Recherche Scientifique (CNRS)-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE), Botanique et Modélisation de l'Architecture des Plantes et des Végétations (UMR AMAP), Centre de Coopération Internationale en Recherche Agronomique pour le Développement (Cirad)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD [France-Sud])-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE)-Université de Montpellier (UM), SILVA (SILVA), AgroParisTech-Université de Lorraine (UL)-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE), Institut National Polytechnique Félix Houphouët-Boigny, and Stellenbosch University more...
- Subjects
Bos- en Landschapsecologie ,WASS ,Plant Ecology and Nature Conservation ,Forests ,[SDV.BID.SPT]Life Sciences [q-bio]/Biodiversity/Systematics, Phylogenetics and taxonomy ,Co-limitation ,Ontwikkelingseconomie ,Forest and Nature Conservation Policy ,Trees ,Soil ,[SDV.EE.ECO]Life Sciences [q-bio]/Ecology, environment/Ecosystems ,Development Economics ,Laboratory of Geo-information Science and Remote Sensing ,Settore BIO/07 - ECOLOGIA ,Life Science ,Laboratorium voor Moleculaire Biologie ,Bos- en Natuurbeleid ,Forest and Landscape Ecology ,Bosecologie en Bosbeheer ,Laboratorium voor Geo-informatiekunde en Remote Sensing ,BIOS Plant Development Systems ,Vegetatie ,Ecology, Evolution, Behavior and Systematics ,biogeography ,biodiversity ,Vegetation ,Ecology ,Biodiversity ,[SDV.BV.BOT]Life Sciences [q-bio]/Vegetal Biology/Botanics ,Latitudinal gradients ,PE&RC ,Forest Ecology and Forest Management ,Bioclimatic dominance ,Biogeography ,LATITUDE ,Plantenecologie en Natuurbeheer ,Vegetatie, Bos- en Landschapsecologie ,Vegetation, Forest and Landscape Ecology ,Laboratory of Molecular Biology ,[SDE.BE]Environmental Sciences/Biodiversity and Ecology ,Corporate Governance & Legal Services ,Tree ,Global LDG - Abstract
The latitudinal diversity gradient (LDG) is one of the most recognized global patterns of species richness exhibited across a wide range of taxa. Numerous hypotheses have been proposed in the past two centuries to explain LDG, but rigorous tests of the drivers of LDGs have been limited by a lack of high-quality global species richness data. Here we produce a high-resolution (0.025° × 0.025°) map of local tree species richness using a global forest inventory database with individual tree information and local biophysical characteristics from ~1.3 million sample plots. We then quantify drivers of local tree species richness patterns across latitudes. Generally, annual mean temperature was a dominant predictor of tree species richness, which is most consistent with the metabolic theory of biodiversity (MTB). However, MTB underestimated LDG in the tropics, where high species richness was also moderated by topographic, soil and anthropogenic factors operating at local scales. Given that local landscape variables operate synergistically with bioclimatic factors in shaping the global LDG pattern, we suggest that MTB be extended to account for co-limitation by subordinate drivers. The team collaboration and manuscript development are supported by the web-based team science platform: science-i.org, with the project number 202205GFB2. We thank the following initiatives, agencies, teams and individuals for data collection and other technical support: the Global Forest Biodiversity Initiative (GFBI) for establishing the data standards and collaborative framework; United States Department of Agriculture, Forest Service, Forest Inventory and Analysis (FIA) Program; University of Alaska Fairbanks; the SODEFOR, Ivory Coast; University Félix Houphouët-Boigny (UFHB, Ivory Coast); the Queensland Herbarium and past Queensland Government Forestry and Natural Resource Management departments and staff for data collection for over seven decades; and the National Forestry Commission of Mexico (CONAFOR). We thank M. Baker (Carbon Tanzania), together with a team of field assistants (Valentine and Lawrence); all persons who made the Third Spanish Forest Inventory possible, especially the main coordinator, J. A. Villanueva (IFN3); the French National Forest Inventory (NFI campaigns (raw data 2005 and following annual surveys, were downloaded by GFBI at https://inventaire-forestier.ign.fr/spip.php?rubrique159; site accessed on 1 January 2015)); the Italian Forest Inventory (NFI campaigns raw data 2005 and following surveys were downloaded by GFBI at https://inventarioforestale.org/; site accessed on 27 April 2019); Swiss National Forest Inventory, Swiss Federal Institute for Forest, Snow and Landscape Research WSL and Federal Office for the Environment FOEN, Switzerland; the Swedish NFI, Department of Forest Resource Management, Swedish University of Agricultural Sciences SLU; the National Research Foundation (NRF) of South Africa (89967 and 109244) and the South African Research Chair Initiative; the Danish National Forestry, Department of Geosciences and Natural Resource Management, UCPH; Coordination for the Improvement of Higher Education Personnel of Brazil (CAPES, grant number 88881.064976/2014-01); R. Ávila and S. van Tuylen, Instituto Nacional de Bosques (INAB), Guatemala, for facilitating Guatemalan data; the National Focal Center for Forest condition monitoring of Serbia (NFC), Institute of Forestry, Belgrade, Serbia; the Thünen Institute of Forest Ecosystems (Germany) for providing National Forest Inventory data; the FAO and the United Nations High Commissioner for Refugees (UNHCR) for undertaking the SAFE (Safe Access to Fuel and Energy) and CBIT-Forest projects; and the Amazon Forest Inventory Network (RAINFOR), the African Tropical Rainforest Observation Network (AfriTRON) and the ForestPlots.net initiative for their contributions from Amazonian and African forests. The Natural Forest plot data collected between January 2009 and March 2014 by the LUCAS programme for the New Zealand Ministry for the Environment are provided by the New Zealand National Vegetation Survey Databank https://nvs.landcareresearch.co.nz/. We thank the International Boreal Forest Research Association (IBFRA); the Forestry Corporation of New South Wales, Australia; the National Forest Directory of the Ministry of Environment and Sustainable Development of the Argentine Republic (MAyDS) for the plot data of the Second National Forest Inventory (INBN2); the National Forestry Authority and Ministry of Water and Environment of Uganda for their National Biomass Survey (NBS) dataset; and the Sabah Biodiversity Council and the staff from Sabah Forest Research Centre. All TEAM data are provided by the Tropical Ecology Assessment and Monitoring (TEAM) Network, a collaboration between Conservation International, the Missouri Botanical Garden, the Smithsonian Institution and the Wildlife Conservation Society, and partially funded by these institutions, the Gordon and Betty Moore Foundation and other donors, with thanks to all current and previous TEAM site manager and other collaborators that helped collect data. We thank the people of the Redidoti, Pierrekondre and Cassipora village who were instrumental in assisting with the collection of data and sharing local knowledge of their forest and the dedicated members of the field crew of Kabo 2012 census. We are also thankful to FAPESC, SFB, FAO and IMA/SC for supporting the IFFSC. This research was supported in part through computational resources provided by Information Technology at Purdue, West Lafayette, Indiana.This work is supported in part by the NASA grant number 12000401 ‘Multi-sensor biodiversity framework developed from bioacoustic and space based sensor platforms’ (J. Liang, B.P.); the USDA National Institute of Food and Agriculture McIntire Stennis projects 1017711 (J. Liang) and 1016676 (M.Z.); the US National Science Foundation Biological Integration Institutes grant NSF‐DBI‐2021898 (P.B.R.); the funding by H2020 VERIFY (contract 776810) and H2020 Resonate (contract 101000574) (G.-J.N.); the TEAM project in Uganda supported by the Moore foundation and Buffett Foundation through Conservation International (CI) and Wildlife Conservation Society (WCS); the Danish Council for Independent Research | Natural Sciences (TREECHANGE, grant 6108- 00078B) and VILLUM FONDEN grant number 16549 (J.-C.S.); the Natural Environment Research Council of the UK (NERC) project NE/T011084/1 awarded to J.A.-G. and NE/S011811/1; ERC Advanced Grant 291585 (‘T-FORCES’) and a Royal Society-Wolfson Research Merit Award (O.L.P.); RAINFOR plots supported by the Gordon and Betty Moore Foundation and the UK Natural Environment Research Council, notably NERC Consortium Grants ‘AMAZONICA’ (NE/F005806/1), ‘TROBIT’ (NE/D005590/1) and ‘BIO-RED’ (NE/N012542/1); CIFOR’s Global Comparative Study on REDD+ funded by the Norwegian Agency for Development Cooperation, the Australian Department of Foreign Affairs and Trade, the European Union, the International Climate Initiative (IKI) of the German Federal Ministry for the Environment, Nature Conservation, Building and Nuclear Safety and the CGIAR Research Program on Forests, Trees and Agroforestry (CRP-FTA) and donors to the CGIAR Fund; AfriTRON network plots funded by the local communities and NERC, ERC, European Union, Royal Society and Leverhume Trust; a grant from the Royal Society and the Natural Environment Research Council, UK (S.L.L.); National Science Foundation CIF21 DIBBs: EI: number 1724728 (A.C.C.); National Natural Science Foundation of China (31800374) and Shandong Provincial Natural Science Foundation (ZR2019BC083) (H.L.). UK NERC Independent Research Fellowship (grant code: NE/S01537X/1) (T.J.); a Serra-Húnter Fellowship provided by the Government of Catalonia (Spain) (S.d.-M.); the Brazilian National Council for Scientific and Technological Development (CNPq, grant 442640/2018-8, CNPq/Prevfogo-Ibama number 33/2018) (C.A.S.); a grant from the Franklinia Foundation (D.A.C.); Russian Science Foundation project number 19-77-300-12 (R.V.); the Takenaka Scholarship Foundation (A.O.A.); the German Research Foundation (DFG), grant number Am 149/16-4 (C.A.); the Romania National Council for Higher Education Funding, CNFIS, project number CNFIS-FDI-2022-0259 (O.B.); Natural Sciences and Engineering Research Council of Canada (RGPIN-2019-05109 and STPGP506284) and the Canadian Foundation for Innovation (36014) (H.Y.H.C.); the project SustES—Adaptation strategies for sustainable ecosystem services and food security under adverse environmental conditions (CZ.02.1.01/0.0/0.0/16_019/0000797) (E.C.); Consejo de Ciencia y Tecnología del estado de Durango (2019-01-155) (J.J.C.-R.); Science and Engineering Research Board (SERB), New Delhi, Government of India (file number PDF/2015/000447)— ‘Assessing the carbon sequestration potential of different forest types in Central India in response to climate change’ (J.A.D.); Investissement d’avenir grant of the ANR (CEBA: ANR-10-LABEX-0025) (G.D.); National Foundation for Science & Technology Development of Vietnam, 106-NN.06-2013.01 (T.V.D.); Queensland government, Department of Environment and Science (T.J.E.); a Czech Science Foundation Standard grant (19-14620S) (T.M.F.); European Union Seventh Framework Program (FP7/2007– 2013) under grant agreement number 265171 (L. Finer, M. Pollastrini, F. Selvi); grants from the Swedish National Forest Inventory, Swedish University of Agricultural Sciences (J.F.); CNPq productivity grant number 311303/2020-0 (A.L.d.G.); DFG grant HE 2719/11-1,2,3; HE 2719/14-1 (A. Hemp); European Union’s Horizon Europe research project OpenEarthMonitor grant number 101059548, CGIAR Fund INIT-32-MItigation and Transformation Initiative for GHG reductions of Agrifood systems RelaTed Emissions (MITIGATE+) (M.H.); General Directorate of the State Forests, Poland (1/07; OR-2717/3/11; OR.271.3.3.2017) and the National Centre for Research and Development, Poland (BIOSTRATEG1/267755/4/NCBR/2015) (A.M.J.); Czech Science Foundation 18-10781 S (S.J.); Danish of Ministry of Environment, the Danish Environmental Protection Agency, Integrated Forest Monitoring Program—NFI (V.K.J.); State of São Paulo Research Foundation/FAPESP as part of the BIOTA/FAPESP Program Project Functional Gradient-PELD/BIOTA-ECOFOR 2003/12595-7 & 2012/51872-5 (C.A.J.); Danish Council for Independent Research—social sciences—grant DFF 6109– 00296 (G.A.K.); Russian Science Foundation project 21-46-07002 for the plot data collected in the Krasnoyarsk region (V.K.); BOLFOR (D.K.K.); Department of Biotechnology, New Delhi, Government of India (grant number BT/PR7928/ NDB/52/9/2006, dated 29 September 2006) (M.L.K.); grant from Kenya Coastal Development Project (KCDP), which was funded by World Bank (J.N.K.); Korea Forest Service (2018113A00-1820-BB01, 2013069A00-1819-AA03, and 2020185D10- 2022-AA02) and Seoul National University Big Data Institute through the Data Science Research Project 2016 (H.S.K.); the Brazilian National Council for Scientific and Technological Development (CNPq, grant 442640/2018-8, CNPq/Prevfogo-Ibama number 33/2018) (C.K.); CSIR, New Delhi, government of India (grant number 38(1318)12/EMR-II, dated: 3 April 2012) (S.K.); Department of Biotechnology, New Delhi, government of India (grant number BT/ PR12899/ NDB/39/506/2015 dated 20 June 2017) (A.K.); Coordination for the Improvement of Higher Education Personnel (CAPES) #88887.463733/2019-00 (R.V.L.); National Natural Science Foundation of China (31800374) (H.L.); project of CEPF RAS ‘Methodological approaches to assessing the structural organization and functioning of forest ecosystems’ (AAAA-A18-118052590019-7) funded by the Ministry of Science and Higher Education of Russia (N.V.L.); Leverhulme Trust grant to Andrew Balmford, Simon Lewis and Jon Lovett (A.R.M.); Russian Science Foundation, project 19-77-30015 for European Russia data processing (O.M.); grant from Kenya Coastal Development Project (KCDP), which was funded by World Bank (M.T.E.M.); the National Centre for Research and Development, Poland (BIOSTRATEG1/267755/4/NCBR/2015) (S.M.); the Secretariat for Universities and of the Ministry of Business and Knowledge of the Government of Catalonia and the European Social Fund (A. Morera); Queensland government, Department of Environment and Science (V.J.N.); Pinnacle Group Cameroon PLC (L.N.N.); Queensland government, Department of Environment and Science (M.R.N.); the Natural Sciences and Engineering Research Council of Canada (RGPIN-2018-05201) (A.P.); the Russian Foundation for Basic Research, project number 20-05-00540 (E.I.P.); European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement number 778322 (H.P.); Science and Engineering Research Board, New Delhi, government of India (grant number YSS/2015/000479, dated 12 January 2016) (P.S.); the Chilean Government research grants Fondecyt number 1191816 and FONDEF number ID19 10421 (C.S.-E.); the Deutsche Forschungsgemeinschaft (DFG) Priority Program 1374 Biodiversity Exploratories (P.S.); European Space Agency projects IFBN (4000114425/15/NL/FF/gp) and CCI Biomass (4000123662/18/I-NB) (D. Schepaschenko); FunDivEUROPE, European Union Seventh Framework Programme (FP7/2007–2013) under grant agreement number 265171 (M.S.-L.); APVV 20-0168 from the Slovak Research and Development Agency (V.S.); Manchester Metropolitan University’s Environmental Science Research Centre (G.S.); the project ‘LIFE+ ForBioSensing PL Comprehensive monitoring of stand dynamics in Białowieża Forest supported with remote sensing techniques’ which is co-funded by the EU Life Plus programme (contract number LIFE13 ENV/PL/000048) and the National Fund for Environmental Protection and Water Management in Poland (contract number 485/2014/WN10/OP-NM-LF/D) (K.J.S.); Global Challenges Research Fund (QR allocation, MMU) (M.J.P.S.); Czech Science Foundation project 21-27454S (M.S.); the Russian Foundation for Basic Research, project number 20-05-00540 (N. Tchebakova); Botanical Research Fund, Coalbourn Trust, Bentham Moxon Trust, Emily Holmes scholarship (L.A.T.); the programmes of the current scientific research of the Botanical Garden of the Ural Branch of Russian Academy of Sciences (V.A.U.); FCT—Portuguese Foundation for Science and Technology—Project UIDB/04033/2020. Inventário Florestal Nacional—ICNF (H. Viana); Grant from Kenya Coastal Development Project (KCDP), which was funded by World Bank (C.W.); grants from the Swedish National Forest Inventory, Swedish University of Agricultural Sciences (B.W.); ATTO project (grant number MCTI-FINEP 1759/10 and BMBF 01LB1001A, 01LK1602F) (F.W.); ReVaTene/ PReSeD-CI 2 is funded by the Education and Research Ministry of Côte d’Ivoire, as part of the Debt Reduction-Development Contracts (C2Ds) managed by IRD (I.C.Z.-B.); the National Research Foundation of South Africa (NRF, grant 89967) (C.H.). The Tropical Plant Exploration Group 70 1 ha plots in Continental Cameroon Mountains are supported by Rufford Small Grant Foundation, UK and 4 ha in Sierra Leone are supported by the Global Challenge Research Fund through Manchester Metropolitan University, UK; the National Geographic Explorer Grant, NGS-53344R-18 (A.C.-S.); University of KwaZulu-Natal Research Office grant (M.J.L.); Universidad Nacional Autónoma de México, Dirección General de Asuntos de Personal Académico, Grant PAPIIT IN-217620 (J.A.M.). Czech Science Foundation project 21-24186M (R.T., S. Delabye). Czech Science Foundation project 20-05840Y, the Czech Ministry of Education, Youth and Sports (LTAUSA19137) and the long-term research development project of the Czech Academy of Sciences no. RVO 67985939 (J.A.). The American Society of Primatologists, the Duke University Graduate School, the L.S.B. Leakey Foundation, the National Science Foundation (grant number 0452995) and the Wenner-Gren Foundation for Anthropological Research (grant number 7330) (M.B.). Research grants from Conselho Nacional de Desenvolvimento Científico e Tecnologico (CNPq, Brazil) (309764/2019; 311303/2020) (A.C.V., A.L.G.). The Project of Sanya Yazhou Bay Science and Technology City (grant number CKJ-JYRC-2022-83) (H.-F.W.). The Ugandan NBS was supported with funds from the Forest Carbon Partnership Facility (FCPF), the Austrian Development Agency (ADC) and FAO. FAO’s UN-REDD Program, together with the project on ‘Native Forests and Community’ Loan BIRF number 8493-AR UNDP ARG/15/004 and the National Program for the Protection of Native Forests under UNDP funded Argentina’s INBN2. more...
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- 2022
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171. Seismic Monitoring of Permafrost in Svalbard, Arctic Norway
- Author
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Isabelle Lecomte, Julie Albaric, Ulrich Polom, Nadège Langet, Dave Harris, Gregor Hillers, Matthias Ohrnberger, Daniela Kühn, Department of Geosciences and Geography, Institute of Seismology, Laboratoire Chrono-environnement - CNRS - UBFC (UMR 6249) (LCE), Université de Franche-Comté (UFC), Université Bourgogne Franche-Comté [COMUE] (UBFC)-Université Bourgogne Franche-Comté [COMUE] (UBFC)-Centre National de la Recherche Scientifique (CNRS), Norwegian Seismic Array (NORSAR), Institut für Geowissenschaften, Universität Potsdam, Deschutes Signal Processing LLC, Maupin, Oregon, Leibniz Institute for Applied Physics, Department of Earth Science, University of Bergen, Institute of Seismology, University of Helsinki, Centre National de la Recherche Scientifique (CNRS)-Université de Franche-Comté (UFC), and Université Bourgogne Franche-Comté [COMUE] (UBFC)-Université Bourgogne Franche-Comté [COMUE] (UBFC) more...
- Subjects
1171 Geosciences ,010504 meteorology & atmospheric sciences ,[SDU.STU.GP]Sciences of the Universe [physics]/Earth Sciences/Geophysics [physics.geo-ph] ,RESIF ,Ambient noise level ,[SDU.STU]Sciences of the Universe [physics]/Earth Sciences ,Seismic noise ,010502 geochemistry & geophysics ,Permafrost ,01 natural sciences ,Physics::Geophysics ,Freezing point ,symbols.namesake ,Geophysics ,Arctic ,13. Climate action ,Seismic array ,symbols ,Shear velocity ,Rayleigh wave ,[SDU.ENVI]Sciences of the Universe [physics]/Continental interfaces, environment ,Geology ,Seismology ,0105 earth and related environmental sciences - Abstract
We analyze data from passive and active seismic experiments conducted in the Adventdalen valley of Svalbard in the Norwegian Arctic. Our objective is to characterize the ambient wavefield of the region and to investigate permafrost dynamics through estimates of seismic velocity variations. We are motivated by a need for early geophysical detection of potentially hazardous changes to permafrost stability. We draw upon several data sources to constrain various aspects of seismic wave propagation in Adventdalen. We use f-k analysis of five years of continuous data from the Spitsbergen seismic array (SPITS) to demonstrate that ambient seismic noise on Svalbard consists of continuously present body waves and intermittent surface waves appearing at regular intervals. A change in wavefield direction accompanies the sudden onset of surface waves when the average temperature rises above the freezing point, suggesting a cryogenic origin. This hypothesis is supported further by our analysis of records from a temporary broadband network, which indicates that the background wavefield is dominated by icequakes. Synthetic Green’s functions calculated from a 3D velocity model match well with empirical Green’s functions constructed from the recorded ambient seismic noise. We use a shallow shear-wave velocity model, obtained from active seismic measurements, to estimate the maximum depth of Rayleigh wave sensitivity to changes in shear velocity to be in the 50–100 m range. We extract seasonal variations in seismic velocities from ambient noise cross-correlation functions computed over three years of SPITS data. We attribute relative velocity variations to changes in the ice content of the shallow (2–4 m depth) permafrost, which is sensitive to seasonal temperature changes. A linear decreasing trend in seismic velocity is observed over the years, most likely due to permafrost warming. more...
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- 2021
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172. Impact of Array Data Flow Analysis on the Design of Energy-Efficient Circuits.
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M. Hillers and Wolfgang Nebel
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- 2006
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173. Impact of Array Data Flow Analysis on the Design of Energy-Efficient Circuits
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Hillers, M., Nebel, W., Hutchison, David, editor, Kanade, Takeo, editor, Kittler, Josef, editor, Kleinberg, Jon M., editor, Mattern, Friedemann, editor, Mitchell, John C., editor, Naor, Moni, editor, Nierstrasz, Oscar, editor, Pandu Rangan, C., editor, Steffen, Bernhard, editor, Sudan, Madhu, editor, Terzopoulos, Demetri, editor, Tygar, Dough, editor, Vardi, Moshe Y., editor, Weikum, Gerhard, editor, Vounckx, Johan, editor, Azemard, Nadine, editor, and Maurine, Philippe, editor more...
- Published
- 2006
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174. Author response for 'Evenness mediates the global relationship between forest productivity and richness'
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null Iris Hordijk, null Daniel S. Maynard, null Simon P. Hart, null Mo Lidong, null Hans ter Steege, null Jingjing Liang, null Sergio de‐Miguel, null Gert‐Jan Nabuurs, null Peter B. Reich, null Meinrad Abegg, null C. Yves Adou Yao, null Giorgio Alberti, null Angelica M. Almeyda Zambrano, null Braulio V. Alvarado, null Alvarez‐Davila Esteban, null Patricia Alvarez‐Loayza, null Luciana F. Alves, null Christian Ammer, null Clara Antón‐Fernández, null Alejandro Araujo‐Murakami, null Luzmila Arroyo, null Valerio Avitabile, null Gerardo A. Aymard C, null Timothy Baker, null Radomir Bałazy, null Olaf Banki, null Jorcely Barroso, null Meredith L. Bastian, null Jean‐Francois Bastin, null Luca Birigazzi, null Philippe Birnbaum, null Robert Bitariho, null Pascal Boeckx, null Frans Bongers, null Olivier Bouriaud, null Pedro H. S. Brancalion, null Susanne Brandl, null Roel Brienen, null Eben N. Broadbent, null Helge Bruelheide, null Filippo Bussotti, null Roberto Cazzolla Gatti, null Ricardo G. César, null Goran Cesljar, null Robin Chazdon, null Han Y. H. Chen, null Chelsea Chisholm, null Emil Cienciala, null Connie J. Clark, null David B. Clark, null Gabriel Colletta, null David Coomes, null Fernando Cornejo Valverde, null Jose J. Corral‐Rivas, null Philip Crim, null Jonathan Cumming, null Selvadurai Dayanandan, null André L. de Gasper, null Mathieu Decuyper, null Géraldine Derroire, null Ben DeVries, null Ilija Djordjevic, null Amaral Iêda, null Aurélie Dourdain, null Engone Obiang Nestor Laurier, null Brian Enquist, null Teresa Eyre, null Adandé Belarmain Fandohan, null Tom M. Fayle, null Leandro V. Ferreira, null Ted R. Feldpausch, null Leena Finér, null Markus Fischer, null Christine Fletcher, null Lorenzo Frizzera, null Javier G. P. Gamarra, null Damiano Gianelle, null Henry B. Glick, null David Harris, null Andrew Hector, null Andreas Hemp, null Geerten Hengeveld, null Bruno Hérault, null John Herbohn, null Annika Hillers, null Eurídice N. Honorio Coronado, null Cang Hui, null Hyunkook Cho, null Thomas Ibanez, null Il Bin Jung, null Nobuo Imai, null Andrzej M. Jagodzinski, null Bogdan Jaroszewicz, null Vivian Johanssen, null Carlos A. Joly, null Tommaso Jucker, null Viktor Karminov, null Kuswata Kartawinata, null Elizabeth Kearsley, null David Kenfack, null Deborah Kennard, null Sebastian Kepfer‐Rojas, null Gunnar Keppel, null Mohammed Latif Khan, null Timothy Killeen, null Kim Hyun Seok, null Kanehiro Kitayama, null Michael Köhl, null Henn Korjus, null Florian Kraxner, null Diana Laarmann, null Mait Lang, null Simon Lewis, null Huicui Lu, null Natalia Lukina, null Brian Maitner, null Yadvinder Malhi, null Eric Marcon, null Beatriz Schwantes Marimon, null Ben Hur Marimon‐Junior, null Andrew Robert Marshall, null Emanuel Martin, null Olga Martynenko, null Jorge A. Meave, null Omar Melo‐Cruz, null Casimiro Mendoza, null Cory Merow, null Miscicki Stanislaw, null Abel Monteagudo Mendoza, null Vanessa Moreno, null Sharif A. Mukul, null Philip Mundhenk, null Maria G. Nava‐Miranda, null David Neill, null Victor Neldner, null Radovan Nevenic, null Michael Ngugi, null Pascal A. Niklaus, null Jacek Oleksyn, null Petr Ontikov, null Edgar Ortiz‐Malavasi, null Yude Pan, null Alain Paquette, null Alexander Parada‐Gutierrez, null Elena Parfenova, null Minjee Park, null Marc Parren, null Narayanaswamy Parthasarathy, null Pablo L. Peri, null Sebastian Pfautsch, null Oliver L. Phillips, null Nicolas Picard, null Maria Teresa Piedade, null Daniel Piotto, null Nigel C. A. Pitman, null Irina Polo, null Lourens Poorter, null Axel Dalberg Poulsen, null John R. Poulsen, null Hans Pretzsch, null Freddy Ramirez Arevalo, null Zorayda Restrepo‐Correa, null Mirco Rodeghiero, null Samir Rolim, null Anand Roopsind, null Francesco Rovero, null Ervan Rutishauser, null Purabi Saikia, null Christian Salas‐Eljatib, null Peter Schall, null Dmitry Schepaschenko, null Michael Scherer‐Lorenzen, null Bernhard Schmid, null Jochen Schöngart, null Eric B. Searle, null Vladimír Šebeň, null Josep M. Serra‐Diaz, null Douglas Sheil, null Anatoly Shvidenko, null Javier Silva‐Espejo, null Marcos Silveira, null James Singh, null Plinio Sist, null Ferry Slik, null Bonaventure Sonké, null Alexandre F. Souza, null Krzysztof Stereńczak, null Jens‐Christian Svenning, null Miroslav Svoboda, null Ben Swanepoel, null Natalia Targhetta, null Nadja Tchebakova, null Raquel Thomas, null Elena Tikhonova, null Peter Umunay, null Vladimir Usoltsev, null Renato Valencia, null Fernando Valladares, null Fons van der Plas, null Do Van Tran, null Michael E. Van Nuland, null Rodolfo Vasquez Martinez, null Hans Verbeeck, null Helder Viana, null Alexander C. Vibrans, null Simone Vieira, null Klaus von Gadow, null Hua‐Feng Wang, null James Watson, null Gijsbert D. A. Werner, null Susan K. Wiser, null Florian Wittmann, null Verginia Wortel, null Roderick Zagt, null Tomasz Zawila‐Niedzwiecki, null Chunyu Zhang, null Xiuhai Zhao, null Mo Zhou, null Zhi‐Xin Zhu, null Irie Casimir Zo‐Bi, and null Thomas W. Crowther more...
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- 2022
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175. Cluster perturbation theory. VII. The convergence of cluster perturbation expansions
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Jeppe Olsen, Andreas Erbs Hillers-Bendtsen, Frederik Ørsted Kjeldal, Nicolai Machholdt Høyer, Kurt V. Mikkelsen, and Poul Jørgensen
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General Physics and Astronomy ,Physical and Theoretical Chemistry - Abstract
The convergence of the recently developed cluster perturbation (CP) expansions [Pawlowski et al., J. Chem. Phys. 150, 134108 (2019)] is analyzed with the double purpose of developing the mathematical tools and concepts needed to describe these expansions at general order and to identify the factors that define the rate of convergence of CP series. To this end, the CP energy, amplitude, and Lagrangian multiplier equations as a function of the perturbation strength are developed. By determining the critical points, defined as the perturbation strengths for which the Jacobian becomes singular, the rate of convergence and the intruder and critical states are determined for five small molecules: BH, CO, H2O, NH3, and HF. To describe the patterns of convergence for these expansions at orders lower than the high-order asymptotic limit, a model is developed where the perturbation corrections arise from two critical points. It is shown that this model allows for rationalization of the behavior of the perturbation corrections at much lower order than required for the onset of the asymptotic convergence. For the H2O, CO, and HF molecules, the pattern and rate of convergence are defined by critical states where the Fock-operator underestimates the excitation energies, whereas the pattern and rate of convergence for BH are defined by critical states where the Fock-operator overestimates the excitation energy. For the NH3 molecule, both forms of critical points are required to describe the convergence behavior up to at least order 25. more...
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- 2022
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176. Cluster perturbation theory. VIII. First order properties for a coupled cluster state
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Andreas Erbs Hillers-Bendtsen, Nicolai Machholdt Høyer, Frederik Ørsted Kjeldal, Kurt V. Mikkelsen, Jeppe Olsen, and Poul Jørgensen
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General Physics and Astronomy ,Physical and Theoretical Chemistry - Abstract
We have extended cluster perturbation (CP) theory to comprehend the calculation of first order properties (FOPs). We have determined CP FOP series where FOPs are determined as a first energy derivative and also where the FOPs are determined as a generalized expectation value of the external perturbation operator over the coupled cluster state and its biorthonormal multiplier state. For S(D) orbital excitation spaces, we find that the CP series for FOPs that are determined as a first derivative, in general, in second order have errors of a few percent in the singles and doubles correlation contribution relative to the targeted coupled cluster (CC) results. For a SD(T) orbital excitation space, we find that the CP series for FOPs determined as a generalized expectation value in second order have errors of about ten percent in the triples correlation contribution relative to the targeted CC results. These second order models, therefore, constitute viable alternatives for determining high quality FOPs. more...
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- 2022
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177. Fulvalene‐Based Polycyclic Aromatic Hydrocarbon Ladder‐Type Structures: Synthesis and Properties
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Mogens Nielsen, Anders Kadziola, Andreas Erbs Hillers-Bendtsen, Kurt V. Mikkelsen, Viktor Bliksted Roug Pedersen, and Jeppe Granhøj
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chemistry.chemical_classification ,Fulvalene ,010405 organic chemistry ,Chemistry ,Graphene ,Organic Chemistry ,Thio ,Polycyclic aromatic hydrocarbon ,General Chemistry ,010402 general chemistry ,Electrochemistry ,01 natural sciences ,Catalysis ,0104 chemical sciences ,law.invention ,chemistry.chemical_compound ,Computational chemistry ,law ,Reagent ,Absorption (chemistry) ,Tetrathiafulvalene - Abstract
Polycyclic aromatic hydrocarbons (PAHs) have found strong interest for their electronic properties and as model systems for graphene. While PAHs have been studied intensively as single units, here PAHs were constructed in ladder-type arrangements using cross-conjugated fulvalene and dithiafulvalene motifs as connecting units and moving forward a convenient synthetic approach for dimerizing (thio)ketones into olefins by the action of Lawesson's reagent. Some of the PAHs can also be regarded as "super-extended" tetrathiafulvalenes (TTFs) with some of the largest cores ever explored, being multi-redox systems that exhibit both reversible oxidations and reductions. Concomitant absorption redshifts were observed when expanding the ladder-type structures from one to two to three indenofluorene units, and optical and electrochemical HOMO-LUMO gaps were found to correlate linearly. Various conformations (and solid-state packing arrangements) were studied by X-ray crystallography and computations. more...
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- 2021
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178. Advancing conservation planning for western chimpanzees using IUCN SSC A.P.E.S.—the case of a taxon-specific database
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Stefanie Heinicke, Roger Mundry, Christophe Boesch, Bala Amarasekaran, Abdulai Barrie, Terry Brncic, David Brugière, Geneviève Campbell, Joana Carvalho, Emmanuel Danquah, Dervla Dowd, Henk Eshuis, Marie-Claire Fleury-Brugière, Joel Gamys, Jessica Ganas, Sylvain Gatti, Laura Ginn, Annemarie Goedmakers, Nicolas Granier, Ilka Herbinger, Annika Hillers, Sorrel Jones, Jessica Junker, Célestin Y Kouakou, Vincent Lapeyre, Vera Leinert, Fiona Maisels, Sergio Marrocoli, Mary Molokwu-Odozi, Paul K N’Goran, Liliana Pacheco, Sébastien Regnaut, Tenekwetche Sop, Els Ton, Joost van Schijndel, Virginie Vergnes, Maria Voigt, Adam Welsh, Erin G Wessling, Elizabeth A Williamson, and Hjalmar S Kühl more...
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species distribution model ,Pan troglodytes verus ,development corridor ,West Africa ,Environmental technology. Sanitary engineering ,TD1-1066 ,Environmental sciences ,GE1-350 ,Science ,Physics ,QC1-999 - Abstract
Even though information on global biodiversity trends becomes increasingly available, large taxonomic and spatial data gaps persist at the scale relevant to planning conservation interventions. This is because data collectors are hesitant to share data with global repositories due to workload, lack of incentives, and perceived risk of losing intellectual property rights. In contrast, due to greater conceptual and methodological proximity, taxon-specific database initiatives can provide more direct benefits to data collectors through research collaborations and shared authorship. The IUCN SSC Ape Populations, Environments and Surveys (A.P.E.S.) database was created in 2005 as a repository for data on great apes and other primate taxa. It aims to acquire field survey data and make different types of data accessible, and provide up-to-date species status information. To support the current update of the conservation action plan for western chimpanzees ( Pan troglodytes verus ) we compiled field surveys for this taxon from IUCN SSC A.P.E.S., 75% of which were unpublished. We used spatial modeling to infer total population size, range-wide density distribution, population connectivity and landscape-scale metrics. We estimated a total abundance of 52 800 (95% CI 17 577–96 564) western chimpanzees, of which only 17% occurred in national parks. We also found that 10% of chimpanzees live within 25 km of four multi-national ‘development corridors’ currently planned for West Africa. These large infrastructure projects aim to promote economic integration and agriculture expansion, but are likely to cause further habitat loss and reduce population connectivity. We close by demonstrating the wealth of conservation-relevant information derivable from a taxon-specific database like IUCN SSC A.P.E.S. and propose that a network of many more such databases could be created to provide the essential information to conservation that can neither be supplied by one-off projects nor by global repositories, and thus are highly complementary to existing initiatives. more...
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- 2019
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179. Modeling Absorption and Emission Spectroscopies of Symmetric and Asymmetric Azaoxahelicenes in Vacuum and Solution
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Hillers-Bendtsen, Andreas Erbs, primary, Todarwal, Yogesh, additional, Pittelkow, Michael, additional, Norman, Patrick, additional, and Mikkelsen, Kurt V., additional
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- 2022
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180. A Written Charm in Oral Tradition: Peter Sat on a Marble Stone in Ireland
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Hillers, Barbara Lisa, primary
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- 2022
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181. Augmented Reality — Helmet for the Manual Welding Process
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Hillers, Bernd, Aiteanu, Dorin, Gräser, Axel, Ong, S. K., editor, and Nee, A. Y. C., editor
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- 2004
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182. Global quieting of high-frequency seismic noise due to COVID-19 pandemic lockdown measures
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Royal Society (UK), German Research Centre for Geosciences, Boğaziçi Üniversity, Netherlands Organization for Scientific Research, Air Force Office of Scientific Research (US), National Science Foundation (US), Consejo Nacional de Ciencia y Tecnología (México), Universidad Nacional Autónoma de México, Agencia Nacional de Investigación y Desarrollo (Chile), Natural Environment Research Council (UK), University of California, Commonwealth Scientific and Industrial Research Organisation (Australia), Belgian Science Policy Office, Fonds National de la Recherche Luxembourg, Lecocq, Thomas [0000-0002-4988-6477], Hicks, Stephen [0000-0002-7476-3284], Noten, Koen Van [0000-0001-8933-4426], Wijk, Kasper van [0000-0003-4994-8030], Plaen, Raphael de [0000-0003-3477-2001], Massin, Frédérick [0000-0002-7532-5139], Hillers, Gregor [0000-0003-2341-1892], Apoloner, Maria-Theresia [0000-0002-4006-1284], Arroyo-Solórzano, Mario [0000-0002-1653-2680], Assink, Jelle [0000-0002-4990-6845], Büyükakpınar, Pinar [0000-0001-8461-674X], Cannata, Andrea [0000-0002-0028-5822], Cannavó, Flavio [0000-0001-7550-8579], Carrasco, Sebastián [0000-0002-6207-8757], Caudron, Corentin [0000-0002-3748-0007], Chaves, Esteban [0000-0002-5724-1513], Cornwell, David G. [0000-0002-9843-7811], Craig, David [0000-0001-9414-1725], Diaz, J. [0000-0003-1801-0541], Donner, Stefanie [0000-0001-7351-8079], Evangelidis, Christos [0000-0001-8733-8984], Evers, Läslo [0000-0003-2825-6211], Fernández, Gonzalo A. [0000-0001-8284-9566], Giannopoulos, Dimitrios [0000-0002-8314-0759], Gibbons, Steven J. [0000-0002-7822-0244], Girona, Társilo [0000-0001-6422-0422], Grecu, Bogdan [0000-0002-7662-996X], Grunberg, Marc [0000-0002-1307-7790], Hetényi, Gyorgy [0000-0001-9036-4761], Horleston, Anna [0000-0002-6748-6522], Inza, Adolfo [0000-0001-5381-9042], Irving, Jessica C. E. [0000-0002-0866-8246], Jamalreyhani, Mohammadreza [0000-0003-4181-7175], Kafka, Alan [0000-0001-6643-1602], Labedz, Celeste [0000-0001-7339-2170], Lindsey, Nathaniel [0000-0001-9522-6683], McKinno, Mika [0000-0002-9274-0377], Megies, Tobias [0000-0002-5033-9921], Miller, Meghan [0000-0001-5494-2296], Minarik, William [0000-0001-5509-5543], Moresi, Louis [0000-0003-3685-174X], Márquez-Ramirez, V. H. [0000-0003-1494-2229], Möllhoff, Martin [0000-0003-1848-1554], Nesbitt, Ian M. [0000-0001-5828-6070], Niyogi, Shankho [0000-0002-8362-4569], Ojeda, Javier [0000-0002-7188-8356], Oth, Adrien [0000-0003-4859-6504], Proud, Simon [0000-0003-3880-6774], Retailleau, Lise [0000-0002-0711-4540], Satriano, Claudio [0000-0002-3039-2530], Savage, Martha [0000-0002-2080-0676], Shani-Kadmiel, Shahar [0000-0003-2215-6164], Sleeman,Reinoud [0000-0002-1928-5056], Sokos, Efthimios [0000-0002-7742-7251], Stott, Alexander [0000-0001-6121-705X], Subedi, Shiba [0000-0002-7009-7333], Sørensen, Mathilde [0000-0002-8589-7480], Taira, Taka'aki [0000-0002-6170-797X], Turhan, Fatih [0000-0003-4612-7421], Pluijm, Ben van der [0000-0001-7737-2791], Vergne, Jérôme [0000-0003-1731-9360], Vuorinen, Tommi A. T. [0000-0002-8186-012X], Warren, Tristram [0000-0003-3877-0046], Wassermann, Joachim [0000-0002-4088-1792], Xiao, Han [0000-0001-8727-8053], Lecocq, Thomas, Hicks, Stephen, Noten, Koen Van, Wijk, Kasper van, Koelemeijer, Paula, Plaen, Raphael de, Massin, Frédérick, Hillers, Gregor, Anthony, Robert E., Apoloner, Maria-Theresia, Arroyo-Solórzano, Mario, Assink, Jelle, Büyükakpınar, Pinar, Cannata, Andrea, Cannavó, Flavio, Carrasco, Sebastián, Caudron, Corentin, Chaves, Esteban, Cornwell, David G., Craig, David, Ouden, Olivier F. C. den, Diaz, J., Donner, Stefanie, Evangelidis, Christos, Evers, Läslo, Fauville, Benoit, Fernández, Gonzalo A., Giannopoulos, Dimitrios, Gibbons, Steven J., Girona, Társilo, Grecu, Bogdan, Grunberg, Marc, Hetényi, Gyorgy, Horleston, Anna, Inza, Adolfo, Irving, Jessica C. E., Jamalreyhani, Mohammadreza, Kafka, Alan, Koymans, Mathijs R., Labedz, Celeste, Larose, Eric, Lindsey, Nathaniel, McKinno, Mika, Megies, Tobias, Miller, Meghan, Minarik, William, Moresi, Louis, Márquez-Ramirez, V. H., Möllhoff, Martin, Nesbitt, Ian M., Niyogi, Shankho, Ojeda, Javier, Oth, Adrien, Proud, Simon, Pulli, Jay, Retailleau, Lise, Rintamäki, Annukka E., Satriano, Claudio, Savage, Martha, Shani-Kadmiel, Shahar, Sleeman,Reinoud, Sokos, Efthimios, Stott, Alexander, Subedi, Shiba, Sørensen, Mathilde, Taira, Taka'aki, Tapia, Mar, Turhan, Fatih, Pluijm, Ben van der, Vergne, Jérôme, Vuorinen, Tommi A. T., Warren, Tristram, Wassermann, Joachim, Xiao, Han, Royal Society (UK), German Research Centre for Geosciences, Boğaziçi Üniversity, Netherlands Organization for Scientific Research, Air Force Office of Scientific Research (US), National Science Foundation (US), Consejo Nacional de Ciencia y Tecnología (México), Universidad Nacional Autónoma de México, Agencia Nacional de Investigación y Desarrollo (Chile), Natural Environment Research Council (UK), University of California, Commonwealth Scientific and Industrial Research Organisation (Australia), Belgian Science Policy Office, Fonds National de la Recherche Luxembourg, Lecocq, Thomas [0000-0002-4988-6477], Hicks, Stephen [0000-0002-7476-3284], Noten, Koen Van [0000-0001-8933-4426], Wijk, Kasper van [0000-0003-4994-8030], Plaen, Raphael de [0000-0003-3477-2001], Massin, Frédérick [0000-0002-7532-5139], Hillers, Gregor [0000-0003-2341-1892], Apoloner, Maria-Theresia [0000-0002-4006-1284], Arroyo-Solórzano, Mario [0000-0002-1653-2680], Assink, Jelle [0000-0002-4990-6845], Büyükakpınar, Pinar [0000-0001-8461-674X], Cannata, Andrea [0000-0002-0028-5822], Cannavó, Flavio [0000-0001-7550-8579], Carrasco, Sebastián [0000-0002-6207-8757], Caudron, Corentin [0000-0002-3748-0007], Chaves, Esteban [0000-0002-5724-1513], Cornwell, David G. [0000-0002-9843-7811], Craig, David [0000-0001-9414-1725], Diaz, J. [0000-0003-1801-0541], Donner, Stefanie [0000-0001-7351-8079], Evangelidis, Christos [0000-0001-8733-8984], Evers, Läslo [0000-0003-2825-6211], Fernández, Gonzalo A. [0000-0001-8284-9566], Giannopoulos, Dimitrios [0000-0002-8314-0759], Gibbons, Steven J. [0000-0002-7822-0244], Girona, Társilo [0000-0001-6422-0422], Grecu, Bogdan [0000-0002-7662-996X], Grunberg, Marc [0000-0002-1307-7790], Hetényi, Gyorgy [0000-0001-9036-4761], Horleston, Anna [0000-0002-6748-6522], Inza, Adolfo [0000-0001-5381-9042], Irving, Jessica C. E. [0000-0002-0866-8246], Jamalreyhani, Mohammadreza [0000-0003-4181-7175], Kafka, Alan [0000-0001-6643-1602], Labedz, Celeste [0000-0001-7339-2170], Lindsey, Nathaniel [0000-0001-9522-6683], McKinno, Mika [0000-0002-9274-0377], Megies, Tobias [0000-0002-5033-9921], Miller, Meghan [0000-0001-5494-2296], Minarik, William [0000-0001-5509-5543], Moresi, Louis [0000-0003-3685-174X], Márquez-Ramirez, V. H. [0000-0003-1494-2229], Möllhoff, Martin [0000-0003-1848-1554], Nesbitt, Ian M. [0000-0001-5828-6070], Niyogi, Shankho [0000-0002-8362-4569], Ojeda, Javier [0000-0002-7188-8356], Oth, Adrien [0000-0003-4859-6504], Proud, Simon [0000-0003-3880-6774], Retailleau, Lise [0000-0002-0711-4540], Satriano, Claudio [0000-0002-3039-2530], Savage, Martha [0000-0002-2080-0676], Shani-Kadmiel, Shahar [0000-0003-2215-6164], Sleeman,Reinoud [0000-0002-1928-5056], Sokos, Efthimios [0000-0002-7742-7251], Stott, Alexander [0000-0001-6121-705X], Subedi, Shiba [0000-0002-7009-7333], Sørensen, Mathilde [0000-0002-8589-7480], Taira, Taka'aki [0000-0002-6170-797X], Turhan, Fatih [0000-0003-4612-7421], Pluijm, Ben van der [0000-0001-7737-2791], Vergne, Jérôme [0000-0003-1731-9360], Vuorinen, Tommi A. T. [0000-0002-8186-012X], Warren, Tristram [0000-0003-3877-0046], Wassermann, Joachim [0000-0002-4088-1792], Xiao, Han [0000-0001-8727-8053], Lecocq, Thomas, Hicks, Stephen, Noten, Koen Van, Wijk, Kasper van, Koelemeijer, Paula, Plaen, Raphael de, Massin, Frédérick, Hillers, Gregor, Anthony, Robert E., Apoloner, Maria-Theresia, Arroyo-Solórzano, Mario, Assink, Jelle, Büyükakpınar, Pinar, Cannata, Andrea, Cannavó, Flavio, Carrasco, Sebastián, Caudron, Corentin, Chaves, Esteban, Cornwell, David G., Craig, David, Ouden, Olivier F. C. den, Diaz, J., Donner, Stefanie, Evangelidis, Christos, Evers, Läslo, Fauville, Benoit, Fernández, Gonzalo A., Giannopoulos, Dimitrios, Gibbons, Steven J., Girona, Társilo, Grecu, Bogdan, Grunberg, Marc, Hetényi, Gyorgy, Horleston, Anna, Inza, Adolfo, Irving, Jessica C. E., Jamalreyhani, Mohammadreza, Kafka, Alan, Koymans, Mathijs R., Labedz, Celeste, Larose, Eric, Lindsey, Nathaniel, McKinno, Mika, Megies, Tobias, Miller, Meghan, Minarik, William, Moresi, Louis, Márquez-Ramirez, V. H., Möllhoff, Martin, Nesbitt, Ian M., Niyogi, Shankho, Ojeda, Javier, Oth, Adrien, Proud, Simon, Pulli, Jay, Retailleau, Lise, Rintamäki, Annukka E., Satriano, Claudio, Savage, Martha, Shani-Kadmiel, Shahar, Sleeman,Reinoud, Sokos, Efthimios, Stott, Alexander, Subedi, Shiba, Sørensen, Mathilde, Taira, Taka'aki, Tapia, Mar, Turhan, Fatih, Pluijm, Ben van der, Vergne, Jérôme, Vuorinen, Tommi A. T., Warren, Tristram, Wassermann, Joachim, and Xiao, Han more...
- Abstract
Human activity causes vibrations that propagate into the ground as high-frequency seismic waves. Measures to mitigate the COVID-19 pandemic caused widespread changes in human activity, leading to a months-long reduction in seismic noise of up to 50%. The 2020 seismic noise quiet period is the longest and most prominent global anthropogenic seismic noise reduction on record. While the reduction is strongest at surface seismometers in populated areas, this seismic quiescence extends for many kilometers radially and hundreds of meters in depth. This provides an opportunity to detect subtle signals from subsurface seismic sources that would have been concealed in noisier times and to benchmark sources of anthropogenic noise. A strong correlation between seismic noise and independent measurements of human mobility suggests that seismology provides an absolute, real-time estimate of population dynamics. more...
- Published
- 2020
183. Massively parallel GPU enabled third-order cluster perturbation excitation energies for cost-effective large scale excitation energy calculations
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Andreas Erbs Hillers-Bendtsen, Dmytro Bykov, Ashleigh Barnes, Dmitry Liakh, Hector H. Corzo, Jeppe Olsen, Poul Jørgensen, and Kurt V. Mikkelsen
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General Physics and Astronomy ,Physical and Theoretical Chemistry - Abstract
We present here a massively parallel implementation of the recently developed CPS(D-3) excitation energy model that is based on cluster perturbation theory. The new algorithm extends the one developed in Baudin et al. [J. Chem. Phys., 150, 134110 (2019)] to leverage multiple nodes and utilize graphical processing units for the acceleration of heavy tensor contractions. Furthermore, we show that the extended algorithm scales efficiently with increasing amounts of computational resources and that the developed code enables CPS(D-3) excitation energy calculations on large molecular systems with a low time-to-solution. More specifically, calculations on systems with over 100 atoms and 1000 basis functions are possible in a few hours of wall clock time. This establishes CPS(D-3) excitation energies as a computationally efficient alternative to those obtained from the coupled-cluster singles and doubles model. more...
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- 2023
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184. The Finnish National Seismic Network: Toward Fully Automated Analysis of Low-Magnitude Seismic Events
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Gregor Hillers, Tommi Vuorinen, Tuija Luhta, Ilmo Elias Salmenperä, Päivi Mäntyniemi, Toni Veikkolainen, Jari Kortström, Timo Tiira, Institute of Seismology, Department of Geosciences and Geography, and Helsinki Institute of Urban and Regional Studies (Urbaria) more...
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1171 Geosciences ,Geophysics ,010504 meteorology & atmospheric sciences ,Fully automated ,Magnitude (mathematics) ,010502 geochemistry & geophysics ,01 natural sciences ,Seismology ,Geology ,0105 earth and related environmental sciences - Abstract
We present an overview of the seismic networks, products, and services in Finland, northern Europe, and the challenges and opportunities associated with the unique combination of prevailing crystalline bedrock, low natural intraplate seismic background activity, and a high level of anthropogenic seismicity. We introduce national and local seismic networks, explain the databases, analysis tools, and data management concepts, outline the Finnish macroseismic service, and showcase data from the 2017 M 3.3 Liminka earthquake in Ostrobothnia, Finland. more...
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- 2021
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185. Promoting the thermal back reaction of vinylheptafulvene to dihydroazulene by physisorbtion on nanoparticles
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Magnus Bukhave Johansen, Kurt V. Mikkelsen, and Andreas Erbs Hillers-Bendtsen
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Materials science ,010405 organic chemistry ,business.industry ,General Physics and Astronomy ,Nanoparticle ,chemistry.chemical_element ,010402 general chemistry ,01 natural sciences ,Copper ,0104 chemical sciences ,Reaction rate constant ,chemistry ,Chemical physics ,Thermal ,Density functional theory ,Back-reaction ,Physical and Theoretical Chemistry ,business ,Polarization (electrochemistry) ,Thermal energy - Abstract
We investigate the effects of nanoparticles on molecular solar thermal energy storage systems and how one can tune chemical reactivities of a molecular photo- and thermoswitch by changing the nanoparticles. We have selected the dihydroazulene/vinylheptafulvene system to illustrate the effects of the nanoparticles on the chemical reactivities of the molecular photo- and thermoswitch. We have utilized the following nanoparticles: a TiO2 nanoparticle along with nanoparticles of gold, silver and copper. We calculate the rate constants for the release of the thermal energy utilizing a QM/MM method coupled to a transition state method. The molecular systems are described by density functional theory whereas the nanoparticles are given by molecular mechanics including electrostatic and polarization dynamics. In order to investigate whether the significant stabilization of the transitions state provided by the nanoparticles is general to the DHA/VHF system, we calculated the transition state rate constant of the parent- and 3-amino-substituted-DHA/VHF systems at 298.15 K in the four different orientations and at the three different separations. We observe that the transition state rate constant of the parent system is only increased as the cyano groups are oriented towards the nanoparticle while the presence of the nanoparticle actually impedes the reactions using the three other orientations. On the other hand, for the substituted system the nanoparticle generally leads to a significant increase in the rate of the reaction. We find that the nanoparticles can have a substantial effect on the calculated rate constants. We observe, depending on the nanoparticle and the molecular orientation, increases of the rate constants by a factor of 106. This illustrates the prospects of utilizing nanoparticles for controlling the release of the stored thermal energy. more...
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- 2021
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- View/download PDF
186. Differences in the Effects of Selective Logging on Amphibian Assemblages in Three West African Forest Types
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Ofori-Boateng, Caleb, Oduro, William, Hillers, Annika, Norris, Ken, Oppong, Samuel K., Adum, Gilbert B., and Rödel, Mark-Oliver
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- 2013
- Full Text
- View/download PDF
187. Electric Properties of Photochromic Molecules Physisorbed on Silver and Copper Nanoparticles
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Andreas Erbs Hillers-Bendtsen, Frederik Ørsted Kjeldal, and Kurt V. Mikkelsen
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Physical and Theoretical Chemistry - Abstract
This paper investigates the electric properties of the photochromic dihydroazulene/vinylheptafulvene system as it is physisorbed onto silver and copper nanoparticles. Our focus is on how the polarizability and hyperpolarizability of the dihydroazulene, s more...
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- 2022
188. Prospects of Improving Molecular Solar Energy Storage of the Norbornadiene/Quadricyclane System through Bridgehead Modifications
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Hillers-Bendtsen, Andreas Erbs, Iuel Lunøe Dünweber, Phillip Gustav, Olsen, Lars Henrik, and Mikkelsen, Kurt V.
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Physical and Theoretical Chemistry - Abstract
We have investigated novel bicyclic diene molecular solar thermal energy storage systems that presently are the ones with the highest predicted energy density. Using a variety of different ab initio quantum chemical methods, we report storage energies, absorption spectra, and reaction barriers for the release of stored energy for a series of bicyclic dienes. The bicyclic dienes are all constructed by modifying the bridgehead of the well-known norbornadiene/quadricyclane (NBD/QC) system. In conclusion, we find it promising that it is possible to significantly amplify the storage energy of the NBD/QC system without seriously compromising other crucial properties by introducing simple modifications to the bridgehead. more...
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- 2022
- Full Text
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189. Global quieting of high-frequency seismic noise due to COVID-19 pandemic lockdown measures
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Han Xiao, Ben A. van der Pluijm, Simon Richard Proud, Adolfo Inza, Stephen Hicks, T. Megies, Alexander E. Stott, William G. Minarik, Efthimios Sokos, Mika McKinnon, Kasper van Wijk, Anna Horleston, Victor H. Márquez-Ramírez, Läslo Evers, Bogdan Grecu, Esteban J. Chaves, Joachim Wassermann, Claudio Satriano, Christos Evangelidis, Paula Koelemeijer, David Craig, Frédérick Massin, Sebastián Carrasco, György Hetényi, Mario Arroyo-Solórzano, Eric Larose, Jay J. Pulli, Társilo Girona, Lise Retailleau, Javier Ojeda, Olivier F. C. den Ouden, Alan L. Kafka, Gonzalo A. Fernandez, Marc Grunberg, Tommi Vuorinen, Robert E. Anthony, Steven J. Gibbons, Stefanie Donner, Martin Möllhoff, Nathaniel J. Lindsey, Jordi Diaz, C. R. Labedz, Meghan S. Miller, Taka'aki Taira, Dave Cornwell, Mathijs Koymans, Corentin Caudron, Klaus Stammler, Andrea Cannata, Flavio Cannavò, Reinoud Sleeman, Mark Vanstone, Shiba Subedi, Raphael S. M. De Plaen, Shankho Niyogi, Koen Van Noten, Shahar Shani-Kadmiel, Jelle Assink, Tristram Warren, Jessica C. E. Irving, Ian M. Nesbitt, Dimitrios Giannopoulos, Martha K. Savage, Mohammadreza Jamalreyhani, Louis Moresi, Maria-Theresia Apoloner, Gregor Hillers, Jérôme Vergne, Benoit Fauville, Fatih Turhan, Annukka E. Rintamäki, Pınar Büyükakpınar, Adrien Oth, Mathilde B. Sørensen, Mar Tapia, Thomas Lecocq, Royal Society (UK), German Research Centre for Geosciences, Boğaziçi Üniversity, Netherlands Organization for Scientific Research, Air Force Office of Scientific Research (US), National Science Foundation (US), Consejo Nacional de Ciencia y Tecnología (México), Universidad Nacional Autónoma de México, Agencia Nacional de Investigación y Desarrollo (Chile), Natural Environment Research Council (UK), University of California, Commonwealth Scientific and Industrial Research Organisation (Australia), Belgian Science Policy Office, Fonds National de la Recherche Luxembourg, Lecocq, Thomas, Hicks, Stephen, Noten, Koen Van, Wijk, Kasper van, Plaen, Raphael de, Massin, Frédérick, Hillers, Gregor, Apoloner, Maria-Theresia, Arroyo-Solórzano, Mario, Assink, Jelle, Büyükakpınar, Pinar, Cannata, Andrea, Cannavó, Flavio, Carrasco, Sebastián, Caudron, Corentin, Chaves, Esteban, Cornwell, David G., Craig, David, Diaz, J., Donner, Stefanie, Evangelidis, Christos, Evers, Läslo, Fernández, Gonzalo A., Giannopoulos, Dimitrios, Gibbons, Steven J., Girona, Társilo, Grecu, Bogdan, Grunberg, Marc, Hetényi, Gyorgy, Horleston, Anna, Inza, Adolfo, Irving, Jessica C. E., Jamalreyhani, Mohammadreza, Kafka, Alan, Labedz, Celeste, Lindsey, Nathaniel, McKinno, Mika, Megies, Tobias, Miller, Meghan, Minarik, William, Moresi, Louis, Márquez-Ramirez, V. H., Möllhoff, Martin, Nesbitt, Ian M., Niyogi, Shankho, Ojeda, Javier, Oth, Adrien, Proud, Simon, Retailleau, Lise, Satriano, Claudio, Savage, Martha, Shani-Kadmiel, Shahar, Sleeman,Reinoud, Sokos, Efthimios, Stott, Alexander, Subedi, Shiba, Sørensen, Mathilde, Taira, Taka'aki, Turhan, Fatih, Pluijm, Ben van der, Vergne, Jérôme, Vuorinen, Tommi A. T., Warren, Tristram, Wassermann, Joachim, Xiao, Han, Lecocq, Thomas [0000-0002-4988-6477], Hicks, Stephen [0000-0002-7476-3284], Noten, Koen Van [0000-0001-8933-4426], Wijk, Kasper van [0000-0003-4994-8030], Plaen, Raphael de [0000-0003-3477-2001], Massin, Frédérick [0000-0002-7532-5139], Hillers, Gregor [0000-0003-2341-1892], Apoloner, Maria-Theresia [0000-0002-4006-1284], Arroyo-Solórzano, Mario [0000-0002-1653-2680], Assink, Jelle [0000-0002-4990-6845], Büyükakpınar, Pinar [0000-0001-8461-674X], Cannata, Andrea [0000-0002-0028-5822], Cannavó, Flavio [0000-0001-7550-8579], Carrasco, Sebastián [0000-0002-6207-8757], Caudron, Corentin [0000-0002-3748-0007], Chaves, Esteban [0000-0002-5724-1513], Cornwell, David G. [0000-0002-9843-7811], Craig, David [0000-0001-9414-1725], Diaz, J. [0000-0003-1801-0541], Donner, Stefanie [0000-0001-7351-8079], Evangelidis, Christos [0000-0001-8733-8984], Evers, Läslo [0000-0003-2825-6211], Fernández, Gonzalo A. [0000-0001-8284-9566], Giannopoulos, Dimitrios [0000-0002-8314-0759], Gibbons, Steven J. [0000-0002-7822-0244], Girona, Társilo [0000-0001-6422-0422], Grecu, Bogdan [0000-0002-7662-996X], Grunberg, Marc [0000-0002-1307-7790], Hetényi, Gyorgy [0000-0001-9036-4761], Horleston, Anna [0000-0002-6748-6522], Inza, Adolfo [0000-0001-5381-9042], Irving, Jessica C. E. [0000-0002-0866-8246], Jamalreyhani, Mohammadreza [0000-0003-4181-7175], Kafka, Alan [0000-0001-6643-1602], Labedz, Celeste [0000-0001-7339-2170], Lindsey, Nathaniel [0000-0001-9522-6683], McKinno, Mika [0000-0002-9274-0377], Megies, Tobias [0000-0002-5033-9921], Miller, Meghan [0000-0001-5494-2296], Minarik, William [0000-0001-5509-5543], Moresi, Louis [0000-0003-3685-174X], Márquez-Ramirez, V. H. [0000-0003-1494-2229], Möllhoff, Martin [0000-0003-1848-1554], Nesbitt, Ian M. [0000-0001-5828-6070], Niyogi, Shankho [0000-0002-8362-4569], Ojeda, Javier [0000-0002-7188-8356], Oth, Adrien [0000-0003-4859-6504], Proud, Simon [0000-0003-3880-6774], Retailleau, Lise [0000-0002-0711-4540], Satriano, Claudio [0000-0002-3039-2530], Savage, Martha [0000-0002-2080-0676], Shani-Kadmiel, Shahar [0000-0003-2215-6164], Sleeman,Reinoud [0000-0002-1928-5056], Sokos, Efthimios [0000-0002-7742-7251], Stott, Alexander [0000-0001-6121-705X], Subedi, Shiba [0000-0002-7009-7333], Sørensen, Mathilde [0000-0002-8589-7480], Taira, Taka'aki [0000-0002-6170-797X], Turhan, Fatih [0000-0003-4612-7421], Pluijm, Ben van der [0000-0001-7737-2791], Vergne, Jérôme [0000-0003-1731-9360], Vuorinen, Tommi A. T. [0000-0002-8186-012X], Warren, Tristram [0000-0003-3877-0046], Wassermann, Joachim [0000-0002-4088-1792], and Xiao, Han [0000-0001-8727-8053] more...
- Subjects
Seismometer ,2019-20 coronavirus outbreak ,010504 meteorology & atmospheric sciences ,Coronavirus disease 2019 (COVID-19) ,General Science & Technology ,Pneumonia, Viral ,Seismic noise ,010502 geochemistry & geophysics ,01 natural sciences ,Seismic wave ,Activities of Daily Living ,Humans ,Pandemics ,0105 earth and related environmental sciences ,Multidisciplinary ,COVID-19 ,Covid19 ,Noise ,Quiet period ,Quarantine ,Séismologie ,Coronavirus Infections ,Geology ,Seismology - Abstract
Human activity causes vibrations that propagate into the ground as high-frequency seismic waves. Measures to mitigate the COVID-19 pandemic caused widespread changes in human activity, leading to a months-long reduction in seismic noise of up to 50%. The 2020 seismic noise quiet period is the longest and most prominent global anthropogenic seismic noise reduction on record. While the reduction is strongest at surface seismometers in populated areas, this seismic quiescence extends for many kilometers radially and hundreds of meters in depth. This provides an opportunity to detect subtle signals from subsurface seismic sources that would have been concealed in noisier times and to benchmark sources of anthropogenic noise. A strong correlation between seismic noise and independent measurements of human mobility suggests that seismology provides an absolute, real-time estimate of population dynamics., P.K. was funded by a Royal Society University Research Fellowship (URF\R1\180377). P.B. and M.J. acknowledge support from the International Training Course “Seismology and Seismic Hazard Assessment” funded by the GeoForschungsZentrum Potsdam (GFZ) and the German Federal Foreign Office through the German Humanitarian Assistance program (grant S08-60 321.50 ALL 03/19). P.B also acknowledges financial support from the Boğaziçi University Research Fund (BAP 15683). O.F.C.d.O acknowledges funding from a Young Investigator Grant from the Human Frontier Science Program (HFSP - project number RGY0072/2017). C.P.E. and E.S. acknowledge funding from the HELPOS Project “Hellenic Plate Observing System” (MIS 5002697). L.E. and S.S.-K. acknowledge funding from a VIDI project from the Dutch Research Council (NWO project number 864.14.005). G.A.F. acknowledges contributions from the Observatorio San Calixto, which is supported by the Air Force Technical Application Center (AFTAC). C.R.L. acknowledge funding from the NSF Graduate Research Fellowship Program (grant No. DGE‐1745301). V.-H.M. and R.D.P. acknowledge support from grant CONACYT-299766. R.D.P. acknowledges support from the UNAM-DGAPA postdoctoral scholarship. J.O. acknowledges support from the Agencia Nacional de Investigación y Desarrollo (Scholarship ANID-PFCHA / Doctorado Nacional / 2020-21200903). S.P. acknowledges financial support from the Natural Environment Research Council (NE/R013144/1). A.E.R. acknowledges support from the K.H. Renlund foundation. M.K.S. acknowledges the New Zealand Earthquake Commission (EQC Project No 20796). H.X. acknowledges support from a Multidisciplinary Research on the Coronavirus and its Impacts (MRCI) grant from UC Santa Barbara. The Australian Seismometers in Schools data used in this research are supported by AuScope, enabled by the Australian Commonwealth NCRIS program. A.O. acknowledges support from the project RESIST, funded by the Belgian Federal Science Policy (contract SR/00/305) and the Luxembourg National Research Fund more...
- Published
- 2020
- Full Text
- View/download PDF
190. Co-limitation towards lower latitudes shapes global forest diversity gradients
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Liang, J., Gamarra, J.G.P., Picard, N., Zhou, M., Pijanowski, B., Jacobs, D.F., Reich, P.B., Crowther, T.W., Nabuurs, G.-J., de-Miguel, S., Fang, J., Woodall, C.W., Svenning, J.-C., Jucker, T., Bastin, J.-F., Wiser, S.K., Slik, F., Hérault, B., Alberti, G., Keppel, G., Hengeveld, G.M., Ibisch, P.L., Silva, C.A., ter Steege, H., Peri, P.L., Coomes, D.A., Searle, E.B., von Gadow, K., Jaroszewicz, B., Abbasi, A.O., Abegg, M., Yao, Y.C. A., Aguirre-Gutiérrez, J., Zambrano, A.M.A., Altman, J., Alvarez-Dávila, E., Álvarez-González, J.G., Alves, L.F., Amani, B.H.K., Amani, C.A., Ammer, C., Ilondea, B.A., Antón-Fernández, C., Avitabile, V., Aymard, G.A., Azihou, A.F., Baard, J.A., Baker, T.R., Balazy, R., Bastian, M.L., Batumike, R., Bauters, M., Beeckman, H., Benu, N.M.H., Bitariho, R., Boeckx, P., Bogaert, J., Bongers, F., Bouriaud, O., Brancalion, P.H.S., Brandl, S., Brearley, F. Q., Briseno-Reyes, J., Broadbent, E.N., Bruelheide, H., Bulte, E., Catlin, A.C., Cazzolla Gatti, R., César, R.G., Chen, H.Y. H., Chisholm, C., Cienciala, E., Colletta, G.D., Corral-Rivas, J.J., Cuchietti, A., Cuni-Sanchez, A., Dar, J.A., Dayanandan, S., de Haulleville, T., Decuyper, M., Delabye, S., Derroire, G., DeVries, B., Diisi, J., Do, T.V., Dolezal, J., Dourdain, A., Durrheim, G.P., Obiang, N.L.E., Ewango, C.E.N., Eyre, T.J., Fayle, T.M., Feunang, L.F.N., Finér, L., Fischer, M., Fridman, J., Frizzera, Lorenzo., de Gasper, A.L., Gianelle, D., Glick, H.B., Gonzalez-Elizondo, M.S., Gorenstein, Lev., Habonayo, R., Hardy, O.J., Harris, D.J., Hector, A., Hemp, A., Herold, M., Hillers, A., Hubau, W., Ibanez, T., Imai, N., Imani, G., Jagodzinski, A.M., Janecek, S., Johannsen, V.K., Joly, C.A., Jumbam, B., Kabelong, B. L. P. R., Kahsay, G.A., Karminov, V., Kartawinata, K., Kassi, J.ustin N., Kearsley, E., Kennard, D.K., Kepfer-Rojas, S., Khan, M. L., Kigomo, J.N., Kim, H.S., Klauberg, C., Klomberg, Y., Korjus, H., Kothandaraman, S., Kraxner, F., Kumar, A., Kuswandi, R., Lang, M., Lawes, M.J., Leite, R.V., Lentner, G., Lewis, S.L., Libalah, M.B., Lisingo, Janvier, López-Serrano, P.M., Lu, H., Lukina, N.V., Lykke, A.M., Maicher, V., Maitner, B.S., Marcon, E., Marshall, A.R., Martin, E. H., Martynenko, O., Mbayu, F.M., Mbuvi, M. T. E., Meave, J. A., Merow, C., Miscicki, S., Moreno, V. S., Morera, A., Mukul, S.A., Müller, J.C., Murdjoko, A., Nava-Miranda, M.G., Ndive, L.E., Neldner, V.J., Nevenic, R.V., Nforbelie, L.N., Ngoh, M.L., N’Guessan, A.E., Ngugi, M.R., Ngute, A. S. K., Njila, E. N. N., Nyako, M.C., Ochuodho, T.O., Oleksyn, J., Paquette, A., Parfenova, E.I., Park, M., Parren, M., Parthasarathy, N., Pfautsch, S., Phillips, O. L., Piedade, M.T. F., Piotto, D., Pollastrini, M., Poorter, L., Poulsen, J. R., Poulsen, A.D., Pretzsch, H., Rodeghiero, M., Rolim, S.G., Rovero, F., Rutishauser, E., Sagheb-Talebi, K., Saikia, P., Sainge, M.N., Salas-Eljatib, C., Salis, A., Schall, P., Shchepashchenko, D., Scherer-Lorenzen, M., Schmid, B., Schöngart, J., Šebeň, V., Sellan, G., Selvi, F., Serra-Diaz, J.M., Sheil, D., Shvidenko, A., Sist, P., Souza, A.F., Stereńczak, K.J., Sullivan, M. J. P., Sundarapandian, S., Svoboda, M., Swaine, M.D., Targhetta, N., Tchebakova, N., Trethowan, L.A., Tropek, R., Mukendi, J.T., Umunay, P.M., Usoltsev, V.A., Vaglio Laurin, G., Valentini, R., Valladares, F., van der Plas, F., Vega-Nieva, D.J., Verbeeck, H., Viana, H., Vibrans, A.C., Vieira, S.A., Vleminckx, J., Waite, C.E., Wang, H.-F., Wasingya, E.K., Wekesa, C., Westerlund, B., Wittmann, F., Wortel, V., Zawiła-Niedźwiecki, T., Zhang, C., Zhao, X., Zhu, J., Zhu, X., Zhu, Z.-X., Zo-Bi, I.C., Hui, C., Liang, J., Gamarra, J.G.P., Picard, N., Zhou, M., Pijanowski, B., Jacobs, D.F., Reich, P.B., Crowther, T.W., Nabuurs, G.-J., de-Miguel, S., Fang, J., Woodall, C.W., Svenning, J.-C., Jucker, T., Bastin, J.-F., Wiser, S.K., Slik, F., Hérault, B., Alberti, G., Keppel, G., Hengeveld, G.M., Ibisch, P.L., Silva, C.A., ter Steege, H., Peri, P.L., Coomes, D.A., Searle, E.B., von Gadow, K., Jaroszewicz, B., Abbasi, A.O., Abegg, M., Yao, Y.C. A., Aguirre-Gutiérrez, J., Zambrano, A.M.A., Altman, J., Alvarez-Dávila, E., Álvarez-González, J.G., Alves, L.F., Amani, B.H.K., Amani, C.A., Ammer, C., Ilondea, B.A., Antón-Fernández, C., Avitabile, V., Aymard, G.A., Azihou, A.F., Baard, J.A., Baker, T.R., Balazy, R., Bastian, M.L., Batumike, R., Bauters, M., Beeckman, H., Benu, N.M.H., Bitariho, R., Boeckx, P., Bogaert, J., Bongers, F., Bouriaud, O., Brancalion, P.H.S., Brandl, S., Brearley, F. Q., Briseno-Reyes, J., Broadbent, E.N., Bruelheide, H., Bulte, E., Catlin, A.C., Cazzolla Gatti, R., César, R.G., Chen, H.Y. H., Chisholm, C., Cienciala, E., Colletta, G.D., Corral-Rivas, J.J., Cuchietti, A., Cuni-Sanchez, A., Dar, J.A., Dayanandan, S., de Haulleville, T., Decuyper, M., Delabye, S., Derroire, G., DeVries, B., Diisi, J., Do, T.V., Dolezal, J., Dourdain, A., Durrheim, G.P., Obiang, N.L.E., Ewango, C.E.N., Eyre, T.J., Fayle, T.M., Feunang, L.F.N., Finér, L., Fischer, M., Fridman, J., Frizzera, Lorenzo., de Gasper, A.L., Gianelle, D., Glick, H.B., Gonzalez-Elizondo, M.S., Gorenstein, Lev., Habonayo, R., Hardy, O.J., Harris, D.J., Hector, A., Hemp, A., Herold, M., Hillers, A., Hubau, W., Ibanez, T., Imai, N., Imani, G., Jagodzinski, A.M., Janecek, S., Johannsen, V.K., Joly, C.A., Jumbam, B., Kabelong, B. L. P. R., Kahsay, G.A., Karminov, V., Kartawinata, K., Kassi, J.ustin N., Kearsley, E., Kennard, D.K., Kepfer-Rojas, S., Khan, M. L., Kigomo, J.N., Kim, H.S., Klauberg, C., Klomberg, Y., Korjus, H., Kothandaraman, S., Kraxner, F., Kumar, A., Kuswandi, R., Lang, M., Lawes, M.J., Leite, R.V., Lentner, G., Lewis, S.L., Libalah, M.B., Lisingo, Janvier, López-Serrano, P.M., Lu, H., Lukina, N.V., Lykke, A.M., Maicher, V., Maitner, B.S., Marcon, E., Marshall, A.R., Martin, E. H., Martynenko, O., Mbayu, F.M., Mbuvi, M. T. E., Meave, J. A., Merow, C., Miscicki, S., Moreno, V. S., Morera, A., Mukul, S.A., Müller, J.C., Murdjoko, A., Nava-Miranda, M.G., Ndive, L.E., Neldner, V.J., Nevenic, R.V., Nforbelie, L.N., Ngoh, M.L., N’Guessan, A.E., Ngugi, M.R., Ngute, A. S. K., Njila, E. N. N., Nyako, M.C., Ochuodho, T.O., Oleksyn, J., Paquette, A., Parfenova, E.I., Park, M., Parren, M., Parthasarathy, N., Pfautsch, S., Phillips, O. L., Piedade, M.T. F., Piotto, D., Pollastrini, M., Poorter, L., Poulsen, J. R., Poulsen, A.D., Pretzsch, H., Rodeghiero, M., Rolim, S.G., Rovero, F., Rutishauser, E., Sagheb-Talebi, K., Saikia, P., Sainge, M.N., Salas-Eljatib, C., Salis, A., Schall, P., Shchepashchenko, D., Scherer-Lorenzen, M., Schmid, B., Schöngart, J., Šebeň, V., Sellan, G., Selvi, F., Serra-Diaz, J.M., Sheil, D., Shvidenko, A., Sist, P., Souza, A.F., Stereńczak, K.J., Sullivan, M. J. P., Sundarapandian, S., Svoboda, M., Swaine, M.D., Targhetta, N., Tchebakova, N., Trethowan, L.A., Tropek, R., Mukendi, J.T., Umunay, P.M., Usoltsev, V.A., Vaglio Laurin, G., Valentini, R., Valladares, F., van der Plas, F., Vega-Nieva, D.J., Verbeeck, H., Viana, H., Vibrans, A.C., Vieira, S.A., Vleminckx, J., Waite, C.E., Wang, H.-F., Wasingya, E.K., Wekesa, C., Westerlund, B., Wittmann, F., Wortel, V., Zawiła-Niedźwiecki, T., Zhang, C., Zhao, X., Zhu, J., Zhu, X., Zhu, Z.-X., Zo-Bi, I.C., and Hui, C. more...
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- 2022
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191. Synthesis, characterization and computational evaluation of bicyclooctadienes towards molecular solar thermal energy storage
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Quant, Maria, Hillers-Bendtsen, Andreas Erbs, Ghasemi, Shima, Erdélyi, Máté, Wang, Zhihang, Muhammad, Lidiya M., Kann, Nina, Mikkelsen, Kurt V., Moth-Poulsen, Kasper, Quant, Maria, Hillers-Bendtsen, Andreas Erbs, Ghasemi, Shima, Erdélyi, Máté, Wang, Zhihang, Muhammad, Lidiya M., Kann, Nina, Mikkelsen, Kurt V., and Moth-Poulsen, Kasper more...
- Abstract
Molecular solar-thermal energy storage (MOST) systems are based on photoswitches that reversibly convert solar energy into chemical energy. In this context, bicyclooctadienes (BODs) undergo a photoinduced transformation to the corresponding higher energy tetracyclooctanes (TCOs), but the photoswitch system has not until now been evaluated for MOST application, due to the short half-life of the TCO form and limited available synthetic methods. The BOD system degrades at higher temperature via a retro-Diels–Alder reaction, which complicates the synthesis of the compounds. We here report a cross-coupling reaction strategy that enables an efficient synthesis of a series of 4 new BOD compounds. We show that the BODs were able to switch to the corresponding tetracyclooctanes (TCOs) in a reversible way and can be cycled 645 times with only 0.01% degradation. Half-lives of the TCOs were measured, and we illustrate how the half-life could be engineered from seconds to minutes by molecular structure design. A density functional theory (DFT) based modelling framework was developed to access absorption spectra, thermal half-lives, and storage energies which were calculated to be 143–153 kJ mol−1 (0.47–0.51 MJ kg−1), up to 76% higher than for the corresponding norbornadiene. The combined computational and experimental findings provide a reliable way of designing future BOD/TCO systems with tailored properties. more...
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- 2022
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192. Modeling Absorption and Emission Spectroscopies of Symmetric and Asymmetric Azaoxahelicenes in Vacuum and Solution
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Hillers-Bendtsen, A. E., Todarwal, Yogesh, Pittelkow, M., Norman, Patrick, Mikkelsen, K. V., Hillers-Bendtsen, A. E., Todarwal, Yogesh, Pittelkow, M., Norman, Patrick, and Mikkelsen, K. V.
- Abstract
Helicenes are of general interest due to the significant chiral signals in both absorption- and emission-based spectroscopy. Herein, the spectroscopic properties of four recently synthesized azaoxahelicenes are studied using density functional theory methods. The azaoxahelicenes have 7, 9, 10, and 13 units and one to two complete turns of the structure. UV-vis absorption and electronic circular dichroism spectra are determined both in vacuum and in solution using explicit solvation through a combined molecular dynamics/polarizable embedding framework. Additionally, emission and circularly polarized luminescence spectra are determined based on vibronic calculations. The resulting spectra are in good agreement with the experimentally available data, highlighting that both absorption- and emission-based spectra of the systems can be modeled computationally such that reliable predictions can be made for systems that are yet to be synthesized., QC 20230524 more...
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- 2022
- Full Text
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193. Co-limitation towards lower latitudes shapes global forest diversity gradients
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Liang, Jingjing, Gamarra, Javier G. P., Picard, Nicolas, Zhou, Mo, Pijanowski, Bryan, Jacobs, Douglass F., Reich, Peter B., Crowther, Thomas W., Nabuurs, Gert-Jan, De-Miguel, Sergio, Fang, Jingyun, Woodall, Christopher W., Svenning, Jens-Christian, Jucker, Tommaso, Bastin, Jean-Francois, Wiser, Susan K., Slik, Ferry, Herault, Bruno, Alberti, Giorgio, Keppel, Gunnar, Hengeveld, Geerten M., Ibisch, Pierre L., Silva, Carlos A., Ter Steege, Hans, Peri, Pablo L., Coomes, David A., Searle, Eric B., Von Gadow, Klaus, Jaroszewicz, Bogdan, Abbasi, Akane O., Abegg, Meinrad, Yao, Yves C. Adou, Aguirre-Gutierrez, Jesus, Zambrano, Angelica M. Almeyda, Altman, Jan, Alvarez-Davila, Esteban, Alvarez-Gonzalez, Juan Gabriel, Alves, Luciana F., Amani, Bienvenu H. K., Amani, Christian A., Ammer, Christian, Ilondea, Bhely Angoboy, Anton-Fernandez, Clara, Avitabile, Valerio, Aymard, Gerardo A., Azihou, Akomian F., Baard, Johan A., Baker, Timothy R., Balazy, Radomir, Bastian, Meredith L., Batumike, Rodrigue, Bauters, Marijn, Beeckman, Hans, Benu, Nithanel Mikael Hendrik, Bitariho, Robert, Boeckx, Pascal, Bogaert, Jan, Bongers, Frans, Bouriaud, Olivier, Brancalion, Pedro H. S., Brandl, Susanne, Brearley, Francis Q., Briseno-Reyes, Jaime, Broadbent, Eben N., Bruelheide, Helge, Bulte, Erwin, Catlin, Ann Christine, Gatti, Roberto Cazzolla, Cesar, Ricardo G., Chen, Han Y. H., Chisholm, Chelsea, Cienciala, Emil, Colletta, Gabriel D., Corral-Rivas, Jose Javier, Cuchietti, Anibal, Cuni-Sanchez, Aida, Dar, Javid A., Dayanandan, Selvadurai, De Haulleville, Thales, Decuyper, Mathieu, Delabye, Sylvain, Derroire, Geraldine, Devries, Ben, Diisi, John, Van Do, Tran, Dolezal, Jiri, Dourdain, Aurelie, Durrheim, Graham P., Obiang, Nestor Laurier Engone, Ewango, Corneille E. N., Eyre, Teresa J., Fayle, Tom M., Feunang, Lethicia Flavine N., Finer, Leena, Fischer, Markus, Fridman, Jonas, Frizzera, Lorenzo, De Gasper, Andre L., Gianelle, Damiano, Glick, Henry B., Gonzalez-Elizondo, Maria Socorro, Gorenstein, Lev, Habonayo, Richard, Hardy, Olivier J., Harris, David J., Hector, Andrew, Hemp, Andreas, Herold, Martin, Hillers, Annika, Hubau, Wannes, Ibanez, Thomas, Imai, Nobuo, Imani, Gerard, Jagodzinski, Andrzej M., Janecek, Stepan, Johannsen, Vivian Kvist, Joly, Carlos A., Jumbam, Blaise, Kabelong, Banoho L. P. R., Kahsay, Goytom Abraha, Karminov, Viktor, Kartawinata, Kuswata, Kassi, Justin N., Kearsley, Elizabeth, Kennard, Deborah K., Kepfer-Rojas, Sebastian, Khan, Mohammed Latif, Kigomo, John N., Kim, Hyun Seok, Klauberg, Carine, Klomberg, Yannick, Korjus, Henn, Kothandaraman, Subashree, Kraxner, Florian, Kumar, Amit, Kuswandi, Relawan, Lang, Mait, Lawes, Michael J., Leite, Rodrigo, Lentner, Geoffrey, Lewis, Simon L., Libalah, Moses B., Lisingo, Janvier, Lopez-Serrano, Pablito Marcelo, Lu, Huicui, Lukina, Natalia, Lykke, Anne Mette, Maicher, Vincent, Maitner, Brian S., Marcon, Eric, Marshall, Andrew R., Martin, Emanuel H., Martynenko, Olga, Mbayu, Faustin M., Mbuvi, Musingo T. E., Meave, Jorge A., Merow, Cory, Miscicki, Stanislaw, Moreno, Vanessa S., Morera, Albert, Mukul, Sharif A., Muller, Jorg C., Murdjoko, Agustinus, Nava-Miranda, Maria Guadalupe, Ndive, Litonga Elias, Neldner, Victor J., Nevenic, Radovan, Nforbelie, Louis N., Ngoh, Michael L., N'Guessan, Anny E., Ngugi, Michael R., Ngute, Alain S. K., Njila, Emile Narcisse N., Nyako, Melanie C., Ochuodho, Thomas O., Oleksyn, Jacek, Paquette, Alain, Parfenova, Elena, Park, Minjee, Parren, Marc, Parthasarathy, Narayanaswamy, Pfautsch, Sebastian, Phillips, Oliver L., Piedade, Maria T. F., Piotto, Daniel, Pollastrini, Martina, Poorter, Lourens, Poulsen, John R., Poulsen, Axel Dalberg, Pretzsch, Hans, Rodeghiero, Mirco, Rolim, Samir G., Rovero, Francesco, Rutishauser, Ervan, Sagheb-Talebi, Khosro, Saikia, Purabi, Sainge, Moses Nsanyi, Salas-Eljatib, Christian, Salis, Antonello, Schall, Peter, Schepaschenko, Dmitry, Scherer-Lorenzen, Michael, Schmid, Bernhard, Seben, Vladimir, Schongart, Jochen, Sellan, Giacomo, Selvi, Federico, Serra-Diaz, Josep M., Sheil, Douglas, Shvidenko, Anatoly Z., Sist, Plinio, Souza, Alexandre F., Sullivan, Martin J. P., Sundarapandian, Somaiah, Svoboda, Miroslav, Swaine, Mike D., Targhetta, Natalia, Tchebakova, Nadja, Trethowan, Liam A., Tropek, Robert, Mukendi, John Tshibamba, Umunay, Peter Mbanda, Usoltsev, Vladimir A., Laurin, Gaia Vaglio, Valentini, Riccardo, Valladares, Fernando, Van der Plas, Fons, Vega-Nieva, Daniel Jose, Verbeeck, Hans, Viana, Helder, Vibrans, Alexander C., Vieira, Simone A., Vleminckx, Jason, Waite, Catherine E., Wang, Hua-Feng, Wasingya, Eric Katembo, Wekesa, Chemuku, Westerlund, Bertil, Wittmann, Florian, Wortel, Verginia, Zawila-Niedziwiecki, Tomasz, Zhang, Chunyu, Zhao, Xiuhai, Zhu, Jun, Zhu, Xiao, Zhu, Zhi-Xin, Zo-Bi, Irie C., Hui, Cang, Liang, Jingjing, Gamarra, Javier G. P., Picard, Nicolas, Zhou, Mo, Pijanowski, Bryan, Jacobs, Douglass F., Reich, Peter B., Crowther, Thomas W., Nabuurs, Gert-Jan, De-Miguel, Sergio, Fang, Jingyun, Woodall, Christopher W., Svenning, Jens-Christian, Jucker, Tommaso, Bastin, Jean-Francois, Wiser, Susan K., Slik, Ferry, Herault, Bruno, Alberti, Giorgio, Keppel, Gunnar, Hengeveld, Geerten M., Ibisch, Pierre L., Silva, Carlos A., Ter Steege, Hans, Peri, Pablo L., Coomes, David A., Searle, Eric B., Von Gadow, Klaus, Jaroszewicz, Bogdan, Abbasi, Akane O., Abegg, Meinrad, Yao, Yves C. Adou, Aguirre-Gutierrez, Jesus, Zambrano, Angelica M. Almeyda, Altman, Jan, Alvarez-Davila, Esteban, Alvarez-Gonzalez, Juan Gabriel, Alves, Luciana F., Amani, Bienvenu H. K., Amani, Christian A., Ammer, Christian, Ilondea, Bhely Angoboy, Anton-Fernandez, Clara, Avitabile, Valerio, Aymard, Gerardo A., Azihou, Akomian F., Baard, Johan A., Baker, Timothy R., Balazy, Radomir, Bastian, Meredith L., Batumike, Rodrigue, Bauters, Marijn, Beeckman, Hans, Benu, Nithanel Mikael Hendrik, Bitariho, Robert, Boeckx, Pascal, Bogaert, Jan, Bongers, Frans, Bouriaud, Olivier, Brancalion, Pedro H. S., Brandl, Susanne, Brearley, Francis Q., Briseno-Reyes, Jaime, Broadbent, Eben N., Bruelheide, Helge, Bulte, Erwin, Catlin, Ann Christine, Gatti, Roberto Cazzolla, Cesar, Ricardo G., Chen, Han Y. H., Chisholm, Chelsea, Cienciala, Emil, Colletta, Gabriel D., Corral-Rivas, Jose Javier, Cuchietti, Anibal, Cuni-Sanchez, Aida, Dar, Javid A., Dayanandan, Selvadurai, De Haulleville, Thales, Decuyper, Mathieu, Delabye, Sylvain, Derroire, Geraldine, Devries, Ben, Diisi, John, Van Do, Tran, Dolezal, Jiri, Dourdain, Aurelie, Durrheim, Graham P., Obiang, Nestor Laurier Engone, Ewango, Corneille E. N., Eyre, Teresa J., Fayle, Tom M., Feunang, Lethicia Flavine N., Finer, Leena, Fischer, Markus, Fridman, Jonas, Frizzera, Lorenzo, De Gasper, Andre L., Gianelle, Damiano, Glick, Henry B., Gonzalez-Elizondo, Maria Socorro, Gorenstein, Lev, Habonayo, Richard, Hardy, Olivier J., Harris, David J., Hector, Andrew, Hemp, Andreas, Herold, Martin, Hillers, Annika, Hubau, Wannes, Ibanez, Thomas, Imai, Nobuo, Imani, Gerard, Jagodzinski, Andrzej M., Janecek, Stepan, Johannsen, Vivian Kvist, Joly, Carlos A., Jumbam, Blaise, Kabelong, Banoho L. P. R., Kahsay, Goytom Abraha, Karminov, Viktor, Kartawinata, Kuswata, Kassi, Justin N., Kearsley, Elizabeth, Kennard, Deborah K., Kepfer-Rojas, Sebastian, Khan, Mohammed Latif, Kigomo, John N., Kim, Hyun Seok, Klauberg, Carine, Klomberg, Yannick, Korjus, Henn, Kothandaraman, Subashree, Kraxner, Florian, Kumar, Amit, Kuswandi, Relawan, Lang, Mait, Lawes, Michael J., Leite, Rodrigo, Lentner, Geoffrey, Lewis, Simon L., Libalah, Moses B., Lisingo, Janvier, Lopez-Serrano, Pablito Marcelo, Lu, Huicui, Lukina, Natalia, Lykke, Anne Mette, Maicher, Vincent, Maitner, Brian S., Marcon, Eric, Marshall, Andrew R., Martin, Emanuel H., Martynenko, Olga, Mbayu, Faustin M., Mbuvi, Musingo T. E., Meave, Jorge A., Merow, Cory, Miscicki, Stanislaw, Moreno, Vanessa S., Morera, Albert, Mukul, Sharif A., Muller, Jorg C., Murdjoko, Agustinus, Nava-Miranda, Maria Guadalupe, Ndive, Litonga Elias, Neldner, Victor J., Nevenic, Radovan, Nforbelie, Louis N., Ngoh, Michael L., N'Guessan, Anny E., Ngugi, Michael R., Ngute, Alain S. K., Njila, Emile Narcisse N., Nyako, Melanie C., Ochuodho, Thomas O., Oleksyn, Jacek, Paquette, Alain, Parfenova, Elena, Park, Minjee, Parren, Marc, Parthasarathy, Narayanaswamy, Pfautsch, Sebastian, Phillips, Oliver L., Piedade, Maria T. F., Piotto, Daniel, Pollastrini, Martina, Poorter, Lourens, Poulsen, John R., Poulsen, Axel Dalberg, Pretzsch, Hans, Rodeghiero, Mirco, Rolim, Samir G., Rovero, Francesco, Rutishauser, Ervan, Sagheb-Talebi, Khosro, Saikia, Purabi, Sainge, Moses Nsanyi, Salas-Eljatib, Christian, Salis, Antonello, Schall, Peter, Schepaschenko, Dmitry, Scherer-Lorenzen, Michael, Schmid, Bernhard, Seben, Vladimir, Schongart, Jochen, Sellan, Giacomo, Selvi, Federico, Serra-Diaz, Josep M., Sheil, Douglas, Shvidenko, Anatoly Z., Sist, Plinio, Souza, Alexandre F., Sullivan, Martin J. P., Sundarapandian, Somaiah, Svoboda, Miroslav, Swaine, Mike D., Targhetta, Natalia, Tchebakova, Nadja, Trethowan, Liam A., Tropek, Robert, Mukendi, John Tshibamba, Umunay, Peter Mbanda, Usoltsev, Vladimir A., Laurin, Gaia Vaglio, Valentini, Riccardo, Valladares, Fernando, Van der Plas, Fons, Vega-Nieva, Daniel Jose, Verbeeck, Hans, Viana, Helder, Vibrans, Alexander C., Vieira, Simone A., Vleminckx, Jason, Waite, Catherine E., Wang, Hua-Feng, Wasingya, Eric Katembo, Wekesa, Chemuku, Westerlund, Bertil, Wittmann, Florian, Wortel, Verginia, Zawila-Niedziwiecki, Tomasz, Zhang, Chunyu, Zhao, Xiuhai, Zhu, Jun, Zhu, Xiao, Zhu, Zhi-Xin, Zo-Bi, Irie C., and Hui, Cang more...
- Abstract
The latitudinal diversity gradient (LDG) is one of the most recognized global patterns of species richness exhibited across a wide range of taxa. Numerous hypotheses have been proposed in the past two centuries to explain LDG, but rigorous tests of the drivers of LDGs have been limited by a lack of high-quality global species richness data. Here we produce a high-resolution (0.025 degrees x 0.025 degrees) map of local tree species richness using a global forest inventory database with individual tree information and local biophysical characteristics from similar to 1.3 million sample plots. We then quantify drivers of local tree species richness patterns across latitudes. Generally, annual mean temperature was a dominant predictor of tree species richness, which is most consistent with the metabolic theory of biodiversity (MTB). However, MTB underestimated LDG in the tropics, where high species richness was also moderated by topographic, soil and anthropogenic factors operating at local scales. Given that local landscape variables operate synergistically with bioclimatic factors in shaping the global LDG pattern, we suggest that MTB be extended to account for co-limitation by subordinate drivers. more...
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- 2022
194. Linear Optical Absorptions of Photo/Thermochromic Organic Molecules Interacting with a Gold Nanoparticle
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Essenbæk, David Nørgaard, Hillers-bendtsen, Andreas Erbs, Mikkelsen, Kurt V., Essenbæk, David Nørgaard, Hillers-bendtsen, Andreas Erbs, and Mikkelsen, Kurt V.
- Abstract
We present linear optical absorptions of photo/thermochromic molecules interacting with a gold nanoparticle. The photo/thermochromic system is the dihydroazulene/vinylheptafulvene (DHA/VHF) system and our aim is to study the effects of the interaction between the gold nanoparticle and the molecular systems. We consider the changes of the one-photon excitations of the dihydroazulene/vinylheptafulvene system as we increase the interactions between the molecules and the nanoparticle by decreasing the distance between them. We utilize a quantum mechanical/molecular mechanical method for investigating the photo/thermochromic molecular system interacting with the gold nanoparticle. The photo/thermochromic molecules are described quantum mechanically using density functional theory whereas the gold nanoparticle is represented as gold atoms with atomic polarizabillities using molecular mechanics. We observed that the optical properties of the photo/thermochromic systems are affected by the presence of the nanoparticle and the changes depend strongly on the conformer of the molecular system along with the relative orientation and distance between the photo/thermochromic molecules and the nanoparticle. more...
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- 2022
195. High throughput screening of norbornadiene/quadricyclane derivates for molecular solar thermal energy storage
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Lynge Elholm, Jacob, Erbs Hillers-Bendtsen, Andreas, Holzel, Helen, Moth-Poulsen, Kasper, Mikkelsen, Kurt, Lynge Elholm, Jacob, Erbs Hillers-Bendtsen, Andreas, Holzel, Helen, Moth-Poulsen, Kasper, and Mikkelsen, Kurt more...
- Abstract
We present a procedure for performing high throughput screening of molecular compounds for molecular solar thermal energy storage devices using extended tight binding (xTB) methods. In order to validate our approach, we performed screening of 3230 norbornadiene/quadricyclane (NBD/QC) derivatives in terms of storage energies, activation barriers and absorption of solar radiation using our approach, and compared it to high level density functional theory (DFT) and cluster perturbation (CP) theory calculations. Our comparisons show that the xTB screening framework correlates very well with DFT and CP theory in that it predicts the same relative trends in the studied parameters although the storage energies and thermal reaction barriers are significantly offset. Utilizing the screening methodology, we have been able to locate compounds that would either be excellent candidates or compounds that should not be considered further for molecular solar thermal energy storage devices. This methodology can readily be extended and applied to screening other molecular motifs for molecular solar energy storage. more...
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- 2022
196. Excited state dynamics and conjugation effects of the photoisomerization reactions of dihydroazulene
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Hillers-Bendtsen, Andreas Erbs, Kjeldal, Frederik Ørsted, Ree, Nicolai, Matito, Eduard, Mikkelsen, Kurt V., Hillers-Bendtsen, Andreas Erbs, Kjeldal, Frederik Ørsted, Ree, Nicolai, Matito, Eduard, and Mikkelsen, Kurt V. more...
- Abstract
Herein, we present an investigation of the excited state dynamics of the dihydroazulene photoswitch and its photoinduced reaction to vinylheptafulvene. The focus is on how the introduction of a benzannulated ring in different sites of the structure can modify the excited state topology and thus the kinetics of the ring opening reaction of DHA by alteration of the excited state conjugation of the system. The dynamics of the systems is obtained utilizing ab initio density functional theory calculations in different solvents coupled with unimolecular reaction theory. To accompany these results, the electron delocalization is investigated using the quantum theory of atoms in molecules partitioning to follow the trends induced by the benzannulated ring. It is observed that the introduction of a benzannulated ring can both enhance and diminish the rate of the photoinduced ring opening of dihydroazulene and that certain patterns of conjugation are consistent with the rate constants. Lastly, we find good agreement with earlier experimental studies indicating that the chosen approach could be used to predict whether photochromic systems lose their photoswitchability upon being optimized for specific applications via functionalization. more...
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- 2022
197. The effects of solvation on the back reaction and storage capabilities of solar thermal energy storage systems
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Kjeldsen, Ida Lützen Hoff, Høvring, Julie Franck, Von Buchwald, Theo Juncker, Hillers-bendtsen, Andreas Erbs, Mikkelsen, Kurt V., Kjeldsen, Ida Lützen Hoff, Høvring, Julie Franck, Von Buchwald, Theo Juncker, Hillers-bendtsen, Andreas Erbs, and Mikkelsen, Kurt V. more...
- Abstract
Solvent effects on molecular solar thermal energy storage systems have been investigated using density functional theory combined with solvent models describing the effects of viscosities and dielectric constants on chemical reaction rates. We have addressed the following issues concerning how solvents influence both the thermochemical properties and the thermal relaxation kinetics of the studied systems, how the friction of the solvent influences the recrossing of the reactions along with the dynamics and force constants of the transition state. We observe that the rate constants for the chemical reactions of the molecular solar thermal energy storage systems depend strongly on the dielectric solvent properties and the viscosities of the solvents. more...
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- 2022
198. Modeling Absorption and Emission Spectroscopies of Symmetric and Asymmetric Azaoxahelicenes in Vacuum and Solution
- Author
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Hillers-Bendtsen, Andreas Erbs, Todarwal, Yogesh, Pittelkow, Michael, Norman, Patrick, Mikkelsen, Kurt V., Hillers-Bendtsen, Andreas Erbs, Todarwal, Yogesh, Pittelkow, Michael, Norman, Patrick, and Mikkelsen, Kurt V. more...
- Abstract
Helicenes are of general interest due to the significant chiral signals in both absorption-and emission-based spectroscopy. Herein, the spectroscopic properties of four recently synthesized azaoxahelicenes are studied using density functional theory methods. The azaoxahelicenes have 7, 9, 10, and 13 units and one to two complete turns of the structure. UV-vis absorption and electronic circular dichroism spectra are determined both in vacuum and in solution using explicit solvation through a combined molecular dynamics/polarizable embedding framework. Addition-ally, emission and circularly polarized luminescence spectra are determined based on vibronic calculations. The resulting spectra are in good agreement with the experimentally available data, highlighting that both absorption-and emission-based spectra of the systems can be modeled computationally such that reliable predictions can be made for systems that are yet to be synthesized. more...
- Published
- 2022
199. Electric Properties of Photochromic Molecules Physisorbed on Silver and Copper Nanoparticles
- Author
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Hillers-Bendtsen, Andreas Erbs, Kjeldal, Frederik Ørsted, Mikkelsen, Kurt V., Hillers-Bendtsen, Andreas Erbs, Kjeldal, Frederik Ørsted, and Mikkelsen, Kurt V.
- Abstract
This paper investigates the electric properties of the photochromic dihydroazulene/vinylheptafulvene system as it is physisorbed onto silver and copper nanoparticles. Our focus is on how the polarizability and hyperpolarizability of the dihydroazulene, s-cis-vinylheptafulvene, and s-trans-vinylheptafulvene molecules depend on molecular orientation with respect to the nanoparticles, the molecule-cluster separation, and the type of nanoparticle. The computational approach utilizes a combined quantum mechanical/molecular mechanical method in which the molecules are treated quantum mechanically while the nanoparticles are treated with a simpler classical method. The molecules are described with density functional theory. The electric properties are calculated using response theory utilizing the long-range-corrected functional CAM-B3LYP and the correlation consistent basis set aug-cc-pVDZ. The atoms of the nanoparticles are represented using atomic polarizabilities. The interactions between the nanoparticles and the molecular systems are calculated using a polarizable embedding scheme after which the molecular properties are calculated with time-dependent density functional theory. The results show that the electric properties are indeed affected by the presence of the nanoparticles. It is also clear that it is the hyperpolarizabilities that change the most while the polarizabilities are less affected. Furthermore, the influence of the nanoparticles on the molecules depends heavily on the relative molecular orientation with respect to the nanoparticles and molecular conformation. Finally, it is observed that a copper nanoparticle has a larger influence on the molecular systems than a silver nanoparticle. more...
- Published
- 2022
200. Optimization of the thermochemical properties of the norbornadiene/quadricyclane photochromic couple for solar energy storage using nanoparticles
- Author
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Hillers-bendtsen, Andreas Erbs, Kjeldal, Frederik Ørsted, Høyer, Nicolai Machholdt, Mikkelsen, Kurt V., Hillers-bendtsen, Andreas Erbs, Kjeldal, Frederik Ørsted, Høyer, Nicolai Machholdt, and Mikkelsen, Kurt V. more...
- Abstract
In this paper, we present an investigation concerning the prospects of using nanoparticles to improve solar energy storage properties of three different norbornadiene/quadricyclane derivatives. Computationally, we study how different nanoparticles influence the properties of the systems that relate to the storage of solar energy, namely, the storage energy and the back reaction barrier. Our approach employs hybrid quantum mechanical/molecular mechanical calculations in which the molecular systems are described using density functional theory while the nanoparticles are described using molecular mechanics. The interactions between the two subsystems are determined using polarization dynamics. The results show that the influence of the nanoparticles on the thermochemical properties largely depends on the type of nanoparticle used, the relative orientation with respect to the nanoparticle, and the distance between the the nanoparticle and the molecular system. Additionally, we find indications that copper and/or titanium dioxide nanoparticles can lower the energy barrier of the back reaction for all of the studied systems without significantly lowering the storage capability of the systems. Consequently, the study shows that nanoparticles can potentially be employed in the optimization of molecular photoswitches towards solar energy storage. more...
- Published
- 2022
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