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This work extends an existing analytical solution for pressure buildup due to CO2 injection in brine aquifers by incorporating effects associated with partial miscibility. These include evaporation of water into CO2, dissolution of CO2 into brine and salt precipitation. The resulting equations are closed-form, including the locations of the associated leading and trailing shock fronts. Derivation of the analytical solution involved making a number of simplifying assumptions including: (1) vertical pressure equilibrium; (2) negligible capillary pressure; and (3) constant fluid properties. The analytical solution was compared to results from TOUGH2 and found to accurately approximate the extent of the dry-out zone around the well, the resulting permeability enhancement due to residual brine evaporation, the volumetric saturation of precipitated salt, and the vertically averaged pressure distribution in both space and time for the four scenarios studied. Whilst brine evaporation is found to have a considerable effect on pressure, the effect of CO2 dissolution is found to be small. The resulting equations remain simple to evaluate in spreadsheet software and represent a significant improvement on current methods for estimating pressure limited CO2 storage capacity. [ABSTRACT FROM AUTHOR]

Abstract: Mathematical tools are needed to screen out sites where Joule–Thomson cooling is a prohibitive factor for CO2 geo-sequestration and to design approaches to mitigate the effect. In this paper, a simple analytical solution is developed by invoking steady-state flow and constant thermophysical properties. The analytical solution allows fast evaluation of spatiotemporal temperature fields, resulting from constant-rate CO2 injection. The applicability of the analytical solution is demonstrated by comparison with non-isothermal simulation results from the reservoir simulator TOUGH2. Analysis confirms that for an injection rate of 3kgs−1 (0.1MTyr−1) into moderately warm (>40°C) and permeable formations (>10−14 m2 (10mD)), JTC is unlikely to be a problem for initial reservoir pressures as low as 2MPa (290psi). [ABSTRACT FROM AUTHOR]

Tidal measurements are of great significance since they may provide us with essential data to apply towards protection of coastal communities and sea traffic. Currently, tide gauge stations and laser altimetry are commonly used for these measurements. On the other hand, muography sensors can be located underneath the seafloor inside an undersea tunnel where electric and telecommunication infrastructures are more readily available. In this work, the world's first under-seafloor particle detector array called the Tokyo-bay Seafloor Hyper-Kilometric Submarine Deep Detector (TS-HKMSDD) was deployed underneath the Tokyo-Bay seafloor for conducting submarine muography. The resultant 80-day consecutive time-sequential muographic data were converted to the tidal levels based on the parameters determined from the first-day astronomical tide height (ATH) data. The standard deviation between ATH and muographic results for the rest of a 79-day measurement period was 12.85 cm. We anticipate that if the length of the TS-HKMSDD is extended from 100 m to a full-scale as large as 9.6 km to provide continuous tidal information along the tunnel, this muography application will become an established standard, demonstrating its effectiveness as practical tide monitor for this heavy traffic waterway in Tokyo and in other important sea traffic areas worldwide. [ABSTRACT FROM AUTHOR]

Proximal to distal fan change in grain size, clay matrix content, and grain-coating clays have been identified as key contributing factors for eservoir quality evolution of submarine fan turbidite sandstones. This study evaluated the role played by grain-coating and pore-filling clays, depositional facies, and diagenesis in reservoir quality evolution of the Paleocene Forties submarine fan sandstones (Central North Sea) from proximal to distal fan settings. To help provide a comprehensive understanding of the role played by pore-filling and grain-coating clays in destroying and preserving reservoir quality, respectively, in turbidite sandstones, we have used a multi-disciplinary approach including petrography, burial history, scanning electron microscopy, and stable isotopes analysis. Results of the study showed that reservoir quality is influenced by both depositional facies and diagenesis. The proximal-fan, amalgamated sandstones facies have the best reservoir quality due to coarser grain size, lower pore-filling clays, and lower amount of ductile grains. In contrast, the distal-fan, mud-prone heterolithic facies have the poorest reservoir quality due to finer grain size, higher pore-filling clays, and higher amount of ductile grains. Pore-filling clays between 10 and 30% have a deleterious effect on reservoir quality, reducing porosities and permeabilities to generally <10% and <1 mD, respectively. Based on the relatively shallow, present-day burial depths of the studied Forties Sandstone Member (2200–3100 m TVDSS), the percentage of clay-coating coverage to significantly inhibit quartz cementation ranges from 40 to 50%. Detrital, grain-coating smectites, probably inherited from the shelf/continental environments and/or emplaced through sediment dewatering, have transformed into chlorite, illite, and illite-smectite. Calcite and siderite, where well-developed, have arrested mechanical compaction and also occluded porosity, thereby rapidly degrading reservoir quality in the sandstones; however, their dissolution by acidic pore fluids could potentially create secondary intergranular porosity, enhancing reservoir quality of the sandstones. Evidence presented demonstrates that, high quality reservoir sandstones that deviate from normal porosity-depth trends for submarine fans sandstones can be attributed to facies changes (composition and grain size) with a complex interplay of mechanical compaction, detrital clays and authigenic clay coatings inhibiting quartz cement precipitation. • Reservoir quality of submarine fan turbidites is controlled by depositional facies and diagenesis. • Down-fan fining and change in clay content impact significantly on reservoir quality of submarine fan turbidites. • Grain-coating and pore-filling clays play a significant role in reservoir quality control of submarine fan turbidite sandstones. The percentage of clay-coat coverage to inhibit quartz cementation ranges between 40 and 50%. Quartz cementation in turbidite sandstones is inhibited by grain-coating clays such as chlorite and illite/illite-smectite. • Carbonate cements, where well-developed, have affected reservoir quality of the sandstones. [ABSTRACT FROM AUTHOR]

Understanding eodiagenesis is essential to decoding the diagenetic pathways of tight sandstones that act as excellent unconventional oil & gas reservoirs. Great paleoclimate change is capable of influencing eodiagenetic processes of tight sandstones through variations of sedimentary environment. However, it is less noted how climate gradients between the greenhouse and the hothouse conditions impact the eodiagenesis of tight sandstones. We examined eodiagenetic processes that has been operated in the Shaximiao Formation sandstones using petrographic observation, scanning electron microscopy, geochemistry, and XRD analysis to reveal impacts of the transitional climate changes on the differential eodiagenesis and implications for the diagenesis-porosity evolution. Based on sequence stratigraphy, the Shaximiao Formation is divided into four sub-members SXM1, SXM2, SXM3, and SXM4, respectively. Dark sandstones and mudstones mainly occurred in the SXM1 and the SXM2. Grey-green clastic rocks are dominant in the SXM3, whereas red mudstones frequently appear in the SXM4. Paleoclimate indices denote that a cyclical aridification from the warm-humid to hot-semiarid conditions took place from the SXM1 to the SXM4. It could have been caused by the megamonsoon effect and the paleogeographic shift along with the breakup of the Pangaea supercontinent. Combined with the migration of depocenters, the paleoclimate change resulted in transformation of sediment provenances from mafic igneous rocks to quartzose sedimentary rock along with the decreasing textural maturity. Therefore, sedimentary environments varied from the high-saline to low-saline and from low-oxygen to high-oxygen conditions respectively, which had a crucial impact on eodiagenetic cements which were formed in the Shaximiao Formation. Chlorite and laumontite cement precipitation was promoted by high-saline alkaline fluids. Chlorite proportions show an arched trend from the SXM1 to the SXM4, compatible with those of primary and secondary porosities. In contrast, laumontite proportions exhibit a decreasing variation from the SXM1 to the SXM4. High percentages of early cements are favorable to improving resistance to the compaction and preservation of primary pores. However, high chlorite (>5%) and laumontite (>10%) proportions are destructive for the reservoir quality. Large quantities of laumontite cements occupy primary pores and impede diagenetic fluids flowing and are not favorable to the dissolution. By contrast, an excess of chlorite cements can be dissolved to produce secondary pores during the organic acid release. Thus, the SXM2 is potential as a reservoir for oil & gas. Therefore, those eodiagenetic cements can control the late diagenetic evolution and the reservoir quality. Observations made here have implications for understanding tight sandstone reservoirs elsewhere in the world. • A late Middle Jurassic cyclical aridification occurred in the Central Sichuan Basin. • Sources of the Shaximiao Formation transformed from mafic to quartzose detrita. • Sedimentary environments varied with salinity decreasing and oxidation strengthening. • Types and intensity of eodiagenesis control late diagenesis and reservoir quality. [ABSTRACT FROM AUTHOR]

Abstract The feldspar group is one of the most common types of minerals in the earth's crust. Feldspar alteration (including the whole processes of feldspar dissolution, transfer of released solutes, and secondary mineral precipitation) is ubiquitous and important in fields including resources and environmental sciences. This paper provides a critical review of feldspar alteration and its geological significance in shallow aquifers to deep hydrocarbon reservoirs, as assessed from peer-reviewed paper in the literature. A variety of mechanisms such as the surface reaction-controlled dissolution mechanism, the preferential leaching-diffusion controlled mechanism, the diffusion-precipitation controlled dissolution mechanism and the interfacial dissolution-reprecipitation mechanism have been proposed to be responsible for the dissolution of feldspars. Feldspar dissolution rates can be affected by the crystal structure, Al/Si ordering, temperature, pH, surface area, organic acids, chemical affinity, and precipitation of secondary minerals. Five main dissolution rate laws have been used to describe feldspar dissolution rates, including the linear transition state theory (L-TST) rate law, non-linear TST rate law, parallel rate law, stepwave model rate law, and partial equilibrium law. The rate inconsistency between laboratory experiments and field observations is interpreted with hypotheses that include the armoring effects of the coating secondary minerals on feldspar surfaces, the possible effects of leached layers, the approach to saturation with respect to feldspars, the inhibition by absorbed Al3+ on the feldspar surface, and the inhibition by simultaneous slow clay precipitation rates. The inorganic-original (meteoric water and deep hot water) and organic-original (kerogen and hydrocarbon degradation) hydrogen ion (H+) in a fluid can probably act as a significant catalyzer of fast dissolution of feldspars in shallow aquifers and deep hydrocarbon reservoirs. Various mineral assemblages including extensively leached feldspars with a wide range of associated amounts of clay minerals and quartz cements can be identified in subsurface reservoirs under different geological conditions. Feldspar dissolution can generate enhanced secondary porosities and rock permeability in open geochemical systems at shallow depth or at a moderate-deep depth where faults develop widely. While in closed geochemical systems at moderate-deep depth, feldspar dissolution is likely to generate redistributional secondary porosities and to decrease rock permeability. Authigenic clay minerals formed following feldspar dissolution alter rock wettability and affect the charging and entrapment of hydrocarbons in reservoir. Feldspar alteration may promote hydrocarbon degradation by promoting bioactivity or by consuming low molecular weight organic acids and CO 2 produced via oil degradation. Further work should be conducted to study hydrocarbon-water-feldspar interactions in deeply buried hydrocarbon reservoirs. Feldspar alteration may promote CO 2 sequestration by consumption of H+, generation of HCO 3 −, and pH buffering of formation water. K-feldspar alteration may also promote illitization in interbedded mudstones by supplying K+. [ABSTRACT FROM AUTHOR]

Abstract Organic-inorganic interactions after oil charging are critical for determining the ongoing evolution of hydrocarbons and rock quality in water-wet siliciclastic reservoirs. It is the conceptual approach of this study to simulate and decipher these interactions by using quantitative analyses of the interrelated changes of minerals, water, hydrocarbons, gases, and organic acids in heated oil-water-rock systems. The experimental results show that organic-inorganic interactions occur between the organic oil and inorganic feldspar in the presence of water. Water promotes the oil degradation by an extra supply of H+ and OH− ions. In the oil-water-rock systems, mutual exchanges of H+ and OH− ions among minerals, water, and hydrocarbons probably result in the mutual interactions between oil degradation and mineral alteration, with water serving as a matrix for the ion exchange. In the oil-water-feldspar system, feldspar alteration does not cease in the oil zone in the presence of some water and, inversely, oil degradation can even accelerate the alterations of the aluminosilicate minerals. The mineral alterations from feldspar to boehmite, illite, and muscovite promote the oil degradation in the oil-deionized water-feldspar systems with the mutual ion exchange. Due to a possible competition between the Brønsted acid sites in the minerals and the halide anions or the direct replacement of K-feldspar by albite, the mineral alterations retard the oil degradation in the oil-NaCl water-feldspar systems. The experimental results also indicate that oil degradation via free radical cross-linking and free radical thermal cracking is extensive in anhydrous oil systems and may lead to blocking of pores and throats by the generated pyrobitumen in the oil zone of a reservoir. In contrast, in the oil-water transition zone of a reservoir, oil degradation via thermal cracking and oxidative decomposition may dominate the oil degradation and may lead to the generation of secondary pores with leaching of minerals by the generated CO 2 and organic acids. This study demonstrates that organic-inorganic interactions are complex and proceed in diverse pathways in different hydrogeochemical systems. Thus, further quantitative investigations of the reaction pathways and reaction kinetics of coupled mineral alteration and oil degradation in oil-water-rock systems are warrented. Meanwhile, the incorporation of such organic-inorganic reactions into geochemical models will improve the prediction of the evolution of organic and inorganic species in petroleum reservoirs. [ABSTRACT FROM AUTHOR]

Abstract Temperature-controlled precipitation kinetics has become the overwhelmingly dominant hypothesis for the control of quartz cementation in sandstones. Here, we integrate quantitative petrographic data, high spatial resolution oxygen isotope analyses of quartz cement, basin modelling and a kinetic model for quartz precipitation to suggest that the supply of silica from stress-sensitive intergranular pressure dissolution at grain contacts is in fact a key control on quartz cementation in sandstones. We present data from highly overpressured sandstones in which, despite the current burial temperature of 190 °C, quartz cement occurs in low amounts (4.6 ± 1.2% of bulk volume). In situ oxygen isotope data across quartz overgrowths suggest that cementation occurred over 100 Ma and a temperature range of 80–150 °C, during which time high fluid overpressures resulted in consistently low vertical effective stress. We argue that the very low amounts of quartz cement can only be explained by the low vertical effective stress which occurred throughout the burial history and which restricted silica supply as a result of a low rate of intergranular pressure dissolution at grain contacts. Highlights • Very low volumes of quartz cement in sandstones buried to 190 °C • Temperature-controlled precipitation kinetic model cannot explain the lack of quartz cement • Oxygen isotope data support very low rates of quartz cementation • History of low effective stress restricts silica supply via dissolution at grain contacts [ABSTRACT FROM AUTHOR]

Abstract The Palaeocene fluvial to shallow marine sandstones of the Farewell Formation are an important proven hydrocarbon reservoir in the Taranaki Basin, New Zealand. The Kapuni Deep-1 well was drilled to target Farewell Formation sandstones in the deeper overpressured (>5000 m, >3000 psi/21 MPa) sections of the onshore Manaia Graben of the Taranaki Basin. However, the Farewell Formation sandstones display anomalously low measured helium porosities (1–4.5%) and intergranular volumes (6–11%) even for their present-day, close to maximum, burial depth (c.5000 m). One dimensional burial history modelling demonstrates initial rapid burial leading to significant porosity reduction via mechanical compaction, enhanced by poor sorting, angular grain morphology and the presence of ductile grains, which allowed efficient packing and plastic deformation. Low intergranular volume (IGV), anhedral nature of quartz overgrowths, a general lack of fluid inclusions, and poor crystalline clay mineral content indicate that early burial compactional processes significantly influenced reservoir quality. The lack of mudstone to siltstone grade lithologies within the overlying Eocene section inhibited the early or shallow onset of overpressure in the Farewell Formation. One dimensional basin modelling has shown that rapid Pliocene subsidence related to exceptionally high sedimentation rates generated overpressure through disequilibrium compaction in the overlying Oligocene to early Miocene section during the past 6 Ma. However, the late and deep (>3000 m) onset of overpressure had no effect on arresting porosity loss in the Farewell Formation. Continued compaction of Farewell Formation sandstones after dissolution of early carbonate cements of CO 2 rich fluids creates zones of extremely low permeability, which have the potential to act with interbedded shales to form pressure seals as seen in the Kapuni Field. Highlights • High vertical effective stress drives porosity reduction in the deep Taranaki Basin. • Onset and development of overpressure is defined through 1D basin modelling. • Porosity and intergranular volume is anomalously low for present burial depth. • Vertical pressure seals within sandstones are identified. [ABSTRACT FROM AUTHOR]

An example of diagenesis and reservoir quality of buried sandstones with ancient incursion of meteoric freshwater is presented in this study. The interpretation is based on information including porosity and permeability, petrography, stable isotopic composition of authigenic minerals, homogenization temperatures (T h ) of aqueous fluid inclusions (AFIs), and pore water chemistry. These sandstones, closely beneath or far from the regional unconformity formed during the late Paleogene period, are located in the thick Shahejie Formation in the Gaoliu area of Nanpu Sag, Bohai Bay Basin, East China. Early-diagenetic calcite cements were leached to form intergranular secondary pores without precipitation of late-diagenetic calcite cements in most sandstones. Feldspars were leached to form abundant intragranular secondary pores, but with small amounts of concomitant secondary minerals including authigenic quartz and kaolinite. The mass imbalance between the amount of leached minerals and associated secondary minerals suggests that mineral leaching reactions occurred most likely in an open geochemical system, and diagenetic petrography textures suggest that advective flow dominated the transfer of solutes from leached feldspars and calcites. Low salinity and ion concentrations of present pore waters, and extensive water rock interactions suggest significant incursion of meteoric freshwater flux in the sandstones. Distances of the sandstones to the regional unconformity can reach up to 1800 m, while with significant uplift in the Gaoliu area, the burial depth of such sandstones (below sea level) can be less than 800–1000 m during the uplift and initial reburial stage. Significant uplift during the Oligocene period provided substantial hydraulic drive and widely developed faults served as favorable conduits for downward penetration of meteoric freshwater from the earth's surface (unconformity) to these sandstone beds. Extensive feldspar leaching has been occurring since the uplift period. Coupled high T h (95∼115 °C) of AFI and low δ 18 O (SMOW) values (+17∼+20‰) within the quartz overgrowths show that quartz cementation occurred in the presence of diagenetic modified meteoric freshwater with δ 18 O (SMOW) values of −7∼−2‰, indicating that authigenic quartz only have been formed during the late reburial stage when meteoric fresh water penetration slowed down. Secondary pores in thin sections and tested porosity suggest that meteoric freshwater leaching of feldspars and calcite minerals generated approximately 7–10% enhanced secondary porosity in these sandstones. Meteoric freshwater leaching reactions cannot be ignored in similar sandstones that located deep beneath the unconformity, with great uplift moving these sandstones above or close to sea level and with faults connecting the earth's surface with the sandstone beds. [ABSTRACT FROM AUTHOR]

Previously CO 2 , as a heat-extraction fluid, has been proposed as a superior substitute for brine in geothermal energy extraction. Hence, the new concept of CO 2 -plume geothermal (CPG) is suggested to generate heat from geothermal aquifers using CO 2 as the working fluid. In January 2015, a CPG-thermosiphon system commenced at the SECARB Cranfield Site, Mississippi. By utilizing CO 2 , the demand for the pumping power is greatly reduced due to the thermosiphon effect at the production well. However, there are still parameters such as aquifer thermal depletion, required high injection rates, and CO 2 -plume establishment time, that hinder CPG from becoming viable. Moreover, the fluvial nature of sedimentary aquifers significantly affects the heat and mass transfer inside the aquifer, as well as the system performance. In the present study, a direct-CO 2 thermosiphon system is considered that produces electricity from a 3D braided-fluvial sedimentary aquifer by providing an excess pressure at the surface that is used in the turbine. The system performance and net power output are analysed in 15 3D fluvial heterogeneous – with channels' widths of 50, 100, and 150 m – and three homogeneous aquifer realizations with different CO 2 injection rates. It is observed that the presence of fluvial channels significantly increases the aquifer thermal depletion pace (22%–120%) and therefore, reduces the system's performance up to about 75%. Additionally, it is found that the CPG system with the CO 2 injection rate of 50 kg/s and the I-P line parallel to the channels provides the maximum cycle operation time (44 years), as well as the optimum performance for the heterogeneous cases of the present study by providing about 0.06–0.12 TWh energy during the simulation time of 50 years. Also, to prevent rapid drops in excess pressure, a system with a yearly adjustable injection rate is implemented, which prevents the production well bottomhole temperature to fall below 80 °C. • Power analysis of a direct-CO 2 thermosiphon system from a 3D braided fluvial aquifer. • Fluvial heterogeneity reduces the system net power up to 75%. • CO 2 injection rate of 50 kg/s has the optimum performance for heterogeneous aquifers. • A CO 2 flowrate of 50 kg/s provides Pnet,avg of 0.3 MWe over 44 years for a homogeneous aquifer. • The cumulative electricity output of CPG over 50 years is in order of tenth of TWh. [ABSTRACT FROM AUTHOR]

Permeability heterogeneity of tight sandstone reservoir is mainly determined by the types and quantities of different cements and dissolution processes that occur during the burial. The thin section description, scanning electron microscopy (SEM), x-ray diffraction (XRD), cathodoluminescence imaging (CL), computed tomography (CT) scans, mercury intrusion tests, electron probe analysis, fluid inclusions and isotopic analysis were used to determine genetic mechanism and its impact on reservoir quality of differential cement combinations in Shaximiao Formation tight sandstone in the Central Sichuan Basin, China. Diagenetic minerals in the Shaximiao Formation (J 2 s) sandstone comprise calcite, laumontite, chlorite and dissolution. The pore space of J 2 s sandstone mainly comprises primary pores and secondary pores formed after mineral dissolution. The reservoir sandstones can be divided into six types according to different combinations of the laumontite, chlorite and calcite. Authigenic chlorite coating of J 2 s sandstones occurred via chloritization of smectite during eodiagenesis. Laumontite cements derived from transformation of volcanic rock fragments, were precipitated in a strong alkaline environment with high pH value (9.5–12) and abundant Ca2+, Si4+, Al3+ during eodiagenesis. The δ13C and δ18O isotopic values and petrological characteristics indicate that calcite cement was related to feldspar dissolution and decarboxylation of organic matter. The different cement combinations were determined mainly by the sedimentary facies and subsequent diagenetic environment evolution. Laumontite precipitation needs a stronger alkaline diagenetic environment than that for chlorite and calcite. The early chlorite coating provided sufficient remaining pore-space for pore-filling laumontite and calcite precipitation. The presence of pore-filling laumontite decreased space for calcite precipitation. However, laumontite is more readily soluble than calcite. The different cement combinations have distinct residual pore space combinations meaning that some intervals of rock have sufficient permeability to act as viable reservoir rock whilst other combinations do not. • Laumontite-chlorite -calcite system can be divided into six combination types. • Cements combinations were determined by sedimentary facies and diagenetic evolution. • Differential precipitation of cements produces strong sandstone heterogeneity. [ABSTRACT FROM AUTHOR]

The differential interferometric synthetic aperture radar (DInSAR) remote sensing technique has proven to be invaluable in the remote monitoring of earth surface movements associated with the extraction and geostorage (subsurface injection) of natural resources (water, oil, gas). However, a significant limitation of this technique is the low density and uneven coverage that may be achieved over vegetated rural environments. The Intermittent Small Baseline Subset (ISBAS) method, an amended version of the established SBAS algorithm, has been designed to improve coverage over rural, vegetated, land cover classes by allowing for the intermittent coherence that is predominant in such areas. In this paper we perform a validation of the ISBAS method over an area of gas production and geostorage in North Holland, the Netherlands. Forty-two ERS-2 (SAR) C-band images (1995–2000) and 63 ENVISAT (ASAR) C-band images (2003–2010) were processed using the ISBAS technique and the derived measurements enabled the identification of subsidence patterns in rural and urban areas alike. The dominant feature was an area of subsidence to the west of Alkmaar, attributed to natural gas production from the Bergermeer reservoir, where subsidence rates in the region of 3 mm/year were measured. Displacements derived using linear and non-linear surface deformation models were validated with respect to the first order system of levelling benchmarks which form the Amsterdam Ordnance Datum (NAP). It was established that ISBAS products were accurate to within 1.52 mm/year and 1.12 mm/year for the ERS and ENVISAT data sets respectively. Errors achieved were comparable to results using persistent scatterers interferometry (PSI) during a validation activity carried out in the European Space Agency Terrafirma project. These results confirm the capability of the ISBAS method to provide a more regular sampling of land motion measurements over gas fields that may be critically used in future to infer the properties of buried, fluid-filled, porous rock. [ABSTRACT FROM AUTHOR]

Turbidite deposits, overpressure, hydrothermal fluid activity, and CO 2 accumulations are the basic geologic characteristics of the Upper Miocene Huangliu Formation sandstone reservoir in the Dongfang gas field, Yinggehai Basin. This study aims to unravel the timing and origin of dissolution in sandstone and evaluate the effects of inorganic CO 2 accumulation on reservoir quality. A comparative study between area DFX-1 (CO 2 -rich) and area DFX-2 (CO 2 -poor) has illustrated the differences in diagenetic alteration and the effects of CO 2 accumulation on the sandstone reservoir. Diagenetic alteration of sandstones in area DFX-1 was characterised by intense dissolution and medium cementation. Dissolution of silicates following inorganic CO 2 charging in the DFX-1 area created a higher percentage of dissolution porosity (41.0%–53.9% of total visible porosity), compared with minor dissolution porosity in the DFX-2 area (16.7%–29.6% of total visible porosity). Small amounts of kaolinite, authigenic quartz, ankerite, and siderite were precipitated by CO 2 -water-rock reactions in area DFX-1; these minerals are almost absent in area DFX-2. The carbonate cement of the Huangliu Formation sandstone in area DFX-1 is characterised by light δ 13 C (−3.3‰ to −1.6‰, PDB), which is consistent with formation from inorganic carbon. The timing of dissolution by inorganic CO 2 is suggested to be at about 0.4 Ma based on the previous simulation experiments. In the two areas studied, overpressure was caused by pressure transmission along deep open faults and was not related to mudstone undercompaction. Overpressure did a little to contribute to porosity preservation. CO 2 accumulating at low partial pressures related to hydrothermal fluid flow cannot make a net increase in porosity in the Huangliu Formation sandstone of the Dongfang gas field. [ABSTRACT FROM AUTHOR]

Thin-bedded beach-bar sandstone reservoirs are common in the Eocene Shahejie Formation (Es4s) of Niuzhuang Sag, along the southern gentle slope of the Dongying Depression. Here we report on the link between sequence stratigraphy, sedimentary facies and diagenetic effects on reservoir quality. Seismic data, wireline logs, core observations and analyses are used to interpret depositional settings and sequence stratigraphic framework. Petrographic study based on microscopic observation of optical, cathodoluminescence (CL), confocal laser scanning (LSCM) and scanning electron microscope (SEM) and X-ray diffraction (XRD) analyses were used to describe the fabric, texture, allogenic and authigenic mineralogy of these highly heterogeneous sandstone reservoirs. The Es4s interval is interpreted as third-order sequence, composed of a lowstand systems tract (LST), a transgressive systems tract (TST) and a highstand systems tract (HST). On the fourth order, twenty-nine parasequences and seven parasequence sets have been identified. Sand bodies were deposited mainly in the shoreface shallow lake beach-bar (clastic beach-bar), semi-deep lake (carbonate beach-bar) and the fluvial channels. The depositional and diagenetic heterogeneities were mainly due to the following factors: (1) fine grain size, poor sorting, and continuous thin inter-bedded mud layers with siltstone/fine-sandstone having argillaceous layers in regular intervals, (2) immature sediment composition, and (3) even with the dissolution of grains and several fractures, destruction of porosity by cementation and compaction. Secondary pores from feldspar dissolution are better developed in sandstones with increased cementation. Grain coating smectite clays preserved the primary porosity at places while dominating pore filling authigenic illite and illite/smectite clays reduced permeability with little impact on porosity. Due to the high degree of heterogeneity in the Es4s beach-bar interval, it is recognized as middle to low permeable reservoir. The aforementioned study reflects significant insight into the understanding of the properties of the beach-bar sands and valuable for the comprehensive reservoir characterization and overall reservoir bed quality. [ABSTRACT FROM AUTHOR]

We review the distribution, timing and probable causes of ∼8000 onshore UK seismic events between the years 1970–2012. Of 1769 onshore seismic events with local magnitudes (M L ) ≥ 1.5, we estimate at least ∼21% of these have an anthropogenic origin, at least ∼40% were natural and ∼39% have an undetermined, anthropogenic or natural origin. The majority of the anthropogenic related earthquakes were caused by coal mining and the decline in their numbers from the 1980s to the 2000s was concurrent with a decline in UK coal production. To date, two earthquakes with M L ≥ 1.5 have been caused by hydraulic fracturing. We have a high level of confidence that the mean number of anthropogenic related earthquakes (M L ≥ 1.5) per year onshore in the UK since 1999 is at least three with an annual range of between zero and eight. If we assumed that 50% of the undetermined events had an anthropogenic origin the mean per year increases to twelve. Although there are inherent uncertainties in assigning an anthropogenic versus natural cause for historical earthquakes, these values provide a baseline for the UK, the first of its kind for any nation state, in advance of the presently planned shale gas and oil exploitation. [ABSTRACT FROM AUTHOR]

North Sea oil is overwhelmingly generated in shales of the Upper Jurassic – basal Cretaceous Kimmeridge Clay Formation. Once generated, the oil is expelled and ultimately migrates to accumulate in sandstone or carbonate reservoirs. The source rock shales, however, still contain the portion of the oil that was not expelled. As a consequence such shales and juxtaposed non-source lithofacies can form the targets for the exploration of ‘unconventional oil’. In this paper, we examine part of the Kimmeridge Clay Formation as a hybrid shale resource system within which ‘Hot Shale’ and organic-lean sandstone and siltstone intervals are intimately interbedded. This hybrid system can contain a greater volume of oil because of the increased storage capacity due to larger matrix porosities of the sand-silt interbeds, together with a lower adsorptive affinity in the interbedded sandstone. The relationship between the estimated volume percentages of sand and mudstone and free oil determined from Rock-Eval ® S1 yields is used to place limits on the drainage of oil from source mudstone to reservoir sand at the decimeter scale. These data are used to determine oil saturations in interbedded sand-mudstone sequences at peak oil maturity. Higher values of free hydrocarbon (as evidenced by the S1 value in mudstone) suggest that more oil is being retained in the mudstone, while higher S1 values in the interbedded sands suggest the oil is being drained to saturate the larger pore spaces. High silica content in the interbeds confirms the brittleness in this mudstone–sandstone lithofacies – an important factor to be considered for fracture stimulation to successfully work in a hybrid system. The key points of this hybrid unconventional system are the thickness, storage capacity and the possibility to capture a portion of the expelled, as well as retained oil. [ABSTRACT FROM AUTHOR]

Carbonates are suggested to dissolve rapidly than feldspars by laboratory experiments. Petrography texture of selective dissolution of feldspars in the presence of carbonates, however, is widespread in buried sandstones and even shales, inspiring a revisit to the chemistry of burial secondary pores. Feldspar dissolution, precipitation of secondary minerals (quartz, clays), and carbonate cementation are common chemical reactions in the Eocene sandstones in the northern Dongying Sag. Petrography evidence demonstrates the selective dissolution of feldspars in the presence of carbonate minerals (both detrital and authigenic minerals) in these buried sandstones. The equilibrium constant of calcite leaching reactions is much smaller than that of K-feldspar leaching reactions. Numerical simulations of chemical reactions in K-feldspar-calcite–CO 2 –H 2 O systems utilizing the Geochemist's Workbench 9.0 (GWB) indicate that only a small amount of calcite was dissolved at the onset of simulation processes, while much K-feldspar was dissolved with precipitation of quartz, clays and some calcite for extended periods of time. Precipitation of secondary calcite could also promote feldspar dissolution. Simulation of reactions in a simplified sandstone system with constraints of present-day pore water and partical pressure of carbon dioxide (pCO 2 ) in the northern Dongying Sag indicates that the pore waters are close to equilibrium with calcite. Petrography evidence and modeling results share consistence in confirming that only feldspar could be dissolved extensively, with precipitation of quartz, clays and some carbonate minerals. The organic CO 2 -leaching theory (Schmidt and McDonald, 1979) regarding the dissolution of mainly carbonates and, to a lesser degree, feldspars to form secondary pores has been questioned due to supposed extensive internal consumption of organic CO 2 in source rocks by carbonate minerals. The CO 2 in sandstones and shales and the isotopic composition of CO 2 and carbonate cements in sandstones, however, suggest migration of organic CO 2 from mudstones (even with large amounts of carbonate) to sandstones. Calculations in this study indicate that, with suppression of carbonate dissolution in sedimentary rocks, many secondary pores can be generated in sandstones through selective dissolution of feldspar by organic CO 2 from thermal evolution of organic matter. Selective dissolution of feldspars, rather than carbonates, in sedimentary rocks is then likely a general mechanism to decipher the chemistry of secondary porosity. Other secondary porosity generation mechanisms were also reevaluated with numerical simulations. Results demonstrate that reverse weathering reactions of silicates may take place with increasing of temperatures, but cannot provide enough H + to dissolve carbonates at elevated temperatures. Additionally, cooling of hot fluids can dissolve only insignificant amounts of carbonate unless significant amounts of water are provided. [ABSTRACT FROM AUTHOR]

Traditionally the power demand of offshore oil platforms is delivered by on-platform gas turbines. Natural gas to fuel these turbines is usually separated from the produced oil. However, in ageing fields as oil production declines so does the associated gas. Ultimately gas supply becomes insufficient; in order to continue producing fuel is imported at great expense. This study proposes the power demand of a platform could be met or supplemented by an on-platform ORC (organic Rankine cycle ) fuelled by coproduced hot brines. This could extend the operating life of oil platforms and reduce both cost and emissions. The potential power output of an ORC is modelled for fields in the North Sea's Brent Province. Results show 6 fields have the potential to generate more than 10 MW via an organic Rankine cycle fuelled by hot brines, with a maximum of 31 MW predicted for the Ninian field. Analysis of simulations for the Eider field shows that ORC plants can scale to size constraints. The cost of a 10 MW ORC is compared to cost of continued use of gas turbines. Payback times of between 3.09 and 4.53 years are predicted for an ORC, without accounting for greenhouse gas emissions levies. [ABSTRACT FROM AUTHOR]

The following study considers the spatial distribution, grade and seasonal variation of waste-heat from industrial sectors in the United Kingdom in 2018. Opportunities to offset the emissions caused by heat generation through the use of waste-heat recovery schemes have been examined. Reducing heat waste is a key intermediate step in avoiding climate disaster until fully decarbonised industrial practices have been developed and implemented. The findings of this study are presented as a 'UK waste heat map'. Data containing information on the natural gas consumption of different industries are used as a proxy for waste heat. This report finds that waste heat is concentrated around densely populated areas and areas with a traditionally strong industrial base. Such areas generate a large amount of the waste heat suitable for heat reuse, such as in a district heating scheme. The total waste heat from UK industry and electricity generation is estimated to be nearly 391,000 GWh per year. The data are represented in the accompanying UK waste heat map as point location data and by waste heat per Local Authority. Opportunities have been identified within each major industrial sector to reclaim and utilise this waste heat. • Waste heat from UK industry are mapped to identify potential waste-heat recovery. • UK industrial waste heat was estimated to be 391,000 GWh in 2018. • Waste heat is concentrated in areas of high population density. • Report details the methodology behind and interpretation of the UK waste heat map. • District heating from certain industries could increase reliance on natural gas. [ABSTRACT FROM AUTHOR]

Lacustrine shale reservoirs with interbedded organic-rich shales and thinly layered tight shell limestones are mainly developed in the Da'anzhai Member of the Lower Jurassic Ziliujing Formation in the Fuling area. These reservoirs generally have low porosities and permeabilities. Natural fractures provide effective spaces for these reservoirs and significantly improve fluid flow capability. However, little research has been conducted on the genesis and distribution of fractures in the Da'anzhai Shale Member. This study aims to understand the features, distribution, and factors that influence natural fractures of these shale reservoirs in the study area. Based on field outcrop observations, core descriptions, and thin section analysis, four types of natural fractures are developed in the study area: tensile fractures, shear fractures, interlayer bedding fractures, and diagenetic shrinkage fractures. Most low-angle and horizontal natural fractures have lengths of 5 cm–10 cm, and the effective fracture density is 0.90 pieces/m. The lithology (Y), thickness of the rock layer (H), regional tectonic stress (F), and fault scale (S) have a significant impact on the development of natural fractures. Most natural fractures develop when there is a large number of laminations in thin rock layers. The large regional tectonic stress in the Late Himalayan, which had a large fracture density index, leads to the formation of natural fractures in numerical simulations. Large faults would have co-developed with more fractures than small faults due to the high energy of large faults. The relationship between the effective permeability and the four parameters (i.e., Y , H , F , and S) was established. Based on this relationship, it is concluded that H is the most critical factor influencing the effective permeability of natural fractures in the study area. As a result, the middle to upper section in the 2nd subsection of the Da'anzhai Member, in which the lithofacies is thinly laminated shales with shells, can be considered to contain favourable shale gas layers. • Genesis and distribution of natural fractures in Da'anzhai Shale reservoir. • The thickness and frequency of interlayers and lamination mainly control on natural fracture intensity and penetration. • The thickness of interlayers is the most critical factor influencing the effective permeability of natural fractures. • The lithofacies of thin-shell lamination shales can be considered as favor shale gas layers. [ABSTRACT FROM AUTHOR]

The original article can be found online at https://doi.org/10.1038/s41598-021-98559-8. Correction to: I Scientific Reports i https://doi.org/10.1038/s41598-021-98559-8, published online 30 September 2021 In the original version of this Article, Masaki Satoh was incorrectly listed as an author of the original Article, and has subsequently been removed. [Extracted from the article]

We present quantitative petrographic data, high spatial resolution oxygen isotope analyses of quartz cement, basin modelling and a kinetic model for quartz precipitation for two Paleocene-Eocene Wilcox Group sandstones from Texas and two Jurassic Fulmar Formation sandstones from the Central North Sea. At each location, one sandstone has been buried to ca. 145 °C and one to ca. 185 °C. A key difference between the Wilcox and Fulmar burial histories is that the Wilcox sandstones are currently at higher vertical effective stresses and, from basin modelling studies, have been subjected to generally higher vertical effective stresses through their burial history. The amounts of quartz cement in the Wilcox sandstones are between 12 and 18%, and between 2 and 6% in the Fulmar sandstones. High-spatial-resolution oxygen isotope data obtained from the quartz cements suggest temperature ranges for quartz precipitation from 60 to 80 °C to values approaching maximum burial temperature. Factors such as grain coatings or the timing of petroleum emplacement cannot explain the differences in the amounts of quartz cement. Petrographic data show that most of the silica for quartz cement can be derived from intergranular pressure dissolution. Although the sample set is small, we interpret the results to suggest that the differences in quartz cementation in Fulmar and Wilcox sandstones can be explained better by differences in their vertical effective stress history than their temperature history; in this case, the supply of silica rather than the precipitation of quartz becomes an important control on the rate and extent of cementation. • 12–18% quartz cement in Wilcox sandstones; 2–6% in Fulmar sandstones. • O isotopes suggest quartz forms from 60 to 80 °C to close to maximum burial temperature. • Most silica for quartz cement can be derived from intergranular pressure dissolution. • Silica supply from IPD may influence rate and extent of quartz cementation. • Consider vertical effective stress history when predicting quartz cement. [ABSTRACT FROM AUTHOR]

Organic-inorganic interactions regulate the dynamics of hydrocarbons, water, minerals, CO 2 , and H 2 in thermal rocks, yet their initiation remains debated. To address this, we conducted isotope-tagged and in-situ visual thermal experiments. Isotope-tagged studies revealed extensive H/O transfers in hydrous n-C 20 H 42 -H 2 O-feldspar systems. Visual experiments observed water microdroplets forming at 150-165 °C in oil phases near the water-oil interface without surfactants, persisting until complete miscibility above 350 °C. Electron paramagnetic resonance (EPR) detected hydroxyl free radicals concurrent with microdroplet formation. Here we propose a two-fold mechanism: water-derived and n-C 20 H 42 -derived free radicals drive interactions with organic species, while water-derived and mineral-derived ions trigger mineral interactions. These processes, facilitated by microdroplets and bulk water, blur boundaries between organic and inorganic species, enabling extensive interactions and mass transfer. Our findings redefine microscopic interplays between organic and inorganic components, offering insights into diagenetic and hydrous-metamorphic processes, and mass transfer cycles in deep basins and subduction zones., (© 2024. The Author(s).)

Navigation in indoor and underground environments has been extensively studied to realize automation of home, hospital, office, factory and mining services, and various techniques have been proposed for its implementation. By utilizing the relativistic and penetrative nature of cosmic-ray muons, a completely new wireless navigation technique called wireless muometric navigation system (MuWNS) was developed. This paper shows the results of the world's first physical demonstration of MuWNS used on the basement floor inside a building to navigate (a person) in an area where global navigation satellite system (GNSS)/ global positioning system (GPS) signals cannot reach. The resultant navigation accuracy was comparable or better than the positioning accuracy attainable with single-point GNSS/GPS positioning in urban areas. With further improvements in stability of local clocks used for timing, it is anticipated that MuWNS can be adapted to improve autonomous mobile robot navigation and positioning as well as other underground and underwater practical applications., Competing Interests: The authors declare no competing interests., (© 2023.)

Helium, nitrogen and hydrogen are continually generated within the deep continental crust 1-9 . Conceptual degassing models for quiescent continental crust are dominated by an assumption that these gases are dissolved in water, and that vertical transport in shallower sedimentary systems is by diffusion within water-filled pore space (for example, refs. 7,8 ). Gas-phase exsolution is crucial for concentrating helium and forming a societal resource. Here we show that crustal nitrogen from the crystalline basement alone-degassing at a steady state in proportion to crustal helium-4 generation-can reach sufficient concentrations at the base of some sedimentary basins to form a free gas phase. Using a gas diffusion model coupled with sedimentary basin evolution, we demonstrate, using a classic intracratonic sedimentary basin (Williston Basin, North America), that crustal nitrogen reaches saturation and forms a gas phase; in this basin, as early as about 140 million years ago. Helium partitions into this gas phase. This gas formation mechanism accounts for the observed primary nitrogen-helium gas discovered in the basal sedimentary lithology of this and other basins, predicts co-occurrence of crustal gas-phase hydrogen, and reduces the flux of helium into overlying strata by about 30 per cent because of phase solubility buffering. Identification of this gas phase formation mechanism provides a quantitative insight to assess the helium and hydrogen resource potential in similar intracontinental sedimentary basins found worldwide., (© 2023. The Author(s), under exclusive licence to Springer Nature Limited.)

Large-scale solid bodies on Earth such as volcanoes and man-made pyramids have been visualized with solid earth muography, and the recently invented technique, acqueous muography, has already demonstrated its capability to visualize ocean tides and tsunami. In this work, atmospheric muography, a technique to visualize and monitor the vertical profile of tropic cyclones (TCs) is presented for the first time. The density distribution and time-dependent behavior of several TCs which had approached Kagoshima, Japan, has been investigated with muography. The resultant time-sequential images captured their warm cores, and their movements were consistent with the TC trails and barometric pressure variations observed at meteorological stations. By combining multidirectional muographic images with barometric data, we anticipate that muography will become a useful tool to monitor the three-dimensional density distribution of a targeted mesoscale convective system., (© 2022. The Author(s).)

Meteorological-tsunami-like (or meteotsunami-like) periodic oscillation was muographically detected with the Tokyo-Bay Seafloor Hyper-Kilometric Submarine Deep Detector (TS-HKMSDD) deployed in the underwater highway called the Trans-Tokyo Bay Expressway or Tokyo Bay Aqua-Line (TBAL). It was detected right after the arrival of the 2021 Typhoon-16 that passed through the region 400 km south of the bay. The measured oscillation period and decay time were respectively 3 h and 10 h. These measurements were found to be consistent with previous tide gauge measurements. Meteotsunamis are known to take place in bays and lakes, and the temporal and spatial characteristics of meteotsunamis are similar to seismic tsunamis. However, their generation and propagation mechanisms are not well understood. The current result indicates that a combination of muography and trans-bay or trans-lake underwater tunnels will offer an additional tool to measure meteotsunamis at locations where tide gauges are unavailable., (© 2022. The Author(s).)

Carbon capture and storage is a transition technology from a past and present fuelled by coal, oil and gas and a planned future dominated by renewable energy sources. The technology involves the capture of carbon dioxide emissions from fossil fuel power stations and other point sources, compression of the CO 2 into a fluid, transporting it and injecting it deep beneath the Earth's surface into depleted petroleum reservoirs and other porous formations. Once injected, the CO 2 must be monitored to ensure that it is emplaced and assimilated as planned and that none leaks back to surface. A variety of methods have been deployed to monitor the CO 2 storage site and many such methods have been adapted from oilfield practice. However, such methods are commonly indirect, episodic, require active signal generation and remain expensive throughout the monitoring period that may last for hundreds of years. A modelling framework was developed to concurrently simulate CO 2 geostorage conditions and background cosmic-ray muon tomography, in which the potential was assessed for using variations in muon attenuation, due to changes in CO 2 abundance, as a means of CO 2 detection. From this, we developed a passive, continuous monitoring method for CO 2 storage sites using muon tomography, the tools for which can be deployed during the active drilling phase (development) of the storage site. To do this, it was necessary to develop a muon detector that could be used in the hostile environment (saline, high temperature) of the well bore. A prototype detector has been built and tested at the 1.1 km deep Boulby potash mine on the northeast coast of England, supported by the existing STFC Boulby Underground Laboratory on the site. The detector is now ready to be commercialized.This article is part of the Theo Murphy meeting issue 'Cosmic-ray muography'., (© 2018 The Author(s).)