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We consider a model of a random copolymer at a selective interface which undergoes a localization/delocalization transition. In spite of the several rigorous results available for this model, the theoretical characterization of the phase transition has remained elusive and there is still no agreement about several important issues, for example the behavior of the polymer near the phase transition line. From a rigorous viewpoint non coinciding upper and lower bounds on the critical line are known. In this paper we combine numerical computations with rigorous arguments to get to a better understanding of the phase diagram. Our main results include: - Various numerical observations that suggest that the critical line lies strictly in between the two bounds. - A rigorous statistical test based on concentration inequalities and super-additivity, for determining whether a given point of the phase diagram is in the localized phase. This is applied in particular to show that, with a very low level of error, the lower bound does not coincide with the critical line. - An analysis of the precise asymptotic behavior of the partition function in the delocalized phase, with particular attention to the effect of rare atypical stretches in the disorder sequence and on whether or not in the delocalized regime the polymer path has a Brownian scaling. - A new proof of the lower bound on the critical line. This proof relies on a characterization of the localized regime which is more appealing for interpreting the numerical data., accepted for publication on J. Stat. Phys

Recently the renormalization group predictions on the effect of disorder on pinning models have been put on mathematical grounds. The picture is particularly complete if the disorder is 'relevant' or 'irrelevant' in the Harris criterion sense: the question addressed is whether quenched disorder leads to a critical behavior which is different from the one observed in the pure, i.e. annealed, system. The Harris criterion prediction is based on the sign of the specific heat exponent of the pure system, but it yields no prediction in the case of vanishing exponent. This case is called 'marginal', and the physical literature is divided on what one should observe for marginal disorder, notably there is no agreement on whether a small amount of disorder leads or not to a difference between the critical point of the quenched system and the one for the pure system. In a previous work (arXiv:0811.0723) we have proven that the two critical points differ at marginality of at least exp(-c/beta^4), where c>0 and beta^2 is the disorder variance, for beta in (0,1) and Gaussian IID disorder. The purpose of this paper is to improve such a result: we establish in particular that the exp(-c/beta^4) lower bound on the shift can be replaced by exp(-c(b)/beta^b), c(b)>0 for b>2 (b=2 is the known upper bound and it is the result claimed in [Derrida, Hakim, Vannimenus, JSP 1992]), and we deal with very general distribution of the IID disorder variables. The proof relies on coarse graining estimates and on a fractional moment-change of measure argument based on multi-body potential modifications of the law of the disorder., 30 pages

The effect of disorder on pinning and wetting models has attracted much attention in theoretical physics. In particular, it has been predicted on the basis of the Harris criterion that disorder is relevant (annealed and quenched model have different critical points and critical exponents) if the return probability exponent alpha, a positive number that characterizes the model, is larger than 1/2. Weak disorder has been predicted to be irrelevant (i.e. coinciding critical points and exponents) if alpha < 1/2. Recent mathematical work has put these predictions on firm grounds. In renormalization group terms, the case alpha = 1/2 is a 'marginal case' and there is no agreement in the literature as to whether one should expect disorder relevance or irrelevance at marginality. The question is particularly intriguing also because the case alpha = 1/2 includes the classical models of two-dimensional wetting of a rough substrate, of pinning of directed polymers on a defect line in dimension (3+1) or (1+1) and of pinning of an heteropolymer by a point potential in three-dimensional space. Here we prove disorder relevance both for the general alpha = 1/2 pinning model and for the hierarchical version of the model proposed by B. Derrida, V. Hakim and J. Vannimenus (JSP, 1992), in the sense that we prove a shift of the quenched critical point with respect to the annealed one. In both cases we work with Gaussian disorder and we show that the shift is at least of order exp(-1/��^4) for beta small, if beta is the standard deviation of the disorder., 27 pages. v2: section 4.1 simplified. To appear on Commun. Pure Appl. Math

We consider a hierarchical model of polymer pinning in presence of quenched disorder, introduced by B. Derrida, V. Hakim and J. Vannimenius in 1992, which can be re-interpreted as an infinite dimensional dynamical system with random initial condition (the disorder). It is defined through a recurrence relation for the law of a random variable {R_n}_{n=1,2,...}, which in absence of disorder (i.e., when the initial condition is degenerate) reduces to a particular case of the well-known Logistic Map. The large-n limit of the sequence of random variables 2^{-n} log R_n, a non-random quantity which is naturally interpreted as a free energy, plays a central role in our analysis. The model depends on a parameter alpha>0, related to the geometry of the hierarchical lattice, and has a phase transition in the sense that the free energy is positive if the expectation of R_0 is larger than a certain threshold value, and it is zero otherwise. It was conjectured by Derrida et al. (1992) that disorder is relevant (respectively, irrelevant or marginally relevant) if 1/21/2 we find the correct scaling form (for weak disorder) of the critical point shift., Comment: 26 pages, 2 figures. v3: Theorem 1.6 improved. To appear on Probab. Theory Rel. Fields

We study the critical point of directed pinning/wetting models with quenched disorder. The distribution K(.) of the location of the first contact of the (free) polymer with the defect line is assumed to be of the form K(n)=n^{-\alpha-1}L(n), with L(.) slowly varying. The model undergoes a (de)-localization phase transition: the free energy (per unit length) is zero in the delocalized phase and positive in the localized phase. For \alpha1, then quenched and annealed critical points differ whenever disorder is present, and we give the scaling form of their difference for small disorder. In agreement with the so-called Harris criterion, disorder is therefore relevant in this case. In the marginal case \alpha=1/2, under the assumption that L(.) vanishes sufficiently fast at infinity, we prove that the difference between quenched and annealed critical points, which is known to be smaller than any power of the disorder strength, is positive: disorder is marginally relevant. Again, the case considered by Forgacs et al. (1986) and Derrida et al. (1992) is out of our analysis and remains open., Comment: 20 pages, 1 figure; v2: few typos corrected, references revised. To appear on Commun. Math. Phys

We consider general disordered models of pinning of directed polymers on a defect line. This class contains in particular the $(1+1)$--dimensional interface wetting model, the disordered Poland--Scheraga model of DNA denaturation and other $(1+d)$--dimensional polymers in interaction with flat interfaces. We consider also the case of copolymers with adsorption at a selective interface. Under quite general conditions, these models are known to have a (de)localization transition at some critical line in the phase diagram. In this work we prove in particular that, as soon as disorder is present, the transition is at least of second order, in the sense that the free energy is differentiable at the critical line, so that the order parameter vanishes continuously at the transition. On the other hand, it is known that the corresponding non--disordered models can have a first order (de)localization transition, with a discontinuous first derivative. Our result shows therefore that the presence of the disorder has really a smoothing effect on the transition. The relation with the predictions based on the Harris criterion is discussed., Comment: 16 pages, 1 figure. v3: proof of the main theorem simplified, typos corrected, 1 reference added. To appear on Commun. Math. Phys