101. Lewis acid activation of Weiss’ reagents ([PhI(Pyr)2]2+) with boranes and isolation of [PhI(4-DMAP)]2+
- Author
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Tiffany B. Poynder, Jack K. Clegg, David J. D. Wilson, Aseel Bakro, Jason L. Dutton, and Lachlan Sharp-Bucknall
- Subjects
010405 organic chemistry ,Xylene ,Metals and Alloys ,Boranes ,General Chemistry ,Electrophilic aromatic substitution ,010402 general chemistry ,01 natural sciences ,Medicinal chemistry ,Toluene ,Catalysis ,Pyridine ligand ,0104 chemical sciences ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,chemistry.chemical_compound ,chemistry ,Reagent ,Materials Chemistry ,Ceramics and Composites ,Lewis acids and bases ,Mesitylene - Abstract
ion of a pyridine ligand from Weiss’ reagent ([PhI(Pyr)2]2+) using BF3-Et2O was found to activate Weiss’ reagent towards electrophilic aromatic substitution reactions. The activated species can be isolated when 4-DMAP is used as the pyridine ligand and was determined to be [PhI(4-DMAP)]2+ in solution. The isolated cation was reactive in electrophilic aromatic substitution reactions towards mesitylene, xylene and toluene that Weiss’ reagent itself does not react with.
- Published
- 2021