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The platinum group elements (PGE) in the mafic-ultramafic suite in the Xinjie layered intrusion and associated basalts and syenites were analyzed using neutron activation techniques after fire-assay preconcentration. On this basis, the geochemistry of the platinum group during the magmatic stage is discussed. With respect to PGE distribution, the Xinjie layered intrusion is similar to the Bushveld ferruginous ultramafic series and is distinct from komatiite and Alpine-type peridotite. It is also similar to the Emeishan basalt in PGE characteristics, implying that the original magmas of them may be of the same type. [ABSTRACT FROM AUTHOR]

A serials of biomimetic photocatalyst zinc(II) meso-tetra(4-carboxyphenyl)porphyrinato (ZnTCP)-sensitized 3D hierarchical TiO2 hollow nanoboxes (TiO2-HNBs) assembled by six ordered nanosheets with dominant {001} facets exposure (ZnTCP@TiO2-HNBs) have been successfully synthesized by a facile one-pot solvothermal method via a topological transformation process with TiOF2 as template. Infrared spectra (IR), UV-vis spectroscopy, and X-ray photoelectron spectroscopy (XPS) confirmed that ZnTCP played a decisive role in constructing 3D hollow nanoboxes through the formation of ester bond combined to TiO2-HNBs, which also provided a transferring photo excited electrons bridge to sensitize TiO2-HNBs for enhancing visible-light response. Due to the superior sensitization and biomimetic activity of ZnTCP, the photodegradation rate of rhodamine B (RhB) of as-prepared ZnTCP@TiO2-HNBs with ZnTCP/TiOF2 mass ratio of 2% (T-2p) improves 3.6 times compared to that of TiO2-HNBs with a degradation yield of 99% for 2 h under simulated sunlight irradiation (> 420 nm). The enhanced photodegradation ability was attributed to synergistic visible photocatalytic mechanism of biomimetic catalyst, which can not only produce hydroxyl radical (•OH) and superoxide radical (•O2−) coming from the excitation process of ZnTCP sensitized TiO2-HNBs, but also generate singlet oxygen (1O2) that was only provided by biomimetic enzyme porphyrins. Furthermore, the photocatalyst showed good recycling stability and dispersibility after five rounds, ascribed to ZnTCP strong chemical bonding to the support TiO2-HNBs. By means of electrochemical cyclic voltammetry analysis, the effect of central zinc ions and parent porphyrin rings on the redox property of biomimetic catalyst was studied. [ABSTRACT FROM AUTHOR]

Imine covalent organic frameworks (I-COFs), including imine-linked COFs and hydrazone-linked COFs, are a new type of crystalline porous organic materials constructed by the condensation of organic monomers by the Schiff-base reaction. Because they are composed of lightweight elements linked by strong covalent bonds, I-COF materials possess the advantages of low skeleton density, large surface area, high porosity, abundant monomer species, controllable pore size, functionalized structure, diverse synthetic methods, excellent adsorption performance, outstanding physical and chemical stabilities, etc. In recent years, interest in the field of I-COFs has increased tremendously because of their exceptional performance and broad applications in gas storage, gas separation, catalysis, sensing, photoelectric materials, sample pretreatment, drug delivery, and other fields. To date, imine bonds are one of the most widely used covalent bonds in COFs, and represent one of the most important ways to obtain I-COFs with excellent chemical stabilities. The synthesis methods for I-COFs include solvothermal synthesis, microwave synthesis, mechanochemical grinding synthesis, and room-temperature synthesis methods. Solvothermal synthesis is the most extensively used method for the production of I-COFs with high specific surface areas and good thermal stabilities. The microwave synthesis method is conducive to the rapid synthesis of COFs in industry, providing a more time-saving, simpler, and safer route for large-scale preparation of I-COFs. The mechanochemical grinding synthesis of porous solids has gained importance as an alternative to conventional solvothermal synthesis, because the process is quick, environment-friendly, and potentially scalable. The room-temperature method is characterized by mild reaction conditions and rapid reactions. It is an energy-saving, economic, safe, and green synthesis method, which has emerged as a hot spot in the preparation of I-COFs in recent years. Research progress over the past years on the application of I-COFs in the field of materials science has undoubtedly established the basis of its application in analytical chemistry. Owing to the excellent physical and chemical properties of I-COF materials, they are suitable for use as separation and enrichment media for trace target compounds in complex samples. The high specific surface area and porosity, extended conjugate network skeleton, and π -electron-rich nature of the materials endow it with a high adsorption capacity. These materials are highly enriched in target analytes by π-π interactions, acid-base interactions, donor-acceptor interactions, hydrogen bonding, hydrophobic interactions, and other intermolecular interactions. Precise control of the microporous structure of I-COFs was obtained by controlling the chain length, geometric structure, doping elements, and substituent groups of the organic monomers. Selective enrichment of target trace substances was achieved by modifying the groups of I-COFs based on the principle of host guest adaptation, molecular sieving, or microporous filling effect. At present, research on the synthesis of I-COF materials is in the stage of rapid development, and many I-COFs with excellent properties and great application potential have been synthesized, allowing widespread application of I-COFs in sample pretreatment medium. This review summarizes the current state-of-the-art on the main types and synthetic methods of I-COFs, as well as the applications of I-COFs in solid-phase extraction, magnetic solid-phase extraction, dispersive solid-phase extraction, and solid-phase microextraction. The prospects of I-COFs in sample pretreatment are also presented.

Various three-dimensional TiO 2 hollow structures have attracted strong scientific and technological attention due to their excellent properties. 3D hierarchical TiO 2 hollow nanocubes (TiO 2 -HNBs) are not good candidates for industrial photocatalytic applications due to their large energy gap which is only activated by UV light. Herein, visible-light-responsive carbon doped and coated TiO 2 -HNBs (C@TiO 2 -HNBs) with a dominant exposure of {001} facets have been prepared via a template-engaged topotactic transformation process using facile one-step solvothermal treatment and a solution containing ethanol, glucose and TiOF 2 . The effects of reaction time and glucose/TiOF 2 mass ratio on the structure and performance of C@TiO 2 -HNBs were systematically studied. We found that glucose played an important role in providing H 2 O during the topological transformation from self-templated TiOF 2 cubes into 3D hierarchical TiO 2 hollow nanocubes versus dehydration reactions, where its main function was as a carbon source. Coated carbon was deposited predominantly on the surface as sp 2 graphitic carbon in extended p conjugated graphite-like environments, and doped carbon mainly replaced Ti atoms in the surface lattice to form a carbonate structure. The results were confirmed using TEM SEM, EDS, XRD, FT-IR, XPS and Raman spectroscopic studies. The C@TiO 2 -HNBs achieved greatly improved RhB photodegradation activity under visible light irradiation. The catalyst prepared with glucose/TiOF 2 at a mass ratio of 0.15 (T24-0.15) showed the highest photodegradation rate of 96% in 40 min, which is 7.0 times higher than those of the TiO 2 -HNBs and P25. This new synthetic approach proposes a novel way to construct carbon hybridized 3D hierarchical TiO 2 hollow nanocubes by combining two modification methods, "element doped" and "surface sensitized", at the same time., Competing Interests: There are no conflicts to declare., (This journal is © The Royal Society of Chemistry.)

Microporous organic polymers (MOPs) are a class of novel porous materials consisting of the lighter elements, which possess low framework density, large surface area, tunable pore size and structure, excellent chemical and physical stability. In recent years, MOPs have shown great potential in the field of sample preparation techniques. In this paper, the classification and synthetic methods of MOPs are summarized, and the applications of MOPs in sample preparation techniques such as solid phase extraction, batch adsorption experiments, monolith and sensing film are reviewed.