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Phenyl‐C61‐butyric acid methyl ester (PCBM) remains the most commonly used electron transport layer in inverted perovskite solar cells (IPSCs). However, its insufficient electrical properties and passivation ability limit the device's performance. In this study, it is demonstrated that introducing an appropriate amount of n‐type polymer N2200 into the PCBM can simultaneously enhance the electrical properties of PCBM and passivate the defects distributed on perovskite surface. This modification of PCBM leads to improved band alignment and enhanced electron mobility. Simultaneously, N2200 polymer contains electron donors such as O, S involved in passivating uncoordinated Pb2+ defects. The PCBM@N2200‐based IPSCs exhibit an enhanced open‐circuit voltage (VOC) of 1.20 V with the minimum 0.36 V voltage loss and reach the champion power conversion efficiency (PCE) of 24.53% (certified PCE is 24.05%) with narrow distribution. Impressively, the corresponding module achieves an efficiency of 20.30% (11.19 cm2). Moreover, the PCBM@N2200‐based IPSCs maintain 96% of their initial efficiency after operating at the maximum power point for 500 h, thanks to the interfacial passivation, improved uniformity, and increased hydrophobicity resulting from N2200 doping. [ABSTRACT FROM AUTHOR]

Carbonyl functional materials as additives are extensively applied to reduce the defects density of the perovskite film. However, there is still a lack of comprehensive understanding for the effect of carbonyl additives to improve device performance. In this work, we systematically study the effect of carbonyl additive molecules on the passivation of defects in perovskite films. After a comprehensive investigation, the results confirm the importance of molecular dipole in amplifying the passivation effect of additive molecules. The additive with strong molecular dipole possesses the advantages of enhancing the efficiency and stability of perovskite solar cells (PSCs). After optimization, the companion efficiency of PSCs is 23.20 %, and it can maintain long‐term stability under harsh conditions. Additionally, a large‐area solar cell module‐modified DLBA was 20.18 % (14 cm2). This work provides an important reference for the selection and designing of efficient carbonyl additives. [ABSTRACT FROM AUTHOR]

The unavoidable iodine loss in the perovskite layer is closely related to carrier non‐radiative and device degradation. During the post‐annealing process, the fragile PbI bond is easy to break, leading to the formation of iodine vacancies and inducing stress‐driven structure collapse. Herein, a PbI6 octahedra stabilization strategy via building robust grain boundary modification networks is developed. The introduction of conjugated structure into amides can significantly enhance their anchoring ability with PbI units, while the π–π stacking effect of benzamide enables a passivation network with polymer‐like effect. This is well evidenced by the excellent properties in eliminated iodine loss and stabilized perovskite lattice. Therefore, benzamide modification not only transform the perovskite films from n‐type to p‐type by suppressing the iodine vacancy‐doping effect, but also reduces defect density, ultimately bringing the perovskite layer longer carrier diffusion length and better charge injection efficiency. Finally, the benzamide modified devices realize both high power conversion efficiency of 24.78% and excellent operating stability. Of particular note, the module efficiency with 14 cm2 active area is over 21%. [ABSTRACT FROM AUTHOR]

This study explores the impact of environmental regulation on executive turnover based on a panel of A‐share listed companies in the Chinese manufacturing industry. Its findings indicate that the stricter the environmental regulation, the more likely it is to lead to executive turnover in the current period. The findings further show that environmental regulation has a significant negative effect on firm performance; that firm performance has a significant mediating effect between environmental regulation and executive turnover; and that in terms of firm heterogeneity, the above pattern is not significant in manufacturing state‐owned enterprises but is significant in manufacturing non‐state‐owned enterprises. [ABSTRACT FROM AUTHOR]

Coalbed methane as an unconventional natural gas is suitable for the utilization in thermal photovoltaic systems through optimized burners. In order to improve the radiation and utilization efficiency of coalbed methane, a combination of bluff body and porous media was proposed. Moreover, the bluff body spacing and porous media structure were changed to analyze the influence on flame characteristics. The results showed that the maximum temperature and radiation efficiency increased with decreasing of bluff body spacing. When the bluff body spacing was 30 mm, the maximum temperature of 933 K was obtained, and the radiation efficiency increased by 68%. The increase of the equivalence ratio also improved the radiation efficiency, and the maximum radiation efficiency was 14.5% at φ = 0.90. In addition, the increase of inlet velocity and bluff body spacing was beneficial to downstream flame propagation, but had a negative effect on upstream propagation. At vin = 40 cm/s, the maximum downstream propagation velocity was 0.267 mm/s. Due to the difference in thermal conductivity, flame fragmentation occurred in the 8 mm pellets, but the flame propagation was gradually stable with the increase of bluff body temperature. [ABSTRACT FROM AUTHOR]

Metal‐cation defects and halogen‐anion defects in perovskite films are critical to the efficiency and stability of perovskite solar cells (PSCs). In this work, a random polymer, poly(methyl methacrylate‐co‐acrylamide) (PMMA‐AM), was synthesized to serve as an interfacial passivation layer for synergistically passivating the under‐coordinated Pb2+ and anchor the I‐ of the [PbI6]4− octahedron. Additionally, the interfacial PMMA‐AM passivation layer cannot be destroyed during the hole transport layer deposition because of its low solubility in chlorobenzene. This passivation leads to an enhancement in the open‐circuit voltage from 1.12 to 1.22 V and improved stability in solar cell devices, with the device maintaining 95 % of the initial power conversion efficiency (PCE) over 1000 h of maximum power point tracking. Additionally, a large‐area solar cell module was fabricated using this approach, achieving a PCE of 20.64 %. [ABSTRACT FROM AUTHOR]

Wastewater treatment plants (WWTPs) have been striving to recover energy and resources, targeting water and carbon near zero emissions. This study aims to develop a water-energy-tailored model for such a proposal. On one hand, this model will unveil the potential for resource and energy recovery by analyzing the energy flow and mass balance of the WWTP. On the other hand, it explores in-situ energy generation by calculating photovoltaic power generation at a specific location using high spatial-temporal resolution data. The model is employed in a typical town-level WWTP with a capacity of 4000 m3/d located in China. The potentials for carbon emission reduction and associated cost-benefit were analyzed under four different power supply paradigms from the perspective of life cycle assessment. Key findings are as follows: firstly, there is untapped chemical energy (1.65 kWh/m3) and thermal energy (2.32 kWh/m3 for heating) potential within wastewater. It is necessary to recover energy from it and enable water reuse to achieve near-zero wastewater discharge. Secondly, it is hard to balance operation energy consumption and in-situ solar energy recovery along with water-borne energy in the WWTP. The tipping point is identified at a scale of 10,000 m3/d, when constructing a photovoltaic and energy storage system within all available space on the plant premises, with a capacity potential of 95 kWh/(m2 ∙ a). Thirdly, under this condition, the cost of the photovoltaic and energy storage system is at least 73% of the electricity cost from the grid over the assessed 25-year period. The economic viability of WWTPs throughout the entire lifecycle remains a challenge. Therefore, caution is warranted in claiming the feasibility of constructing near-zero carbon WWTPs. Policy implications are also carefully discussed, targeting to achieve a balance among technology, economy, and environment while making the model work in real. [Display omitted] • A water-carbon near-zero emission model of wastewater treatment plants is developed • Coupling energy in influent and solar-roof energy is crucial to achieving the zero goals • Life cycle energy recovery and cost benefits are explored in four scenarios • The model is empirically used at a town-scale wastewater treatment plant [ABSTRACT FROM AUTHOR]

Solvents employed for perovskite film fabrication not only play important roles in dissolving the precursors but also participate in crystallization process. High boiling point aprotic solvents with O-donor ligands have been extensively studied, but the formation of a highly uniform halide perovskite film still requires the participation of additives or an additional step to accelerate the nucleation rate. The volatile aliphatic methylamine with both coordinating ligands and hydrogen protons as solvent or post-healing gas facilitates the process of methylamine-based perovskite films with high crystallinity, few defects, and easy large-scale fabrication as well. However, the attempt in formamidinium-containing perovskites is challenged heretofore. Here, we reveal that the degradation of formamidinium-containing perovskites in aliphatic amines environment results from the transimination reaction of formamidinium cation and aliphatic amines along with the formation of ammonia. Based on this mechanism, ammonia is selected as a post-healing gas for a highly uniform, compact formamidinium-based perovskite films. In particular, low temperature is proved to be crucial to enable formamidinium-based perovskite materials to absorb enough ammonia molecules and form a liquid intermediate state which is the key to eliminating voids in raw films. As a result, the champion perovskite solar cell based on ammonia post-healing achieves a power conversion efficiency of 23.21% with excellent reproducibility. Especially the module power conversion efficiency with 14 cm2 active area is over 20%. This ammonia post-healing treatment potentially makes it easier to upscale fabrication of highly efficient formamidinium-based devices. Solvents used for perovskite film fabrication not only dissolve the precursors but also play a role in the crystallization process. Here, authors study the role of transamination reactions in the underlying degradation mechanism of formamidinium-containing perovskites in aliphatic amines environment. [ABSTRACT FROM AUTHOR]