101. Temperature dependence of conductivity enhancement induced by nanoceramic fillers in polymer electrolytes
- Author
-
G. B. Xue, Bin Wang, X. L. Yan, Jianxin Zhong, and Shecheng Gao
- Subjects
Nanocomposite ,Materials science ,Physics and Astronomy (miscellaneous) ,Polymer nanocomposite ,chemistry.chemical_element ,Electrolyte ,Conductivity ,Nanoceramic ,chemistry ,Chemical engineering ,Phase (matter) ,Polymer chemistry ,Ionic conductivity ,Lithium - Abstract
The microstructure and ionic conductivity of polymer nanocomposite electrolytes doped with ZnO have been systematically studied. Compared with the undoped one, a less crystalline phase, a restrained main chain movement, a reduced symmetry in the configuration of ethylene oxide/lithium ion, and an at least five-fold increase in conductivity were observed for the filler incorporated electrolyte. Lewis acid-base interactions are determining in causing these changes. The temperature dependence of conductivity is explained by the Vogel-Tammann-Fulcher equation based on the free volume theory. The mechanism of temperature dependent conductivity enhancement is interpreted by a modeling function proposed.
- Published
- 2013
- Full Text
- View/download PDF