101. EFFECT OF ORGANOCLAY LOADING ON RHEOLOGICAL BEHAVIOUR OF IMPACT-MODIFIED PBT/PTT BLENDS-BASED NANOCOMPOSITES.
- Author
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Sharma, Ranjana, Jain, Purnima, and Upadhyay, Prabhat K.
- Subjects
ORGANOCLAY ,NANOCOMPOSITE materials ,SILICATES ,VISCOELASTIC materials ,POLYMER blends - Abstract
Impact-modified PBT/PTT blends and their nanocomposites with organically modified layered silicates (Cloisite 30B) were prepared via melt blending in a twin screw extruder to explore their rheological behaviour. The linear viscoelastic behaviour of nanocomposites was measured by parallel plate rheometer. ULDPE-g-GMA was used as an impact modifier for PBT and PTT polymeric matrix. It was observed from results that the storage modulus, loss modulus and complex viscosity of the nanocomposites increased with the incorporation of organoclay (OMMT). Addition of organoclay to polymer matrix increased the storage modulus of prepared nanocomposites and alters the shear thinning behaviour at low frequencies. Compositions having 5 wt % of organoclay showed high value of the storage modulus, loss modulus and complex viscosity. Moreover, storage modulus (G') and loss modulus (G") of impact-modified 25/75 PBT/PTT (NA3), 50/50 PBT/PTT (NB3) and 75/25 PBT/PTT blends based nanocomposites with 5 wt % organoclay loading increased more significantly at lower frequency range relative to other compositions. PBT/PTT blends based nanocomposites followed a strong shear thinning flow behaviour and decreased with increasing shear rates or frequency. This change in behaviour showed a solid like behaviour and it is related to the morphological changes. The complex viscosity of neat PBT, neat PTT and impact-modified PBT and PTT decreases with increasing frequency because of the shear thinning behaviour. [ABSTRACT FROM AUTHOR]
- Published
- 2017