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The evolution of a surf‐zone released tracer (≈100 $\approx 100$ Liter over 4 hr) was observed for ≈30 $\approx 30$ h. Surf‐zone tracer was transported alongshore (y) with relatively steady mean speed vSZ ≈ 0.18 m s−1, consistent with obliquely incident wave forcing. Maximum in situ surf‐zone tracer concentration decayed exponentially with 1.6 km alongshore e‐folding length scale, that is, 2.5 hr advective time scale. Surf‐zone tracer time‐series evolved downstream of the release from a top‐hat structure for y ≤ 1 km to increasingly skewed farther downstream. Within ≈1.5 $\approx 1.5$ km of the northward propagating tracer front, inner‐shelf tracer was confined to onshore of ≈4LSZ $\approx 4{L}_{\mathrm{S}\mathrm{Z}}$ (surf‐zone width LSZ ≈ 100 m) and was alongshore patchy. A coupled surf‐zone/inner‐shelf tracer advection‐diffusion‐exchange box model reproduces the observed surf‐zone downstream max concentration decay and temporal skewness, with surf‐zone flushing time kSZ−1≈2.3 ${k}_{\mathrm{S}\mathrm{Z}}^{-1}\approx 2.3$ h. A weaker inner‐shelf unidirectional‐exchange rate kIS ≈ kSZ/2 indicates reduced horizontal mixing outside the surf‐zone. Surf‐zone temporal skewness is linked to inner‐shelf tracer storage, differential surf‐zone/inner‐shelf advection, and recirculation, that is, non‐asymptotic shear dispersion. On the inner‐shelf (≈3LSZ $\approx 3{L}_{\mathrm{S}\mathrm{Z}}$), tracer vertical structure differed in the morning versus afternoon suggesting internal tide and solar forced thermal modulation. Model parameters representing surf‐zone processes are well constrained by existing observations and scales. However, the many overlapping inner‐shelf processes make a single process based generalization of inner‐shelf cross‐shore exchange rate (i.e., kIS) and alongshore transport difficult. Plain Language Summary: Transport and mixing impact nearshore systems, such as larval recruitment in intertidal ecosystems and water quality impacts from coastal pollution, and can be studied using shoreline released tracers, like fluorescent dye. In the region of depth‐limited wave breaking, the surf‐zone, alongshore directed currents driven by oblique breaking waves transport tracers over long distances. Tracer is also mixed across the surf‐zone by eddying currents and exported onto the inner‐shelf (region offshore of the surf‐zone) by rip currents, which decreases shoreline tracer concentration. Horizontal mixing also increases tracer plume length‐scales, known as dispersion, and cross‐shore variation in the alongshore current can induce enhanced alongshore dispersion. Over long‐distances/times, tracer evolution depends on both surf‐zone and inner‐shelf currents and alongshore dispersion. Here, the evolution of a surf‐zone released dye tracer is observed for ≈30 h and over several kilometers downstream (alongshore). Downstream of the release, the surf‐zone maximum concentration decayed and concentration time‐series developed long‐duration tails (skewness). A surf‐zone/inner‐shelf box model reproduces the surf‐zone tracer observations, providing insight to the relative roles of cross‐shore exchange, recirculation and alongshore dispersion. Importantly, recirculation between the surf‐zone and the inner‐shelf is a critical process that changes the tracer distribution close to shore. Key Points: Tracer evolution from a 3.8 hr surfzone release was observed for ≈30 hr and ≈7 km alongshoreSurfzone alongshore tracer transport and exchange with inner‐shelf lead to surf‐zone tracer decay and skewed timeseries farther downstreamA coupled surfzone/inner‐shelf tracer model quantifies how inner‐shelf retention and recirculation are key to surfzone tracer evolution [ABSTRACT FROM AUTHOR]

Summary: Changes in bed topography that build and maintain channel morphology are driven by the displacements of individual particles, either though their entrainment or deposition. However, the linkages between these topographic changes and individual grain displacements have not been comprehensively addressed, as many historical tracer studies have not included coincident topographic data. In this study, we compare the movements of bedload tracers to the differences in repeat topographic surveys across four gravel‐bed river reaches. To do this, we apply a 1‐D Bayesian survival process model to the starting and ending locations of tracers. This model estimates downstream trapping probabilities, which represent the likelihood that a given segment of channel will "trap" an entrained particle. We then adapt this model to estimate downstream trapping probabilities using digital elevation models of difference and compare the results. The estimates from the tracer and topographic trapping models showed general alignment, meaning that tracers were preferentially trapped in segments that experienced deposition along the channel. Thus, tracers in this study were able to identify downstream differences in bedload transport. The comparison also highlighted that tracer‐estimated trapping probabilities were larger than topographically estimated ones. This supports previous observations that sediment travel distances estimated using tracers are shorter than those estimated using morphological methods. We find that the differences between these two estimates vary systematically across study environments. These variations are attributable to either study design (i.e., tracers being larger than the median size of the sediment that deforms the bed) or differences in compensating scour and fill. We explore potential causes for differences in compensating scour and fill, including hydrograph shape, sediment delivery regime, channel deformation style, and channel width, highlighting that morphodynamics needs to be considered in designing bedload tracer studies. [ABSTRACT FROM AUTHOR]

The mean age since air was last at the Northern Hemisphere (NH) midlatitude surface is a fundamental property of tropospheric transport. Here we approximate the mean age in terms of an "SF6 age" (ΓSF6), derived from surface and aircraft measurements of SF6 that are broader in spatial scope and cover a longer time period (1997–2018) than considered previously. At the surface, ΓSF6 increases from near‐zero values north of 30°N to ∼1.5 years over the Southern Hemisphere (SH) extratropics, with the largest meridional gradients occurring in the tropics. By comparison, vertical gradients in ΓSF6 are weak throughout, with only slight increases/decreases with height in the NH/SH. The broader spatial coverage of the measurements reveals strong variations in the seasonal cycle of ΓSF6 within the (sub)tropics that are weaker over the Atlantic and Pacific oceans, compared to over the Indian Ocean. Observations from 2000 to 2018 reveal that the SF6 age at sites in the SH has been decreasing by ∼0.12 years/dec. However, this decrease is not due to changes in transport but, rather, is likely related to changes in emissions, which have increased globally and reportedly shifted from northern midlatitudes into the subtropics. Simulations, which reproduce the SF6 age trends, show no decreases in an age‐of‐air tracer, reinforcing the fact that ΓSF6 represents only an approximation to the mean age. Finally, the modeled SF6 ages are older than observed, by ∼0.3–0.4 years throughout the southern extratropics. We show that this bias is partly related to an overestimation in simulated SF6 near emissions regions, likely reflecting a combination of uncertainties in emissions and model transport. Plain Language Summary: The mean age since air was last at the Northern Hemisphere midlatitude surface is a fundamental timescale of tropospheric transport. The mean age is not directly observable, but can be estimated from measurements of SF6 to derive an "SF6 age" (ΓSF6), or the time lag since the SF6 mixing ratio at a given location equaled the mixing ratio over a northern midlatitude source region. Here we use new surface and aircraft measurements of SF6 to construct an estimate of the mean age that covers a longer period (1997–2018) and is more globally resolved, compared to previous estimates. The broader spatial coverage reveals strong variations in the seasonal cycle of ΓSF6 within the (sub)tropics that are weaker over the Atlantic and Pacific oceans, compared to over the Indian Ocean. The longer temporal record also reveals that ΓSF6 has been decreasing by ∼0.12 years/dec. Quite importantly, this decrease is not due to underlying changes in transport but, rather, is likely related to changes in SF6 emissions, which increase globally while shifting from northern midlatitudes into the subtropics. We also show that the longstanding old bias in modeled ΓSF6 is partly related to an overestimation in simulated SF6 near emissions regions. Key Points: The mean age since air was last at the Northern Hemisphere (NH) midlatitude surface features large (small) meridional gradients in the tropics (extratropics)Recent mean age trends in the Southern Hemisphere (SH), estimated from measurements of SF6, likely reflect shifts in SF6 emissions, not transport changesModeled SF6 ages in the SH are older than observed, partly due to overestimation in simulated SF6 mixing ratios near NH emissions regions [ABSTRACT FROM AUTHOR]

This guideline on molar activity (Am) and specific activity (As) focusses on small molecules, peptides and macromolecules radiolabelled for diagnostic and therapeutic applications. In this guideline we describe the definition of Am and As, and how these measurements must be standardised and harmonised. Selected examples highlighting the importance of Am and As in imaging studies of saturable binding sites will be given, and the necessity of using appropriate materials and equipment will be discussed. Furthermore, common Am pitfalls and remedies are described. Finally, some aspects of Am in relation the emergence of a new generation of highly sensitive PET scanners will be discussed. [ABSTRACT FROM AUTHOR]

This study focuses on characterizing the contributions of key terrestrial pathways that deliver dissolved organic carbon (DOC) to streams during hydrological events and on elucidating factors governing variation in water and DOC fluxes from these pathways. We made high‐frequency measurements of discharge, specific conductance (SC), and fluorescent dissolved organic matter (FDOM) during 221 events recorded over 2 years within four Vermont (USA) watersheds that range in area from 0.4 to 139 km2. Using the SC measurements, together with statistical information on discharge, we separated the event hydrographs into contributions from three terrestrial pathways, which we refer to as riparian quickflow, subsurface quickflow, and slow‐flow groundwater. The pathway discharges were used as input to a mixing model that closely approximated sub‐hourly streamwater DOC concentrations as measured with the FDOM sensors. Subsurface quickflow, comprised of pre‐event water, was the leading contributor to streamwater DOC fluxes, while riparian quickflow, comprised of event water, was the second‐leading contributor to streamwater DOC fluxes, despite comprising the smallest proportion of streamflow yield among the three end‐member pathways. Fixed‐effects regression analysis revealed that the relationship between DOC fluxes from the end‐member pathways and event magnitude was consistent across the four watersheds. This analysis also showed that DOC fluxes from the quickflow pathways increased significantly with temperature and varied inversely, but weakly, with catchment antecedent wetness. We believe that our approach, which leverages in‐stream sensors that enable high‐frequency measurements over extended periods, may be applicable for evaluating controls on DOC export from other watersheds within and beyond our study region. Key Points: Calculations of a mixing model reproduce sub‐hourly observations of streamwater dissolved organic carbon (DOC) concentrations in four watershedsStreamwater specific conductance can be used to quantify discharge from terrestrial flowpaths and constrain the DOC mixing modelDOC fluxes from principal flow paths vary discernibly with event magnitude, temperature, and antecedent wetness [ABSTRACT FROM AUTHOR]

Plastics have long been an environmental contaminant of concern as both large-scale plastic debris and as micro- and nano-plastics with demonstrated wide-scale ubiquity. Research in the past decade has focused on the potential toxicological risks posed by microplastics, as well as their unique fate and transport brought on by their colloidal nature. These efforts have been slowed by the lack of analytical techniques with sufficient sensitivity and selectivity to adequately detect and characterize these contaminants in environmental and biological matrices. To improve analytical analyses, microplastic tracers are developed with recognizable isotopic, metallic, or fluorescent signatures capable of being identified amidst a complex background. Here we describe the synthesis, characterization, and application of a novel synthetic copolymer nanoplastic based on polystyrene (PS) and poly(2-vinylpyridine) (P2VP) intercalated with gold, platinum or palladium nanoparticles that can be capped with different polymeric shells meant to mimic the intended microplastic. In this work, particles with PS and polymethylmethacrylate (PMMA) shells are used to examine the behavior of microplastic particles in estuarine sediment and coastal waters. The micro- and nanoplastic tracers, with sizes between 300 and 500 nm in diameter, were characterized using multiple physical, chemical, and colloidal analysis techniques. The metallic signatures of the tracers allow for quantification by both bulk and single-particle inductively-coupled plasma mass spectrometry (ICP-MS and spICP-MS, respectively). As a demonstration of environmental applicability, the tracers were equilibrated with sediment collected from Bellingham Bay, WA, United States to determine the degree to which microplastics bind and sink in an estuary based of grain size and organic carbon parameters. In these experiments, between 80 and 95% of particles were found to associate with the sediment, demonstrative of estuaries being a major anticipated sink for these contaminants. These materials show considerable promise in their versatility, potential for multiplexing, and utility in studying micro- and nano-plastic transport in real-world environments.

The Connecticut River plume interacts with the strong tidal currents of the ambient receiving waters in eastern Long Island Sound. The plume formed during ambient flood tides is studied as an example of tidal river plumes entering into energetic ambient tidal environments in estuaries or continental shelves. Conservative passive freshwater tracers within a high-resolution nested hydrodynamic model are applied to determine how source waters from different parts of the tidal cycle contribute to plume composition and interact with bounding plume fronts. The connection to source waters can be cut off only under low-discharge conditions, when tides reverse surface flow through the mouth after max ambient flood. Upstream plume extent is limited because ambient tidal currents arrest the opposing plume propagation, as the tidal internal Froude number exceeds one. The downstream extent of the tidal plume always is within 20 km from the mouth, which is less than twice the ambient tidal excursion. Freshwaters in the river during the preceding ambient ebb are the oldest found in the new flood plume. Connectivity with source waters and plume fronts exhibits a strong upstream-to-downstream asymmetry. The arrested upstream front has high connectivity, as all freshwaters exiting the mouth immediately interact with this boundary. The downstream plume front has the lowest overall connectivity, as interaction is limited to the oldest waters since younger interior waters do not overtake this front. The offshore front and inshore boundary exhibit a downstream progression from younger to older waters and decreasing overall connectivity with source waters. Plume-averaged freshwater tracer concentrations and variances both exhibit an initial growth period followed by a longer decay period for the remainder of the tidal period. The plume-averaged tracer variance is increased by mouth inputs, decreased by entrainment, and destroyed by internal mixing. Peak entrainment velocities for younger waters are higher than values for older waters, indicating stronger entrainment closer to the mouth. Entrainment and mixing time scales (1–4 h at max ambient flood) are both shorter than half a tidal period, indicating entrainment and mixing are vigorous enough to rapidly diminish tracer variance within the plume.

It has been hypothesized that submesoscale flows play an important role in the vertical transport of climatically important tracers, due to their strong associated vertical velocities. However, the multiscale, nonlinear, and Lagrangian nature of transport makes it challenging to attribute proportions of the tracer fluxes to certain processes, scales, regions, or features. Here we show that criteria based on the surface vorticity and strain joint probability distribution function (JPDF) effectively decompose the surface velocity field into distinguishable flow regions, and different flow features, like fronts or eddies, are contained in different flow regions. The JPDF has a distinct shape and approximately parses the flow into different scales, as stronger velocity gradients are usually associated with smaller scales. Conditioning the vertical tracer transport on the vorticity–strain JPDF can therefore help to attribute the transport to different types of flows and scales. Applied to a set of idealized Antarctic Circumpolar Current simulations that vary only in horizontal resolution, this diagnostic approach demonstrates that small-scale strain-dominated regions that are generally associated with submesoscale fronts, despite their minuscule spatial footprint, play an outsized role in exchanging tracers across the mixed layer base and are an important contributor to the large-scale tracer budgets. Resolving these flows not only adds extra flux at the small scales, but also enhances the flux due to the larger-scale flows. [ABSTRACT FROM AUTHOR]

This study aimed to reconstruct the sedimentation rates over time and identify the changing sources of sediment in a major hydropower reservoir in Tanzania, the Nyumba ya Mungu (NYM). Fallout 210Pb measurements were used to estimate age of sediment deposits and broad changes in sedimentation rates were reconstructed. Sedimentation peaks were cross referenced to geochemical profiles of allogenic and autogenic elemental constituents of the sediment column to confirm a causal link. Finally, geochemical fingerprinting of the sediment cores and potential sources were compared using a Bayesian mixing model (MixSIAR) to attribute the dominant riverine and land use sources to the reservoir together with changes through recent decades. Reservoir sedimentation generally increased from 0.1 g cm-2 yr-1 in the lower sediment column to 1.7 g cm-2 yr-1 in the most recent deposits. These results correlated to changes in allogenic and autogenic tracers. The model output pointed to one of two major tributaries, the Kikuletwa River with 60.3%, as the dominant source of sediment to the entire reservoir, while the other tributary, Ruvu River, contributed approximately 39.7%. However, downcore unmixing results indicated that the latest increases in sedimentation seem to be mainly driven by an increased contribution from the Ruvu River. Cultivated land (CU) was shown to be the main land use source of riverine sediment, accounting for 38.4% and 44.6% in Kikuletwa and Ruvu rivers respectively. This study explicitly demonstrated that the integration of sediment tracing and dating tools can be used for quantifying the dominant source of sediment infilling in East African hydropower reservoirs. The results underscore the necessity for catchmentwide management plans that target the reduction of both hillslope erosion reduction and the sediment connectivity from hillslope source areas to rivers and reservoirs, which will help to maintain and enhance food, water and energy security in Eastern Africa. [ABSTRACT FROM AUTHOR]

Measurements of radiocarbon concentration (Δ14C) in fossil biogenic carbonates have been interpreted as reflecting a reduced ventilation of the deep Atlantic during the last ice age. Here we evaluate the (in)consistency of an updated compilation of fossil Δ14C data for the last deglaciation with the abyssal circulation in the modern Atlantic. A Δ14C transport equation, in which the mean velocity field is a modern field estimate and turbulent flux divergence is treated as a random fluctuation, is fitted to deglacial Δ14C records by using recursive weighted least squares. This approach allows us to interpret the records in terms of deviations from the modern flow with due regard for uncertainties in the fossil data, the Δ14C transport equation, and its boundary conditions. We find that the majority of fit residuals could be explained by uncertainties in fossil Δ14C data, for two distinct estimates of the modern flow and of the error variance in the boundary conditions. Thus, most, not all, deglacial data appear consistent with present-day ventilation rates. From 20% to 32% of the residuals exceed in magnitude the published errors in the fossil data by a factor of 2. Residuals below 4000 m in the western North Atlantic are all negative, suggesting that deglacial Δ14C values from this region are too low to be explained by modern ventilation. While deep water ventilation appeared different from today at some locations, a larger database and a better understanding of error (co)variances are needed to make reliable paleoceanographic inferences from fossil Δ14C records. [ABSTRACT FROM AUTHOR]

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The inflow to an estuary originates on the shelf. It flushes the estuary and can bring in nutrients, heat, salt, and hypoxic water, having consequences for estuarine ecosystems and fjordic glacial melt. However, the source of estuarine inflow has only been explored in simple models that do not resolve interactions between inflow and outflow outside of the estuarine channel. This study addressed the estuary inflow problem using variations on a three-dimensional primitive equation model of an idealized estuarine channel next to a sloping, unstratified shelf with mixing provided by a single-frequency, 12-h tide. Inflow was identified using particle tracking, momentum budgets, and total exchange flow. Inflow sources were found in shelf water downstream of the estuary, river plume water, and shelf water upstream of the estuary. Downstream is defined here with respect to the direction of coastal trapped wave propagation, which is to the right for an observer looking seaward from the estuary mouth in the Northern Hemisphere. Downstream of the estuary and offshore of the plume, the dynamics were quasigeostrophic, consistent with previous simple models. The effect of this inflowing current on the geometry of the river plume front was found to be small. Novel sources of inflow were identified which originated from within the plume and upstream of the estuary. [ABSTRACT FROM AUTHOR]

In the circulating atmosphere, diabatic heating influences the potential temperature content of air masses far from where the heating occurs. Budgets that balance local diabatic sources with local heat divergence and storage do not retain information about this remote influence, which requires airmass tracking. In this study, a process-based, passive-tracer diagnostic, called heat tagging, is introduced. Heat tagging locally decomposes the potential temperature into contributions from the distinctive diabatic processes that generate them, wherever they occur. The distribution, variability, and transport of atmospheric heat tags are studied in the relatively simple setting of an idealized aquaplanet model. Heat tags from latent heating are generated in the deep tropics and the midlatitude storm track and then transported throughout the troposphere. By contrast, dry sensible heat tags are enhanced near the surface, and radiative tags are mainly confined to the stratosphere. As a result, local heat transport, variability of potential temperature, and global poleward heat transport are dominated by heat tags related to latent heating, with heat tags from sensible and radiative heating only making contributions in the polar near-surface and the stratosphere, respectively. Heat tagging thus quantifies how water vapor and latent heating link the structural characteristics of the atmosphere and illustrates the importance of the hydrological cycle in poleward energy transport. [ABSTRACT FROM AUTHOR]

Estuarine mangroves are often considered nurseries for the Atlantic Goliath grouper juveniles. Yet, the contributions of different estuarine primary producers and habitats as sources of organic matter during early ontogenetic development remain unclear. Given the species' critically endangered status and protection in Brazil, obtaining biological samples from recently settled recruits in estuaries is challenging. In this study, we leveraged a local partnership with fishers and used stable isotope (C and N) profiles from the eye lenses of stranded individuals or incidentally caught by fishery to reconstruct the trophic and habitat changes of small juveniles. The eye lens grows by the apposition of protein-rich layers. Once these layers are formed, they become inert, allowing to make inferences on the trophic ecology and habitat use along the development of the individual until its capture. We used correlations between fish size and the entire eye lens size, along with estuarine baselines, to reconstruct the fish size and trophic positions for each of the lens layers obtained. We then used dominant primary producers and basal sources from mangrove sheltered, exposed estuarine and marine habitats to construct an ontogenetic model of trophic and habitat support changes since maternal origins. Our model revealed marine support before the juveniles reached 25 mm (standard length), followed by a rapid increase in reliance on mangrove sheltered sources, coinciding with the expected size at settlement. After reaching 60 mm, individuals began to show variability. Some remained primarily supported by the mangrove sheltered area, while others shifted to rely more on the exposed estuarine area around 150 mm. Our findings indicate that while mangroves are critical for settlement, as Goliath grouper juveniles grow, they can utilize organic matter produced throughout the estuary. This underscores the need for conservation strategies that focus on seascape connectivity, as protecting just one discrete habitat may not be sufficient to preserve this endangered species and safeguard its ecosystem functions. [Display omitted] • Isotopes in eye lenses has unveiled changes in habitat and trophic support of juvenile stages. • Before reaching the anticipated size at settlement, all individuals primarily relied on marine sources. • Immediately following settlement, the primary support was obtained from sheltered mangrove estuarine sources. • When individuals exceeded 100 mm, some began to rely more heavily on the exposed estuary, while others continued to draw significant support from mangroves. [ABSTRACT FROM AUTHOR]

• We have developed a 3D sector model to predict the CO 2 storage capacity of the Kızıldere geothermal field. • The developed model is calibrated using static pressure and temperature measurements, chloride concentrations, and two inter-well tracer tests. • It has been predicted that 78–79 % of the injected CO 2 circulates in the reservoir. • It is possible to store 200,000 tons of CO 2 in the Kızıldere reservoir if the CO 2 is re-injected from multiple injection wells. Many geothermal power plants in Turkey emit high amounts of non-condensable gas (NCG), consisting mainly of CO 2. Thus, it is crucial to mitigate the NCG emissions by re-injecting the captured gas back into the reservoir. In this study, a numerical sector reservoir model is developed to inspect how the reinjected NCG dissipates in the reservoir for successful sequestration. To accurately characterize the flow characteristics in the reservoir, chloride concentrations observed at the production wells were matched. Furthermore, two multi-well slug tracer tests (one with NCG injection well and one from the northernmost shallow injection well by using different naphthalene-sulphonates) results have been used to calibrate the numerical model. Consequently, a high degree of quantitative and qualitative characterization of the reservoir section near the injection site has been achieved. Using the calibrated model, the impact of CO 2 -brine injection has been studied for different injection scenarios with varying injection rates and durations. The results of the CO 2 -charged brine injection showed that approximately 20 % of the injected CO 2 circulates in the reservoir, ensuring reduced CO 2 emissions. It has been estimated that 200 Mt of CO 2 emission can be safely removed if all injection wells are used for NCG re-injection. [ABSTRACT FROM AUTHOR]

The efficiency of biological wastewater treatment systems is linked fundamentally to the hydraulic performance of each treatment unit. These units should guarantee an adequate contact between the microorganisms and the residual water, and the compliance with the hydraulic retention time established, in order to decrease the number of dead zones or short circuits that may exist inside the reactors. In this work, hydraulic performance was evaluated in seven Expanded Granular Sludge Bed (EGSB) reactors with a useful volume of 3,4 L and constructed in acrylic. The analysis was carried out through the stimulus-response test, using bromide as tracer. Two hydraulic retention times (8 and 24 h) and the effect of the presence of granular biomass were considered. Results were analyzed qualitatively through the construction of curves C, E and F, and quantitatively through the construction of a mathematical model of axial dispersion. The results of the hydraulic performance of the reactors revealed a marked tendency to a complete mix flow pattern, with a low effect of HRT or the presence of granular biomass on their operation.

To identify pollutant origins and their potential sources from either long-range transported (LRT) or local emissions, the Boron (B) concentrations and the B isotopic compositions (δ11B) in the water-soluble fraction of aerosols were determined. These aerosols were collected from an islet offshore in northeastern Taiwan, Peng Chia Yu (PCY), a non-residential islet, from January 1998 to March 2000. This islet may be influenced by various pollutants or chemical transport during monsoon periods, but suffers minimal human perturbation locally. The B in the specimens falls to 0.3–1.63 ng m−3 during the SW monsoon seasons when compared to 0.46–2.56 ng m−3 in the NE monsoon. However, the δ11B results show no clear variations in both monsoon seasons (10.7–24.3‰), regardless of differences in air mass origin. A two end-member mixing scenario is proposed to explain our observations using the obtained δ11B and 1/[B] results. The ocean endmember is characterized by high 1/[B] and high δ11B; while other endmember is from continental endmember or anthropogenic contributions that are characterized by of 1/[B] and lowδ11B (δ11B < 10‰). Based on these chemical and isotopic results, we found aerosol emissions in northern Taiwan are characterized as low B with nearly constant δ11B, when compared with long-range transported continental endmembers derived from nearby regions. This study provides preliminary B and δ11B levels in aerosols derived from LRT/local emissions and discusses potential monsoonal effects on aerosols offshore of NE Taiwan.

Krypton-85 and other radioactive noble gases are widely used for groundwater dating purposes. 85Kr analysis require large volumes of water to reach the analytical requirements. Conventionally, this water is pumped to the surface to be degassed with a gas extraction system. The large pumping rate may disturb the natural flow field and requires substantial field logistics. Hence, we propose a new in-situ degassing method, in which membrane contactors are used to degas the groundwater directly in the well and gas is collected at the surface. This way, field work is facilitated, groundwater system disturbance is minimized, and the gas sample is collected at a specific depth. We demonstrate the tightness of the system regarding atmospheric air contamination for a collection times of 24 h, which is sufficient for both low-level counting and laser-based counting methods for 85Kr. The minimal borehole diameter is 7.5 cm for the prototype presented in this research but can easily be reduced to smaller diameters. In a case study, we compare the results obtained with the new passive method with those from a conventional packer setup sampling. Additionally, 3H/3He samples were collected for both sampling regimes and the dating results were compared with those from 85Kr. A good agreement between tracer ages is demonstrated and the age stratigraphy is consistent with the expected age distribution for a porous unconfined aquifer. In addition, our study emphasizes the differences between the age information sampled with various methods. In conclusion, we demonstrate that the new in situ quasi-passive method provides a more representative age stratigraphy with depth in most cases.

Abstract Qualitative and quantitative measuring in water bodies, nuclear medicine, agriculture, and world oil production use tracers to monitor, evaluate and continuously improve their processes. The bibliometric information about the past and the future of artificial tracers, to monitor surface and groundwater by using sustainable biodegradable materials it will be important for future generation. To fulfil this purpose, bibliometric literature analysis has been considered as a solution to identify research areas that need to be improved. The results of this paper showed that even with the increase in research in biopolymers, and the use of artificial tracers, academic development is still not significant. The United States, China, and Germany are the top publishers in this field however, there is no country that constantly develops research in these areas concomitantly using biodegradable polymers. Because of that, this field could be further explored, globally using innovative techniques and materials for new tracers.

Radiocarbon dates of fossil carbonates sampled from sediment cores and the seafloor have been used to infer that deep ocean ventilation during the last ice age was different from today. In this first of two companion papers, the time-averaged abyssal circulation in the modern Atlantic is estimated by combining a hydrographic climatology, observational estimates of volume transports, Argo float velocities at 1000 m, radiocarbon data, and geostrophic dynamics. Different estimates of modern circulation, obtained from different prior assumptions about the abyssal flow and different errors in the geostrophic balance, are produced for use in a robust interpretation of fossil records in terms of deviations from the present-day flow, which is undertaken in Part II. We find that, for all estimates, the meridional transport integrated zonally and averaged over a hemisphere, ⟨Vk⟩, is southward between 1000 and 4000 m in both hemispheres, northward between 4000 and 5000 m in the South Atlantic, and insignificant between 4000 and 5000 m in the North Atlantic. Estimates of ⟨Vk⟩ obtained from two distinct prior circulations—one based on a level of no motion at 4000 m and one based on Argo float velocities at 1000 m—become statistically indistinguishable when Δ14C data are considered. The transport time scale, defined as τ k = V k / 〈 V k 〉 , where V k is the volume of the kth layer, is estimated to about a century between 1000 and 3000 m in both the South and North Atlantic, 124 ± 9 yr (203 ± 23 yr) between 3000 and 4000 m in the South (North) Atlantic, and 269 ± 115 yr between 4000 and 5000 m in the South Atlantic. [ABSTRACT FROM AUTHOR]

Sampling intervals of precipitation geochemistry measurements are often coarser than those required by fine-scale hydrometeorological models. This study presents a statistical method to temporally downscale geochemical tracer signals in precipitation so that they can be used in high-resolution, tracer-enabled applications. In this method, we separated the deterministic component of the time series and the remaining daily stochastic component, which was approximated by a conditional multivariate Gaussian distribution. Specifically, statistics of the stochastic component could be explained from coarser data using a newly identified power-law decay function, which relates data aggregation intervals to changes in tracer concentration variance and correlations with precipitation amounts. These statistics were used within a copula framework to generate synthetic tracer values from the deterministic and stochastic time series components based on daily precipitation amounts. The method was evaluated at 27 sites located worldwide using daily precipitation isotope ratios, which were aggregated in time to provide low-resolution testing datasets with known daily values. At each site, the downscaling method was applied on weekly, biweekly, and monthly aggregated series to yield an ensemble of daily tracer realizations. Daily tracer concentrations downscaled from a biweekly series had average (±standard deviation) absolute errors of 1.69‰ (1.61‰) for δ2H and 0.23‰ (0.24‰) for δ18O relative to observations. The results suggest coarsely sampled precipitation tracers can be accurately downscaled to daily values. This method may be extended to other geochemical tracers in order to generate downscaled datasets needed to drive complex, fine-scale models of hydrometeorological processes. [ABSTRACT FROM AUTHOR]

There are few works where magnetic tracers are used for the assessment of water erosion, focusing on the traceability of sediments over the soil surface and in small areas (i.e., for laminar erosion survey). The main limitation of magnetic tracers is associated with its preparation and application, as the tracer is typically mixed with a large amount of soil and then spread manually over experimental sites susceptible to erosion. In gully erosion studies, the experimental sites (field areas where a gully is expected to develop) can be quite large. Consequently, the high volume/weight of the material (soil + tracer) to be prepared, transported, and applied renders this technique unfeasible. Moreover, eroded channels can reach a depth of several centimeters, requiring the tracer to be (re)located in the soil profile ideally at this same depth. This work presents a novel technique for the application and distribution of magnetite in the soil profile to track sediments in gully erosion assessments. Experiments were carried out in microplots, where a mixture of magnetite and water was applied over the soil surface using a backpack sprayer. Redistribution of the tracer in the soil profile was carried out with different conventional tillage implements. The control plots were subjected to the same experiments, but using a soil–tracer mixture (conventional technique). The application technique proposed herein enables a correct application of magnetite over large areas, being a promising alternative to the conventional technique. Hoeing tillage implements, such as the rotavator, ensure an approximately homogeneous redistribution of tracer in the soil profile when good soil moisture content is present. [ABSTRACT FROM AUTHOR]

Hydrogeochemical based mixing models have been successfully used to investigate the composition and source identification of streamflow. The applicability of these models is limited due to the high costs associated with data collection and the hydrogeochemical analysis of water samples. Fortunately, a variety of mixing models exist, requiting different amount of data as input, and in data scarce regions it is likely that preference will be given to models with the lowest requirement of input data. An unanswered question is if models with high or low input requirement are equally accurate. To this end, the performance of two mixing models with different input requirement, the mixing model analysis (MMA) and the end‐member mixing analysis (EMMA), were verified on a tropical montane headwater catchment (21.7 km2) in the Ecuadorian Andes. Nineteen hydrogeochemical tracers were measured on water samples collected weekly during 3 years in streamflow and eight potential water sources or end‐members (precipitation, lake water, soil water from different horizons and springs). Results based on 6 conservative tracers, revealed that EMMA (using all tracers) and MMA (using pair‐combinations out of the 6 conservative ones), identified the same end‐members: rainfall, soil water and spring water., as well as, similar contribution fractions to streamflow from rainfall 21.9% and 21.4%, soil water 52.7% and 52.3%, and spring water 26.1% and 28.7%, respectively. Our findings show that a hydrogeochemical mixing model requiring a few tracers can provide similar outcomes than models demanding more tracers as input data. This underlines the value of a preliminary detailed hydrogeochemical characterization as basis to derive the most cost‐efficient monitoring strategy. [ABSTRACT FROM AUTHOR]

[Display omitted] • RTD gas tracer responses vary depending on catalyst porosity and affinity. • A Heaviside step function is imprecise and incapable of quantifying tailing. • Detecting changes in catalyst morphology on-line are feasible with RTD. • CO 2 adsorbs on FCC which delays the RTD leading edge and extends the tail. • Without reaction, tracers egress the reactor as a function of their diffusivity. The residence time distribution (RTD) characterizes the flow patterns of tracer particles in continuous systems to identify phenomena like channelling, dispersion, dead volume, and back-mixing. Understanding the hydrodynamics in experimental reactors is imperative to derive reaction kinetics. Here, we applied the RTD methodology to examine the relationship between the physico-chemical properties of powders and gas flow patterns in an 8 mm diameter quartz micro-fluidized bed. H 2 and He tracers egressed the reactor sooner than Kr, O 2 , CO, CH 4 , CO 2 demonstrating that gas diffusivity is a factor to consider when choosing a tracer gas. Intraparticle porosity is a second factor that delays the RTD curve: the residence time was 7% greater for virgin vanadium pyrophosphate catalyst (VPP) with a lower particle density than an equilibrated VPP. These results suggest that RTD experiments are sensitive enough to detect phenomena like catalyst sintering and pore blocking due to coke in situ. The RTD curve of CO and CH 4 tracers with a bed of fluid catalytic cracking catalyst (FCC) had a noticeable trailing edge (tail). For the CO 2 tracer, the leading edge of the RTD curve was delayed, the peak height was 50% shorter, and the tail was extended demonstrating adsorption phenomena like a chromatographic effect. The residence time of Kr, with a similar gas diffusivity as CO 2 was also longer compared to CO or CH 4 , but the tail was shorter than for CO 2 , which confirms the adsorptive nature of the FCC surface with CO 2. A bolus-pulse input function detected these hydrodynamic anomalies with a greater certainty than a Heaviside-step input. [ABSTRACT FROM AUTHOR]

The paper describes the observational and modeling efforts performed under the Bolzano Tracer Experiment (BTEX). BTEX focused on the basin surrounding the city of Bolzano, at the junction of three tributary valleys on the southern side of the Alps, to characterize the ground-level impact of pollutants emitted by a waste incinerator close to the city, and atmospheric factors controlling dispersion processes in the whole basin, under different winter weather situations. As part of the experiment, two controlled releases of a passive gas tracer (sulfur hexafluoride, SF6) were performed through the stack of the incinerator on 14 February 2017 at two different times, starting respectively at 0700 and 1245 LST, representative of distinct phases of the daily cycle. Samples of ambient air were collected at target sites, and later analyzed using a mass spectrometer, allowing a detectability limit down to 30 ppt. Meanwhile, meteorological conditions were continuously monitored by means of a high-resolution, nonconventional network of ground-based instruments, including 15 weather stations, one temperature profiler, one sodar, and one Doppler wind lidar. Data from the above measurements represent one of the rare examples of integrated datasets available to the community for the characterization of dispersion processes in a typical mountainous environment. In particular, they offered a reference benchmark for testing and calibrating a series of combined numerical modeling suites for weather prediction and pollutant dispersion simulation in such a complex terrain, as shown in the paper. [ABSTRACT FROM AUTHOR]

We present a new method to estimate second-order horizontal velocity structure functions, as well as their Helmholtz decomposition into rotational and divergent components, from sparse data collected along Lagrangian observations. The novelty compared to existing methods is that we allow for anisotropic statistics in the velocity field and also in the collection of the Lagrangian data. Specifically, we assume only stationarity and spatial homogeneity of the data and that the cross covariance between the rotational and divergent flow components is either zero or a function of the separation distance only. No further assumptions are made and the anisotropy of the underlying flow components can be arbitrarily strong. We demonstrate our new method by testing it against synthetic data and applying it to the Lagrangian Submesoscale Experiment (LASER) dataset. We also identify an improved statistical angle-weighting technique that generally increases the accuracy of structure function estimations in the presence of anisotropy. [ABSTRACT FROM AUTHOR]

In gully erosion, the detached soil can be transported over long distances along the landscape. The eroded material can be redistributed and/or deposited on the soil surface along the landscape and then eventually be buried by newly eroded and deposited sediment. There can be significant variability of the soil conditions (e.g., texture and moisture content) over which the eroded material travels. The eroded material can be detected through the use of magnetic tracers attached to or mixed with the eroded soil. In this study we evaluated the degree to which the magnetic signal of the magnetite is conditioned by (i) burial depth of tracer, (ii) condition of soil covering the tracer and (iii) tracer concentration. In the laboratory containers were filled with a specific soil. In the filling process, a 0.5‐cm layer of a soil–magnetite mixture was interspersed in the soil profile at a certain depth. Experiments encompassed three different soil–tracer concentrations (1000:1, 200:1, 100:1), four burial depths of tracer (0 cm, 3 cm, 5 cm and 10 cm from soil surface), and two different soils. In each case, the magnetic susceptibility was measured with a susceptometer. Experiments were repeated with different soil moisture contents. If the tracer is located under the soil surface, a minimum soil–tracer concentration of 200:1 is required for its correct detection. The intensity of the magnetic signal decreases dramatically with the vertical distance of the tracer from the soil surface. The maximum detection depth for the tracer's magnetic signal is strongly dependent on the natural magnetic susceptibility of the soil, which masks the tracer's signal. Variation in soil moisture content does not significantly affect the magnetic signal. For extensive field studies, the soil–tracer volume to be handled would be very high and therefore, it is necessary to explore new tracer application techniques. [ABSTRACT FROM AUTHOR]

The impacts of forest conversion on runoff generation in the tropics have received much interest, but scientific progress is still hampered by challenging fieldwork conditions and limited knowledge about runoff mechanisms. Here, we assessed the runoff generation, flow paths and water source dynamics of a pristine rainforest catchment in Costa Rica using end member mixing analysis (EMMA) and a Bayesian mixing model (MixSIAR). Geochemical tracer data collected over a 4‐week field campaign were combined with tritium data used to assess potential deeper groundwater flow pathways to the perennial stream. The streamflow composition was best captured using three end‐members, namely throughfall, shallow (5–15 cm) and deeper (15–50 cm) soil water. We estimated the end‐member contributions to the main stream and two tributaries using the two mixing approaches and found good agreement between results obtained from EMMA and MixSIAR. The system was overwhelmingly dominated by near‐surface sources, with little evidence for deeper and older groundwater as tritium‐derived baseflow mean transit time was between 2.0 and 4.4 years. The shallow soil flow pathway dominated streamflow contributions in the main stream (median 39% and 49% based on EMMA and MixSIAR, respectively), followed by the deeper soil (32% and 31%) and throughfall (25% and 19%). The two tributaries had even greater shallow soil water contributions relative to the main stream (83% and 74% for tributary A and 42% and 63% for tributary B). Tributary B had no detectable deep soil water contribution, reflecting the morphology of the hillslope (steeper slopes, shallower soils and lower vegetation density compared to hillslope A). Despite the short sampling campaign and associated uncertainties, this study allowed to thoroughly assess runoff generation mechanisms in a humid tropical catchment. Our results also provide a first comparison of two increasingly used mixing models and suggest that EMMA and MixSIAR yield comparable estimates of water source partitioning in this tropical, volcanic rainforest environment. [ABSTRACT FROM AUTHOR]

The Panola Mountain Research Watershed (PMRW) is a 41‐hectare forested catchment within the Piedmont Province of the Southeastern United States. Observations, experimentation, and numerical modelling have been conducted at Panola over the past 35 years. But to date, these studies have not been fully incorporated into a more comprehensive synthesis. Here we describe the evolving perceptual understanding of streamflow generation mechanisms at the PMRW. We show how the long‐term study has enabled insights that were initially unforeseen but are also unachievable in short‐term studies. In particular, we discuss how the accumulation of field evidence, detailed site characterization, and modelling enabled a priori hypotheses to be formed, later rejected, and then further refined through repeated field campaigns. The extensive characterization of the soil and bedrock provided robust process insights not otherwise achievable from hydrometric measurements and numerical modelling alone. We focus on two major aspects of streamflow generation: the role of hillslopes (and their connection to the riparian zone) and the role of catchment storage in controlling fluxes and transit times of water in the catchment. Finally, we present location‐independent hypotheses based on our findings at PMRW and suggest ways to assess the representativeness of PMRW in the broader context of headwater watersheds. [ABSTRACT FROM AUTHOR]

Turbulent mixing across density surfaces transforms abyssal ocean waters into lighter waters and is vital to close the deepest branches of the global overturning circulation. Over the last 20 years, mixing rates inferred from in situ microstructure profilers and tracer release experiments (TREs) have provided valuable insights in the connection between small-scale mixing and large-scale ocean circulation. Problematically, estimates based on TREs consistently exceed those from collocated in situ microstructure measurements. These differences have been attributed to a low bias in the microstructure estimates that can miss strong, but rare, mixing events. Here we demonstrate that TRE estimates can suffer from a high bias, because of the approximations generally made to interpret the data. We first derive formulas to estimate mixing from the temporal growth of the second moment of a tracer patch by extending Taylor's celebrated formula to account for both density stratification and variations in mixing rates. The formulas are validated with tracers released in numerical simulations of turbulent flows and then used to discuss biases in the interpretation of TREs based estimates and how to possibly overcome them. [ABSTRACT FROM AUTHOR]

Enhanced Southern Ocean ventilation in recent decades has been suggested to be a relevant modulator of the observed changes in ocean heat and carbon uptake. This study focuses on the Southern Ocean midlatitude ventilation changes from the 1960s to the 2010s. A global 1/4° configuration of the NEMO–Louvain-la-Neuve sea ice model, version 2 (LIM2), including the inert tracer CFC-12 (a proxy of ocean ventilation) is forced with the CORE, phase II (CORE-II), and JRA-55 driving ocean (JRA55-do) atmospheric reanalyses. Sensitivity experiments, where the variability of wind stress and/or the buoyancy forcing is suppressed on interannual time scales, are used to unravel the mechanisms driving ventilation changes. Ventilation changes are estimated by comparing CFC-12 interior inventories among the different experiments. All simulations suggest a multidecadal fluctuation of Southern Ocean ventilation, with a decrease until the 1980s–90s and a subsequent increase. This evolution is related to the atmospheric forcing and is caused by the (often counteracting) effects of wind stress and buoyancy forcing. Until the 1980s, increased buoyancy gains caused the ventilation decrease, whereas the subsequent ventilation increase was driven by strengthened wind stress causing deeper mixed layers and a stronger meridional overturning circulation. Wind stress emerges as the main driver of ventilation changes, even though buoyancy forcing modulates its trend and decadal variability. The three Southern Ocean basins take up CFC-12 in distinct density intervals but overall respond similarly to the atmospheric forcing. This study suggests that Southern Ocean ventilation is expected to increase as long as the effect of increasing Southern Hemisphere wind stress overwhelms that of increased stratification. [ABSTRACT FROM AUTHOR]

Residence time distribution (RTD) is a critically important characteristic of groundwater flow systems; however, it cannot be measured directly. RTD can be inferred from tracer data with analytical models (few parameters) or with numerical models (many parameters). The second approach permits more variation in system properties but is used less frequently than the first because large‐scale numerical models can be resource intensive. Using a novel automated approach, a set of 115 inexpensive general simulation models (GSMs) was used to create RTD metrics (fraction of young groundwater, defined as <65 years old; mean travel time of young fraction; median travel time of old fraction; and mean path length). GSMs captured the general trends in measured tritium concentrations in 431 wells. Boosted Regression Tree metamodels were trained to predict these RTD metrics using available wall‐to‐wall hydrogeographic digital sets as explanatory features. The metamodels produced a three‐dimensional distribution of predictions throughout the glacial system that generally matched with the numerical model RTD metrics. In addition to the expected importance of aquifer thickness and recharge rate in predicting RTD metrics, two new data sets, Multi‐Order Hydrologic Position (MOHP) and hydrogeologic terrane were important predictors. These variables by themselves produced metamodels with Nash‐Sutcliffe efficiency close to the full metamodel. Metamodel predictions showed that the volume of young groundwater stored in the glaciated United States is about 6,000 km3, or about 0.5% of globally stored young groundwater. Plain Language Summary: Groundwater is an important source of water for people and ecosystems. The quality of groundwater depends partly on how long it has resided underground, but this is difficult to know. There are several methods to determine groundwater residence time, but they mostly do not apply over large regional aquifers. In this study, we used a novel method coupling statistical learning and numerical modeling to calculate groundwater residence time throughout the glaciated areas of the United States. The results reveal that most of the groundwater in the area is less than 65 years old and usually travels distances ranging from less than 1 km to about 30 km before discharging to streams, rivers, and lakes. Key Points: A novel method coupling statistical learning and numerical models is presentedThree‐dimensional continuous digital data sets of groundwater age metrics are presentedTwo novel data sets, Multi‐Order Hydrologic Position and hydrogeologic terrane, contain information about groundwater residence time [ABSTRACT FROM AUTHOR]

Fibres, as abundant in agricultural by-products, exhibit a large range of physicochemical properties that can influence digestive processes such as digesta mean retention time (MRT), thereby affecting nutrient digestion kinetics. In this study, we investigated the effects of particle size of insoluble fibres, and gelation of soluble fibres on MRT of liquids, fine solids, and fibrous particles in the different segments of the gastrointestinal tract (GIT) of pigs. Twenty-four boars (51.6 ± 4.90 kg) were allocated to four diets; two diets contained 15% wheat straw, either coarsely chopped or finely ground (1-mm screen), two diets contained 27% wheat bran without or with the addition of 10% low-methylated pectin. After 14 days of adaptation to the diet, a total collection of faeces was performed to determine the total tract digestibility of nutrients. Thereafter, pigs were fed diets supplemented with tracers for at least 5 days and dissected following a frequent feeding procedure to approach steady-state passage of digesta. The MRT of liquids (Co-EDTA), fine solids (TiO 2 ), and fibrous particles (Chromium-mordanted fibres) in the different segments of the GIT were quantified. In the stomach, particle size reduction of straw decreased the MRT of fine solids by 02:39 h, and fibrous particles by 07:21 h (P < 0.10). Pectin addition to the wheat bran diet reduced the MRT of fine solids by 03:09 h, and fibrous particles by 07:10 h (P < 0.10), but not of liquids, resulting in less separation between digesta phases in the stomach compared with the bran diet (P < 0.05). In the mid-small intestine (SI), pectin addition reduced the MRT of fibrous particles and the separation between fibrous particles and fine solids. No further effects of particle size reduction of straw nor pectin addition on MRT and digestibility of starch, nitrogen, or fat were observed in the SI. In the large intestine (LI), particle size reduction of straw reduced separation between fibrous particles and fine solids (P < 0.10), while pectin addition had no effects. Total tract, non-starch polysaccharide degradation of straw was poor (∼31%), and unaffected by particle size reduction (P > 0.10). The complete fermentation of pectin did not influence the degradation of wheat bran fibres (∼51%). In conclusion, the effects of particle size of insoluble fibres and gelling properties of soluble fibres on the passage of digesta phases were most pronounced in the stomach, but less prominent in distal segments of the GIT., (Copyright © 2024 The Author(s). Published by Elsevier B.V. All rights reserved.)

Stratospheric mean residence time  and mean age on the tropopause ΓΩ are shown to measure physically distinct aspects of stratospheric transport. Both ΓΩ and  are mean transit times through the stratosphere of air that enters through tropopause region Ω i and exits through region Ω f, but they represent averages over different populations of fluid elements. The averaging for ΓΩ is based on the population of fluid elements exiting the stratosphere, while  is based on the population of Ω i → Ω f fluid elements residing in the stratosphere. Thus, ΓΩ is the mean age on exit, while is the expected mean residence time in the interior of the stratosphere. The physical basis for defining and robustly computing both timescales is the one-way stratosphere-to-troposphere flux of air labeled with the boundary-propagator Green function, . By re-expressing the boundary-value problem for in terms of first-order loss in a tropopause layer with a timescaleτ c in the limit τ c → 0, we show that both  and ΓΩ can be obtained as ratios of moments of  extrapolated to the tropopause. One obtains  = ΓΩ + 2Δ2/ΓΩ, where Δ quantifies the width of the transit-time distribution. Because the moments of  can be estimated from the mixing ratio of transient trace gases, it is in principle possible to estimate  from measurements of two independent transient tracers. The distinctness of  and ΓΩ is elucidated using idealized models.

Two types of models are used to describe the interactions of tracers dissolved in the ocean with marine sediments: equilibrium and dynamic models. A brief description of these models is given in this opinion paper, and some examples are presented to show that preference should be given to the dynamic descriptions in modern pollutant transport models to be used in emergencies as well as in the case of chronic tracer releases to the sea.

Trying to obtain a more detailed understanding of the hydrological functioning of mountain catchments represents an important challenge in the effort of counteracting possible consequences of climate and land use change on water resources availability. Long-term ( 10 years) hydro-meteorological monitoring in small (typically 10 km2) experimental catchments constitutes a valuable tool to achieve these goal. One of these sites is the Rio Vauz Catchment (1.9 km2), in the Italian Dolomites, that represents an excellent example of long-term snowmelt-dominated catchment in Dolomitic regions. The strong elevation gradient of the Rio Vauz Catchment and the different physiographic properties of its nested subcatchments make this a unique site for investigating fundamental runoff generation mechanisms in mountain headwaters. In this work, we provide a review of physical processes that have been inferred from 12 years of hydrological monitoring in this catchment. We present the available dataset and summarize the main hydrological mechanisms that explain the internal functioning of the Rio Vauz Catchment, primarily focusing on three characterizing hydrological behaviours, namely thresholds, hysteresis and connectivity. The main control on surface and subsurface runoff threshold response is constituted by a combination of soil moisture antecedent conditions, rainfall amount and topography. Changes in hysteresis patterns (clockwise and anti-clockwise loops) between streamflow and soil moisture, water table depth and electrical conductivity were governed by distinct runoff generation processes and rainfall event characteristics. Hillslope-riparian-stream subsurface connectivity was controlled by antecedent wetness conditions and rainfall amount. The composition in environmental tracers (stable isotopes of water and electrical conductivity) in different water sources and the application of tracer-based mixing models helped to distinguish the geographical sources to runoff and to quantify the role of rainfall and snowmelt in streamflow. Finally, we define a perceptual model of runoff generation processes for dry and wet conditions that can be considered representative for many mountain headwater catchments in the world.

Water mixing problems are common in hydrology. A 1998 paper describing uncertainty analysis in tracer‐based mixing problems is widely cited but does not present the equations needed for three‐component problems. This Commentary presents the equations needed to compute the uncertainties in the mixing fractions for a three‐component water mixing problem based on tracer data. Key Points: A widely cited 1998 paper on uncertainty analysis for water mixing problems does not present critical equations for three‐component problemsThe equations are presented here to facilitate calculation of uncertainty in three‐component mixing problems [ABSTRACT FROM AUTHOR]

Purpose: This review of sediment source fingerprinting assesses the current state-of-the-art, remaining challenges and emerging themes. It combines inputs from international scientists either with track records in the approach or with expertise relevant to progressing the science. Methods: Web of Science and Google Scholar were used to review published papers spanning the period 2013–2019, inclusive, to confirm publication trends in quantities of papers by study area country and the types of tracers used. The most recent (2018–2019, inclusive) papers were also benchmarked using a methodological decision-tree published in 2017. Scope: Areas requiring further research and international consensus on methodological detail are reviewed, and these comprise spatial variability in tracers and corresponding sampling implications for end-members, temporal variability in tracers and sampling implications for end-members and target sediment, tracer conservation and knowledge-based pre-selection, the physico-chemical basis for source discrimination and dissemination of fingerprinting results to stakeholders. Emerging themes are also discussed: novel tracers, concentration-dependence for biomarkers, combining sediment fingerprinting and age-dating, applications to sediment-bound pollutants, incorporation of supportive spatial information to augment discrimination and modelling, aeolian sediment source fingerprinting, integration with process-based models and development of open-access software tools for data processing. Conclusions: The popularity of sediment source fingerprinting continues on an upward trend globally, but with this growth comes issues surrounding lack of standardisation and procedural diversity. Nonetheless, the last 2 years have also evidenced growing uptake of critical requirements for robust applications and this review is intended to signpost investigators, both old and new, towards these benchmarks and remaining research challenges for, and emerging options for different applications of, the fingerprinting approach. [ABSTRACT FROM AUTHOR]

Constituents in the feed of reverse osmosis (RO) processes pass into the product by two mechanisms: diffusion through the membrane and advection through defects in the system. While minerals and tracers pass via both mechanisms, pathogens pass only via advection. Using mass and flow balances, a rigorous model is developed to characterize the response of both viruses and tracers in RO systems. The model is used to assess several tracers being considered today. Early virus testing and the commercial requirements of desalination are reviewed, leading to the conclusion that some degree of advection can be expected to be present in RO systems but that commercial incentives can be expected to maintain pathogen removal due to defects somewhat greater than 4.0 log. Model results suggest that the best tracers currently in use can detect defects near this log reduction value but that there is still room for improvement. [ABSTRACT FROM AUTHOR]

Radio‐frequency identification (RFID) transponders are now widely used to track sediment in a variety of environments. A recent innovation placed the transponder inside of a rotating inner mechanism that is designed to minimize missed detections due to burial and shielding or 'signal collision' effects between tracers, while also allowing a rapid measurement of the burial depth of the particle. Here we test a developed protocol for burial depth measurement and deploy the 'Wobblestone' tracers in the field for the first time. Results show that new tracers can be reliably positioned in the horizontal plane (median error ± 0.03 m) and that the burial depth can be accurately measured (~0.02 m maximum error). The field study was characterized by high mobility and travel lengths, and ~20% of the tracers were buried at depths up to 0.15 m. A comparison of exponential distributions for travel length of surface deposited and buried tracers indicate that the buried tracers on average traveled farther and earlier in the flood event. Tracers that did not move were also buried at one site as a result of sediment transport from upstream. Overall the technique has great potential for characterizing vertical mixing and understanding this rarely considered control on sediment transport. © 2020 John Wiley & Sons, Ltd. [ABSTRACT FROM AUTHOR]

Accurate simulation of planetary boundary layer height (PBLH) is key to greenhouse gas emission estimation, air quality prediction, and weather forecasting. This paper describes an extensive performance assessment of several Weather Research and Forecasting (WRF) Model configurations in which novel observations from ceilometers, surface stations, and a flux tower were used to study their ability to reproduce the PBLH and the impact that the urban heat island (UHI) has on the modeled PBLHs in the greaterWashington, D.C., area. In addition, CO2 measurements at two urban towers were compared with tracer transport simulations. The ensemble of models used four PBL parameterizations, two sources of initial and boundary conditions, and one configuration including the building energy parameterization urban canopy model. Results have shown low biases over the whole domain and period for wind speed, wind direction, and temperature, with no drastic differences between meteorological drivers. We find that PBLH errors are mostly positively correlated with sensible heat flux errors and that modeled positive UHI intensities are associated with deeper modeled PBLs over the urban areas. In addition, we find that modeled PBLHs are typically biased low during nighttime for most of the configurations with the exception of those using theMYNN parameterization, and these biases directly translate to tracer biases. Overall, the configurations using the MYNN scheme performed the best, reproducing the PBLH and CO2 molar fractions reasonably well during all hours and thus opening the door to future nighttime inverse modeling. [ABSTRACT FROM AUTHOR]

Eddy diffusivity models are a common method to parameterize turbulent fluxes in the atmospheric sciences community. However, their inability to handle convective boundary layers leads to the addition of a nondiffusive flux component (usually called nonlocal) alongside the original diffusive term (usually called local). Both components are often modeled for convective conditions based on the shape of the eddy diffusivity profile for neutral conditions. This assumption of shape is traditionally employed due to the difficulty of estimating both components based on numerically simulated turbulent fluxes without any a priori assumptions. In this manuscript we propose a novel method to avoid this issue and estimate both components from numerical simulations without having to assume any a priori shape or scaling for either. Our approach is based on optimizing results from a modeling perspective and taking as much advantage as possible from the diffusive term, thus maximizing the eddy diffusivity. We use our method to diagnostically investigate four different large-eddy simulations spanning different stability regimes, which reveal that nondiffusive fluxes are important even when trying to minimize them. Furthermore, the calculated profiles for both diffusive and nondiffusive fluxes suggest that their shapes change with stability, which is an effect that is not included in most models currently in use. Finally, we use our results to discuss modeling approaches and identify opportunities for improving current models. [ABSTRACT FROM AUTHOR]

Warm-season rainfall associated with mesoscale convective systems (MCSs) in the central United States is characterized by higher intensity and nocturnal timing compared to rainfall from non-MCS systems, suggesting their potentially different footprints on the land surface. To differentiate the impacts of MCS and non-MCS rainfall on the surface water balance, a water tracer tool embedded in the Noah land surface model with multiparameterization options (WT-Noah-MP) is used to numerically ''tag'' water from MCS and non-MCS rainfall separately during April-August (1997-2018) and track their transit in the terrestrial system. From the water-tagging results, over 50% of warm-season rainfall leaves the surface-subsurface system through evapotranspiration by the end of August, but non-MCS rainfall contributes a larger fraction. However, MCS rainfall plays a more important role in generating surface runoff. These differences are mostly attributed to the rainfall intensity differences. The higher-intensity MCS rainfall tends to produce more surface runoff through infiltration excess flow and drives a deeper penetration of the rainwater into the soil. Over 70% of the top 10th percentile runoff is contributed by MCS rainfall, demonstrating its important contribution to local flooding. In contrast, lower-intensity non-MCS rainfall resides mostly in the top layer and contributes more to evapotranspiration through soil evaporation. Diurnal timing of rainfall has negligible effects on the flux partitioning for both MCS and non- MCS rainfall. Differences in soil moisture profiles for MCS and non-MCS rainfall and the resultant evapotranspiration suggest differences in their roles in soil moisture-precipitation feedbacks and ecohydrology. [ABSTRACT FROM AUTHOR]