101. Valorization and Evaluation of Terminalia Ivorensis Fibrous Waste for Its Environmental Sequestration Potential for Industrial Anionic Dyes in Aqua System.
- Author
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Olatunde, Abimbola M., Omorogie, Martins O., Agbadaola, Michael T., Adesina, Oreoluwa O., Adeleye, Elizabeth O., and Babalola, Jonathan O.
- Subjects
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ADSORPTION kinetics , *POINTS of zero charge , *INDUSTRIAL capacity , *FIELD emission electron microscopy , *TERMINALIA , *SURFACE analysis - Abstract
This research depicts the pragmatic sequestration capacity of ubiquitous Terminalia ivorensis tree bark (TITB) on toxic anionic dyes (congo red (CR), methyl orange (MO), chlorophenol red (CPR), and Eosin Y (EY)) from aqua system. Surface characterization of TITB by bulk density, Boehm titration, pH of point of zero charge (pHPZC), field emission-scanning electron microscopy (FE-SEM) and Fourier transform infrared (FTIR) spectroscopy revealed that TITB comprise rough intertwined texture with some functional moieties which adsorbed the industrial dyes. The adsorption capacities ( q e ) of MO, CR, and EY were maximum at pH 2.0 ( q e = 84.59, 92.67 and 92 mg.g−1 respectively) while that of CPR was maximum at pH 6.0 ( q e = 99.05 mg.g−1). Langmuir monolayer coverage capacity ( q max ) of TITB was obtained for the adsorption of EY, which was 142.45 mg.g−1. Adsorption kinetics conformed to pseudo-second order kinetic model with a rate constant, k 2 ≤ 0.9702 min−1. The change in Gibbs free energy (ΔG°) for the adsorption process was found to be negative showing that the maximum adsorption was spontaneous at operational temperatures for all dyes. Enthalpy and entropy change (∆H° and ∆S°) were positive for CR, MB, and EY describing endothermic form and increased disorderliness between the adsorbent-dye interface. [ABSTRACT FROM AUTHOR]
- Published
- 2022
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