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101. Contributors

Author

Adarsh, K.S., primary, Alcaide Monterrubio, Francisco, additional, Alegre, C., additional, Bernardo, M., additional, Chandrasekaran, Naveen, additional, Collett, Catherine, additional, Davies, Gareth, additional, Durán-Valle, C., additional, El Sheikh, Ahmed, additional, Fonseca, I., additional, Fraile, José M., additional, Gao, Junkuo, additional, García, Gonzalo, additional, García-Bordejé, Enrique, additional, Gunasekar, Gunniya Hariyanandam, additional, Karimi, Babak, additional, Lázaro, M.J., additional, Matos, I., additional, Mayoral, E. Pérez, additional, McGregor, James, additional, Pastor, Elena, additional, Pérez-Rodríguez, S., additional, Pires, Elisabet, additional, Sadjadi, Samahe, additional, Sadjadi, Sodeh, additional, Sebastián, D., additional, Wu, Yuhang, additional, Xu, Hui, additional, Yakub, Ibrahim, additional, and Yoon, Sungho, additional

Published
2021
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116. Ion-Exchange Resin-Supported Ru NPs Dispersed in Randomly Methylated α-Cyclodextrin Aqueous Solution: A Step Toward an Efficient and Recyclable Catalyst for the Hydrogenation of Fatty Acid Methyl Esters and Derivatives

Author

Madureira, Antonio, primary, Kania, Nicolas, additional, Léger, Bastien, additional, Ferreira, Michel, additional, Sadjadi, Samahe, additional, Ponchel, Anne, additional, Monflier, Eric, additional, and Noël, Sébastien, additional

Published
2023
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117. Influence of the Ethanol Content of Adduct on the Comonomer Incorporation of Related Ziegler–Natta Catalysts in Propylene (Co)polymerizations

Author

Mehdizadeh, Mohammadreza, primary, Karkhaneh, Fereshteh, additional, Nekoomanesh, Mehdi, additional, Sadjadi, Samahe, additional, Emami, Mehrsa, additional, Teimoury, HamidReza, additional, Salimi, Mehrdad, additional, Solà, Miquel, additional, Poater, Albert, additional, Bahri-Laleh, Naeimeh, additional, and Posada-Pérez, Sergio, additional

Published
2023
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125. List of contributors

Author

Beyer, Günter, primary, Cavallaro, Giuseppe, additional, Chiappisi, Leonardo, additional, Dana, Kausik, additional, de Melo Barbosa, Raquel, additional, Ferreira, Marianna Araújo, additional, Guan, Huijuan, additional, Kausar, Ayesha, additional, Lazzara, Giuseppe, additional, Lisuzzo, Lorenzo, additional, Massaro, Marina, additional, Meirelles, Lyghia Maria Araújo, additional, Milioto, Stefana, additional, Otazaghine, Belkacem, additional, Parisi, Filippo, additional, Pasbakhsh, Pooria, additional, Raffin, Fernanda Nervo, additional, Rashidi, Ali, additional, Riela, Serena, additional, Sadjadi, Samahe, additional, Saeb, Mohammad Reza, additional, Sarkar, Madhuchhanda, additional, Scholtzová, Eva, additional, Solanki, Nishal Ashvin, additional, Sonnier, Rodolphe, additional, Taguet, Aurélie, additional, Trusilewicz, Lidia Natalia, additional, Vahabi, Henri, additional, Villanova-de-Benavent, Cristina, additional, Zhao, Yafei, additional, and Zorato, Nicole, additional

Published
2020
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148. Eutectic solvents containing Al-compounds: new benign alternatives to BF3 co-initiator in producing low viscosity polyalphaolefin oils.

Author

Izadi, Zahra, Nekoomanesh-Haghighi, Mehdi, Sadjadi, Samahe, Ahmadi, Mostafa, and Bahri-Laleh, Naeimeh

Subjects
VISCOSITY, SOLVENTS, EUTECTICS, MOLECULAR weights, DISTILLED water, OLIGOMERIZATION
Abstract

As being a hazardous and corrosive co-initiator in α-olefin oligomerization, replacement of AlCl3 with other Al-based compounds or with an environmentally friendly deep eutectic solvent (DES) was assessed. To synthetize DES, first, a 1:1.5 molar ratio mixture of glucose and urea was reacted with an equimolar mixture of ZnCl2 and distilled water. The as-synthesized DES was employed along with Al-containing precursors, AlEt3, AlEt2Cl, AlCl3, et al./DES = 2 molar ratio, in 1-decene oligomerizations to poly(α-olefin) (PAO) oils. The as-prepared PAOs were fully characterized to shed light on their microstructure and flow properties. It was found that AlEt2Cl and AlEt3, in neat from and along with DES, render low molecular weight oligomers with low KV100 (3.6–4.1 cSt). NMR results indicated that PAOs from AlEt3-DES, AlEt2Cl-DES exhibited similar amount of short chain branching (58.9 and 62.3%) compared to that obtained from the neat AlCl3 co-initiator (58.5%). The overall results affirmed that employing DES as the main ingredient of the initiating system based on AlEt2Cl and AlEt3 compounds not only provides more environmentally benign protocol by decreasing the need for hazardous and corrosive Al compound, but also it favors production of low viscosity PAOs, with KV100 ~ 4 cSt, that constitute the highest share of PAO market. These systems can be outstanding alternatives to commercially employed BF3 co-initiator. [ABSTRACT FROM AUTHOR]

Published
2023
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