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A mixing model for Apollo 16 regolith samples has been developed, which differs from other A-16 mixing models in that it is both petrographically constrained and statistically sound. The model was developed using three components representative of rock types present at the A-16 site, plus a representative mare basalt. A linear least-squares fitting program employing the chi-squared test and sum of components was used to determine goodness of fit. Results for surface soils indicate that either there are no significant differences between Cayley and Descartes material at the A-16 site or, if differences do exist, they have been obscured by meteoritic reworking and mixing of the lithologies.

It is shown that the Apollo 17 drill core 70009-70001 is heterogeneous with depth, containing five stratigraphic units, and has a bulk soil chemistry governed by the coarse fractions because of their greater weight proportions. The four components (1) KREEP, (2) anorthositic gabbro, (3) mare basalt, and (4) orange glass are used to model the compositions of the coarse and fine fractions of the entire drill core. It is found that the chemistry of the fused soil component in the five stratigraphic units is more similar to the chemistry of the fine, less than 20-micron fractions than the coarse fraction, suggesting that agglutinates may prefferentially meld and replicate the chemistry of the finer size fractions. The sources of Zn are the orange/black glasses, and the Zn profile is anticorrelated with the maturity index of Morris et al (1979), indicating the liberation of Zn during soil maturation.

The present investigation is concerned with questions regarding a preferential transport of finer-grained material on the lunar surface. Attention is also given to a possible appearance of volatization effects in the case of fine-grained glass beads. It is found that preferential lateral transport of fine-grained material is not efficient over the distances required to introduce mare material into the Apollo-16 (A-16) lunar highlands. The presence of granitic glasses found in the 20-10 micron fractions is attributed to comminution of mesostasis. The composition of mesostasis and the silica-rich phases contained within it reported by other investigators supports this conclusion. No evidence could be found of increased volatilization in the finer grained samples.

The paper reports on a synthesis of the silicate mineralogy of a planetary basalt suite, which concerns itself only with specific aspects of pyroxene cation substitutional couples. Consideration is given to the mineral chemistry and the basalt suites in an overview fashion. Attention is given to those characteristics of pyroxene chemistry that reflect planetary constraints on the host basalts from which the pyroxenes crystallized. It is concluded that the inspection of a large number of high quality silicate analyses of pyroxenes demonstrates conclusively that these phases carry a signature of the planetary body in which they evolved. In addition, it is noted that there are planetary probes capable of constraining thermodynamic parameters that were obtained during the petrogenesis of their host basaltic liquids

Recent literature (1975-1978) on planetary basalts is reviewed. Terrestrial basalts are considered in relation to Nd and Sm isotopic studies, magma mixing, chemical and mineralogical heterogeneities in basalt source regions, and partial melting controls on basalt chemistry. Attention is also given to features of mare basalts, eucrites, and comparisons of basalts for the earth, the moon, and the parent body of basaltic achondrites.

Data for 35 major, minor, and trace elements in 40 bulk and size fractions of core 70005-70003 (140-250 cm) are presented. The core is heterogeneous with depth. Moreover, the 1000 to 90 micron coarse fractions are nearly identical but quite different from the less than 20 micron fine fraction. The bulk soil chemistry is governed by the coarse fractions, because of their greater weight proportion in the sample. The 1000-90 micron fraction contains more ilmenite basalt and less orange glass components than the 90-20 micron fraction. The less than 20 micron fraction is consistently enriched in highland material at all depths in the drill core.

Modal data support a five-unit stratigraphy for the Apollo 17 drill core. The upper unit E (0-22 cm depth) is marked by high content of fused soil, brown glass, and mare basalt fragments. This unit corresponds with a portion of the core excavated and refilled within the last 2 m.y. The underlying unit D (22071 cm depth) has a low abundance of fused soil (i.e., low maturity) and is rich in coarse (less than 200 microns) mare fragments. A large section of the core, unit C (71-224 cm depth), is finer-grained, more mature (richer in agglutinates), more feldspathic and has more highland lithic, mineral and glass fragments than unit D. The next underlying unit, B (224-256 cm depth), has yellow/colorless KREEP glasses with a high Si, low-alkali composition unlike the common Apollo 15 or Apollo 17 KREEP series. The petrologic (fused soil) and Is/FeO maturity of this layer is also lower than the units above and below. The deepest unit, A (256-284 cm depth), is marked by its relatively higher maturity and lower yellow/colorless KREEP glass content. The most prominent petrographic/stratigraphic indicators are the pyroxene-rich immature mare unit D and the abundance of KREEP glass in unit B. This KREEP glass is distinctive petrographically and compositionally, and is probably exotic to the Apollo 17 site. It is suggested here that the KREEP glass in unit B is derived from Tycho, which implies widespread distribution of KREEP on the lunar nearside.

Major differences which exist between terrestrial midocean ridge basalts (MORBs) and lunar mare basalts reflect the different planetary characteristics of earth and moon. MORBs are enriched in aluminum and have higher Mg/(Mg + Fe(2+)). These features reflect a more aluminum- and magnesium-rich mantle source for MORBs. Mare basalts are depleted in sodium and potassium relative to MORBs and, consequently, mare feldspars are depleted in the albite component relative to MORB feldspars; these features are a reflection of the alkali-depleted nature of the moon relative to earth. The oxygen fugacities that obtained during MORB petrogenesis follow the quartz-magnetite-fayalite buffer curve very closely, while those of mare basalts are several orders of magnitude lower. This results in reduced valence states for Fe, Cr, and Ti in mare basalts, which, in turn, has a significant effect on mineral-melt partitioning.

Recent studies have greatly expanded knowledge of lunar mare basalts. Since 1976 there has been a revision of the Apollo 12 low-Ti mare basalt suite and the discovery of a new very low-Ti (VLT: less than 1% TiO2) basalt suite at Apollo 17 and in the new Soviet samples from Mare Crisium (LUNA 24). Current studies suggest that the VLT basalts may be in some way related to the enigmatic 'green glasses' which are found in the soils from every lunar landing site. Telescopic studies of spectral reflectance and crater systematics show that basalts of varying Ti content were extruded throughout the history of mare volcanism. These new discoveries indicate that mare basalts can no longer be classified into the two simple groups of older high-Ti basalts and younger low-Ti basalts.

Size can be used as a criterion to select 18 large (larger than 1 cm) samples from among 148 melt-rock fragments of all sizes. This selection provides a suite of large samples which represent the important chemical variants among highland melt rocks; each large sample has enough material for a number of sample-destructive studies, as well as for future reference. Cluster analysis of the total data base of 148 highland melt rocks shows six distinct groups: anorthosite, gabbroic anorthosite, anorthositic gabbro ('highland basalt'), low K Fra Mauro, intermediate-K Fra Mauro, and high-K. Large samples are available for four of the melt-rock groups (gabbroic anorthosite, anorthositic gabbro, low-K Fra Mauro, and intermediate-K Fra Mauro). This sample selection reveals two subgroups of anorthositic gabbro (one anorthite-poor with negative Eu anomaly and one anorthite-rich without Eu anomaly). There is a sharp distinction between those Apollo 16 melt rocks and glasses which have both been classified as 'gabbroic anorthosite'.

The ferrogabbro 24077,13, with pyroxene and plagioclase major and minor element chemical ranges comparable to the dominant ferrogabbro component in the Luna 24 core, has a Ar-39-Ar-40 temperature release age of 3.33 plus or minus 0.21 billion years. The metaferrobasalt 24077,63 is very fine-grained with a texture and mineralogy consistent with contact metamorphism between superimposed basalt flows or within a single flow. The Ar-39-Ar-40 plateau age of 24077,63 is 3.26 plus or minus 0.4 billion years. The basalt flows in Mare Crisium are about the same age as those of Mare Imbrium and younger than those of Mare Tranquillitatis and Mare Serenitatis.

Detailed petrographic examination of 22 thin sections from the impregnated portion of the Apollo 16 double drive tube supports the findings of previous workers. A well-gardened unit exists at the top of 60010, indicated petrographically by an increase in agglutinates near the lunar surface. There is a coarse-grained anorthositic layer near the bottom of 60009. Few, if any, of the modal variations are stratigraphically correlatable with the deep drill core 60002-7, which was recovered 50 m southwest of drive tube 60009/60010.

Results are summarized for a consortium study of the chemistry, mineralogy, and petrology of seven Luna 24 fragments greater than 1 mm in size and having a mass of about 2 mg each. The fragments include four samples of mare ferrobasalt composition, one vitrophyre with the composition of a Mg-rich VLT mare basalt, one agglutinate, and one plagioclase fragment. It is found that: (1) the ferrobasalt is a highly fractionated mare rock very low in alkalis and TiO2, is similar to the less fractionate Apollo 17 VLT basalts, and is quite low in large-ion lithophile trace-element content; (2) the rare-earth-element patterns of the ferrobasalts are typical of VLT basalt, but some ophitic basalts have positive Eu anomalies, while others have negative Eu anomalies typical of mare basalts; and (3) the agglutinate is feldspathic and similar in composition to soil fines in Fe, Cr, Ca, and Al.

Instrumental neutron activation analysis was used to examine 34 major, minor and trace elements in 48 bulk soils and size fractions (90-1000 microns, 20-90 microns and less than 20 microns) of the Apollo 17 deep drill core sections 70009-70006 (upper 130 cm). Modal data were also obtained for the less than 20 micron size fraction. Preliminary results indicate that (1) the chemistry of the greater than 90 micron and 20-90 micron coarse fractions is identical but quite different from the less than 20 micron fine fraction; (2) the upper 50 cm of the drill core is highly enriched in mare material; (3) the dominant source of highland material is KREEPy instead of anorthositic; and (4) indigenous volatiles such as Zn are quite high in all size fractions.

The paper summarizes petrographic and electron microprobe data from 22 polished thin sections that represent the total length of double drive tube 60009/60010 and discusses a new application of the method of modal recombination to estimate bulk chemistry. The modal recombination approach can be used to reliably calculate the chemistry of the greater than 0.02-mm size fraction and, more significantly, to derive the total major element partitioning among the regolith components.

Phaneritic fragments, vitrophyres, and glass beads of a new very low Ti (VLT) mare basalt are found in the Apollo 17 drill core. VLT lithic fragments are characterized by TiO2 content of approximately 0.5%, Mg/(Mg + Fe) of approximately 0.52, CaO/Al2O3 of approximately 0.9, and low alkali content. Although mineral systematics and modal composition of VLT basalt are similar to Apollo 12 and 15 low Ti basalts, VLT basalts cannot be related to these mare basalts by crystal fractionation. Since VLT basalt is isochemical with some of the less mafic green glasses, fractionation of VLT magma from a liquid of green-glass composition is a possibility. Spectral reflectance studies suggest that VLT-type basalts may be relatively common in mare basins.

On the basis of modal petrography the upper, mare basalt-rich portion of the Apollo 17 drill core (sections 70007, 70008, 70009) can be subdivided into three major stratigraphic units. The lower unit (a) falls within 70007, is relatively mature, and contains evidence of an increase in highland component and decrease of mare component within the lower approximately 8 cm. The middle unit (b) is coarse-grained and relatively immature; this unit has the highest concentration of mare basalt lithic and mineral fragments and mare orange/black glasses. The top unit (c) falls within 70009 and is relatively mature. Within these three sections of the drill core, there are compositional clusters of glass beads that correspond to high Ti subfloor basalt (orange/black glass), anorthositic gabbro (clear glass), and a new very low Ti (VLT) mare basalt (yellow/green glass).

Compositionally, lunar mare basalts are similar to some very young subalkaline basalts from terrestrial mid-ocean ridges and to very old pods of basaltic material incorporated into ancient metamorphic rocks. Basalt flows in Mare Imbrium are considered, taking into account the results of orbital gamma ray spectroscopic studies. The results of the analyses of lunar samples obtained from the Apollo missions are evaluated and various models are discussed in connection with an interpretation of the observed conditions.

The paper attempts a synthesis of the major-element chemistry, petrography, mineral chemistry, and crystal chemistry of the mare basalts returned by Apollo and Luna missions. A classification of the mare basalts based on major-element chemistry is given, and textural sequences within each major-element group are identified. The mineral chemistry and crystal chemistry of each mineral group are considered within the framework of the major-element groups and the textural sequences. The various classes of models for the origin of the mare basalts and the nature of their source regions are discussed in the context of the major- and trace-element chemistries and experimental investigations.

Review of the crystallization histories suggested by the chemical, crystallographic, morphological, and paragenetic relationships observed in pyroxenes from basalts collected on the Apollo 11, 12, 14, 15, and Luna 16 missions. Although the final stages of lunar basalt crystallization appear to be rapid near-surface events, the initial stages are shown to vary considerably among the different basalt types.

Basaltic and monomineralic fragments from the 150-425 micron size fractions of the Luna 16 core obtained from the Sea of Fertility were studied by optical petrographic, electron microprobe, and single-crystal X-ray diffraction techniques. Three textural varieties were identified in the basalts (intersertal, subophitic, and recrystallized). These textures, the assemblages, and individual mineral compositions (especially pyroxenes) indicate that these basalts crystallized under conditions very similar to those from Apollo 11. The pyroxenes have slightly lower Ti/Al (atomic) ratios than the Apollo 11 pyroxenes. We interpret the presence of octahedral Al as being due to the low TiO2/Al2O3 (weight %) ratio in the bulk rock. All observations made on the fine-grained basalt fragments are consistent with a rapid, near-surface, one-stage crystallization history.

Apollo 12 clinopyroxenes exsolution and epitaxy by electron microprobe and single crystal X ray diffraction

Clinopyroxene crystallization histories of Apollo 12 porphyritic basalt rocks 12021 and 12052 from Oceanus Procellarum

High temperature phase transition and composition of Apollo 12 pigeonite/augite clinopyroxene crystal rock 12021 from X ray diffraction

Apollo 11 igneous rock vug clinopyroxene composite crystal with tabular pigeonite nucleus and subcalcic augite precipitation

Clinopyroxenes from Apollo 12 rocks studied by X ray diffraction and electron microprobe methods, noting phenocrysts, chemical composition and crystallization

Apollo 11 lunar rocks and fines, examining clinopyroxenes augite and pigeonite by single crystal X ray diffraction microprobe optical and electron optical techniques

Basalt and single-mineral particles, ranging from 150 to 425 microns, from the Luna-16 sample are studied by electron microanalysis, X-ray fluorescence analysis, and petrographic techniques. Three basalt species of different structure are identified. The structure and composition of the individual minerals (in particular of pyroxenes) indicate that the basalts have crystallized under conditions similar to those established for Apollo-11 samples.

The petrography, phase chemistry, and Ar-40/Ar-39 ages of 2-4 mm fragments from the soils of both mare and highlands stations sampled by Apollo 17 are studied. It is found that the massifs consist of a complex stratigraphy of interlayered noritic breccias of varying metamorphic grades, melt rocks, and anorthositic rocks. A stratigraphic correlation of the lithologies within the North Massif and the South Massif is carried out. The petrogenesis of rock types with respect to thermal and impact history is discussed. The observed spinel cataclasites may represent relatively deep material sampled by the Serenitatis event.

Two distinct chemical basalt types have been sampled at the Apollo 17 landing site. Very high-titanium basalts (about 13 wt % TiO2) are the dominant type and display a textural range from olivine-porphyritic, ilmenite vitrophyres to plagioclase-poikilitic, ilmenite microgabbros. Most of these rocks could have come from one flow. These basalts appear to represent partial melts from feldspar-ilmenite cumulates with an Ar-40/Ar-39 age of about 3.7 G.y., which have experienced little, if any, near-surface fractionation of olivine and Fe-Mg-Ti oxides. A second type of basalt virtually identical to the Apollo 11 (low-K) basalts is much less common.

Only fine-grained rocks are present in the Luna 20 samples, and coarser-grained rocks are represented by fragments of single crystals. A petrologic study has been made of 47 fine-grained crystalline rocks, microbreccias, and glassy aggregates. In addition, a total of 33 single crystals of pyroxene, plagioclase, olivine, and spinel, in the size range from 125 to 500 microns, have been examined using electron microprobe and single-crystal X-ray diffraction techniques. The most abundant fine-grained crystalline rocks in the samples examined are recrystallized anorthositic norite and anorthositic troctolite. Gabbroic rocks, anorthosite, and KREEP basalt are present but not common. Most of the single crystals of pyroxene and plagioclase could have been derived from coarser-grained noritic, troctolitic, and anorthositic rocks. However, three of the 14 pyroxene crystals, and two of the five olivine crystals have Fe/(Fe + Mg) contents greater than 0.45 and are believed to have been derived from mare basalts or related rocks.

The results of detailed petrographic, X-ray, electron microprobe, ion probe, and Ar-40/Ar-39 age studies of pyroxene poikiloblastic breccias, an important lunar highlands lithology, are interpreted to indicate that high grade metamorphic recrystallization occurred over wide regions of the moon at about 4.0 G.y. This metamorphism was probably related to a period of high meteorite influx at that time. The temperatures achieved were highly variable but in some cases were sufficiently intense to cause varying degrees of partial melting of the precursor highlands breccias. A complete spectrum of metamorphic grades from only slight recrystallization to virtually complete melting would be expected in such a model. Such a spectrum is observed in the Apollo 16 rocks.

Analysis of 'inverted pigeonites' found in Apollo 14 samples 14082 and 14083 (a polymict breccia, the 'white rock') by a combination of optical, electron probe, and single-crystal X-ray diffraction techniques. These 'inverted pigeonites' are regarded as samples of plutonic rocks that have been blasted out of the Imbrium Basin. It is also concluded that lunar pigeonites will invert to orthopyroxenes, given sufficiently slow cooling histories even in very anhydrous environments.