101. THE ROVIBRATIONAL INTENSITIES OF THE 2ν3 BAND OF 12C16O18O AT 4639cm-1
- Author
-
Charles Chackerian, R. J. Kshirsagar, Linda R. Brown, and Lawrence P. Giver
- Subjects
Radiation ,Solar observatory ,Materials science ,Carbon-12 ,Analytical chemistry ,Natural abundance ,Rotational–vibrational spectroscopy ,Atomic and Molecular Physics, and Optics ,Spectral line ,Nuclear magnetic resonance ,Observatory ,HITRAN ,Spectroscopy ,Oxygen-16 - Abstract
The absolute intensities of transitions in the 2 ν 3 vibrational band of 12 C 16 O 18 O at 4639.5 cm -1 have been measured in natural isotopic abundance; the spectra were obtained with 0.012 cm -1 resolution using the McMath Fourier transform spectrometer of the National Solar Observatory located at Kitt Peak National Observatory. About 70 transitions have been fitted with an rms deviation of approximately 1.5% to obtain the rotationless band strength of S 0 vib =1.442×10 -23 cm molecule -1 at 296 K along with a small first-order Herman–Wallis parameter of A 1 =3.5×10 -5 ; higher order Herman–Wallis parameters could not be determined. The measured line positions, obtained using the CO 2 gas samples in the range of 45–65 Torr at room temperature, confirm the current HITRAN tabulated values. The internal precision of our intensity measurements is very high, and the uncertainty due to possible systematic errors is judged to be less than ±3%.
- Published
- 1999