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101. Total synthesis of pinguisone

Author

Massimo Sisti, Stefania Montanari, Silvana Bernasconi, Pierluigi Gariboldi, and Giancarlo Jommi

Subjects
Chemistry, Stereochemistry, Total synthesis, Stereoselectivity
Abstract

A stereoselective total synthesis of pinguisone (1) from the known (S)-(+)2,3,7,7a-tetrahydro-7a-methyl-6H-indene-1,5-dione (3) is described. The utilization of common intermediates in the synthesis of pinguisone-like and 7-epi-pinguisone-like compounds is discussed.

Published
1981
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