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In this study, we present a full characterization of the electronic properties of phase change material (PCM) double-layered heterostructures deposited on silicon substrates. Thin films of amorphous Ge-rich Ge-Sb-Te (GGST) alloys were grown by physical vapor deposition on Sb2 Te3 and on Ge2 Sb2 Te5 layers. The two heterostructures were characterized in situ by X-ray and ultraviolet photoemission spectroscopies (XPS and UPS) during the formation of the interface between the first and the second layer (top GGST film). The evolution of the composition across the heterostructure interface and information on interdiffusion were obtained. We found that, for both cases, the final composition of the GGST layer was close to Ge2 SbTe2 (GST212), which is a thermodynamically favorable off-stoichiometry GeSbTe alloy in the Sb-GeTe pseudobinary of the ternary phase diagram. Density functional theory calculations allowed us to calculate the density of states for the valence band of the amorphous phase of GST212, which was in good agreement with the experimental valence bands measured in situ by UPS. The same heterostructures were characterized by X-ray diffraction as a function of the annealing temperature. Differences in the crystallization process are discussed on the basis of the photoemission results.

Submarine hydrothermal systems along active volcanic ridges and arcs are highly dynamic, responding to both oceanographic (e.g., currents, tides) and deep-seated geological forcing (e.g., magma eruption, seismicity, hydrothermalism, and crustal deformation, etc.). In particular, volcanic and hydrothermal activity may also pose profoundly negative societal impacts (tsunamis, the release of climate-relevant gases and toxic metal(loid)s). These risks are particularly significant in shallow (<1000m) coastal environments, as demonstrated by the January 2022 submarine paroxysmal eruption by the Hunga Tonga-Hunga Ha’apai Volcano that destroyed part of the island, and the October 2011 submarine eruption of El Hierro (Canary Islands) that caused vigorous upwelling, floating lava bombs, and natural seawater acidification. Volcanic hazards may be posed by the Kolumbo submarine volcano, which is part of the subduction-related Hellenic Volcanic Arc at the intersection between the Eurasian and African tectonic plates. There, the Kolumbo submarine volcano, 7 km NE of Santorini and part of Santorini’s volcanic complex, hosts an active hydrothermal vent field (HVF) on its crater floor (~500m b.s.l.), which degasses boiling CO2–dominated fluids at high temperatures (~265°C) with a clear mantle signature. Kolumbo’s HVF hosts actively forming seafloor massive sulfide deposits with high contents of potentially toxic, volatile metal(loid)s (As, Sb, Pb, Ag, Hg, and Tl). The proximity to highly populated/tourist areas at Santorini poses significant risks. However, we have limited knowledge of the potential impacts of this type of magmatic and hydrothermal activity, including those from magmatic gases and seismicity. To better evaluate such risks the activity of the submarine system must be continuously monitored with multidisciplinary and high resolution instrumentation as part of an in-situ observatory supported by discrete sampling and measurements. This paper is a design study that d

The Brazilian Amazon has been a focus of land development with large swaths of forests converted to agriculture. Forest degradation by selective logging and fires has accompanied the agricultural frontier and has resulted in significant impacts on Amazonian ecosystems. Changes in forest structure resulting from forest disturbances have large impacts on the surface energy balance, including on land surface temperature (LST) and evapotranspiration (ET). This study's objective is to assess the effects of forest disturbances on water fluxes and forest structure in a transitional forest site in the Southern Amazon. We used ET and LST products from MODIS and Landsat 8 and GEDI-derived forest structure data to address our research questions. We found that disturbances induced seasonal water stress, more pronounced in croplands/pastures than in forests (differences up to 20% in the dry season), and more pronounced in second-growth and recently burned areas than in logged and intact forests (differences up to 12% in the dry season). Moreover, ET and LST were negatively related, with more consistent relationships across disturbance classes in the dry season (R2: 0.41–0.87) than in the wet season (R2: 0.18–0.49). Forest and cropland or pasture classes showed contrasting relationships in the dry season. Finally, we found that forest structure exhibited stronger relationships with ET and LST in the most disturbed forests (R2: 0.01–0.43) than in the least disturbed forests (R2 < 0.05). Our findings help to elucidate degraded forests functioning under a changing climate and to improve estimates of water and energy fluxes in Amazonian degraded forests.

Understanding the effects of intensification of Amazon basin hydrological cycling manifest as increasingly frequent floods and droughts on water and energy cycles of tropical forests is essential to meeting the challenge of predicting ecosystem responses to climate change including forest tipping points Here we investigated the impacts of hydrological extremes on forest function using 12 years of observations between 2001 2020 of water and energy fluxes from eddy covariance along with associated ecological dynamics from biometry at the Tapaj s National Forest Measurements encompass the strong 2015 2016 El Ni o drought and La Ni a 2008 2009 wet events We found that the forest responded strongly to El Ni o Southern Oscillation ENSO Drought reduced water availability for evapotranspiration ET leading to large increases in sensible heat fluxes H Partitioning ET by an approach that assumes transpiration T is proportional to photosynthesis we found that water stress induced reductions in canopy conductance G sub s sub drove T declines partly compensated by higher evaporation E By contrast the abnormally wet La Ni a period gave higher T and lower E with little change in seasonal ET Both El Ni o Southern Oscillation ENSO events resulted in changes in forest structure manifested as lower wet season leaf area index However only during El Ni o 2015 2016 we observed a breakdown in the strong meteorological control of transpiration fluxes via energy availability and atmospheric demand because of slowing vegetation functions via shutdown of G sub s sub and significant leaf shedding Drought reduced T and G sub s sub higher H and E amplified by feedbacks with higher temperatures and vapor pressure deficits signaled that forest function had crossed a threshold from which it recovered slowly with delay post drought Identifying such tipping point onsets beyond which future irreversible processes may occur at local scale is crucial for predicting basin scale threshold crossing changes

The collection of articles in this symposium is dedicated to Gerd Weinrich, our friend, mentor and colleague. A workshop in his honor, was held on November 12, 2021 at Catholic University in Milano, where some of these articles were presented. This symposium marks our appreciation of his contribution to economics and of his dedication to research and teaching.

This paper presents an improved 2D modelling strategy which aims to represent the behavior of historical unreinforced masonry buildings on shallow foundations subjected to ground settlements. The application is presented with reference to a two-storey building, typical of the Dutch built heritage. The novelty comprises the inclusion of the effect of the lateral house-to-house separation walls of such old buildings. Additionally, the masonry strip foundation is modelled and supported by a boundary interface representing the interaction between the soil and the foundation. Two realistic hogging and sagging settlement configurations are applied to the model and their intensity is characterized using the angular distortion of the settlement shape. The response in terms of damage and deformations of the proposed modelling strategy is compared with the ones of five selected approaches based on the state of the art. For all the selected models, the damage severity is quantified objectively by means of a scalar parameter, which is computed considering the cracks’ number, length, and width. The results of the proposed 2D model agree in terms of displacements, crack patterns and damage with the 3D models. On the contrary, the façade models that do not include the effect of the lateral walls do not exhibit the same cracking and damage, resulting in lower damage and deformations for the same applied angular distortion. Accordingly, the proposed modelling strategy requires less modelling complexity and the analyses are 9 to 28 times faster to run with respect to the 3D models. The efficient and accurate model allows performing a wide number of analyses to easily investigate the role of the various building’s features., Green Open Access added to TU Delft Institutional Repository ‘You share, we take care!’ – Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public., Applied Mechanics, Geo-engineering

Canals delimited by masonry quay walls are integral elements of many cities in the Netherlands. Historically built to enable the efficient transportation of goods, today such infrastructure also gives the cities their historical and monumental character. In recent years, many quay walls in the Netherlands have shown substantial deformation and damage, and in few cases even collapse. Historical quay walls, which are constructed in thick multi-wythe unreinforced brick masonry and are supported on a system of timber piles, nowadays sustain traffic loads larger than the one they were designed for. Instances of collapse and severe damage has given rise to a need for research assessing the safety of these structures, which are not appropriately covered by any normative or standardised guidelines. This paper presents a novel methodology to numerically assess the performance of masonry walls in historical quays under the dynamic effect of traffic loads. Application of the proposed methodology to a case study in Amsterdam, the Netherlands, is presented., Green Open Access added to TU Delft Institutional Repository ‘You share, we take care!’ – Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public., Applied Mechanics

Historical masonry façades are sensitive to various damaging processes. A recent study, looking at the initiation and progression of cracks in masonry, in the range of 0.1 to 5 mm in width and thus corresponding to light damage [1], has allowed for the calibration of finite-element models that include a material model capable of accurately replicating this damage and which is populated with material properties corresponding to existing structures [6]. The models, which also include a soil-structure interaction boundary designed to account for the effect of the soil during earthquake vibrations [7], have been used to determine the fragility of masonry buildings via the proxy of 2D walls [2]. In the study presented herein, the finite element models are employed to replicate the geometry of (historical) masonry facades to determine their sensitivity to light damage as a consequence of the two damaging processes observed to be most common for this type of façade, namely (differential) settlements and (earthquake) vibrations [3]. The masonry façades were first pre-damaged via settlement distortions which generate just-visible cracks in the order of 0.1 mm to 1 mm in width. Then, an acceleration time history corresponding to two different Dutch earthquake events and two recordings of traffic-induced building vibrations [9] were separately applied at the base of the models. In this manner, the effect of existing damage could be assessed in regards to the aggravation generated by vibrations. The settlement part of the study revealed that long façades were more vulnerable to applied soil distortions, for instance. Then, subsequent vibrations further increased damage for intensities measured with a peak ground velocity (PGV) larger than 2 mm/s while the control set of virgin or uncracked façades remained undamaged at this PGV. At 32 mm/s, many pre-damaged façades also exceeded the light damage range. At equal PGV, the traffic vibrations, with a larger number of effective c, Green Open Access added to TU Delft Institutional Repository ‘You share, we take care!’ – Taverne project https://www.openaccess.nl/en/you-share-we-take-care Otherwise as indicated in the copyright section: the publisher is the copyright holder of this work and the author uses the Dutch legislation to make this work public., Applied Mechanics

Uncertainty in how the land carbon (C) sink will change over time contributes to uncertainty in Earth system model (ESM) projections of climate change. Much of the land sink is thought to reside in old-growth tropical forests, but recent analyses suggest a diminishing C sink in these forests due to rising temperatures and drought. Thus, there is an urgent need to better understand tropical forest responses to drought and to incorporate this understanding into ESMs. Previous work with vegetation demographic models (VDMs) – which represent the dynamics of individuals or cohorts, along with hydrology and biogeochemistry − suggest that functional diversity can enhance tropical forest resilience to climate change. However, there is little understanding of how different approaches to representing trait diversity and demography affect model outcomes. To explore the potential for trait diversity to moderate tropical forest responses to drought, we explored the behavior of nine VDMs, ranging from models with detailed site-level parameterizations to more generalized land models designed as ESM components. The behavior of each model was studied using soil and meteorological data collected at each of two tropical forest sites: Paracou Research Station, French Guiana, and Tapajos National Forest, Brazil. Low and high trait-diversity scenarios were simulated for each model using historical meteorology, as well as reduced rainfall scenarios. Few models showed strong effects of trait diversity on drought resistance (short-term response of forest biomass to rainfall reduction), but most models showed positive effects of diversity on resilience (long-term recovery of forest biomass following the initial biomass loss due to rainfall reduction). Long-term recovery was always associated with shifts in community composition towards greater drought-tolerance. However, there were large differences among models in the degree and time-scale of recovery. These differences were unrelated to th

This paper demonstrates the use of non-linear finite element modelling to investigate the response of structures subjected to different shapes of subsidence-related ground settlements. The approach is presented with reference to a two-storey unreinforced masonry façade resting on a shallow foundation. Eight realistic settlement shapes, based on field and literature data, are applied in the model with increasing intensity. The intensity of the subsidence profiles is characterized using their (angular) distortion. The extent of the induced damage on the façade is objectively and directly quantified by a damage parameter, based on the number of cracks, their length and opening. The performance of different settlement indicators and corresponding limiting values, typically employed in the state of the art, is in this paper discussed in relation to the damage modelling strategy; these are observed to be dependent on the shape of the settlement profiles. The aim of this paper is thus to provide insight into the extent to which the vulnerability of masonry buildings depends on the shape of the subsidence pattern and may serve as a warning not to use (deterministic) damage indicators such as angular distortion without considering the settlement shape., Applied Mechanics, Geo-engineering

This study aims to investigate the damage response of unreinforced masonry (URM) façades resting on strip foundations and subjected to ground settlements via numerical models. The models depict the non-linear constitutive behaviour of both the masonry, via smeared cracking, and of the soil-foundation interaction, via nonlinear interface elements. The influence of building features, such as the masonry material, the length over height (L/H) ratio of the geometry, the wall thickness, the number and size of openings and different types of strip foundations (i.e. reinforced concrete and unreinforced) is examined. A sensitivity study additionally investigates the influence of the interface stiffness and its constitutive model. A Gaussian curve is used to replicate the shape of the ground settlements; These simulate the loss of support underneath the foundation due to urban subsidence. Eight settlement shapes are applied in the FE models, including both symmetric and asymmetric profiles, while the angular distortion is used to measure their intensity. A new aspect is that the extent of the induced damage to the façade is assessed objectively using a damage parameter that represents the number, length and width of cracks in a single scalar value. The method distinguishes between the applied settlement profile at the bottom of the interface and the retrieved settlement profile measured on the façade. The analyses indicate that for a value of the angular distortion equal to 2 ‰ (or 1/500), computed from the resulting deformations of the façades, 60% of the models exhibit serviceability damage associated with cracks of about 5 mm width. Accordingly, the limit values available in the literature are observed to be too optimistic and not conservative in relation to the analyses presented in this study. A key outcome is that facades with an L/H smaller or equal to 1 do not exhibit cracks wider than 1 mm. Façades on reinforced concrete foundations were observed to be less susce, Applied Mechanics, Geo-engineering

Historical quay walls constructed in unreinforced masonry are integral elements of many cities. Originally designed as gravity retaining walls, they are nowadays often subjected to the action of traffic loads as a result of vehicles travelling on roads constructed on their backfill. This paper presents a numerical analysis procedure for carrying out the structural assessment of quay walls under traffic loads. The procedure simulates the non-linear dynamic response of the quay wall under the effect of the passage of a vehicle. Non-linear dynamic calculations are performed not only to be representative of the actual nature of loading but also to produce realistic estimations of structural safety, load redistribution capacities and displacements. Adopting a tier-based approach, the computational burden typically associated with such simulations is significantly reduced. This is obtained by adopting simplifications which allow for the modelling the 3D soil block comprising the backfill of the quay wall only in the first tier of the procedure. To demonstrate the implementation of the procedure, a detailed application to an existing quay wall in Amsterdam, the Netherlands, is presented. Different foundation damage scenarios are also considered. Though the procedure is presented in this paper for a specific typology of quay walls, it has conceptual and methodological value. With appropriate modifications it can be used for the structural assessment of other earth retaining structures as well, under the effect of vehicular traffic on their backfills., Applied Mechanics