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101. Substrate water exchange in photosystem II core complexes of the extremophilic red alga Cyanidioschyzon merolae

102. Absence of Mn-Centered Oxidation in the S2 → S3 Transition: Implications for the Mechanism of Photosynthetic Water Oxidation

103. High-resolution X-ray spectroscopy of rare events: a different look at local structure and chemistry

104. Hydration of the oxygen-evolving complex of photosystem II probed in the dark-stable S1 state using proton NMR dispersion profiles

105. Substrate-water exchange in photosystem II is arrested before dioxygen formation

106. Ammonia binding to the oxygen-evolving complex of photosystem II identifies the solvent-exchangeable oxygen bridge (μ-oxo) of the manganese tetramer

107. Electronic Structural Changes of Mn in the Oxygen-Evolving Complex of Photosystem II During the Catalytic Cycle

108. Efficiency of photosynthetic water oxidation at ambient and depleted levels of inorganic carbon

109. Simultaneous femtosecond X-ray spectroscopy and diffraction of photosystem II at room temperature

110. On the functional significance of substrate accessibility in the photosynthetic water oxidation mechanism

111. An EPR and ENDOR Spectroscopic Investigation of the Ca2+-Depleted Oxygen-Evolving Complex of Photosystem II

112. Artificial photosynthesis as a frontier technology for energy sustainability

113. Studying the oxidation of water to molecular oxygen in photosynthetic and artificial systems by time-resolved membrane-inlet mass spectrometry

114. Toward a Low‐Cost Artificial Leaf: Driving Carbon‐Based and Bifunctional Catalyst Electrodes with Solution‐Processed Perovskite Photovoltaics

115. Detection of one slowly exchanging substrate water molecule in the S3 state of photosystem II

116. Energy-dispersive X-ray emission spectroscopy using an X-ray free-electron laser in a shot-by-shot mode

117. Principles of photosynthesis

118. Room temperature femtosecond X-ray diffraction of photosystem II microcrystals

119. Analyses of pH-Induced Modifications of the Period Four Oscillation of Flash-Induced Oxygen Evolution Reveal Distinct Structural Changes of the Photosystem II Donor Side at Characteristic pH Values

120. Photosynthetic O2 Evolution

121. Importance of post-translational modifications for functionality of a chloroplast-localized carbonic anhydrase (CAH1) in Arabidopsis thaliana

122. Effect of Ca2+/Sr2+ substitution on the electronic structure of the oxygen-evolving complex of photosystem II: a combined multifrequency EPR, 55Mn-ENDOR, and DFT study of the S2 state

123. Membrane-inlet mass spectrometry reveals a high driving force for oxygen production by photosystem II

124. Calcium manganese oxides as oxygen evolution catalysts: O2 formation pathways indicated by 18O-labelling studies

126. X-ray emission spectroscopy to study ligand valence orbitals in Mn coordination complexes

127. A new quantum chemical approach to the magnetic properties of oligonuclear transition-metal complexes: application to a model for the tetranuclear manganese cluster of photosystem II

128. On-line mass spectrometry: membrane inlet sampling

129. Photo-catalytic oxidation of a di-nuclear manganese centre in an engineered bacterioferritin 'reaction centre'

130. Catalysts for solar water splitting

132. Effects of methanol on the Si-state transitions in photosynthetic water-splitting

133. Formate-Induced Release of Carbon Dioxide/ Hydrogencarbonate from Photosystem II

135. Substrate Water Bound to the S2-State of the Mn4OxCa Cluster in Photosystem II Studied by Advanced Pulse EPR Spectroscopy

136. Oxygen Evolving Reactions by Synthetic Manganese Complexes

137. Effects of Chloride/Bromide Substitution on Substrate Water Exchange Rates in Photosystem II

138. Structure of the Photosynthetic Mn4Ca Cluster Using X-ray Spectroscopy

139. Electronic Structure and Oxidation State Changes in the Mn4Ca Cluster of Photosystem II

140. Focusing the view on nature's water-splitting catalyst

141. High-resolution structure of the photosynthetic Mn4Ca catalyst from X-ray spectroscopy

142. Electronic Structure of the Mn4Ca Cluster in the Oxygen-Evolving Complex of Photosystem II Studied by Resonant Inelastic X-Ray Scattering

143. Chapter 17. Photosynthetic Water Splitting

144. Valence-to-Core X-Ray Emission Spectroscopy as a Tool for Investigation of Organometallic Systems

145. Structure and orientation of the Mn4Ca cluster in plant photosystem II membranes studied by polarized range-extended x-ray absorption spectroscopy

146. High-resolution Mn EXAFS of the oxygen-evolving complex in photosystem II: structural implications for the Mn4Ca cluster

147. Evidence that bicarbonate is not the substrate in photosynthetic oxygen evolution

148. X-ray damage to the Mn4Ca complex in single crystals of photosystem II: A case study for metalloprotein crystallography

149. Electron spin-lattice relaxation of the S0 state of the oxygen-evolving complex in photosystem II and of dinuclear manganese model complexes

150. Mechanism of Photosynthetic Oxygen Production

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