101. Superconductivity and Magnetic Ordering of Pr in <font>CaLa</font>1-x<font>Pr</font>x<font>BaCu</font>3<font>O</font>7 System
- Author
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A. V. Narlikar, E. Gmelin, J.M. Ferreira, D.A. Landínez Téllez, J. Albino Aguiar, V. P. S. Awana, Rajvir Singh, and S. Uma
- Subjects
Superconductivity ,Paramagnetism ,Tetragonal crystal system ,Materials science ,Condensed matter physics ,Impurity ,Transition temperature ,Antiferromagnetism ,Statistical and Nonlinear Physics ,Condensed Matter Physics ,Magnetic susceptibility ,Heat capacity - Abstract
We present the results of superconductivity, normal state magnetic susceptibility and heat capacity measurements on the tetragonal CaLa 1-x Pr x BaCu 3 O 7 compound. Ac susceptibility measurements show that the transition temperature T c of the unsubstituted sample decreases with an increase in the Pr concentration. Normal state dc magnetic susceptibility measurements performed in an applied field of 0.5 T show a Curie–Weiss behaviour in terms of the paramagnetic moment of Pr. The effective paramagnetic moment of Pr appears to be intermediate between those of the free Pr 3+ and Pr 4+ ions. For the nonsuperconducting samples i.e., x = 0.70 and 1.0, we observe an antiferromagnetic ordering temperature T N of nearly 4 K and 8 K respectively. The X-ray diffraction results show that the CaPrBaCu 3 O 7 compound is free from other phases, having a minor (less than 8%, in terms of peak intensity) impurity phase. The lower T N (8 K) of PrBaCaCu 3 O 7 as compared to the known antiferromagnetic ordering temperature of 17 K for PrBa 2 Cu 3 O 7 indicates a less deleterious effect of Pr in the present case.
- Published
- 1997
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