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The limited mechanical properties of Al–Si alloys hinder their application in demanding and extreme conditions. The cracking tendency of high-strength aluminum alloys and high-cost of rare-earth elements pose challenges for the large-scale application of aluminum alloys in additive manufacturing. The novel and practical high-speed scanning remelting proposed in this study enables Al–Si alloys to exhibit significant proportion of fine microstructures and nano-precipitates, surpassing the mechanical properties of aluminum alloys fabricated by normal methods with exceptional strength (496.1 ± 5.8 MPa) and plasticity (21.4 ± 0.9%). This in-situ microstructure control method opens new pathways for the application in demanding engineering contexts. [ABSTRACT FROM AUTHOR]

The inferior creep ductility of Inconel 718 (IN718) fabricated by selective laser melting (SLM), which is unable to meet aerospace material specification (≥4%), limits its engineering application. Despite persistent optimization efforts in the SLM process and post-heat treatment, this issue remains unresolved. This study involved SLM fabrication of the modified IN718 with trace amounts of LaB6 and/or P, followed by homogenization and double aging heat treatment. The addition of trace LaB6 notably influenced the recrystallized grain structure and carbide precipitation at grain boundaries, while trace P addition had minimal impact. All samples exhibited similar γ′ and γ″ strengthening precipitates. Creep tests conducted at 650°C/690 MPa revealed that the individual modification of LaB6 showed limited improvement in creep performance and P showed no improvement, but the combined addition of LaB6 and P led to a substantial enhancement in creep performance, especially reaching as high as 8.6% creep strain. This remarkable improvement in creep ductility is unlikely to arise from the altered grain structure and grain boundary precipitates induced by LaB6 but predominantly arises from the synergistic effect of P and B in enhancing resistance to crack propagation during the third stage of creep. [ABSTRACT FROM AUTHOR]

Waste tires, used in combination with polymers, have been extensively employed in the construction of asphalt pavements. The performance of these hybrid asphalts varies depending on the manufacturing process, the characteristics of the neat binder, and other factors. The present study aims to investigate the effect of crumb rubber, polymer, and neat asphalt on physicochemical and rheological properties of terminal blend rubberized asphalt (TBRA). Thermal gravimetric (TG) testing was performed to analyze the component distribution of different crumb rubber modifiers (CRMs). Fourier transform infrared spectroscopy (FTIR), gel permeation chromatography (GPC), and solubility and storage stability tests were used to characterize the physicochemical properties of TBRA binders. The rotational viscosity (RV) test, high-temperature performance grade (PG), and rheological master curve were used to compare the rheological properties of various TBRA binders, respectively. Results indicated that crumb rubber and neat binder characteristics, as well as the addition of polymer, impact TBRA performance. However, the influence of neat binder and polymer is more significant than that of crumb rubber. The primary differences in the physicochemical properties of TBRA prepared with different crumb rubber types are related to solubility and degradation degree. The interaction between Zhonghai neat asphalt and crumb rubber is weaker than that of ESSO and Jinshan asphalt, as evidenced by a comparison of molecular weight distribution. Moreover, 3.0% styrene-butadiene-styrene (SBS) polymer can significantly improves the elastic property of TBRA produced with ESSO neat asphalt, which is evidenced by similar phase angle plateau region with 4.5% SBS modified asphalt. [ABSTRACT FROM AUTHOR]

Lipids are organic nonpolar molecules with essential biological and economic importance. While the genetic pathways and regulatory networks of lipid biosynthesis and metabolism have been extensively studied and thoroughly reviewed in oil crops such as soybeans, less attention has been paid to the biological roles of lipids in rice, a staple food for the global population and a model species for plant molecular biology research, leaving a considerable knowledge gap in the biological roles of lipids. In this review, we endeavor to furnish a current overview of the advancements in understanding the genetic foundations and physiological functions of lipids, including triacylglycerol, fatty acids, and very-long-chain fatty acids. We aim to summarize the key genes in lipid biosynthesis, metabolism, and transcriptional regulation underpinning rice's developmental and growth processes, biotic stress responses, abiotic stress responses, fertility, seed longevity, and recent efforts in rice oil genetic improvement. [ABSTRACT FROM AUTHOR]

Effects of secondary gas injection on flame shape and combustion stability of a premixed swirl methane/air flame were investigated experimentally. Without secondary gas injection, an attached M-shaped flame was observed with pressure oscillations up to a sound pressure level of 68 dB. The flame exhibited significant oscillations due to flame–vortex interactions induced by velocity fluctuations. The secondary methane or air was separately injected into the outer recirculation zone to suppress the flame oscillations at a volume flow rate of 0.5% of the primary flow rates. For lower primary air flow rates ( Q air ≤ 60 L/min), both secondary methane and air injections were able to suppress the thermoacoustic instability and performed the sound pressure level reduction of 45 dB. Meanwhile, the flame transformed from an attached unstable M-shaped flame to a detached stable V-shaped flame. The secondary methane or air injection served to stabilize the flame and anchor its spatial heat release distribution by limiting the variation of flame shape in the outer recirculation zone, suppressing thermoacoustic oscillation. For higher primary air flow rates ( Q air = 80 L/min), the secondary methane injection could reduce sound pressure levels to noise levels, while secondary air injection could not. The velocity disturbances and heat release fluctuations introduced by secondary methane injection could lead to a transformation in flame shape and achieve the suppression of thermoacoustic oscillation. However, the velocity disturbances induced by secondary air injection were insufficient to stabilize the flame. [ABSTRACT FROM AUTHOR]

Difenoconazole-loaded (CS-DIF) microcapsules were synthesized by encapsulating difenoconazole into biocompatible chitosan. The physical and chemical properties indicated that the encapsulation and chemical loading rates were 85.58% and 61.98%, respectively. The microcapsules exhibited prominent controlled-release and surface stability performance. The cumulative release rate was only 33.6% in 168 h, and the contact angle decreased by 11.73° at 120 s compared with difenoconazole. The antifungal activity of the CS-DIF microcapsules against Curvularia lunata was confirmed through observations of colony growth, in vitro and in vivo inoculation, mycelium morphology, as well as DNA and protein leakage. The antioxidant enzyme activity of superoxide dismutase, peroxidase, and catalase decreased by 65.1%, 84.9%, and 69.7%, respectively, when Curvularia lunata was treated with 200 μg/mL microcapsules, compared with the control in 24 h. The enzymatic activity of polyphenol oxidase decreased by 323.8%. The reactive oxygen species contents of hydrogen peroxide and superoxide anions increased by 204.6% and 164%, respectively. Additionally, the soluble sugar and soluble protein contents decreased by 65.5% and 69.6%, respectively. These findings provided a novel approach to control the growth of C. lunata efficiently, laying a foundation for reducing the quantity and enhancing the efficiency of chemical pesticides. The CS-DIF microcapsules exhibited a strong inhibitory effect on fungus, effectively preventing and controlling leaf spot disease and showing potential for field applications. This study might be of great significance in ensuring plant protection strategies. [ABSTRACT FROM AUTHOR]

The accurate evaluation of green innovation efficiency is a critical prerequisite for enterprises to achieve sustainable development goals and improve environmental performance and economic efficiency. This paper evaluates the green innovation efficiency of 72 new-energy enterprises by using a hybrid method of Data Envelopment Analysis (DEA) and a random forest model. The non-parametric DEA model is combined with the parametric SFA model to analyze the real green innovation efficiency on the basis of removing environmental factors and random factors. Then, the random forest model based on a nonlinear relationship is used to evaluate factors impacting green innovation efficiency. This paper proposes a comprehensive evaluation method designed to assess the green innovation efficiency of new-energy enterprises. By applying this method, companies can gain a comprehensive understanding of the current performance in green innovation, facilitating informed decision-making and accelerating sustainable development. [ABSTRACT FROM AUTHOR]