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Street dusts from heavy density traffic area (HDTA), tourism area (TA), residential area (RA), and educational area (EA) in Beijing were collected to explore the distribution, health risk assessment, and source of lead (Pb). The average concentration of Pb in TA was the highest among the four areas. Compared with other cities, Pb concentrations in Beijing were generally at moderate or low levels. The average value (14.05) of ecological risk index (RI) indicated that Pb was at 'low pollution risk' status. According to the calculation on hazard index (HI), the ingestion of dust particles of children and adults was the major route of exposure to street dusts in four studied areas, followed by dermal contact. The lower values of HI than 1 further suggested that non-carcinogenic risks of Pb in the street dusts were in the low range. Comparing Pb/Pb and Pb/Pb ratios of street dusts with other environmental samples, it was found that atmospheric deposition of coal combustion dust might be the main pathway for anthropogenic Pb input to the street dusts in four functional areas. [ABSTRACT FROM AUTHOR]

The sorption of two phthalate esters (PAEs) and phenanthrene (PHE) by different natural organic matter fractions (NOMs) was examined. The surface area of the NOMs correlated positively with the starting decomposition temperature (SDT), implying increased number of micropores with the rise of condensation. Sorption of PHE on nonhydrolyzable carbons (NHCs) and other NOMs was respectively dependent on aromatic and aliphatic C contents. Likely physical blocking of the aliphatic moieties and input of black carbon materials led to elevated sorption capacity for PHE of aromatic domains in the NHCs. Sorption of PAEs by NOMs excluding NHCs was jointly regulated by hydrophobic partitioning and H-bonding interactions. The SDT of the NOMs correlated negatively with the K oc when SDT ≥304 °C, likely because the highly condensed domains may impair the availability of amorphous moieties for sorption. This study highlights the influence of domain accessibility of NOMs on sorption of hydrophobic organic contaminants. [ABSTRACT FROM AUTHOR]

The importance of the composition of soil organic matter (SOM) for carbon (C) cycling is still under debate. Here a single soil source was used to examine the specific influence of its composition on stability ( 14 C activity) of SOM fractions while constraining other influential C turnover factors such as mineral, climate and plant input. The following SOM fractions were isolated from two soil samples: four humic acids, two humins, non-hydrolyzable carbon, and the demineralized fraction. We examined the isotope ratios of SOM fractions in relation to composition (such as aliphatic and aromatic C content) using solid state 13 C nuclear magnetic resonance (NMR) and thermal analysis. The Δ 14 C values of the fractions isolated from both an albic soil (SOMs-A) and a black soil (SOMs-B) correlated negatively with their peak temperature of decomposition and the temperature where half of the total heat of reaction was evolved, implying a potential link between thermal and biogeochemical stability of SOM fractions. Aryl C contents of SOMs-A determined using 13 C NMR varied inversely with δ 15 N values and directly with δ 13 C values, suggesting that part of aryl C of SOMs-A might be fire-derived. The Δ 14 C values of SOMs-A correlated positively with aliphatic C content and negatively with aromatic C content. We therefore concluded that fire-derived aromatic C in SOMs-A appeared to be more stable than microbially-derived aliphatic C. The greater decomposition of SOMs-B fractions weakened the relationship of their Δ 14 C values with alkyl and aryl C contents. Hence, the role of the composition of SOM fractions in regulating stability might be dependent on the source of specific C forms and their stage of decomposition. [ABSTRACT FROM AUTHOR]

Understanding marine pollution in the South China Sea is crucial for preserving marine ecosystems and biodiversity. Despite extensive research on pollutants, there is a significant gap in knowledge about microplastics (MPs) in the archipelago region. This study focused on four typical islands, examining MPs in seawater and sediments, their distribution, and environmental risks. Most MPs (>90 %) were smaller than 2.5 mm, with black fiber-shaped polyethylene terephthalate MPs being predominant. MPs in seawater had lower abundance (5-12 items/L) compared to sediment (100-2600 items/kg) but showed richer polymer composition. Pollution load index (PLI) and risk index analysis indicated all regions were contaminated (PLI > 1), with the Zhongsha islands being the most polluted. Correlation analysis highlighted black, fibrous PET-like polymers with large particle sizes (>0.5 mm) as major contributors. This study could help to understand the MPs distribution and pollution in the archipelago region of the South China Sea., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Soil microbiomes drive many soil processes and maintain the ecological functions of terrestrial ecosystems. Microplastics (MPs, size < 5 mm) are pervasive emerging contaminants worldwide. However, how MPs affect soil microbial activity has not been well elucidated. This review article first highlights the effects of MPs on overall soil microbial activities represented by three soil enzymes, i.e., catalase, dehydrogenase, and fluorescein diacetate hydrolase (FDAse), and explores the underlying mechanisms and influencing factors. Abundant evidence confirms that MPs can change soil microbial activities. However, existing results vary greatly from inhibition to promotion and non-significance, depending on polymer type, degradability, dose, size, shape, additive, and aging degree of the target MPs, soil physicochemical and biological properties, and exposure conditions, such as exposure time, temperature, and agricultural practices (e.g., planting, fertilization, soil amendment, and pesticide application). MPs can directly affect microbial activities by acting as carbon sources, releasing additives and pollutants, and shaping microbial communities via plastisphere effects. Smaller MPs (e.g., nanoplastics, 1 to < 1000 nm) can also damage microbial cells through penetration. Indirectly, MPs can change soil attributes, fertility, the toxicity of co-existing pollutants, and the performance of soil fauna and plants, thus regulating soil microbiomes and their activities. In conclusion, MPs can regulate soil microbial activities and consequently pose cascading consequences for ecosystem functioning., Competing Interests: Declaration of Competing Interest ☒ The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. ☐ The authors declare the following financial interests/personal relationships which may be considered as potential competing interests:, (Copyright © 2024. Published by Elsevier Inc.)

Microplastics (MPs), including conventional hard-to-biodegrade petroleum-based and faster biodegradable plant-based ones, impact soil structure and microbiota in turn affecting the biodiversity and functions of terrestrial ecosystems. Herein, we investigated the effects of conventional and biodegradable MPs on aggregate distribution and microbial community composition in microhabitats at the aggregate scale. Two MP types (polyethylene (PE) and polylactic acid (PLA) with increasing size (50, 150, and 300 μm)) were mixed with a silty loam soil (0-20 cm) at a ratio of 0.5 % (w/w) in a rice-wheat rotation system in a greenhouse under 25 °C for one year. The effects on aggregation, bacterial communities and their co-occurrence networks were investigated as a function of MP aggregate size. Conventional and biodegradable MPs generally had similar effects on soil aggregation and bacterial communities. They increased the proportion of microaggregates from 17 % to 32 %, while reducing the macroaggregates from 84 % to 68 %. The aggregate stability decreased from 1.4 mm to 1.0-1.1 mm independently of MP size due to the decline in the binding agents gluing soil particles (e.g., microbial byproducts and proteinaceous substances). MP type and amount strongly affected the bacterial community structure, accounting for 54 % of the variance. Due to less bioavailable organics, bacterial community composition within microaggregates was more sensitive to MPs addition compared to macroaggregates. Co-occurrence network analysis revealed that MPs exacerbated competition among bacteria and increased the complexity of bacterial networks. Such effects were stronger for PE than PLA MPs due to the higher persistence of PE in soils. Proteobacteria, Bacteroidetes, Chloroflexi, Actinobacteria, and Gemmatimonadetes were the keystone taxa in macroaggregates, while Actinobacteria and Chloroflexi were the keystone taxa in microaggregates. Proteobacteria, Actinobacteria, and Chloroflexi were the most sensitive bacteria to MPs addition. Overall, both conventional and biodegradable MPs reduced the portion of large and stable aggregates, altering bacterial community structures and keystone taxa, and consequently, the functions., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier Ltd.)

To investigate the mechanisms by which g-C 3 N 4 alleviates metal(loid)-induced phytotoxicity, rice seedlings were exposed to 100 and 250 mg/kg graphitic carbon nitride (g-C 3 N 4 ) with or without coexposure to 10 mg/kg Cd and 50 mg/kg As for 30 days. Treatment with 250 mg/kg g-C 3 N 4 significantly increased shoot and root fresh weight by 22.4-29.9%, reduced Cd and As accumulations in rice tissues by 20.6-26.6%, and elevated the content of essential nutrients (e.g., K, S, Mg, Cu, and Zn) compared to untreated controls. High-throughput sequencing showed that g-C 3 N 4 treatment increased the proportion of plant-growth-promoting endophytic bacteria, including Streptomyces , Saccharimonadales , and Thermosporothrix , by 0.5-3.30-fold; these groups are known to be important to plant nutrient assimilation, as well as metal(loid) resistance and bioremediation. In addition, the population of Deinococcus was decreased by 72.3%; this genus is known to induce biotransformation As(V) to As(III). Metabolomics analyses highlighted differentially expressed metabolites (DEMs) involved in the metabolism of tyrosine metabolism, pyrimidines, and purines, as well as phenylpropanoid biosynthesis related to Cd/As-induced phytotoxicity. In the phenylpropanoid biosynthesis pathway, the increased expression of 4-coumarate (1.13-fold) and sinapyl alcohol (1.26-fold) triggered by g-C 3 N 4 coexposure with Cd or As played a critical role in promoting plant growth and enhancing rice resistance against metal(loid) stresses. Our findings demonstrate the potential of g-C 3 N 4 to enhance plant growth and minimize the Cd/As-induced toxicity in rice and provide a promising nanoenabled strategy for remediating heavy metal(loid)-contaminated soil.

Due to the high biological toxicity, the concurrent elimination of lead (Pb (II)) and methylene blue (MB) has become a challenging problem. Therefore, a newly β-cyclodextrin (β-CD) modified magnetic alginate/biochar (β-CD@MBC P ) material was developed. Comprehensive characterizations proved the successful coating of β-CD onto MBC P surface by microwave-aided fabrication. The β-CD@MBC P achieved high-efficiency uptake for contaminants under a wide pH scope. In the dual system, Pb (II) elimination was facilitated with the presence of MB, due to the active sites provided by MB. In the presence of Pb (II), MB uptake was inhibited due to the electrostatic repulsion between positively charged MB and Pb (II). Electrostatic attraction and complexation contributed to capturing Pb (II), while π-π interactions, host-guest effect, and H-bonding were important in MB elimination. After four cycles, β-CD@MBC P maintained comparatively good renewability. Findings demonstrated that β-CD@MBC P could be an effective remediation material for Pb (II)/MB adsorption from aqueous environments., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier Ltd. All rights reserved.)

This present study investigated pork bone-derived biochar as a promising amendment to reduce Cd accumulation and alleviate Cd-induced oxidative stress in rice. Micro/nanoscale bone char (MNBC) pyrolyzed at 400 °C and 600 °C was synthesized and characterized before use. The application rates for MNBCs were set at 5 and 25 g·kg -1 and the Cd exposure concentration was 15 mg·kg -1 . MNBCs increased rice biomass by 15.3-26.0% as compared to the Cd-alone treatment. Both types of MNBCs decreased the bioavailable Cd content by 27.4-54.8%; additionally, the acid-soluble Cd fraction decreased by 10.0-12.3% relative to the Cd alone treatment. MNBC significantly reduced the cell wall Cd content by 50.4-80.2% relative to the Cd-alone treatment. TEM images confirm the toxicity of Cd to rice cells and that MNBCs alleviated Cd-induced damage to the chloroplast ultrastructure. Importantly, the addition of MNBCs decreased the abundance of heavy metal tolerant bacteria, Acidobacteria and Chloroflexi, by 29.6-41.1% in the rhizosphere but had less impact on the endophytic microbial community. Overall, our findings demonstrate the significant potential of MNBC as both a soil amendment for heavy metal-contaminated soil remediation and for crop nutrition in sustainable agriculture., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

Photocatalytic microplastics (MPs) conversion into valuable products is a promising approach to alleviate MPs pollution in aquatic environments. Herein, we developed an amorphous alloy/photocatalyst composite (FeB/TiO 2 ) that can successfully convert polystyrene (PS) MPs to clean H 2 fuel and valuable organic compounds (92.3% particle size reduction of PS-MPs and 103.5 μmol H 2 production in 12 h). FeB effectively enhanced the light-absorption and carrier separation of TiO 2 , thereby promoting more reactive oxygen species generation (especially ‧OH) and combination of photoelectrons with protons. The main products (e.g., benzaldehyde, benzoic acid, etc.) were identified. Additionally, the dominant PS-MPs photoconversion pathway was elucidated based on density functional theory calculations, by which the significant role of ‧OH was demonstrated in combination with radical quenching data. This study provides a prospective approach to mitigate MPs pollution in aquatic environments and reveals the synergistic mechanism governing the photocatalytic conversion of MPs and generation of H 2 fuel., Competing Interests: The authors declare no competing interests., (© 2023 The Author(s).)

The function of biochar (BC) as an eco-friendly adsorbent for environmental remediation is gaining much attention. However, the pristine BC had limited abilities for the removal of As (III, V). Towards this issue, this study synthesized biochar/micro-nanosized α-MnO 2 (BM) composites with different mass ratios of biochar to MnO 2 . Comprehensive characterizations confirmed the successful loading of micro-nanosized α-MnO 2 onto the BC surface and the obvious specific surface area enhancement (7.5-13.5 times) of BM relative to BC. BM composites exhibited 5.0-13.0 folds higher removal capacity for As (III, V) than pristine BC since the composites gave full play to the oxidation contributed by micro-nanosized α-MnO 2 substrate and adsorption functions provided by the Mn-OH, BC-COOH, and BC-OH functional groups. Moreover, BM was well reused maintaining a relatively high removal efficiency for As (III, V). Regardless of reaction time and initial As (III) concentration (C 0 ), the removal of As (III) by pristine BC was negligibly contributed by the oxidized As (V) remaining in solutions, with the relative contribution <15.0%. For the BM composites, relative contribution of adsorbed As (III, V) dominated over that of oxidation to mobile As (V) remaining in solution, and exhibited the decreasing trend with increasing C 0 . These findings demonstrated BM as a promising candidate in remediating As (III, V)-polluted water, and provide mechanistic insights into the role of oxidation and adsorption in As (III, V) removal., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier B.V. All rights reserved.)