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Contourites are deposits formed by along-slope bottom currents and are therefore sensitive to changes in current velocity, sediments supply and paleoceanographic conditions. They are typically associated with high accumulation rates making these archives ideal for paleoenviromental reconstructions. Nevertheless, they are also occasionally affected by winnowing of fine particles and erosion/deposition of allochthonous material, which alters the grain-size and mineralogy. These processes can, as such, promote significant bias in proxy interpretation compared with other pelagic deposits. X-ray fluorescence (XRF) core-scanning is ideal to assess elemental variations in these high accumulation rate sequences. The comparison between lithological changes, Natural Gamma Ray and other parameters with XRF scanning data, along with statistical analysis can provide very useful information to support improved proxy interpretation. Using this approach at Site U1387, (detrital contourite system at Gulf of Cadiz), results indicate that the Zr/Al ratio represents a promising proxy for bottom current speed and show the transition from a hemipelagic to a contouritic system during the Miocene/Pliocene transition. Carbonate content and Ba/Al ratio appear to represent paleo-productivity variations and later to be completely overprinted by current activit y. At Site U1475 (carbonate contourite system at Agulhas Plateau) Zr content is just one artifact associated with high Sr content and the Ca/Sr ratio appears to be a more promising proxy for contourite reconstruction that is influenced by carbonate dissolution by deep corrosive waters. Comparing both locations we can conclude that proxies associated with the continuous background sediment settling over the seafloor (e.g. planktonic foraminifera) do not appear to be severely biased in countourite systems.

Previous work showed that South Atlantic sediments have lower glacial than Holocene 231Pa/230Th, which was attributed to a switch in the flow direction of Atlantic deep-water. Debate exists, however as to the degree to which two processes – circulation and scavenging – determine sedimentary 231Pa/230Th, making this interpretation contentious. Here we address this issue using 145-kyr records of paleocirculation proxies. Benthic foraminiferal δC13, neodymium isotopes (εNd) and sedimentary 231Pa/230Th were all measured in a single sediment core from the South Atlantic subtropical gyre. This site largely excludes the influence of local productivity changes on 231Pa/230Th records. Measured 231Pa/230Th ranges between ∼0.041 during glacials and ∼0.055 during interglacial periods and is consistently lower than the production ratio, indicating export of 231Pa from the central South Atlantic for the entire duration of the record. The lower glacial 231Pa/230Th is regionally consistent, suggesting that basin-scale oceanographic processes cause the decrease. In turn, less radiogenic εNd and lower benthic δC13 confirm the classical picture of an increase in Southern Component Water (SCW) influence in the Atlantic during glacial periods and point to a circulation control on the observed 231Pa/230Th decrease rather than a local productivity change. We suggest that associated with this change in water mass distribution the dominant sink for 231Pa shifted from the margins of the South Atlantic and/or the Southern Ocean during interglacials, to the North Atlantic during glacial periods. Indeed, elevated 231Pa/230Th in the deep North Atlantic during glacials supports this mechanism of northward transport of 231Pa by SCW.

Despite the relative climate stability of the present interglacial, it has been punctuated by several centennial-scale climatic oscillations; the latest of which are often colloquially referred to as the Medieval Climatic Anomaly (MCA) and the Little Ice Age (LIA). The most favored explanation for the cause of these anomalies is that they were triggered by variability in solar irradiance and/or volcanic activity and amplified by ocean-atmosphere-sea ice feedbacks. As such, changes in the strength of the Atlantic Meridional Overturning Circulation (AMOC) are widely believed to have been involved in the amplification of such climatic oscillations. The Labrador Sea is a key area of deep water formation. The waters produced here contribute approximately one third of the volume transport of the deep limb of the AMOC and drive changes in the North Atlantic surface hydrography and subpolar gyre circulation. In this study, we present multiproxy reconstructions from a high-resolution marine sediment core located south of Greenland that suggest an increase in the influence of polar waters reaching the Labrador Sea close to MCA-LIA transition. Changes in freshwater forcing may have reduced the formation of Labrador Sea Water and contributed toward the onset of the LIA cooling.

New high-resolution sea surface temperature (SST) and sea surface salinity (SSS) estimates are presented from the Agulhas Bank slope in the Atlantic sector of the Agulhas Corridor using planktic foraminiferal (Globigerinoides ruber) O-18 and Mg/Ca-derived SST. By focusing on the last 80,000years, this is the first fine-scale Agulhas leakage record that overlaps in time with much of the Greenland ice core record of abrupt climate changes in the North Atlantic region. The multicentennial profiles indicate instances of warm SST and/or increased SSS coincident with Northern Hemisphere cool periods, followed by Northern Hemisphere warming. These periods of enhanced SST and SSS in the Agulhas Corridor occur at the last glacial termination (T1) and during North Atlantic cold episodes associated with Heinrich (H) meltwater events. To a first-order approximation, the timing of maximal salinity events in relation to periods of North Atlantic freshwater perturbation is consistent with the concept suggested by climate models that enhanced Agulhas leakage provides for buoyancy compensation and can potentially trigger increased convective activity in the North Atlantic, thereby restoring Atlantic overturning circulation after relatively weak states.

An ensemble of new, high-resolution records of surface ocean hydrography from the Indian-Atlantic oceanic gateway, south of Africa, demonstrates recurrent and high-amplitude salinity oscillations in the Agulhas Leakage area during the penultimate glacial-interglacial cycle. A series of millennial-scale salinification events, indicating strengthened salt leakage into the South Atlantic, appear to correlate with abrupt changes in the North Atlantic climate and Atlantic Meridional Overturning Circulation (AMOC). This interhemispheric coupling, which plausibly involved changes in the Hadley Cell and midlatitude westerlies that impacted the interocean transport at the tip of Africa, suggests that the Agulhas Leakage acted as a source of negative buoyancy for the perturbed AMOC, possibly aiding its return to full strength. Our finding points to the Indian-to-Atlantic salt transport as a potentially important modulator of the AMOC during the abrupt climate changes of the Late Pleistocene.

© The Author(s), 2013. This article is distributed under the terms of the Creative Commons Attribution License. The definitive version was published in Climate of the Past 9 (2013): 2073-2084, doi:10.5194/cp-9-2073-2013., The overflow of deep water from the Nordic seas into the North Atlantic plays a critical role in global ocean circulation and climate. Approximately half of this overflow occurs via the Iceland–Scotland (I–S) overflow, yet the history of its strength throughout the Holocene (~ 0–11 700 yr ago, ka) is poorly constrained, with previous studies presenting apparently contradictory evidence regarding its long-term variability. Here, we provide a comprehensive reconstruction of I–S overflow strength throughout the Holocene using sediment grain size data from a depth transect of 13 cores from the Iceland Basin. Our data are consistent with the hypothesis that the main axis of the I–S overflow on the Iceland slope was shallower during the early Holocene, deepening to its present depth by ~ 7 ka. Our results also reveal weaker I–S overflow during the early and late Holocene, with maximum overflow strength occurring at ~ 7 ka, the time of a regional climate thermal maximum. Climate model simulations suggest a shoaling of deep convection in the Nordic seas during the early and late Holocene, consistent with our evidence for weaker I–S overflow during these intervals. Whereas the reduction in I–S overflow strength during the early Holocene likely resulted from melting remnant glacial ice sheets, the decline throughout the last 7000 yr was caused by an orbitally induced increase in the amount of Arctic sea ice entering the Nordic seas. Although the flux of Arctic sea ice to the Nordic seas is expected to decrease throughout the next century, model simulations predict that under high emissions scenarios, competing effects, such as warmer sea surface temperatures in the Nordic seas, will result in reduced deep convection, likely driving a weaker I–S overflow., Funding was provided by NERC RAPID grant NER/T/S/2002/00436 to I. N. McCave, and a WHOI OCCI post-doctoral scholarship to D. J. R. Thornalley. Work on EW9302 cores was supported by NSF grant OCE01- 18001 to D. W. Oppo and J. F. McManus. The contributions of J. F. McManus and S. Praetorius were also supported in part by the Comer Research and Education Foundation. M. Blaschek,F. J. Davies and H. Renssen are supported by the European Community’s 7th Framework Programme FP7 2007/2013, Marie-Curie Actions, under Grant Agreement No. 10 238111 CASE ITN.

Author Posting. © American Geophysical Union, 2013. This article is posted here by permission of American Geophysical Union for personal use, not for redistribution. The definitive version was published in Paleoceanography 28 (2013): 253–262, doi:10.1002/palo.20025., Six Ocean Drilling Program (ODP) sites, in the Northwest Atlantic have been used to investigate kinematic and chemical changes in the “Western Boundary Undercurrent” (WBUC) during the development of full glacial conditions across the Marine Isotope Stage 5a/4 boundary (~70,000 years ago). Sortable silt mean grain size inline image measurements are employed to examine changes in near bottom flow speeds, together with carbon isotopes measured in benthic foraminifera and % planktic foraminiferal fragmentation as proxies for changes in water-mass chemistry. A depth transect of cores, spanning 1.8–4.6 km depth, allows changes in both the strength and depth of the WBUC to be constrained across millennial scale events. inline image measurements reveal that the flow speed structure of the WBUC during warm intervals (“interstadials”) was comparable to modern (Holocene) conditions. However, significant differences are observed during cold intervals, with higher relative flow speeds inferred for the shallow component of the WBUC (~2 km depth) during all cold “stadial” intervals (including Heinrich Stadial 6), and a substantial weakening of the deep component (~3–4 km) during full glacial conditions. Our results therefore reveal that the onset of full glacial conditions was associated with a regime shift to a shallower mode of circulation (involving Glacial North Atlantic Intermediate Water) that was quantitatively distinct from preceding cold stadial events. Furthermore, our chemical proxy data show that the physical response of the WBUC during the last glacial inception was probably coupled to basin-wide changes in the water-mass composition of the deep Northwest Atlantic., This work was supported by the Natural Environment Research Council (NERC, UK) grants NE/F002734/1, NE/I006370/1 and NE/G004021/1. We also thank the Comer Science and Education Foundation and the Leverhulme Trust for financial support., 2013-11-30

High resolution flow speed reconstructions of two core sites located on Gardar Drift in the northeast Atlantic Basin and Orphan Knoll in the northwest Atlantic Basin reveal a long-term decrease in flow speed of Northeast Atlantic Deep Water (NEADW) after 6,500 years. Benthic foraminiferal oxygen isotopes of sites currently bathed in NEADW show a 0.2 parts per thousand depletion after 6,500 years, shortly after the start of the development of a carbon isotope gradient between NEADW and Norwegian Sea Deep Water. We consider these changes in near-bottom flow vigor and benthic foraminiferal isotope records to mark a significant reorganization of the Holocene deep ocean circulation, and attribute the changes to a weakening of NEADW flow during the mid to late Holocene that allowed the shoaling of Lower Deep Water and deeper eastward advection of Labrador Sea Water into the northeast Atlantic Basin.

Planktonic delta(18)O and Mg/Ca-derived sea surface temperature (SST) records from the Agulhas Corridor off South Africa display a progressive increase of SST during glacial periods of the last three climatic cycles. The SST increases of up to 4 degrees C coincide with increased abundance of subtropical planktonic foraminiferal marker species which indicates a progressive warming due to an increased influence of subtropical waters at the core sites. Mg/Ca-derived SST maximizes during glacial maxima and glacial Terminations to values about 2.5 degrees C above full-interglacial SST. The paired planktonic delta(18)O and Mg/Ca-derived SST records yield glacial seawater delta(18)O anomalies of up to 0.8%, indicating measurably higher surface salinities during these periods. The SST pattern along our record is markedly different from a U(37)(K')-derived SST record at a nearby core location in the Agulhas Corridor that displays SST maxima only during glacial Terminations. Possible explanations are lateral alkenone advection by the vigorous regional ocean currents or the development of SST contrasts during glacials in association with seasonal changes of Agulhas water transports and lateral shifts of the Agulhas retroflection. The different SST reconstructions derived from U(37)(K') and Mg/Ca pose a significant challenge to the interpretation of the proxy records and demonstrate that the reconstruction of the Agulhas Current and interocean salt leakage is not as straightforward as previously suggested.

Increased fluxes of ice-rafted detritus (IRD) from European ice sheets have been documented some 1000-1500 years before the arrival of Laurentide Ice Sheet (LIS)-sourced IRD during Heinrich (H) events. These early fluxes have become known as 'precursor events', and it has been suggested that they have mechanistic significance in the propagation of H events. Here we present a re-analysis of one of the main cores used to generate the precursor concept, OMEX-2K from the Goban Spur covering the last 30 ka, in order to identify whether the British-Irish Ice Sheet (BIIS) IRD fluxes occur only as precursors before H layers. IRD characterization and planktonic foraminiferal delta 18O measurements constrained by a new age model have enabled the generation of a continuous record of IRD sources, timing, frequency and flux, and of local contemporary hydrographic conditions. The evidence indicates that BIIS IRD precursors are not uniquely, or mechanistically, linked to H events, but are part of the pervasive millennial-scale cyclicity. Our results support an LIS source for the IRD comprising H layers, but the ambient glacial sections are dominated by assemblages typical of the Irish Sea Ice Stream. Light isotope excursions associated with H events are interpreted as resulting from the melting of the BIIS, with ice-sheet destabilization attributed to eustatic jumps generated by LIS discharge during H events. This positive-feedback mechanism probably caused similar responses in all circum-Atlantic ice-sheet margins, and the resulting gross freshwater flux contributed to the perturbation of the Atlantic Meridional Overturning Circulation during H events.

The meridional overturning circulation (MOC) of the Atlantic Ocean is considered to be one of the most important components of the climate system. This is because its warm surface currents, such as the Gulf Stream, redistribute huge amounts of energy from tropical to high latitudes and influence regional weather and climate patterns, whereas its lower limb ventilates the deep ocean and affects the storage of carbon in the abyss, away from the atmosphere. Despite its significance for future climate, the operation of the MOC under contrasting climates of the past remains controversial. Nutrient-based proxies and recent model simulations indicate that during the Last Glacial Maximum the convective activity in the North Atlantic Ocean was much weaker than at present. In contrast, rate-sensitive radiogenic 231 Pa/230 Th isotope ratios from the North Atlantic have been interpreted to indicate only minor changes in MOC strength. Here we show that the basin-scale abyssal circulation of the Atlantic Ocean was probably reversed during the Last Glacial Maximum and was dominated by northward water flow from the Southern Ocean. These conclusions are based on new high-resolution data from the South Atlantic Ocean that establish the basin-scale north to south gradient in 231 Pa/ 230 Th, and thus the direction of the deep ocean circulation. Our findings are consistent with nutrient-based proxies and argue that further analysis of 231 Pa/ 230 Th outside the North Atlantic basin will enhance our understanding of past ocean circulation, provided that spatial gradients are carefully considered. This broader perspective suggests that the modern pattern of the Atlantic MOCg-with a prominent southerly flow of deep waters originating in the North Atlanticg-arose only during the Holocene epoch.

1] There is much uncertainty surrounding the mechanisms that forced the abrupt climate fluctuations found in many palaeoclimate records during Marine Isotope Stage (MIS)-3. One of the processes thought to be involved in these events is the Atlantic Meridional Overturning Circulation ( MOC), which exhibited large changes in its dominant mode throughout the last glacial period. Giant piston core MD95- 2006 from the northeast Atlantic Ocean records a suite of palaeoceanographic proxies related to the activity of both surface and deep water masses through a period of MIS- 3 when abrupt climate fluctuations were extremely pronounced. A two- stage progression of surface water warming during interstadial warm events is proposed, with initial warming related to the northward advection of a thin warm surface layer within the North Atlantic Current, which only extended into deeper surface layers as the interstadial progressed. Benthic foraminifera isotope data also show millennialscale oscillations but of a different structure to the abrupt surface water changes. These changes are argued to partly be related to the influence of low- salinity deepwater brines. The influence of deepwater brines over the site of MD95- 2006 reached a maximum at times of rapid warming of surface waters. This observation supports the suggestion that brine formation may have helped to destabilize the accumulation of warm, saline surface waters at low latitudes, helping to force the MOC into a warm mode of operation. The contribution of deepwater brines relative to other mechanisms proposed to alter the state of the MOC needs to be examined further in future studies.

Benthic foraminiferal assemblages and the carbon isotope composition of the epifaunal benthic foraminifera Epistominella exigua and Fontbotia wuellerstorfi have been investigated along core MD02-2589 located at the southern Agulhas Plateau ( 41 degrees 26.03'S, 25 degrees 15.30'E, 2660 m water depth). This study aims to evaluate changes in the benthic paleoenvironment and its influence on benthic delta(13)C with a notable focus on E. exigua, a species associated with phytodetritus deposits and poorly studied in isotope paleoceanographic reconstructions. The benthic foraminiferal assemblages (> 63 mu m) show large fluctuations in species composition suggesting significant changes in the pattern of ocean surface productivity conceivably related to migrations of the Subtropical Convergence ( STC) and Subantarctic Front ( SAF). Low to moderate seasonality and relatively higher food supply to the seafloor are indicated during glacial marine isotope stages ( MIS) 6, 4, and 2 and during MIS 3, probably associated with the northward migration of the SAF and confluence with the more stationary STC above the southern flank of the Agulhas Plateau. The lowest organic carbon supply to the seafloor is indicated from late MIS 5b to MIS 4 as a consequence of increased influence of the Agulhas Front ( AF) and/ or weakening of the influence of the STC over the region. Episodic delivery of fresh organic matter, similar to modern conditions at the core location, is indicated during MIS 5c-MIS 5e and at Termination I. Comparison of this paleoenvironmental information with the paired delta(13)C records of E. exigua and F. wuellerstorfi suggests that organic carbon offsets delta(13)C of E. exigua from ambient bottom water delta(13)C(DIC), while its delta(13)C amplitude, on glacial-interglacial timescales, does not seem affected by changes of organic carbon supply to the seafloor. This suggests that this species calcifies preferentially during the short time span of the year when productiv

Sortable silt mean grain sizes together with oxygen and carbon isotopic data produced on the benthic foraminiferal species Fontbotia wuellerstorfi are used to construct high-resolution records of near-bottom flow vigour and deep water ventilation at a core site MD02-2589 located at 2660 m water depth on the southern Agulhas Plateau. The results suggest that during glacial periods ( marine oxygen isotope stages 2 and 6, MIS 2 and MIS 6, respectively), there was a persistent contribution of a well-ventilated water mass within the Atlantic to Indian oceanic gateway with a delta(13)C signature similar to present-day Northern Component Water (NCW), e. g., North Atlantic Deep Water (NADW). The records of chemical ventilation and near-bottom flow vigor reflect changes in the advection of northern source waters and meridional variability in the location of the Antarctic Circumpolar Current and its associated fronts. We suggest that during Termination II (TII), changes in chemical ventilation are largely decoupled from near-bottom physical flow speeds. A mid-TII climate optimum is associated with a low-flow speed plateau concurrent with a period of increased ventilation shown in the benthic delta(13)C of other Southern Ocean records but not in our benthic delta(13)C of MD02-2589. The climate optimum is followed by a period of southern cooling around 128 ka coincident with a stronger influence of NCW to interglacial levels at around 124 ka. All proxy records show a near synchronous and rapid shift during the transition from MIS 5a-4 (73 ka). This large event is attributed to a rapid decrease in NADW influence and replacement over the Agulhas Plateau by southern source waters.