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An Erratum to this paper has been published: https://doi.org/10.1134/S1028334X23070152 [ABSTRACT FROM AUTHOR]

• The study proposes tools to improve environmental assessment of a mineral deposit. • XRF, mineral spectrometer, carbonate staining compose the preliminary protocol. • Application on two mining projects: a developed mine and an exploration project. • Protocol compared with traditional environmental assessment. Environmental assessment is generally performed when a mining project is at an advanced development stage, such as the prefeasibility study. It involves several laboratory tests such as detailed characterisation and geochemical mobility prediction tests, which require many samples considered representative of the deposit. Having early characterisation information could be useful to select the most relevant samples for the overall environmental assessment. The present study proposes a selection of non destructive and portable tools for improving the early environmental assessment of a mineral deposit. Three tools (x-ray fluorescence (XRF), mineral spectrometer, carbonate staining) were identified to form a preliminary environmental assessment methodology that can be performed directly on the exploration site. This methodology was applied to two different mining projects: i) a well developed mine, LaRonde zone 5, with available geochemical data in a volcanic-associated massive sulfide (VMS) context, and ii) an exploration project, O'Brien, with ongoing geochemical acquisition in an Au-quartz vein context. Both mine sites are in the south of the Blake River Group within the Abitibi greenstone belt, Quebec, Canada. The first site was used to validate the developed methodology, whereas the second acted as a test site to apply the methodology as a preliminary environmental assessment. The results on the first site confirmed that the selected tools provide geochemical and mineralogical data sets comparable to those of traditional testing methods. The developed methodology then enabled the classification of preliminary geo-environmental domains for the second site. Standard static and kinetic tests were performed on the second site samples to confront the preliminary assessment protocol. The proposed preliminary protocol made it possible to discriminate low-risk samples versus those with a potentially higher risk for the selection of subsequent environmental assessments. [ABSTRACT FROM AUTHOR]

This study presents a comprehensive account of the petrogenetic and geodynamic evolution of the Bellara Trap volcanic rocks from the Ingaldhal Formation, Chitradurga Group, western Dharwar Craton (WDC). Geochemical attributes of these rocks are consistent with two groups with distinct evolutionary trends: one comprising tholeiitic, MORB (mid-ocean ridge basalt) type basalts (BTB) and the other corresponding to calc-alkaline andesites (BTA). Basalts are essentially composed of clinopyroxene and plagioclase whereas the andesites are porphyritic with phenocrysts of plagioclase, clinopyroxene and polycrystalline quartz embedded in a groundmass of K-feldspar, quartz and opaques. Primary igneous mineralogy is overprinted by greenschist facies metamorphism resulting in chlorite-actinolite-plagioclase assemblage. The BTB samples reflect nearly flat REE patterns with weak LREE enrichment in contrast to pronounced LREE enhancement over HREE discernible for BTA. Tectonically, the BTB samples correspond to an active mid-oceanic ridge-rift setting with a MORB composition, whereas a back-arc basin (BAB) regime is corroborated for the BTA samples fractionating from back-arc basin basalts. Geochemical imprints of subduction input are more pronounced in BTA compared to BTB as mirrored by their elevated abundances of incompatible fluid mobile elements like Ba, Th, U and LREE. The BTB is endowed with an N- to E-MORB signature attributable to minor contributions from subduction-related components at the inception of a back-arc basin in the vicinity of an active subduction system. The BTA derived through differentiation of a basaltic magma with BABB (back-arc basin basalt) affinity compositionally akin to a heterogeneous source mantle carrying depleted MORB-type and enriched arc-type components inducted with progressive subduction. The BABB-type andesites and MORB-type basalts from Bellara Traps record a compositional heterogeneity of mantle in an intraoceanic arc-back arc system. Mantle processes invoke a BABB-MORB spectrum with a MORB-like endmember and an arc-like endmember associated with a juvenile back-arc basin. This study infers a Neoarchean analogue of Mariana-type back-arc rift setting proximal to the arc with a gradual transition from anhydrous to hydrous melting processes synchronized with MORB-mantle and arc-mantle interaction during initiation of a nascent back arc adjacent to the arc. The MORB-BABB compositional spectrum for the Bellara Traps conforms to a Neoarchean back-arc basin that evolved under an extensional tectonic regime associated with incipient stages of back-arc rifting and incorporation of subduction-derived components in the mantle output. This study complies with Neoarchean intraoceanic accretionary cycle plate tectonics in WDC. [ABSTRACT FROM AUTHOR]

An occurrence of Palaeoarchaean ferropicrite cumulates and ferrobasalts is being reported from the Jojohatu area of the Iron Ore Group (IOG) greenstone belt, which is situated in the northern part of the Singhbhum Craton (eastern India). The ferropicrite cumulates contain serpentine and clinopyroxene as major constituents and spinel, magnetite, and ilmenite as accessories. Their bulk rock chemistry exhibits an extremely high amount of FeOT (19.0–20.8 wt%) and MgO (22.0–23.9 wt%) and quite low Al2O3 (4.5–5.2 wt%) and Na2O + K2O (<1.0 wt%), thus making them as one of the most Fe‐rich ferropicrite cumulates in the world. They are also characterized by high contents of compatible trace elements (Ni: 986–1,470 ppm; Cr: 990–1,256 ppm) and moderate TiO2 (1.5–1.7 wt%), Nb (15–18 ppm), and Zr (82–90 ppm). These cumulates are possibly formed due to accumulation of olivine from the ferrobasaltic melts. In comparison, ferrobasalts consisting of plagioclase, pyroxene, and opaques are alkaline in nature. Some of the plagioclase and pyroxene grains have shown a signature of metasomatic alteration, which resulted into formation of secondary minerals such as epidote, chlorite, and hornblende. They exhibit relatively low contents of FeOT (14.6–18.4 wt%), MgO (8.4–10.8 wt%), Ni (32–122 ppm), and Cr (41–131 ppm) than the ferropicrite cumulates, while TiO2 (2.9–4.1 wt%), Nb (42–61 ppm), and Zr (216–318 ppm) contents are higher. Incompatible elemental patterns and their ratios, as well as Zr/Y versus Nb/Y plot, indicate their ocean island basalts (OIB) affinity and genesis from a hot mantle plume, having mantle potential temperature of about 1,600°C and pressure of 3.5–5 GPa. Considerably low CaO (3.00–7.16 wt%) and FeO/MgO and CaO/MgO systematics indicate that the primary source of the basaltic melt could be pyroxenite. These volcanic occurrences possibly represent remnants of the OIB formed during the Palaeoarchean in the eastern part of the Indian shield. [ABSTRACT FROM AUTHOR]

The Sonakhan greenstone belt (SGB), located in the north‐eastern Bastar craton of the Indian shield, comprises mafic‐ultramafic and volcanic‐intrusive sequences in the lower stratigraphic units. We investigate the Platinum‐group element (PGE) relations of Boradih intrusion of the SGB to evaluate its tectono‐magmatic evolution. The chondrite‐normalized PGE patterns of boninitic cumulate rocks exhibit higher abundance of Palladium group PGEs (∑PPGE = 292–496 ppb) relative to the Iridium group PGEs (∑IPGE = 32–52 ppb) along with variable Au concentrations (51.34–718.05 ppb). The PGE concentrations are attributed to a boninitic parental melt, where the IPGEs in the source possibly partitioned into a monosulphide solid solution. The Cu (22–80 ppm), elevated Pt (22–238 ppb), and Pd (31–377 ppb) concentrations indicate Pt and Pd have partitioned into a semi‐metal rich melt during the later stages of crystallization. The geochemical characteristics of the basalts and ultramafic cumulates of the SGB indicate a supra‐subduction zone tectonic setting for its formation. Similar geochemical and litho‐tectonic correlations are also noticed between the SGB of Bastar craton and greenstone belts of the Eastern Dharwar craton of south India. The SGB (V/Yb =146 ± 25) and greenstone belts of Eastern Dharwar craton (V/Yb = 134 ± 52) record similar oxidation conditions of Phanerozoic subduction zones. Accordingly, we propose magmatic as well as tectonic correlations are possible for the Archean‐Palaeoproterozoic Bastar and Eastern Dharwar cratons. [ABSTRACT FROM AUTHOR]

A huge amount of legacy drilling data is available in geological survey but cannot be used directly as they are compiled and recorded in an unstructured textual form and using different formats depending on the database structure, company, logging geologist, investigation method, investigated materials and/or drilling campaign. They are subjective and plagued by uncertainty as they are likely to have been conducted by tens to hundreds of geologists, all of whom would have their own personal biases. dh2loop (https://github.com/Loop3D/dh2loop , last access: 30 September 2021​​​​​​​) is an open-source Python library for extracting and standardizing geologic drill hole data and exporting them into readily importable interval tables (collar, survey, lithology). In this contribution, we extract, process and classify lithological logs from the Geological Survey of Western Australia (GSWA) Mineral Exploration Reports (WAMEX) database in the Yalgoo–Singleton greenstone belt (YSGB) region. The contribution also addresses the subjective nature and variability of the nomenclature of lithological descriptions within and across different drilling campaigns by using thesauri and fuzzy string matching. For this study case, 86 % of the extracted lithology data is successfully matched to lithologies in the thesauri. Since this process can be tedious, we attempted to test the string matching with the comments, which resulted in a matching rate of 16 % (7870 successfully matched records out of 47 823 records). The standardized lithological data are then classified into multi-level groupings that can be used to systematically upscale and downscale drill hole data inputs for multiscale 3D geological modelling. dh2loop formats legacy data bridging the gap between utilization and maximization of legacy drill hole data and drill hole analysis functionalities available in existing Python libraries (lasio , welly , striplog). [ABSTRACT FROM AUTHOR]

Data-driven methods have increasingly been applied to solve geoscientific problems. Incorporation of data-driven methods with hypothesis testing can be effective to address some long-standing debates and reduce interpretation uncertainty by leveraging larger volumes of data and more objective data analytics, which leads to increased reproducibility. In this study, lithogeochemical data from regionally persistent Archean shale units were aggregated from literature, with special reference to the Kaapvaal Craton of South Africa—namely, shales from the Barberton, Witwatersrand, Pongola, and Transvaal Supergroups—and the Belingwe and Buhwa Greenstone Belts of the Zimbabwe Craton. We examine the feasibility of using machine-learning algorithms to produce a geochemical classification and demonstrate that machine learning is capable of accurately correlating stratigraphy at the formation, group, and supergroup levels. We demonstrate the ability to extract highly useful scientific findings through a data-driven approach, such as geological implications for the uniqueness of the sediment compositions of the Central Rand and West Rand Groups. We further demonstrate that when lithogeochemistry and machine-learning algorithms are used, only about 50 samples per geological unit are necessary to reach accuracy levels of around 80%–90% for our shale samples. Consequently, for many traditional tasks, such as rock identification and mapping, some expensive analyses and manual labor can be replaced by an abundance of cheaper data and machine learning. This approach could transform large-scale geological surveys by enabling more detailed mapping than currently possible, by vastly increasing the coverage rate and total coverage. In addition, the aggregation of historical data facilitates data reuse and open science. These results justify the need to bridge data- and hypothesis-driven techniques for the stratigraphic correlation and prediction of rock units, which can improve the accuracy of the inferred stratigraphic correlation and basin setting. [ABSTRACT FROM AUTHOR]

The Kelle Bidjoka Iron Formations (IFs) occur at the northmost margin of the Neoarchean to Paleoproterozoic Nyong group greenstone belts in SW Cameroon. This contribution presents for the first time the petrographical, geochemical, and geochronological data of the Kelle Bidjoka IFs and associated metaigneous (metatonalite) and metasedimentary (pyroxene gneiss) rocks. The studied IFs form a thin unit of 3.21 m thick and comprise magnetite pyroxene gneiss, garnet-bearing magnetite pyroxene gneiss, pyroxene BIFs, and grunerite BIFs. Petrographic studies have revealed mineral assemblages indicating retrograde amphibolite facies metamorphism. Magnetite pyroxene gneiss and pyroxene BIFs show signatures of both seawater and hydrothermal fluids, with magnetite pyroxene gneiss deposited closer to the vent source. In contrast, garnet-bearing magnetite pyroxene gneiss and grunerite BIFs are devoid of hydrothermal characteristics and show significant crustal contamination. The lack of Ce anomaly in most samples indicates anoxic to suboxic conditions during their deposition. The geochemical characteristics of the associated metaigneous and metasedimentary rocks indicate that Kelle Bidjoka IFs were deposited in a submarine volcanic arc environment, similar to the Algoma-type BIFs. Detrital zircon LA-ICP-MS U-Pb dating suggests that the Kelle Bidjoka BIFs were deposited during early Paleoproterozoic (ca. 2423 Ma) and were metamorphosed up to granulite facies during the Eburnean/Transamozian (ca. 2050 Ma) orogeny. [ABSTRACT FROM AUTHOR]

A new lithostratigraphic framework based upon a review of historic data, field mapping and remote sensing, including aerial photography, high-resolution airborne aeromagnetic and radiometric data, is proposed for the Archaean geology along the southeastern margin of the Kaapvaal Craton, South Africa. A synthesis of new and existing data reveals that previously accepted lithostratigraphic schemes require complete revision, with reinterpretations identifying multiple major shear zones and previously unidentified granitoid successions along the margin of the craton. In this new lithostratigraphic framework, lithologies of the Southern Syncline previously correlated with the Nsuze Group of the Pongola Supergroup, are redefined as greenstone lithologies associated with the Ilangwe Greenstone Belt. The geology of the Nkandla region can be subdivided into five distinct geophysical domains including: (i) an extension of the Ilangwe Greenstone Belt, (Domain 1) which is subdivided into; a lower volcanic succession, the Thathe Formation, comprising pillow and amygdaloidal volcanics; the adjoining Sabiza Formation, comprising pillow volcanics exposed in the southeast of the study area; the volcano-sedimentary Mtshwili Formation, which overlies the Thathe and Sabiza formations, consisting of quartz (sericite) schist, phyllite, metavolcanics and iron formation; the Nomangci Formation, which occurs as a region of highly deformed quartz-kyanite-sericite schists, and the Simbagwezi Formation, which comprises maroon to green phyllites and schists in the north of the study area. (ii) granitoids of the Impisi Granitoid Suite (Domain 2) which border the greenstone succession to the north, intruding the Nomangci and Simbagwezi formations. (iii) a southern complex of sheared granitoids termed the Umgabhi Granitoid Suite (Domain 3), which intrudes the Thathe, Sabiza and Mtshwili formations. (iv) The two remaining domains, comprise the Mesoproterozoic Mfongosi and Ntingwe Groups (Domain 4) and Mesoarchaean volcano-sedimentary sequences of the Pongola Supergroup (Domain 5). [ABSTRACT FROM AUTHOR]

The chemical compositions of Phanerozoic basalts of all known geodynamic settings (mid-ocean ridges, oceanic plateaus, oceanic islands, island arcs, fore-arc and back-arc basins, continental rifts, large igneous provinces) are compared with Archean basalts, including basalts of greenstone belts and high-grade gneiss complexes. Linear discriminant analysis has shown that the Archean basalts differ significantly from Phanerozoic basalts in terms of the content of the least mobile major and trace elements. In this regard, the geochemical systematics of Phanerozoic basalts in most cases cannot be used to reconstruct the geodynamic settings of Archean basalts. The results obtained are illustrated by the example of the Mesoarchean basalts of the Olondo fragment of the Tokko–Khani greenstone belt. [ABSTRACT FROM AUTHOR]

Komatiitic magmatism is a characteristic feature of Archean cratons, diagnostic of the addition of juvenile crust, and a clue to the thermal evolution of early Earth lithosphere. The Slave craton in northwest Canada contains >20 greenstone belts but no identified komatiite. The reason for this dearth of komatiite, when compared to other Archean cratons, remains enigmatic. The Central Slave Cover Group (ca. 2.85 Ga) includes fuchsitic quartzite with relict detrital chromite grains in heavy-mineral laminations. Major and platinum group element systematics indicate that the chromites were derived from Al-undepleted komatiitic dunites. The chromites have low 187Os/188Os ratios relative to chondrite with a narrow range of rhenium depletion ages at 3.19 ± 0.12 Ga. While these ages overlap a documented crust formation event, they identify an unrecognized addition of juvenile crust that is not preserved in the bedrock exposures or the zircon isotopic data. The documentation of komatiitic magmatism via detrital chromites indicates a region of thin lithospheric mantle at ca. 3.2 Ga, either within or at the edge of the protocratonic nucleus. This study demonstrates the applicability of detrital chromites in provenance studies, augmenting the record supplied by detrital zircons. [ABSTRACT FROM AUTHOR]

Two high-resolution seismic reflection profiles acquired north and south of Chibougamau, located in the northeast of the Abitibi subprovince of Canada, help understand historic volcanically hosted massive sulfide (VMS) deposits and hydrothermal Cu–Au mineralization found there. Major faults crossed by the profiles include the Barlow fault in the north and the Doda fault and the Guercheville fault in the south, all targets of this study that seeks to determine spatial relationships with a known metal endowment in the area. Common-offset DMO corrections and common-offset pre-stack time migrations (PSTMs) were considered. Irregularities of the trace midpoint distribution resulting from the crooked geometry of both profiles and their relative contribution to the DMO and PSTM methods and seismic illumination were assessed in the context of the complex subsurface architecture of the area. To scrutinize this contribution, seismic images were generated for offset ranges of 0–9 km using increments of 3 km. Migration of out-of-plane reflections used cross-dip element analysis to accurately estimate the fault dip. The seismic imaging shows the thickening of the upper-crustal rocks near the fault zones along both profiles. In the northern seismic reflection section, the key geological structures identified include the Barlow fault and two diffraction sets imaged within the fault zone that represent potential targets for future exploration. The south seismic reflection section shows rather a complicated geometry of two fault systems. The Guercheville fault observed as a subhorizontal reflector connects to a steeply dipping reflector. The Doda fault dips subvertical in the shallow crust but as a steeply dipping reflection set at depth. Nearby gold showings suggest that these faults may help channel and concentrate mineralizing fluids. [ABSTRACT FROM AUTHOR]

The southern basement of the Cuddapah Basin comprises the Dharwar Batholith and greenstone belt complex. Granitoids of the batholith exhibit extensive variation in terms of geomorphology, age, mineralogy, and micro/meso scale structures. The eastern part of Dharwar Craton along 13°50′ to 14°8′N latitude and 78°45′ to 79°05′E longitude was studied to enlighten the rheological influence on crustal evolution. Frequent occurrences of migmatites of restricted dimension are observed in the south of 14°10′N latitude. The granite‐migmatite contacts are not sharp in general. Different types of migmatite complex and their relationships with granitoids as well as older country rocks represent an exhumed segment of the crustal catazone. The widespread group of migmatitic rocks are classified in a composite manner on the basis of morphology and structure. Furthermore, genetic implication vis‐a‐vis anatexis history is also evaluated. Static and dynamic modes of migmatites are recognized with reference to geothermal gradient and tectonics. Based on the degree of anatexis, two categories of migmatites are identified in the field, that is, metatexites and diatexites. In addition, metatexites are classified into four sub‐types (viz, patch, dilatant, net, and stromatic) and diatexites are also sub‐divided into two categories (viz, schollen or raft and schlieren). The hybrid nature of migmatitic rocks with both metamorphic and igneous characteristics are used to analyse pre‐ and post‐anatectic events. The preserved evidences of partial melting are marked as leucocratic patches. In situ stagnation of the melt or subsequent separation from the remaining solid provides different morphology of static mode. Importance of dihedral angle at solid–liquid contacts is also considered in the present context to describe the grain boundary penetration by partial melt. Folds, veins, and boudins of different styles and generations played significant role in dynamic mode migmatitization. The syn‐ and post‐metamorphic deformation events and granite melt generation from migmatites are schematically defined. Spatial and temporal relationships of schist‐gneiss‐migmatites of both static as well as dynamic mode reveal initiation of the crustal development by vertical accretion of ultramafic‐mafic lava and TTG. Cyclic partial remelting of the metabasic lava and TTG and underplating led to development of the lithospheric plate. Later upwelling material at convergent plate and associated heat transfer led to generation of granitic magma. The established prograde and retrograde cycle of metamorphism were possibly interrupted by crustal reworking events. This study confirms about the crustal catazone segment (with >15 km depth and >500°C) in which physical processes control generation, segregation, ascent, and emplacement of juvenile granite from migmatites. [ABSTRACT FROM AUTHOR]

The timing of emplacement of the oldest supracrustal rocks represented by Sargur Group is significant in understanding crustal evolution processes in the western Dharwar craton. The age of ultramafic-mafic rocks of the Sargur Group is not well-constrained as the komatiitic and komatiitic basaltic rocks have always given unreliable ages due to larger errors attributed to their alteration. New Sm-Nd isotope data from relatively less-altered layered intrusive ultramafic-mafic rocks of Nuggihalli and Holenarsipur greenstone belts of Sargur Group, western Dharwar craton give a much precise age of 2934 ± 88 Ma. This is the youngest age obtained for the ultramafic-mafic rock complexes of Sargur Group and is indistinguishable from the oldest ages reported for the overlying Dharwar Supergroup rocks. Sargur Group rocks might merely represent older ultramafic equivalents of the Dharwar Supergroup. A clear temporal distinction does not exist to support the stratigraphic classification of these two groups separately. However, the sub-contemporaneous to older ages obtained for the tonalite-trondhjemite-granodiorite gneisses that surround these greenstone belts would imply that the narrow belts tucked within the gneisses are younger, and therefore, the greenstone belts, whose dismembered roots and parts are exposed alongside the gneisses, could represent an Archaean analogue of an ophiolite suite. [ABSTRACT FROM AUTHOR]

The Neoarchean U-Th-Pb (SHRIMP-II) age of 2718 ± 7 Ma was established for the large copper–nickel Allarechka deposit located in the Kola–Norwegian region of the Fennoscandian shield. The deposit is associated with metamorphosed and deeply eroded volcano-plutonic complexes, which are the age and formational analogues of the Neoarchean greenstone belts. The compositional similarity of hyperbasites of the Allarechka ore district and host metavolcanic rocks of the Annama Formation with komatiite–tholeiitic metavolcanic rocks of the similar age of the Ura Guba–Kolmozero–Voron'ya greenstone belt suggests that they are ascribed to the komatiite–tholeiite volcanoplutonic series, the parental high-Fe komatiite melts of which were derived by partial melting of depleted upper mantle εNd(t) = +7.0 ± 0.4) at high PT parameters. The petrographic and geochemical composition of ore peridotites indicates that they are a cumulate formed by fractionation of Ol + Opx ± Pl, Mag from the primary high-Fe komatiite melt in a shallow (P ~ 4 kbar) magma chamber at a liquidus temperature of at least 1200°С. The absence of a significant crustal contamination of the hyperbasites by Mesoarchean TTG-complexes is proved by the trace and rare-earth element geochemistry, the Nd isotopic composition, as well as by the homogeneous morphology and isotopic composition of the accessory magmatic zircon. In contrast, Re-Os and sulfur isotopic systematics of sulfide ores indicate the contribution of not only mantle but likely crustal component in the evolution of sulfide melt. After separation from a primary mantle melt under subcrustal conditions, the silicate and sulfide melts evolved independently. Obtained data suggest that a local Ni, Cu, and PGE-rich mantle anomaly was formed through a plume–lithosphere interaction beneath the Kola–Norwegian Terrane (in its present-day outlines) of the Fennoscandian Shield at 2.75–1.9 Ga. This anomaly was a source of ore matter for three Early Precambrian copper–nickel ore epochs, in particular, for Neoarchean (~ 2750 Ma) deposits of the Allarechka ore field, Paleoproterozoic deposits (~ 2500 Ma) of the layered intrusions (e.g., Monchegorsk and Fedorova-Pana), and Pechenga group (~ 1900 Ma). [ABSTRACT FROM AUTHOR]

The paper summarizes major, trace, and Sm-Nd isotopic data on metabasites of the Urik greenstone belt (GB) (Sharyzhalgai uplift, southwestern Siberian craton). The Archean metabasalts (amphibolites and garnet amphibolites) of the supracrustal complex and sheeted bodies represent four geochemical types. The first type includes low-Ti amphibolites of the Urik area. Their characteristic features are a clear LREE depletion ((La/Sm)n = 0.8–1.1), the absent negative Nb anomaly, and positive εNd(t) values (up to +4.1). The second type corresponds to moderate-Ti amphibolites of the Urik area. They differ from the rocks of the first type in the higher (La/Sm)n ratio (1.0–1.5), Th, Zr, Nb, Y contents, and lower εNd(t) values (+0.4...–1.6), but, like the low-Ti amphibolites, they do not show Nb depletion. The third type includes amphibolites of the Tagna area, which show an increase in the concentrations of TiO2, LREE, Th, Zr, and Nb with a decrease in Mg# and have εNd(t) values from +1.3 to –0.5. They are characterized by the elevated (La/Sm)n ratio (1.1–2.3) and Zr and Nb contents and the presence of a clear Nb minimum. The fourth type includes all high-Ti amphibolites of sheeted bodies, which are enriched in LREE ((La/Sm)n = 1.9–3.4), Th, Zr, and Nb, have an increased (Gd/Yb)n (1.4–2.0), a sharp Nb depletion, and negative εNd(t) values. Geochemical modeling coupled with trace element and isotopic composition indicates the formation of the low- and moderate-Ti metabasalts of the Urik area from weakly depleted and nearly primitive mantle sources, respectively. Their protoliths were oceanic basalts. The metabasalts of the Tagna area were formed from a weakly depleted and hydrated mantle source contaminated with crustal material. The enrichment of the source with incompatible elements could be caused by sediment subduction shortly before basalt formation. The metabasalts of the fourth type originated from a long-lived enriched source such as subcontinental lithospheric mantle. They resemble the present-day intraplate continental basalts. None of the three dominant types of metabasalts of the Urik GB shows signatures of sharply depleted or sharply enriched mantle sources, which indicates a weak differentiation of the mantle by the Meso- Neoarchean boundary (~2.8 Ga). The formation of a subduction-modifed lithospheric mantle (hydrated mantle) has only occurred since ~ 2.8 Ga. Different compositional and isotopic characteristics of the metabasalts of the Urik GB suggest that the Bulun terrane was formed by accretion and tectonic juxtaposition of fragments of the oceanic crust, an oceanic island arc, and an older TTG continental crust at ~ 1.86 –1.82 Ga. [ABSTRACT FROM AUTHOR]

Trace elements in native gold provide a "fingerprint" that tends to be unique to individual gold deposits. Fingerprinting can distinguish gold sources and potentially yield insights into geochemical processes operating during gold deposit formation. Native gold grains come from three historical gold ore deposits: Hollinger, McIntyre (quartz-veined ore), and Aunor near Timmins, Ontario, at the western end of the Porcupine gold camp and the southwestern part of the Abitibi greenstone belt. Laser ablation – inductively coupled plasma – mass spectrometry (LA–ICP–MS) trace element concentrations were determined on 20–25 µm wide, 300 µm long rastor trails in ∼60 native gold grains. Analyses used Ag as an internal standard with Ag and Au determined by a scanning electron microscope with an energy dispersive spectrometer. The London Bullion Market AuRM2 reference material served as the external standard for 21 trace element analytes (Al, As, Bi, Ca, Cr, Cu, Fe, Mg, Mn, Ni, Pb, Pd, Pt, Rh, Sb, Se, Si, Sn, Te, Ti, Zn; Se generally below detection in samples). Trace elements in native gold associate according to Goldschmidt's classification of elements strongly suggesting that element behaviour in native Au is not random. Such element behaviour suggests that samples from each Timmins deposit formed under similar but slightly variable geochemical conditions. Chalcophile and siderophile elements provide the most compelling fingerprints of the three ore deposits and appear to be mostly in solid solution in Au. Lithophile elements are not very useful for distinguishing these deposits and element concentrations may be controlled by microinclusions such as tourmaline. The deposits show low Ag contents, which is consistent with mesothermal Au. Hollinger and McIntyre deposits have similar trace element abundances with higher Ag, Pb, Bi, Sb, and Pd and generally low Cu; however, Cu concentrations in McIntyre are higher than in Hollinger. In contrast, Aunor shows comparatively low Ag, Bi, Sb, Pb, and Pd and higher Au/Ag consistent with higher hydrothermal fluid temperatures. Gold grain signatures reflect the chemical characteristics of the host rock superimposed on a chemical signature inherited from the mineralizing fluid. The association of Pb–Bi–Cu bearing phases such as galena and chalcopyrite with gold apparently enriched in these elements supports precipitation from hydrothermal fluids carrying the elements. [ABSTRACT FROM AUTHOR]

Komatiites and sedimentary rocks sampled during the International Continental Drilling Program (BARB1-2–3-4–5) in the Barberton greenstone belt, South Africa, were analyzed for 146Sm-142Nd systematics. Resolved negative μ142Nd values (down to −7.7 ± 2.8) were identified in komatiites from the 3.48 Ga Komati Formation and this signature correlates with low Hf/Sm ratios measured in these samples. The negative μ142Nd point to a source with subchondritic Sm/Nd ratio which formed during the Hadean. No analytically resolvable 142Nd anomalies were measured in crustal detritus-rich, Si-rich, Ca-Fe-rich sediments and cherts from the Buck Reef (3.42 Ga) and the Fig Tree Group (3.23–3.28 Ga). Our new measurements are incorporated into a larger set of 147Sm-143Nd and 176Lu-176Hf data to better understand the 142,143Nd-176Hf isotope signatures in the mantle source at the time of komatiite crystallization. Our calculations show that the 142,143Nd-176Hf isotope signatures and Hf/Sm ratios cannot be produced by recycling into the komatiite source of detrital sediments like those sampled in the Barberton area. Only cherts have the required trace element characteristics – low Hf/Sm, radiogenic ε176Hf –but the trace element concentrations in the cherts are so low that unrealistic amounts of chert would need to be added. We propose a four-stage model for the formation of these rocks. Negative μ142Nd and low Hf/Sm ratios developed during the crystallization of a deep magma ocean soon after Earth accretion. The material that ultimately became the source of komatiites was a residual liquid produced by 50% crystallization leaving a bridgmanite/ferropericlase/Ca-perovskite cumulate. The Lu-Hf and Sm-Nd isotope systems were decoupled at this stage. After extinction of 146Sm around 4 Ga, parent/daughter ratios fractionated during a melt extraction event. With this model we explain the positive ε176Hf and slightly negative ε143Nd in these samples. The 3.55 Ga Schapenburg komatiites in another part of the Barberton belt share similar chemical signatures, supporting our model of fractionation in a deep magma ocean early in Earth's history. [ABSTRACT FROM AUTHOR]

• Devolatilized fluids from metabasalts at ∼550 °C have δ11B between −14.2 to −10.8‰. • Metapelites at similar temperatures release fluids with δ 11B between −5.7 to 0.0‰. • Tourmaline δ 11B from worldwide orogenic gold deposits match modelled δ 11B for metamorphic fluids. • Tourmaline δ 11B in Hutti and Kolar (−14.0 to −3.3‰) suggest precipitation from metamorphic fluids. • Li and V in tourmaline may be used as reliable source rock indicators. The source of the mineralizing fluid in Archean greenstone-hosted orogenic gold deposits is widely debated, with the available geochemical and isotope data interpreted as reflecting the involvement of metamorphogenic fluid produced by devolatilization of greenstone belt metaigneous/metasedimentary rocks or granite-derived magmatic-hydrothermal fluids or both. Orogenic gold deposits form in complex geologic environment involving multiple fluid sources, reflected in the large variation in the B-isotope composition of tourmaline (δ11B = −24.8‰ to +19.8‰). The δ11B distribution of tourmaline from world-wide orogenic gold deposits define two peaks, one at ca. −15‰, and the other between −5 and 0‰. In this study, we modelled the release of boron and associated B-isotope fractionation during prograde metamorphic dehydration of representative mafic and pelitic greenstone rocks using a mass balance approach and compared the results with the B-isotope composition of tourmalines measured globally from orogenic gold deposits. The results indicate that the boron content of greenstone belt metabasalts decreases from ∼26 ppm to ∼2.7 ppm by 530 °C while those in metapelites decrease from ∼60 ppm at 300 °C to ∼40 ppm by the terminal chlorite breakdown temperature of about 570 °C. In both mafic and pelitic assemblages, terminal chlorite breakdown reactions occurring during the greenschist to amphibolite facies transition (530–570 °C) release large amounts of 10B-rich fluids, which rapidly lower the δ11B of the metamorphic fluid. The δ11B of the fluids released from metabasalts and metapelites at these conditions are estimated to be about −14.2 to −10.8‰ and −5.7 to 0.0‰, respectively. Tourmalines precipitating from such metabasalt-derived fluid are expected to have δ11B between −18.0‰ and −12.4‰ while those crystallizing from metapelite-derived fluid will have δ11B between −9.5‰ and −1.6‰ for the temperature range of ore formation (300–550 °C) in orogenic gold deposits. Our calculated range of δ11B for the metabasalt- and metapelite-derived metamorphic fluids matches closely with the two peaks in the δ11B distribution of tourmaline from orogenic gold deposits. The δ11B of metabasalt-derived fluid is highly variable (+2‰ to −15‰ between 450 °C and 610 °C) and strongly dependent on the metamorphic grade attained by the greenstone belt lithologies. The majority of measured tourmaline δ11B values from orogenic gold deposits of all ages can potentially be explained by different peak metamorphic temperatures with a single fluid source from metabasalts, or by mixing between basalt-derived and pelite-derived metamorphic fluids, or both. Prior characterization of the metamorphic grade of the rocks and the temperature of mineralization are desirable before using the B-isotope composition of tourmaline for evaluating fluid source. The δ11B (−14.0‰ to −3.3‰) of tourmalines measured by us from the Hutti and Kolar gold deposits as a case study can be explained by our modelled results with the isotopic variations attributed to mixing between metapelite- and metabasalt-derived fluids. Low Li concentrations in the tourmalines of Hutti and Kolar (avg. 21.7 and 28.0 ppm in Hutti and Kolar, respectively) further support a metamorphic origin for the hydrothermal fluid. The relatively higher V contents of the Hutti tourmalines (avg. 962 ppm) vis-à-vis the Kolar tourmalines (avg. 615 ppm) is suggestive of greater pelitic input in Hutti. [ABSTRACT FROM AUTHOR]

The crustal evolution of Venus appears to be principally driven by intraplate processes that may be related to mantle upwelling as there is no physiographic (i.e. mid-ocean ridge, volcanic arc) evidence of Earth-like plate tectonics. Rocks with basaltic composition were identified at the Venera 9, 10, 13, and 14, and Vega 1 and 2 landing sites whereas the rock encountered at the Venera 8 landing site may be silicic. The Venera 14 rock is chemically indistinguishable from terrestrial olivine tholeiite but bears a strong resemblance to basalt from terrestrial Archean greenstone belts. Forward petrological modeling (i.e. fractional crystallization and partial melting) and primary melt composition calculations using the rock compositions of Venus can yield results indistinguishable from many volcanic (ultramafic, intermediate, silicic) and plutonic (tonalite, trondhjemite, granodiorite, anorthosite) rocks that typify Archean greenstone belts. Evidence of chemically precipitated (carbonate, evaporite, chert, banded-iron formation) and clastic (sandstone, shale) sedimentary rocks is scarce to absent, but their existence is dependent upon an ancient Venusian hydrosphere. Nevertheless, it appears that the volcanic--volcaniclastic--plutonic portion of terrestrial greenstone belts can be constructed from the known surface compositions of Venusian rocks and suggests that it is possible that Venus and Early Earth had parallel evolutionary tracks in the growth of proto-continental crust. [ABSTRACT FROM AUTHOR]

The sources of metals enriched in Archean orogenic gold deposits have long been debated. Metasedimentary rocks, which are generally accepted as the main metal source in Phanerozoic deposits, are less abundant in Archean greenstone belts and commonly discounted as a viable metal source for Archean deposits. We report ultralow-detection-limit gold and traceelement concentrations from a suite of metamorphosed sedimentary rocks from the Abitibi belt and Pontiac subprovince, Superior Province, Canada. Systematic decreases in the Au content with increasing metamorphic grade indicate that Au was mobilized during prograde metamorphism. Mass balance calculations show that over 10 t of Au, 30,000 t of As, and 600 t of Sb were mobilized from 1 km3 of Pontiac subprovince sedimentary rock metamorphosed to the sillimanite metamorphic zone. The total gold resource in orogenic gold deposits in the southern Abitibi belt (7500 t Au) is only 3% of the Au mobilized from the estimated total volume of high-metamorphic-grade Pontiac sedimentary rock in the region (25,000 km3), indicating that sedimentary rocks are a major contributor of metals to the orogenic gold deposits in the southern Abitibi belt. [ABSTRACT FROM AUTHOR]

This study presents new field and petrological observations combined with geochemical data on a range of komatiitic to tholeiitic volcanic rocks from the ca. 3.48 Ga mid-lower Komati Formation type-section of the Barberton Greenstone Belt, South Africa. A range of mafic-ultramafic rocks is identified across a 1.44 km profile, leading to the proposition of a new preliminary volcanic architecture for the mid-lower Komati Formation type-section. Major, trace and rare earth element (REE) data in conjunction with Lu-Hf isotopic constraints indicate that the tholeiites, newly recognized highmagnesium basalts, basaltic komatiites and komatiites in the volcanic sequence have a primitive mantle signature with no geochemical affinity to Archaean or modern-day supra-subduction zone boninites. The whole rock initial εHf values of spinifex and massive komatiite flows in the lowermost part of the Komati type-section are negative, ranging between -1.9 and -3.1, whereas the second overlying spinifex and massive flow unit records positive initial εHf values between +0.5 and +4.7. A new geodynamic model involving crustal contamination of the mafic-ultramafic lavas is proposed for the Barberton mid-lower Komati Formation type-section, involving mantle plume-crust interaction. The new observations and data indicate that the komatiites erupted as a result of a mantle plume from a hot (>1 600oC) mid-Archaean mantle, in which the earliest volcanic flows were variably affected by crustal contamination during their ascent and eruption. The possibility of incorporation of lower crustal material and/or recycled crust residing in the mantle source region cannot be excluded. This indicates that modern-style plate tectonic processes, such as subduction, may not have been a requirement for the formation of the 3.48 Ga Barberton komatiite suite, with implications for the hydration state, geodynamic processes and secular thermal evolution of the Archaean mantle. [ABSTRACT FROM AUTHOR]

The Neoarchean potassic granite from the Hosadurga region adjacent to the Chitradurga greenstone belt (CGB), part of the western Dharwar Craton (WDC), is studied for its petrogenesis. The combined field, petrographic, whole‐rock elemental, and Nd–Sr isotope data of granite and associated Tonalite–Trondhjemite–Granodiorite (TTG) gneiss from this region are presented here. The granites are alkali‐calcic to calc‐alkalic in terms of modified alkali lime index (MALI) and are weakly peraluminous (molar Al2O3/(CaO + Na2O + K2O) = 1.0–1.1). The geochemical data indicate that these are formed by the melting of TTG gneiss at depths above the garnet stability field. Isotopic data (εNd = −2.9 to −7.6 at T = 2,600 Ma, ISr = 0.715–0.729, TDM > 3.0 Ga) also show the involvement of Archean crustal sources. Trace element modelling was carried out using non‐modal equilibrium melting equation, which constraints partial melting of TTG source to a low degree (11%) for the formation of this granite. This model could also produce a major element composition consistent with this granite. The upper bounds on the magmatic temperatures (724–785°C) assessed from zircon saturation thermometry suggest that fluid influx is required. TTG samples show variable and very high positive epsilon Nd values (1.5–8.9), higher than the contemporaneous mantle, suggesting re‐melting of mafic crust. The observed high Nd isotope ratios in TTG indicate involvement of a mafic source that formed as early as ~3.8 Ga, probably as a result of global differentiation of the early Earth. [ABSTRACT FROM AUTHOR]

Unravelling the petrogenesis and stratigraphy of Archean mafic lava flows is essential to our comprehension of the early geodynamic evolution and economic potential of greenstone belts. This study focuses on one of the oldest and thickest sequences of lava flows observed in the Neoarchean Abitibi Subprovince (greenstone belt), that is, the Obatogamau Formation. The undated formation extends for more than 100 km in an E–W direction and consists mostly of aphyric and feldspar megacryst-bearing basaltic-andesite lava flows. These lava flows are tholeiitic, mostly Fe-rich, and have nearly homogeneous chemistry. Petrogenetic modelling carried out using MELTS software points to limited magmatic differentiation as most samples of mafic lava flows did not reach Fe-Ti-oxide saturation. Zircon U-Pb dating establishes a crystallization age of 2726.2 ± 1.6 Ma for a felsic unit located at an intermediate stratigraphic position in the sequence of lava flows. Constraints from stratigraphically overlying volcanic units suggest that the Obatogamau Formation was likely emplaced rapidly, possibly within a few million years and as a consequence of frequent replenishment of shallow magma accumulations. High eruption rates are consistent with short episodes of volcanic quiescence deduced from field observations, indicating non-optimal conditions for volcanogenic massive sulfide systems. The pressure and temperature of peak metamorphism deduced from amphibole chemistry, however, points to favorable conditions for the release of metamorphic fluids. The study area may thus be prospective for orogenic gold mineralization, provided that fluids had access to a source of gold and that structural conduits allowed for the channeling of hydrothermal fluids. [ABSTRACT FROM AUTHOR]

The article analyzes the position of individual and average data points of the Archean and Early Proterozoic metaaleuropelites (Isua and Akilia associations, West Greenland; Beit Bridge Complex, Limpopo Province, South Africa; Moodies, Mozaan, and Pretoria groups, Barberton Mountain Land, South Africa; Kola Group, Baltic Shield, Russia; Nurmes paragneisses, Eastern Finland; Onot greenstone belt, southeastern Sayan region, Russia; Rampur Group, Lesser Himalayas, India; Kan metamorphic complex, eastern Sayan region, Russia; Ladoga Group, northern Ladoga region, Russia; Yenisei metamorphic complex, Russia; and others) in the (La/Yb)N–Eu/Eu* and (La/Yb)N–Th diagrams with classification fields constructed from data on the content of REE and Th in the fine grained clastic/aleuropelitic sediments near the estuary of different-category modern rivers, according to (Bayon et al., 2015). It has been shown that the vast majority of data points of metaaleuropelites are localized in fields 1 (particulates of major rivers in the world), 2 (particulates of rivers draining sedimentary substrates) and 4 (particulates of rivers flowing through volcanic rock terrains), as well as the zone overlapping fields 1–3 (particulates of rivers feeding on erosion products of the magmatic/metamorphic terrains). Data points of all examined objects with an age of more than 2.8 Ga in the (La/Yb)N–Eu/Eu* diagram are concentrated mainly in field 4. If all our assumptions are correct, these observations suggest the following conclusion: until the above-indicated time, large rivers and, most likely, rivers draining mainly sedimentary rocks did not exist, and processes of the recycling of fine-grained aluminosiliciclastics were reduced. [ABSTRACT FROM AUTHOR]

Characterization of terrestrial analog sites is critical for detection and determination of clay mineralogy in remote sensing studies of Mars aimed at geological, hydrological, and potentially biological investigations. In this study, we investigate a suite of hydrothermally altered early Archean rocks from the Barberton greenstone belt (BGB) of South Africa as potential petrological, mineralogical, and spectral analogs to hydrothermally altered metabasalts and mafic-ultramafic intrusions in the martian subsurface and impact craters. We present the first spectral imaging measurements on exceptionally well-preserved early Archean mafic-ultramafic rocks from the BGB, with the aim of studying their clay mineralogy and spectral signatures. Multiple spectral analyses were conducted on different sample textures (rock powders, crushed rocks, and rock slabs) appropriate for Mars rover and remote sensing exploration. Visible/near-infrared (VNIR) and mid-IR reflectance spectra were acquired on particulate samples, while VNIR spectral imaging data were collected on rock slabs. Mid-IR emission spectra were measured for the rock slabs and grains. Spectral features are compared from these different spectral techniques to identify the minerals present in the samples and compare macroscale vs. microscale detections. The measured spectra reveal absorption bands that correspond to clay mineralogy of the serpentine and chlorite mineral groups, consistent with petrographic observations, as well as magnetite, olivine, quartz, feldspar, and Al-phyllosilicate. The spectral data acquired in this study expand the reference spectra data set for remote sensing studies. The implications of this study are that rocks from early Archean greenstone belts, such as those of the BGB, serve as potential clay-bearing petrological analogs for hydrothermal environments on Mars. [ABSTRACT FROM AUTHOR]

Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) and electron microprobe analysis (EMPA) techniques were used to determine the mineralogy and chemistry of dominant sulphide and associated gold deposits at the Fairview Gold Mine of the Barberton Greenstone Belt (BGB). The rocks and ore mineral associations at the Fairview Mine indicate mesothermal (orogenic) conditions for the gold deposit. The whole rock chemistry of the Fairview Mine reflects calc-alkaline affinities, and felsic provenance is revealed by high SiO2, K2O, Al2O3, and TiO2, and low Fe2O3, MgO, Ni, and Cr contents. The mineral assemblages of the Fairview Mine rocks and ores indicate three phases of metamorphisms; regional prograde, thermal, and retrograde metamorphism, which caused zonation and heterogeneity of the ore minerals. The principal ore minerals in this deposit are pyrite, arsenopyrite, pyrrhotite, chalcopyrite, and rare sphalerite, as well as minor gold. The obtained results revealed that sulphides of the Fairview Mine are divided into two types (generations) varying in their morphology, association, and elemental composition. The old type 1 is porous, anhedral, heterogeneous, contains inclusions and rich in As, Ni, Co, and Au compared to type 2. Trace-element distribution and occurrence mode of gold at Fairview mine reflect two phases of gold mineralization. The first stage is associated with sulphides (mainly pyrite and arsenopyrite), whilst the second phase is free-lode hosted by silicates (mainly quartz). [ABSTRACT FROM AUTHOR]

The paper presents results of the first geochronologic study (LA-ICP-MS zircon method) of metasedimentary rocks that host the banded iron formation (BIF) and the metarhyolites (halleflinta) of the Gimoly Group in the Kostimuksha greenstone belt,Karelian Craton. Felsic magmatism that produced the rhyolite sills and dikes was dated at 2759 ± 19–2743 ± 15 Ma. The clearly predominant group of zircons in the schists (metagraywacke) has an isotope age of 2753 ±19 Ma, and scarce zircon grains of these rocks vary in age from 3.1 to 2.8 Ga. Geochemically, zircons from metarhyolites fall into three types (1) Eu-depleted and Ce-enriched, (2) Eu- and Ce-enriched, and (3) LREE- and MREE-enriched. The zircons of geochemical types (1) and (2) are also predominant in the sediments. The morphology and structure of zircon crystals in the rhyolites and sediments are also identical. The rhyolites were thus a major source of zircons for the metagraywacke, which alternates with BIF, while the Mesoarchean rocks played a subordinate role. The BIF of the Gimoly Group in the Kostomuksha Greenstone Belt was formed simultaneously with felsic volcanism at 2760–2740 Ma. [ABSTRACT FROM AUTHOR]

The ~3.22 Ga Moodies Group, Barberton Greenstone Belt (BGB), South Africa, provides a unique window into Archaean sedimentary, magmatic and ecological processes. In the central BGB, a regional mafic complex, consisting of a genetically related major mafic sill, a peperitic dyke stockwork, and extensive basaltic lava flows affected thick quartzose sandstones of the Moodies Group. We argue that epithermal hydrothermalism associated with this magmatic event occurred, at least in part, syndepositionally and in places destroyed, in other places preserved the abundant benthic microbial mats in terrestrial- and coastal-facies sandstone of this unit. We differentiate four principal types of hydrothermal alteration: (1) Sericitization resulted from ubiquitous feldspar breakdown; (2) iron-oxide alteration replaced the original matrix by fine-grained iron oxide; (3) silicification replaced matrix and most nonsilica grains by microcrystalline silica and locally preserved kerogenous microbial mats; and (4) hydraulic fracturing at shallow depth brecciated consolidated Moodies Group sandstone and created closely spaced, randomly oriented fractures and quartz-filled veins. Because stockwork intrusion locally interacted with unconsolidated water-saturated sediment and because the dykes connect the sill with the mafic lava but also follow zones of structural weakness, we suggest that hydrothermalism associated with this magmatic event occurred syndepositionally but was also - within the resolution of radiometric age data - contemporaneous with tight regional folding. We conclude that microbial organisms in Paleoarchaean coastal (tidal, estuarine) environments may have been formerly widespread, possibly even abundant, but are nearly nowhere preserved because they were easily degradable. Preservation of Early Archaean microbial mats in a thermal aureole in the central BGB was controlled by the "just right" degree of heating and very early hydrothermal silicification. [ABSTRACT FROM AUTHOR]

The Stolzburg domain to the south of the Barberton Greenstone Belt preserves evidence for a 3.23 Ga subduction- collision tectonic event. Garnet amphibolite greenstone remnants have previously yielded conventional thermobarometric P-T estimates of 12 to 15 kbar at 600 to 650°C, 8 to 11 kbar at 650 to 700°C and 7.5 to 8.5 kbar at 560 to 640°C from, respectively, the Inyoni shear zone along the western margin of the Stolzburg domain, the central part of the domain and from the Tjakastad schist belt on the boundary with the main body of the Barberton Greenstone Belt. Pseudosection calculations constrain the stability conditions of the peak metamorphic assemblages at the three localities to be 10 kbar at 675 to 690°C, ~10 kbar at 700°C and ~7 and 10 kbar at 660°C respectively. Although it is possible that the peak metamorphic assemblages may be displaced to somewhat lower conditions if Mn is considered in the calculations, these estimates are generally in good agreement with existing estimates, and confirm that the Stolzburg domain exposes an intact mid- to lower-crustal section that was metamorphosed in a relatively cool environment at 3.23 Ga. Our results do not support previously documented higher-pressure conditions, and we contend that the mineral assemblages used to derive these estimates can equally reflect the conditions determined here. The presence of albite-epidote inclusion assemblages in garnet indicates that the likely prograde path involved a component of heating at depth, which is typical of subduction-collision environments and markedly different from the heating-burial paths expected for sinking greenstones in a vertical tectonic model. [ABSTRACT FROM AUTHOR]

Interpretations of the structural/tectonic evolution of the Barberton Greenstone Belt (BGB) and its surrounding granitoid rocks remain controversial, with proponents for both horizontal thrust-accretion (plate tectonic) and partial convective overturn (vertical tectonic) models. Here, an area of complex folds that was used to support the operation of plate tectonic-derived gliding and overthrust nappe tectonics is re-investigated in detail and placed within the broader structural development of the BGB and surrounding granitoid domains via a re-analysis of structures, and geochronological, stratigraphic and metamorphic data across the whole of this important geological terrain. The results of detailed field mapping show that the complex folds, which occur on the northern limb of the 20 km wavelength, vertically plunging, Onverwacht Anticline, do not represent a re-folded, originally recumbent, isoclinal fold, as previously interpreted. Instead, the folds represent a moderately shallow east-plunging fold train that formed from a single episode of deformation. Fold asymmetry is consistent with formation during originally north-side-up reverse shear on bounding faults, consistent with the offset direction required to explain the faultrepeated slices of Mendon Formation + Fig Tree Group rocks that uniquely occur across the northern limb of the Onverwacht Anticline. More broadly, a review of the BGB and surrounding granitoid rocks show that formation was likely through two discrete, ~120 Ma long, episodes of mantle upwelling, or plume, magmatism, each of which led to crustal melting and partial convective overturn (PCO), a tectonic mechanism that arises from the gravity-driven interaction between dense, upper crustal greenstones and partially melted, more buoyant, granitoid-dominated middle crust. The first mantle upwelling episode, at 3 530 to 3 410 Ma, commenced with long-lived eruption of ultramafic-mafic lavas of the Sandspruit, Theespruit, Komati, and lower Hooggenoeg formations (3 530 to 3 470 Ma). Heat from this magmatic event gave rise to partial melting of the crust that, combined with fractionation of mafic magma chambers produced widespread felsic magmatism at 3 470 to 3 410 Ma (upper Hooggenoeg Formation and Buck Reef Chert), the latter parts of which were accompanied by the formation of D1 dome-and-keel structures via PCO in deeperlevels of the crust represented by the Stolzburg Domain in the far southwest part of the belt. The second mantle upwelling, or plume, episode commenced at 3 334 to 3 215 Ma with the eruption of ultramaficmafic lavas of the Kromberg, Mendon and Weltevreden formations. Heat from this magmatic event gave rise to renewed partial melting of the crust that, combined with fractionation of mafic magma chambers, produced widespread felsic magmatism at 3 290 to 3 215 Ma. A second, longer-lived and more complex, multi-stage episode of PCO (D2-D4) accompanied deposition of the Fig Tree and Moodies groups from 3 250 to 3 215 Ma. Late D5 deformation accompanied emplacement of the Mpulizi and Piggs Peak batholiths at ca. 3.01 Ga, as previously identified. The Inyoka and Kromberg faults, which separate domains with distinct structural styles, represent neither terrane boundaries nor suture zones, but rather axial faults that separate deformed but generally inward-facing greenstone panels that sank inwards off rising granitoid domains that surround the BGB. [ABSTRACT FROM AUTHOR]

The formation and evolution of Palaeoarchaean De Kraalen and Witrivier Greenstone Belts (DKGB and WGB) of the Kaapvaal Craton are poorly known. Here we report zircon and rutile in situ U-Pb ages and zircon Hf isotopic data from a variety of supracrustal rocks. The zircon cores from a metamafic amphibole-bearing gneiss from the DKGB give a protolith age of 3 441 ± 5 Ma, whereas the zircon mantle domains give a metamorphic age of 3 211 ± 16 Ma. The 176Hf/177Hft values for all zircon domains give a tight cluster around 0.280596 ± 0.00006 (2 SD). U-Pb analyses of zircon for an amphibolite intercalated with thin calc-silicate layers from the WGB give a single crystallisation age of 3 230 ± 3 Ma, but the Hf isotope ratios of these zircon grains define two different populations. The first population yields 176Hf/177Hf~3.23 Ga = 0.28064 ± 0.00004, corresponding to eHf~3.23 Ga = 2.4 ± 1.9 (2SD) and Hf model ages between ca. 3.51 to 3.30 Ga. These are Hf isotope characteristics for zircons from a relatively juvenile source extracted from a depleted mantle source ca. 0.28 to 0.07 Ga prior zircon crystallisation. The second population yields 176Hf/177Hf~3.23 Ga = 0.28093 ± 0.00004 with eHf~3.23 Ga = 8.1 ± 1.3 (2SD). These Hf data combined with the 206Pb/207Pb ages lead to isotope ratios that lie above those of Depleted Mantle. The unusually high Hf isotope signature for the cores of the zircons from the WGB amphibolite most likely represent a contribution from an early highly depleted mantle source. A rutile in situ U-Pb age of 3.085 Ga from a recrystallised quartzite indicate that the rocks from the DKGB experienced slow cooling following the 3.21 Ga metamorphic event or (partial) resetting due to elevated geothermal gradient caused by the ca. 3.1 Ga intrusions of the Vrede Granitiod Suite. The latter interpretation is preferred because ~145 Ma of slow cooling from the amphibolite facies conditions of peak metamorphism to the blocking temperature for mass diffusion of Pb in rutile is unlikely. While the Zr-in-rutile temperature of ca. 710°C at 7 kbar for DKGB most likely records the peak temperature of the ~3.23 to 3.21 Ga event. The trace element concentrations of the metamorphic rutile grains within the quartzite of the DKGB indicate that the source rock was enriched in Cr. Either due to silification during hydrothermal alteration of the (ultra)mafic country rock or during deposition in an atmosphere that allowed for chromite grains to be part of the sediment. [ABSTRACT FROM AUTHOR]

The Kaapvaal and Zimbabwe cratons host some of the earliest evidence for life. When compared to the contemporaneous East Pilbara craton, cherts and other metasedimentary horizons in southern Africa preserve traces of life with far greater morphological and geochemical fidelity. In spite of this, most fossiliferous horizons of southern Africa have received relatively limited attention. This review summarises current knowledge regarding the nature of early life and its distribution with respect to environments and ecosystems in the Archaean (>2.5 Ga) of the region, correlating stratigraphic, sedimentological, geochemical and palaeontological understanding. There is abundant and compelling evidence for both anoxygenic photosynthetic and chemosynthetic biomes dominating Palaeoarchaean-Mesoarchaean strata dating back to around 3.5 Ga, and the prevalence of each is tied to palaeoenvironmental parameters deducible from the rock record. Well-developed, large stromatolites characteristic of younger Mesoarchaean-Neoarchaean sequences were probably constructed by oxygenic photosynthesisers. Isotopic evidence from the Belingwe greenstone belt and the Transvaal Supergroup indicates that both a full sulphur cycle and complex nitrogen cycling were in operation by the Mesoarchaean-Neoarchaean. The Archaean geological record of southern Africa is thus a rich repository of information regarding the co-evolving geosphere and biosphere in deep time. [ABSTRACT FROM AUTHOR]

The Inyoni shear zone represents an important tectonic boundary between (i) the ca. 3.45 Ga high-pressure amphibolite facies, granite-greenstone domain south of the Barberton greenstone belt, termed the Stolzburg terrane, and (ii) the ca. 3.29 to 3.23 Ga rocks of the trondhjemitic Badplaas pluton to the west. The Stolzburg terrane is separated from the greenschist facies rocks of the rest of the Barberton greenstone belt by the Komati fault, which records >10 km uplift of the Stolzburg terrane relative to the lower-grade rocks of the greenstone belt at ca. 3.23 Ga. A number of studies within the Stolzburg terrane have documented high-pressure amphibolite facies metamorphism that occurred concurrently with exhumation, with the lowest apparent geothermal gradients documented in the Inyoni shear zone, where strong constraints on the age of metamorphism are most limited. In addition, different studies on Inyoni metamorphism have produced significantly different temperature estimates. This study utilizes garnet Sm-Nd geochronology in combination with P-T modelling to directly date the metamorphism and re-evaluate the P-T conditions of the Inyoni shear zone. Two petrologically distinct samples produce similar P-T evolutions. A heterogeneous sample with both garnet-bearing and garnet-absent domains gives up-P evolutions reaching conditions of 550 to 675°C and 7 to 10 kbar, whereas a homogenous sample containing garnet and clinopyroxene produces a similar dominantly up-P evolution reaching peak conditions of 650°C and 8 to 10 kbar. Sm-Nd garnet ages of 3 201.6 ± 4.7 Ma (MSWD = 1.02) and 3 200.3 ± 5.3 Ma (MSWD = 0.44) were obtained from two samples of the homogenous garnet and clinopyroxene-bearing amphibolite. The Sm-Nd garnet geochronology provides accurate ages for the metamorphism of the Inyoni shear zone, with age results suggesting activity on the Inyoni shear zone may have continued after the regional metamorphism at ca. 3.23 Ga previously established by zircon U-Pb geochronology. However, 147Sm decay constant uncertainty leaves open the possibility that Inyoni garnet growth could have coincided with the previously recognized 3.23 Ga regional metamorphism. [ABSTRACT FROM AUTHOR]

Layered ultramafic-mafic complexes are a common component of the stratigraphically uppermost part of the Onverwacht Group of the Barberton Greenstone Belt. Associated with the Mendon Formation in the south and the Weltevreden Formation in the north, they represent an assemblage of thick differentiated flows and shallow synvolcanic intrusions ranging in composition from dunite to gabbro. U-Pb zircon dating of gabbro from the Sawmill and the Mundt's Concession ultramafic complexes from the northern part of the Barberton Greenstone Belt yielded ages of 3 258 ± 8 Ma and 3 244 ± 11 Ma, respectively. The ultramafic complexes are thus regarded to have been emplaced during a magmatic flare-up in the final stage of Weltevreden Formation volcanism, post-dating ultramafic magmatism in the southern part of the belt by several millions of years and thus suggesting diachronous evolution of the Onverwacht Group in the Barberton Greenstone Belt. [ABSTRACT FROM AUTHOR]

The paper presents newly acquired isotope-geochemical and U–Pb isotope zircon dating (SHRIMP) results on four posttectonic granitoid massifs in the southeastern part of the Karelian Granite–Greenstone Province (GGP) in the Fennoscandian Shield. The massifs are located near the Hautavaara Structure, in the southeastern part of the Mesoarchean (3.05–2.85 Ga) Vedlozero–Segozero Greenstone Belt, which is confined to the western margin of the Vodlozero crustal block with a Paleoarchean (TNdDM > 3.2 Ga) prehistory. All four massifs (Hautavaara, Chalka, Shuya, and Nyalmozero) were shown to have similar structural–tectonic settings, were emplaced nearly simultaneously (at 2745–2740 Ma), and display variations in the rock compositions that were predetermined by differences in the composition of the magma sources and the conditions of their derivation. The Hautavaara Massif in the central part of the structure and the Chalka Massif on its western margin are made up of moderately alkaline high-Mg granitoids (sanukitoids), whose initial diorite melts were derived by melting the lithospheric mantle metasomatized in an active-margin setting at 3.00–2.90 Ga. The Shuya granodiorites and Nyalmozero leucogranites, which are confined to the eastern flank of the structure, yield highly fractionated HREE patterns (Dyn/Ybn = 3.5 to 5.14), negative εNdT = –0.9 to –2.8, and were produced by melting a Mesoarchean crustal source at various depths. This source was similar to the 3.05- to 2.90-Ga felsic volcanics in the Hautavaara Structure. The Shuya granodiorites contain elevated Cr and Ni concentrations, suggesting that the melts were generated in the crust with the involvement of mafic magma, which was likely coeval with the primitive sanukitoids. The melting of the continental lithosphere at mantle and crustal levels in the Karelian GGP in the latest Neoarchean are thought to have occurred in an extensional environment during collapse of the collisional orogen, in accordance with the model (Laurent et al., 2014). [ABSTRACT FROM AUTHOR]

This paper focusses on obtaining a better understanding of the subsurface geology of the Chibougamau area, in the northeast of the Abitibi greenstone belt (Superior craton), using geophysical data collected along a 128 km long traverse with a rough southwest–northeast orientation. We have constructed two-dimensional (2D) models of the study area that are consistent with newly collected gravity data and high-resolution magnetic data sets. The initial models were constrained at depth by an interpretation of a new seismic section and at surface by the bedrock geology and known geometry of lithological units. The attributes of the model were constrained using petrophysical measurements so that the final model is compatible with all available geological and geophysical data. The potential-field data modelling resolved the geometry of plutons and magnetic bodies that are transparent on seismic sections. The new model is consistent with the known structural geology, such as open folding, and provides an improvement in estimating the size, shape, and depth of the Barlow and Chibougamau plutons. The Chibougamau pluton is known to be associated with Cu–Au magmatic-hydrothermal mineralisation and, as the volume and geometry of intrusive bodies is paramount to the exploration of such mineralisation, the modelling presented here provides a scientific foundation to exploration models focused on such mineralisation. [ABSTRACT FROM AUTHOR]

The nature of Earth's earliest crust and the processes by which it formed remain major issues in Precambrian geology. Due to the absence of a rock record older than ~4.02 Ga, the only direct record of the Hadean is from rare detrital zircon and that largely from a single area: the Jack Hills and Mount Narryer region of Western Australia. Here, we report on the geochemistry of Hadean detrital zircons as old as 4.15 Ga from the newly discovered Green Sandstone Bed in the Barberton greenstone belt, South Africa. We demonstrate that the U-Nb-Sc-Yb systematics of the majority of these Hadean zircons show a mantle affinity as seen in zircon from modern plume-type mantle environments and do not resemble zircon from modern continental or oceanic arcs. The zircon trace element compositions furthermore suggest magma compositions ranging from higher temperature, primitive to lower temperature, and more evolved tonalite-trondhjemitegranodiorite (TTG)-like magmas that experienced some reworking of hydrated crust. We propose that the Hadean parental magmas of the Green Sandstone Bed zircons formed from remelting of mafic, mantle-derived crust that experienced some hydrous input during melting but not from the processes seen in modern arc magmatism. [ABSTRACT FROM AUTHOR]

The Oleninskoe gold deposit is located in the northwestern part of the Kolmozero–Voron'ya greenstone belt (Kola Peninsula), in a sequence of amphibolite with granite porphyry sills. The sills are genetically connected with a big granodiorite- and granite-porhyry massif, which hosts the Pellapahk Cu–Mo porphyry deposit. The geochemical association of the Oleninskoe includes As, Pb, Ag, Cu, Sb, and Au; the Au/Ag ratio is less than 0.2. The ore is of very complex mineral composition (more than 50 mineral names of intermetallic compounds, sulfides, and sulfosalts are defined), with widespread Ag and Sb minerals. Fluid inclusions in quartz are of high salinity with anomalous concentration of minor elements. All these characteristics show that the deposit formed in an Early Precambrian porphyry-epithermal system. Then the deposit underwent metamorphism (lower amphibolite facies) in the Neoarchean and Paleoproterozoic, indicating the absence of chlorite and a scarcity of carbonates in metasomatic rocks, replacement of pyrite with pyrrhotite, and signatures of sulfide anatexis in ore. This is the first finding of this genetic type of gold deposits in the northern part of the Fennoscandian Shield. [ABSTRACT FROM AUTHOR]

In comparison to the greenstone belt volcano-sedimentary successions, mature arenite dominated sedimentary deposits are very rarely preserved in Paleo-Mesoarchean rock record. Such arenitic deposits may be important for the recognition of extensive development of continental freeboard and onset of Phanerozoic style plate tectonics. The Keonjhar siliciclastics are ∼715-m thick mature arenite-dominated Mesoarchean succession that unconformably overlies Paleo-Mesoarchean granite-greenstone core of the Singhbhum craton. The succession is mapped on 1:50,000 scale, and is designated as the Keonjhar Quartzite. It is subdivided into conglomerate dominated lower unit as the Asurkhol Member and mature arenite dominated upper unit as the Kamalpur Member. A lensoid body of iron ore clast bearing conglomerate unconformably overlies the Keonjhar Quartzite, and is designated here as the Chamakpur Conglomerate. The succession is repeated by three westerly dipping reverse faults that have upthrown the deeper parts of the basinal transects against shallower parts. The Asurkhol Member represents subaerial part of a coastal alluvial fan. The Kamalpur Member represents shallow-shelf depositional setting. Detailed mapping and recognition of the fault slices led to the reconstruction of the paleogeographic setting. The present study also highlights the importance for the stratigraphic correlation of the Keonjhar Quartzite with underlying metabasics of Malangtaoli-Jagannathpur lava and the overlying western IOG succession. The internal stratigraphic classification proposed here is also significant from economic point of view with regard to the occurrences of uraniferous QPCs in the Asurkhol Member and detrital iron ore deposits in the Chamakpur Conglomerate. [ABSTRACT FROM AUTHOR]

The early tectonic history of the Eastern Goldfields Terrane (EGT) is poorly understood, but in places ca 2800 Ma mafic–ultramafic sequences are conformably overlain by ca 2720–2670 Ma sequences (e.g. Leonora and Laverton districts), suggesting minimal early deformation. The first significant angular unconformities occur at the base of the ca 2670–2655 Ma late basins and indicate that deformation was contemporaneous with deposition of the late basins. These basins mark the end of the volcano-sedimentary record in the EGT and typically grade upwards from polymictic mafic-dominated conglomerates to more siliciclastic compositions with abundant granitic clasts. The clastic sequences record the uplift and exhumation of granite-cored domes. There is a distinct lack of clasts with internal deformation fabrics (e.g. schist or gneiss). The timing of late basin formation overlaps with the ca 2672–2660 Ma D1 event, which has been variously described as extensional or compressional. D1 structures comprise a bedding-parallel S1 that is axial planar to F1 folds. The late basins and early D1 fabrics are overprinted by upright north-trending F2 folds and a sub-vertical S2. A period of crustal thickening was achieved by autochthonous processes with deposition of greenstone sequences into local basins between ca 2720 and 2670 Ma. Partial convective overturn (or granite-up, greenstone-down tectonics) developed as a result of gravitational instability. As the large granite–gneiss bodies rose, solid-state extensional D1 shears developed around the granites with a radial pattern of L1 extension lineations. Areas of compression developed within the sinking greenstone sequences. A final phase of subsidence in the central parts of the greenstone belts produced depocentres (late basins). A shift from dominantly vertical tectonics to horizontal tectonics at ca 2655–2650 Ma is marked by the onset of east–west D2 compression and the change in granite compositions from high-Ca to low-Ca granites. Older ca 2800 Ma mafic–ultramafic sequences are conformably overlain by ca 2720–2670 Ma sequences suggesting minimal early deformation in the EGT. The first significant angular unconformities are at the base of the ca 2665 Ma late basin sequences. Late basin sequences record the uplift and exhumation of granite-cored domes and sedimentation is contemporaneous with the regional ca 2672–2660 Ma D1 event. The D1 event represents granite-up, greenstone-down tectonics (D1 event) that developed as a result of gravitational instability arising from autochthonous crustal thickening from ca 2720–2670 Ma. Granite-up, greenstone-down tectonics precludes an accretionary model for the development of the EGT. [ABSTRACT FROM AUTHOR]

In this article, we present the textural, mineralogical, and geochemical studies of a suite of volcanic rocks and their economic mineral potential from the Kadiri Volcanic Province (KVP) – a greenstone belt in the Eastern Dharwar Craton (EDC) of southern peninsular India. The volcanic rocks are represented by primary pyroclastic deposits dominated by tuff breccia, minor lapilli tuff, and pyroclastic flows together with lava flows, namely, metabasalts, andesites, dacites, and rhyolites. Metabasalts and high‐Mg andesites in the KVP are associated with sporadic occurrences of disseminated‐type gold. The ancient works on gold are confined to the ductile‐brittle shear zones in en‐echelon pattern. The source of gold is likely to be from deep fractures (>200 km) at mantle depths that paved the magma to move upper crustal levels due to partial melting of peridotites which tapped the siderophile elements (Au–Ag) from deeper source. Some andesites and dacites contain atomic minerals [uranium, thorium, and rare earth element (REE)], which requires attention in future studies. Monazite occurring in such dacites is a major source of REE such as cerium (Ce), lanthanum (La), neodymium (Nd), and Yttrium (Y), contributing 50–60% of REEs. Presence of thorite (ThSiO4) in dacite, a metamict mineral, strongly radioactive containing upto 10% uranium (U). This study confirms multi‐metal mineralization in KVP, for example, gold, silver, atomic (U and Th), rare‐earths along with base metals. Emplacements of rhyolite and alkali granite appears to be synchronous with the major thermal event at 2.51 Ga of the Dharwar Craton. The diverse volcanic associations are formed in a subduction–accretion orogeny at ~2.7 Ga, coeval with the global accretion event and gold mineralization. Au–U–Th–REE abundances in the composite arc‐back arc system of Kolar‐Hutti‐Kadiri‐Jonnagiri greenstone belts of EDC are primarily attributed to devolatilization and melting of subducted oceanic slab, fluid‐fluxed metasomatism of mantle wedge and elemental cycling associated with different stages of subduction. [ABSTRACT FROM AUTHOR]

A new 3D crustal-scale model has been created for the Kautokeino Greenstone Belt (KKGB) in northern Norway based on 3D density modelling and aeromagnetic data, integrated with qualitative interpretation of geophysical and geological data. Detailed geophysical analyses and their integration with an existing petrophysical database allowed us to identify and interconnect shallow and deeper structures throughout the study area. To have better control on the regional tectonic setting of the KKGB, the model area has been extended to include the northern part of Finland and Sweden. The new 3D density model reveals that the KKGB is broader than supposed previously. The 3D analysis indicates that the belt reaches depths of approximately 5-6 km and is emplaced as a highly deformed structure between the Archaean Jergul Gneiss Complex (JGC) to the east and the Rommaeno Gneiss Complex (RoGC) in Finland to the west. The Raiseatnu Gneiss Complex (RaGC) in the western part of the KKGB is characterised by a dominant NNW-SSE magnetic trend that is sub-parallel to the main trend of the KKGB. Moreover, the RaGC is similar to the KKGB in terms of the presence of a large number of sub-parallel magnetic anomalies. This gneiss complex shows mostly short-wavelength anomalies and some circular anomalies that differ from the more subdued and irregular anomaly pattern of the JGC and RoGC. In the new 3D model, the RaGC is assumed to constitute a migmatised part of the Kautokeino Greenstone Belt. At a large scale, this Proterozoic greenstone belt has some similarities to Archaean counterparts, where most of the deformation is caused by gravitational tectonics. This study shows that careful integration of geological and geophysical data can strongly improve the 3D understanding of the complex, poorly exposed, Precambrian terranes of the Finnmarksvidda region in Norway. [ABSTRACT FROM AUTHOR]

The Bailadila Group of the Bastar Craton, India, is host to a 200-m-thick banded iron formation (BIF). We document the lithostratigraphic context for the BIF, informally referred to as the Bose iron formation, and provide radiometric constraints for its depositional age. Field evidence illustrates that the BIF was deposited on an inner-shelf succession with a quartz arenite that grades upward into the BIF through storm-dominated offshore shelf deposits. The quartz arenite to BIF transition records a relative sea level rise from transgressive to highstand systems tract when the BIFs were deposited in a starved outer continental shelf. U-Pb SHRIMP analyses of zircons from the basement of the Bailadila Group yielded mostly highly discordant U-Pb SHRIMP ages. However, the ages fall on well-defined discordia lines from which concordia intercept ages could be determined. These ages, in combination with the ages of a few zircons that are less than 6% discordant, indicate that the granitoid basement crystallized at 3500–3550 Ma. The maximum depositional age of the Bailadila Group is constrained from the weighted mean 207Pb/206Pb SHRIMP age of 2725 ± 57 Ma from detrital zircons from the basal arenites. A well-constrained weighted mean 207Pb/206Pb SHRIMP age of 2733 ± 53 Ma for zircons from a unit that unconformably overlies the Bailadila Group is within error of that age. Stratigraphic relationships suggest that the Bailadila succession is unconformably overlain by the ~2.5 Ga Kotri and Dongargarh Supergroups. The depositional age of the Bailadila Group is well constrained between ~2.7 and 2.5 Ga. In contrast to most other Archean Algoma-type iron formations of peninsular India, which are closely related to volcanic rocks in greenstone belts, the Bose iron formation is associated with siliciclastic shelf succession. It thus is considered a Superior-type iron formation that represents the oldest known one of its kind in India. [ABSTRACT FROM AUTHOR]

Most Archean orogenic gold deposits are associated with major faults such as the Larder Lake-Cadillac fault zone (LLCFZ) in the Superior craton and are hosted in or adjacent to second-order structures as quartz vein systems. Microstructures induced by quartz deformation in these faults or shear zones, such as typical textures of recovery and dynamic recrystallization, give indication of the P-T conditions during deformation. Electron backscatter diffraction (EBSD) analysis of grain lattice orientation and grain size determination, for flow stress calculation, are commonly performed on mylonite or quartzite samples from shear zones. This study tests the validity of such methods on hydrothermal auriferous quartz veins to better constrain the conditions of quartz vein deformation in the vicinity of the LLCFZ and evaluate the effect of depth and local variations on the microstructures and flow stress. Samples were collected in 24 gold deposits and showings along the LLCFZ. The microstructural observations and EBSD analysis allowed the distinction of six microstructural types within the studied samples. Samples analyzed with EBSD display a log-normal distribution of recrystallized grain sizes that is consistent with data for natural samples. The calculated flow stress is highly variable between samples and ranges from 38.2 + 5.1/-6.1 to 74.5 + 2.2/-3.0 MPa in surface samples only. Quartz recrystallization overprints primary textures in all but one samples, which indicates that recrystallization and its associated deformation occurred after the complete crystallization of the veins. Samples with bimodal distribution of recrystallized quartz grain sizes highlight the potential of quartz veins to record several deformation events. Samples are recrystallized at higher temperature and lower stress in the east than in the west of the LLCFZ, which could indicate the exposure of a deeper crust in the east. These data underline the potential of quartz vein microstructures to contribute to the evaluation and evolution of deformation conditions of auriferous quartz vein in an orogenic context. • Archean orogenic gold quartz veins from the southern Abitibi greenstone belt are overprinted by dynamic recrystallization. • Flow stress calculated from recrystallized grain size ranges from 21.2 + 4.9/-5.4 MPa to 103 + 3/-2 MPa. • Microstructural and EBSD analyses allowed to decipher at least two deformation events for some hydrothermal gold quartz veins. • DRX microstructures indicate a deeper crustal level in the eastern part of the Larder Lake-Cadillac fault zone. [ABSTRACT FROM AUTHOR]

The granitoid magmatism in the Chitradurga greenstone belt implies crustal reworking in the western Dharwar Craton during the Neoarchean. High-K granites and low-K trondhjemites are studied for their petrogenesis using the whole-rock elemental and Nd isotopic composition and compared with the earlier works. These granitoids were formed by partial reworking of older crust, which includes TTG gneisses and metabasites. Low Sr/Y ratios (0.1–7.6) and zircon saturation temperatures (< 850 °C) suggest that crustal anatexis occurred at the shallower crustal levels by low-T fluid-present melting. Phase equilibrium and trace element modelling show that the potassic granites were formed by partial melting of TTG gneisses at shallower depths corresponding to 4–6 kb pressures and melt extraction in batches leaving a final residue comprising ∼66% plagioclase, ∼ 30% quartz, ∼ 3% orthopyroxene, and ∼ 1% ilmenite. Monzogranite was formed from the melt extracted at a higher temperature with some entrained minerals, whereas the early batches of water saturated melt modified by fractional crystallization during the ascent formed syenogranites. The low-K trondhjemites were formed by 10–12% partial melting of metabasites at 4–5 kb pressures, leaving residual assemblages with plagioclase (42–46%), amphibole (24–26%), orthopyroxene (20–21%), ilmenite (4–5%), and garnet (2–9%). The partial melting of various crustal source rocks at different crustal levels indicates a reworking event in the terrane, which was likely triggered by mafic underplating and H 2 O dominated fluid flux. [Display omitted] • 2.6 Ga granitoids represent a crustal reworking event in the western Dharwar Craton. • High-K granite derived from TTG gneisses by partial melting. • Low-K trondhjemites derived from metabasites by partial melting. • Granite magma experienced fractional crystallization. • Phase equilibrium modelling combined with trace elements explains granitoid origin. [ABSTRACT FROM AUTHOR]

• Analysis of four new volcano-sedimentary complexes (VSC) in the Pilbara increasing insight in Paleoarchean basin settings. • Multistorey architecture of the 3.5 Ma Coonterunah Subgroup, with a megaslide (new Bergamina Unit) as upper storey. • Recognition of the east-west Warrawoona Lineament as a D1 structure dividing two areas of basin superposition. • Comparison of VSC's of the Pilbara with the Buck Reef-VSC of the South African Barberton greenstone belt. • Introduction of a proxy for Paleoarchean basin depth by comparing VSC-architecture with Phanerozoic passive margins. Four new volcano-sedimentary complexes (VSC's), respectively c. 3510, 3460, 3430, and 3320 Ma old, are identified in the East Strelley, Coongan, and Kelly belts of the East Pilbara craton and compared with the extraordinarily complete c. 3450 Ma Buck Reef-VSC in the southern African Kaapvaal craton. The VSC's reveal an intricate relationship between volcanic deposition, sedimentation, development of syndepositional fault arrays, both extensional and contractional, and magmatism. The geometry and kinematics of these fault systems were analyzed after restoring the tilt of the stratigraphic sequences back to the depositional horizontal. The growth fault arrays are interpreted to have been generated by lack of lateral support of depositional basin margin prisms as known from present-day deltas and passive margins. This 'basin margin collapse' scenario for deformation and kinematics of the topmost section of the crust relies on topographic relief combined with vertical crustal oscillation. The relationship between supracrustal collapse and coeval deformation on deeper-seated detachments within the basement of the Pilbara remains as yet unsolved. The restoration corroborates the (semi-)circular basin architecture we proposed in 2017, which preceded, and is unrelated to, the present-day configuration of granitoid complexes and greenstone belts. The new findings also assess an early, syndepositional presence of the east–west Warrawoona Lineament as a major dividing line of as yet unknown structural character between two areas of basin superposition. For the Coonterunah Subgroup a multistorey architecture is established: the Table Top/Coucal-VSC with its near-water level chert top is overlain by regularly bedded Double Bar Basalt. The ensemble is truncated by the newly introduced tectono-stratigraphic Bergamina Unit, interpreted as a mega-avalanche emplaced somewhere between 3496 and 3466 Ma, possibly time-equivalent to the Duffer Fm. The crustal depths of the detachments below the (water-level) tops of all VSC's identified, in other words the thicknesses of the VSC's, are used as proxy for determining minimum basin centre depths ranging from 1000 to 3800 m. The greatest depth was reached in the North and South Coongan Basins, where voluminous bimodal volcanism of the Duffer Fm, maximum subsidence and deposition rates resulted in maximum basin margin instability. [ABSTRACT FROM AUTHOR]

• New geochronological data bracket the age of the volcano-sedimentary Karasjok Greenstone Belt between 2.47 Ga and 1.96 Ga. • The 2.47 Ga Vuomegielas Formation is the oldest unit in the Karasjok Greenstone Belt and were deposited in a intracratonic rift setting, likely as a part of the Matachewan (LIP) plume event. • The Gollebáiki Formation hosts mid-Jatulian (c. 2.22–2.15 Ga) mafic intrusions and tholeiitic basalts, corresponding to another rifting event in a shallow-marine environment on the Fennoscandian Shield. • The uppermost Báhkilvárre Formation contains flood basalts, komatiites, and andesitic lavas extruded at c. 1.98–1.96 Ga. • Carbon isotope data for marine carbonates of the Skuvanvárri and Gollebáiki formations are elevated with δ13 C values from + 3.7 to + 12.4 ‰, indicating their deposition during the c. 2.22–2.06 Ga Lomagundi Carbon Isotope Excursion. New geochronological data for the amphibolite-facies volcano-sedimentary Karasjok Greenstone Belt in northwestern Fennoscandia bracket its age between 2.47 and 1.96 Ga. The volcano-sedimentary units were deposited on the 3005 ± 24 to 2776 ± 69 Ma crystalline basement rocks of the Jergul Gneiss Complex. The lowermost Vuomegielas Formation contains rhyodacites dated at 2469 ± 12 Ma that were deposited in an intracratonic rift setting related to the Matachewan mantle plume event. The overlying Skuvanvárri Formation, correlative with the early Jatulian (c. 2.2 Ga) units on the Fennoscandian Shield, consists of siliciclastic sedimentary rocks deposited in coastal deltaic and shallow-marine settings. The overlying mid-Jatulian Gollebáiki Formation contains 2151 ± 5 Ma mafic intrusions and tholeiitic basalts related to a rifting event and breakup of the Superia supercraton that resulted in voluminous volcanic and shallow-marine deposits. The Ni-Cu-PGE-mineralized Porsvann intrusion, hosted by the Gollebáiki Formation, yielded an age of 2056 ± 10 Ma, which corresponds with other Ni-Cu-PGE-bearing intrusions on the Fennoscandian Shield. The uppermost Báhkilvárre Formation consists of basalts, komatiites, and andesitic lavas. A synvolcanic gabbro within the komatiites in the lower part of the formation yielded an age of 1984 ± 16 Ma. Andesites in the upper part of the same formation were dated at 1961 ± 1 Ma. They represent the final Paleoproterozoic magmatic event that affected large areas of the Fennoscandian Shield prior to the Lapland-Kola and Svecofennian orogenies. Carbon isotope values for carbonates of the Skuvanvárri and Gollebáiki formations range up to highly positive (+12.4 ‰) values, corresponding to the c. 2.22–2.06 Ga Lomagundi carbon isotope excursion. In contrast, carbonates from the Báhkilvárre Formation do not yield elevated δ 13C values, indicating that it was deposited in the aftermath of the Lomagundi carbon isotope excursion. New geochronologic and chemostratigraphic data for the Karasjok Greenstone Belt support correlation with the early Paleoproterozoic sedimentary successions deposited on the eastern margin of the Superior craton and position the northern-northwestern margin of the Karelia-Kola craton against the eastern margin of the Superior craton between c. 2.5 and 2.05 Ga. [ABSTRACT FROM AUTHOR]