Abstract Over 300 matrix and fracture acidizing treatments, utilizing a thermally stable acid gelling agent, were performed in carbonate formations, worldwide. The initial results of several treatments were presented earlier (Ref. 1). Since then, trends toward sustained increases in production have been documented and are presented. Reductions in production decline rates have resulted in improved recovery of reserves. Improved live acid penetration results from the effects of stable viscosity, retarded reaction rate and proper treatment design. In addition, the gelling agent must be non-damaging, requiring tolerance to calcium and magnesium ions in the spent acid during cleanup. A gelling agent is described that provides the features of thermal stability and solubility in the live and spent acid. Introduction Commercial utilization of hydrochloric acid for stimulating oil and gas production from carbonate reservoirs began in the early 1930's. The beauty of using acid in treating carbonates lies in it's utter simplicity. Injected at matrix rates, significant amounts of new permeability are generated, thus removing the effects of formation damage near the wellbore. Under fracturing conditions, substantial fracture conductivity is created through the dissolution of the fracture face. This apparent simplicity, however, belies a complexity of interrelated and interdependent factors that determine the success of it's application. During the past fifty six years, much of the technological developments in acidizing have focused on the understanding of the processes limiting treatment results, and on methods and materials that could be used to overcome these limitations. In particular, recent years have seen the development of viscosifiers for acid, which are intended to impart characteristics that, if present, would enhance treatment results by increasing live acid penetration. Many of these materials have been used with only limited success, due to their inherent instability in live or spent acid, or incompatibility with common additives and contaminants. In 1983, a polymer was introduced, which provides the desired characteristics of stable viscosity, acid retardation and compatibility with most of the common acid additives. It has since been successfully applied in more than 300 matrix and fracture acidizing treatments. This paper provides a description of this gelling agent and details of several case histories. Discussion A synthetic polymer has been developed for use as a viscosifying agent for hydrochloric acid, tested under extremes of field conditions and found to be successful in enhancing the results of carbonate acidizing treatments. This material (Polymer A) was originally developed as a thermally stable viscosifier for brine solutions containing calcium and magnesium ions. It's composition is designed to resist thermal degradation and hydrolysis at high temperatures. Early in it's development, it was recognized that Polymer A also resisted acid hydrolysis and could be effectively employed as an acid gelling agent. Polymer A is readily soluble in hydrochloric acid, and develops viscosity rapidly. Figure 1 illustrates the relationship between the polymer concentration and fluid viscosity. As would be expected, the relationship is non-linear, with viscosity increasing rapidly at the higher polymer concentrations. Polymer A is effective in all commonly used hydrochloric acid systems, and the viscosity is independent of acid concentration. It's resistance to thermal degradation and acid hydrolysis provides stable viscosity and continued solubility at elevated temperatures. P. 259^