203 results on '"Changjiang Zhou"'
Search Results
102. Heavy-Atom Effect Promotes Multi-Resonance Thermally Activated Delayed Fluorescence
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Chuluo Yang, Cheng Zhong, Changjiang Zhou, Shaolong Gong, Zhengqi Xiao, Xiaosong Cao, Zhongyan Huang, Nengquan Li, Lisi Zhan, and Tao Hua
- Abstract
As one type of latest emitters with simultaneous high efficiency and color-purity, the development of multi-resonance thermally activated delayed fluorescence (MR-TADF) materials represents an important advancement for organic light-emitting diodes (OLEDs). We herein present a new strategy to improve the performance of MR-TADF emitters by fusing sulfur element into the B-N based framework, aiming to utilize the non-metal heavy-atom effect in accelerating the reverse intersystem crossing (RISC) process of the emitter. Two compounds, namely 2PTZBN and 2PXZBN, were developed in this work through rigidifying the DABNA-1 skeleton by sulfur or oxygen atoms. The theoretical calculations and photoluminescence studies revealed that the sulfur-incorporated 2PTZBN enabled considerable rate constant of RISC (kRISC) up to 2.8 × 105 s-1 in toluene due to larger spin-orbital coupling (SOC) values and smaller singlet-triplet energy splitting (ΔEST) compared with 2PXZBN. Consequently, organic light-emitting diodes based on 2PTZBN exhibited highly efficient green emission with maximum external quantum efficiency (EQE) of 25.5%.
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- 2021
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103. Solution-Processed OLEDs Based on Thermally Activated Delayed Fluorescence Copper(I) Complexes with Intraligand Charge-Transfer Excited State
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Changjiang Zhou, Kai Li, Teng Teng, Jinfan Xiong, Xialei Lv, and Gang Cheng
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TADF ,Photoluminescence ,Materials science ,Pharmaceutical Science ,chemistry.chemical_element ,Electroluminescence ,intraligand charge-transfer ,Photochemistry ,Ligands ,Article ,Analytical Chemistry ,lcsh:QD241-441 ,lcsh:Organic chemistry ,Coordination Complexes ,Drug Discovery ,OLED ,Physical and Theoretical Chemistry ,Fluorescent Dyes ,Cu(I) complexes ,solution process ,Molecular Structure ,Organic Chemistry ,Temperature ,Fluorescence ,Copper ,Solutions ,chemistry ,Chemistry (miscellaneous) ,Excited state ,Molecular Medicine ,Quantum Theory ,Quantum efficiency ,Density functional theory - Abstract
A new series of tetrahedral heteroleptic copper(I) complexes exhibiting efficient thermally-activated delayed fluorescence (TADF) in green to orange electromagnetic spectral regions has been developed by using D-A type N^N ligand and P^P ligands. Their structures, electrochemical, photophysical, and electroluminescence properties have been characterized. The complexes exhibit high photoluminescence quantum yields (PLQYs) of up to 0.71 at room temperature in doped film and the lifetimes are in a wide range of 4.3–24.1 μs. Density functional theory (DFT) calculations on the complexes reveal the lowest-lying intraligand charge-transfer excited states that are localized on the N^N ligands. Solution-processed organic light emitting diodes (OLEDs) based on one of the new emitters show a maximum external quantum efficiency (EQE) of 7.96%.
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- 2021
104. An Integrated Digital Pathology Platform for Tumors Using Artificial Intelligence Analysis
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Changjiang Zhou, Xiaobing Feng, Hongbin Cai, Yi Jin, Harvest F. Gu, Youcai Zhao, Xiaodong Teng, Lingchuan Guo, Jiatong Ji, Shuopeng Jia, Yan Xing, Xiangshan Fan, and Jun Liao
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History ,Polymers and Plastics ,Business and International Management ,Industrial and Manufacturing Engineering - Published
- 2021
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105. Modulating LUMO extension of Spiro-junction TADF emitters for efficient OLEDs with relieved efficiency Roll-Off
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Ranran Pei, Jingli Lou, Ganggang Li, He Liu, Xiaojun Yin, Changjiang Zhou, Zhiming Wang, and Chuluo Yang
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General Chemical Engineering ,Environmental Chemistry ,General Chemistry ,Industrial and Manufacturing Engineering - Published
- 2022
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106. Cis‐Trans Isomerism Inducing Cocrystal Polymorphism with Thermally Activated Delayed Fluorescence and Two‐Photon Absorption
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Xiangyu Zhang, Jianbo De, Haichao Liu, Qing Liao, Shi‐Tong Zhang, Changjiang Zhou, Hongbing Fu, and Bing Yang
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Atomic and Molecular Physics, and Optics ,Electronic, Optical and Magnetic Materials - Published
- 2022
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107. High-efficiency and low roll-off deep-blue OLEDs enabled by thermally activated delayed fluorescence emitter with preferred horizontal dipole orientation
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Chuluo Yang, Yu-Chun Liu, Nengquan Li, Chung-Chih Wu, Zhongyan Huang, Tao Hua, Chih-Wei Huang, Xiaosong Cao, and Changjiang Zhou
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Photoluminescence ,Materials science ,Quenching (fluorescence) ,business.industry ,General Chemical Engineering ,Exciton ,Doping ,General Chemistry ,Acceptor ,Industrial and Manufacturing Engineering ,Full width at half maximum ,OLED ,Environmental Chemistry ,Optoelectronics ,Quantum efficiency ,business - Abstract
Highly efficient blue thermally activated delayed fluorescence (TADF) materials with high horizontal dipole orientation (Θ//) remain a big challenge due to the concentration quenching effects and serious efficiency roll-offs in their corresponding organic light-emitting diodes (OLEDs). We herein report two novel TADF compounds, namely 2TDBA-SBA and TDBA-SBA, which were facilely synthesized by utilizing a rigid oxygen-bridged cyclized triarylboron-based unit (TDBA) as the acceptor and a spiro acridine (SBA) as the donor. Benefiting from the rigid and planar skeleton of the acceptor and the linear molecular shape, high Θ//s and photoluminescence quantum yields (PLQYs) of ∼ 90% were achieved. Significantly, TDBA-SBA exhibited excellent TADF properties with a short delayed fluorescence lifetime of only 684 ns and narrow full-width at half-maximum (FWHM) of 44 nm in solution state, accompanied by the high PLQYs of over 80% at high doping concentrations, manifesting the alleviated exciton quenching effects. Consequently, OLEDs based on TDBA-SBA achieved a high maximum external quantum efficiency (EQE) of 29.3% and a maximum brightness of 27663 cd cm−2. Importantly, an EQE over 20% was realized even at the high brightness of 10000 cd cm−2, signifying a small efficiency roll-off.
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- 2022
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108. Simple Acridan-Based Multi-Resonance Structures Enable Highly-Efficient Narrowband Green TADF Electroluminescence
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Changjiang Zhou, Xialei Lv, Pengcheng Jiang, Chuluo Yang, Zhongyan Huang, Shaolong Gong, Yang Zou, Xiaosong Cao, Lisi Zhan, and Fan Ni
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Materials science ,Narrowband ,Quenching (fluorescence) ,business.industry ,Bathochromic shift ,OLED ,Optoelectronics ,Quantum efficiency ,Electroluminescence ,Luminescence ,business ,Fluorescence - Abstract
Multi-resonance thermally activated delayed fluorescence (MR-TADF) offered exceptional solution for narrowband organic light emitting diode (OLED) devices in terms of color purity and luminescence efficiency, while the development of new MR skeleton remained an exigent task, especially for long wavelength region. We hereby demonstrate that a simple modification of the B (boron)-N (nitrogen) framework by sp3 -carbon insertion would significant bathochromic shift the short-range chargetransfer emission and improve the device performances. The bis(acridan)phenylenebased skeleton developed in this contribution presented a non-planar conformation and allowed facile introduction of isolating units to prevent triplet-involved quenching, deriving two luminophores with quantum yields approaching 90% and narrow FWMHs below 30 nm in film state. Corresponding green-emissive devices realized superior performances comparing to the planar carbazolyl-based MR-TADF analogues, with a maximum external quantum efficiency (EQEmax) up to 28.2% and small efficiency rolloff without the involvement of any sensitizing host
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- 2020
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109. A Modified Wear Model Considering Contact Temperature for Spur Gears in Mixed Elastohydrodynamic Lubrication
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Changjiang Zhou, Mingcai Xing, Zhaoyao Shi, and Bo Hu
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Materials science ,Mechanical Engineering ,Bulk temperature ,Angular velocity ,02 engineering and technology ,Surfaces and Interfaces ,021001 nanoscience & nanotechnology ,Surfaces, Coatings and Films ,Pressure angle ,020303 mechanical engineering & transports ,0203 mechanical engineering ,Mechanics of Materials ,Flash (manufacturing) ,Tooth wear ,Lubrication ,Surface roughness ,Torque ,Composite material ,0210 nano-technology - Abstract
In this study, a modified wear model considering contact temperature for spur gears in mixed elastohydrodynamic lubrication (EHL) is proposed. The contact temperature consists of bulk temperature and flash temperature. The bulk temperature is determined by the thermal network model, whereas the flash temperature is estimated through the published method. The bulk temperature, which was rarely included in the previous works, substantially has a considerable influence on the tooth wear in mixed EHL. It is also found that the lower contact temperature contributes to the reduction of gear wear depth. Furthermore, the effects of gear basic geometrical parameter and operating parameter on wear depth are investigated. The results show that the wear depth decreases with the increased tooth width, module, pressure angle and rotational velocity but increases with the surface roughness and torque. It indicates that wear resistance of tooth surfaces can be enhanced by optimising the design parameters of gear drives.
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- 2020
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110. Lighting Silver(I) Complexes for Solution-Processed Organic Light-Emitting Diodes and Biological Applications via Thermally Activated Delayed Fluorescence
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Jinfan Xiong, Kai Li, Taotao Zou, Chao Wu, Chuluo Yang, Gang Cheng, Hong-Xing Zhang, Yuan Wang, Jiafang Li, Teng Teng, He Liu, Jian Wang, Changjiang Zhou, and Chi-Ming Che
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Models, Molecular ,Photoluminescence ,Silver ,Light ,Molecular Conformation ,chemistry.chemical_element ,Electroluminescence ,Diamines ,010402 general chemistry ,Photochemistry ,Ligands ,01 natural sciences ,Fluorescence ,Inorganic Chemistry ,Transition metal ,Coordination Complexes ,OLED ,Iridium ,Physical and Theoretical Chemistry ,010405 organic chemistry ,Temperature ,0104 chemical sciences ,Ruthenium ,Solutions ,chemistry ,Semiconductors ,Quantum Theory ,Luminescence - Abstract
Luminescent coinage metal complexes have shown promising applications as electroluminescent emitters, photocatalysts/photosensitizers, and bioimaging/theranostic agents, rendering them attractive alternatives to transition metal complexes based on iridium, ruthenium, and platinum that have extremely low earth abundance. In comparison to the widely studied Au(I) and Cu(I) complexes, Ag(I) complexes have seldom been explored in this field because of their inferior emission properties. Herein, we report a novel series of [Ag(N^N)(P^P)]PF6 complexes exhibiting highly efficient thermally activated delayed fluorescence by using easily accessible neutral diamine ligands and commercially available ancillary diphosphine chelates. The photoluminescence quantum yields (PLQYs) of the Ag(I) emitters are ≤0.62 in doped films. The high PLQY with a large delayed fluorescence ratio enabled the fabrication of solution-processed organic light-emitting diodes (OLEDs) with a high maximum external quantum efficiency of 8.76%, among the highest values for Ag(I) emitter-based OLEDs. With superior emission properties and an excited state lifetime in the microsecond regime, together with its potent cytotoxicity, the selected Ag(I) complex has been used for simultaneous cell imaging and anticancer treatment in human liver carcinoma HepG2 cells, revealing the potential of luminescent Ag(I) complexes for biological applications such as theranostics.
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- 2020
111. Histopathology classification and localization of colorectal cancer using global labels by weakly supervised deep learning
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Changjiang Zhou, Yu-Hong Wang, Yi Jin, Shan Huang, Jun Liao, Yuzong Chen, Rengpeng Huang, Yao Chen, Lingchuan Guo, and Youcai Zhao
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Cancer classification ,Colorectal cancer ,Computer science ,Health Informatics ,030218 nuclear medicine & medical imaging ,03 medical and health sciences ,0302 clinical medicine ,Deep Learning ,Cancer genome ,medicine ,Image Processing, Computer-Assisted ,Humans ,Radiology, Nuclear Medicine and imaging ,Radiological and Ultrasound Technology ,business.industry ,Deep learning ,Pattern recognition ,medicine.disease ,Computer Graphics and Computer-Aided Design ,Manual annotation ,Clinical diagnosis ,Computer Vision and Pattern Recognition ,Artificial intelligence ,Feature combination ,business ,Colorectal Neoplasms ,030217 neurology & neurosurgery - Abstract
Colorectal cancer (CRC) is the second leading cause of cancer-related mortality worldwide. In coping with it, histopathology image analysis (HIA) provides key information for clinical diagnosis of CRC. Nowadays, the deep learning methods are widely used in improving cancer classification and localization of tumor-regions in HIA. However, these efforts are both time-consuming and labor-intensive due to the manual annotation of tumor-regions in the whole slide images (WSIs). Furthermore, classical deep learning methods to analyze thousands of patches extracted from WSIs may cause loss of integrated information of image. Herein, a novel method was developed, which used only global labels to achieve WSI classification and localization of carcinoma by combining features from different magnifications of WSIs. The model was trained and tested using 1346 colorectal cancer WSIs from the Cancer Genome Atlas (TCGA). Our method classified colorectal cancer with an accuracy of 94.6 %, which slightly outperforms most of the existing methods. Its cancerous-location probability maps were in good agreement with annotations from three individual expert pathologists. Independent tests on 50 newly-collected colorectal cancer WSIs from hospitals produced 92.0 % accuracy and cancerous-location probability maps were in good agreement with the three pathologists. The results thereby demonstrated that the method sufficiently achieved WSI classification and localization utilizing only global labels. This weakly supervised deep learning method is effective in time and cost, as it delivered a better performance in comparison with the state-of-the-art methods.
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- 2020
112. Segment selection of cultural noise recordings in urban environment to improve quality of surface-wave image
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Jianghai Xia, Ling Ning, Jingyin Pang, Hongyu Zhang, Chaoqiang Xi, Changjiang Zhou, Ya Liu, Tianyu Dai, and Feng Cheng
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Noise ,Surface wave ,business.industry ,media_common.quotation_subject ,Computer vision ,Quality (business) ,Artificial intelligence ,business ,Selection (genetic algorithm) ,Urban environment ,Geology ,media_common ,Image (mathematics) - Published
- 2020
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113. A simple and effective strategy to lock the quasi-equatorial conformation of acridine by H-H repulsion for highly efficient thermally activated delayed fluorescence emitters
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Yang Zou, Xiaoxuan Su, Chuluo Yang, Xuan Zeng, Danyang Chai, Cheng Zhong, Changjiang Zhou, and Shaolong Gong
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Steric effects ,Materials science ,Chemical substance ,Metals and Alloys ,Electron donor ,General Chemistry ,Photochemistry ,Fluorescence ,Catalysis ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,chemistry.chemical_compound ,chemistry ,Acridine ,Materials Chemistry ,Ceramics and Composites ,OLED ,Science, technology and society - Abstract
A novel electron donor, namely, TMDBP is designed by angularly fusing two acridine moieties. The DMAC subunits in TMDBP exhibit a dominant quasi-equatorial conformation due to steric H-H repulsion. The new TADF emitters render excellent OLED performances with EQE up to 24.2% and small efficiency roll-off.
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- 2020
114. Molecular Engineering Enables TADF Emitters Well Suitable for Non‐Doped OLEDs with External Quantum Efficiency of Nearly 30%
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Ziyang Xie, Chen Cao, Yang Zou, Xiaosong Cao, Changjiang Zhou, Jiawei He, Chun‐Sing Lee, and Chuluo Yang
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Biomaterials ,Electrochemistry ,Condensed Matter Physics ,Electronic, Optical and Magnetic Materials - Published
- 2022
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115. Chiral thermally activated delayed fluorescence emitters for circularly polarized luminescence and efficient deep blue OLEDs
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Zhongyan Huang, Chuluo Yang, Zhengqi Xiao, Tao Hua, Chih-Wei Huang, Changjiang Zhou, Nengquan Li, Yukun Tang, Xiaosong Cao, and Chung-Chih Wu
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Materials science ,Photoluminescence ,business.industry ,Process Chemistry and Technology ,General Chemical Engineering ,Doping ,Fluorescence ,OLED ,Optoelectronics ,Quantum efficiency ,Enantiomer ,business ,Deep blue ,Luminescence - Abstract
The development of the thermally activated delayed fluorescence (TADF) emitters with circularly polarized luminescence (CPL), particularly those exhibiting deep-blue emission is still a formidable challenge. In this work, we reported a simple and easily accessed molecular design strategy for deep-blue circularly polarized TADF (CP-TADF) enantiomers. Two chiral compounds, namely (S)-NPE-AcDPS and (R)-NPE-AcDPS, were successfully designed and synthesized, which featured concurrently TADF, CPL, and aggregation-induced enhanced emission (AIEE) properties. The CPL exhibited a maximum gPL value of 3.0 × 10−4. These emitters exhibited deep blue emission peaking at 451 nm in doped film with a high photoluminescence of 86% and a small singlet-triplet splitting of 0.05 eV. Furthermore, the deep blue OLED based on (S)-NPE-AcDPS demonstrated a high external quantum efficiency (EQE) up to 18.5%.
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- 2022
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116. Terminal velocity and drag coefficient models for disc-shaped particles based on the imaging experiment
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Changjiang Zhou, Jie Su, Haikang Chen, and Zhaoyao Shi
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General Chemical Engineering - Published
- 2022
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117. Ambient noise data selection based on the asymmetry of cross-correlation functions for near surface applications
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Jingyin Pang, Changjiang Zhou, Ya Liu, and Chaoqiang Xi
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Normalization (statistics) ,Data processing ,010504 meteorology & atmospheric sciences ,Cross-correlation ,Bidirectional traffic ,media_common.quotation_subject ,Ambient noise level ,Traffic noise ,010502 geochemistry & geophysics ,01 natural sciences ,Asymmetry ,Geophysics ,Surface wave ,Algorithm ,0105 earth and related environmental sciences ,media_common - Abstract
Passive surface wave methods utilizing traffic noise have been studied in recent years to estimate shear wave velocity in urban near-surface explorations. Suitable processing scheme is necessary for the emergence of coherent signal, and even to account for the azimuthal effects in acquired noise data. We propose a new ambient noise data selection technique based on the asymmetry of the cross-correlation functions to refine the quality of data processing in the complex city environment. The asymmetry coefficient is defined by the logarithmic energy ratio of the casual and acausal surface waves to measure the correlation asymmetry, and two kinds of symmetric functions are taken into account to establish the screening conditions. The underlying physics for the symmetries of the correlation functions are demonstrated to prove the feasibility of our algorithm. Two numerical tests suggest that the bidirectional inline sources are adequately highlighted, and the high velocity anomalies caused by the offline sources are eliminated by our method. Furthermore, the significances of the applications of time window and normalization are investigated to improve the reliability of the algorithm. We also apply the method to three-component field data acquired from the city pavement. The comparisons between the results of raw and selected data confirmed that the random noise and the artifacts can be effectively suppressed, and the dispersion energy trends emerge clearly and become more convergent toward the lower frequency. Finally, our method is concluded to be practical for urban bidirectional traffic noise.
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- 2018
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118. A novel prediction method for gear friction coefficients based on a computational inverse technique
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Bo Hu, Xuanlv Qian, Changjiang Zhou, and Xu Han
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0209 industrial biotechnology ,Mechanical Engineering ,Rolling resistance ,Mathematical analysis ,Inverse ,Rotational speed ,02 engineering and technology ,Surfaces and Interfaces ,Physics::Classical Physics ,Surfaces, Coatings and Films ,020303 mechanical engineering & transports ,020901 industrial engineering & automation ,Surrogate model ,0203 mechanical engineering ,Mechanics of Materials ,Convergence (routing) ,Lubrication ,Torque ,Radial basis function ,Mathematics - Abstract
A novel prediction method for gear friction coefficients with or without lubrication is developed with a computational inverse technique. A surrogate model is introduced to describe the mapping between the friction coefficients and root stresses, according to an adaptive radial basis function. The convergence criterion for solving the friction coefficients is determined based on the calculated and measured root stresses. A nonzero friction coefficient at the pitch point, which is closely relative to the action of rolling friction, is detected using the proposed method. Results show that the gear friction coefficients decrease with an increase in rotation speed or a decline in applied torque. Moreover, the friction coefficients without lubrication are more than twice those with lubrication.
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- 2018
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119. An adhesive wear prediction method for double helical gears based on enhanced coordinate transformation and generalized sliding distance model
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Hong-Bing Wang and Changjiang Zhou
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Materials science ,Normal force ,Plane (geometry) ,Mechanical Engineering ,Coordinate system ,Helix angle ,Bioengineering ,Geometry ,Wear coefficient ,02 engineering and technology ,021001 nanoscience & nanotechnology ,Curvature ,Computer Science Applications ,Contact force ,law.invention ,Computer Science::Hardware Architecture ,020303 mechanical engineering & transports ,0203 mechanical engineering ,Mechanics of Materials ,law ,Cartesian coordinate system ,0210 nano-technology ,human activities - Abstract
An adhesive wear prediction method for double helical gears is proposed according to enhanced coordinate transformation and generalized sliding distance model in conjunction with Archard's wear equation. To describe transient contact ellipse and identify the contact point pairs conveniently, a transform coordinate plane is set in coincidence with the plane of action and a coordinate axe parallels to the contact line. The contact pressure distribution is determined by contact line length, contact width and normal force, and a modified sliding distance model is proposed by generalized moving distance replacement of Hertz contact width. As the wear coefficient, contact pressure and sliding distance are given, the tooth wear depths are predicted by a developed numerical procedure. Effects of major geometrical and working parameters on the wear depth are investigated. The results show that the wear depth becomes smaller, which is mainly determined by the contact force per unit length, equivalent curvature radius and sliding distance as normal module, normal pressure angle, helix angle, tooth width or transmission ratio increases. However, the wear depth becomes larger when input torque is improved. It is indicated that rational parameters match in gear design and uniform wear distribution are beneficial for wear resistance.
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- 2018
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120. Stiffness and damping models for the oil film in line contact elastohydrodynamic lubrication and applications in the gear drive
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Changjiang Zhou and Zeliang Xiao
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Materials science ,Applied Mathematics ,Stiffness ,Rotational speed ,02 engineering and technology ,Mechanics ,Physics::Classical Physics ,021001 nanoscience & nanotechnology ,Curvature ,Contact force ,Physics::Fluid Dynamics ,Vibration ,Shear rate ,020303 mechanical engineering & transports ,0203 mechanical engineering ,Modeling and Simulation ,medicine ,Lubrication ,medicine.symptom ,Lubricant ,0210 nano-technology - Abstract
Innovative stiffness and damping models for oil films are developed to account for the impacts in both normal and tangential directions. Given that these models are applied to a gear drive in line contact elastohydrodynamic lubrication (EHL), the combined stiffness is derived from the stiffness of both the oil film and gear tooth while the combined damping is established from the damping of these parts. The effects of three fundamental parameters (contact force, rotation speed, and tooth numbers) of the gear drive in line contact EHL on the combined stiffness and damping are then investigated. The results reveal that the small normal and tangential stiffness of the lubricant can alleviate meshing impact and shear vibration, while the impact and friction heat can be reduced by using an oil film with either a large normal damping or small tangential damping. Given that its amplitude and fluctuation are closely related to shear rate, effective viscosity, entrainment velocity, and curvature radii, the improved combined stiffness and damping can be obtained by rationally matching the geometric and operating parameters.
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- 2018
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121. Transparent and soluble polyimide films containing 4,4′-isopropylidenedicyclohexanol (Cis -HBPA) units: Preparation, characterization, thermal, mechanical, and dielectric properties
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Daming Wang, Hongwei Zhou, Zhiming Mi, Chunbo Wang, Zhixiao Liu, Changjiang Zhou, Liu Yuhan, Chunhai Chen, Yumin Zhang, and Xiaogang Zhao
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Materials science ,Polymers and Plastics ,Organic Chemistry ,02 engineering and technology ,Dielectric ,010402 general chemistry ,021001 nanoscience & nanotechnology ,01 natural sciences ,0104 chemical sciences ,Characterization (materials science) ,Chemical engineering ,Thermal mechanical ,Materials Chemistry ,0210 nano-technology ,Polyimide - Published
- 2018
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122. Enhancing the Electroluminescent Efficiency of Acridine-Based Donor–Acceptor Materials: Quasi-Equivalent Hybridized Local and Charge-Transfer State
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Bing Yang, Changjiang Zhou, Yu Gao, Haichao Liu, Shitong Zhang, Dengli Cong, Jinyu Li, Qiaolin Wu, and Qing Su
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Photoluminescence ,Materials science ,Exciton ,02 engineering and technology ,Electroluminescence ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Photochemistry ,01 natural sciences ,Acceptor ,0104 chemical sciences ,Surfaces, Coatings and Films ,Electronic, Optical and Magnetic Materials ,chemistry.chemical_compound ,General Energy ,chemistry ,Excited state ,Acridine ,Physical and Theoretical Chemistry ,0210 nano-technology ,Luminescence ,Diode - Abstract
Excited-state properties (characteristics and composition) play a crucial role in luminescence properties of the new-generation organic light-emitting materials. As a special excited species, the hybridized local and charge-transfer (HLCT) state is composed of locally excited (LE) state and charge-transfer (CT) state, which can harvest simultaneous high photoluminescence (PL) efficiency and high exciton utilization in organic light-emitting diodes. In this work, we designed and synthesized three donor (D)–acceptor (A) compounds with different donor units and a typical electron-deficient unit acridine as the acceptor unit to investigate the different hybridization statuses among them. As is revealed by the molecular design, the three compounds precisely show the different hybridization statuses: LE-dominated hybridization (CZP-1AC), quasi-equivalent HLCT (qHLCT, TPA-1AC), and CT-dominated hybridization (PTZ-1AC). As a result, TPA-1AC exhibits the highest PL efficiency and multifold device performance, meri...
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- 2018
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123. Transparent and soluble polyimide films from 1,4:3,6-dianhydro-D-mannitol based dianhydride and diamines containing aromatic and semiaromatic units: Preparation, characterization, thermal and mechanical properties
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Chunhai Chen, Yumin Zhang, Zhixiao Liu, Hongwei Zhou, Changjiang Zhou, Xiaogang Zhao, Chunbo Wang, Daming Wang, Zhiming Mi, and Jianan Yao
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chemistry.chemical_classification ,Materials science ,Polymers and Plastics ,02 engineering and technology ,Dielectric ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,01 natural sciences ,0104 chemical sciences ,Characterization (materials science) ,Alicyclic compound ,chemistry.chemical_compound ,chemistry ,Mechanics of Materials ,Diamine ,Thermal ,Polymer chemistry ,Materials Chemistry ,Transmittance ,Solubility ,0210 nano-technology ,Polyimide - Abstract
To develop colorless and soluble polyimide films, a novel dianhydride containing 1,4:3,6-dianhydro-D-mannitol unit, 2,5-bis(3,4-dicarboxyphenoxy)-1,4:3,6-dianhydromannitol dianhydride (IMDA) was synthesized. And two series of polyimides were prepared via a two-step thermal imidization, PI−(1–4) were obtained from IMDA and four kinds of aromatic diamines while PI−(5–7) from IMDA and three kinds of semiaromatic diamines. All the polyimides were readily soluble in common polar solvents and could afford flexible, tough and colorless films with transparency up to 89% at 450 nm. Especially, polyimides simultaneously containing 1,4:3,6-dianhydrohexitol units in diamine and dianhydride exhibited comparable optical and soluble performance with the alicyclic fluorinated ones. Meanwhile, it was certified that 1,4:3,6-dianhydrohexitol fragment in dianhydride was more determinant in solubility and transmittance of polyimides than that in diamine. An overall investigation of these polyimides on thermal, mechanical, morphological, soluble, optical and dielectric properties was presented, and their structure-property relationships were discussed in detail.
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- 2018
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124. Coupling of the 2D microtopography of tooth surface and transmission error
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Siyu Chen, Zhonghua Wang, and Changjiang Zhou
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Coupling ,Power transmission ,Materials science ,Mechanical Engineering ,Acoustics ,Coordinate system ,Monte Carlo method ,Tooth surface ,02 engineering and technology ,021001 nanoscience & nanotechnology ,Gaussian filter ,Mechanism (engineering) ,symbols.namesake ,020303 mechanical engineering & transports ,0203 mechanical engineering ,Mechanics of Materials ,symbols ,0210 nano-technology ,Transmission errors - Abstract
This paper provides a method coupling the 2D microtopography filtered by ISO Gaussian filter of spur gears, which is typically used in power transmission devices, and Transmission error (TE) together. A gearbox with certain transmission ratio is selected as a research object for analysis. This gearbox comprises a mathematical model of TE calculation based on the Monte Carlo method and the coordinate transformation method, which couples the 2D microtopography of spur gears and TE. Two TE models are established to study their effects on the coupling results: a) The single TE model, which means only one gear owns TE, and b) the synthetic TE model, which means both gears possess TE. The new model of the 2D microtopography of tooth surfaces can be utilized further to investigate the mechanism of engagement and the approximate contact position of asperities on the tooth surface. The new model is also significant in studying the tooth root bending stress.
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- 2018
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125. A Multilocus Blood-Based Assay Targeting Circulating Tumor DNA Methylation Enables Early Detection and Early Relapse Prediction of Colorectal Cancer
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Renjie Wang, Li Liang, Bo-Qun Zhu, Changjiang Zhou, Wei Guo, Yuqiang Nie, Lingyu Han, Hui Wang, Chengcheng Ma, Xiaoliang Lan, Sanjun Cai, Wenqiang Xiang, Guoxiang Cai, Weixin Dai, Zhixi Su, Yingfei Li, Ping-Hong Zhou, Rui Liu, Beili Wang, Zhiqiang Feng, Binyang Luo, Ye Xu, Shaobo Mo, Ming-Yan Cai, and Lijing Zhang
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Adenoma ,Epigenomics ,Time Factors ,Colorectal cancer ,Early Relapse ,Early detection ,Pilot Projects ,Circulating Tumor DNA ,Epigenesis, Genetic ,Epigenome ,Text mining ,Predictive Value of Tests ,Biomarkers, Tumor ,medicine ,Humans ,Colectomy ,Early Detection of Cancer ,Neoplasm Staging ,Hepatology ,business.industry ,Gastroenterology ,Reproducibility of Results ,Methylation ,DNA Methylation ,medicine.disease ,Treatment Outcome ,Circulating tumor DNA ,Cancer research ,Neoplasm Recurrence, Local ,Colorectal Neoplasms ,business - Published
- 2021
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126. Heavy-atom effect promotes multi-resonance thermally activated delayed fluorescence
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Xiaosong Cao, Chuluo Yang, Tao Hua, Zhengqi Xiao, Zhongyan Huang, Cheng Zhong, Shaolong Gong, Nengquan Li, Changjiang Zhou, and Lisi Zhan
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Materials science ,Photoluminescence ,business.industry ,General Chemical Engineering ,Resonance ,General Chemistry ,Industrial and Manufacturing Engineering ,Intersystem crossing ,Atom ,OLED ,Environmental Chemistry ,Optoelectronics ,Quantum efficiency ,business ,Diode ,Common emitter - Abstract
As one type of latest emitters with simultaneous high efficiency and color-purity, the development of multi-resonance thermally activated delayed fluorescence (MR-TADF) materials represents an important advancement for organic light-emitting diodes (OLEDs). We herein present a new strategy to improve the performance of MR-TADF emitters by fusing sulfur element into the B-N based framework, aiming to utilize the non-metal heavy-atom effect in accelerating the reverse intersystem crossing (RISC) process of the emitter. Two compounds, namely 2PTZBN and 2PXZBN, were developed in this work through rigidifying the DABNA-1 skeleton by sulfur or oxygen atoms. The theoretical calculations and photoluminescence studies revealed that the sulfur-incorporated 2PTZBN enabled considerable rate constant of RISC (kRISC) up to 2.8 × 105 s-1 in toluene due to larger spin-orbital coupling (SOC) values and smaller singlet-triplet energy splitting (ΔEST) compared with 2PXZBN. Consequently, organic light-emitting diodes based on 2PTZBN exhibited highly efficient green emission with maximum external quantum efficiency (EQE) of 25.5%.
- Published
- 2021
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127. Wear life prediction method of crowned double helical gear drive in point contact mixed elastohydrodynamic lubrication
- Author
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Hongbing Wang, Changjiang Zhou, Zhaoyao Shi, and Lewei Tang
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Materials science ,business.product_category ,Work (physics) ,Mechanical engineering ,Rotational speed ,Surfaces and Interfaces ,Condensed Matter Physics ,Herringbone gear ,Surfaces, Coatings and Films ,Point contact ,Machining ,Mechanics of Materials ,Materials Chemistry ,Lubrication ,Surface roughness ,Torque ,business - Abstract
Double helical gears are widely applied in the aviation, marine and energy equipment, and generally required to be modified as the crowned since the machining error and assembling error of the gear drive are inevitable. The crowned gears usually operate in point contact mixed elastohydrodynamic lubrication (EHL), and adhesive wear has been one of the most prominent problems, but few previous researches were focused on this problem. In this work, a wear life prediction model of crowned double helical gears in point contact mixed EHL is proposed. The tooth profiles of the crowned gears are obtained according to the generating principle, and the load is attained in consideration of multi-tooth pairs contact. The contact pressure is derived from Hertzian elastic contact theory and load sharing concept, and the sliding distance is determined by a generalized model. Then, the wear rate in point contact mixed EHL is evaluated by extending the Archard theory to lubricated case, and the extended Archard's wear model is used to formulate the gear tooth wear. Moreover, the wear life prediction model which takes account of rotation speed and input torque is established, and the influences of surface roughness and crowned amount on the wear life of the crowned gears are further studied. Results show that surface roughness has a great influence on the wear life at different rotational speeds, while input torque has a great influence on the wear life at different crowned amount. It indicates that the wear life of the crowned double helical gears can be improved by reasonable matching lubrication, modification and working parameters.
- Published
- 2021
- Full Text
- View/download PDF
128. Side by Side Alignment of Donors Enabling High‐Efficiency TADF OLEDs with Insensitivity to Doping Concentration
- Author
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Zhiwen Liu, Chuluo Yang, Kai Li, Ganggang Li, Changjiang Zhou, He Liu, and Zhiming Wang
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Materials science ,business.industry ,Doping ,OLED ,Concentration quenching ,Optoelectronics ,business ,Atomic and Molecular Physics, and Optics ,Electronic, Optical and Magnetic Materials - Published
- 2021
- Full Text
- View/download PDF
129. Simple Acridan‐Based Multi‐Resonance Structures Enable Highly Efficient Narrowband Green TADF Electroluminescence
- Author
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Yang Zou, Zhongyan Huang, Changjiang Zhou, Pengcheng Jiang, Lisi Zhan, Fan Ni, Xialei Lv, Xiaosong Cao, Chuluo Yang, Zhanxiang Chen, and Shaolong Gong
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Materials science ,Narrowband ,business.industry ,Simple (abstract algebra) ,OLED ,Optoelectronics ,Electroluminescence ,business ,Atomic and Molecular Physics, and Optics ,Electronic, Optical and Magnetic Materials - Published
- 2021
- Full Text
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130. A novel contact model for rough surfaces using piecewise linear interpolation and its application in gear wear
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Hong-Bing Wang, Bo Hu, Changjiang Zhou, Haihang Wang, and Zhongming Liu
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Work (thermodynamics) ,Materials science ,Discretization ,02 engineering and technology ,Surfaces and Interfaces ,Mechanics ,Surface finish ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,Integral equation ,Surfaces, Coatings and Films ,Piecewise linear function ,Pressure angle ,020303 mechanical engineering & transports ,0203 mechanical engineering ,Mechanics of Materials ,Materials Chemistry ,Torque ,0210 nano-technology ,Linear equation - Abstract
Wear is directly related to rough surface contact, and the accuracy of a wear prediction model depends on the accurate determination of contact pressure. In this work, a numerical model with high computational accuracy for rough surface contact is developed and applied to the wear prediction of spur gears. To acquire contact pressure, the integral equation that contact pressure should satisfy is discretized into a set of linear equations by piecewise linear interpolating contact pressure. Then, a gear wear model including rough surface contact is established. The proposed contact model is verified by comparing with smooth and rough surface contact, and the wear depths of a spur gear drive with geometry and pressure updates are analyzed. Result shows that a small roughness value among contact surfaces may cause a large change in contact pressure. The effects of main design parameters on gear wear are subsequently investigated. Gear wear is found to decrease with increased module and pressure angle but increases with increased transmission ratio and input torque. These findings indicate that reasonable parameter matching is beneficial to improving gear wear resistance.
- Published
- 2021
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131. Non-Newtonian thermal elastohydrodynamic lubrication in point contact for a crowned herringbone gear drive
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Lijun Pan, Jing Xu, Xu Han, and Changjiang Zhou
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Materials science ,business.product_category ,Mechanical Engineering ,Thermal deformation ,02 engineering and technology ,Surfaces and Interfaces ,021001 nanoscience & nanotechnology ,Herringbone gear ,Non-Newtonian fluid ,Surfaces, Coatings and Films ,Pressure range ,Point contact ,020303 mechanical engineering & transports ,0203 mechanical engineering ,Mechanics of Materials ,Thermal ,Lubrication ,Shear stress ,Forensic engineering ,Composite material ,0210 nano-technology ,business - Abstract
Non-Newtonian thermal elastohydrodynamic lubrication (EHL) theory in point contact which deals with the lubrication for a crowned herringbone gear drive is developed, combined with the verified numerical procedure. Effects of the major geometry and working parameters on the lubrication performance (the pressure, film thickness, temperature rise and shear stress), are investigated. The results show that the enlargement of normal module, normal pressure angle, helix angel, and transmission ratio is beneficial for pitting resistance, and that the excessive crowned can debase the contact fatigue strength. It is indicated that severe thermal deformation and scuffing are prone to generation under large load and speed.
- Published
- 2017
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132. An enhanced flexible dynamic model and experimental verification for a valve train with clearance and multi-directional deformations
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Changjiang Zhou, Bo Hu, Liping He, and Siyu Chen
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Engineering ,Acoustics and Ultrasonics ,Rocker arm ,business.industry ,Mechanical Engineering ,Rotational speed ,02 engineering and technology ,Structural engineering ,Condensed Matter Physics ,01 natural sciences ,Finite element method ,Contact force ,Polynomial interpolation ,Computer Science::Robotics ,020303 mechanical engineering & transports ,0203 mechanical engineering ,Mechanics of Materials ,0103 physical sciences ,Piecewise ,Torque ,Elasticity (economics) ,business ,010301 acoustics - Abstract
An enhanced flexible dynamic model for a valve train with clearance and multi-directional deformations is proposed based on finite element method (FEM), and verified by experiment. According to the measured cam profile, the available internal excitations in numerical solution to the model are achieved by using piecewise cubic Hermite interpolating polynomial. The comparative analysis demonstrates that the bending deformation of the rocker arm is much larger than the radial deformation, signifying the necessities of multi-directional deformations in dynamic analysis for the valve train. The effects of valve clearance and cam rotation speed on contact force, acceleration and dynamic transmission error (DTE) are investigated. Both theoretical predictions and experimental measurements show that the amplitudes and fluctuations of contact force, acceleration and DTE become larger, when the valve clearance or cam speed increases. It is found that including the elasticity and the damping will weaken the impact between the rocker arm and the valve on the components (not adjacent to the valve) at either unseating or seating scenario. Additionally, as valve clearance or cam rotation speed becomes larger, the valve lift and the working phase decrease, which eventually leads to inlet air reduction. Furthermore, our study shows that the combustion rate improvement, input torque, and components durability can be improved by tuning valve clearance or adjustment the cam profile.
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- 2017
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133. Isomerization effect of triphenylamine-acridine derivatives on excited-state modification, photophysical property and electroluminescence performance
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Changjiang Zhou, Yu Gao, Bing Yang, Tingke Zhang, Haichao Liu, Weijun Li, Shitong Zhang, Qing Su, Qiaolin Wu, and Jiangshan Chen
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Photoluminescence ,Process Chemistry and Technology ,General Chemical Engineering ,Solvatochromism ,02 engineering and technology ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Triphenylamine ,Photochemistry ,01 natural sciences ,0104 chemical sciences ,chemistry.chemical_compound ,chemistry ,Excited state ,Acridine ,OLED ,0210 nano-technology ,HOMO/LUMO ,Isomerization - Abstract
Charge-transfer (CT) state is becoming a useful excited state to design next-generation luminescence materials for high-performance organic light-emitting diode (OLED). However, strong CT state usually causes serious decrease in photoluminescence (PL) efficiency due to the small overlap between HOMO and LUMO. In order to harvest both high exciton utilization and high PL efficiency in fluorescent OLEDs, figuring out the strategy of fine modification of CT component in excited state through structural modulation is important. In this work, four donor–acceptor structure triphenylamine (TPA) - acridine (AC) isomers (TPA-9AC, TPA-1AC, TPA-2AC and TPA-3AC) were designed and synthesized to investigate structure-property relationship between isomerization effect and excited state properties. Density functional theory (DFT) calculations and solvatochromic absorption, emission and photoluminescence decay spectra are carried out for the deep understanding of their emissive state character. The four isomers exhibit gradually increased PL efficiency from low-polarity hexane to medium-polarity tetrahydrofuran (THF), which could be assigned to the formation of hybridized local and charge-transfer (HLCT) states and effectively suppressed non-radiative transition arised from acridine in medium-polarity solvents. Among four isomers, TPA-3AC achieved the best EL performance, due to the proper LE and CT compositions in the emissive state, demonstrating that isomerization of donor and acceptor functional moieties is an effective approach for structural modification for high-efficiency fluorescent OLED emitters.
- Published
- 2017
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134. Analytical solution to bending and contact strength of spiral bevel gears in consideration of friction
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Bo Hu, Zuodong Li, Changjiang Zhou, Haifei Zhan, and Xu Han
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0209 industrial biotechnology ,Engineering ,business.product_category ,Normal force ,business.industry ,Spiral bevel gear ,Mechanical Engineering ,Tooth surface ,02 engineering and technology ,Structural engineering ,Bending ,Physics::Classical Physics ,Condensed Matter Physics ,020303 mechanical engineering & transports ,020901 industrial engineering & automation ,Contact mechanics ,0203 mechanical engineering ,Flexural strength ,Mechanics of Materials ,Shear strength ,Bevel gear ,General Materials Science ,business ,Civil and Structural Engineering - Abstract
Friction is not considered in the calculation of load capacity for spiral bevel gears according to either ISO or AGMA gear standard, and friction effects on the bending, contact and shear of the gears have rarely been discussed. In this regard, the present work establishes analytical solutions to calculate bending and contact strength for spiral bevel gears incorporating friction on the tooth surface, which are verified by ISO gear standard and finite element method (FEM). The bending strength is calculated based on Lewis cantilever beam approximation, utilizing the modified normal force and the friction component. The modified normal force is derived at the highest point of single tooth contact (HPSTC) in the normal equivalent gear. Follow Hertz contact theory, the contact strength is calculated when the modified normal force and the friction component are exerted at the lowest point of single tooth contact (LPSTC) in the normal equivalent gear. The calculated bending and contact stresses agree well with those obtained from the FEM analysis while considering the influence of friction. Both theoretical predictions and FEM analysis have shown that friction has a crucial effect on load capacity of a spiral bevel gear drive, and that it exerts stronger influence on the bending strength (compared with the contact strength). When friction coefficients become larger (with the same input torque), the bending stress considering only the modified normal force decreases at HPSTC, whereas it increases if both the modified normal force and the friction component are included. In comparison, the contact stress will increase at LPSTC under both scenarios. Furthermore, it is illustrated that shear strength check of the tooth is necessary as large friction occurs in the contact zone. This developed analytical solution can be well applied to the determination of load capacity of spiral bevel gears, especially under harsh working conditions or in the demand for higher performance.
- Published
- 2017
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135. Discrete Dimeric Anthracene Stackings in Solids with Enhanced Excimer Fluorescence
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Changjiang Zhou, Bing Yang, Yunpeng Ge, Yue Shen, Yating Wen, Haichao Liu, Dengli Cong, Jun Wang, Ling Ye, Xiaohui Tang, and Bao Li
- Subjects
Anthracene ,Intermolecular force ,02 engineering and technology ,General Chemistry ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,Photochemistry ,Excimer ,01 natural sciences ,Fluorescence ,0104 chemical sciences ,Organic semiconductor ,chemistry.chemical_compound ,chemistry ,Optical materials ,General Materials Science ,0210 nano-technology ,Luminous efficacy - Abstract
Polyaromatic compounds are significant members of leading candidates for organic semiconductors and optical materials. However, a thorny problem of polyaromatic materials is that their good emissive abilities in solutions are seriously weakened in solids due to strong π–π interactions between aromatics. As a typical case, the intermolecular π–π interaction tends to form excimers for polyaromatic system, which were always considered to quench fluorescence and decrease luminous efficiency in the past decades. Herein, anthracene is modified by meta-substituted bromobenzene to facilitate the formation of discrete dimeric stack in solids, leading to the enhanced anthracene excimer fluorescence. Particularly, instead of excimer quenching fluorescence, the more anthracene dimers in solids, the higher fluorescence efficiency, namely, excimer-induced enhanced solid-state emission. This work not only provides a meta-substituted strategy for molecular design to form excimer in solids but also demonstrates that high-...
- Published
- 2017
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136. Normal and tangential oil film stiffness of modified spur gear with non-Newtonian elastohydrodynamic lubrication
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Xu Han, Zeliang Xiao, Changjiang Zhou, and Siyu Chen
- Subjects
Materials science ,Mechanical Engineering ,Stiffness ,Rotational speed ,02 engineering and technology ,Surfaces and Interfaces ,021001 nanoscience & nanotechnology ,Non-Newtonian fluid ,Surfaces, Coatings and Films ,Physics::Fluid Dynamics ,Shear rate ,Pressure angle ,Viscosity ,020303 mechanical engineering & transports ,0203 mechanical engineering ,Mechanics of Materials ,Lubrication ,Shear stress ,medicine ,Composite material ,medicine.symptom ,0210 nano-technology - Abstract
A new normal stiffness model of the oil film is established by the viscous-elastic fluid between a spur gear drive being equivalent to a massless spring element, and the tangential stiffness model is proposed according to the hypothesis of equal shear stress on laminar element surfaces. Effects of operating parameters (contact force and rotation speed) and geometry parameters (module, tooth number, pressure angle and modification) on the oil film stiffness from the root to the tip are investigated. The results show that the amplitude and fluctuation of the stiffness are closely related to the shear rate, effective viscosity and curvature radii. It is indicated that the rational parameter match is valid in mesh impact reduction and stationarity enhancement.
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- 2017
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137. Folding-Induced Spin-Orbit Coupling Enhancement for Efficient Pure Organic Room-Temperature Phosphorescence.
- Author
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Guocui Pan, Zhiqiang Yang, Haichao Liu, Yating Wen, Xiangyu Zhang, Yue Shen, Changjiang Zhou, Shi-Tong Zhang, and Bing Yang
- Published
- 2022
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138. Review for 'An improved stiffness model for line contact elastohydrodynamic lubrication and its application in gear pairs'
- Author
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Changjiang Zhou
- Subjects
Materials science ,medicine ,Lubrication ,Stiffness ,Mechanics ,Line (text file) ,medicine.symptom - Published
- 2019
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139. Visualization of Ultrasensitive and Recyclable Dual-Channel Fluorescence Sensors for Chemical Warfare Agents Based on the State Dehybridization of Hybrid Locally Excited and Charge Transfer Materials
- Author
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Changjiang Zhou, Yining Lv, Siyu Chang, Bing Yang, Xiaobai Li, Shitong Zhang, Wanqi Mo, Huaqian Liu, and Hongwei Ma
- Subjects
Chemical Warfare Agents ,Chemistry ,010401 analytical chemistry ,Static Electricity ,Charge (physics) ,Nanotechnology ,DUAL (cognitive architecture) ,010402 general chemistry ,01 natural sciences ,Fluorescence ,Sarin ,0104 chemical sciences ,Analytical Chemistry ,Visualization ,Organophosphorus Compounds ,Spectrometry, Fluorescence ,Limit of Detection ,Excited state ,Equipment Reuse ,Humans ,State (computer science) ,Communication channel ,Fluorescent Dyes ,Reagent Strips - Abstract
Simple and fast detection of chemical warfare agents vapor is necessary and urgent to fight against uncertain terrorist attacks and wars. In this contribution, inspired by the design of the hybrid locally excited and charge transfer (HLCT) excited state, two fast and highly sensitive visualization and fluorescence probes for DCP detection with relative small interstate coupling (J) TPA-2AC and TPA-9AC are reported. Upon exposure to saturated DCP vapor, the TPA-9AC test strips exhibited a rapid fluorescent response in no more than 1 s, accompanied by a change of the color from green to red. The detection limit of the test strips can be estimated as sensitive as 0.15 ppb, which is far superior to the "harmless" level (7 ppb) of human response to acute sarin exposure. More impressively, the fluorescent intensity of the test strips can be quickly restored when exposed to ammonia vapor for cyclic utilization, demonstrating an application prospect in the real-time detection of chemical warfare agents.
- Published
- 2019
140. Segment selection in cultural noise recordings for imaging near-surface surface waves
- Author
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Chaoqiang Xi, Jianghai Xia, Jingyin Pang, Hongyu Zhang, Feng Cheng, Tianyu Dai, Ya Liu, Ling Ning, and Changjiang Zhou
- Subjects
Physics ,Surface (mathematics) ,Noise ,Surface wave ,Acoustics ,Selection (genetic algorithm) - Published
- 2019
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141. 3D Triptycene‐Fused Acridine Electron Donor Enables High‐Efficiency Nondoped Thermally Activated Delayed Fluorescent OLEDs
- Author
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Qun Zhan, Taian Huang, Ziyang Xie, Chuluo Yang, Chun-Sing Lee, Yang Zou, Changjiang Zhou, and Chen Cao
- Subjects
chemistry.chemical_compound ,Materials science ,chemistry ,Triptycene ,Acridine ,OLED ,Electron donor ,Photochemistry ,Fluorescence ,Atomic and Molecular Physics, and Optics ,Electronic, Optical and Magnetic Materials - Published
- 2021
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142. Using ambient noise tomography and MAPS for high resolution stratigraphic identification in Hangzhou urban area
- Author
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Changjiang Zhou, Xinhua Chen, Jingyin Pang, Hongyu Zhang, Huaixue Xing, and Xiaojun Chang
- Subjects
geography ,geography.geographical_feature_category ,010504 meteorology & atmospheric sciences ,Bedrock ,Ambient noise level ,Traffic noise ,Inversion (geology) ,Borehole ,010502 geochemistry & geophysics ,01 natural sciences ,Geophysics ,Passive seismic ,Tomography ,Seismology ,Geology ,Noise (radio) ,0105 earth and related environmental sciences - Abstract
Near-surface ( urban sustainable development and expansion. Complex urbanized environments, however, limit the application of traditional active-source seismic surveys . Passive seismic surveys provide an alternative for investigating near-surface structures by utilizing abundant traffic noise. We presented a case study of fine-scale shear-wave velocity (Vs) structure imaging in the Hangzhou urban area (eastern China) and compared inversion results of ambient noise tomography and multichannel analysis of passive surface wave (MAPS). Noise data were recorded within one day by a dense seismic network (130 m × 120 m). The average adjacent station interval is about 10 m. Our goal is to investigate the top 100 m of the subsurface at the survey area. The two inverted Vs models by tomography and MAPS are similar and they both tally with the logging data. The subsurface geology structures are analyzed based on tomography inversion results and borehole data. The bedrock surface is determined at about 60 m depth and a high-velocity layer is found at around 45– 50 m depth. The sedimentary formation and bedrock in the survey area are further stratified under the control of borehole data.
- Published
- 2021
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143. Nonlinear tribo-dynamic model and experimental verification of a spur gear drive under loss-of-lubrication condition
- Author
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Bo Hu, Changjiang Zhou, Siyu Chen, and Hong-Bing Wang
- Subjects
0209 industrial biotechnology ,Materials science ,business.industry ,Mechanical Engineering ,Work (physics) ,Aerospace Engineering ,Natural frequency ,02 engineering and technology ,Structural engineering ,01 natural sciences ,Noise (electronics) ,Computer Science Applications ,Vibration ,Nonlinear system ,020901 industrial engineering & automation ,Control and Systems Engineering ,Tooth wear ,0103 physical sciences ,Signal Processing ,Lubrication ,business ,010301 acoustics ,Bifurcation ,Civil and Structural Engineering - Abstract
Gearbox is required to serve for ≥ 30 min in helicopter design to improve survivability, when the gear drive loses lubrication due to battle damage. Under such loss-of-lubrication condition, tooth friction, wear and temperature pose serious problems to dynamic performance of gears. Therefore, a nonlinear tribo-dynamic model of spur gear drives is established and experimentally validated in this work. The time-varying friction coefficient is predicted under loss-of-lubrication condition on the basis of computational inverse technique. The temperature rise and tooth wear caused by friction were included by using thermal network model and dynamic wear model. The flexibility of gear shafts and the gyroscopic effect of gear rotors are also considered. The results indicate the gyroscopic effect apparently affects the natural frequency of the gear drive, while friction has negligible effect on the natural frequency but has considerable effect on the nonlinear behavior. The influence of temperature and gyroscopic effect on nonlinear behavior are reflected in the region of middle and high speed, while tooth wear mainly affects the bifurcation at the middle speed. In addition, tooth wear not only aggravates gear vibration but also can change the phase of dynamic transmission error. The analysis and experiment results can be an important reference in reducing friction and wear, restraining nonlinear behavior, and reducing vibration and noise.
- Published
- 2021
- Full Text
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144. A novel thermal network model for predicting the contact temperature of spur gears
- Author
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Bo Hu, Hong-Bing Wang, Changjiang Zhou, and Mingcai Xing
- Subjects
Convection ,Work (thermodynamics) ,Materials science ,020209 energy ,Bulk temperature ,General Engineering ,02 engineering and technology ,Mechanics ,Physics::Classical Physics ,Condensed Matter Physics ,Thermal conduction ,01 natural sciences ,010305 fluids & plasmas ,Pressure angle ,Flash (manufacturing) ,0103 physical sciences ,Thermal ,0202 electrical engineering, electronic engineering, information engineering ,Torque - Abstract
This paper proposes a thermal network model to predict the contact temperature of spur gears. A crucial parameter in gear scuffing evaluation is the contact temperature, which comprises the bulk and flash temperatures. Herein, thermal network models of gear bulk temperature and flash temperature are established, by dispersing tooth into multiple temperature elements connected by the thermal resistances of heat conduction and heat convection. The thermal network model of gear bulk temperature is verified by the finite element model and previous work, and the presented model for gear flash temperature is validated by Blok flash temperature formula. Following ISO standard, gear scuffing is evaluated by comparing the contact temperature with scuffing critical temperature. The effects of geometric and operating parameters on the gear temperature are subsequently investigated. Contact temperature is found to decrease with increased tooth width, pressure angle and module, but increases with increased rotational velocity and input torque. These findings indicate that reasonable geometric and operating parameter matching are beneficial for increasing gear-scuffing resistance.
- Published
- 2021
- Full Text
- View/download PDF
145. Prediction and validation of dynamic characteristics of a valve train system with flexible components and gyroscopic effect
- Author
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Lairong Yin, Bo Hu, Changjiang Zhou, and Hong-Bing Wang
- Subjects
Centrifugal force ,0209 industrial biotechnology ,Computer science ,Rotor (electric) ,Mechanical Engineering ,Camshaft ,Stiffness ,Bioengineering ,Natural frequency ,Gyroscope ,02 engineering and technology ,Computer Science Applications ,law.invention ,Vibration ,Stress (mechanics) ,020303 mechanical engineering & transports ,020901 industrial engineering & automation ,0203 mechanical engineering ,Mechanics of Materials ,Control theory ,law ,medicine ,medicine.symptom - Abstract
Flexibility and inner stress of transmission components are main considerations in the development of high-precision and lightweight engines. Gyroscopic effect of rotary shaft and rotor should also be considered in high-speed engines. Therefore, an elastic dynamic model of a valve train system is proposed. The model includes multiaxial flexibilities of camshaft and linkages, gyroscopic effect of the camshaft and cam rotor, centrifugal force of cams and friction force and moment of the cam–tappet pair. Then, the natural frequency, mode shape, pushrod stress and housing vibration are predicted using the proposed model. Results show that the gyroscopic effect of the rotors and camshaft apparently affects the natural frequency of the system by changing the camshaft stiffness. The proposed model can effectively predict the dynamic stress, as proven by a stress experiment. In addition, idling and maximum working speeds are recommended using the predicted model and verified by a vibration experiment. Thus, the proposed model can be an important reference in engine adjustment, improvement of component durability and determination of idling and maximum speeds.
- Published
- 2021
- Full Text
- View/download PDF
146. Effects of centring error and angular misalignment on crack initiation life in herringbone gears
- Author
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Haoye Wang, Luyuan Ning, Changjiang Zhou, and Lewei Tang
- Subjects
Materials science ,business.product_category ,Plane (geometry) ,business.industry ,Work (physics) ,General Engineering ,Contact analysis ,020101 civil engineering ,02 engineering and technology ,Structural engineering ,Herringbone gear ,0201 civil engineering ,Stress (mechanics) ,Centring ,020303 mechanical engineering & transports ,0203 mechanical engineering ,Crack initiation ,General Materials Science ,business ,Stress concentration - Abstract
The effects of centring error and angular misalignment on crack initiation life in herringbone gears are investigated in this work. Herringbone gears with centring error or angular misalignment are modelled for contact analysis. A crack initiation life model of standard and error gears is proposed in accordance with tooth stress history and a critical plane method for nonproportional loading. Then, the effects of centring error and angular misalignment on crack initiation life in herringbone gears are investigated. Results show that centring error and angular misalignment sharply reduce crack initiation life, but a moderate tip relief can eliminate stress concentration and extend crack initiation life. Furthermore, angular adjustment balances the load distribution of the left and right teeth in herringbone gears with centring error, improving tooth crack initiation life.
- Published
- 2021
- Full Text
- View/download PDF
147. Urban near-surface imaging from ambient noise tomography using dense seismic networks
- Author
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Ling Ning, Jingyin Pang, Changjiang Zhou, Binbin Mi, Chaoqiang Xi, Jianghai Xia, Hongyu Zhang, Huaixue Xing, Xiaojun Chang, and Ya Liu
- Subjects
Surface (mathematics) ,Optics ,business.industry ,Ambient noise level ,Tomography ,business ,Geology - Abstract
It is of scientific and engineering significance to extract surface wave signals from urban ambient noise for fine-scale three-dimensional velocity structure imaging of underground medium. A series of issues such as ambient noise characteristics in urban environment, observation system design and resolution of small-scale imaging, have put forward a lot of new requirements and challenges to traditional methods and technologies. We utilized the dense array with its aperture extend below hundred meters in Hangzhou urban area, to carry out the ambient noise data acquisition experiments within one day. Based on the time-frequency analysis of noise cross-correlations, we conducted surface wave travel time tomography. Finally, the phase velocity slices were inverted to build a three-dimensional S-wave velocity structure, and the profiles were compared with the drilling data for validations. We concluded that these geometry and processing parameters adopted in the urban environment are feasible for near-surface tomography and can meet the demands of three-dimensional geological survey in cities efficiently.
- Published
- 2021
- Full Text
- View/download PDF
148. Design and analysis of high-speed cam mechanism using Fourier series
- Author
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Bo Hu, Lin Ma, Changjiang Zhou, and Siyu Chen
- Subjects
0209 industrial biotechnology ,Engineering ,business.industry ,Mechanical Engineering ,Bioengineering ,02 engineering and technology ,Transfer function ,Displacement (vector) ,Computer Science Applications ,Computer Science::Robotics ,Mechanism (engineering) ,Error function ,Jerk ,020303 mechanical engineering & transports ,020901 industrial engineering & automation ,0203 mechanical engineering ,Mechanics of Materials ,Control theory ,Torque ,business ,Fourier series ,Cam follower - Abstract
This study proposes an innovative and comprehensive method for the design and analysis of a high-speed cam mechanism. In the proposed method, the displacement function of the cam follower is described using Fourier series. The coefficients of the series are obtained by constraint equations during the cam rise period and the minimum principle of displacement error function (where, error function refers to the variance between actual displacement and ideal displacement of the cam follower during the dwell). The validity of the proposed design method is verified through a case study with focus on high-speed cam mechanism design. In the design case, kinematic characteristic analysis of this cam follower shows that the order of continuous derivative of displacement transfer function is higher, the characteristic value of its dynamic torque is smaller, and its jerk at the impact point is smaller than some common disc cam mechanisms. The results indicate that the proposed method can reduce the vibration of the cam mechanisms and its impact velocity is smaller than the existing design methods.
- Published
- 2016
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- View/download PDF
149. Wireless measurement and dynamic contact analysis on the root stress of a light-load spur gear drive
- Author
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Bo Hu, Lin Ma, Siyu Chen, and Changjiang Zhou
- Subjects
0209 industrial biotechnology ,Engineering ,business.product_category ,Spiral bevel gear ,business.industry ,Mechanical Engineering ,Coordinate system ,Root (chord) ,02 engineering and technology ,Structural engineering ,Physics::Classical Physics ,Signal ,Stress (mechanics) ,020303 mechanical engineering & transports ,020901 industrial engineering & automation ,Non-circular gear ,0203 mechanical engineering ,Machining ,Torque ,business ,ComputingMethodologies_COMPUTERGRAPHICS - Abstract
This paper carries out the experimental and numerical investigations on the root stress of a light-load spur gear drive. An improved gear test rig is developed to enable the dynamic root stress of a light-load spur gear drive to be wirelessly measured, and the signals of root strain, rotational speeds and torques of input/output gear shafts are sent or received wirelessly. After the random electrical noise is eliminated by multi-point average method, the key parameters of dynamic contact analysis on the root stress (rotational speeds and torque) are obtained, and the root strain signal is converted into root stress. Based on the curve of the measured root stress, the impact of meshing teeth and the alternative variation in the single and double pair gear meshing can be attained quantitatively. The geometric model of gear is developed by the generative machining principle and the coordinate transformation method. Then, the dynamic contact analysis is performed by the display centre difference metho...
- Published
- 2016
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- View/download PDF
150. Analysis of Gear Strength by Static and Dynamic Finite Element Methods
- Author
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Si Yu Chen, Lin Ma, and Changjiang Zhou
- Subjects
Engineering ,Non-circular gear ,Computer simulation ,business.industry ,Face (geometry) ,Contact analysis ,General Medicine ,Structural engineering ,Bearing capacity ,Static analysis ,business ,Statics ,Finite element method - Abstract
As key factor of numerical simulation for gear strength, namely determination of effective loads between meshing teeth profiles, their numerical calculation principles of static and dynamic finite element methods are analyzed according to the loads on gear teeth. The static analysis of gear strength can be classified to effective statics and static contact analysis, and the numerical simulation method for face distribution as the rule of Hertz contact is advanced. The differences between static and dynamic contact and their influences in results are researched. Compared with the empirical formulas, the analytical results about bearing capacity of gear drive under different effective loads show: (1) As the sequence of concentrated force, linear distribution force, face distribution force as the rule of Hertz contact, static contact analysis, the accuracy and reliability of calculating results under different effective loads are improved, especially the results from face distribution and static contact being very close. (2) Dynamic contact analysis can be used to simulated the effect well. The above studies could be referenced to calculation in bearing capacity of gear drive.
- Published
- 2016
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